EP1912532B2 - Toothbrush comprising inclined and pointed bristles - Google Patents
Toothbrush comprising inclined and pointed bristles Download PDFInfo
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- EP1912532B2 EP1912532B2 EP06761256A EP06761256A EP1912532B2 EP 1912532 B2 EP1912532 B2 EP 1912532B2 EP 06761256 A EP06761256 A EP 06761256A EP 06761256 A EP06761256 A EP 06761256A EP 1912532 B2 EP1912532 B2 EP 1912532B2
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- European Patent Office
- Prior art keywords
- tufts
- row
- bristles
- brush head
- distance
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B9/00—Arrangements of the bristles in the brush body
- A46B9/02—Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
- A46B9/04—Arranged like in or for toothbrushes
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
Definitions
- the present invention relates to brush heads for toothbrushes in which a part of the tufts are tilted.
- Toothbrushes with a mixed stocking perpendicular to the bristle carrier towering tufts on the one hand and inclined, cross-shaped x-shaped tufts are from the EP-A-0 885 573 known.
- the Applicant of the present application sells three toothbrushes of this type in Europe under the names Elmex Inter X, Elmex Inter X sensitive and Elmex Inter X junior. These toothbrushes are distinguished from a brush with exclusively vertical or exclusively x-shaped crossed tufts by a good cleaning performance both in the tooth surfaces and in the interdental spaces.
- toothbrushes after their completion whether with vertical tufts, with x-shaped tufts or with the above-mentioned mixed stocking, usually trimmed to a uniform height within a tuft. If desired, the trimmed bristle ends are then mechanically rounded to reduce the risk of injury to the gums.
- FR 683,311 discloses a toothbrush having rows of vertical tufts and rows of sloping tufts whose ends cross each other in pairs so that the ends form a single active area.
- JP 2004-129683 A discloses a toothbrush with rows of vertical tufts and rows of inclined, mutually inclined tufts. The ends of all tufts are cut in a sawtooth shape, with the ends of the vertical tufts forming a serration on their own and the ends of the mutually inclined tufts forming a sawtooth in pairs. As starting material, pointed bristles are used; the ends of the bristles are largely cut off by sawtooth cutting.
- the not pre-published EP 1 827 164 discloses brush heads for toothbrushes.
- paragraphs 21-25 and Figures 1-5 Two possible shapes of the bristle profile (cylindrical or tapered) are disclosed, and in paragraph 34 and Figs. 5A and 5B, two possible forms of tuft orientation (vertical or inclined) are disclosed. In addition, a mixed vertical / inclined tufts are not disclosed.
- Object of the present invention was a further improvement of the brush heads for toothbrushes.
- inclined in the context of the present application means that an inclined tuft is inclined at an acute angle to an imaginary line perpendicular to the bristle face, this imaginary line passing through the center of the hole in the bristle carrier associated with said tuft.
- This acute angle is 1 to 10 °, preferably about 7 to 9 ° and more preferably about 8 °.
- An inclined tuft can thus be inclined in the said acute angle about forward, backward or to one side.
- All inclined tufts are tilted forward or backward.
- tilted backwards in the context of the present application means that a tucked-back tuft is inclined in the longitudinal direction of the bristle carrier at the acute angle to the handle part
- tiltted forward means in the context of the present application, in that a forwardly inclined tuft, viewed in the longitudinal direction of the bristle carrier, is inclined away from the handle part at the acute angle.
- the brush head of the invention has a surface which may be flat or curved, and which has imaginary holes for receiving the tufts.
- the bristle tufts protrude from this surface in the finished brush head. This surface is called a "bristle face”.
- the brush heads according to the invention comprise, in addition to inclined tufts, a series of tufts protruding vertically from the bristle face, which are not inclined with respect to an imaginary line perpendicular to the bristle face passing through the center of the hole in the bristle carrier associated with the tuft.
- These tufts protruding perpendicularly from the bristle surface preferably contain only non-pointed bristles.
- the tufts of the inventive brush head are arranged in transverse to its longitudinal transverse rows, in each transverse row either only forward slanted tufts with tapered bristles, or only backward inclined tufts with tapered bristles, or only perpendicular from the bristle surface protruding bristle tufts are present wherein at least one transverse row of forwardly or rearwardly inclined tufts with pointed bristles and at least one transverse row of tufts protruding perpendicularly from the bristle face with non-pointed bristles is provided.
- the tufts of the brush head according to the invention preferably have a circular cross-section.
- pointed bristle is common in the art and refers to a particular cylindrical bristle, the ends of which are reduced by chemical etching (eg with sulfuric acid or sodium hydroxide solution) or by mechanical tapering in diameter such that the bristle is tapered towards its end, such as receives conical profile. If both ends of the bristle are treated in this way, one speaks of a "two-sided sharpened bristle", otherwise of a “one-sided sharpened bristle”. Details of pointed bristle manufacturing techniques are described in various patent publications; it will be exemplary on the EP-A-1 234 525 , Korean Patent No. 130932 and the US-A-2004/0070258 pointed. Sharpened bristles suitable for the present invention are also available on the market, such as from the manufacturers Sogo, Hylon, Best Whasung, Cheil Jedang, Lion and Whessen.
- the pointed ends of the bristles taper towards their tapered end, rotationally symmetric about a central axis of the bristle.
- the sharpened bristles particularly preferably have a profile (ie a diameter of the body of revolution as a function of the distance from the pointed end) which corresponds approximately to the numerical values from one of the following Tables 1 to 4.
- Tables 1 to 4 the average diameters of the bristles are listed as a function of the distance from the pointed end.
- the "diameter range" given in these tables is a typical standard deviation of the diameter determined from several copies of the bristle; this standard deviation can also be considered as range limits of the diameter for these four particularly preferred profiles according to the invention.
- the pointed bristles may be made of any material commonly used for pointed toothbrush bristles.
- the bristles are made of a polyester, in particular a poly (C 2 -C 8 ) alkylene terephthalate, wherein the (C 2 -C 8 ) alkylene is unbranched.
- Rather preferred as bristle materials are polyethylene terephthalate, polypropylene terephthalate, polybutylene terephthalate and polypentylene terephthalate; Particularly preferred is polybutylene terephthalate.
- the non-tapered portion of the sharpened bristles when cylindrical, may have a diameter of about 0.15 to 0.25, preferably about 0.17 to 0.20 mm.
- the non-tapered bristles may be made of any material commonly used for toothbrush bristles.
- the non-sharpened bristles are preferably made of a polyamide, in particular of a polyamide, which is produced from an unbranched (C 2 -C 8 ) -1, ⁇ -diamine and an unbranched (C 4 -C 14 ) -1, ⁇ -dicarboxylic acid , Rather preferred as the bristle materials for the non-tapered bristles Polydimethylenadipinamid, Polytrimethylenadipinamid, Polytetramethylenadipinamid, Polypentamethylenadipinamid, Polyhexamethylenadipinamid, Polydimethylendodecanamid, Polytrimethylendodecanamid, Polytetramethylendodecanamid, Polypentamethylendodecanamid and Polyhexamethylendodecanamid. Particularly preferred is polyhexamethylenedodecanamide.
- the non-sharpened bristles are preferably cylindrical and then preferably have a diameter of from about 0.15 to about 0.20, preferably from about 0.17 to about 0.19 mm.
- the inventive brush head can be used for a manual toothbrush or for an electric toothbrush.
- the bristles mounted on the brush head are set in motion either by hand movements, by motor drive or by sound waves.
- the production of the brush heads according to the invention can be carried out analogously to the production of previously known brush heads.
- one-sided or two-sided sharpened bristles may be used.
- the holes of the bristle carrier which serve to receive the tufts, may have previously been drilled at any angle ⁇ or ⁇ in the bristle carrier, preferably they can also be produced directly in the manufacture of the bristle carrier by injection molding using punch punches.
- the holes are preferably circular in cross section to allow the preferred circular tuft cross section.
- the tuft is preferably anchored by means of an anchor plate or a loop in a hole of the bristle carrier.
- all the bristles of the forming tufts are bent U-shaped within the hole, so that both ends of each bristle protrude from the hole.
- the holes are usually not consistent here.
- the proportion of the pointed ends of the tuft here is just equal to the proportion of double-pointed bristles used.
- the tuft may be anchored in the hole as previously described or fabricated using the known AFT (anchor-free tufting) process.
- AFT anchor-free tufting
- the bristles are inserted into a support plate having through holes, and the bristles of each tuft are welded together at the back hole opening with each other by means of a heating punch.
- the bristles then protrude from the front hole opening of the carrier plate.
- the tufts provided with the tufts can then be poured or welded into a brush head. Details of this procedure are approximately in the EP-A-0 405 204 described.
- Tufts containing only non-pointed bristles are preferably trimmed according to the invention to a uniform height. Tufts containing pointed and non-pointed bristles, or only pointed bristles, are preferably not trimmed according to the invention.
- the selective trimming of the tufts can most easily be carried out with a small, pointed pair of scissors, for example a microscope scissors.
- the steps of planting the tufts with non-tapered bristles, trimming and optionally rounding the bristles of these tufts, and finally planting the inclined tufts, wholly or partially made up of pointed bristles, may be placed in separate successive rows Operations are performed. The machinery and procedural details for each step are known to those skilled in the art.
- gaps between tufts are understood to be measured at the height of the bristle surface of the bristle carrier between the central axes of the two tufts.
- “Lengths of the brush head” are understood to mean distances between two transverse rows of tufts such that at the level of the bristle surface of the bristle carrier in the longitudinal direction, the distance between a first line connecting the center axes of the tufts of the first transverse row and a second line the central axes of the tufts of the second transverse row connects, is measured. This concerns eg in the FIG. 1 shown distance d x . In the figures, the central axes of the tufts are indicated by dashed lines.
- the distance "in the longitudinal direction of the brush head” between any transverse row of tufts and a double row of X-shaped crossed tufts is the average of a) the distance "in the longitudinal direction of the brush head” between the arbitrary transverse row and the transverse row forming a double row, and b) the distance "in the longitudinal direction of the brush head” between the arbitrary transverse row and the second transverse row forming the double row.
- the distance d xx shown is the average of a) the distance between the forward slanted transverse row represented by its tuft 302 and the rearwardly slanted transverse row represented by its tuft 303, and b) the distance between rearwardly slanted transverse row represented by its tuft 301 and the forward slanted transverse row represented by its tuft 304.
- FIGS. 1 . 4 and 5 illustrate the definition of some of the above metrics.
- the height h s it should be noted that it may be of medium height, as the tufts with pointed bristles preferably are not trimmed and therefore the individual bristles contained therein may have different heights.
- This scattering of bristle height is in FIG. 1 Not shown.
- This figure also shows that brush heads according to the invention need not necessarily have the inclined tufts in the form of an X-shaped crossed arrangement; the slanted rows of tufts may also be present either slanted forward or backward.
- the brush heads comprise one or two double rows of x-shaped crossing tufts with pointed bristles. These double rows are each from a first transverse row of inclined backwards tufts with pointed bristles and a to this first transverse row in the direction of the handle portion at a distance d x adjacent second transverse row of forward slanted, compared to the tufts of the first transverse row offset in the transverse direction tufts pointed bristles formed ( Figures 2 and 3 ).
- the distance d x between the forward and backward slanted tufts is 0.7 to 1.3 mm, more preferably 0.9 to 1.1 mm, and most preferably about 1.0 mm.
- the height h s of the inclined tufts is 13.0 to 14.0 mm and preferably about 13.5 mm.
- the brush head additionally comprises transverse rows of tufts protruding perpendicularly from the bristle surface with non-tapered bristles, such that each double row of x-shaped crossed tufts each have a vertical transverse row in the longitudinal direction of the handle portion and a further vertical transverse row in the longitudinal direction Headboard is adjacent.
- X-shaped crossed tufts ( FIG. 2 ) are preferably at a distance d xx in the longitudinal direction of about 8.0 to 10.0 mm, more preferably 8.5 to 9.5 mm and more preferably about 8.9 mm apart.
- d xx in the longitudinal direction of about 8.0 to 10.0 mm, more preferably 8.5 to 9.5 mm and more preferably about 8.9 mm apart.
- two of them lie between the double rows in the form of a first and second middle transverse row, and the other two lie outside the two double rows and form an inner transverse row (in the direction of the handle part 11) and an outer transverse row (in the direction of the head part 12).
- the distance d a between the double rows of X-crossed bristles and the middle transverse rows is preferably 2.5 to 4.0 mm, more preferably 3.0 to 3.5 mm, and particularly preferably about 3.2 mm.
- the preferably trimmed height h a of the tufts of said middle transverse rows is preferably 9.0 to 11.0 mm, more preferably 9.5 to 10.5 mm and particularly preferably about 10.0 mm.
- the distance d b of the said inner and outer transverse rows from the respective double row is preferably 2.5 to 3.5 mm, more preferably 2.7 to 3.3 mm and particularly preferably about 3.0 mm.
- the preferably trimmed height h b of the tufts of the said inner and outer transverse rows is preferably 9.0 to 11.0 mm, more preferably 9.5 to 10.5 mm and particularly preferably about 10.0 mm.
- said two transverse rows of vertical tufts adjoining the double row form an inner transverse row spaced apart from the double row by a distance d e in the direction of the handle portion 11 and an outer transverse row extending towards the head portion 12 in FIG a distance d f is spaced from the double row.
- the distances d e and d f are preferably 3.0 to 4.5 mm and more preferably 3.0 to 4.0 mm. More preferably, d e is about 3.2 mm and d f is about 3.1 mm.
- the preferably trimmed height h ef of the tufts of the inner and outer transverse row is preferably 9.0 to 11.0, more preferably 9.0 to 10.0, and particularly preferably about 10.0 mm.
- a first particularly preferred embodiment of the brush head of the invention has a first double row of inclined, X-shaped crossed bristle tufts, the bristles of which are pointed and not trimmed. It is formed by a first transverse row of tufts of bristles tipped backwards (represented by its foremost tuft 301) and a second transverse row of two tufts inclined forwardly (represented by its foremost tuft 302).
- the distance d x is about 1 mm.
- the height h s of the slanted Tufts are about 13.5 mm, and the angles ⁇ and ⁇ , respectively, in which the tufts inclined forwardly and rearwardly are inclined, are about + 8 ° and about -8 °, respectively (definitions of d x , h s , ⁇ and ⁇ according to FIG. 1 ).
- a second, identical double row of x-shaped crossed tufts is arranged.
- a third transverse row of two backward slanted tufts (represented by their foremost tuft 303) and a fourth transverse row of three forward tipped tufts (represented by their foremost tuft 304).
- the distances between the tufts in the transverse direction are about 4.5 mm.
- a second middle transverse row of four vertical tufts with non-pointed bristles and trimmed to uniform height h a bristles present is a second middle transverse row of four vertical tufts with non-pointed bristles and trimmed to uniform height h a bristles present.
- the widths of the tufts in the transverse direction are about 2.9 mm and the height h a is about 10.0 mm.
- All bristles have a circular cross section over their entire length; the sharpened parts of the pointed bristles are thus rotational bodies.
- the diameter D n of all non-sharpened bristles and the maximum diameter D z of all pointed bristles is about 0.175 mm.
- All tufts are of circular cross-section; the diameter of all tufts is about 1.7 mm.
- This brush head has a first double row of slanted and pointed bristle tufts crossing over in an X-shape as described in the first embodiment (represented by the foremost tufts 301, 302).
- the rearwardly slanted transverse row (tuft 301) has two tufts spaced transversely of about 4.6 mm and the forward slanted row (tuft 302) has three tufts at a transverse spacing of about 4.6 mm each ,
- the distance d x between the backward and the forward slanted transverse row in the longitudinal direction of the brush head is about 1 mm.
- the height h s of the inclined tufts is about 13.5 mm, and the angles ⁇ and ⁇ , respectively, in which the tufts inclined forwardly and rearwardly are inclined, are about + 8 ° and about -8 °, respectively (definitions of d x , h s , ⁇ and ⁇ according to FIG. 1 ).
- d e of about 3.2 mm in the longitudinal direction of the handle part 11 from the first double row, an inner transverse row of four tufts with non-pointed, h ef trimmed to a uniform height hef bristles arranged.
- an outer transverse row of four tufts with non-pointed, h ef trimmed bristles is arranged.
- the distances between the tufts in the transverse direction are approximately 2.9 mm and the heights h ef approximately 10 mm.
- a further inner transverse row of four tufts with non-pointed bristles trimmed to a uniform height h gh is arranged.
- a further outer transverse row of four tufts with non-pointed bristles trimmed to a uniform height h gh is arranged.
- I the other inner transverse row and the other outer transverse row are the distances of the tufts in the transverse direction about 2.9 mm and the height h gh about 11 mm.
- d i of about 8.2 mm in the longitudinal direction of the handle part 11 from the first double row
- an innermost transverse row of three tufts with non-pointed bristles trimmed to a uniform height h ij is arranged.
- an outermost transverse row of three tufts with non-pointed bristles trimmed to a uniform height h ij is arranged.
- the distances between the tufts in the transverse direction amount to about 2.4 mm and the height h ij about 11.5 mm.
- FIGS. 6 . 7 and Fig. 8 are the cleaning performances achieved with different brush heads in horizontal, vertical and circular cleaning movement, respectively.
- the teeth of a maxillary sextant model (with 3 molars, 2 prebend teeth and 1 incisor) were first stained black and then whitewashed with a titanium dioxide paste (25g / v in 26% ethanol). After a standardized brushing process with the brush heads to be tested of 1 minute duration with 2.45 newtons of contact force, the percentage of tooth surfaces freed from the titanium dioxide paste was determined.
- the standardized brushing process consisted of 60 reciprocating motions with an amplitude of 30 mm; in vertical cleaning it consisted of 60 up and down movements with an amplitude of 8 mm; and in the circular cleaning it consisted of 60 circles of radius 4 mm with 16 horizontal reciprocating movements with amplitude of 30 mm at the same time.
Abstract
Description
Die vorliegende Erfindung betrifft Bürstenköpfe für Zahnbürsten, bei denen ein Teil der Büschel schräggestellt sind.The present invention relates to brush heads for toothbrushes in which a part of the tufts are tilted.
Zahnbürsten mit einem gemischten Besatz senkrecht vom Borstenträger aufragenden Büscheln einerseits und schräggestellten, sich x-förmig überkreuzenden Büscheln sind aus der
Um eine möglichst plane Reinigungsfläche der Büschel zu erzielen, werden Zahnbürsten nach ihrer Fertigstellung ob mit senkrechten Büscheln, mit x-förmigen Büscheln oder mit dem oben erwähnten gemischten Besatz, in der Regel auf eine innerhalb eines Büschels einheitliche Höhe getrimmt. Gewünschtenfalls werden die getrimmten Borstenenden anschliessend mechanisch verrundet, um das Verletzungsrisiko auf das Zahnfleisch zu verringern.In order to achieve a clean as possible cleaning surface of the tufts, toothbrushes after their completion, whether with vertical tufts, with x-shaped tufts or with the above-mentioned mixed stocking, usually trimmed to a uniform height within a tuft. If desired, the trimmed bristle ends are then mechanically rounded to reduce the risk of injury to the gums.
Seit neuerer Zeit sind, etwa aus der
Die nicht vorveröffentlichte
Aufgabe der vorliegenden Erfindung war eine weitere Verbesserung der Bürstenköpfe für Zahnbürsten.Object of the present invention was a further improvement of the brush heads for toothbrushes.
Diese Aufgabe wird gelöst durch einen Bürstenkopf nach Anspruch 1.This object is achieved by a brush head according to
Bevorzugte Ausführungsformen ergeben sich aus den Unteransprüchen.Preferred embodiments will be apparent from the dependent claims.
Es wurde überraschenderweise gefunden, dass die Reinigungsleistung auf die Zahnflächen erhöht und gleichzeitig ein schonenderes Reinigen der Zahnflächen möglich ist, wenn in einer Bürste mit gemischt senkrecht stehendem / schräggestelltem Besatz gemäss
Kurzer Beschrieb der Figuren
-
Figur 1 -
Figuren 23 zeigen zwei Ausführungsformen des erfindungsgemässen Bürstenkopfes. -
Figuren 4 und 5 bzw. 3 geeignet ist.Figur 2 -
Figuren 67 und8 zeigen die Messwerte der Reinigungsleistungen, die mit verschiedenen erfindungsgemässen Bürstenköpfen erzielt wurden.
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FIG. 1 shows how to understand some of the sizes used in the present invention concerning the inclined and pointed bristle tufts. -
Figures 2 and3 show two embodiments of the inventive brush head. -
FIGS. 4 and 5 show two embodiments of the arrangement of the Büschellöcher on the bristle carrier, in particular for brush heads according toFIG. 2 or 3 is suitable. -
FIGS. 6 .7 and8th show the measured values of the cleaning performance, which were achieved with various brush heads according to the invention.
Der Begriff "schräggestellt" bedeutet im Rahmen der vorliegenden Anmeldung, dass ein schräggestelltes Büschel in einem spitzen Winkel gegenüber einer gedachten, senkrecht zur Borstenfläche stehenden Line geneigt ist, wobei diese gedachte Linie durch den Mittelpunkt des zu dem besagten Büschel zugehörigen Lochs im Borstenträger geht. Dieser spitze Winkel ist 1 bis 10°, bevorzugt etwa 7 bis 9° und eher bevorzugt etwa 8°. Ein schräggestelltes Büschel kann also in dem besagten spitzen Winkel etwa nach vorne, nach hinten oder zu einer Seite schräggestellt sein.The term "inclined" in the context of the present application means that an inclined tuft is inclined at an acute angle to an imaginary line perpendicular to the bristle face, this imaginary line passing through the center of the hole in the bristle carrier associated with said tuft. This acute angle is 1 to 10 °, preferably about 7 to 9 ° and more preferably about 8 °. An inclined tuft can thus be inclined in the said acute angle about forward, backward or to one side.
Alle schräggestellten Büschel sind nach vorne oder nach hinten schräggestellt. Der Begriff "nach hinten schräggestellt" bedeutet im Rahmen der vorliegenden Anmeldung, dass ein nach hinten schräggestelltes Büschel in Längsrichtung des Borstenträgers gesehen in dem spitzen Winkel zum Griffteil hin geneigt ist, und der Begriff "nach vorne schräggestellt" bedeutet im Rahmen der vorliegenden Anmeldung, dass ein nach vorne schräggestelltes Büschel in Längsrichtung des Borstenträgers gesehen in dem spitzen Winkel vom Griffteil weg geneigt ist.All inclined tufts are tilted forward or backward. The term "tilted backwards" in the context of the present application means that a tucked-back tuft is inclined in the longitudinal direction of the bristle carrier at the acute angle to the handle part, and the term "tilted forward" means in the context of the present application, in that a forwardly inclined tuft, viewed in the longitudinal direction of the bristle carrier, is inclined away from the handle part at the acute angle.
Der Bürstenkopf der Erfindung weist eine Oberfläche auf, die plan oder auch gewölbt sein kann, und die die zur Aufnahme der Büschel gedachten Löcher aufweist. Die Borstenbüschel ragen im fertigen Bürstenkopf aus dieser Oberfläche heraus. Diese Oberfläche wird als "Borstenfläche" bezeichnet.The brush head of the invention has a surface which may be flat or curved, and which has imaginary holes for receiving the tufts. The bristle tufts protrude from this surface in the finished brush head. This surface is called a "bristle face".
Sämtliche Borstenspitzen in den schräggestellten Büscheln sind zugespitzt.All bristle tips in the slanted tufts are sharpened.
Die erfindungsgemässen Bürstenköpfe umfassen neben schräggestellten Büscheln noch eine Reihe von senkrecht aus der Borstenfläche herausragenden Büscheln, die gegenüber einer gedachten, senkrecht zur Borstenfläche stehenden Linie, die durch den Mittelpunkt des zu dem besagten Büschel zugehörigen Lochs im Borstenträger geht, nicht geneigt sind. Diese senkrecht aus der Borstenfläche herausragenden Büschel enthalten bevorzugt nur nicht zugespitzte Borsten.The brush heads according to the invention comprise, in addition to inclined tufts, a series of tufts protruding vertically from the bristle face, which are not inclined with respect to an imaginary line perpendicular to the bristle face passing through the center of the hole in the bristle carrier associated with the tuft. These tufts protruding perpendicularly from the bristle surface preferably contain only non-pointed bristles.
Die Büschel des erfindungsgemässen Bürstenkopfs sind in zu seiner Längsrichtung quer verlaufenden Querreihen angeordnet, wobei in jeder Querreihe entweder nur nach vorne schräggestellte Büschel mit zugespitzten Borsten, oder nur nach hinten schräggestellte Büschel mit zugespitzten Borsten, oder nur senkrecht aus der Borstenfläche herausragende Borstenbüschel vorhanden sind, wobei mindestens eine Querreihe von nach vorne oder nach hinten schräggestellten Büscheln mit zugespitzten Borsten und mindestens eine Querreihe von senkrecht aus der Borstenfläche herausragenden Büscheln mit nicht zugespitzten Borsten vorhanden ist.The tufts of the inventive brush head are arranged in transverse to its longitudinal transverse rows, in each transverse row either only forward slanted tufts with tapered bristles, or only backward inclined tufts with tapered bristles, or only perpendicular from the bristle surface protruding bristle tufts are present wherein at least one transverse row of forwardly or rearwardly inclined tufts with pointed bristles and at least one transverse row of tufts protruding perpendicularly from the bristle face with non-pointed bristles is provided.
Bevorzugt weisen die Büschel des erfindungsgemässen Bürstenkopfs einen kreisförmigem Querschnitt auf.The tufts of the brush head according to the invention preferably have a circular cross-section.
Der Begriff "zugespitzte Borste" ist fachüblich und bezeichnet eine insbesondere zylinderförmige Borste, deren Enden mittels chemischem Abätzen (z.B. mit Schwefelsäure oder mit Natronlauge) oder mittels mechanischem Zuspitzen im Durchmesser dergestalt verringert werden, dass die Borste ein sich zu ihrem Ende hin verjüngendes, etwa konisches Profil erhält. Wenn beide Enden der Borste so behandelt werden, spricht man von einer "zweiseitig zugespitzten Borste", andernfalls von einer "einseitig zugespitzten Borste". Details für Herstellungsverfahren für zugespitzte Borsten sind in diversen Patentveröffentlichungen beschrieben; es wird beispielhaft auf die
Bevorzugt sind die zugespitzten Enden der Borsten sich zu ihrem zugespitzten Ende hin verjüngende, um eine Mittelachse der Borste rotationssymmetrische Rotationskörper. In dem Falle weisen die zugespitzten Borsten besonders bevorzugt ein Profil (d.h. einen Durchmesser des Rotationskörpers in Funktion des Abstandes vom zugespitzten Ende) auf, das etwa den numerischen Werten aus einer der folgenden Tabellen 1 bis 4 entspricht. In diesen Tabellen sind die mittleren Durchmesser der Borsten in Abhängigkeit vom Abstand vom zugespitzten Ende aufgeführt. Als "Durchmesserbereich" ist in diesen Tabellen ein typische, aus mehreren Exemplaren der Borste ermittelte Standardabweichung des Durchmessers angegeben; diese Standardabweichung kann auch als Bereichsgrenzen des Durchmessers für diese vier erfindungsgemäss besonders bevorzugten Profile gelten.
Die zugespitzten Borsten können aus jedem Material bestehen, das üblicherweise für zugespitzte Zahnbürstenborsten verwendet wird. Bevorzugt sind die Borsten aus einem Polyester, insbesondere einem Poly(C2-C8)alkylenterephthalat hergestellt, wobei das (C2-C8)Alkylen unverzweigt ist. Eher bevorzugt sind als Borstenmaterialien Polyethylenterephthalat, Polypropylenterephthalat, Polybutylenterephthalat und Polypentylenterephthalat; besonders bevorzugt ist Polybutylenterephthalat.The pointed bristles may be made of any material commonly used for pointed toothbrush bristles. Preferably, the bristles are made of a polyester, in particular a poly (C 2 -C 8 ) alkylene terephthalate, wherein the (C 2 -C 8 ) alkylene is unbranched. Rather preferred as bristle materials are polyethylene terephthalate, polypropylene terephthalate, polybutylene terephthalate and polypentylene terephthalate; Particularly preferred is polybutylene terephthalate.
Der nicht zugespitzte Teil der zugespitzten Borsten kann, wenn er zylindrisch ist, einen Durchmesser von etwa 0,15 bis 0,25, bevorzugt etwa 0,17 bis 0,20 mm aufweisen.The non-tapered portion of the sharpened bristles, when cylindrical, may have a diameter of about 0.15 to 0.25, preferably about 0.17 to 0.20 mm.
Die nicht zugespitzten Borsten können aus jedem Material bestehen, das üblicherweise für Zahnbürstenborsten verwendet wird. Bevorzugt sind die nicht zugespitzten Borsten aus einem Polyamid, insbesondere aus einem Polyamid, das aus einem unverzweigten (C2-C8)-1,ω-Diamin und einer unverzweigten (C4-C14)-1,ω-Dicarbonsäure hergestellt ist. Eher bevorzugt sind als Borstenmaterialien für die nicht zugespitzten Borsten Polydimethylenadipinamid, Polytrimethylenadipinamid, Polytetramethylenadipinamid, Polypentamethylenadipinamid, Polyhexamethylenadipinamid, Polydimethylendodecanamid, Polytrimethylendodecanamid, Polytetramethylendodecanamid, Polypentamethylendodecanamid und Polyhexamethylendodecanamid. Besonders bevorzugt ist Polyhexamethylendodecanamid.The non-tapered bristles may be made of any material commonly used for toothbrush bristles. The non-sharpened bristles are preferably made of a polyamide, in particular of a polyamide, which is produced from an unbranched (C 2 -C 8 ) -1, ω-diamine and an unbranched (C 4 -C 14 ) -1, ω-dicarboxylic acid , Rather preferred as the bristle materials for the non-tapered bristles Polydimethylenadipinamid, Polytrimethylenadipinamid, Polytetramethylenadipinamid, Polypentamethylenadipinamid, Polyhexamethylenadipinamid, Polydimethylendodecanamid, Polytrimethylendodecanamid, Polytetramethylendodecanamid, Polypentamethylendodecanamid and Polyhexamethylendodecanamid. Particularly preferred is polyhexamethylenedodecanamide.
Die nicht zugespitzten Borsten sind bevorzugt zylinderförmig und weisen dann bevorzugt einen Durchmesser von etwa 0,15 bis etwa 0,20, bevorzugt etwa 0,17 bis etwa 0,19 mm auf.The non-sharpened bristles are preferably cylindrical and then preferably have a diameter of from about 0.15 to about 0.20, preferably from about 0.17 to about 0.19 mm.
Der erfindungsgemässe Bürstenkopf kann für eine Handzahnbürste oder für eine elektrische Zahnbürste eingesetzt werden. Dabei werden die auf dem Bürstenkopf angebrachten Borsten entweder durch Handbewegungen, durch Motorantrieb oder durch Schallwellen in Bewegung gesetzt.The inventive brush head can be used for a manual toothbrush or for an electric toothbrush. The bristles mounted on the brush head are set in motion either by hand movements, by motor drive or by sound waves.
Die Herstellung der erfindungsgemässen Bürstenköpfe kann in Analogie zu der Herstellung vorbekannter Bürstenköpfe erfolgen.The production of the brush heads according to the invention can be carried out analogously to the production of previously known brush heads.
Zur Herstellung der Büschel können einseitig oder zweiseitig zugespitzte Borsten verwendet werden.To produce the tufts, one-sided or two-sided sharpened bristles may be used.
Die Löcher des Borstenträgers, die zur Aufnahme der Büschel dienen, können vorgängig in jedem beliebigen Winkel α oder β in den Borstenträger gebohrt worden sein, bevorzugt können sie auch direkt bei der Herstellung des Borstenträgers im Spritzguss unter Verwendung von Lochstempeln hergestellt werden. Die Löcher sind bevorzugt von kreisförmigem Querschnitt, um den bevorzugten kreisförmigen Büschelquerschnitt zu ermöglichen.The holes of the bristle carrier, which serve to receive the tufts, may have previously been drilled at any angle α or β in the bristle carrier, preferably they can also be produced directly in the manufacture of the bristle carrier by injection molding using punch punches. The holes are preferably circular in cross section to allow the preferred circular tuft cross section.
Wenn zweiseitig zugespitzte und nicht zugespitzte Borsten in beliebigem Verhältnis gemischt in einem Büschel mitverwendet werden, wird das Büschel bevorzugt mittels eines Ankerplättchens oder einer Schlaufe in einem Loch des Borstenträgers verankert. Dabei werden alle Borsten des sich bildenden Büschels innerhalb des Lochs u-förmig umgebogen, so dass beide Enden jeder Borste aus dem Loch herausragen. Die Löcher sind hier in der Regel nicht durchgängig. Der Anteil der zugespitzten Enden des Büschels ist hier gerade gleich dem verwendeten Anteil an doppelt zugespitzten Borsten.If bilaterally pointed and non-sharpened bristles are mixed in any ratio used in a tuft, the tuft is preferably anchored by means of an anchor plate or a loop in a hole of the bristle carrier. In this case, all the bristles of the forming tufts are bent U-shaped within the hole, so that both ends of each bristle protrude from the hole. The holes are usually not consistent here. The proportion of the pointed ends of the tuft here is just equal to the proportion of double-pointed bristles used.
Wenn einseitig zugespitzte und nicht zugespitzte Borsten gemischt, oder nur nicht zugespitzte Borsten, in einem Büschel verwendet werden, kann das Büschel einerseits wie vorher beschrieben im Loch verankert oder mittels des bekannten AFT-("anchor free tufting"-)Verfahrens hergestellt werden. Bei diesem Verfahren werden die Borsten in ein Trägerplättchen, das durchgängige Löcher aufweist, eingeführt und die Borsten jedes Büschels werden an der rückseitigen Lochöffung miteinander mittels eines Heizstempels verschweisst. Die Borsten ragen dann aus der frontseitigen Lochöffnung des Trägerplättchens heraus. Das mit den Büscheln versehene Plättchen kann dann in einen Bürstenkopf eingegossen oder eingeschweisst werden. Details dieses Verfahrens sind etwa in der
Büschel, die nur nicht zugespitzte Borsten enthalten, werden erfindungsgemäss bevorzugt auf eine einheitliche Höhe getrimmt. Büschel, die zugespitzte und nicht zugespitzte Borsten gemischt, oder nur zugespitzte Borsten, enthalten, werden erfindungsgemäss bevorzugt nicht getrimmt. Zur Herstellung von Prototypen kann das selektive Trimmen der Büschel, die nur nicht zugespitzte Borsten enthalten, am einfachsten mit einer kleinen, spitzen Schere, etwa einer Mikroskopierschere, durchgeführt werden. Im Serienmassstab können die Schritte des Einpflanzens der Büschel mit nur nicht zugespitzte Borsten, des Trimmens und optionalen Verrundens der Borsten dieser Büschel, und schlussendlich des Einpflanzens der schräggestellten Büschel, die ganz oder teilweise aus zugespitzten Borsten bestehen, in der angegebenen Reihenfolge in getrennten, hintereinandergeschaltenen Arbeitsgängen durchgeführt werden. Die Maschinen und verfahrenstechnischen Einzelheiten für jeden Schritt sind dem Fachmann bekannt.Tufts containing only non-pointed bristles are preferably trimmed according to the invention to a uniform height. Tufts containing pointed and non-pointed bristles, or only pointed bristles, are preferably not trimmed according to the invention. For the production of prototypes, the selective trimming of the tufts, which contain only non-sharpened bristles, can most easily be carried out with a small, pointed pair of scissors, for example a microscope scissors. On a mass scale, the steps of planting the tufts with non-tapered bristles, trimming and optionally rounding the bristles of these tufts, and finally planting the inclined tufts, wholly or partially made up of pointed bristles, may be placed in separate successive rows Operations are performed. The machinery and procedural details for each step are known to those skilled in the art.
Unter Verweis auf
Für diese bevorzugten Ausführungsformen werden Abstände zwischen Büscheln so verstanden, dass auf der Höhe der Borstenfläche des Borstenträgers zwischen den Mittelachsen der beiden Büschel gemessen wird. Des Weiteren werden Abstände "in Längsrichtung des Bürstenkopfs" zwischen zwei Querreihen von Büscheln so verstanden, dass auf der Höhe der Borstenfläche des Borstenträgers in Längsrichtung der Abstand zwischen einer ersten Linie, die die Mittelachsen der Büschel der ersten Querreihe miteinander verbindet, und einer zweiten Linie, die die Mittelachsen der Büschel der zweiten Querreihe miteinander verbindet, gemessen wird. Dies betrifft z.B. den in der
Die Bürstenköpfe umfassen eine oder zwei Doppelreihen von sich x-förmig überkreuzenden Büscheln mit zugespitzen Borsten. Diese Doppelreihen werden je von einer ersten Querreihe von nach hinten schräggestellten Büscheln mit zugespitzten Borsten und einer zu dieser ersten Querreihe in Richtung des Griffteils in einem Abstand dx benachbarte zweite Querreihe von nach vorne schräggestellten, gegenüber den Büscheln der ersten Querreihe in Querrichtung versetzten Büscheln mit zugespitzten Borsten gebildet (
Noch eher bevorzugt umfasst der Bürstenkopf zusätzlich Querreihen von senkrecht aus der Borstenfläche herausragenden Büscheln mit nicht zugespitzten Borsten, dergestalt, dass an jede Doppelreihe von x-förmig überkreuzten Büscheln je eine senkrechte Querreihe in Längsrichtung zum Griffteil hin und je eine weitere senkrechte Querreihe in Längsrichtung zum Kopfteil hin angrenzt.Even more preferably, the brush head additionally comprises transverse rows of tufts protruding perpendicularly from the bristle surface with non-tapered bristles, such that each double row of x-shaped crossed tufts each have a vertical transverse row in the longitudinal direction of the handle portion and a further vertical transverse row in the longitudinal direction Headboard is adjacent.
Wenn genau zwei Doppelreihen von X-förmig überkreuzten Büscheln vorhanden sind (
Wenn genau eine Doppelreihe von X-förmig überkreuzten Büscheln vorhanden ist (
Eine erste besonders bevorzugte Ausführungsform des Bürstenkopfs der Erfindung (
Analog zu der vorstehend beschriebenen Ausführungsform können weitere Bürstenköpfe wie in der folgenden Tabelle 5 beschrieben ausgestaltet sein. In diesen weiteren Ausführungsformen sind alle numerischen Parameter, die nicht angegeben sind, wie in der vorstehend beschriebenen ersten Ausführungsform. Die Bedeutung der Variablen in den Spaltenköpfen ist gleich wie bei der vorstehend beschriebenen ersten Ausführungsform. Die Spalte "Besatzcd" gibt den Typ der Borsten in den Büscheln der besagten innersten und äussersten Querreihe an: "n" bedeutet "nicht zugespitzt, auf einheitliche Höhe getrimmt" und "z" bedeutet "zugespitzt".
Unter Verweis auf
Zu der vorstehend beschriebenen zwölften Ausführungsform analog können weitere Bürstenköpfe wie in der folgenden Tabelle 6 beschrieben ausgestaltet sein. In diesen weiteren Ausführungsformen sind alle numerischen Parameter, die nicht angegeben sind, gleich wie in der vorstehend beschriebenen zwölften Ausführungsform. Die Bedeutung der Variablen in den Spaltenköpfen ist gleich wie bei der vorstehend beschriebenen zwölften Ausführungsform.
In den
Es wurden für jeden getesteten Bürstenkopftyp und jeden der drei Reinigungstests 4 Exemplare des Bürstenkopfs an je 4 Oberkiefer-Sextanten getestet. Die Mittelwerte der totalen erzielten Reinigungsleistungen für den horizontalen, vertikalen bzw. kreisförmigen Reinigungstest (in Prozent der gereinigten Zahnfläche, mit Streuung) sind in den
Claims (18)
- A brush head (1) for a toothbrush, which brush head has a grip part (11), a head part (12) and a bristle surface with bristle tufts (201, 202, 203, 204, 301, 302, 303, 304, 401, 402, 501, 502, 601, 602, 701, 702) inserted therein and arranged in transverse rows running transversely with respect to the longitudinal direction of the bristle surface, characterised in that that in each transverse row of tufts either only forwardly inclined tufts (302, 304) with solely tapered bristles or only rearwardly inclined tufts with solely tapered bristles (301, 303) or only bristle tufts projecting vertically out of the bristle surface are present, whereby one or two double rows of tufts crossing over in an x-shaped manner with tapered bristles are present, which are each formed by a first transverse row of rearwardly inclined tufts (301, 303) with solely tapered bristles with a height hs of 13.0 to 14.0 mm and a second transverse row, adjacent to this first transverse row in the direction of the grip part (11) at a distance dx of 0.7 to 1.3 mm, of forwardly inclined tufts (302, 304) with solely tapered bristles with a height hs of 13.0 to 14.0 mm, offset with respect to the tufts of the first transverse row in the transverse direction, such that the tufts of the first and second transverse rows form the double row of tufts crossing over in an x-shaped manner, whereby the tufts of the transverse row with forwardly inclined tufts are inclined forwardly at an angle α of +1 to +10° with respect to a line standing perpendicularly to the bristle surface; or the tufts of the one transverse row with rearwardly inclined tufts are inclined rearwardly at an angle β of -1 to -10° with respect to a line standing perpendicularly to the bristle surface, and in that at least one transverse row of tufts projecting vertically out of the bristle surface (201, 202, 203, 204, 401, 402, 501, 502, 601, 602, 701, 702) with non-tapered bristles is present.
- The brush head of claim 1, characterised in that the tufts of the transverse row with forwardly inclined tufts are inclined forwardly at an angle α of +7 to +9°, more preferably of about +8°, with respect to a line standing perpendicularly to the bristle surface; or in that the tufts of the transverse row with rearwardly inclined tufts are inclined rearwardly at an angle β of -7 to -9°, more preferably of about -8°, with respect to a line standing perpendicularly to the bristle surface.
- The brush head of claims 1 or 2, characterised in that it has two double rows of tufts crossing over in an x-shaped manner in the form of a first double row and a second double row, whereby said second double row is arranged at a distance dxx from said first double row in the longitudinal direction of the brush head toward the head part (12), whereby this distance dxx is preferably 8.0 to 10.0 mm, more preferably 8.5 to 9.5 mm and particularly preferably about 8.9 mm.
- The brush head of claim 3, characterised in that it has a first middle transverse row of non-tapered tufts projecting vertically out of the bristle surface with bristles trimmed to a uniform height ha, which is arranged at a distance da from said first double row in the longitudinal direction of the brush head toward the head part (12), and has a second middle transverse row of non-tapered tufts projecting vertically out of the bristle surface and having bristles trimmed to a uniform height ha, which is arranged at a distance da from said second double row in the longitudinal direction of the brush head toward the grip part (11), whereby the distance da is preferably 2.5 to 4.0 mm, more preferably 3.0 to 3.5 mm and particularly preferably about 3.2 mm.
- The brush head of claim 4, characterised in that the height ha of the tufts of said middle transverse rows is 9.0 to 11.0 mm and preferably 9.5 to 10.5 mm.
- The brush head of one of claims 3 to 5, characterised in that it has an inner transverse row of non-tapered tufts projecting vertically out of the bristle surface with bristles trimmed to a uniform height hb, which is arranged at a distance db from said first double row in the longitudinal direction of the brush head toward the grip part (11), and has an outer transverse row of non-tapered tufts projecting vertically out of the bristle surface and having bristles trimmed to a uniform height hb, which is arranged at a distance db from said second double row in a longitudinal direction of the bristle carrier toward the head part (12), whereby the distance db is preferably 2.5 to 3.5 mm, more preferably 2.7 to 3.3 mm and particularly preferably about 3.0 mm.
- The brush head of claim 6, characterised in that the height hb of the tufts of said inner and outer transverse rows is 9.0 to 11.0 mm, preferably 9.5 to 10.5 mm and more preferably about 10.0 mm.
- The brush head of claim 6 or 7, characterised in that it has an innermost transverse row of tufts projecting vertically out of the bristle surface and having tapered or non-tapered bristles, which is arranged at a distance dc from said first double row in the longitudinal direction of the bristle carrier toward the grip part (11), whereby the distance dc is preferably 5.0 to 6.0 mm, more preferably 5.3 to 5.7 mm and particularly preferably about 5.5 mm, and has an outermost transverse row of tufts projecting vertically out of the bristle surface and having tapered or non-tapered bristles, which is arranged at a distance dd from said second double row in the longitudinal direction of the bristle carrier toward the head part (12), whereby the distance dd is preferably 5.0 to 6.0 mm, more preferably 5.2 to 5.6 mm and particularly preferably about 5.5 mm.
- The brush head of claim 8, characterised in that the bristles of the tufts of said innermost and outermost transverse rows are non-tapered, and the height hcd of the tufts is 10.0 to 12.0 mm and preferably 10.5 to 11.5 mm.
- The brush head of claim 8, characterised in that the bristles of the tufts of said innermost and outermost transverse rows are tapered, and the height hcd of the tufts is 10.5 to 12.5 mm and preferably 11.0 to 12.0 mm.
- The brush head of claim 1, characterised in that it has one double row of tufts crossing over in an x-shaped manner and an inner transverse row of tufts projecting vertically out of the bristle surface with non-tapered bristles, which is arranged at a distance de from said double row in the longitudinal direction of the brush head toward the grip part (11), and has an outer transverse row of tufts projecting vertically out of the bristle surface with non-tapered bristles, which is arranged at a distance df from said double row in the longitudinal direction of the brush head toward the head part (12), whereby the distances de and df are preferably 3.0 to 4.5 mm and more preferably 3.0 to 4.0 mm, and whereby de is particularly preferably about 3.2 mm and df is particularly preferably about 3.1 mm.
- The brush head of claim 11, characterised in that the tufts of said inner and outer transverse rows are trimmed to a uniform height hef of 9.0 to 11.0 mm and preferably 9.0 to 10.0 mm.
- The brush head of claim 11 or 12, characterised in that it has a further inner transverse row of non-tapered tufts projecting vertically out of the bristle surface, which is arranged at a distance dg from said first double row in the longitudinal direction of the bristle carrier toward the grip part (11), and has a further outer transverse row of non-tapered tufts projecting vertically out of the bristle surface, which is arranged at a distance dh from said first double row in the longitudinal direction of the bristle carrier toward the head part (12), whereby the distances dg and dh are preferably 5.0 to 6.5 mm and more preferably 5.5 to 6.0 mm, and dg is particularly preferably about 5.7 mm and dh is particularly preferably about 5.6 mm.
- The brush head of claim 13, characterised in that the tufts of the further inner transverse row and further outer transverse row are trimmed to a uniform height hgh of 10.0 to 12.0 mm and preferably 10.0 to 11.0 mm.
- The brush head of claim 13 or 14, characterised in that it has an innermost transverse row of non-tapered tufts projecting vertically out of the bristle surface, which is arranged at a distance di from said first double row in the longitudinal direction of the bristle carrier toward the grip part (11), and has an outermost transverse row of non-tapered tufts projecting vertically out of the bristle surface, which is arranged at a distance dj from said first double row in the longitudinal direction of the bristle carrier toward the head part (12), whereby the distances di and dj are preferably 7.5 to 9.0 mm and more preferably 8.0 to 8.5 mm, and whereby di is particularly preferably about 8.2 mm and dj about 8.0 mm.
- The brush head of claim 15, characterised in that the tufts of said innermost and outermost transverse rows are trimmed to a uniform height hij of 10.5 to 12.5 mm and preferably 10.5 to 11.5 mm.
- The brush head of one of claims 1 to 16, characterised in that all tapered bristles consist of a poly(C2-C8)alkyleneterephthalate, in particular of polybutyleneterephthalate, and in that all non-tapered bristles consist of a polyamide produced from an unbranched (C2-C8)-1, ω-diamine and an unbranched (C4-C14)-1,ω-dicarboxylic acid, in particular of polyhexamethylenedodecanamide.
- A toothbrush comprising a brush head of one of claims 1 to 17.
Priority Applications (2)
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SI200630614T SI1912532T2 (en) | 2005-08-08 | 2006-08-03 | Toothbrush comprising inclined and pointed bristles |
PL06761256T PL1912532T5 (en) | 2005-08-08 | 2006-08-03 | Toothbrush comprising inclined and pointed bristles |
Applications Claiming Priority (2)
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CH13072005 | 2005-08-08 | ||
PCT/CH2006/000405 WO2007016802A1 (en) | 2005-08-08 | 2006-08-03 | Toothbrush comprising inclined and pointed bristles |
Publications (4)
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EP1912532A1 EP1912532A1 (en) | 2008-04-23 |
EP1912532B1 EP1912532B1 (en) | 2010-01-06 |
EP1912532B2 true EP1912532B2 (en) | 2013-01-09 |
EP1912532B8 EP1912532B8 (en) | 2013-02-20 |
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EP06761256A Active EP1912532B8 (en) | 2005-08-08 | 2006-08-03 | Toothbrush comprising inclined and pointed bristles |
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US (1) | US8239996B2 (en) |
EP (1) | EP1912532B8 (en) |
CN (1) | CN101299943B (en) |
AT (1) | ATE454060T1 (en) |
BR (1) | BRPI0614152B1 (en) |
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RU (1) | RU2401030C2 (en) |
SI (1) | SI1912532T2 (en) |
WO (1) | WO2007016802A1 (en) |
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- 2006-08-03 ES ES06761256T patent/ES2339385T5/en active Active
- 2006-08-03 CN CN2006800291015A patent/CN101299943B/en not_active Expired - Fee Related
- 2006-08-03 US US11/997,951 patent/US8239996B2/en active Active
- 2006-08-03 PL PL06761256T patent/PL1912532T5/en unknown
- 2006-08-03 PT PT06761256T patent/PT1912532E/en unknown
- 2006-08-03 WO PCT/CH2006/000405 patent/WO2007016802A1/en active Application Filing
- 2006-08-03 DE DE502006005864T patent/DE502006005864D1/en active Active
- 2006-08-03 EP EP06761256A patent/EP1912532B8/en active Active
- 2006-08-03 RU RU2008109020/12A patent/RU2401030C2/en not_active IP Right Cessation
- 2006-08-03 BR BRPI0614152-8A patent/BRPI0614152B1/en not_active IP Right Cessation
- 2006-08-03 SI SI200630614T patent/SI1912532T2/en unknown
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- 2006-08-03 DE DE202006020598U patent/DE202006020598U1/en not_active Expired - Lifetime
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WO2004049860A1 (en) † | 2002-12-03 | 2004-06-17 | Young-Jun Kwon | Toothbrush having needle-shaped bristle tapered at one end and manufacturing method thereof |
Also Published As
Publication number | Publication date |
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CN101299943B (en) | 2012-12-05 |
PT1912532E (en) | 2010-04-14 |
CA2618383A1 (en) | 2007-02-15 |
CN101299943A (en) | 2008-11-05 |
PL1912532T3 (en) | 2010-10-29 |
US8239996B2 (en) | 2012-08-14 |
CA2618383C (en) | 2014-04-22 |
EP1912532B8 (en) | 2013-02-20 |
BRPI0614152B1 (en) | 2018-01-09 |
BRPI0614152A2 (en) | 2012-11-20 |
RU2401030C2 (en) | 2010-10-10 |
PL1912532T5 (en) | 2013-09-30 |
WO2007016802A1 (en) | 2007-02-15 |
ATE454060T1 (en) | 2010-01-15 |
ES2339385T5 (en) | 2013-05-06 |
EP1912532B1 (en) | 2010-01-06 |
ES2339385T3 (en) | 2010-05-19 |
EP1912532A1 (en) | 2008-04-23 |
IL188246A (en) | 2011-12-29 |
SI1912532T2 (en) | 2013-06-28 |
IL188246A0 (en) | 2008-04-13 |
DE202006020598U1 (en) | 2009-02-26 |
DE502006005864D1 (en) | 2010-02-25 |
US20080271276A1 (en) | 2008-11-06 |
SI1912532T1 (en) | 2010-09-30 |
RU2008109020A (en) | 2009-10-10 |
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