EP2029713A1 - Flüssigwaschmittelzusammensetzungen mit polymeren auf der basis von polyacrylsäure mit geringer polydispersität - Google Patents

Flüssigwaschmittelzusammensetzungen mit polymeren auf der basis von polyacrylsäure mit geringer polydispersität

Info

Publication number
EP2029713A1
EP2029713A1 EP07784463A EP07784463A EP2029713A1 EP 2029713 A1 EP2029713 A1 EP 2029713A1 EP 07784463 A EP07784463 A EP 07784463A EP 07784463 A EP07784463 A EP 07784463A EP 2029713 A1 EP2029713 A1 EP 2029713A1
Authority
EP
European Patent Office
Prior art keywords
units
formula
mixtures
backbone
liquid detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP07784463A
Other languages
English (en)
French (fr)
Inventor
Robb Richard Gardner
Jeffrey Scott Dupont
Kenneth Nathan Price
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of EP2029713A1 publication Critical patent/EP2029713A1/de
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate

Definitions

  • Typical builders such as citrates and fatty acids
  • polymer additives such as polyacrylates, and higher molecular weight/high charge density molecules
  • Typical builders such as citrates and fatty acids
  • polymer additives such as polyacrylates, and higher molecular weight/high charge density molecules
  • Typical builders such as citrates and fatty acids
  • polymer additives such as polyacrylates, and higher molecular weight/high charge density molecules
  • Typical builders such as citrates and fatty acids
  • polymer additives such as polyacrylates, and higher molecular weight/high charge density molecules
  • a fully non-branched linear modified polyamine according to the present invention has the formula
  • R4 is CJ-CJ 2 alkylene, C4-C12 alkenylene, Cg-Cj 2 arylalkylene, Cg-CjQ arylene, preferably CJ-CJQ alkylene, Cg-Cj 2 arylalkylene, more preferably C 2 -Cg alkylene, most preferably ethylene or butylene.
  • 20 E units are selected from the group consisting of -(CH 2 )pCO 2 M, -(CH 2 )q-S ⁇ 3M, -
  • indices have the following values: p has the value from 1 to 6; q has the value from 0 to 6; r has the value 0 or 1; w has the value 0 or 1; x has the value from 1 to 100; y has the value from 0 to 100; z has the value 0 or 1; k has the value from 0 to about 20; m has the value from 4 to about 400; n has the value from 0 to about 200; preferably m + n has the value of at least 5.
  • [J-R] n -J wherein the [J-R] units represent the amino units which comprise the main backbone and any branching chains.
  • the zwitterionic polyamines prior to modification, mter alia, quaternization, substitution of an amino unit hydrogen with an alkyleneoxy unit have backbones which comprise from 2 to about 100 amino units.
  • the index n which describes the number of backbone units present is further described herein below.
  • the anionic groups of the present invention include both units which are covalently attached to the polymer, as well as, external anions which are present to achieve charge neutrality.
  • Non-limiting examples of anions suitable for use include halogen, inter alia, chloride; methyl sulfate; hydrogen sulfate, and sulfate.
  • the formulator will recognize by the herein described examples that the anion will typically be a unit which is part of the quaternizing reagent, inter alia, methyl chloride, dimethyl sulfate, benzyl bromide.
  • Non-limiting examples of backbones according to the present invention include 1,9- diamino-3,7-dioxanonane; 1 , 10-diamino-3,8-dioxadecane; 1 , 12-diamino-3,10-dioxadodecane; l,14-diamino-3,12-dioxatetradecane.
  • backbones which comprise more than two nitrogens may comprise one or more repeating units having the formula:
  • the formulator may form zwitterionic polymers which have an excess of charge or an equivalent amount of charge type.
  • An example of a preferred zwitterionic polyamine according to the present invention which has an excess of backbone quaternized units, has the formula:

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP07784463A 2006-06-19 2007-06-18 Flüssigwaschmittelzusammensetzungen mit polymeren auf der basis von polyacrylsäure mit geringer polydispersität Ceased EP2029713A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US81493806P 2006-06-19 2006-06-19
PCT/US2007/071441 WO2007149806A1 (en) 2006-06-19 2007-06-18 Liquid detergent compositions with low polydispersity polyacrylic acid based polymers

Publications (1)

Publication Number Publication Date
EP2029713A1 true EP2029713A1 (de) 2009-03-04

Family

ID=38577489

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07784463A Ceased EP2029713A1 (de) 2006-06-19 2007-06-18 Flüssigwaschmittelzusammensetzungen mit polymeren auf der basis von polyacrylsäure mit geringer polydispersität

Country Status (6)

Country Link
EP (1) EP2029713A1 (de)
JP (1) JP2009542896A (de)
BR (1) BRPI0712934A2 (de)
CA (1) CA2652467A1 (de)
MX (1) MX2008016448A (de)
WO (1) WO2007149806A1 (de)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9376648B2 (en) 2008-04-07 2016-06-28 The Procter & Gamble Company Foam manipulation compositions containing fine particles
PL2300588T3 (pl) 2008-06-06 2019-07-31 The Procter & Gamble Company Kompozycja detergentu zawierająca odmianę z grupy 44 ksyloglukanazy
EP2288697B1 (de) 2008-06-06 2013-11-06 Novozymes A/S Varianten der Familie-44-Xyloglucanase
US20110150817A1 (en) * 2009-12-17 2011-06-23 Ricky Ah-Man Woo Freshening compositions comprising malodor binding polymers and malodor control components
US20120220513A1 (en) 2009-12-29 2012-08-30 Novozymes A/S Polypeptides Having Detergency Enhancing Effect
EP2357220A1 (de) 2010-02-10 2011-08-17 The Procter & Gamble Company Reinigungszusammensetzungen mit Amylasevarianten mit hoher Stabilität in Gegenwart eines Chelatwirkstoffs
CN105039284B (zh) 2010-02-10 2021-04-13 诺维信公司 在螯合剂存在下具有高稳定性的变体和包含变体的组合物
US8865637B2 (en) 2010-02-25 2014-10-21 Novozymes Als Variants of a lysozyme and polynucleotides encoding same
US8492325B2 (en) * 2010-03-01 2013-07-23 The Procter & Gamble Company Dual-usage liquid laundry detergents comprising a silicone anti-foam
US20130266554A1 (en) 2010-09-16 2013-10-10 Novozymes A/S Lysozymes
US20140038270A1 (en) 2011-02-16 2014-02-06 Novozymes A/S Detergent Compositions Comprising Metalloproteases
EP2675883A2 (de) 2011-02-16 2013-12-25 Novozymes A/S Waschmittelzusammensetzungen mit metalloproteasen
MX2013009177A (es) 2011-02-16 2013-08-29 Novozymes As Composiciones detergentes que comprenden metaloproteasas de m7 o m35.
WO2014029821A1 (en) 2012-08-22 2014-02-27 Novozymes A/S Metalloproteases from alicyclobacillus sp.
EP2888358A1 (de) 2012-08-22 2015-07-01 Novozymes A/S Waschmittelzusammensetzungen mit metalloproteasen
WO2014029819A1 (en) 2012-08-22 2014-02-27 Novozymes A/S Metalloprotease from exiguobacterium
DE102013216776A1 (de) * 2013-08-23 2015-02-26 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit verbesserter Leistung
WO2016066369A1 (en) * 2014-10-29 2016-05-06 Unilever Plc Reduction of colour damage during the laundry process
WO2017129754A1 (en) 2016-01-29 2017-08-03 Novozymes A/S Beta-glucanase variants and polynucleotides encoding same
WO2018224544A1 (en) 2017-06-08 2018-12-13 Novozymes A/S Compositions comprising polypeptides having cellulase activity and amylase activity, and uses thereof in cleaning and detergent compositions
CN111373036A (zh) 2017-10-02 2020-07-03 诺维信公司 具有甘露聚糖酶活性的多肽和编码它们的多核苷酸
WO2019068713A1 (en) 2017-10-02 2019-04-11 Novozymes A/S POLYPEPTIDES HAVING MANNANASE ACTIVITY AND POLYNUCLEOTIDES ENCODING THESE POLYPEPTIDES
WO2019081515A1 (en) 2017-10-24 2019-05-02 Novozymes A/S COMPOSITIONS COMPRISING POLYPEPTIDES HAVING MANNANASE ACTIVITY
WO2020070199A1 (en) 2018-10-03 2020-04-09 Novozymes A/S Polypeptides having alpha-mannan degrading activity and polynucleotides encoding same
MX2021011981A (es) 2019-04-03 2021-11-03 Novozymes As Polipeptidos que tienen actividad de beta-glucanasa, polinucleotidos que los codifican y usos de los mismos en composiciones de limpieza y de detergente.
EP4097226A1 (de) 2020-01-31 2022-12-07 Novozymes A/S Mannanase-varianten und dafür codierende polynukleotide
JP2023511739A (ja) 2020-01-31 2023-03-22 ノボザイムス アクティーゼルスカブ マンナナーゼバリアント及びそれをコードするポリヌクレオチド
WO2023247348A1 (en) 2022-06-21 2023-12-28 Novozymes A/S Mannanase variants and polynucleotides encoding same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0969024A2 (de) * 1998-07-02 2000-01-05 Nippon Shokubai Co., Ltd. Waschmittelbilder, Verfahren zu seiner Herstellung und Poly(meth)acrylsäure (oder Salz) Polymer und seine Verwendung
US20030008995A1 (en) * 2001-05-01 2003-01-09 Shigeru Yamaguchi Acrylic acid (salt) polymer, its production process and uses

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AU581417B2 (en) * 1984-11-16 1989-02-23 Ciba Specialty Chemicals Water Treatments Limited Water soluble polymers and dispersions containing them
US7442749B2 (en) * 2002-08-29 2008-10-28 Nippon Shokubai Co., Ltd. Sulfur-containing poly (unsaturated carboxylic acid) and its uses and production process
BR0314184B1 (pt) * 2002-09-12 2013-02-05 sistema de polÍmeros, composiÇço para limpeza e mÉtodo para limpeza de local.

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0969024A2 (de) * 1998-07-02 2000-01-05 Nippon Shokubai Co., Ltd. Waschmittelbilder, Verfahren zu seiner Herstellung und Poly(meth)acrylsäure (oder Salz) Polymer und seine Verwendung
US20030008995A1 (en) * 2001-05-01 2003-01-09 Shigeru Yamaguchi Acrylic acid (salt) polymer, its production process and uses
US6794473B2 (en) * 2001-05-01 2004-09-21 Nippon Shokubai Co., Ltd. Acrylic acid (salt) polymer, its production process and uses

Non-Patent Citations (1)

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Title
See also references of WO2007149806A1 *

Also Published As

Publication number Publication date
CA2652467A1 (en) 2007-12-27
WO2007149806A1 (en) 2007-12-27
BRPI0712934A2 (pt) 2013-03-26
MX2008016448A (es) 2009-01-22
JP2009542896A (ja) 2009-12-03

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