EP2045360A1 - Procédé de fabrication d'un composant en acier par façonnage à chaud et composant en acier fabriqué par façonnage à chaud - Google Patents
Procédé de fabrication d'un composant en acier par façonnage à chaud et composant en acier fabriqué par façonnage à chaud Download PDFInfo
- Publication number
- EP2045360A1 EP2045360A1 EP07117719A EP07117719A EP2045360A1 EP 2045360 A1 EP2045360 A1 EP 2045360A1 EP 07117719 A EP07117719 A EP 07117719A EP 07117719 A EP07117719 A EP 07117719A EP 2045360 A1 EP2045360 A1 EP 2045360A1
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- EP
- European Patent Office
- Prior art keywords
- coating
- steel
- flat
- product
- base layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 127
- 239000010959 steel Substances 0.000 title claims abstract description 127
- 238000000034 method Methods 0.000 title claims abstract description 53
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 238000000576 coating method Methods 0.000 claims abstract description 114
- 239000011248 coating agent Substances 0.000 claims abstract description 111
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 33
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 33
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 29
- 238000010438 heat treatment Methods 0.000 claims abstract description 25
- 229910052742 iron Inorganic materials 0.000 claims abstract description 25
- 230000008569 process Effects 0.000 claims abstract description 11
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 9
- 239000000956 alloy Substances 0.000 claims abstract description 9
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 3
- 229910000712 Boron steel Inorganic materials 0.000 claims abstract 3
- PALQHNLJJQMCIQ-UHFFFAOYSA-N boron;manganese Chemical compound [Mn]#B PALQHNLJJQMCIQ-UHFFFAOYSA-N 0.000 claims abstract 3
- 238000003856 thermoforming Methods 0.000 claims description 25
- 238000001816 cooling Methods 0.000 claims description 9
- 238000005246 galvanizing Methods 0.000 claims description 9
- 238000005269 aluminizing Methods 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 230000000284 resting effect Effects 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000005554 pickling Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000011253 protective coating Substances 0.000 claims 1
- 239000011701 zinc Substances 0.000 abstract description 54
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 10
- 238000005240 physical vapour deposition Methods 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 5
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 239000010703 silicon Substances 0.000 abstract description 2
- 238000005275 alloying Methods 0.000 abstract 1
- 238000010923 batch production Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 52
- 229910000789 Aluminium-silicon alloy Inorganic materials 0.000 description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 18
- 230000007797 corrosion Effects 0.000 description 14
- 238000005260 corrosion Methods 0.000 description 14
- 239000000758 substrate Substances 0.000 description 7
- 208000027418 Wounds and injury Diseases 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- 238000000137 annealing Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 230000003746 surface roughness Effects 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000003618 dip coating Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000004210 cathodic protection Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000797 Ultra-high-strength steel Inorganic materials 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
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- 230000003111 delayed effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 235000001892 vitamin D2 Nutrition 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D7/00—Modifying the physical properties of iron or steel by deformation
- C21D7/02—Modifying the physical properties of iron or steel by deformation by cold working
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0278—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
- C21D9/48—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals deep-drawing sheets
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0224—Two or more thermal pretreatments
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/024—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by cleaning or etching
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/12—Aluminium or alloys based thereon
Definitions
- the invention relates to a method for producing a steel component provided with a metallic coating which protects against corrosion, in particular by a cathodic protective effect, by thermoforming a flat steel product produced from a low-alloy tempered steel. Moreover, the invention relates to a steel component produced by thermoforming a flat steel product and provided with a corrosion protection coating which protects against corrosion, in particular by a cathodic protective action.
- a process that allows the production of correspondingly high-strength and at the same time thin-walled steel components is hot-press hardening.
- hot press hardening a circuit board is first cut from a steel strip. This board is then heated to a thermoforming temperature that is typically above the Ar3 temperature of the particular steel material being processed. The thus heated board is then placed in a hot state in a forming tool and placed in the desired component shape. Subsequently, or meanwhile, there is a cooling of the molded component, in which a hardened or hardened structure is produced in the processed steel.
- the thus composed steel strip is according to the EP 0 971 044 B1 provided with a coating based on aluminum or an aluminum alloy.
- this coating is an AlSi coating which has Fe contents.
- the thus coated steel strip is heated to a temperature of more than 750 ° C, formed into a component and then cooled at a cooling rate, under which forms a hardness structure.
- the object of the invention was to provide an economical process for the production of high-strength steel components, which have optimized corrosion protection and are particularly suitable for use in automobile bodies.
- a suitably procured steel component should be created.
- a metallic coating is produced on a flat steel product produced from a low-alloy tempered steel, which consists of two successively applied in two process steps Layers is formed.
- the tempering steel may be, for example, a Mn-B steel, as it is already widely used in the prior art.
- the flat steel product produced from the suitably composed tempering steel is provided with an Al coating containing at least 85% by weight Al, with additional contents of up to 15% by weight present in the Al coating applied according to the invention could be.
- Typical variants of the Al coating applied according to the invention are a coating consisting almost entirely of Al or an AlSi variant in which the Si content of the applied AlSi coating is 8-12% by weight Si.
- a Zn coating is applied to this Al-coating, which consists of at least 90 wt .-% of zinc.
- the two-layered coated flat steel product is then heated to at least 750 ° C hot forming temperature. This results in the formation of an alloyed Al, Fe, Zn and Si base layer in which Al has the largest share, but Fe, Zn and Si emerge as essential ingredients.
- thermoforming temperatures of 850 to 950 ° C., in particular 850 to 900 ° C., are typically set according to the invention.
- the heated to the hot forming temperature flat steel product is thermoformed in a further step in a conventional manner to the respective component and in one accelerated for the desired training of the tempering or hardening structure accelerated.
- the heating to the thermoforming temperature can be preceded by a division of the flat product, which has previously been present as a strip in the manner according to the invention in two layers, into sheets.
- each of the individual coating steps may be preceded by a cleaning of the surface of the flat steel product or the coating applied thereto.
- coated flat steel product proved both for a direct, d. h as a one-step work step without previous cold forming performed thermoforming, as well as for an indirect, d. H. at least two-stage shaping characterized by a succession of cold working and hot working.
- each thermoforming carried out in a steel component according to the invention is a zinc alloy Surface having a zinc content of at least 60 wt .-%, in particular of at least 80 wt .-%, before. This results in a cathodic corrosion protection, which is clearly detectable electrochemically.
- the accelerated corrosion test salt spray test
- coatings produced according to the invention have a resistance to corrosion which is at least comparable to pure zinc coatings.
- the high level of Al having, between the Zn-dominated top layer and the respective steel substrate arranged base layer of the metallic total coating produced according to the invention protects it against excessive zinc and iron diffusion during the heat treatment in accordance with the invention preferably in the range of 750 to 900 ° C, in particular 850 to 900 ° C selected thermoforming temperatures.
- One of the advantages of the barrier effect of the base layer is the delayed formation of red rust on the surface.
- the base layer prevents zinc from reaching the grain boundaries of the steel substrate, which would lead to the risk of cracking during hot forming.
- the Al-Fe-Zn-Si-containing base layer of the total coating produced according to the invention moreover protects the steel substrate particularly effectively against oxidation with the oxygen of the environment.
- a steel component obtained in accordance with the invention bears a metallic coating which is formed by a base layer resting on the flat steel product and a cover layer lying on the base layer, the base layer containing at least 30% by weight Al, at least 20% by weight. % Fe and at least 3 wt .-% Si and the top layer at least 60 wt .-% Zn, in particular at least 80 wt .-%, and at least 5 wt .-% Al and up to 10 wt .-% Fe and up to 10 wt .-% Si has.
- the Al-coating can be applied by fire aluminizing as the first coating layer on the respective flat steel product.
- the Zn coating can then also be applied particularly economically in a comparable, known manner and proven in practice by hot-dip galvanizing onto the Al layer previously applied to the flat steel product.
- the Zn coating is deposited electrolytically on the Al coating as an alternative to hot-dip galvanizing.
- electrolytic galvanizing is preferably a layer with a Zn content of at least 99 wt .-% deposited.
- Another alternative way of applying the Zn layer is to deposit the Zn coating on the Al coating in a PVD process.
- PVD Physical Vapor Deposition
- At least one other element of Al, Mg or Fe may be included.
- the contents should not exceed 5% by weight Al, 5% by weight Mg and / or 0.5% by weight Si.
- the contents of other accompanying elements in the Zn coating should not exceed 1 wt .-% in total.
- the flat products coated according to the invention are passed through an acid bath which rinses the oxide layer off them, without attacking the surface of the flat steel product itself.
- the Oxidabtrag is controlled so that you get a favorable set for the electrolytic strip galvanizing surface.
- the process according to the invention can be carried out in a particularly economical manner when the Al coating and then the Zn coating and all the work steps required between the respective coating steps are completed in a sequence of operations continuously following each other.
- coated steel strip according to the invention proves to be particularly insensitive to those in hot forming in one Traces occurring even if the respective component receives a complex shape.
- the flat steel product may undergo at least one cold forming step before being heated to the hot forming temperature.
- the deformation can take place almost completely during the cold forming, so that in this case the hot forming step carried out after the cold forming represents rather a warm calibration with subsequent quenching in the tool.
- an invention according to the invention in two operations to deforming flat product applied metallic coating typically has a total thickness of 7 - 35 microns on.
- a base layer which is directly on the flat steel product and consists predominantly of Al and additional Fe, Zn and Si contents, on which predominantly Zn and additional contents are present Al, Si and Fe existing cover layer is located.
- the base layer has at least 30 wt .-% Al, at least 20 wt .-% Fe, at least 3 wt .-% Si and at most 30 wt .-% Zn, while in the top layer at least 60 wt .-%, in particular at least 80 wt .-%, Zn at least 5 wt .-% Al and at most 10 wt .-% Fe and at most 10 wt .-% Si are present.
- the thickness of the base layer of the finished molded component according to the invention is typically 10 to 50 ⁇ m, in particular 15 to 25 ⁇ m, while the thickness of the cover layer is typically in the range of 5 to 20 ⁇ m, in particular 3 to 10 ⁇ m.
- FIGS. 1 to 5 various possibilities of practical implementation of the method according to the invention are given by way of example.
- the respective examples are based on a cold-rolled steel strip which is produced, for example, from the known 22MnB5 steel.
- Fig. 2 shows an example where the in Fig. 1 are passed through specified work steps, but not in a continuous, but in a broken sequence. So is in the in Fig. 2 Example given after the passing of the previously hot-rolled steel strip, the strip wound into a coil, brought to an electrolytic coating device, cleaned there and dekapiert and then provided electrolytically with the applied to the AlSi coating Zn coating.
- the cold strip cleaning, fire aluminizing ie: annealing and passing through an AlSi melt bath
- hot dip galvanizing ie, cooling to the bath inlet temperature and passing through a Zn melt bath
- skin pass coating operations are performed in a continuous process while the in-line Fig. 4 illustrated example, the same steps so far be completed discontinuously, as there after the fire aluminizing provided with the AlSi coating tape is cooled to room temperature and placed in a hot-dip galvanizing plant before being annealed there and passed through the melt bath.
- Fig. 5 there is an example of a procedure in which the steel strip is first cleaned, then fire-aluminized (ie annealed and passed through an AlSi melt bath), then finish rolled, then cleaned, and finally by using a PVD method the Zn layer is coated.
- Fig. 6 shows in its left half the layer structure of a coating, as it is present in the inventive procedure before heating to thermoforming temperature. Accordingly, an alloy layer containing Al, Si and Fe is formed between the steel substrate and the overlying AlSi layer containing typically 90 wt% and 10 wt% Si.
- the AlSi layer (“first layer”) and the alloy layer together form the "base layer” of the overall coating.
- the Zn layer (“second layer”) which typically consists of 99% by weight of Zn and less than 1% by weight of Al, is applied to the "base layer" as the "top layer".
- Fig. 6 shows the layer structure of the overall coating, which is at a temperature of more than five minutes extending heating of the layer structure shown in the left half of 900 ° C.
- a base layer consisting of 40% by weight of Al, 30% by weight of Fe, 20% by weight of Zn and 5% by weight of Si, on which a covering layer consisting of 80% by weight of Zn, 16% by weight of Al, 2% by weight of Si and 2% by weight of Fe.
- Cover layer and base layer together form the total coating there as well.
- a steel strip made of a hardenable steel having a carbon content of 0.22%, a Mn content of 1.2%, a Cr content of 0.20% and a B content of 0.003% is referred to as a cold-rolled strip in annealed in a continuous hot dip coating line and coated with an AlSi melt.
- the tape was first cleaned in a cleaning part of the debris from the cold rolling process and then went through an annealing furnace by being heated to 750 ° C.
- the strip has been recrystallized in the annealing furnace in a protective gas atmosphere with 10% H 2 and balance N 2 recrystallizing.
- the tape After cooling to a temperature of 680 ° C (also still under inert gas 10% H 2 , balance N 2 ), the tape has entered an aluminum bath with a temperature of 660 ° C.
- the aluminum bath additionally contained about 10% by weight of silicon.
- the surface roughness of the strip provided with the AlSi coating is adjusted by temper rolling in a skin pass mill.
- the strip was then first chemically treated in an aqueous solution with 80 g / l HCl (hydrochloric acid) for 10 s at 40 ° C.
- Fig. 9 is shown for the existing on the thus produced component total coating.
- a steel strip of a hardenable steel is as a cold-rolled strip in a continuous Hot dip coating line annealed and coated.
- the tape has first been cleaned and annealed as in Example 1. Subsequently, it has undergone an aluminum-silicon bath (Si content 10%) whose temperature was 660 ° C. The thickness of the resulting AlSi coating then adjusted by means of wiping nozzles was 15 ⁇ m. After a cooling section, over which the tape has been cooled to 480 ° C, the tape is immersed in a second molten bath of zinc, which was provided with an addition of 0.2% Al. With the subsequent wiping a zinc coating thickness of 5 microns has been set. After cooling the strip to ⁇ 50 ° C, the setting of the surface roughness was carried out in a skin pass mill. Finally, the tape has been wound into a finished coil.
- a steel strip of a hardenable steel has been annealed and coated as a cold rolled strip in a continuous hot dip coating line.
- the tape is first cleaned as in Example 1, annealed and provided with an AlSi coating.
- the coating thickness set by the wiping nozzles is in this case 20 ⁇ m. After cooling the strip to ⁇ 50 ° C, the surface roughness was adjusted by temper rolling in a skin pass mill.
- the strip was first cleaned alkaline, then to be coated in a PVD module with a zinc coating of 3 microns. Finally, the tape has been wound into a finished coil.
- Blanks were cut from the coated strip for the hot forming process and heated in an oven at 900 ° C for 5 min. Subsequently, the boards are transferred by manipulator in a forming press and here converted into a component and cooled in the tool accelerated.
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- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
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Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07117719A EP2045360B1 (fr) | 2007-10-02 | 2007-10-02 | Procédé de fabrication d'un composant en acier par façonnage à chaud et composant en acier fabriqué par façonnage à chaud |
AT07117719T ATE535631T1 (de) | 2007-10-02 | 2007-10-02 | Verfahren zum herstellen eines stahlbauteils durch warmformen und durch warmformen hergestelltes stahlbauteil |
PCT/EP2008/063139 WO2009047183A1 (fr) | 2007-10-02 | 2008-10-01 | Procédé de production d'un composant en acier par façonnage à chaud, et composant en acier obtenu par façonnage à chaud |
US12/681,286 US20100294400A1 (en) | 2007-10-02 | 2008-10-01 | Method for producing a steel component by hot forming and steel component produced by hot forming |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07117719A EP2045360B1 (fr) | 2007-10-02 | 2007-10-02 | Procédé de fabrication d'un composant en acier par façonnage à chaud et composant en acier fabriqué par façonnage à chaud |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2045360A1 true EP2045360A1 (fr) | 2009-04-08 |
EP2045360B1 EP2045360B1 (fr) | 2011-11-30 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP07117719A Revoked EP2045360B1 (fr) | 2007-10-02 | 2007-10-02 | Procédé de fabrication d'un composant en acier par façonnage à chaud et composant en acier fabriqué par façonnage à chaud |
Country Status (4)
Country | Link |
---|---|
US (1) | US20100294400A1 (fr) |
EP (1) | EP2045360B1 (fr) |
AT (1) | ATE535631T1 (fr) |
WO (1) | WO2009047183A1 (fr) |
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WO2011054571A1 (fr) * | 2009-11-03 | 2011-05-12 | Voestalpine Stahl Gmbh | Réalisation de tôles recuites après galvanisation par traitement thermique de tôles revêtue par voie électrolytique |
WO2013000458A3 (fr) * | 2011-06-30 | 2013-04-11 | Benteler Automobiltechnik Gmbh | Procédé de production de pièces façonnées trempées à la presse |
WO2015036151A1 (fr) * | 2013-09-13 | 2015-03-19 | Thyssenkrupp Steel Europe Ag | Procédé de fabrication d'un élément de construction en acier doté d'un revêtement de protection anticorrosion métallique et élément de construction en acier |
DE102012214274B4 (de) * | 2011-08-12 | 2015-04-09 | GM Global Technology Operations, LLC (n.d. Ges. d. Staates Delaware) | Vordiffundierte Al-Si-Beschichtungen zur Verwendung bei einer schnellen Induktionsaufheizung von pressgehärtetem Stahl |
WO2016132194A1 (fr) * | 2015-02-19 | 2016-08-25 | Arcelormittal | Procede de fabrication d'une piece phosphatable a partir d'une tôle revêtue d'un revêtement a base d'aluminium et d'un revêtement de zinc |
EP2233598B1 (fr) | 2009-03-26 | 2017-05-03 | Bayerische Motoren Werke Aktiengesellschaft | Procédé de fabrication d'une pièce de formage en tôle pouvant être revêtue et/ou souple dotée d'un revêtement anticorrosion |
CN106795613A (zh) * | 2014-09-05 | 2017-05-31 | 蒂森克虏伯钢铁欧洲股份公司 | 具有Al涂层的扁钢产品及其制造方法和钢部件及其制造方法 |
WO2018153755A1 (fr) | 2017-02-21 | 2018-08-30 | Salzgitter Flachstahl Gmbh | Procédé de revêtement de tôles d'acier ou de bandes d'acier et procédé de fabrication d'éléments trempés à la presse à partir desdites tôles ou bandes |
CN111334775A (zh) * | 2018-12-18 | 2020-06-26 | 大众汽车有限公司 | 制造热成型且压硬化的钢板构件用的钢基质及热成型方法 |
WO2023202765A1 (fr) | 2022-04-20 | 2023-10-26 | Thyssenkrupp Steel Europe Ag | Produit plat en acier pourvu d'un revêtement en al, son procédé de fabrication, composant en acier et son procédé de fabrication |
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ES2345029B1 (es) * | 2010-04-19 | 2011-07-18 | Autotech Engineering, Aie | Componente estructural de un vehiculo y procedimiento de fabricacion. |
JP6113539B2 (ja) * | 2013-03-18 | 2017-04-12 | 日新製鋼株式会社 | めっき鋼板の製造方法 |
DE102014004657A1 (de) | 2014-03-29 | 2015-10-01 | Daimler Ag | Bauteil, insbesondere Strukturbauteil, für einen Kraftwagen, sowie Verfahren zum Herstellen eines Bauteils |
DE102017208727A1 (de) | 2017-05-23 | 2018-11-29 | Thyssenkrupp Ag | Verbesserung der Kaltumformeignung aluminiumbasierter Beschichtung durch Zulegieren von Erdalkalimetallen |
WO2020048602A1 (fr) * | 2018-09-06 | 2020-03-12 | Thyssenkrupp Steel Europe Ag | Tôle fine à froid zinguée aux propriétés tribologiques ii améliorées |
WO2020048601A1 (fr) * | 2018-09-06 | 2020-03-12 | Thyssenkrupp Steel Europe Ag | Tôle fine à froid zinguée dotée de propriétés tribologiques i améliorées |
KR20210070681A (ko) * | 2019-12-05 | 2021-06-15 | 주식회사 포스코 | 알루미늄계 합금 도금강판 및 그 제조방법 |
CN115261714A (zh) * | 2021-04-29 | 2022-11-01 | 宝山钢铁股份有限公司 | 一种压力容器用钢及其制备方法 |
WO2023132349A1 (fr) * | 2022-01-06 | 2023-07-13 | 日本製鉄株式会社 | Tôle d'acier pour estampage à chaud ainsi que procédé de fabrication de celle-ci, et corps moulé par estampage à chaud |
WO2023132350A1 (fr) * | 2022-01-06 | 2023-07-13 | 日本製鉄株式会社 | Tôle d'acier pour estampage à chaud ainsi que procédé de fabrication de celle-ci, et corps moulé par estampage à chaud |
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- 2007-10-02 AT AT07117719T patent/ATE535631T1/de active
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EP2233598B1 (fr) | 2009-03-26 | 2017-05-03 | Bayerische Motoren Werke Aktiengesellschaft | Procédé de fabrication d'une pièce de formage en tôle pouvant être revêtue et/ou souple dotée d'un revêtement anticorrosion |
WO2011054571A1 (fr) * | 2009-11-03 | 2011-05-12 | Voestalpine Stahl Gmbh | Réalisation de tôles recuites après galvanisation par traitement thermique de tôles revêtue par voie électrolytique |
WO2013000458A3 (fr) * | 2011-06-30 | 2013-04-11 | Benteler Automobiltechnik Gmbh | Procédé de production de pièces façonnées trempées à la presse |
DE102012214274B4 (de) * | 2011-08-12 | 2015-04-09 | GM Global Technology Operations, LLC (n.d. Ges. d. Staates Delaware) | Vordiffundierte Al-Si-Beschichtungen zur Verwendung bei einer schnellen Induktionsaufheizung von pressgehärtetem Stahl |
US9677145B2 (en) | 2011-08-12 | 2017-06-13 | GM Global Technology Operations LLC | Pre-diffused Al—Si coatings for use in rapid induction heating of press-hardened steel |
WO2015036151A1 (fr) * | 2013-09-13 | 2015-03-19 | Thyssenkrupp Steel Europe Ag | Procédé de fabrication d'un élément de construction en acier doté d'un revêtement de protection anticorrosion métallique et élément de construction en acier |
US10287647B2 (en) | 2013-09-13 | 2019-05-14 | Thyssenkrupp Steel Europe Ag | Method for producing a steel component having a metal coating protecting it against corrosion, and steel component |
US11692234B2 (en) | 2014-09-05 | 2023-07-04 | Thyssenkrupp Steel Europe Ag | Flat steel product with an AI-coating, method for producing the same, steel component and method for producing the same |
CN106795613A (zh) * | 2014-09-05 | 2017-05-31 | 蒂森克虏伯钢铁欧洲股份公司 | 具有Al涂层的扁钢产品及其制造方法和钢部件及其制造方法 |
US10669603B2 (en) | 2014-09-05 | 2020-06-02 | Thyssenkrupp Steel Europe Ag | Flat steel product with an Al-coating, method for producing the same, steel component and method for producing the same |
WO2016132194A1 (fr) * | 2015-02-19 | 2016-08-25 | Arcelormittal | Procede de fabrication d'une piece phosphatable a partir d'une tôle revêtue d'un revêtement a base d'aluminium et d'un revêtement de zinc |
WO2016132165A1 (fr) * | 2015-02-19 | 2016-08-25 | Arcelormittal | Procede de fabrication d'une piece phosphatable a partir d'une tole revetue d'un revetement a base d'aluminium et d'un revetement de zinc |
CN107250414A (zh) * | 2015-02-19 | 2017-10-13 | 安赛乐米塔尔公司 | 由涂覆有基于铝的涂层和锌涂层的板生产可磷酸盐化部件的方法 |
CN107250414B (zh) * | 2015-02-19 | 2019-04-02 | 安赛乐米塔尔公司 | 由涂覆有基于铝的涂层和锌涂层的板生产可磷酸盐化部件的方法 |
RU2686164C2 (ru) * | 2015-02-19 | 2019-04-24 | Арселормиттал | Способ изготовления фосфатируемой детали из листа, содержащего покрытие на основе алюминия и цинковое покрытие |
WO2018153755A1 (fr) | 2017-02-21 | 2018-08-30 | Salzgitter Flachstahl Gmbh | Procédé de revêtement de tôles d'acier ou de bandes d'acier et procédé de fabrication d'éléments trempés à la presse à partir desdites tôles ou bandes |
RU2729674C1 (ru) * | 2017-02-21 | 2020-08-11 | Зальцгиттер Флахшталь Гмбх | Способ нанесения покрытия на стальной лист или стальную полосу и способ изготовления закаленных под прессом деталей из них |
US11613791B2 (en) | 2017-02-21 | 2023-03-28 | Salzgitter Flachstahl Gmbh | Method for coating steel sheets or steel strips and method for producing press-hardened components therefrom |
CN111334775B (zh) * | 2018-12-18 | 2022-12-23 | 大众汽车有限公司 | 制造热成型且压硬化的钢板构件用的钢基质及热成型方法 |
CN111334775A (zh) * | 2018-12-18 | 2020-06-26 | 大众汽车有限公司 | 制造热成型且压硬化的钢板构件用的钢基质及热成型方法 |
WO2023202765A1 (fr) | 2022-04-20 | 2023-10-26 | Thyssenkrupp Steel Europe Ag | Produit plat en acier pourvu d'un revêtement en al, son procédé de fabrication, composant en acier et son procédé de fabrication |
Also Published As
Publication number | Publication date |
---|---|
EP2045360B1 (fr) | 2011-11-30 |
WO2009047183A1 (fr) | 2009-04-16 |
US20100294400A1 (en) | 2010-11-25 |
ATE535631T1 (de) | 2011-12-15 |
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