EP2031970A2 - Preparation destinee a ameliorer la constitution des plantes - Google Patents

Preparation destinee a ameliorer la constitution des plantes

Info

Publication number
EP2031970A2
EP2031970A2 EP07785531A EP07785531A EP2031970A2 EP 2031970 A2 EP2031970 A2 EP 2031970A2 EP 07785531 A EP07785531 A EP 07785531A EP 07785531 A EP07785531 A EP 07785531A EP 2031970 A2 EP2031970 A2 EP 2031970A2
Authority
EP
European Patent Office
Prior art keywords
preparation according
component
plants
substance
betaine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07785531A
Other languages
German (de)
English (en)
Inventor
Iradj Scharafat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tilco Biochemie GmbH
Original Assignee
Tilco Biochemie GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tilco Biochemie GmbH filed Critical Tilco Biochemie GmbH
Publication of EP2031970A2 publication Critical patent/EP2031970A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00—Other organic fertilisers
    • C05F11/10—Fertilisers containing plant vitamins or hormones
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05B—PHOSPHATIC FERTILISERS
    • C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants

Definitions

  • the invention relates to a preparation for improving the constitution of plants which has a first component and a second component which is different from the first component and in which the first component contains at least one organic substance and the second component contains at least one inorganic substance.
  • the object of the present invention is therefore to improve a preparation of the aforementioned type such that a comprehensive increased effectiveness is achieved.
  • a substance is contained, which has at least partially a betaine at least similar molecular structure.
  • the at least similar molecular structure to betaine leads to a significant increase in efficacy.
  • the corresponding substance has the effect of an inducer or a transfer substance.
  • the substance is combined with a second application-specific component.
  • Such an inducer stimulates the plant to produce its own substance from antibodies.
  • betaine, choline or betaine-based substances can be made synthetically or based on natural starting materials.
  • inexpensive production based on vinasse can occur.
  • Vinasse is typically present as an extract and has the extract composition explained in more detail below.
  • the extract contains a large number of solid, as well as colloidally and ionically dissolved non-sucrose substances with very different properties. They are either extracted from the sugar beets in the context of extract extraction or formed from the beet ingredients during extract extraction by chemical, microbiological and enzymatic processes. A large proportion of the nonsugar substances can be extracted faster than sucrose during extract extraction. These substances may undergo undesirable reactions under certain conditions.
  • the available nonsugar substances in the extract have different effects on the quality characteristics of the intermediates and of the purified extract. Table 1 shows the important properties of the non-sucrose substances of the extract in the extract purification.
  • Table 1 describes non-sucrose substances in the extract and their properties in an aqueous solution.
  • D-glucose D-fructose. These substances are converted to dyes and acids when heated.
  • - Amide glutamine, asparagine are converted by heating to ammonia and acids.
  • the sucrose content of the extract depends on the sucrose content of the sugar beet and the extraction guide and is between 12% and 18% a.
  • the purity of the extract in normal extract is between 85% and 91% and has a pH between 5.8 and 6.3.
  • the beet extract is a dispersed system in which heterogeneous particles are suspended.
  • the continuous phase consists of sucrose solution and the disperse phase consists of particle structures high molecular weight components, especially protein body, nucleoproteins, hemicellulose, polysaccharides, dyes and pectin.
  • the high-molecular components of the extract exert a great influence on the flow behavior of the extract.
  • the viscosity of beet extracts is influenced by the amount and type of high molecular weight non-sucrose substances. These colloids are also responsible for further structure formation and structure changes in extract purification that allow measurable changes for novel rheological detection of extract purification.
  • colloidal protein and pectin and in frost-damaged turnips dissolved polysaccharides such as dextran and levan in larger quantities.
  • the nitrogen compounds of sugar beets are of the order of 1.0-1.2%.
  • the nitrogen-containing organic substances are z.
  • proteins amino acid, amides, purine, pyrimidine, ammonium, organically bound nitrates and nitrites.
  • More than half of the nitrogen-containing components in sugar beets consist of protein substances (about 0.4 - 0.7%), of which At 0.14-0.73%, tain represents the largest proportion of proteins specific for the composition in sugar beet.
  • Protein substances consist of amino acids, which are protected by different bonds, such. As covalent bond, electrostatic bond, hydrogen bond and Van der Waals bond are linked together. Proteins of the extract are hydrophilic high-molecular, complicated compounds that can be hydrated by hydrogen bonding with water. This water is called hydration shell and causes an increase in the protein volume by a multiple.
  • the macromolecules of the protein are in principle polypeptide chains, of which two forms are possible: spherical and linear protein molecules. In the linear protein molecules, the chains are formed in the form of long bundles. In the case of globular proteins, the chains form spirals that assemble into spherical balls. The proteins are generally spherical in their native form. The conformation of the native macromolecule is destroyed when denatured by thermal or chemical agents. In this case, the chain, which is folded several times in the spherical colloid, unrolled and causes a formation as a linear shape of the molecule.
  • Sugar beet proteins are the most important constituent of the protoplasm and the cell wall, which also occur in the cell juice of sugar beet. More than 25% of the total sugar beet proteins are extracted in beet extract, depending on the extraction temperature and duration.
  • the proteins of the extract can be obtained either by strong acidification at a pH of 3.5, in the process of sugar production because of the great influence is not relevant to the sucrose degradation reaction (hydrolysis) or precipitates via alkalization (liming) by means of dehydration and flocculation at an optimum pH value end point of the preliming together with the pectin substances.
  • Betaine (trimethylglycine) is one of the main components of the sugar beet water-soluble nitrogen compounds, which is concentrated in the young, intensely growing sugar beet tissue. The biosynthesis of betaine occurs predominantly in the leaves, where a significantly higher betaine content is detected. The betaine content increases under salt and dry stress. In adult sugar beet, the betaine content is 0.14 - 0.73%, ie. H. 0,6 - 1,6 g / 100 g TS. The proportion of betaine nitrogen content in the total nitrogen content of the turnip is 14-20% and makes up 25-32% of the soluble nitrogen fraction of the turnip. Betaine is chemically very stable. Therefore, the conventional extract purification method is unable to remove the betaine from the extract. Betaine remains unchanged in thick juice, and there is an accumulation in the syrups of the sugar house up to 3 g / 100 g TS, and in the molasses up to 8 g / 100 g TS instead.
  • the proportion of total nitrogen in the molasses can be 33 - 42%. Therefore, one calls betaine as "molasses” or “harmful nitrogen compound". Betaine causes a decrease in the saccharosensitivity in the water and has a significant negative impact on the crystallization rate of the sucrose.
  • the pectin content of the beets is between 1 and 2% ie approx. 25 - 30 g / 100 g DM of the extracted cut zel.
  • the pectin content of the beet extract varies between 0.1-0.8 g / 100 g TS, according to different authors.
  • Pectin is the second high-molecular-weight constituent of the extract, in addition to the protein, which is of great importance for the occurrence of a flocculation point in preliming.
  • the building block of the actual pectin is D-galacturonic acid. This is linked in pectin a -1, 4-glycosidically to a polygalacturonic acid chain.
  • Pectins are macromolecules with a relative molecular weight between 15,000 and 70,000.
  • the pectin substances are five different structures. They are pectinic acid, pectates, pectin, pectinates and protopectin.
  • the pectin content of the extract is dependent on beet conditions, extraction conditions such as temperature, pH, duration of stay, chippings properties and the pressure water treatment.
  • the carboxyl groups of pectin are esterified with about 55% methanol. In beet pectin, 4% of the carboxyl groups are esterified with ethanol.
  • the secondary hydroxyl groups (OH groups 2 or 3 of the polygalacturonic acid) are additionally partially esterified with acetic acid.
  • the acetyl content of beet pectin is between 5 and 6%.
  • L-arabanose, D-galactose, L-rhamnose and ferulic acid occur together with the pectin (van der Poel et al., 2000).
  • Figure 1 shows the structure of a pectin chain.
  • Fig. 1 Structure of a pectin chain
  • pectin is saponified to a calcium pectate which is difficult to dissolve in water.
  • the pectin content of the extract has a negative influence on the crystallization of the CaCO3 crystals during the 1st carbonation and the filterability of the resulting calcium carbonate suspension of the 1st carbonation.
  • Dextran is a high molecular weight polysaccharide, which can be formed in the beets mainly as a metabolite of the hetero-fermentative lactic acid bacteria of the genus Leuconostoc mesenteroides and Leuconostoc dextranicum of the exo-enzyme dextran sucrase.
  • Table 2 shows the dextran and lava content of the extract and the purified extract from normal and frost damaged sugar beet.
  • Table 2 shows the levan and dextran contents of the extract and of the purified extract from normal and frost-damaged sugar beet.
  • the bacterial cell divides, the dextran sucrase is released and enters the medium, b. the sucrose is split,
  • the dextranes are configured by means of a branched chain of glucose molecules with a -1.6 in the main chain and a - 1.4 in the backbone (branches in C3 and C4 positions).
  • Figure 2 shows the structure of a dextran chain (van der Poel et al., 2000).
  • Fig. 2 Dextran molecules of Leuconostoc mesanterides
  • the dextran molecule has a filamentary structure with a molecular weight that may range from a few thousand to several millions, depending on the length of the main chain and the number of branches.
  • Some dextranes isolated from sugar beets have a specific rotation> - a ⁇ ⁇ 20 of 200 °
  • a warm weather after a frosty season thaws the frozen beets, and the microorganisms can invade and multiply in the frost-damaged beet tissue.
  • They form slimy substances, which mainly consist of dextran and levan (polysaccharide from fructose molecules). These polysaccharides are readily soluble in hot water and extract them. during the extraction process in the extraction water. They are responsible for the known processing difficulties, in particular for the filtration capacity of the calcium carbonate suspension of the 1st or 2nd carbonation in the frost campaigns.
  • the invention relates to preparations such.
  • Known such preparations are used individually and mixed to improve the nutrient requirements of crops and the soil or to improve the air, water and nutrient storage capacity of the soil.
  • the known preparations generally have a specific effect and the requirements for efficacy against diseases with good nutrient supply can not be met.
  • the above component combinations may additionally be mixed with known and practical fertilizers to achieve a broader and / or longer effect.
  • the preparations can be formulated as solid and liquid spraying, spraying or granulating agents.
  • the preparations can also be realized as a paste for brushing and as a solid formulation for spreading.
  • liquid and solid natural or synthetic organic or inorganic compounds and mixtures which bring about a resistance of the plants to fungal diseases, an increased growth and improvement of the health of the plants and / or increase in yield and better quality.
  • acids, bases and their organic and inorganic salts sulfur, sulfuric acid, sulfuric acid, phosphorus, phosphoric acid, phosphorous acid, nitric acid, hydrochloric acid, chlorine, potassium, potassium hydroxide, potassium oxide, hydroxide, sodium, sodium oxide, hydroxide, Sodium hydroxide, calcium, calcium lye, ammonia, ammonium lye, which have a fertilizing effect and resistance-promoting properties are used.
  • Beets, beetroot cane sugar or other plant species, extracts of molasses, vinasse, syrup, (microbial, chemically or physically digested), or manufactured synthetically.
  • Formulation with organic (eg laminarin and glucosides) or inorganic substances such as phosphoric acid, phosphorous acid, salts of phosphoric acid and phosphorous acids (K, Na, NH4, Mg, Ca, Fe, Mn, Cu, Zn, Al, etc.) phosphates , Pyrophosphates, also polyphosphates and phosphites, pyrophosphites and polyphosphites.
  • Formulating agents such as emulsifiers, wetting agents, adhesives, suspending agents.
  • Granulating substances such as kaolin or diatomaceous earth or organic substances, algins, pectinates, seaweed extracts (digested or cold-pressed), herbal extracts: stinging nettle, horsetail, humic acids, minerals (eg montmorillonite), compost, manure, grains, yeast, other plant residues, Silica, rock flour and other additives, amino acids, polysaccharides, sugars, honey, microorganisms for activation and import into the cells. Effect:
  • the mixtures of the abovementioned compounds, 1: 1 parts with vinasse from sugar beet lead to induced resistance (PRI formation) of the plants to diseases of the individual substances and are more effective than vinasse without addition.
  • the leaves of the plants are thicker, stronger, darker greener, healthier, less infested with plant diseases, such as mildew, and more sustainable in growth than all varieties.
  • the deciding factor is that the resistance strength increases as a result of PRl formation of the plants, with good growth of the plants.
  • the vinasse (betaine, betaine compounds and other proteins and ingredients) may contain in any amount and form a content of phosphorus (P2O5) of 2 to 50%, nitrogen (N) of 2 to 46% potassium (K2O) of 2 to 50% and sulfur 2 to 30%.
  • P2O5 phosphorus
  • N nitrogen
  • K2O potassium
  • NPK + AA NPK + Vinasse positive
  • NPK + AA NPK + Vinasse positive
  • the products may be dispersed as granules or formulated as liquid spraying, spraying, pouring agents. They can also be formulated with aids that cause a slow-release effect.
  • mixtures of seaweed extracts with vinasse with vinasse and, in particular, proved to be suitable for spraying, pouring or dipping NPK as beneficial.
  • the use of molasses and trace nutrients is also beneficial.
  • the solubility and the rate of action can be influenced by the respective chemical composition of the salt.
  • a long-term effect is supported by the addition of sodium, potassium, ammonium, calcium or their acids and alkalis.
  • Spurennähr comprise copper, zinc, manganese, molybdenum, etc. are advantageous for securing the nutrition of the plants. Proven all phosphite and phosphate compounds and sulfites have been found such.
  • composition of the preparations it should be pointed out again that in particular an addition to Vinasse + NPK, Mg with polysaccharides in digested algae to a targeted resistance of the plants and to protect the nutrients from leaching and fixation and continuous dosing of nutrients the plants that promote the health of the plants and fertilize the soil. lends.
  • acids, alkalis and salts which are formulated or granulated only in this composition with vinasee enhance plant tolerance.
  • the efficacy of the algal material used can be significantly improved by the process of digestion.
  • the digestion of the algae material for example in the form of algae flour, algae extracts and / or algae pastes, takes place by contact of the algae material with a digestion substance.
  • a digestion substance can for example consist of sodium oxide, hydroxide, carbonate and / or other salts or potassium oxide, hydroxide, carbonate and / or other salts or alkali metals.
  • Such digestion preferably takes place in a moist state of the algae material after addition of water.
  • the digestion is carried out with compounds of alkali metals or alkaline earth metals, in particular of potassium, sodium, ammonium and / or magnesium.
  • Particularly suitable compounds are oxides, hydroxides or carbonates.
  • the process of digestion can be done for example in stirred tanks or in rotating drums.
  • it is intended to use rotating drums with a substantially horizontal or oblique axis of rotation.
  • the process of digestion is preferably carried out gently with moderate mechanical stress on the algal material.
  • moderate mechanical stress on the algal material Depending on the respective digestion result may be a slight temperature of the algae material and thus a heat supply of advantage.
  • betaine With regard to the combination of betaine with phosphate and / or phosphite, it has been found that the phosphate leads to a linking of several betaine molecules. As a result, the effectiveness can be improved in certain applications. It has generally been found that betaine molecules have bipolar properties similar to water molecules. This assists penetration through the cell wall and facilitates the chaining of molecules. In general, it is expedient to carry out a combination of betaine with a second component in an application-specific manner.
  • An application of the preparation can be made via the soil, the roots of the plants, the stems or leaves of the plants and by injection into strains of the plants.
  • the invention also contemplates pharmaceutical or cosmetic applications.
  • the applications can be internal and / or external. With regard to external applications, mention should be made in particular of an application against athlete's foot.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Fertilizers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne une préparation destinée à améliorer la constitution des plantes et présente un premier composant et un second composant qui est différent du premier composant. Le premier composant renferme au moins une substance organique, et le second composant renferme au moins une substance inorganique. Le premier composant contient une substance présentant, au moins localement, une structure moléculaire au moins analogue à celle de la bétaïne.
EP07785531A 2006-06-26 2007-06-11 Preparation destinee a ameliorer la constitution des plantes Withdrawn EP2031970A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006029558 2006-06-26
PCT/DE2007/001030 WO2008000214A2 (fr) 2006-06-26 2007-06-11 Préparation destinée à améliorer la constitution des plantes

Publications (1)

Publication Number Publication Date
EP2031970A2 true EP2031970A2 (fr) 2009-03-11

Family

ID=38698712

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07785531A Withdrawn EP2031970A2 (fr) 2006-06-26 2007-06-11 Preparation destinee a ameliorer la constitution des plantes

Country Status (3)

Country Link
EP (1) EP2031970A2 (fr)
DE (1) DE112007001999A5 (fr)
WO (1) WO2008000214A2 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2340713A3 (fr) * 2009-12-18 2011-07-13 Tilco Biochemie GmbH Préparation pour le traitement de choux

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2473502A1 (fr) * 1980-01-11 1981-07-17 Doncoeur Armand Procede de preparation d'un engrais fluide thioxotropique a base de vinasse et produit obtenu
CZ257192A3 (en) * 1992-08-21 1994-03-16 Hofschneider Miroslav Liquid organo-mineral fertilizer based on molasses residues and process for preparing thereof
SK281704B6 (sk) * 1996-01-18 2001-07-10 Miroslav Hofschneider Kvapalné organominerálne hnojivo
AUPO529397A0 (en) * 1997-02-26 1997-03-20 Ab Tall (Holdings) Pty Ltd Pest resistance enhancement method
ES2300284T3 (es) * 1999-12-22 2008-06-16 Kemira Growhow Oyj Recubrimiento de semilla destinado a mejorar la eficacia de los nutrientes vegetales y de la semilla recubierta.
RU2189719C2 (ru) * 2000-06-08 2002-09-27 Горский государственный аграрный университет Способ внекорневой обработки семенного травостоя клевера
DE10034103B4 (de) * 2000-07-13 2009-01-29 Tilco Biochemie Gmbh Präparat mit fungizider Wirkung
WO2004095926A2 (fr) * 2003-04-28 2004-11-11 Monsanto Technology, Llc Traitement de plantes et materiaux de propagation de plantes avec un antioxydant pour l'amelioration de la sante de plantes et/ou l'accroissement de rendement
DE102004017876A1 (de) * 2004-04-13 2005-11-03 Heinze, Gerald, Prof. Dr. Verfahren zur Herstellung von organischen und organisch-mineralischen Düngemitteln unter Verwendung von Vinasse und die nach dem Verfahren hergestellten Düngemittel
FR2878173B1 (fr) * 2004-11-25 2007-01-19 Valoragri Sa Sa Procede de traitement de dechets de poudres d'extincteur, et engrais obtenu a partir d'un tel procede.
DE102005038967A1 (de) * 2005-08-16 2007-02-22 Tilco Biochemie Gmbh Präparat zur Behandlung von Pflanzen

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2008000214A2 *

Also Published As

Publication number Publication date
WO2008000214A3 (fr) 2008-09-12
WO2008000214A2 (fr) 2008-01-03
DE112007001999A5 (de) 2009-06-04

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