CN103194013A - Low-cost cable filler and preparation method thereof - Google Patents

Low-cost cable filler and preparation method thereof Download PDF

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Publication number
CN103194013A
CN103194013A CN201310066453XA CN201310066453A CN103194013A CN 103194013 A CN103194013 A CN 103194013A CN 201310066453X A CN201310066453X A CN 201310066453XA CN 201310066453 A CN201310066453 A CN 201310066453A CN 103194013 A CN103194013 A CN 103194013A
Authority
CN
China
Prior art keywords
low
cable
parts
preparation
acid ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310066453XA
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Chinese (zh)
Inventor
陶善如
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Jintian Communications Industrial Co Ltd
Original Assignee
Anhui Jintian Communications Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Jintian Communications Industrial Co Ltd filed Critical Anhui Jintian Communications Industrial Co Ltd
Priority to CN201310066453XA priority Critical patent/CN103194013A/en
Publication of CN103194013A publication Critical patent/CN103194013A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895Barrel or housing

Abstract

The invention discloses a low-cost cable filler and a preparation method thereof. The filler is prepared by mixing a composition raw material polyethylene resin, EVA, polyamide resin, a silane coupling agent, calcium carbonate, diatomite, titanate, zine stearate, ethyl acetate, attapulgite, fatty acid ester, straw ash, carbon black, epoxypropane phenyl ether and an antioxidant 1010 according to a certain ratio. The low-cost cable filler is stable in chemical structure, not decomposed by microorganisms, good in gel performance, and high in expansion capability, improves electrical performance of the cable, prolongs service life of the cable and saves resources.

Description

A kind of low-cost electric cable stopping composition and preparation method thereof
Technical field
The present invention relates to cable and use the auxiliary material field, be specifically related to a kind of low-cost electric cable stopping composition and preparation method thereof.
Background technology
Very general of the application of China's high voltage power cable and extensively is comparatively moist mostly at high voltage power cable underground its environment that is laid in mostly.The very easy construction of cable inside that is penetrated into of moisture. therefore the electric stress theory is thought under normal high pressure energising situation, and the internal stress of cable in production and operational process is the major cause that promotes the water tree growth.When cable when standing voltage and water, in the high pressure power frequency electric field, polar water molecules produces strong migration and electric field energy is converted into kinetic energy and heat energy, obtains the water molecules of huge energy in the inner strenuous exercise of insulation.When the water molecules energy is enough to interrupt cable insulation XLPE molecular chain, will be at the trickle crackle of the inner generation of insulation, near the strain of the XLPE insulation the conductor will increase, and in the bigger zone of strain (locating as impurity and pore etc.) just generate water tree.Reduce the dielectric level of insulating material greatly, thereby shortened the work-ing life of cable, cause enormous economic loss.
The cable of my company exploitation is with vertical waterproofing type packing material, mainly be by in cable stranding process, vertically filling the water blockoff strip material, can absorb big water gaging, the turgidity height, and under heat effect, have higher gel viscosity and enough resistance toheats, and be convenient to the convenient of cable production industry and use, this material have the steady chemical structure that realizes the cable water shutoff material, not good by microbiological degradation, gellifying property, certain swelling capacity and speed of expansion requirement arranged.
Summary of the invention
In order to alleviate the deficiencies in the prior art and defective, the invention discloses a kind of low-cost electric cable stopping composition and preparation method thereof, low-cost electric cable stopping composition of the present invention has steady chemical structure, not good by microbiological degradation, gellifying property, the swelling capacity height, the electric property of cable improves, prolong the work-ing life of cable, saved resource.
The technical solution used in the present invention is as follows for achieving the above object:
The low-cost electric cable stopping composition is characterized in that the weight part of its constitutive material is:
Polyvinyl resin 90-110 part
EVA 10-15 part
Polyamide resin 10-20 part
Silane coupling agent 3-8 part
Calcium carbonate 20-25 part
Diatomite 20-25 part
Titanic acid ester 1-2 part
Zinic stearas 3-10 part
Ethyl acetate 5-10 part
Attapulgite 10-15 part
Fatty acid ester 5-10 part
Stalk ashes 10-15 part
Carbon black 20-30 part
Propylene oxide phenyl ether 5-10 part
Anti-aging agent 1010 2-5 parts
The preparation method of described low-cost electric cable stopping composition is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, mix, and the extruder hopper of packing into, the barrel zone temperature control of extruding machine generates the molten state compound at 130-190 ℃;
(2) in the molten state compound, pour nitrogen, take out and pass through 75-95 ℃ hot water tank and room temperature tank, the air-dry finished product that obtains successively.
Beneficial effect of the present invention:
Low-cost electric cable stopping composition of the present invention has steady chemical structure, not good by microbiological degradation, gellifying property, the swelling capacity height, and the electric property of cable improves, and has prolonged the work-ing life of cable, has saved resource.
Embodiment
Embodiment 1:The low-cost electric cable stopping composition, the weight part of its constitutive material is:
90 parts of polyvinyl resins
10 parts of EVA
10 parts of polyamide resins
3 parts of silane coupling agents
20 parts in calcium carbonate
20 parts in diatomite
1 part of titanic acid ester
3 parts of Zinic stearass
5 parts of ethyl acetate
10 parts of attapulgites
5 parts of fatty acid esters
10 parts in stalk ashes
20 parts of carbon blacks
5 parts of propylene oxide phenyl ethers
1,010 2 parts in anti-aging agent
The preparation method of low-cost electric cable stopping composition may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, mix, and the extruder hopper of packing into, the barrel zone temperature control of extruding machine generates the molten state compound at 130-190 ℃;
(2) in the molten state compound, pour nitrogen, take out and pass through 75-95 ℃ hot water tank and room temperature tank, the air-dry finished product that obtains successively.
Embodiment 2:The low-cost electric cable stopping composition, the weight part of its constitutive material is:
110 parts of polyvinyl resins
15 parts of EVA
20 parts of polyamide resins
8 parts of silane coupling agents
25 parts in calcium carbonate
25 parts in diatomite
2 parts of titanic acid ester
10 parts of Zinic stearass
10 parts of ethyl acetate
15 parts of attapulgites
10 parts of fatty acid esters
15 parts in stalk ashes
30 parts of carbon blacks
10 parts of propylene oxide phenyl ethers
1,010 5 parts in anti-aging agent
The preparation method of low-cost electric cable stopping composition may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, mix, and the extruder hopper of packing into, the barrel zone temperature control of extruding machine generates the molten state compound at 130-190 ℃;
(2) in the molten state compound, pour nitrogen, take out and pass through 75-95 ℃ hot water tank and room temperature tank, the air-dry finished product that obtains successively.
Embodiment 3:Low-cost electric cable stopping composition physics of the present invention, machinery and flame retardant properties, as following table 1:
Table 1:
Performance Unit Test value Test method
Tensile strength Mpa 14.2 GB1040
Elongation at break % 238 GB1040
Impact embrittlement temperature -20℃ By GB5470
Thermal distortion % 20.7 GB8815
20 ℃ of volume specific resistances Ω.m 2.08×10 11 GB1410
Dielectric strength MV/m 27.6 GB1408
Oxygen index - 53.5 GB2406

Claims (2)

1. low-cost electric cable stopping composition is characterized in that the weight part of its constitutive material is:
Polyvinyl resin 90-110 part
EVA 10-15 part
Polyamide resin 10-20 part
Silane coupling agent 3-8 part
Calcium carbonate 20-25 part
Diatomite 20-25 part
Titanic acid ester 1-2 part
Zinic stearas 3-10 part
Ethyl acetate 5-10 part
Attapulgite 10-15 part
Fatty acid ester 5-10 part
Stalk ashes 10-15 part
Carbon black 20-30 part
Propylene oxide phenyl ether 5-10 part
Anti-aging agent 1010 2-5 parts.
2. the preparation method of a low-cost electric cable stopping composition as claimed in claim 1 is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, mix, and the extruder hopper of packing into, the barrel zone temperature control of extruding machine generates the molten state compound at 130-190 ℃;
(2) in the molten state compound, pour nitrogen, take out and pass through 75-95 ℃ hot water tank and room temperature tank, the air-dry finished product that obtains successively.
CN201310066453XA 2013-03-02 2013-03-02 Low-cost cable filler and preparation method thereof Pending CN103194013A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310066453XA CN103194013A (en) 2013-03-02 2013-03-02 Low-cost cable filler and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310066453XA CN103194013A (en) 2013-03-02 2013-03-02 Low-cost cable filler and preparation method thereof

Publications (1)

Publication Number Publication Date
CN103194013A true CN103194013A (en) 2013-07-10

Family

ID=48716839

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310066453XA Pending CN103194013A (en) 2013-03-02 2013-03-02 Low-cost cable filler and preparation method thereof

Country Status (1)

Country Link
CN (1) CN103194013A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103524863A (en) * 2013-09-25 2014-01-22 吴江市天源塑胶有限公司 Heat-conducting wear-resistant plastic
CN103589147A (en) * 2013-10-29 2014-02-19 安徽安缆模具有限公司 Impact-resistance nylon PA12 material for automobile connectors

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101807451A (en) * 2010-04-14 2010-08-18 四川新蓉电缆有限责任公司 Cable fillers
EP2244267A1 (en) * 2006-12-26 2010-10-27 Nexans Bipolymer-based composition for a cable and/or a telecommunication cable
CN102391593A (en) * 2011-11-10 2012-03-28 安徽金田通信科技实业有限公司 Environment-friendly cable filler and preparation method thereof
CN102443228A (en) * 2011-10-18 2012-05-09 安徽金田通信科技实业有限公司 Fire resistant cable filler and preparation method thereof
CN102504436A (en) * 2011-10-18 2012-06-20 池州灵芝化建材料科技有限公司 Flame-retardant cable filler and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2244267A1 (en) * 2006-12-26 2010-10-27 Nexans Bipolymer-based composition for a cable and/or a telecommunication cable
CN101807451A (en) * 2010-04-14 2010-08-18 四川新蓉电缆有限责任公司 Cable fillers
CN102443228A (en) * 2011-10-18 2012-05-09 安徽金田通信科技实业有限公司 Fire resistant cable filler and preparation method thereof
CN102504436A (en) * 2011-10-18 2012-06-20 池州灵芝化建材料科技有限公司 Flame-retardant cable filler and preparation method thereof
CN102391593A (en) * 2011-11-10 2012-03-28 安徽金田通信科技实业有限公司 Environment-friendly cable filler and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103524863A (en) * 2013-09-25 2014-01-22 吴江市天源塑胶有限公司 Heat-conducting wear-resistant plastic
CN103589147A (en) * 2013-10-29 2014-02-19 安徽安缆模具有限公司 Impact-resistance nylon PA12 material for automobile connectors

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PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
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Application publication date: 20130710

RJ01 Rejection of invention patent application after publication