EP2003395A2 - Abfallvergasungsverfahren in einem Drehherdofen und Ofen zum Vergasen von Abfällen - Google Patents
Abfallvergasungsverfahren in einem Drehherdofen und Ofen zum Vergasen von Abfällen Download PDFInfo
- Publication number
- EP2003395A2 EP2003395A2 EP20080156964 EP08156964A EP2003395A2 EP 2003395 A2 EP2003395 A2 EP 2003395A2 EP 20080156964 EP20080156964 EP 20080156964 EP 08156964 A EP08156964 A EP 08156964A EP 2003395 A2 EP2003395 A2 EP 2003395A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- waste
- furnace
- hearth
- oven
- coke
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000002699 waste material Substances 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 35
- 238000002309 gasification Methods 0.000 title claims abstract description 19
- 239000007789 gas Substances 0.000 claims abstract description 32
- 239000000571 coke Substances 0.000 claims abstract description 30
- 230000000284 resting effect Effects 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 11
- 239000010815 organic waste Substances 0.000 claims abstract description 11
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims description 15
- 238000000227 grinding Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 4
- 239000003517 fume Substances 0.000 claims description 4
- 238000012216 screening Methods 0.000 claims description 4
- 239000010959 steel Substances 0.000 claims description 4
- 238000011282 treatment Methods 0.000 claims description 4
- 239000002154 agricultural waste Substances 0.000 claims description 3
- 239000010791 domestic waste Substances 0.000 claims description 3
- 239000000446 fuel Substances 0.000 claims description 3
- -1 grinding scrap Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000002440 industrial waste Substances 0.000 claims description 3
- 239000010808 liquid waste Substances 0.000 claims description 3
- 230000002093 peripheral effect Effects 0.000 claims description 3
- 239000010802 sludge Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 description 9
- 238000002485 combustion reaction Methods 0.000 description 5
- 235000021183 entrée Nutrition 0.000 description 4
- 239000002956 ash Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000001149 thermolysis Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005325 percolation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/24—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber
- F23G5/26—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber having rotating bottom
Definitions
- the present invention relates generally to the field of waste gasification.
- the invention relates, according to a first aspect, a gasification process of organic waste.
- the known waste gasification techniques are based on fluid bed or percolation technologies through a fixed bed.
- the present invention aims to provide a waste gasification process satisfactory in terms of gasification efficiency, simplified implementation, and faster realization.
- the invention therefore has the advantage of providing waste gasification free of heavy preparation upstream, which simplifies the process as a whole and saves time and a reduced cost of implementation.
- the method further includes a third step of burning the coke residues of the second step by raising them to a temperature of between 1000 and 1300 ° C.
- At least a portion of the synthesis gases obtained in the second stage are extracted and recovered energetically.
- the heat generated by the third step is used for the heat treatments of at least the first and second stages.
- Part of the synthesis gases obtained in the second stage are advantageously burned in the third stage.
- the furnace hearth stores heat during the third step and restores it at least during the first and second steps.
- the waste before being introduced into the oven, can be subjected to grinding and / or screening.
- the waste introduced into the furnace preferably has a larger dimension at most equal to 100 millimeters.
- the water vapor is for example injected into the coke resting on the sole, preferably through the sole.
- oxygen and in particular air, is supplied to the oven.
- the materials resting on the hearth of the furnace such as waste or coke
- plowshares for example of steel.
- material refers to waste products and all their products obtained from the reactions of the first, second and third stages.
- floor-based materials are termed waste and their products which are based on the hearth of the oven.
- the waste is a mixture of solid, pulverulent and / or liquid waste.
- the waste introduced into the furnace is deposited on the hearth, at the periphery thereof, and then, during the rotation of the hearth, punctually pushed towards the center of the furnace. sole, materials resting on the oven floor, such as waste or coke, following a spiral-shaped path.
- each step takes place respectively in a defined volume inside the oven.
- At least a portion of the gases and / or fumes present in the third step are burned at this stage and circulate above the volumes defined in the furnace to indirectly heat the contents of said volumes.
- Oxygen, and in particular air, can be injected above the defined volumes in the furnace.
- the waste is preferably introduced as a continuous flow into the oven.
- the waste is selected from alternative fuels made from household and industrial waste, grinding scrap, sludge from water treatment plants, contaminated wood, industrial organic waste, and / or agricultural waste.
- the invention relates to a rotary hearth furnace for the gasification of organic waste, comprising an oven enclosure delimited by a bottom, a peripheral wall and an upper wall, and a rotating hearth, above the bottom of the enclosure, capable of rotation about an axis, and intended to receive the waste.
- Said oven is characterized in that it further comprises an internal set of walls above the rotating hearth, defining three chambers inside the enclosure, around the axis of rotation of the hearth.
- the oven according to the invention may advantageously further comprise mixing means in the oven chamber above the hearth, said mixing means being at least intended to return and mix materials resting on the hearth, such as the waste or coke.
- the mixing means are particularly rables, such as rakes or plowshares, for example steel.
- the mixing means are arranged radially relative to the axis of rotation of the sole.
- waste 1 is introduced into the furnace (not shown) and undergoes the first step 2 therein.
- This first step 2 consists of drying and at least partly producing the thermolysis of the waste. It produces coke which rests on the hearth of the furnace and is thus directed, by the rotation of the sole, towards the second stage 3.
- Gases are also obtained during this first step 2. They contain incondensable gases, such as methane CH 4 , ethane C 2 H 6 , carbon monoxide CO, and hydrogen H 2 , and condensable gases, such as tar and phenol.
- incondensable gases such as methane CH 4 , ethane C 2 H 6 , carbon monoxide CO, and hydrogen H 2
- condensable gases such as tar and phenol.
- the second step 3 is successive to the first step 2 for the same batch of waste. These two steps 2, 3 are concomitant in the oven.
- the second step 3 is carried out at a temperature higher than that of the first step 2 and possibly makes it possible to terminate the thermolysis of the waste and of their reaction products resulting from the first step 2.
- This second step 3 is the gasification step. This is done through the introduction of 4 steam.
- the water vapor is injected in particular into the coke resting on the sole, and preferably through the sole.
- This water vapor allows the cracking of coke and condensable gases from the first stage 2.
- the gases obtained in the second stage 3, called synthesis gas, are preferably extracted, at the outlet 5, from this stage 3.
- the extracted synthesis gas is for example washed, dusted, and filtered, before being recovered energy in a gas turbine or boiler.
- the process includes a third combustion step 6, at a temperature of between 1000 and 1300 ° C.
- This third step 6 is successive to the second step 3 for the same batch of waste.
- the three steps 2, 3, 6 are carried out concomitantly in the oven.
- An oxidant in this case the oxygen of the air, is brought to the inlet 7.
- part of the synthesis gases obtained in the second step 3 can also be burned in the third step 6.
- the third step 6 generates a lot of heat, by the combustion of coke residues, which are for example in the state of smoke at this stage, as well as by that of a part of the gases coming from the second stage 3.
- This heat is advantageously used, as shown by the arrows 8, for the heat treatments of the first and second stages 2, 3.
- the heat generated in the third step 6 is sufficient to heat the oven, and in particular for the heat input required respectively for the unfolding of the first, second and third steps 2, 3, 6.
- the heat generated in the third step 6 is for example stored by the oven floor, which is made of refractory material.
- the sole then restores this stored heat to the materials in the furnace, and in particular to the materials resting on the sole.
- each step 2, 3, 6 of the process according to the invention takes place respectively in a defined volume inside the furnace.
- Each volume is for example a chamber as described below.
- At least a portion of the gases and / or fumes present in the third step 6, in other words obtained directly at this step 6 and possibly from the second step 3, can advantageously circulate above the volumes defined in the oven to indirectly heat up the content of said volumes.
- Oxygen, and in particular air, is preferably injected above the volumes defined in the furnace to promote the combustion of gases and / or fumes circulating therein.
- FIG. 2 To the figure 2 is shown a rotary hearth furnace, adapted to the implementation of the method according to the invention, gasification of organic waste.
- This oven comprises a furnace enclosure 10 delimited by a bottom 11, a peripheral wall 12 and an upper wall 13.
- the rotating hearth 14 is rotatable about an axis 15. It is intended to receive the waste introduced by the inlet 16.
- the oven further comprises an internal assembly 17 of walls above the rotating hearth 14.
- the assembly 17 of walls defines at least two, and preferably three, chambers 18a, 18b, 18c within the enclosure 10, around the axis 15 of rotation of the sole.
- the set 17 of walls has one or more planes preferably perpendicular to that of the hearth 14. It spares one or more passage spaces above the hearth 14, so that the materials resting on the hearth can circulate under the set of 17 walls.
- the rooms defined by the set of walls are not quite closed by the wall or walls.
- the method according to the invention can advantageously operate continuously.
- the waste is then introduced in continuous flow into the oven.
- the oven hearth rotates advantageously continuously and at a constant speed.
- the speed of the sole is adjustable.
- the oven can operate in piston mode, or in spiral mode.
- the waste is preferably deposited on a radius of the hearth and the ashes obtained at the end of the process are extracted from the oven using for example an extraction screw.
- the waste introduced into the furnace is deposited on the sole, on the periphery thereof, then, during the rotation of the hearth, punctually pushed towards the center of the hearth, the materials resting on the oven floor, such as waste or coke, following a spiral path.
- the waste is deposited on 50 centimeters on this width.
- the spiral mode offers the advantage of greater waste processing speed compared to the piston mode.
- the rotation speed of the hearth is generally greater in spiral mode than in piston mode.
- the oven may include mixing means in the oven enclosure above the hearth. These mixing means are at least intended to return and mix the materials (waste, coke, etc.) resting on the sole.
- These mixing means are, for example, saddles, such as rakes or sets of plowshares. They are preferably made of steel.
- Materials resting on the hearth of the furnace such as waste or coke, can thus be mixed during the process.
- This mixture prevents the formation of a top layer of ash on the pile of materials, which layer has the disadvantage of isolating the rest of the cluster.
- the mixing means are for example arranged radially relative to the axis of rotation of the sole.
- the materials resting on the hearth of the oven can be not only mixed by the mixing means, but also pushed by these means, particularly in the context of operation of the spiral oven.
- the organic waste concerned by the invention may be of a heterogeneous nature, and in particular be mixtures of solid, pulverulent and / or liquid waste.
- the waste is selected from alternative fuels made from household and industrial waste, grinding scrap, sludge from water treatment plants, contaminated wood, industrial organic waste, and / or agricultural waste.
- the waste before being introduced into the oven, is subjected to grinding and / or screening, to advantageously select waste having a larger dimension at most equal to 100 millimeters.
- One of the advantages of the process of the invention is to possibly require only a grinding and / or a summary screening, and to accept waste of heterogeneous size, such as between about 1 millimeter and about 100 millimeters.
- the method according to the invention makes it possible to limit importantly the emission of carbon dioxide CO 2 , for the same amount of treated waste.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0704298A FR2917486B1 (fr) | 2007-06-15 | 2007-06-15 | Procede de gazeification de dechets dans un four a sole tournante, et four pour sa mise en oeuvre |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2003395A2 true EP2003395A2 (de) | 2008-12-17 |
Family
ID=39016102
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP20080156964 Withdrawn EP2003395A2 (de) | 2007-06-15 | 2008-05-27 | Abfallvergasungsverfahren in einem Drehherdofen und Ofen zum Vergasen von Abfällen |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP2003395A2 (de) |
| FR (1) | FR2917486B1 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2488042C1 (ru) * | 2012-02-16 | 2013-07-20 | Михаил Васильевич Жуков | Плазмоэлектролизный генератор электроэнергии, удобрений и воды из стоков и органических отходов |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2324053A1 (en) * | 2000-10-20 | 2002-04-20 | Malahat Systems Corporation | Gasifier |
| JP3961795B2 (ja) * | 2001-08-22 | 2007-08-22 | 株式会社神戸製鋼所 | 可燃性廃棄物の燃焼処理方法およびその装置 |
| AT412308B (de) * | 2003-05-14 | 2004-12-27 | Kwb Kraft Und Waerme Aus Bioma | Heizeinrichtung |
-
2007
- 2007-06-15 FR FR0704298A patent/FR2917486B1/fr not_active Expired - Fee Related
-
2008
- 2008-05-27 EP EP20080156964 patent/EP2003395A2/de not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2488042C1 (ru) * | 2012-02-16 | 2013-07-20 | Михаил Васильевич Жуков | Плазмоэлектролизный генератор электроэнергии, удобрений и воды из стоков и органических отходов |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2917486A1 (fr) | 2008-12-19 |
| FR2917486B1 (fr) | 2009-09-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2776540B1 (de) | Reaktor zur trocknung und torrefizierung einer biomasse, vorzugsweise einer lignocellulose- biomasse | |
| EP2627739B1 (de) | Vorrichtung zur umwandlung eines brennstoffes | |
| WO1996009357A1 (en) | Pyrolytic waste treatment system | |
| EP2435533B1 (de) | Neuartiges verfahren zur pyrovergasung von biomüll | |
| CA2859480A1 (fr) | Procede et equipement de gazeification en lit fixe | |
| EP2189512A1 (de) | Röstverfahren der Biomasse und Kontrolle dieses Verfahrens | |
| EP2129748A2 (de) | Verfahren und anlage zur mit variabler stärke erfolgenden gasifizierung brennbarer materialien | |
| EP3856870B1 (de) | Mehrregalofen mit armen mit kratzerzähnen mit optimiertem profil, anwendung zum rösten von biomasse | |
| EP1413826A1 (de) | Verfahren und Vorrichtung zur Mikrowellen-Behandlung von Festrückständen der thermischen Zersetzung einer organische Stoffe enthaltende Beschichtung | |
| EP2003395A2 (de) | Abfallvergasungsverfahren in einem Drehherdofen und Ofen zum Vergasen von Abfällen | |
| EP2723832B1 (de) | Gasgenerator, der mit festem kohlenstoffbrennstoff funktioniert | |
| WO2017134075A1 (fr) | Four a soles multiples pour utilisation a basse temperature | |
| EP4186589B1 (de) | Anlage und verfahren zur herstellung von hydrophoben biomassepellets | |
| EP2753677B1 (de) | Gasgenerator, der mit festem kohlenstoffbrennstoff funktioniert | |
| EP4098942B1 (de) | Verfahren zur behandlung von organischen abfällen durch pyrolyse | |
| WO2008125460A1 (fr) | Procedes et dispositifs de fabrication de charbon de bois ameliores | |
| WO2003064562A2 (fr) | Procede et installation pour gazeifier des matieres combustibles | |
| FR3044013A1 (fr) | Reacteur de pyrolyse rapide de particules organiques de biomasse avec injection a contre-courant de gaz chauds | |
| FR2827609A1 (fr) | Procede et installation de production de gaz combustibles a partir de gaz issus de la conversion thermique d'une charge solide | |
| FR2833189A1 (fr) | Procede et installation de traitement de gaz issus de la decomposition par effet thermique d'une charge solide | |
| FR2916760A1 (fr) | Module, systeme et procede de traitement de biomasse a lit fixe horizontal | |
| CA3140859A1 (fr) | Four a soles multiples comprenant des bras incurves, application a la torrefaction de biomasse | |
| FR2955175A1 (fr) | Procede et dispositif de torrefaction d'une charge de biomasse | |
| EP3878925A1 (de) | Herstellungsverfahren von bio-ölen durch pyrolyse von olivenzweigen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR |
|
| AX | Request for extension of the european patent |
Extension state: AL BA MK RS |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 20111201 |