EP1967363B1 - Screen printing device and method for manufacturing the same - Google Patents
Screen printing device and method for manufacturing the same Download PDFInfo
- Publication number
- EP1967363B1 EP1967363B1 EP07023414.1A EP07023414A EP1967363B1 EP 1967363 B1 EP1967363 B1 EP 1967363B1 EP 07023414 A EP07023414 A EP 07023414A EP 1967363 B1 EP1967363 B1 EP 1967363B1
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- EP
- European Patent Office
- Prior art keywords
- fabric
- screen printing
- template
- coating
- printing device
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000007650 screen-printing Methods 0.000 title claims description 47
- 238000000034 method Methods 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000004744 fabric Substances 0.000 claims description 60
- 238000000576 coating method Methods 0.000 claims description 42
- 239000011248 coating agent Substances 0.000 claims description 38
- 238000007639 printing Methods 0.000 claims description 25
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 4
- 150000001722 carbon compounds Chemical class 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 230000002209 hydrophobic effect Effects 0.000 claims description 4
- 239000002210 silicon-based material Substances 0.000 claims description 4
- 230000008569 process Effects 0.000 description 14
- 238000005516 engineering process Methods 0.000 description 13
- 239000000758 substrate Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 6
- 239000010409 thin film Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000005253 cladding Methods 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 235000019589 hardness Nutrition 0.000 description 3
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 206010063493 Premature ageing Diseases 0.000 description 1
- 208000032038 Premature aging Diseases 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 TeflonĀ® Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F15/00—Screen printers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/24—Stencils; Stencil materials; Carriers therefor
- B41N1/247—Meshes, gauzes, woven or similar screen materials; Preparation thereof, e.g. by plasma treatment
Definitions
- the present invention relates to a screen printing device with a fabric and arranged in the fabric template in the form of a photolithographically structured emulsion.
- the invention further relates to a method for producing such a screen printing device.
- Screen printing is a printing process in which an ink or print paste is printed through a fine mesh fabric onto the material to be printed with a knife-like tool, the rubber squeegee. Screen printing is therefore also referred to as a through-printing process.
- the mesh apertures of the fabric are impermeable to the ink or printing paste by a stencil (e.g., photolithographically structured emulsion) disposed on the fabric.
- LTCC Low Temperature Cofired Ceramics
- vias involve represents.
- the circuit elements are screen printed on the green sheets of the later ceramic support, which are then stacked and sintered.
- thin-film process is itself a costly process.
- thin-film structures can only be realized coplanar on the substrate surface. The use of multi-layer technology with fine-line structures could bring a significant cost reduction compared to thin-film technology and also offer the advantage of using several levels, including for screen layers.
- the screen frames are usually made of aluminum and are covered with a steel mesh, which can be achieved during the printing process elastic deflection of the screen.
- An elastic deflection of the screen during the printing process is required for the so-called bounce, d. H. for the realizable between tissue and substrate to be printed distance. For example, too little jump may lead to cloud formation in the print, since the fabric behind the squeegee does not immediately detach from the printed paste film - it remains "stuck" in the printed paste.
- Too much bounce on the other hand, increases tissue tension which, on the one hand, leads to exceeding the elastic yield strength of the tissue and thus leading to premature aging of the fabric and, on the other, impure printouts due to paste spatters, so that the template edge can no longer draw a clean print image ,
- the wire thickness of the fabrics used today is approximately between 30 micrometers and 16 micrometers.
- the permeability of the fabric is described by its mesh size, which is indicated by the so-called mesh number.
- 325 mesh means that there are 325 stitches per square inch (square inches).
- the stencil is often made as a direct stencil by a photographic process.
- the fabric is coated with photosensitive polymers, which with be exposed to the desired structures. Subsequently, the exposed structures are developed and the unexposed areas are washed out.
- the fabric, stencil (emulsion) and printing frame together form the screen printing screen.
- the printing paste is applied to the screen and distributed evenly on the structured screen by means of a so-called flood doctor blade. Subsequently, the actual printing takes place, wherein the squeegee is pulled over the wire with a suitably adjusted hardness.
- the screen is in this printing at a certain distance from the substrate to be printed, for example, an LTCC film.
- the screen is pressed by means of the printing doctor down elastically in the direction of the substrate to be printed.
- a shear of the printing paste which reduces its viscosity due to their thixotropic property during the shear and thereby can be pressed through the openings of the screen printing screen. After completion of the shear stress, the printing paste again has the initial viscosity.
- d. H If smaller resolutions of the printed structures (fine-line structures) are to be achieved, d. H. For example, if the resolution is less than 50 microns or even less than 30 microns, there is a problem that the fabric and the template must have correspondingly fine structures with small openings and these fine structures and small openings in the template and the fabric through the flow of colors or pastes inhibit the screen printing screen.
- the plastic filaments of the fabric are coated with a vapor-deposited or sputtered cladding layer, which in turn is covered by a metal coating which bears the emulsion of the stencil and which has been produced by electroplating.
- the cladding layer is produced by a sputtering or sputtering process with a layer thickness of about 5 nanometers to over 200 nanometers.
- the application of the cladding layer by means of electrodeposition. For example, a copper or nickel layer is applied.
- the metallised plastic fabric results in a high reproducible stencil quality with excellent edge definition and exact ink dosage, as it ensures minimum elongation with sufficient basic strength.
- the EP 1 147 887 A1 discloses a screen printing plate for applying coatings to a glass sheet, especially disks of an automobile, which has an oil-repellent coating on both sides of the screen. Here, large-area coatings are carried out. The said printing plate is therefore not suitable for printing fine structures.
- the publication DE 10 2004 055 113 A1 discloses a method of hydrophilizing screen-printed stencil media which substantially improves the wetting of the stencil stencil sheet with stencil material.
- the screen printing stencil carrier ie the screen printing fabric
- this is provided with very fine oxide particles, such as nanometer particles of metal oxide, for example. Titanium oxide, alumina or zirconium oxide, and a wetting agent.
- a wetting agent for example, a surfactant can be used.
- the hydrophilizing agent may also be employed in the removal of stencil material from the screen-printed fabrics, preferably by adding it to the decoating liquid.
- the screen stencil carrier is not only freed from the stencil material but at the same time hydrophilized for the next coating process. Consequently, the coating of the screen-printed fabric indicated in this publication does not solve the above-indicated problem of producing finer structures.
- the object of the present invention is therefore to provide a screen printing apparatus which enables the printing of finer structures.
- the object of the present invention is to provide a method for producing a screen printing device, which allows easy and cost-effective the printing of finer structures, in particular for a steel fabric.
- the object is achieved by a screen printing apparatus in which the fabric and / or the stencil has a nanocrystalline coating which reduces the adhesion of a screen printing paste or a screen printing ink to the fabric and / or to the stencil on the surface.
- the indicated coating reduces the inhibition of the passage or passage of the screen printing paste or the screen printing ink through the fabric stitches or the openings in the stencil so that a fabric with a smaller mesh size or a stencil with smaller openings can be used and thus finer structures can be generated.
- the effect of reduced adhesion of the screen printing paste or the screen printing ink to the fabric or stencil is also referred to as the lotus effect.
- the non-stick coating becomes particularly simple by means of a nanocrystalline coating, which preferably has crystals with a diameter of less than 10 nanometers.
- a nanocrystalline coating which preferably has crystals with a diameter of less than 10 nanometers.
- Such a coating also has the advantage that it can be applied very thin so that it does not cause any significant additional change in the mesh size or the opening width of the template.
- a carbon compound having a diamond-like structure (DLC) and / or a fluoride and / or a fluorine-based compound, preferably Teflon (polytetrafluoroethylene, PTFE), and / or a silicon-based compound can be used.
- the screen printing device has a coating with a layer thickness between about 100 nm and about a few micrometers.
- these layer thicknesses are sufficiently thick to ensure with a high degree of stability the easier passage of the screen printing ink or the screen printing paste through the fabric stitches or the stencil openings, and on the other hand permit the printing of fine-line structures.
- the coating is designed to be oleophobic in order to suppress sticking / sticking .
- This design of the screen printing device causes a clean distribution of the screen printing paste or screen ink (flooding of the screen) on the top and a good separation of the screen printing paste or the screen printing ink after the elimination of the shear forces applied by the doctor on the underside of the screen printing screen.
- the above object is also achieved by a method of manufacturing a screen printing apparatus in which the fabric is adhered to the fabric prior to applying the template to the fabric and / or the fabric and the template is applied to the fabric after application of the template to the fabric a screen printing paste or a screen printing ink to the fabric or stencil-reducing coating is provided.
- the inventive method causes very simple and inexpensive, the tissue can be used with smaller mesh size or templates with smaller openings and thereby allows the pressure of finer structures.
- the method according to the invention involves only a single additional coating step for this purpose.
- the known method for producing a SiebdrĆ¼ckvorraum is thereby not significantly expensive or complicated.
- a particularly simple and cost-effective coating option is given by a coating which is nanocrystalline, with a crystal diameter of less than 10 nanometers.
- a coating having a layer thickness of between about 100 nm and about a few micrometers is produced in the production method according to the invention. As already indicated above, these layer thicknesses allow the printing of fine-line structures with a high resistance.
- Further improvement of the coating properties can be achieved by placing the fabric and / or the stencil on top with an oleophilic (lipophilic / hydrophobic / hydrophobic) coating and / or on the underside of the fabric and / or the stencil and / or the interstices of the fabric and / or the template are provided with an oleophobic coating.
- the steel mesh of a screen printing device is coated after a plasma cleaning step by means of a plasma CVD process either with a silicone-like amorphous surface with about 100 nm layer thickness or with a DLC (Diamond Like Carbon) layer of 1 .mu.m (for example, trade name CARBOCER Ā® from PLASMA ELECTRONIC GmbH).
- the DLC coating is significantly harder than the silicone-type, whereas the latter can be applied at lower process temperatures.
- the coating of the fabric takes place at a temperature of about 80 Ā° C or correspondingly lower.
- the template is applied to the fabric.
- the stencil can be provided with this coating. The sequence depends on the material of the stencil and its heat resistance.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Textile Engineering (AREA)
- Printing Plates And Materials Therefor (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Coloring (AREA)
Description
Die vorliegende Erfindung betrifft eine Siebdruckvorrichtung mit einem Gewebe und eine in dem Gewebe angeordnete Schablone in Form einer fotolithographisch strukturierten Emulsion. Die Erfindung betrifft ferner ein Verfahren zur Herstellung einer derartigen Siebdruckvorrichtung.The present invention relates to a screen printing device with a fabric and arranged in the fabric template in the form of a photolithographically structured emulsion. The invention further relates to a method for producing such a screen printing device.
Der Siebdruck ist ein Druckverfahren, bei dem eine Druckfarbe oder Druckpaste mit einem messerƤhnlichen Werkzeug, dem Gummirakel (Druckrakel), durch ein feinmaschiges Gewebe hindurch auf das zu bedruckende Material gedruckt wird. Der Siebdruck wird deshalb auch als Durchdruckverfahren bezeichnet. An den Stellen des Gewebes, wo dem Bildmotiv entsprechend keine Farbe gedruckt werden soll, sind die Maschenƶffnungen des Gewebes durch eine an dem Gewebe angeordnete Schablone (z.B. fotolithographisch strukturierte Emulsion) undurchlƤssig fĆ¼r die Druckfarbe oder Druckpaste.Screen printing is a printing process in which an ink or print paste is printed through a fine mesh fabric onto the material to be printed with a knife-like tool, the rubber squeegee. Screen printing is therefore also referred to as a through-printing process. At the locations of the fabric where no color is to be printed according to the image motif, the mesh apertures of the fabric are impermeable to the ink or printing paste by a stencil (e.g., photolithographically structured emulsion) disposed on the fabric.
Neben dem Einsatz im Bereich der Werbung und Beschriftung, im Textil- oder Keramikdruck wird der Siebdruck heute hƤufig auch fĆ¼r das Drucken von Schaltungen im Bereich der Hybridtechnologie, zum Beispiel im Bereich der Mehrlagenkeramiktechnologie verwendet. Ein Beispiel fĆ¼r eine Mehrlagenkeramiktechnologie ist die sogenannte LTCC-Technologie (LTCC = Low Temperature Cofired Ceramics, dt. Niedertemperatur-Einbrand-Keramik), die eine kostengĆ¼nstige Technologie zur Herstellung von Mehrlagenschaltungen auf der Basis von gesinterten KeramiktrƤgern, die in mehreren Lagen Verdrahtungsebenen verbunden durch z-Kontaktierungen, sog. Vias beinhalten, darstellt. Bei der LTCC-Technologie werden die Schaltungselemente mittels Siebdruck auf die GrĆ¼nfolien des spƤteren KeramiktrƤgers aufgebracht, die dann gestapelt und gesintert werden.In addition to advertising and lettering, textiles and ceramics printing, screen printing today is frequently also used for printing circuits in the field of hybrid technology, for example in the field of multilayer ceramic technology. An example of a multilayer ceramic technology is the so-called LTCC (Low Temperature Cofired Ceramics) technology, which is a cost-effective technology for producing multilayer circuits based on sintered ceramic substrates that are interconnected in multiple layers of wiring z-contacts, so-called vias involve represents. In the LTCC technology, the circuit elements are screen printed on the green sheets of the later ceramic support, which are then stacked and sintered.
Die moderne Packaging-Entwicklung fordert heute ungeachtet des Einsatzgebietes das Drucken von feineren Strukturen (Feinstline-Strukturen), um Einbauplatz zu sparen oder um den Verbrauch hochpreisiger Pasten zu minimieren. AuĆerdem fordert die moderne Hochfrequenztechnik in AbhƤngigkeit der Einsatzfrequenz enge Leiterzugbreiten, die auf Basis von Verlusten und gegebenen Impedanzen durch umfangreiche Simulationen vorgegeben werden. Es ist daher wĆ¼nschenswert, feinere Strukturen zu drucken. Zudem kƶnnten, wenn es gelƤnge, feinere Strukturen zu drucken, Mehrlagentechnologie-Prozesse wie LTCC Schaltungen ersetzen, die bisher mittels der DĆ¼nnfilm-Technik hergestellt wurden. Die DĆ¼nnfilm-Technik wird aufgrund ihrer hohen Strukturauflƶsung bisher auf dem Gebiet der Hochfrequenzschaltungen im Hƶchstfrequenz-Bereich verwendet, um HF-taugliche Strukturen zu realisieren. Diese Technik wird durch Abscheidungs- und ĆtzvorgƤnge realisiert. Sie erfordert den Einsatz sehr ebener, vorbehandelter und hochpreisiger Substrate. Zudem ist der DĆ¼nnfilm-Prozess an sich ein kostenintensives Verfahren. DĆ¼nnfilmstrukturen lassen sich auĆerdem nur koplanar auf der SubstratoberflƤche realisieren. Der Einsatz der Mehrlagentechnologie mit Feinstline-Strukturen kƶnnte gegenĆ¼ber der DĆ¼nnfilm-Technik eine deutliche Kostenreduzierung bringen und auĆerdem den Vorteil der Nutzung mehrerer Ebenen u. a. auch fĆ¼r Schirmlagen bieten.Today, regardless of the field of application, modern packaging development demands the printing of finer structures (fine-line structures) in order to save space or to minimize the consumption of high-priced pastes. In addition, the modern high-frequency technology calls depending on the frequency use close Leiterzugbreiten that on Basis of losses and given impedances can be predetermined by extensive simulations. It is therefore desirable to print finer structures. Additionally, if one were able to print finer structures, multi-layer technology processes such as LTCC could replace circuits previously made using thin-film technology. Due to its high structural resolution, the thin-film technique has hitherto been used in the field of high-frequency circuits in the ultra-high frequency range in order to realize structures suitable for HF. This technique is realized by deposition and etching processes. It requires the use of very flat, pretreated and high-priced substrates. In addition, the thin-film process is itself a costly process. In addition, thin-film structures can only be realized coplanar on the substrate surface. The use of multi-layer technology with fine-line structures could bring a significant cost reduction compared to thin-film technology and also offer the advantage of using several levels, including for screen layers.
FĆ¼r den Siebdruck im Bereich der Mehrlagen-Technologie (Dickschichttechnik) sind die Siebdruckrahmen meistens aus Aluminium und werden mit einem Stahlgewebe bespannt, mit dem sich die wƤhrend des Druckvorgangs erforderliche elastische Durchbiegung des Siebes erreichen lƤsst. Eine elastische Durchbiegung des Siebes wƤhrend des Druckvorgangs ist erforderlich fĆ¼r den sogenannten Absprung, d. h. fĆ¼r die zwischen Gewebe und zu bedruckendem Substrat realisierbare Distanz. Zu wenig Absprung kann beispielsweise zur Wolkenbildung im Druck fĆ¼hren, da sich das Gewebe hinter dem Rakel nicht sofort aus dem gedruckten Pastenfilm lƶst - es bleibt in der gedruckten Paste "kleben". Zuviel Absprung erhƶht hingegen die Gewebespannung, was zum einen zu einem Ćberschreiten der elastischen Dehngrenze des Gewebes fĆ¼hrt und damit zu einem Vorzeitigen Altern des Gewebes, und zum anderen zu unsauberen Ausdrucken aufgrund von Pastenspritzern fĆ¼hren kann, so dass die Schablonenkante kein sauberes Druckbild mehr zeichnen kann.For screen printing in the field of multi-layer technology (thick-film technology), the screen frames are usually made of aluminum and are covered with a steel mesh, which can be achieved during the printing process elastic deflection of the screen. An elastic deflection of the screen during the printing process is required for the so-called bounce, d. H. for the realizable between tissue and substrate to be printed distance. For example, too little jump may lead to cloud formation in the print, since the fabric behind the squeegee does not immediately detach from the printed paste film - it remains "stuck" in the printed paste. Too much bounce, on the other hand, increases tissue tension which, on the one hand, leads to exceeding the elastic yield strength of the tissue and thus leading to premature aging of the fabric and, on the other, impure printouts due to paste spatters, so that the template edge can no longer draw a clean print image ,
Die DrahtstƤrke der verwendeten Gewebe betrƤgt heute etwa zwischen 30 Mikrometern und 16 Mikrometern. Die DurchlƤssigkeit des Gewebes wird durch seine Maschenweite beschrieben, die mittels der sogenannten Mesh-Zahl angegeben wird. Beispielsweise bedeutet 325 Mesh, dass 325 Maschen je Quadratzoll (Quadratinch) vorliegen.The wire thickness of the fabrics used today is approximately between 30 micrometers and 16 micrometers. The permeability of the fabric is described by its mesh size, which is indicated by the so-called mesh number. For example, 325 mesh means that there are 325 stitches per square inch (square inches).
Die Schablone wird hƤufig als Direktschablone mittels eines fotografischen Verfahrens hergestellt. HierfĆ¼r wird das Gewebe mit fotosensitiven Polymeren beschichtet, die mit den gewĆ¼nschten Strukturen belichtet werden. AnschlieĆend werden die belichteten Strukturen entwickelt und die unbelichteten Bereiche ausgewaschen. Das Gewebe, die Schablone (Emulsion) und der Druckrahmen bilden zusammen das Siebdrucksieb.The stencil is often made as a direct stencil by a photographic process. For this purpose, the fabric is coated with photosensitive polymers, which with be exposed to the desired structures. Subsequently, the exposed structures are developed and the unexposed areas are washed out. The fabric, stencil (emulsion) and printing frame together form the screen printing screen.
Beim Drucken wird die Druckpaste auf das Sieb aufgebracht und gleichmƤĆig mittels eines sogenannten Flutrakels auf dem strukturierten Sieb verteilt. AnschlieĆend findet der eigentliche Druckvorgang statt, wobei das Druckrakel mit einer entsprechend angepassten HƤrte Ć¼ber das Sieb gezogen wird. Das Sieb befindet sich bei diesem Druckvorgang in einem bestimmten Abstand von dem zu bedruckenden Substrat, beispielsweise einer LTCC-Folie. Das Sieb wird mittels des Druckrakels elastisch nach unten in Richtung des zu bedruckenden Substrates gedrĆ¼ckt. Gleichzeitig erfolgt mittels des Druckrakels eine Scherung der Druckpaste, die aufgrund ihrer thixotropen Eigenschaft wƤhrend der Scherung ihre ViskositƤt erniedrigt und hierdurch durch die Ćffnungen des Siebdrucksiebs gepresst werden kann. Nach Beendigung der Scherbeanspruchung weist die Druckpaste wieder die AusgangsviskositƤt auf.During printing, the printing paste is applied to the screen and distributed evenly on the structured screen by means of a so-called flood doctor blade. Subsequently, the actual printing takes place, wherein the squeegee is pulled over the wire with a suitably adjusted hardness. The screen is in this printing at a certain distance from the substrate to be printed, for example, an LTCC film. The screen is pressed by means of the printing doctor down elastically in the direction of the substrate to be printed. At the same time by means of the printing doctor blade, a shear of the printing paste, which reduces its viscosity due to their thixotropic property during the shear and thereby can be pressed through the openings of the screen printing screen. After completion of the shear stress, the printing paste again has the initial viscosity.
Wenn kleinere Auflƶsungen der gedruckten Strukturen (Feinstline-Strukturen) erreicht werden sollen, d. h. eine Auflƶsung unter 50 Mikrometern oder sogar unter 30 Mikrometern, ergibt sich das Problem, dass hierfĆ¼r das Gewebe und die Schablone entsprechend feine Strukturen mit kleinen Ćffnungen aufweisen mĆ¼ssen und diese feinen Strukturen und kleinen Ćffnungen in der Schablone und dem Gewebe den Farben- oder Pastenfluss durch das Siebdrucksieb hemmen.If smaller resolutions of the printed structures (fine-line structures) are to be achieved, d. H. For example, if the resolution is less than 50 microns or even less than 30 microns, there is a problem that the fabric and the template must have correspondingly fine structures with small openings and these fine structures and small openings in the template and the fabric through the flow of colors or pastes inhibit the screen printing screen.
In der Druckschrift
Die
Die Druckschrift
Die Aufgabe der vorliegenden Erfindung ist es daher, eine Siebdruckvorrichtung anzugeben, die das Drucken feinerer Strukturen ermƶglicht. AuĆerdem besteht die Aufgabe der vorliegenden Erfindung darin, ein Verfahren zur Herstellung einer Siebdruckvorrichtung anzugeben, das einfach und kostengĆ¼nstig das Drucken feinerer Strukturen, insbesondere fĆ¼r ein Stahlgewebe, ermƶglicht.The object of the present invention is therefore to provide a screen printing apparatus which enables the printing of finer structures. In addition, the object of the present invention is to provide a method for producing a screen printing device, which allows easy and cost-effective the printing of finer structures, in particular for a steel fabric.
ErfindungsgemĆ¤Ć wird die Aufgabe durch eine Siebdruckvorrichtung gelƶst, bei der das Gewebe und/oder die Schablone jeweils auf der OberflƤche eine das Anhaften einer Siebdruckpaste oder einer Siebdruckfarbe an das Gewebe und/oder an die Schablone vermindernde nanokristallinen Beschichtung aufweist.According to the invention, the object is achieved by a screen printing apparatus in which the fabric and / or the stencil has a nanocrystalline coating which reduces the adhesion of a screen printing paste or a screen printing ink to the fabric and / or to the stencil on the surface.
Durch die angegebene Beschichtung wird erfindungsgemĆ¤Ć die Hemmung des Durchflusses oder Durchtretens der Siebdruckpaste oder der Siebdruckfarbe durch die Gewebemaschen bzw. die Ćffnungen in der Schablone verringert, sodass ein Gewebe mit einer kleineren Maschenweite bzw. eine Schablone mit kleineren Ćffnungen verwendet werden kann und hierdurch feinere Strukturen erzeugt werden kƶnnen. Der Effekt des verringerten Anhaftens der Siebdruckpaste oder der Siebdruckfarbe an dem Gewebe bzw. der Schablone wird auch als Lotus-Effekt bezeichnet.The indicated coating, according to the invention, reduces the inhibition of the passage or passage of the screen printing paste or the screen printing ink through the fabric stitches or the openings in the stencil so that a fabric with a smaller mesh size or a stencil with smaller openings can be used and thus finer structures can be generated. The effect of reduced adhesion of the screen printing paste or the screen printing ink to the fabric or stencil is also referred to as the lotus effect.
Besonders einfach wird die Antihaft-Beschichtung mittels einer nanokristallin ausgebildeten Beschichtung, die vorzugsweise Kristalle mit einem Durchmesser von weniger als 10 Nanometern aufweist. Eine derartige Beschichtung hat zudem den Vorteil, dass sie sehr dĆ¼nn aufgetragen werden kann, so dass sie keine wesentliche zusƤtzliche Ćnderung der Maschenweite oder der Ćffnungsweite der Schablone bewirkt.The non-stick coating becomes particularly simple by means of a nanocrystalline coating, which preferably has crystals with a diameter of less than 10 nanometers. Such a coating also has the advantage that it can be applied very thin so that it does not cause any significant additional change in the mesh size or the opening width of the template.
Als besonders geeignetes Beschichtungsmaterial fĆ¼r die Beschichtung kann eine Kohlenstoff-Verbindung mit einer diamantƤhnlichen Struktur (DLC) und/oder ein Fluorid und/oder eine fluorbasierte Verbindung, vorzugsweise Teflon (Polytetrafluorethylen, PTFE), und/oder eine siliziumbasierte Verbindung verwendet werden.As a particularly suitable coating material for the coating, a carbon compound having a diamond-like structure (DLC) and / or a fluoride and / or a fluorine-based compound, preferably Teflon (polytetrafluoroethylene, PTFE), and / or a silicon-based compound can be used.
In einem weiteren bevorzugten AusfĆ¼hrungsbeispiel weist die Siebdruckvorrichtung eine Beschichtung mit einer Schichtdicke zwischen etwa 100 nm und etwa einigen Mikrometern auf. Diese Schichtdicken sind einerseits genĆ¼gend dick, um mit einer hohen BestƤndigkeit das leichtere Hindurchtreten der Siebdruckfarbe oder der Siebdruckpaste durch die Gewebemaschen bzw. die Schablonenƶffnungen zu gewƤhrleisten, und erlauben andererseits das Drucken von Feinstline-Strukturen.In a further preferred embodiment, the screen printing device has a coating with a layer thickness between about 100 nm and about a few micrometers. On the one hand, these layer thicknesses are sufficiently thick to ensure with a high degree of stability the easier passage of the screen printing ink or the screen printing paste through the fabric stitches or the stencil openings, and on the other hand permit the printing of fine-line structures.
In einem besonders bevorzugten AusfĆ¼hrungsbeispiel ist die Beschichtung auf der Oberseite des Gewebes und/oder der Schablone, d. h. auf der dem zu bedruckenden Substrat abgewandten Seite des Gewebes und/oder der Schablone, oleophil (hydrophil/-phob, lipophil/-phob) um durch das Anhaften der Paste eine Rollbewegung und damit eine gute Scherung zu erreichen, um den Tixotropieeffekt aufzubauen. Auf der Unterseite des Gewebes und/oder der Schablone, d. h. auf der dem zu bedruckenden Substrat zugewandten Seite des Gewebes und/oder der Schablone, und in den ZwischenrƤumen des Gewebes und der Schablone ist die Beschichtung oleophob ausgebildet, um ein Anhaften/Kleben zu unterdrĆ¼cken. Diese Gestaltung der Siebdruckvorrichtung bewirkt ein sauberes Verteilen der Siebdruckpaste oder der Siebdruckfarbe (Fluten des Siebes) auf der Oberseite und ein gutes Ablƶsen der Siebdruckpaste bzw. der Siebdruckfarbe nach dem Wegfall der durch das Rakel aufgebrachten ScherkrƤfte auf der Unterseite des Siebdrucksiebs.In a particularly preferred embodiment, the coating on the top of the fabric and / or the template, ie on the side facing away from the substrate to be printed on the tissue and / or the template, oleophilic (hydrophilic / -phobic, lipophilic / -phobic) by Sticking the paste a rolling motion and thus a good To achieve shear to build up the Tixotropieeffekt. On the underside of the fabric and / or the stencil, ie on the side of the fabric and / or the stencil facing the substrate to be printed, and in the interstices of the fabric and the stencil, the coating is designed to be oleophobic in order to suppress sticking / sticking , This design of the screen printing device causes a clean distribution of the screen printing paste or screen ink (flooding of the screen) on the top and a good separation of the screen printing paste or the screen printing ink after the elimination of the shear forces applied by the doctor on the underside of the screen printing screen.
Die obige Aufgabe wird auĆerdem durch ein Verfahren zur Herstellung einer Siebdruckvorrichtung gelƶst, bei dem das Gewebe vor dem Aufbringen der Schablone an dem Gewebe und/oder das Gewebe und die Schablone nach dem Aufbringen der Schablone an dem Gewebe jeweils auf der OberflƤche mit einer das Anhaften einer Siebdruckpaste oder einer Siebdruckfarbe an das Gewebe oder an der Schablone vermindernde Beschichtung versehen wird.The above object is also achieved by a method of manufacturing a screen printing apparatus in which the fabric is adhered to the fabric prior to applying the template to the fabric and / or the fabric and the template is applied to the fabric after application of the template to the fabric a screen printing paste or a screen printing ink to the fabric or stencil-reducing coating is provided.
Das erfindungsgemƤĆe Verfahren bewirkt sehr einfach und kostengĆ¼nstig, das Gewebe mit kleinerer Maschenweite bzw. Schablonen mit kleineren Ćffnungen verwendet werden kƶnnen und ermƶglicht hierdurch den Druck feinerer Strukturen. Das erfindungsgemƤĆe Verfahren beinhaltet hierfĆ¼r lediglich einen einzigen zusƤtzlichen Beschichtungsschritt. Das bekannte Verfahren zur Herstellung einer SiebdrĆ¼ckvorrichtung wird dadurch nicht wesentlich verteuert bzw. verkompliziert.The inventive method causes very simple and inexpensive, the tissue can be used with smaller mesh size or templates with smaller openings and thereby allows the pressure of finer structures. The method according to the invention involves only a single additional coating step for this purpose. The known method for producing a SiebdrĆ¼ckvorrichtung is thereby not significantly expensive or complicated.
Eine besonders einfache und kostengĆ¼nstige Beschichtungsmƶglichkeit wird durch eine Beschichtung gegeben, die nanokristallin, mit einem Kristalldurchmesser von weniger als 10 Nanometern ausgebildet ist.A particularly simple and cost-effective coating option is given by a coating which is nanocrystalline, with a crystal diameter of less than 10 nanometers.
In einem weiteren bevorzugten AusfĆ¼hrungsbeispiel wird bei dem erfindungsgemƤĆen Herstellungsverfahren eine Beschichtung mit einer Schichtdicke zwischen etwa 100 nm und etwa einigen Mikrometern erzeugt. Wie oben bereits dargestellt, erlauben diese Schichtdicken das Drucken von Feinstline-Strukturen mit einer hohen BestƤndigkeit.In a further preferred embodiment, a coating having a layer thickness of between about 100 nm and about a few micrometers is produced in the production method according to the invention. As already indicated above, these layer thicknesses allow the printing of fine-line structures with a high resistance.
Ebenso ist eine kostengĆ¼nstige Beschichtung durch ein Beschichtungsmaterial erreichbar, das eine Kohlenstoff-Verbindung mit einer diamantƤhnlichen Struktur (DLC = diamond like carbon) und/oder ein Fluorid und/oder eine fluorbasierte Verbindung, vorzugsweise PTFE, und/oder eine siliziumbasierte Verbindung enthƤlt. Eine weitere Verbesserung der Eigenschaften der Beschichtung kann erreicht werden, indem das Gewebe und/oder die Schablone auf ihrer Oberseite mit einer oleophilen (lipophil/-phoben, hydrophil/-phoben) Beschichtung und/oder auf der Unterseite des Gewebes und/oder der Schablone und/oder die ZwischenrƤume des Gewebes und/oder der Schablone mit einer oleophoben Beschichtung versehen werden.Likewise, an inexpensive coating can be achieved by a coating material which has a carbon compound with a diamond-like structure (DLC = diamond-like structure) carbon) and / or a fluoride and / or a fluorine-based compound, preferably PTFE, and / or contains a silicon-based compound. Further improvement of the coating properties can be achieved by placing the fabric and / or the stencil on top with an oleophilic (lipophilic / hydrophobic / hydrophobic) coating and / or on the underside of the fabric and / or the stencil and / or the interstices of the fabric and / or the template are provided with an oleophobic coating.
Weitere Ziele, Merkmale, Vorteile und Anwendungsmƶglichkeiten der Erfindung ergeben sich aus der nachfolgenden Beschreibung eines AusfĆ¼hrungsbeispiels. Alle beschriebennen und/oder bildlich dargestellten Merkmale bilden fĆ¼r sich oder in beliebiger Kombination den Gegenstand der vorliegenden Erfindung, unabhƤngig von ihrer Zusammenfassung in den einzelnen AnsprĆ¼chen oder deren RĆ¼ckbeziehung.Other objects, features, advantages and applications of the invention will become apparent from the following description of an embodiment. All described and / or illustrated features form the subject of the present invention, alone or in any combination, regardless of their summary in the individual claims or their dependency.
Das Stahlgewebe einer Siebdruckvorrichtung wird nach einem Plasma-Reinigungsschritt mittels eines Plasma-CVD Verfahrens entweder mit einer silikonartigen amorphen OberflƤche mit ca. 100 nm SchichtstƤrke beschichtet oder mit einer DLC (Diamond Like Carbon) -Schicht von 1 Āµm (z. B. Handelsname CARBOCERĀ® der Firma PLASMA ELECTRONIC GmbH) versehen. Die DLC-Beschichtung ist deutlich hƤrter als die silikonartige, wobei die letztere dagegen bei niedrigeren Prozesstemperaturen aufgebracht werden kann. Die Beschichtung des Gewebes erfolgt bei einer Temperatur von ca. 80Ā°C oder entsprechend niedriger. AnschlieĆend wird die Schablone auf das Gewebe aufgebracht. Alternativ kann zusƤtzlich auch die Schablone mit dieser Beschichtung versehen werden. Die Abfolge hƤngt vom Material der Schablone und seiner WƤrmebestƤndigkeit ab.The steel mesh of a screen printing device is coated after a plasma cleaning step by means of a plasma CVD process either with a silicone-like amorphous surface with about 100 nm layer thickness or with a DLC (Diamond Like Carbon) layer of 1 .mu.m (for example, trade name CARBOCER Ā® from PLASMA ELECTRONIC GmbH). The DLC coating is significantly harder than the silicone-type, whereas the latter can be applied at lower process temperatures. The coating of the fabric takes place at a temperature of about 80 Ā° C or correspondingly lower. Then the template is applied to the fabric. Alternatively, in addition, the stencil can be provided with this coating. The sequence depends on the material of the stencil and its heat resistance.
Deutlich niedrigere Abscheidetemperaturen kƶnnen mit einer amorphen (glasartigen) Beschichtung erreicht werden. Diese silikonartige OberflƤche hat zwar den Vorteil der geringeren Prozesstemperatur, weist allerdings lediglich eine OberflƤchenhƤrte geringer als Glas auf. Es sind bei dieser Abscheidung 40Ā°C angestrebt im Vergleich zu 80Ā°C bei DLC Schichten, die wiederum HƤrten annƤhernd Diamant (Mohs 9-10) aufweisen. Alle Schichten werden im Plasma-CVD-Verfahren abgeschieden. Auch die oleophilen Schichten werden mit einem Plasma-CVD-Prozess aufgebracht und sind den DLC-Schichten Ƥhnlich. Lediglich ein anderer Zusatz von Dotiergasen verƤndert die OberflƤcheneigenschaften. Sich ausbildende WasserstoffbrĆ¼cken, OH-Gruppen oder Carboxyle verƤndern die OberflƤcheneigenschaften in Richtung oleo- (lippo- / hydro-) phil oder -phob. Ein Einbau von erhƶhten Sauerstoffanteilen fƶrdert den oleophilen Charakter der OberflƤche. Der Einbau von Silizium fƶrdert den oleophoben Charakter. Der Handelsname des oleophilen (hydrophile) Beschichtungsverfahrens der Firma PLASMA ELECTRONIC ist AQUA-CERĀ®. Significantly lower deposition temperatures can be achieved with an amorphous (glassy) coating. Although this silicone-like surface has the advantage of lower process temperature, but has only a surface hardness lower than glass. The aim of this deposition is 40 Ā° C compared to 80 Ā° C for DLC layers, which in turn have hardnesses close to diamond (Mohs 9-10). All layers are deposited by plasma CVD. The oleophilic layers are also applied by a plasma CVD process and are similar to the DLC layers. Only another addition of doping gases changes the surface properties. Forming hydrogen bonds, OH groups or carboxyls alter the surface properties in the direction of oleo (lipo / hydro) phil or phob. Incorporation of increased levels of oxygen promotes the oleophilic character of the surface. The incorporation of silicon promotes the oleophobic character. The commercial name of the PLASMA ELECTRONIC oleophilic (hydrophilic) coating process is AQUA-CERĀ®.
Claims (10)
- A screen printing device having a fabric and a template arranged on said fabric, characterized in that said fabric and/or said template each have, on a surface, a nanocrystalline coating which reduces adhesion of a screen printing paste or a screen printing ink to said fabric and/or to said template.
- The screen printing device according to claim 1, characterized in that said nanocrystalline coating includes crystals with a diameter of less than 10 nm.
- The screen printing device according to any of the preceding claims, characterized in that said coating contains a carbon compound having a diamond-like structure (DLC) and/or a fluoride and/or a fluorine-based compound, preferably PTFE, and/or a silicon-based compound.
- The screen printing device according to any of the preceding claims, characterized in that said coating has a layer thickness between approximately 100 nm and approximately a few micrometers.
- The screen printing device according to any of the preceding claims, characterized in that said coating is implemented on a top side of said fabric and/or said template as oleophilic (hydrophilic/hydrophobic, lipophilic/lipophobic), and/or as oleophobic on a bottom side of said fabric and/or said template and/or in intermediate spaces of said fabric and/or said template.
- A method for producing a screen printing device according to any of the preceding claims, characterized in that said fabric, before application of said template to said fabric, and/or said fabric and said template, after application of said template to said fabric, are each provided on the surface of a side facing toward a printing product and in intermediate spaces with a nanocrystalline coating which reduces adhesion of a screen printing paste or a screen printing ink to said fabric and/or to said template.
- The method according to claim 6, characterized in that the nanocrystalline coating is implemented with a crystal diameter of less than 10 nm.
- The method according to one of claims 6 to 7, characterized in that said coating contains a carbon compound having a diamond-like structure (DLC) and/or a fluoride and/or fluorine-based compound, preferably PTFE, and/or a silicon-based compound.
- The method according to one of claims 6 to 8, characterized in that said coating is generated having a layer thickness between approximately 100 nm and approximately a few micrometers.
- The method according to one of claims 6 to 9, characterized in that said fabric and/or said template is provided on its top side with an oleophilic (lipophilic/lipophobic, hydrophilic/hydrophobic) coating and/or on a bottom side of said fabric and/or said template and/or intermediate spaces of said fabric and/or said template with an oleophobic coating.
Applications Claiming Priority (1)
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DE102007010936A DE102007010936A1 (en) | 2007-03-07 | 2007-03-07 | Screen printing apparatus and method of making the same |
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EP1967363A2 EP1967363A2 (en) | 2008-09-10 |
EP1967363A3 EP1967363A3 (en) | 2010-11-03 |
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DE (1) | DE102007010936A1 (en) |
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DE102011083733A1 (en) | 2011-09-29 | 2013-04-04 | Siemens Aktiengesellschaft | Screen printing stencil and method for coating screen printing stencils |
CN103192594A (en) * | 2012-01-06 | 2013-07-10 | ęå±±å ååå ēµē§ęęéå ¬åø | Solar energy compound screen |
CN102615932B (en) * | 2012-04-06 | 2013-12-11 | ę·±å³å éµč¾¾å ēµē§ęč”份ęéå ¬åø | Metal printing template, manufacturing method of metal printing template and coating solution used in metal printing template |
WO2014189026A1 (en) * | 2013-05-20 | 2014-11-27 | å¤Ŗé½åå¦å·„ę„ę Ŗå¼ä¼ē¤¾ | Structure and stencil printing plate which have been subjected to wettability-improving surface modification, and processes for producing both |
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AT30664B (en) | 1906-04-02 | 1907-11-25 | Anton Mattig | Counter. |
US2790726A (en) * | 1953-02-12 | 1957-04-30 | Wilson Arts & Crafts | Silk screen paint materials |
US3008601A (en) * | 1954-12-13 | 1961-11-14 | Collette Gregoire | Polytetrafluoroethylene coated cooking utensils |
US3672934A (en) * | 1970-05-01 | 1972-06-27 | Du Pont | Method of improving line resolution in screen printing |
US4088073A (en) * | 1973-12-27 | 1978-05-09 | Xerox Corporation | Process for preparing ink releasing stencil |
US3951060A (en) * | 1973-12-27 | 1976-04-20 | Xerox Corporation | Process for preparing waterless lithographic masters |
US4718340A (en) * | 1982-08-09 | 1988-01-12 | Milliken Research Corporation | Printing method |
GB9319070D0 (en) * | 1993-09-15 | 1993-11-03 | Ncr Int Inc | Stencil having improved wear-resistance and quality consistency and method of manufacturing the same |
DE19738873A1 (en) | 1996-09-13 | 1998-04-16 | Sefar Ag | Screen printing forme |
US6669781B2 (en) * | 1997-09-23 | 2003-12-30 | Micron Technology, Inc. | Method and apparatus for improving stencil/screen print quality |
US20020011159A1 (en) | 2000-04-19 | 2002-01-31 | Asahi Glass Company, Limited | Screen printing plate, method for making it and screen printing method |
DE10231698A1 (en) * | 2002-03-26 | 2003-10-23 | Fraunhofer Ges Forschung | Process for improving the transfer of additive material to support used in the production of printed circuit boards comprises using template having openings with coating for the structured transfer of the additive material to the support |
US7152530B2 (en) * | 2002-12-19 | 2006-12-26 | Heidelberger Druckmaschinen Ag | Printing form and method for modifying its wetting properties |
DE102004055113A1 (en) | 2004-11-15 | 2006-05-18 | Kissel & Wolf Gmbh | Method for the hydrophilization of screen printing stencil carriers and method for removing stencil material from a screen stencil carrier and decoating liquid therefor |
DE102005063510B4 (en) | 2005-09-22 | 2010-06-02 | Siemens Aktiengesellschaft | Use of a method for coating a printing stencil of an SMT process |
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- 2007-03-07 DE DE102007010936A patent/DE102007010936A1/en not_active Withdrawn
- 2007-12-04 HU HUE07023414A patent/HUE037624T2/en unknown
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HUE037624T2 (en) | 2018-09-28 |
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