CN101805463B - Starch filled biodegradable polypropylene and preparation method thereof - Google Patents
Starch filled biodegradable polypropylene and preparation method thereof Download PDFInfo
- Publication number
- CN101805463B CN101805463B CN 201010153392 CN201010153392A CN101805463B CN 101805463 B CN101805463 B CN 101805463B CN 201010153392 CN201010153392 CN 201010153392 CN 201010153392 A CN201010153392 A CN 201010153392A CN 101805463 B CN101805463 B CN 101805463B
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- Prior art keywords
- starch
- polypropylene
- filled biodegradable
- starch filled
- biodegradable polypropylene
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920002472 Starch Polymers 0.000 title claims abstract description 34
- 235000019698 starch Nutrition 0.000 title claims abstract description 34
- 239000008107 starch Substances 0.000 title claims abstract description 34
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 33
- -1 polypropylene Polymers 0.000 title claims abstract description 33
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000002270 dispersing agent Substances 0.000 claims abstract description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 16
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- BTVVNGIPFPKDHO-UHFFFAOYSA-K cerium(3+);octadecanoate Chemical compound [Ce+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O BTVVNGIPFPKDHO-UHFFFAOYSA-K 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- 239000004033 plastic Substances 0.000 claims description 8
- 229920003023 plastic Polymers 0.000 claims description 8
- 238000005453 pelletization Methods 0.000 claims description 7
- 239000004902 Softening Agent Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 2
- 238000005461 lubrication Methods 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 9
- 238000012856 packing Methods 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 229920006238 degradable plastic Polymers 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229920005629 polypropylene homopolymer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical group C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 description 1
- 229920000164 Cereplast Polymers 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- MOVRNJGDXREIBM-UHFFFAOYSA-N aid-1 Chemical compound O=C1NC(=O)C(C)=CN1C1OC(COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)CO)C(O)C1 MOVRNJGDXREIBM-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- ZJOLCKGSXLIVAA-UHFFFAOYSA-N ethene;octadecanamide Chemical compound C=C.CCCCCCCCCCCCCCCCCC(N)=O.CCCCCCCCCCCCCCCCCC(N)=O ZJOLCKGSXLIVAA-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000002362 mulch Substances 0.000 description 1
- 239000010816 packaging waste Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000013502 plastic waste Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Abstract
Description
Component concentration (% by weight) | Testing standard | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
Starch content | 30 | 40 | 50 | 60 | 70 | |
Softening agent | 8 | 13 | 13 | 13 | 15 | |
Polypropylene | 55 | 40 | 30 | 20 | 8 | |
Dispersion agent | 1 | 1 | 1 | 1 | 1 | |
Toughner | 5 | 5 | 5 | 5 | 5 | |
Photodegradable aid | 1 | 1 | 1 | 1 | 1 | |
Tensile strength (MPa) | ASTMD-628 | 21.2 | 17.4 | 21.05 | 13.9 | 12.17 |
Elongation at break (%) | ASTMD-628 | 7.4 | 4.9 | 24.65 | 4.9 | 4.77 |
Flexural strength (MPa) | ASTMD-790 | 30.4 | 27.0 | 24.9 | 21.72 | 19.04 |
Modulus in flexure (MPa) | ASTMD-790 | 856 | 883.4 | 731.36 | 634.4 | 562.02 |
Notched Izod impact strength (KJ/m2) | ASTMD-256 | 58.6 | 42.5 | 58.3 | 56.55 | 51.02 |
Melting index (g/10min) | ASTM D-1238 | 22.8 | 16.63 | 13.6 | 9.76 | 9.3 |
Proportion (g/cm3) | ASTM D-792 | 1.021 | 1.074 | 1.097 | 1.152 | 1.209 |
The sample classification | Original thickness (mm) | Three months thickness (mm) | Thickness minimizing value (mm) | Thickness decrement % |
Prior art | 3 | 3 | 0 | 0 |
Embodiment 1-5 | 3 | 1.8 | 1.2 | 40.0 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201010153392 CN101805463B (en) | 2010-04-16 | 2010-04-16 | Starch filled biodegradable polypropylene and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201010153392 CN101805463B (en) | 2010-04-16 | 2010-04-16 | Starch filled biodegradable polypropylene and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101805463A CN101805463A (en) | 2010-08-18 |
CN101805463B true CN101805463B (en) | 2013-04-17 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN 201010153392 Expired - Fee Related CN101805463B (en) | 2010-04-16 | 2010-04-16 | Starch filled biodegradable polypropylene and preparation method thereof |
Country Status (1)
Country | Link |
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CN (1) | CN101805463B (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2966769B1 (en) * | 2010-10-27 | 2014-02-07 | Roquette Freres | MULTILAYER STRUCTURE COMPRISING AN ADHESIVE COMPOSITION BASED ON AMYLACEOUS MATERIAL |
CN103589178B (en) * | 2012-08-17 | 2016-06-01 | 杭州康赛环保科技有限公司 | A kind of sponge and its preparation method |
CN103937036A (en) * | 2014-04-23 | 2014-07-23 | 苏州羽帆新材料科技有限公司 | Environment-friendly plastic containing modified starch |
CN104830000A (en) * | 2015-04-29 | 2015-08-12 | 安徽松泰包装材料有限公司 | Production method of food package material |
CN106279787A (en) * | 2016-08-10 | 2017-01-04 | 欧小宇 | modified starch composite mulching film |
CN107540948A (en) * | 2017-09-19 | 2018-01-05 | 四川大学 | Degraded film formulation |
CN107488303B (en) * | 2017-09-19 | 2020-03-31 | 四川大学 | Degradable film |
CN108676200A (en) * | 2018-06-07 | 2018-10-19 | 苏州汉丰新材料股份有限公司 | Biodegradable plastic base material and preparation method thereof |
CN108976592A (en) * | 2018-06-11 | 2018-12-11 | 全椒祥瑞塑胶有限公司 | A kind of plastics that environmental protection is degradable |
CN109265937A (en) * | 2018-09-21 | 2019-01-25 | 袁志平 | The method for preparing the dedicated agricultural mulching of peanut using automobile-used acoustical cotton corner dead meal |
CN109776875A (en) * | 2018-12-17 | 2019-05-21 | 合肥信达膜科技有限公司 | A kind of ceramic membrane environmental protection package formula and its production technology |
CN113150396A (en) * | 2021-03-31 | 2021-07-23 | 方龙 | Preparation method of packaging bag capable of being rapidly degraded |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1205346A (en) * | 1998-02-25 | 1999-01-20 | 李嘉琛 | Controllable light biological whole degradation plastic |
CN1280146A (en) * | 2000-07-13 | 2001-01-17 | 天津丹海股份有限公司 | Biologically degradable fibre level resin composition and its producing method |
CN1563172A (en) * | 2004-04-20 | 2005-01-12 | 杨凌沃林国际降解树脂发展有限公司 | Packing materials of starch-polypropylene foam, an preparation method |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2910692A1 (en) * | 2006-12-26 | 2008-06-27 | Nexans Sa | COMPOSITION FOR ENERGY CABLE AND / OR TELECOMMUNICATION BASED ON BIOPOLYMER |
-
2010
- 2010-04-16 CN CN 201010153392 patent/CN101805463B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1205346A (en) * | 1998-02-25 | 1999-01-20 | 李嘉琛 | Controllable light biological whole degradation plastic |
CN1280146A (en) * | 2000-07-13 | 2001-01-17 | 天津丹海股份有限公司 | Biologically degradable fibre level resin composition and its producing method |
CN1563172A (en) * | 2004-04-20 | 2005-01-12 | 杨凌沃林国际降解树脂发展有限公司 | Packing materials of starch-polypropylene foam, an preparation method |
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CN101805463A (en) | 2010-08-18 |
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Denomination of invention: Starch filled biodegradable polypropylene and preparation method thereof Effective date of registration: 20150817 Granted publication date: 20130417 Pledgee: China Everbright Bank Shenzhen branch Pledgor: Polymer Science (Anhui) New Material Co., Ltd. Registration number: 2015990000681 |
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Denomination of invention: Starch filled biodegradable polypropylene and preparation method thereof Effective date of registration: 20170106 Granted publication date: 20130417 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Anhui science and Technology Co., Ltd.|Shenzhen branch poly new materials Co., Ltd.|Xu Dong Registration number: 2016990001133 |
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Date of cancellation: 20180904 Granted publication date: 20130417 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Polymer Science (Anhui) New Material Co., Ltd.|Shenzhen Keju New Material Co., Ltd.|Xu Dong Registration number: 2016990001133 |
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Denomination of invention: Starch filled biodegradable polypropylene and preparation method thereof Effective date of registration: 20180912 Granted publication date: 20130417 Pledgee: Bank of Shizuishan Limited by Share Ltd Yinchuan branch Pledgor: Polymer Science (Anhui) New Material Co., Ltd.|Shenzhen Keju New Material Co., Ltd. Registration number: 2018440020055 |
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