EP1945857A1 - Integration de particules de securite non allongees dans des documents de valeur - Google Patents

Integration de particules de securite non allongees dans des documents de valeur

Info

Publication number
EP1945857A1
EP1945857A1 EP20060778438 EP06778438A EP1945857A1 EP 1945857 A1 EP1945857 A1 EP 1945857A1 EP 20060778438 EP20060778438 EP 20060778438 EP 06778438 A EP06778438 A EP 06778438A EP 1945857 A1 EP1945857 A1 EP 1945857A1
Authority
EP
European Patent Office
Prior art keywords
tape
sheet
particles
product
binder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP20060778438
Other languages
German (de)
English (en)
Inventor
Karel Soete
Carl Vromant
Dominique Santens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bekaert NV SA
Original Assignee
Bekaert NV SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bekaert NV SA filed Critical Bekaert NV SA
Priority to EP20060778438 priority Critical patent/EP1945857A1/fr
Publication of EP1945857A1 publication Critical patent/EP1945857A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]

Definitions

  • the present invention relates to a coherent sheet-like or tape- like product with security particles. According to a second aspect, the present invention also relates to a value document comprising such a sheet-like or tape-like product. According to a third aspect, the invention relates to two methods of manufacturing a sheet-like or tape-like product.
  • US-A-4,265,703 discloses a method of integrating security particles in the form of metal fibers into a fibrous structure such as paper. Indeed, the difference in specific gravity between metal fibers and paper-like material makes a homogeneous distribution of the metal fibers in a paper substrate difficult, if no precautions are taken.
  • the precautions taken by US-A-4,265,703 consist in subjecting a bundle of metal particles to a bath of a hydro soluble binder so as to make a coated bundle.
  • the hydro soluble binder is either polyvinyl alcohol or starch.
  • the fiber bundle is dried and cut into predetermined lengths of agglomerates binder- fiber.
  • the agglomerates are mixed with paper particles to form a sheet-like structure where the metal particles are homogeneously distributed.
  • the binder material serves as material for separating the filaments.
  • US-A-4,265,703 can also be applied to incorporate metal particles at limited locations in value documents. These limited locations may take the form of bands or strips. Experience has shown that it is difficult to keep the width of such bands or strips within predetermined narrow limits. Furthermore, some dimensions, e.g. very small widths, are not obtainable.
  • the security level to be provided by the metal particles also depends on the exact geographical location of the metal particles in the value document, too big a variation in this geographical location is not acceptable.
  • a coherent sheet-like or tape-like product adapted to be integrated into value products or documents.
  • the product comprises :
  • value documents refer to all types of valuable documents such as bank notes, bonds, passports, credit-cards, access tickets, ...
  • the security particles are be either integrated into or onto the documents.
  • non-elongated security particles are used in order to make a distinction with fiber-like products and refer to particles where the various dimensions (e.g. length, width, depth) can vary with respect to each other only to a limited extent, e.g. to a factor less than 10, preferably less than 6, e.g. less than 5.
  • non-elongated particles cover powders, small spheres, pigments and the like. The absolute values of the dimensions are smaller than the ultimate thickness of the final value documents.
  • the particles In order to function as "security particles", the particles have parameters, which are detectably different from the substrate material .
  • the detectable difference may take various forms such as optical difference (e.g. difference in reflection or absorption or transmittance), electrical conductivity, magnetic coercivity, harmonic response, microwave reflection, microwave absorptions or the like.
  • non-elongated security particles may also be added.
  • particles which have an affinity with the substrate already at this stage in the sheet-like or tape-like product.
  • the substrate comprises paper
  • the non-elongated security particles may be present in the sheet-like or tape-like product in a concentration ranging from 1. OxIO "6 to 1.0xl0 "3 g/cm 2 .
  • a paper or plastic compatible binder refer to a binder that can be integrated easily into a paper or plastic matrix. Either the binder disappears during the process of integration or the binder can be bound to paper or plastic.
  • the binder is a water-soluble binder. This makes the binder particularly advantageous for integration in paper.
  • the binder may be selected from the group consisting of polyvinyl alcohols, methyl cellulose ethers, hydroxypropylmethylcellulose, polyethers from ethylene oxide, acrylic acid polymers or acrylic copolymers.
  • methyl cellulose has following advantages as a binder in this context : it is a cheap binder material, any shaping or mixing can be done under room conditions, reuse of the methyl cellulose and of the material mixed with it, is possible.
  • the binder material methyl cellulose easily disintegrates when heated.
  • the tape-like or sheet-like product has only a transitory existence. Its purpose is to control better the concentration of the security particles and the geometry of the region of security particles. This control is done at the level of the tape-like or sheet-like material and not at the level of the final value document or value product.
  • the tape- like or sheet-like product is to integrate with the value document or value product. Once this integration step done, it is no longer possible to extract the tape-like or sheet-like material intact from the value document or value product. So during its life, the tape-like or sheet-like product must stay coherent and strong. At the time of integration with the value document or value product, the tape-like or sheet-like product must cease to exist as such.
  • a plasticizer may be added and mixed together with the security particles and the binder material in the solvent.
  • a plasticizer makes the sheet-like or tape-like product stronger and more flexible.
  • An example of a plasticizer is polyethylene glycol.
  • Another example is polyvinyl alcohol.
  • the plasticizer may also have another function, particularly in case the sheet-like or tape-like product is to be integrated in paper value documents. Paper manufacturing is done in a very humid atmosphere with a lot of water. Correct amounts of plasticizer present in the tape-like or sheet-like product may control the time required for the disintegration process of the tape-like or sheet-like material and its integration in the paper value documents. Next to plasticizers, titantiumdioxide (TiO 2 ) and carbonates may also fulfill this function. The higher the amount of plasticizer, TiO 2 or carbonates, the longer the disintegration process takes.
  • color additives may be mixed together with the security particles and the binder material. This may give a particular and predetermined color to the sheet-like or tape-like product. The given color may mask the presence of security particles.
  • the sheet-like or tape-like product is made porous, e.g. by making small perforations in the sheet-like or tape-like product. This porosity facilitates the evacuation of water during the integration of the sheet-like or tape-like product in a paper substrate.
  • a value document or a value product in which or on which the tape-like or sheet-like product has been integrated.
  • the first method comprises the following steps : a) providing a binder in a liquid form or loose form, e.g. in a solvent such as water ; b) providing non-elongated particles which will function as security particles ; c) mixing the particles in or with the binder ; d) casting the binder with the particles ; e) drying or heat treating the cast binder with the particles to form a coherent sheet-like or tape-like product.
  • step c) the particles are mixed with the binder material in a controllable and determinable concentration. If abstraction is made of the non-security particles, possible other additives and of the solvent, the only parameters are the amount of security particles, the amount of binder material and the degree of mixing. Both the amount of security particles and the amount of binder material can be exactly determined.
  • the degree of mixing can be easily controlled e.g. by the revolutions of a screw in the mixture and by the working temperature.
  • the mixed particles in the binder are cast and dried or heat- treated, e.g. to vaporize the solvent, and form a coherent sheet-like or tape-like product.
  • the concentration of the security particles in this sheet-like or tape-like product and the variations hereof can be determined on this sheet-like or tape-like product before any integration into the final product.
  • the concentration of the security particles in the sheet-like or tape-like product is directly related to the concentration of the security particles in the final product or final document.
  • the tape-like or sheet-like product may be cast using an applicator such as a doctor blade.
  • the method further comprises the step of cutting the sheet-like or tape-like product.
  • This additional step has the advantage of exactly determining the dimensions of the location where the security particles can be found. Moreover, this exact determination is done in advance prior to the final value product or value document manufacturing. This means that this separate and prior cutting makes the whole method more robust and less dependent upon the particular way of integrating the security particles into the final value document or onto a value product.
  • the dried binder with the security particles is integrated in the substrate of the value document or value product.
  • the second method comprises the following steps: a) providing a substrate ; b) providing non-elongated security particles in the form of metal particles or metal coated particles on the substrate ; c) casting or spraying a binder in liquid or loose form on the security particles ; d) drying or heat treating the combination of binder and security particles so that a coherent sheet-like or tape- like product is obtained separable from the substrate.
  • the concentration of security particles and the geometry of the region with security particles is controlled mainly in step b).
  • FIGURE 1 is a drawing of a cast and dried binder mixed with non-elongated security particles; - FIGURE 2a (upper view) and FIGURE 2b (cross- section) show a value document of paper; FIGURE 3a (upper view) and FIGURE 3b (cross- section) show a value document of plastic.
  • FIGURE 1 shows an sheet-like or tape-like product 10 as result of the invention method.
  • the sheet-like or tape-like product 10 comprises a cast and dried solvent with binder 12 mixed with non-elongated security particles 14.
  • the security particles 14 may be e.g. glass particles or powders. As a matter of example, the glass particles have diameter ranging from 0.1 ⁇ m to 30 ⁇ m.
  • the sheet-like or tape-like product 10 is made in the following way : a) an amount of binder such as methyl cellulose is poured in a receptacle filled with a solvent such as water ; b) a predetermined amount of non-elongated particles 14 is poured in the same receptacle ; c) the particles 14 are mixed in the methyl cellulose in order to obtain a distribution which is as homogeneous as possible ; for example, the amount of particles may range from 0.1 g particles per liter solvent - methyl cellulose to 4.5 g particles per liter solvent - methyl cellulose, e.g.
  • the slurry solvent - methyl cellulose 12 - particles 14 is cast on a flat surface, e.g. a metal surface ; e) the cast mixture is leveled to a predetermined thickness, e.g. a thickness varying between 30 ⁇ m and 500 ⁇ m, e.g. between 60 ⁇ m and 300 ⁇ m ; this leveling can be done by means of a leveling lath, e.g. by means of the clearance of a doctor blade ; f) the leveled mixture is dried ; g) the dried mixture may be cut to the desired lengths and widths.
  • a predetermined thickness e.g. a thickness varying between 30 ⁇ m and 500 ⁇ m, e.g. between 60 ⁇ m and 300 ⁇ m ; this leveling can be done by means of a leveling lath, e.g. by means of the clearance of a doctor blade ; f) the leveled mixture is dried ; g) the dried mixture may be cut to the
  • Any control on the concentration itself and on the variation of the concentration of the particles 14 in the methyl cellulose can be done on the sheet-like or tape-like product 10. Any sheet- like or tape-like product not meeting the concentration specifications can be recuperated.
  • the cutting to the desired width may allow avoiding side effects on the concentration, if any.
  • the concentration in the sheet-like or tape-like product may range, for example, from 0.05 g/m 2 to 10.0 g/m 2 , e.g. from 0.1 g/m 2 to 1.0 g/m 2 , e.g. 0.5 g/m 2 .
  • FIGURE 2a is an upper view and FIGURE 2b a cross-section of a value document 20 with a paper substrate 22 and with two small bands 24, 26 comprising non-elongated particles.
  • a value document may be a bank note.
  • the two small bands 24 originate from the sheet-like or tape-like product 10, which has been cut in advance to the desired width.
  • the width can be determined with more accuracy than in the prior art case where the loose particles are being integrated into the paper substrate during the paper manufacturing process.
  • the binder material is methyl cellulose dissolved in a solvent as water, it may dissolve partially or completely during the integration into the paper substrate as a result of the water used during paper manufacturing and the heat produced during paper manufacturing. This 'disappearance', however, has no negative influence on the concentration and the distribution of the particles in the document.
  • FIGURE 3a is an upper view and FIGURE 3b is a cross-section of a value document 30 with a plastic substrate 32 and with a layer 34 comprising particles.
  • a value document may be a credit card or a plastic bank note.
  • the value document 30 may be made by laminating the sheet-like or tape-like product 10 with the non-elongated particles 14 between two plastic foils 32.
  • methyl cellulose dissolved in a solvent as water is used as binder material, it may disappear partially or completely as a result of the heat generated during lamination.

Abstract

La présente invention concerne un produit (10) cohérent de type feuille ou ruban conçu pour être intégré dans des produits ou des documents de valeur. Ledit produit comprend : - des particules de sécurité non allongées (14) sous la forme de particules métalliques ou de particules revêtues de métal ; - un liant (12) compatible avec le papier ou le plastique. Le produit de type feuille ou ruban permet de mieux réguler la concentration des particules de sécurité et d’intégrer facilement les particules de sécurité dans les documents de valeur.
EP20060778438 2005-11-08 2006-09-14 Integration de particules de securite non allongees dans des documents de valeur Withdrawn EP1945857A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP20060778438 EP1945857A1 (fr) 2005-11-08 2006-09-14 Integration de particules de securite non allongees dans des documents de valeur

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP05110473 2005-11-08
PCT/EP2006/066371 WO2007054390A1 (fr) 2005-11-08 2006-09-14 Integration de particules de securite non allongees dans des documents de valeur
EP20060778438 EP1945857A1 (fr) 2005-11-08 2006-09-14 Integration de particules de securite non allongees dans des documents de valeur

Publications (1)

Publication Number Publication Date
EP1945857A1 true EP1945857A1 (fr) 2008-07-23

Family

ID=36114962

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20060778438 Withdrawn EP1945857A1 (fr) 2005-11-08 2006-09-14 Integration de particules de securite non allongees dans des documents de valeur

Country Status (8)

Country Link
US (1) US20080280122A1 (fr)
EP (1) EP1945857A1 (fr)
JP (1) JP2009515063A (fr)
CN (1) CN101316963A (fr)
BR (1) BRPI0618363A2 (fr)
CA (1) CA2627949A1 (fr)
RU (1) RU2008122892A (fr)
WO (1) WO2007054390A1 (fr)

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3804092A (en) * 1973-01-15 1974-04-16 Johnson & Johnson Water dispersible nonwoven fabric
FR2425937A1 (fr) * 1978-05-17 1979-12-14 Arjomari Prioux Structure fibreuse contenant des fibres metalliques, son procede de preparation, et son application notamment dans l'industrie du papier
US4408156A (en) * 1979-05-01 1983-10-04 N. V. Bekaert S.A. Sheet articles of non-conductive material marked for identification purposes, and method and apparatus for identifying such articles
NL193609C (nl) * 1981-12-30 2000-04-04 Bekaert Sa Nv Samengestelde streng voor verwerking als granulaat in kunststofproducten en werkwijze voor het vervaardigen van een kunststofmenggranulaat.
US4775580A (en) * 1986-03-08 1988-10-04 The Dow Chemical Company Porous random fiber composites and a method for preparing same
DE3938055A1 (de) * 1989-11-16 1991-05-23 Merck Patent Gmbh Mit plaettchenfoermigen pigmenten beschichtete materialien
US5601931A (en) * 1993-12-02 1997-02-11 Nhk Spring Company, Ltd. Object to be checked for authenticity and a method for manufacturing the same
US5824413A (en) * 1996-07-15 1998-10-20 Ppg Industries, Inc. Secondary coating for fiber strands, coated strand reinforcements, reinforced polymeric composites and a method of reinforcing a polymeric material
SE0100552D0 (sv) * 2001-02-19 2001-02-19 Luciano Beghello Non-metallic security elements for authentification purposes
US6896828B2 (en) * 2001-11-13 2005-05-24 Dow Global Technologies Inc. Electrically conductive thermoplastic polymer composition
US20080107898A1 (en) * 2004-04-29 2008-05-08 Nv Bekaert Sa Integrating Security Particles in Value Documents or Value Products
US20050282001A1 (en) * 2004-06-17 2005-12-22 Jenkines Randall C Polyurethane compositions with glass filler and method of making same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2007054390A1 *

Also Published As

Publication number Publication date
CA2627949A1 (fr) 2007-05-18
US20080280122A1 (en) 2008-11-13
RU2008122892A (ru) 2009-12-20
CN101316963A (zh) 2008-12-03
BRPI0618363A2 (pt) 2011-08-30
WO2007054390A1 (fr) 2007-05-18
JP2009515063A (ja) 2009-04-09

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