EP1977468A2 - Centrale a piles a combustible pem a refrigerant non circulant comprenant un systeme d'evacuation d'air antigel a contre-pression - Google Patents

Centrale a piles a combustible pem a refrigerant non circulant comprenant un systeme d'evacuation d'air antigel a contre-pression

Info

Publication number
EP1977468A2
EP1977468A2 EP05858680A EP05858680A EP1977468A2 EP 1977468 A2 EP1977468 A2 EP 1977468A2 EP 05858680 A EP05858680 A EP 05858680A EP 05858680 A EP05858680 A EP 05858680A EP 1977468 A2 EP1977468 A2 EP 1977468A2
Authority
EP
European Patent Office
Prior art keywords
antifreeze
water
layer
air
power plant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05858680A
Other languages
German (de)
English (en)
Other versions
EP1977468A4 (fr
Inventor
Robert Darling
Tommy Skiba
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UTC Power Corp
Original Assignee
UTC Power Corp
UTC Fuel Cells LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UTC Power Corp, UTC Fuel Cells LLC filed Critical UTC Power Corp
Publication of EP1977468A2 publication Critical patent/EP1977468A2/fr
Publication of EP1977468A4 publication Critical patent/EP1977468A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04029—Heat exchange using liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04253—Means for solving freezing problems
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04156—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying with product water removal
    • H01M8/04164—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying with product water removal by condensers, gas-liquid separators or filters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04291—Arrangements for managing water in solid electrolyte fuel cell systems
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the present invention relates to a polymer electrolyte membrane (PEM) fuel cell power plant which is cooled evaporatively by a non-circulating water (NWM) coolant, an NWM PEM fuel cell system. More particularly, this invention relates to a PEM fuel cell power plant which can operate at freezing temperatures.
  • the system has an air-water separator for separating air from water which are contained in the cathode effluent gas stream. Air from the separator is then vented from the system through an antifreeze column and the water is returned to the coolant section of the system.
  • Polymer electrolyte membrane fuel cell assemblies are relatively low temperature low operating pressure fuel cell assemblies that utilize a catalyzed polymer membrane electrolyte to process air and a hydrogen-rich fuel to produce electricity and water.
  • PEM fuel ceils are well suited for use in mobile applications such as automobiles, buses, and the like, because they are relatively compact, light in weight and operate at essentially ambient pressure.
  • This type of fuel cell system can be cooled evaporatively by a non- circulating water coolant.
  • the cooler has an outer plate that is formed with channels which contain the water coolant.
  • the cooler also has an inner porous plate which faces the cathode side of the fuel cell through which an air reactant stream flows.
  • the cell is cooled by water which flows through the porous plate to the air stream and evaporates therein so as to cool the cell. During operation, a small amount of air also diffuses through the porous plate into the water coofant.
  • the cathode reactant stream effluent will comprise a water vapor and air mixture.
  • the water vapor and air components of the cathode effluent mixture are passed through a condenser where water is condensed out of the mixture.
  • the resultant water/air mixture is then passed through a separator station where the condensed water is removed from the mixture and air is vented out of the fuel cell assembly.
  • the water is then returned to the coolant flow field in the fuel cell assembly.
  • the separator air venting portion of the system typically includes a passage to ambient surroundings which passage permits controlled airflow from the separator by means of mechanical valves and/or fixed nozzles. These valves and/or fixed nozzles in the air bleed passage serve to control back pressure in the liquid/air separator during normal operation.
  • the air stream which is vented from the separator is humid after leaving the condenser. This fact causes operational problems during freezing conditions since the valves and/or nozzles in the air bleed line can freeze up so that air flow can no longer be properly controlled from the system, thus forcing shut down of the system and of the power plant.
  • This problem can be fixed by heating the air bleed line but this solution requires additional heating equipment in the system that increases system complexity and cost
  • This invention relates to an improved system for venting air from an air/water separator component in an NWM PEM fuel cell power plant, and to a method using said system, which power plant is designed primarily for use in mobile applications, such as powering automobiles, buses, and the like.
  • the improved air vent system of this invention can be used in freezing conditions, and does not involve the use of mechanical valves and/or mechanical nozzles for proper operation.
  • the fuel cell power plant is a PEM cell power plant which typically operates at relatively low temperatures and at pressures which are above ambient pressure.
  • the fuel cell power plant includes a conventional catalyzed polymer membrane electrode having an anode side which receives a hydrogen-rich fuel stream and a cathode side which receives an air reactant stream.
  • a cooling flow field is disposed in heat exchange relationship with the active portion of the fuel cell so as to cool the fuel cell during operation thereof.
  • the coolant used in the system is typically water.
  • the coolant in the cooling flow field does not circulate as a liquid through the fuel cell assembly.
  • the cooling is accomplished by evaporation of the coolant into the reactant flow field.
  • the air and hydrogen reactant streams are at higher pressures than the coolant water whereby these gases can be ingested into the coolant water through the porous coolant plates in the cells.
  • water vapor will vaporize into the air stream from the reaction and from water evaporated in the cooling operation, and will be contained in the cathode side effluent stream that is expelled from the cathode side of the cells in the power plant cell stack.
  • the air-water vapor is circulated through a condenser, and the resultant air/water mixture is then circulated through a separator where the air component is separated from the water component, and the humid air component is vented from the system into ambient surroundings.
  • the water is returned to the coolant flow field from the separator.
  • the humidified air stream is vented from the fuel cell system to ambient surroundings through a hydrophobic porous body and into and through a passive column of antifreeze which is disposed in proximity with the separator.
  • the air in the vented stream bubbles through the antifreeze into ambient surroundings. Any water in the vented stream also passes through the antifreeze.
  • the antifreeze can be one which is immiscible with water whereby the water constituent will rise through the antifreeze and will separate from the antifreeze, and will not dilute the antifreeze.
  • the water layer can then be removed from the antifreeze layer by means of a micro porous membrane.
  • the antifreeze layer will maintain the desired back pressure in the fuel cell system.
  • the air stream in the system is pressurized for several reasons.
  • the antifreeze air venting component of the system will function properly at freezing and subfreezing temperatures, and is passive in that it does not require any moving parts in contact with freezing water for proper operation.
  • FIG.1 is a schematic view of a PEM fuel cell assembly which is used in the power plant of this invention.
  • FIG. 2 is a schematic view of the passive air venting portion of the assembly of FIG. 1.
  • FIG. 1 is a schematic view of a PEM cell subassemb ⁇ y part denoted generally by the numeral 2 of a fuel cell power plant formed in accordance with this invention.
  • the fuel cell 4 includes a catalyzed polymer electrolyte membrane 6 which is interposed between a fuel reactant flow field 8 (the anode side) and an oxidant reactant flow field 10 (the cathode side).
  • a coolant flow field 12 is disposed adjacent to the cathode side 10 of the fuel cell 4, however, the coolant flow field 12 could be positioned closer to the anode side 8 of the cell 4.
  • the coolant flow field 12 contains a non-circulating aqueous coolant that serves to cool the PEM cell subassembly 2 so as to maintain the proper operating temperature of the fuel cell 4.
  • the hydrogen in the fuel and the oxygen in the air are converted to electrons and product water.
  • Some of this product water is evaporated from the coolant flow field, in the form of water vapor, into the oxidant flow field 10 of the cell 4 and is removed, along with residual air, as cathode effluent through a line 14 which leads to a condenser 16.
  • the condenser 16 condenses water out of the air/water vapor stream, and the resultant water- air mixture is then taken through a line 18 to a water-air separator 20 where the water fraction of the mixture is separated from the air fraction of the mixture.
  • the air fraction is removed from the separator 20 through a vent line 22 and is vented into ambient surroundings from the line 22 and from assembly 2 through a passive vent structure denoted generally by the numeral 24.
  • the nature of the vent structure 24 will be clarified herein below.
  • the coolant flow field 12 may be kept under a slightly negative pressure, approximately 7kPa below the air and fuel pressures, by an optional vacuum pump 32 which is connected to the flow field 12 through a line 30 and a hydrophobic porous plug 28 or by pressurizing fuel and air.
  • the vacuum pump 32 will draw any gases, such as air and/or hydrogen, which may be present in the coolant flow field 12 out of the coolant flow field 12 through the porous plug 28.
  • gases such as air and/or hydrogen
  • the pores and the height of the plug 28 are sized so as to allow passage of gases through the plug 28 but prevent passage of the coolant liquid there through. Gases siphoned out of the coolant flow field 12 are vented to the ambient surroundings from the pump 32.
  • the structure 24 includes a sparging vessel 36 which contains a column of antifreeze 40.
  • the vessel 36 has a porous bottom wall 37 which is formed from a hydrophobic porous material which allows passage of air there through but blocks passage of liquids there through.
  • the antifreeze 40 can be a material which is immiscible with water, or it can be miscibie with water. The former is preferred so as to preserve the ability of the antifreeze to remain liquid under freezing ambient conditions. When the latter is used, the antifreeze layer must be periodically replaced with fresh antifreeze.
  • Immiscible antifreezes can include 3M hydrofluoroether 7400, polydimethylsiloxane, polyphenylmethsiloxane, or the like. Miscibie antifreezes can include ethylene glycol, polyethylene glycol, propylene glycol, of the like.
  • the air stream entering the tank 36 will be humidified so that water may condense out of the air stream in the antifreeze 40.
  • the air in the stream will bubble upwardly through the antifreeze layer 40 and exit the system as indicated by the arrow 34.
  • any water that condenses out in the antifreeze will layer out in one area 38 of the vessel 36, which is preferably at the top of the vessel 36 and on top of the antifreeze layer 40.
  • the system also includes an auxiliary tank 44 which contains additional antifreeze. Antifreeze located in the area 40 can be periodically removed therefrom through a line 42 which is controlled by a drain valve 43. The back pressure in the system will vary with changes in current density, flow rates and variations in the height of the antifreeze column 40 that the air must bubble through.
  • the height of the antifreeze layer 40 can be increased by pumping antifreeze out of the tank 44 through a line 46 and a pump 48 and back into the tank 36.
  • the height of the antifreeze layer 40 can be selectively altered in response to system operating conditions.
  • the air vent assembly of this invention will operate during ambient freezing conditions, and will not freeze up during operation of the power plant. This fact makes the vent assembly particularly useful in a PEM fuel cell power plant that is designed for use in a mobile device such as a car or the like which often must operate in freezing conditions.
  • the vent assembly of this invention is also a very simple assembly in that it does not require any moving mechanical devices such as valves or nozzles that are exposed to the air stream being vented from the power plant.
  • the air vent assembly will vent air from a humid air stream produced in an air reactant effluent recycling loop to ambient surroundings. The humid air stream is vented through a passive vent structure which includes a column of antifreeze and does not include mechanical valves or nozzles that are prone to freezing.
  • the system of this invention also will alter the height of the column of antifreeze in response to changes in system operating conditions.

Abstract

L'invention se rapporte à une centrale à piles à combustible PEM (4) qui comprend un évent passif (24) à travers lequel l'air séparé d'un courant effluent de cathode peut être évacué de la centrale. L'évent fonctionne de manière satisfaisante dans des conditions de gel ambiant, c'est pourquoi il est particulièrement adapté aux applications mobile telles que les automobiles ou les autobus à pile à combustible PEM, ou analogues. L'évent est formé d'une couche de liquide antigel (40) disposée dans un réservoir de barbotage (36) qui communique avec l'atmosphère ambiante. Les quelconques vapeurs d'eau présentes dans le courant peuvent se condenser du courant gazeux dans l'antigel. Afin de faciliter ce phénomène, l'antigel peut être un liquide non miscible dans l'eau de sorte que l'eau condensée forme une couche séparée (38) dans le réservoir de barbotage.
EP05858680A 2005-12-23 2005-12-23 Centrale a piles a combustible pem a refrigerant non circulant comprenant un systeme d'evacuation d'air antigel a contre-pression Withdrawn EP1977468A4 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2005/046913 WO2007078276A2 (fr) 2005-12-23 2005-12-23 Centrale a piles a combustible pem a refrigerant non circulant comprenant un systeme d'evacuation d'air antigel a contre-pression

Publications (2)

Publication Number Publication Date
EP1977468A2 true EP1977468A2 (fr) 2008-10-08
EP1977468A4 EP1977468A4 (fr) 2011-01-19

Family

ID=38228642

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05858680A Withdrawn EP1977468A4 (fr) 2005-12-23 2005-12-23 Centrale a piles a combustible pem a refrigerant non circulant comprenant un systeme d'evacuation d'air antigel a contre-pression

Country Status (5)

Country Link
EP (1) EP1977468A4 (fr)
JP (1) JP2009521780A (fr)
KR (1) KR101200144B1 (fr)
CN (1) CN101366140B (fr)
WO (1) WO2007078276A2 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100974762B1 (ko) 2008-05-15 2010-08-06 현대자동차주식회사 연료전지 스택용 냉각수 라인의 공기빼기장치

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000063994A1 (fr) * 1999-04-20 2000-10-26 International Fuel Cells, Llc Systeme de traitement d'eau destine a un ensemble de piles a combustible
US6242118B1 (en) * 1999-10-14 2001-06-05 International Fuel Cells Llc Method and apparatus for removing contaminants from the coolant supply of a fuel cell power plant
WO2001078178A1 (fr) * 2000-04-06 2001-10-18 International Fuel Cells, Llc Integration fonctionnelle de plusieurs composants dans une centrale a piles a combustible
US6428916B1 (en) * 1999-12-20 2002-08-06 Utc Fuel Cells, Llc Coolant treatment system for a direct antifreeze cooled fuel cell assembly

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US3615838A (en) * 1968-05-10 1971-10-26 Albert C Erickson Fuel cell unit with novel fluid distribution drain and vent features
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JPH0668889A (ja) * 1992-08-20 1994-03-11 Fuji Electric Co Ltd 燃料電池用改質ガスの冷却システム
US5362577A (en) * 1993-06-04 1994-11-08 Aer Energy Resources, Inc. Diffusion vent for a rechargeable metal-air cell
ATE295616T1 (de) * 1998-09-22 2005-05-15 Ballard Power Systems Kühlsubsystem mit frostschutzmittel
JP4439076B2 (ja) 2000-03-31 2010-03-24 株式会社東芝 固体高分子型燃料電池スタック
US6365291B1 (en) * 2000-04-05 2002-04-02 Utc Fuel Cells, Llc Direct antifreeze solution concentration control system for a fuel cell power plant
JP3698083B2 (ja) * 2001-10-03 2005-09-21 日産自動車株式会社 冷却水循環装置
US6699612B2 (en) * 2001-12-26 2004-03-02 Utc Fuel Cells, Llc Fuel cell power plant having a reduced free water volume
US6814841B2 (en) * 2002-04-24 2004-11-09 Proton Energy Systems, Inc. Gas liquid phase separator with improved pressure control
JP4626797B2 (ja) * 2002-11-12 2011-02-09 株式会社豊田中央研究所 燃料電池システム
JP2007109555A (ja) * 2005-10-14 2007-04-26 Toyota Motor Corp 燃料電池システム及び燃料電池車両

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000063994A1 (fr) * 1999-04-20 2000-10-26 International Fuel Cells, Llc Systeme de traitement d'eau destine a un ensemble de piles a combustible
US6242118B1 (en) * 1999-10-14 2001-06-05 International Fuel Cells Llc Method and apparatus for removing contaminants from the coolant supply of a fuel cell power plant
US6428916B1 (en) * 1999-12-20 2002-08-06 Utc Fuel Cells, Llc Coolant treatment system for a direct antifreeze cooled fuel cell assembly
WO2001078178A1 (fr) * 2000-04-06 2001-10-18 International Fuel Cells, Llc Integration fonctionnelle de plusieurs composants dans une centrale a piles a combustible

Non-Patent Citations (1)

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Title
See also references of WO2007078276A2 *

Also Published As

Publication number Publication date
KR101200144B1 (ko) 2012-11-12
WO2007078276A3 (fr) 2007-11-15
EP1977468A4 (fr) 2011-01-19
KR20080079251A (ko) 2008-08-29
JP2009521780A (ja) 2009-06-04
CN101366140A (zh) 2009-02-11
CN101366140B (zh) 2010-12-08
WO2007078276A2 (fr) 2007-07-12

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