EP1939895B1 - Composition for an energy and/or a telecommunication cable based on biopolymer - Google Patents
Composition for an energy and/or a telecommunication cable based on biopolymer Download PDFInfo
- Publication number
- EP1939895B1 EP1939895B1 EP07150419A EP07150419A EP1939895B1 EP 1939895 B1 EP1939895 B1 EP 1939895B1 EP 07150419 A EP07150419 A EP 07150419A EP 07150419 A EP07150419 A EP 07150419A EP 1939895 B1 EP1939895 B1 EP 1939895B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- power
- polyester
- telecommunications cable
- cable according
- polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 229920001222 biopolymer Polymers 0.000 title claims abstract description 14
- 229920000728 polyester Polymers 0.000 claims abstract description 23
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 20
- 229920002472 Starch Polymers 0.000 claims abstract description 19
- 239000008107 starch Substances 0.000 claims abstract description 19
- 235000019698 starch Nutrition 0.000 claims abstract description 19
- 229920002678 cellulose Polymers 0.000 claims abstract description 13
- 239000004626 polylactic acid Substances 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 claims abstract description 7
- 229920000903 polyhydroxyalkanoate Polymers 0.000 claims abstract description 7
- 229920000229 biodegradable polyester Polymers 0.000 claims abstract description 5
- 239000004622 biodegradable polyester Substances 0.000 claims abstract description 5
- 229920000642 polymer Polymers 0.000 claims description 25
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 11
- 239000000945 filler Substances 0.000 claims description 11
- 239000003063 flame retardant Substances 0.000 claims description 11
- 229920001059 synthetic polymer Polymers 0.000 claims description 10
- 239000000347 magnesium hydroxide Substances 0.000 claims description 9
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 8
- -1 polyethylene Polymers 0.000 claims description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 7
- 239000001095 magnesium carbonate Substances 0.000 claims description 7
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 7
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000007799 cork Substances 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 2
- OUHCLAKJJGMPSW-UHFFFAOYSA-L magnesium;hydrogen carbonate;hydroxide Chemical compound O.[Mg+2].[O-]C([O-])=O OUHCLAKJJGMPSW-UHFFFAOYSA-L 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims 1
- 238000005253 cladding Methods 0.000 claims 1
- 229910001679 gibbsite Inorganic materials 0.000 claims 1
- 239000001913 cellulose Substances 0.000 description 10
- 239000005038 ethylene vinyl acetate Substances 0.000 description 8
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 8
- 239000000470 constituent Substances 0.000 description 6
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 6
- 238000009413 insulation Methods 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 3
- 229920000331 Polyhydroxybutyrate Polymers 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- GGMMWVHTLAENAS-UHFFFAOYSA-M (1,1-diethylpyrrolidin-1-ium-3-yl) 2-hydroxy-2,2-diphenylacetate;bromide Chemical compound [Br-].C1[N+](CC)(CC)CCC1OC(=O)C(O)(C=1C=CC=CC=1)C1=CC=CC=C1 GGMMWVHTLAENAS-UHFFFAOYSA-M 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229920001074 Tenite Polymers 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 229920001727 cellulose butyrate Polymers 0.000 description 2
- 229920003174 cellulose-based polymer Polymers 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- CWEFIMQKSZFZNY-UHFFFAOYSA-N pentyl 2-[4-[[4-[4-[[4-[[4-(pentoxycarbonylamino)phenyl]methyl]phenyl]carbamoyloxy]butoxycarbonylamino]phenyl]methyl]phenyl]acetate Chemical compound C1=CC(CC(=O)OCCCCC)=CC=C1CC(C=C1)=CC=C1NC(=O)OCCCCOC(=O)NC(C=C1)=CC=C1CC1=CC=C(NC(=O)OCCCCC)C=C1 CWEFIMQKSZFZNY-UHFFFAOYSA-N 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- UGZICOVULPINFH-UHFFFAOYSA-N acetic acid;butanoic acid Chemical compound CC(O)=O.CCCC(O)=O UGZICOVULPINFH-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 229920002988 biodegradable polymer Polymers 0.000 description 1
- 239000004621 biodegradable polymer Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000070 poly-3-hydroxybutyrate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920003179 starch-based polymer Polymers 0.000 description 1
- 239000004628 starch-based polymer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/185—Substances or derivates of cellulose
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/42—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes polyesters; polyethers; polyacetals
- H01B3/421—Polyesters
- H01B3/422—Linear saturated polyesters derived from dicarboxylic acids and dihydroxy compounds
Definitions
- the present invention relates to energy and / or telecommunication cables comprising at least one constituent element made of an extruded material derived from an extrudable composition.
- Energy and / or telecommunication cables generally comprise coatings or insulating sheaths of synthetic polymers such as polyethylene, polyethylene vinyl acetate or polyvinyl chloride.
- the document JP2004-311063 presents an energy cable comprising an extruded layer of a biodegradable polymer, in particular a polylactic resin.
- EP-A-0 714 914 discloses a biodegradable insulating coating of water-swellable starch ester for an electric cable.
- the technical problem to be solved, by the object of the present invention is to propose an energy and / or telecommunication cable comprising at least one constituent element made of an extruded material resulting from an extrudable composition making it possible to avoid the problems of the state of the art by offering in particular alternative compositions to those of the prior art.
- the Applicant has carried out intensive tests to find compositions making it possible to limit the significant use of polymers. synthetic while maintaining mechanical properties, insulation and fire resistance identical to or even superior to the properties of the cable sheaths of the prior art.
- extrudable composition comprises a biopolymer of the starch polymer type complexed with a biodegradable polyester.
- the extrudable composition may further comprise other biopolymers selected from cellulose ester polymers, polyhydroxyalkanoate polymers and / or polylactic acid polymers comprising an acid mixture.
- biopolymers selected from cellulose ester polymers, polyhydroxyalkanoate polymers and / or polylactic acid polymers comprising an acid mixture.
- polylactic and polyester may further comprise other biopolymers selected from cellulose ester polymers, polyhydroxyalkanoate polymers and / or polylactic acid polymers comprising an acid mixture.
- polylactic and polyester may benzophenylene glycol glycol glycol glycol, poly(2-aminoxyl)
- other biopolymers selected from cellulose ester polymers, polyhydroxyalkanoate polymers and / or polylactic acid polymers comprising an acid mixture.
- polylactic and polyester may further comprise other biopolymers selected from cellulose ester polymers, polyhydroxyalkanoate polymers and / or polylactic acid polymers comprising an acid mixture.
- biopolymer means that the carbons of said polymer come from renewable biological sources.
- the biopolymer can come from a direct extraction from biomass, a regeneration of the biomass by fermentation or hydrolysis, or by microbial transformation of biomonomers.
- biopolymers are biodegradable, that is, they break down by the enzymatic action of microorganisms into carbon dioxide, methane, water and inorganic compounds.
- Starch polymers are thermoplastic polymers derived from the chemical, thermal and / or mechanical treatment of starch.
- Starch is found in many plants such as maize, wheat, legumes, roots, tubers and rhizomes such as potatoes or cassava.
- Cellulose or cellulose-based polymers are generally produced by the chemical modification of natural cellulose.
- Cotton and wood are the materials behind the industrial production of cellulose.
- Polyhydroxyalkanoate or polyhydroxyalkanoate polymers are naturally produced by bacterial fermentation of sugars or lipids and may have thermoplastic or elastomeric properties.
- the polylactic acid or polylactic acid polymers are aliphatic polyesters produced from corn starch.
- said extrudable composition further comprises a synthetic polymer, preferably selected from polyethylene, polypropylene, ethyl vinyl acetate copolymer, polyvinyl chloride and polyester, or their mixture.
- a synthetic polymer preferably selected from polyethylene, polypropylene, ethyl vinyl acetate copolymer, polyvinyl chloride and polyester, or their mixture.
- each constituent element of said cable is selected from an insulating coating, a protective sheath and a filler.
- a cable is schematically constituted by at least one electrical or optical conducting element extending inside at least one insulating element. .
- At least one of the insulating elements may also act as protection means and / or that the cable may also have at least one specific protective element forming a sheath, in particular for electrical cables.
- the cable may comprise a filling material which is essentially intended to maintain said insulated conductors and which is commonly called stuffing.
- the cellulose ester polymers are chosen from cellulose butyrate polymer, cellulose acetate polymer and cellulose propionate polymer.
- the polyhydroxyalkanoate polymer is a homopolymer or a copolymer of poly (3-hydroxybutyrate).
- the polylactic acid polymers comprise at least about 10% by weight of polylactic acid, preferably at least about 40% by weight of polylactic acid, and more preferably at most about 90% by weight of polylactic acid. polylactic acid.
- the polylactic acid polymers may comprise at least 40% by weight of polyester.
- polylactic acid polymers comprising about 40% by weight of polylactic acid and about 60% by weight of polyester, or comprising about 10% by weight of polylactic acid and about 90% by weight of polylactic acid. polyester weight.
- the extrudable composition further comprises a flame retardant filler.
- the flame-retardant filler is chosen from aluminum trihydroxide Al (OH) 3 , magnesium dihydroxide Mg (OH) 2 , a mixture of hydrated magnesium carbonate and calcium and magnesium carbonate, zinc borate, and / or cork powder.
- Table 1 details various samples according to the invention and according to the prior art, whose mechanical properties and fire resistance are studied.
- compositions referenced 2, 2bis and 3 correspond to a composition according to the present invention comprising a biopolymer combined or not with a synthetic polymer.
- compositions referenced 6 and 7 are those relating to the prior art.
- Table 1 the amounts mentioned in Table 1 are expressed in parts by weight (phr) per 100 parts of polymer.
- Table 1 ⁇ / u> Composition constituents 1 (not according to the invention) 100 pcr Cellulose 2 (according to the invention) 100 pcr Starch N F03A 2 bis (according to the invention) 100 pcr Starch NF08 3 (according to the invention) 25 pcr Starch NF03A, and 75 pb PE 4 (not according to the invention) 100 pb PHB 5 (not according to the invention) 100 pcr PLA-polyester 467F 5 bis (not according to the invention) 100 pcr PLA-polyester 219F 6 (according to the prior art) 100 pcr EVA 7 (according to the prior art) 100 pb PE
- the plates After cooling and demolding, the plates are cut to make the samples on which mechanical tests are performed.
- Table 2 summarizes the results of a number of measurements from samples 1 to 7 to evaluate their tensile strength and elongation at break. ⁇ u> Table 2 ⁇ / u> Sample Tensile strength (MPa) Elongation at break (%) 1 33 26 2 11 500 2 bis 15 240 3 14 640 4 17 9 5 26 410 5 bis 13 430 6 29 767 7 16 630
- Cone-calorimeter analyzes are also performed to evaluate and compare the fire behavior of the different samples.
- This type of analysis consisting of burning samples in the ambient air while subjecting them to an external energy radiation of less than 100 kW / m 2 power and imposed by a radiant heating controlled in temperature, makes it possible to obtain the released heat expressed in MJ / m 2 and the peak of heat output expressed in kW / m 2 .
- each sample is shaped into square plates 10 cm square and 3 mm thick.
- Table 3 collects the data collected by the cone-calorimeter analyzes with the samples from Table 2. ⁇ u> Table 3 ⁇ / u> Sample Heat release rate (MJ / kg) Peak of heat released (kW / m 2 ) 1 23 910 2 21 1030 2 bis 19 756 4 23 755 5 22 860 5 bis 23 228 6 37 1360 7 43 1310
- Sample 8 is a composition comprising a biopolymer (Cellulose), a synthetic polymer (EVA) and magnesium hydroxide.
- Samples 9 to 11 respectively correspond to samples 2, 6 and 7 added with a flame retardant filler.
- Samples 12 to 14 correspond to sample 2, supplemented with a flame retardant filler.
- Samples 15 to 17 correspond to the sample 5 bis supplemented with a flame retardant filler.
- Sample 18 corresponds to sample 2 bis added with a flame retardant filler.
- the samples in accordance with the invention have better flame-retarding properties since the heat content released from samples 9, 12-14 and 18 according to the invention are much lower than those of samples 10 and 11. for lower or equivalent peak heat values.
- the sample 12 thus obtained makes it possible to obtain a tensile strength of 19 MPa and an elongation at break of 70%.
- the mixture of these two biopolymers advantageously has well-balanced mechanical properties, whose tensile strength is greater than that of the sample 2 and the elongation at break is greater than that of the sample 1.
- compositions according to the present invention for a cable application, the inventive composition 2 as well as the compositions 1, 5 and 5 bis of Table 1 are extruded on a metal conductor of 1.03 mm diameter in one layer of about 0.50 mm, to obtain the respective electrical son 1, 2, 5 and 5 bis.
- the extrusion profile for the composition 1 extends from 145 ° C. to 200 ° C. under a pressure of 15 MPa (150 Bar), that of the composition 2 extends from 100 ° C to 135 ° C under a pressure of 13.5 MPa (135 Bar), and that of the compositions 5 and 5 bis extends from 120 to 150 ° C under a pressure of 19 MPa (190 bar), these profiles extrusion being well known to those skilled in the art.
- the insulation test according to IEC 60502-1 consists in immersing the electric wires in water for at least one hour before said test.
- a DC voltage between 80V and 500V is then applied for a sufficient time (between 1 and 5 min) then the resistance of the ring is measured. This is used to determine the insulation constant.
- Ki values are advantageously greater than those recommended for certain materials, especially for polyvinyl chloride.
- the extrusion of said composition makes it possible to achieve significant layer thicknesses of the order of at least 0.3-0.5 mm, unlike film-forming coatings, and thus makes it possible to obtain optimized insulating properties.
- compositions in question are used in the production of extruded insulating and / or sheathing and / or stuffing materials for energy and / or telecommunication cables.
- composition may furthermore comprise other additives, especially antioxidants, UV stabilizing agents, plasticizing agents, pigmentation agents or coloring agents.
- the plasticizing agents may be added to the composition according to the present invention in order to improve the elongation at break of said composition.
- plasticizer of castor oil, crodamide or triethyl citrate.
- the present invention is not limited to the examples of compositions which have just been described and generally relates to all the cables that can be envisaged from the general indications given in the description of the invention.
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- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
Description
La présente invention se rapporte à des câbles d'énergie et/ou de télécommunication comportant au moins un élément constitutif réalisé en un matériau extrudé issu d'une composition extrudable.The present invention relates to energy and / or telecommunication cables comprising at least one constituent element made of an extruded material derived from an extrudable composition.
Les ressources naturelles minérales telles que le pétrole ou le gaz sont à l'origine de la synthèse de nombreux polymères synthétiques tels que les polyoléfines, et se font de plus en plus rares.Mineral natural resources such as oil or gas are at the origin of the synthesis of many synthetic polymers such as polyolefins, and are becoming increasingly rare.
Il est crucial de limiter l'utilisation de ces ressources naturelles afin de préserver leur existence mais aussi de s'affranchir d'une hausse des prix trop importante.It is crucial to limit the use of these natural resources in order to preserve their existence but also to avoid excessive price increases.
Les câbles d'énergie et/ou de télécommunication comprennent généralement des revêtements ou des gaines isolantes en polymères synthétiques tels qu'en polyéthylène, en polyéthylène vinyle acétate ou en polychlorure de vinyle.Energy and / or telecommunication cables generally comprise coatings or insulating sheaths of synthetic polymers such as polyethylene, polyethylene vinyl acetate or polyvinyl chloride.
Le document
Toutefois, il est important de pouvoir diversifier le nombre de compositions polymères extrudables limitant l'utilisation de polymère synthétique, voire n'en comprenant pas du tout, et présentant des caractéristiques thermomécaniques au moins semblables aux compositions existantes sur le marché pour l'application câble.However, it is important to be able to diversify the number of extrudable polymer compositions limiting the use of synthetic polymer, or even not including it at all, and having thermomechanical characteristics at least similar to the existing compositions on the market for the cable application. .
Aussi le problème technique à résoudre, par l'objet de la présente invention, est de proposer un câble d'énergie et/ou de télécommunication comportant au moins un élément constitutif réalisé en un matériau extrudé issu d'une composition extrudable permettant d'éviter les problèmes de l'état de la technique en offrant notamment des compositions alternatives à celles de l'art antérieur.Therefore, the technical problem to be solved, by the object of the present invention, is to propose an energy and / or telecommunication cable comprising at least one constituent element made of an extruded material resulting from an extrudable composition making it possible to avoid the problems of the state of the art by offering in particular alternative compositions to those of the prior art.
Ainsi, la demanderesse a effectué des essais intensifs pour trouver des compositions permettant de limiter l'utilisation significative de polymères synthétiques tout en gardant des propriétés mécaniques, isolantes et de résistances au feu identiques, voire supérieures aux propriétés des gaines de câbles de l'art antérieur.Thus, the Applicant has carried out intensive tests to find compositions making it possible to limit the significant use of polymers. synthetic while maintaining mechanical properties, insulation and fire resistance identical to or even superior to the properties of the cable sheaths of the prior art.
La solution du problème technique posé réside, selon la présente invention, en ce que ladite composition extrudable comprend un biopolymère du type polymère d'amidon complexé avec un polyester biodégradable.The solution of the technical problem lies, according to the present invention, in that said extrudable composition comprises a biopolymer of the starch polymer type complexed with a biodegradable polyester.
Selon un mode de réalisation de l'invention, la composition extrudable peut comprendre en outre d'autres biopolymères choisis parmi les polymères d'ester de cellulose, les polymères de polyhydroxyalkanoate et/ou les polymères d'acide polylactique comprenant un mélange d'acide polylactique et de polyester.According to one embodiment of the invention, the extrudable composition may further comprise other biopolymers selected from cellulose ester polymers, polyhydroxyalkanoate polymers and / or polylactic acid polymers comprising an acid mixture. polylactic and polyester.
Le terme « biopolymère » signifie que les carbones dudit polymère proviennent de sources biologiques renouvelables.The term "biopolymer" means that the carbons of said polymer come from renewable biological sources.
A titre d'exemples, le biopolymère peut provenir d'une extraction directe à partir de la biomasse, d'une régénération de la biomasse par fermentation ou hydrolyse, ou encore par transformation microbienne de biomonomères.By way of examples, the biopolymer can come from a direct extraction from biomass, a regeneration of the biomass by fermentation or hydrolysis, or by microbial transformation of biomonomers.
La plupart des biopolymères sont biodégradables, c'est-à-dire qu'ils se décomposent par l'action enzymatique de microorganismes en dioxyde de carbone, méthane, eau et en composés inorganiques.Most biopolymers are biodegradable, that is, they break down by the enzymatic action of microorganisms into carbon dioxide, methane, water and inorganic compounds.
Les polymères d'amidon, ou à base d'amidon, sont des polymères thermoplastiques provenant du traitement chimique, thermique et/ou mécanique de l'amidon.Starch polymers, or starch-based polymers, are thermoplastic polymers derived from the chemical, thermal and / or mechanical treatment of starch.
On trouve l'amidon dans de nombreux végétaux tels que le maïs, le froment, les légumineuses, les racines, tubercules et rhizomes comme la pomme de terre ou le manioc.Starch is found in many plants such as maize, wheat, legumes, roots, tubers and rhizomes such as potatoes or cassava.
Les polymères de cellulose, ou à base de cellulose, sont produits généralement par la modification chimique de la cellulose naturelle.Cellulose or cellulose-based polymers are generally produced by the chemical modification of natural cellulose.
Le coton et le bois sont des matériaux à l'origine de la production industrielle de cellulose.Cotton and wood are the materials behind the industrial production of cellulose.
Les polymères de polyhydroxyalkanoate, ou à base de polyhydroxyalkanoate, sont produits naturellement par fermentation bactérienne de sucres ou de lipides et peuvent avoir des propriétés thermoplastiques ou élastomériques.Polyhydroxyalkanoate or polyhydroxyalkanoate polymers are naturally produced by bacterial fermentation of sugars or lipids and may have thermoplastic or elastomeric properties.
La formule générale I des polyhydroxyalkanoates est la suivante :
- R peut être un hydrogène ou une chaîne hydrocarbonée en C1-C16, et
- X est un entier supérieur ou égale à 1.
- R can be a hydrogen or a C 1 -C 16 hydrocarbon chain, and
- X is an integer greater than or equal to 1.
Les polymères d'acide polylactique, ou à base d'acide polylactique, sont des polyesters aliphatiques produits à partir d'amidon de maïs.The polylactic acid or polylactic acid polymers are aliphatic polyesters produced from corn starch.
Dans une réalisation particulière, ladite composition extrudable comprend en outre un polymère synthétique, de préférence choisi parmi le polyéthylène, le polypropylène, le copolymère d'éthyle vinyle acétate, le polychlorure de vinyle et le polyester, ou leur mélange.In a particular embodiment, said extrudable composition further comprises a synthetic polymer, preferably selected from polyethylene, polypropylene, ethyl vinyl acetate copolymer, polyvinyl chloride and polyester, or their mixture.
Selon une caractéristique de la présente invention, chaque élément constitutif dudit câble est choisi parmi un revêtement isolant, une gaine de protection et une matière de remplissage.According to a feature of the present invention, each constituent element of said cable is selected from an insulating coating, a protective sheath and a filler.
Qu'il soit électrique ou optique, destiné au transport d'énergie ou à la transmission de données, un câble est schématiquement constitué d'au moins un élément conducteur électrique ou optique s'étendant à l'intérieur d'au moins un élément isolant.Whether electrical or optical, intended for energy transmission or data transmission, a cable is schematically constituted by at least one electrical or optical conducting element extending inside at least one insulating element. .
Il est à noter qu'au moins un des éléments isolants peut également jouer le rôle de moyen de protection et/ou que le câble peut disposer en outre d'au moins un élément de protection spécifique formant une gaine, notamment pour les câbles électriques.It should be noted that at least one of the insulating elements may also act as protection means and / or that the cable may also have at least one specific protective element forming a sheath, in particular for electrical cables.
Par ailleurs, dans le cas où il intègre plusieurs conducteurs électriques isolés, le câble peut comporter une matière de remplissage qui est essentiellement destinée à maintenir lesdits conducteurs isolés et qui est communément appelée bourrage.On the other hand, in the case where it incorporates several insulated electrical conductors, the cable may comprise a filling material which is essentially intended to maintain said insulated conductors and which is commonly called stuffing.
Selon une composition préférée, les polymères d'ester de cellulose sont choisis parmi le polymère de butyrate de cellulose, le polymère d'acétate de cellulose et le polymère de propionate de cellulose.According to a preferred composition, the cellulose ester polymers are chosen from cellulose butyrate polymer, cellulose acetate polymer and cellulose propionate polymer.
Selon une autre composition préférée, le polymère de polyhydroxyalkanoate est un homopolymère ou un copolymère de poly(3-hydroxybutyrate).According to another preferred composition, the polyhydroxyalkanoate polymer is a homopolymer or a copolymer of poly (3-hydroxybutyrate).
Selon une autre composition préférée, les polymères d'acide polylactique comprennent au moins environ 10 % en poids d'acide polylactique, de préférence au moins environ 40 % en poids d'acide polylactique, et plus préférentiellement au plus environ 90 % en poids d'acide polylactique.According to another preferred composition, the polylactic acid polymers comprise at least about 10% by weight of polylactic acid, preferably at least about 40% by weight of polylactic acid, and more preferably at most about 90% by weight of polylactic acid. polylactic acid.
Avantageusement, les polymères d'acide polylactique peuvent comprendre au moins 40 % en poids de polyester.Advantageously, the polylactic acid polymers may comprise at least 40% by weight of polyester.
A titre d'exemple, on peut citer les polymères d'acide polylactique comprenant environ 40 % en poids d'acide polylactique et environ 60 % en poids de polyester, ou comprenant environ 10 % en poids d'acide polylactique et environ 90 % en poids de polyester.By way of example, mention may be made of polylactic acid polymers comprising about 40% by weight of polylactic acid and about 60% by weight of polyester, or comprising about 10% by weight of polylactic acid and about 90% by weight of polylactic acid. polyester weight.
Dans un mode de réalisation particulier, la composition extrudable comprend en outre une charge ignifugeante.In a particular embodiment, the extrudable composition further comprises a flame retardant filler.
De préférence, la charge ignifugeante est choisie parmi le trihydroxyde d'aluminium AI(OH)3, le dihydroxyde de magnésium Mg(OH)2, un mélange de carbonate de magnésium hydraté et carbonate de calcium et de magnésium, le borate de zinc, et/ou de la poudre de liège.Preferably, the flame-retardant filler is chosen from aluminum trihydroxide Al (OH) 3 , magnesium dihydroxide Mg (OH) 2 , a mixture of hydrated magnesium carbonate and calcium and magnesium carbonate, zinc borate, and / or cork powder.
D'autres caractéristiques et avantages de la présente invention apparaîtront à la lumière des exemples qui vont suivre, lesdits exemples étant donnés à titre illustratif et nullement limitatif.Other features and advantages of the present invention will emerge in the light of the examples which follow, said examples being given by way of illustration and in no way limiting.
Afin de montrer les avantages obtenus avec les compositions extrudables selon la présente invention, le Tableau 1 détaille différents échantillons selon l'invention et selon l'art antérieur, dont les propriétés mécaniques et de résistances au feu sont étudiées.In order to show the advantages obtained with the extrudable compositions according to the present invention, Table 1 details various samples according to the invention and according to the prior art, whose mechanical properties and fire resistance are studied.
Les compositions référencées de 2, 2bis et 3 correspondent à une composition selon la présente invention comprenant un biopolymère combiné ou non avec un polymère synthétique.The compositions referenced 2, 2bis and 3 correspond to a composition according to the present invention comprising a biopolymer combined or not with a synthetic polymer.
Les compositions référencées de 6 et 7 sont celles relatives à l'art antérieur.The compositions referenced 6 and 7 are those relating to the prior art.
Il est noté que les quantités mentionnées dans le Tableau 1 sont exprimées en parties en poids (pcr) pour 100 parties de polymère.
L'origine des différents constituants du Tableau 1 est la suivante :
- « Cellulose » correspond au polymère d'acétate de butyrate de cellulose, référencé Tenite 485E2R30010 et commercialisé par la société Eastman.
- « Amidon NF03A» correspond au polymère d'amidon complexé avec un polyester biodégradable, référencé Mater-bi NF03A et commercialisé par la société Novamont.
- « Amidon NF08 » correspond au polymère d'amidon complexé avec un polyester biodégradable, référencé Mater-bi NF08 et commercialisé par la société Novamont.
- « PHB » correspond au polymère de polyhydroxyde butyrate, référencé P209 et commercialisé par la société Biomer.
- « PLA-polyester 467F» correspond au polymère d'acide polylactique, référencé 467F, comprenant environ 40 % en poids d'acide polylactique et environ 60 % en poids de polyester, et commercialisé par la société FKUR.
- « PLA-polyester 219F » correspond au polymère d'acide polylactique, référencé 219F, comprenant environ 10 % d'acide polylactique et environ 90 % de polyester, et commercialisé par la société FKUR.
- « EVA » correspond au copolymère d'éthylène vinyle acétate (polymère synthétique), référencé EVATANE 2803 et commercialisé par la société ARKEMA.
- « PE » correspond au polyéthylène (polymère synthétique), référencé LL4004 et commercialisé par la société Exxon.
- "Cellulose" corresponds to the polymer of cellulose butyrate acetate, referenced Tenite 485E2R30010 and marketed by Eastman.
- "Starch NF03A" corresponds to the starch polymer complexed with a biodegradable polyester, referenced Mater-bi NF03A and marketed by Novamont.
- "Starch NF08" corresponds to the starch polymer complexed with a biodegradable polyester, referenced Mater-bi NF08 and marketed by Novamont.
- "PHB" corresponds to the polyhydroxide butyrate polymer, referenced P209 and sold by the company Biomer.
- "PLA-polyester 467F" corresponds to the polylactic acid polymer, referenced 467F, comprising approximately 40% by weight of polylactic acid and about 60% by weight of polyester, and marketed by FKUR.
- "PLA-polyester 219F" corresponds to the polylactic acid polymer, referenced 219F, comprising about 10% of polylactic acid and about 90% of polyester, and marketed by FKUR.
- "EVA" corresponds to the copolymer of ethylene vinyl acetate (synthetic polymer), referenced EVATANE 2803 and sold by the company Arkema.
- "PE" corresponds to polyethylene (synthetic polymer), referenced LL4004 and marketed by Exxon.
Pour étudier les propriétés mécaniques, des échantillons 1 à 7 correspondant respectivement aux compositions 1 à 7, ont été préparés selon le protocole suivant :
- mettre en oeuvre le ou les polymères dans un mélangeur interne, et
- mouler la composition en formant des plaques dans une presse chauffante, sous une pression de 10 MPa (100 bars) pendant 5 minutes.
- to use the polymer (s) in an internal mixer, and
- molding the composition by forming plates in a heating press at a pressure of 10 MPa (100 bar) for 5 minutes.
Après refroidissement et démoulage, les plaques sont coupées pour réaliser les échantillons sur lesquels des tests mécaniques sont effectués.After cooling and demolding, the plates are cut to make the samples on which mechanical tests are performed.
Le Tableau 2 rassemble les résultats d'un certain nombre de mesures relevées sur les échantillons 1 à 7 afin d'évaluer leur résistance à la traction et leur allongement à la rupture.
Des analyses par cône-calorimétre sont également réalisées afin d'évaluer et de comparer le comportement au feu des différents échantillons.Cone-calorimeter analyzes are also performed to evaluate and compare the fire behavior of the different samples.
Ce type d'analyse, consistant à brûler des échantillons à l'air ambiant tout en les soumettant à un rayonnement énergétique externe de puissance inférieure à 100 kW/m2 et imposé par un chauffage radiant contrôlé en température, permet d'obtenir le taux de chaleur dégagée exprimé en MJ/m2 et le pic de chaleur dégagée exprimé en kW/m2.This type of analysis, consisting of burning samples in the ambient air while subjecting them to an external energy radiation of less than 100 kW / m 2 power and imposed by a radiant heating controlled in temperature, makes it possible to obtain the released heat expressed in MJ / m 2 and the peak of heat output expressed in kW / m 2 .
Pour ce faire, chaque échantillon est façonné en plaques carrées de 10 cm de côté et de 3 mm d'épaisseur.To do this, each sample is shaped into square plates 10 cm square and 3 mm thick.
Les échantillons ainsi conformés sont testés au moyen d'un calorimètre à cône conformément à la norme ISO 5660-1 relative aux débits calorifiques des produits du bâtiment.The samples thus conformed are tested using a cone calorimeter in accordance with the ISO 5660-1 standard for the heat flows of building products.
Plus le pic de chaleur dégagée et le taux de chaleur dégagée sont faibles numériquement, meilleures sont les propriétés ignifugeantes de la composition.The higher the peak of heat released and the rate of heat released are numerically lower, the better the flame retardant properties of the composition.
Le Tableau 3 rassemble les données collectées par les analyses en cône-calorimètre avec les échantillons du Tableau 2.
Au regard des résultats des Tableaux 2 et 3, il apparaît clairement que les échantillons à base de biopolymères selon la présente invention présentent des propriétés mécaniques ainsi que des propriétés de résistance au feu identiques, voire meilleures, que les polymères de l'art antérieur PE et EVA.With regard to the results of Tables 2 and 3, it is clear that the biopolymer-based samples according to the present invention have identical or even better mechanical properties and fire resistance properties than the polymers of the prior art. and EVA.
Pour améliorer les propriétés de résistance au feu, de nouveaux échantillons comprenant une charge ignifugeante sont détaillés dans le Tableau 4.To improve the fire resistance properties, new samples comprising a flame retardant filler are detailed in Table 4.
L'échantillon 8 est une composition comprenant un biopolymère (Cellulose), un polymère synthétique (EVA) et de l'hydroxyde de magnésium.Sample 8 is a composition comprising a biopolymer (Cellulose), a synthetic polymer (EVA) and magnesium hydroxide.
Les échantillons 9 à 11 correspondent respectivement aux échantillons 2, 6 et 7 additionnés d'une charge ignifugeante.Samples 9 to 11 respectively correspond to samples 2, 6 and 7 added with a flame retardant filler.
Les échantillons 12 à 14 correspondent à l'échantillon 2 additionné d'une charge ignifugeante.Samples 12 to 14 correspond to sample 2, supplemented with a flame retardant filler.
Les échantillons 15 à 17 correspondent à l'échantillon 5 bis additionné d'une charge ignifugeante.Samples 15 to 17 correspond to the sample 5 bis supplemented with a flame retardant filler.
L'échantillon 18 correspond à l'échantillon 2 bis additionné d'une charge ignifugeante.Sample 18 corresponds to sample 2 bis added with a flame retardant filler.
A cet égard, il est noté que les quantités mentionnées dans le Tableau 4 sont exprimées en parties en poids (pcr) pour 100 parties de polymère.
L'origine des charges ignifugeantes utilisées dans les échantillons 8 à 18 est la suivante :
- l'hydroxyde de magnésium et l'hydroxyde d'aluminium sont commercialisés par la société Martinswerk respectivement sous la référence Magnifin H10 et OL104 ; et
- le mélange de carbonate de magnésium hydraté et carbonate de calcium et de magnésium est commercialisé par la société Minelco sous la référence Ultracarb U5.
- magnesium hydroxide and aluminum hydroxide are marketed by Martinswerk respectively under the reference Magnifin H10 and OL104; and
- the mixture of hydrated magnesium carbonate and calcium and magnesium carbonate is marketed by Minelco under the reference Ultracarb U5.
Au regard des résultats du Tableau 4, les échantillons conformes à l'invention présentent de meilleures propriétés ignifugeantes puisque le taux de chaleur dégagée des échantillons 9, 12-14 et 18 conforme à l'invention sont bien inférieurs à ceux des échantillons 10 et 11 pour des valeurs de pic de chaleur dégagée inférieures ou équivalentes.With regard to the results in Table 4, the samples in accordance with the invention have better flame-retarding properties since the heat content released from samples 9, 12-14 and 18 according to the invention are much lower than those of samples 10 and 11. for lower or equivalent peak heat values.
Afin de montrer les avantages obtenus selon une autre réalisation particulière de la présente invention et à titre d'exemple, deux biopolymères différents, à savoir 75 pcr d'Amidon et 25 pcr de Cellulose, sont mélangés et moulés sous presse dans les mêmes conditions qu'énoncées précédemment.In order to show the advantages obtained according to another particular embodiment of the present invention and by way of example, two different biopolymers, namely 75 phr of Starch and 25 phr of Cellulose, are mixed and molded in press under the same conditions as previously stated.
L'échantillon 12 ainsi obtenu permet d'obtenir une résistance à la traction de 19 MPa et un allongement à la rupture de 70 %.The sample 12 thus obtained makes it possible to obtain a tensile strength of 19 MPa and an elongation at break of 70%.
Ainsi, le mélange de ces deux biopolymères présente avantageusement des propriétés mécaniques bien équilibrées, dont la résistance à la traction est supérieure à celle de l'échantillon 2 et l'allongement à la rupture est supérieur à celui de l'échantillon 1.Thus, the mixture of these two biopolymers advantageously has well-balanced mechanical properties, whose tensile strength is greater than that of the sample 2 and the elongation at break is greater than that of the sample 1.
Enfin, pour valider l'utilisation des compositions selon la présente invention pour une application câble, la composition inventive 2 ainsi que les compositions 1, 5 et 5 bis du Tableau 1 sont extrudées sur un conducteur métallique de 1,03 mm de diamètre en une couche d'environ 0,50 mm, afin d'obtenir les fils électriques respectifs 1, 2, 5 et 5 bis.Finally, to validate the use of the compositions according to the present invention for a cable application, the inventive composition 2 as well as the compositions 1, 5 and 5 bis of Table 1 are extruded on a metal conductor of 1.03 mm diameter in one layer of about 0.50 mm, to obtain the respective electrical son 1, 2, 5 and 5 bis.
Le profil d'extrusion pour la composition 1 s'étend de 145°C à 200°C sous une pression de 15 MPa (150 Bar), celui de la composition 2 s'étend de 100°C à 135°C sous une pression de 13,5 MPa (135 Bar), et celui des compositions 5 et 5 bis s'étend de 120 à 150°C sous une pression de 19 MPa (190 bars), ces profils d'extrusion étant bien connus de l'homme du métier.The extrusion profile for the composition 1 extends from 145 ° C. to 200 ° C. under a pressure of 15 MPa (150 Bar), that of the composition 2 extends from 100 ° C to 135 ° C under a pressure of 13.5 MPa (135 Bar), and that of the compositions 5 and 5 bis extends from 120 to 150 ° C under a pressure of 19 MPa (190 bar), these profiles extrusion being well known to those skilled in the art.
Ces compositions extrudées sont soumises à des tests d'isolation. Le test d'isolation selon la norme IEC 60502-1 consiste à immerger les fils électriques dans de l'eau pendant au moins une heure avant ledit test.These extruded compositions are subjected to insulation tests. The insulation test according to IEC 60502-1 consists in immersing the electric wires in water for at least one hour before said test.
Une tension continue comprise entre 80V et 500V est alors appliquée pendant une durée suffisante (entre 1 et 5 min) puis la résistance de la couronne est mesurée. Celle-ci permet de déterminer la constante d'isolement.A DC voltage between 80V and 500V is then applied for a sufficient time (between 1 and 5 min) then the resistance of the ring is measured. This is used to determine the insulation constant.
Les constantes d'isolement (Ki) à 20°C obtenues pour les compositions extrudées des fils électriques 1, 2, 5 et 5bis sont rassemblées dans le Tableau 5 ci-après.
Ces valeurs de Ki sont avantageusement supérieures à celles préconisées pour certains matériaux, notamment pour le polychlorure de vinyle.These Ki values are advantageously greater than those recommended for certain materials, especially for polyvinyl chloride.
L'extrusion de ladite composition permet de réaliser des épaisseurs de couche importantes de l'ordre d'au moins 0,3-0,5 mm, contrairement aux revêtements filmogènes, et permet ainsi d'obtenir des propriétés isolantes optimisées. Plus l'épaisseur extrudée est importante, meilleure est l'isolation électrique.The extrusion of said composition makes it possible to achieve significant layer thicknesses of the order of at least 0.3-0.5 mm, unlike film-forming coatings, and thus makes it possible to obtain optimized insulating properties. The higher the extruded thickness, the better the electrical insulation.
On précise que les compositions en question sont utilisées dans la réalisation des matériaux extrudés isolants et/ou de gainage et/ou de bourrage pour les câbles d'énergie et/ou de télécommunication.It is specified that the compositions in question are used in the production of extruded insulating and / or sheathing and / or stuffing materials for energy and / or telecommunication cables.
La composition peut par ailleurs comprendre d'autres additifs, notamment des agents antioxydants, des agents stabilisants UV, des agents plastifiants, des agents de pigmentation ou des agents colorants.The composition may furthermore comprise other additives, especially antioxidants, UV stabilizing agents, plasticizing agents, pigmentation agents or coloring agents.
Avantageusement, les agents plastifiants peuvent être ajoutés à la composition conforme à la présente invention afin d'améliorer l'allongement à la rupture de ladite composition.Advantageously, the plasticizing agents may be added to the composition according to the present invention in order to improve the elongation at break of said composition.
A titre d'exemple, on peut citer comme agent plastifiant l'huile de ricin, le crodamide ou le triéthyle citrate.By way of example, mention may be made, as a plasticizer, of castor oil, crodamide or triethyl citrate.
La présente invention n'est pas limitée aux exemples de compositions qui viennent d'être décrit et porte dans sa généralité sur tous les câbles envisageables à partir des indications générales fournies dans l'exposé de l'invention.The present invention is not limited to the examples of compositions which have just been described and generally relates to all the cables that can be envisaged from the general indications given in the description of the invention.
Claims (7)
- A power and/or telecommunications cable, including at least one constitutive element made in an extruded material stemming from an extrudable composition, characterized in that said extrudable composition comprises a biopolymer of the starch polymer type complexed with a biodegradable polyester.
- The power and/or telecommunications cable according to claim 1, characterized in that said extrudable composition further comprises a synthetic polymer.
- The power and/or telecommunications cable according to claim 2, characterized in that said synthetic polymer is selected from polyethylene, polypropylene, ethyl vinyl acetate copolymer, polyvinyl chloride and polyester, or a mixture thereof.
- The power and/or telecommunications cable according to any of claims 1 to 3, characterized in that said constitutive element is selected from an insulating cladding, a protective sheath and a filling material.
- The power and/or telecommunications cable according to any of the preceding claims, characterized in that said extrudable composition further comprises a flame-retardant filler.
- The power and/or telecommunications cable according to claim 5, characterized in that the flame-retardant filler is selected from aluminum trihydroxyde Al(OH)3, magnesium dihydroxide Mg(OH)2, a mixture of magnesium carbonate hydrate and calcium and magnesium carbonate, zinc borate and/or cork powder.
- The power and/or telecommunications cable according to any of the preceding claims, characterized in that the extrudable composition further comprises other biopolymers selected from polymers of cellulose ester, polymers of polyhydroxyalkanoate, and/or polymers of polylactic acid comprising a mixture of polylactic acid and of polyester.
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EP10167309A EP2244267A1 (en) | 2006-12-26 | 2007-12-26 | Bipolymer-based composition for a cable and/or a telecommunication cable |
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FR0655944A FR2910692A1 (en) | 2006-12-26 | 2006-12-26 | COMPOSITION FOR ENERGY CABLE AND / OR TELECOMMUNICATION BASED ON BIOPOLYMER |
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EP10167309.3 Division-Into | 2010-06-25 |
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EP1939895B1 true EP1939895B1 (en) | 2012-04-25 |
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---|---|---|---|
EP07150419A Not-in-force EP1939895B1 (en) | 2006-12-26 | 2007-12-26 | Composition for an energy and/or a telecommunication cable based on biopolymer |
EP10167309A Withdrawn EP2244267A1 (en) | 2006-12-26 | 2007-12-26 | Bipolymer-based composition for a cable and/or a telecommunication cable |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10167309A Withdrawn EP2244267A1 (en) | 2006-12-26 | 2007-12-26 | Bipolymer-based composition for a cable and/or a telecommunication cable |
Country Status (4)
Country | Link |
---|---|
US (1) | US7884143B2 (en) |
EP (2) | EP1939895B1 (en) |
AT (1) | ATE555482T1 (en) |
FR (1) | FR2910692A1 (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2880028B1 (en) * | 2004-12-24 | 2007-02-23 | Nexans Sa | FIRE-RESISTANT COMPOSITION, IN PARTICULAR FOR CABLE MATERIAL OF ENERGY AND / OR TELECOMMUNICATION |
CN102597107B (en) | 2009-08-27 | 2015-09-16 | 梅塔玻利克斯公司 | Toughness reinforcing poly (hydroxyalkanoate) ester composition |
KR101106169B1 (en) * | 2009-12-30 | 2012-01-20 | 삼신이노텍 주식회사 | Eco-friendly earphone cord |
CN101805463B (en) * | 2010-04-16 | 2013-04-17 | 安徽科聚新材料有限公司 | Starch filled biodegradable polypropylene and preparation method thereof |
FR2978966B1 (en) * | 2011-08-12 | 2013-09-27 | Schneider Electric Ind Sas | FLAME RETARDANT MATERIAL COMPRISING A BIOPOLYMER. |
US9475930B2 (en) | 2012-08-17 | 2016-10-25 | Metabolix, Inc. | Biobased rubber modifiers for polymer blends |
CN103194013A (en) * | 2013-03-02 | 2013-07-10 | 安徽金田通信科技实业有限公司 | Low-cost cable filler and preparation method thereof |
CN103172922A (en) * | 2013-03-02 | 2013-06-26 | 安徽金田通信科技实业有限公司 | Multi-component cable filling material and preparation method thereof |
US10669417B2 (en) | 2013-05-30 | 2020-06-02 | Cj Cheiljedang Corporation | Recyclate blends |
US10611903B2 (en) | 2014-03-27 | 2020-04-07 | Cj Cheiljedang Corporation | Highly filled polymer systems |
FR3029345B1 (en) * | 2014-11-27 | 2016-11-18 | Nexans | CABLE COMPRISING A COATING BASED ON A PLASTIC POLYMER AND FUNCTIONALIZED CELLULOSE PARTICLES |
RU2741986C1 (en) * | 2020-05-12 | 2021-02-01 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) | Biodegradable material |
CN115873311A (en) * | 2022-12-23 | 2023-03-31 | 江西广源新材料有限公司 | Starch-based magnesium salt powder, preparation method and application thereof, energy cable composite material and preparation method thereof |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB515666A (en) | 1937-02-27 | 1939-12-11 | British Thomson Houston Co Ltd | Improvements in and relating to electric conductors |
GB588210A (en) | 1945-02-05 | 1947-05-16 | William Henry Moss | Improvements relating to the manufacture of electrical insulators from thermoplastic cellulose derivatives |
US2549101A (en) * | 1947-03-18 | 1951-04-17 | Hercules Powder Co Ltd | Insulated electrical conductor |
US5847031A (en) * | 1993-05-03 | 1998-12-08 | Chemische Fabrik Stockhausen Gmbh | Polymer composition, absorbent composition, their production and use |
DE4442606C2 (en) | 1994-11-30 | 1998-09-17 | Degussa | Swellable starch ester, process for its production and use |
SE9504678D0 (en) * | 1995-12-28 | 1995-12-28 | Pacesetter Ab | electrode Cable |
DE19632504A1 (en) | 1996-08-12 | 1998-02-19 | Gt Gmbh Elektrotechnische Prod | Plastic sleeve for electrical cable fittings |
JP2002275360A (en) * | 2001-03-16 | 2002-09-25 | Toyobo Co Ltd | Electrical insulating material |
JP4497822B2 (en) * | 2003-02-26 | 2010-07-07 | 三井化学株式会社 | Electrical insulation material |
JP2004311064A (en) * | 2003-04-02 | 2004-11-04 | Fujikura Ltd | Dc power cable |
JP2004311063A (en) * | 2003-04-02 | 2004-11-04 | Fujikura Ltd | Power cable |
-
2006
- 2006-12-26 FR FR0655944A patent/FR2910692A1/en not_active Withdrawn
-
2007
- 2007-12-21 US US12/005,133 patent/US7884143B2/en not_active Expired - Fee Related
- 2007-12-26 AT AT07150419T patent/ATE555482T1/en active
- 2007-12-26 EP EP07150419A patent/EP1939895B1/en not_active Not-in-force
- 2007-12-26 EP EP10167309A patent/EP2244267A1/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
EP2244267A1 (en) | 2010-10-27 |
ATE555482T1 (en) | 2012-05-15 |
FR2910692A1 (en) | 2008-06-27 |
EP1939895A2 (en) | 2008-07-02 |
US20080153941A1 (en) | 2008-06-26 |
EP1939895A3 (en) | 2008-07-09 |
US7884143B2 (en) | 2011-02-08 |
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