EP1910087B1 - Printing apparatus for controlling the printing head of a printing cartridge - Google Patents
Printing apparatus for controlling the printing head of a printing cartridge Download PDFInfo
- Publication number
- EP1910087B1 EP1910087B1 EP06761748A EP06761748A EP1910087B1 EP 1910087 B1 EP1910087 B1 EP 1910087B1 EP 06761748 A EP06761748 A EP 06761748A EP 06761748 A EP06761748 A EP 06761748A EP 1910087 B1 EP1910087 B1 EP 1910087B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- signal
- master
- pulses
- address
- printing system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/015—Ink jet characterised by the jet generation process
- B41J2/04—Ink jet characterised by the jet generation process generating single droplets or particles on demand
- B41J2/045—Ink jet characterised by the jet generation process generating single droplets or particles on demand by pressure, e.g. electromechanical transducers
- B41J2/04501—Control methods or devices therefor, e.g. driver circuits, control circuits
- B41J2/04541—Specific driving circuit
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/015—Ink jet characterised by the jet generation process
- B41J2/04—Ink jet characterised by the jet generation process generating single droplets or particles on demand
- B41J2/045—Ink jet characterised by the jet generation process generating single droplets or particles on demand by pressure, e.g. electromechanical transducers
- B41J2/04501—Control methods or devices therefor, e.g. driver circuits, control circuits
- B41J2/04543—Block driving
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/015—Ink jet characterised by the jet generation process
- B41J2/04—Ink jet characterised by the jet generation process generating single droplets or particles on demand
- B41J2/045—Ink jet characterised by the jet generation process generating single droplets or particles on demand by pressure, e.g. electromechanical transducers
- B41J2/04501—Control methods or devices therefor, e.g. driver circuits, control circuits
- B41J2/0458—Control methods or devices therefor, e.g. driver circuits, control circuits controlling heads based on heating elements forming bubbles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/015—Ink jet characterised by the jet generation process
- B41J2/04—Ink jet characterised by the jet generation process generating single droplets or particles on demand
- B41J2/045—Ink jet characterised by the jet generation process generating single droplets or particles on demand by pressure, e.g. electromechanical transducers
- B41J2/04501—Control methods or devices therefor, e.g. driver circuits, control circuits
- B41J2/04588—Control methods or devices therefor, e.g. driver circuits, control circuits using a specific waveform
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/015—Ink jet characterised by the jet generation process
- B41J2/04—Ink jet characterised by the jet generation process generating single droplets or particles on demand
- B41J2/045—Ink jet characterised by the jet generation process generating single droplets or particles on demand by pressure, e.g. electromechanical transducers
- B41J2/04501—Control methods or devices therefor, e.g. driver circuits, control circuits
- B41J2/04591—Width of the driving signal being adjusted
Landscapes
- Particle Formation And Scattering Control In Inkjet Printers (AREA)
- Ink Jet (AREA)
Abstract
Description
Die Erfindung betrifft eine Druckvorrichtung gemäß Oberbegriff des Anspruchs 1.The invention relates to a printing device according to the preamble of claim 1.
Bekannte Drucksysteme verwenden Druckerpatronen, bei denen der Druckkopf in der Druckerpatrone integriert angeordnet ist. Derartige Druckerpatronen sind herkömmlich mit Druckertinte auf Wasserbasis befüllt. Zum Bedrucken nicht saugender Oberflächen, wie Kunststoffoberflächen, Aluminium oder andere Metalloberflächen, sind Druckertinten auf Wasserbasis nicht geeignet, da diese dort nicht wischfest austrocknen. Aufdrucke mit Druckertinte auf Wasserbasis lassen sich von solchen Oberflächen auch noch nach längerer Zeit problemlos mit der Hand abwischen.Known printing systems use printer cartridges in which the print head is integrated in the printer cartridge. Such printer cartridges are conventionally filled with water-based printer ink. For printing non-absorbent surfaces, such as plastic surfaces, aluminum or other metal surfaces, water-based printer inks are not suitable because they do not wipe dry there. Water-based printing inks can be easily wiped off such surfaces even after a long time by hand.
Aus der
Der Erfindung liegt die Aufgabe zugrunde, eine Druckvorrichtung zur Ansteuerung des Druckkopfes von herkömmlichen Druckerpatronen zu schaffen, mit dem gute und insbesondere wischfeste Druckergebnisse zur industriellen Kennzeichnung auch auf nicht saugenden Oberflächen realisierbar sind.The invention has for its object to provide a printing device for controlling the printhead of conventional printer cartridges, with the good and In particular wipe-resistant printing results for industrial marking can also be realized on non-absorbent surfaces.
Die Lösung dieser Aufgabe erhält man durch die im Anspruch 1 angegebenen Merkmale. Bei herkömmlichen Druckerpatronen mit integriertem Druckkopf, die an sich für Drucktinte auf Wasserbasis vorgesehen sind, werden die Heizelemente der Tintenausstoßelemente mit gleichen Spannungswerten für die Spalten- und Zeilensignale der Matrixanordnung angesteuert. Dabei werden die Heizelemente mit relativ hohen und langen Spannungsimpulsen betätigt. Beim Gegenstand der vorliegenden Erfindung ist dagegen vorgesehen, dass die Spaltensignale, die auch als Stammsignale bezeichnet werden können, Stammimpulse haben, die eine geringere Signalamplitude besitzen als die Adressimpulse des Adresssignals, welches als Zeilensignal bezeichnet werden kann. Es wird erfmdungsgemäß also eine Aufteilung der Adresssignale und der Stammsignale vorgesehen, so dass hier mit unterschiedlichen Spannungswerten und vorzugsweise auch mit unterschiedlichen Impulsbreiten die Ansteuerung erfolgen kann. Dadurch wird ein optimales Druckergebnis mit einer Druckertinte mit hohem Alkoholanteil erreicht, wobei als Alkohol vorzugsweise Ethanol verwendet wird.The solution to this problem is obtained by the features specified in claim 1. In conventional integrated printhead ink cartridges, which are themselves water-based inks, the heating elements of the ink ejection elements are driven with equal voltage values for the column and row signals of the matrix array. The heating elements are actuated with relatively high and long voltage pulses. In contrast, in the subject matter of the present invention, it is provided that the column signals, which may also be referred to as master signals, have master pulses which have a lower signal amplitude than the address pulses of the address signal, which may be referred to as a row signal. According to the invention, therefore, a division of the address signals and of the master signals is provided, so that activation can take place here with different voltage values and preferably also with different pulse widths. As a result, an optimal printing result is achieved with a printer ink with a high alcohol content, ethanol preferably being used as the alcohol.
Versuche haben dabei gezeigt, dass durch diese Maßnahme Druckertinte mit hohem Alkoholanteil in diesen herkömmlichen Druckerpatronen mit integriertem Druckkopf Verwendung finden kann und optimale Druckergebnisse erzielt werden können, die auf nicht saugenden Oberflächen bereits unmittelbar nach dem Druck wischfest sind.Experiments have shown that this measure printer ink can be used with high alcohol content in these conventional printer cartridges with built-in printhead and optimal printing results can be achieved that are wiping on non-absorbent surfaces immediately after printing.
Die erfindungsgemäße Ansteuerung der Heizelemente der Tintenausstoßelemente mit geringerer elektrischer Energie berücksichtigt die Tatsache, dass Druckertinte auf Wasserbasis einen höheren Siedepunkt hat, als Druckertinte auf Alkoholbasis.The driving of the heating elements of the lower-energy ink ejection elements according to the present invention takes into consideration the fact that water-based ink is higher in boiling point than the alcohol-based ink.
Vorteilhaft ist es in diesem Zusammenhang, wenn die Signalamplitude der Stammimpulse deutlich niedriger ist als die Signalamplitude der Adressimpulse. So kann die Signalamplitude der Stammimpulse im Bereich zwischen 6 Volt und 9 Volt liegen, während die Adressimpulse etwa eine Signalamplitude von 12 Volt haben. Bei einer Signalamplitude der Stammimpulse im Bereich zwischen 6 Volt und 9 Volt wurden mit Impulsbreiten für die Adressimpulse im Bereich zwischen 1700ns und 2100ns optimale Druckergebnisse auf unterschiedlichen nicht saugenden Oberflächen erzielt. Die Impulsbreite der Stammimpulse lag dabei bei 2800ns.It is advantageous in this context if the signal amplitude of the master pulses is significantly lower than the signal amplitude of the address pulses. Thus, the signal amplitude of the stem pulses in the range between 6 volts and 9 volts while the address pulses have approximately a signal amplitude of 12 volts. With a signal amplitude of the master pulses in the range between 6 volts and 9 volts, pulse widths for the address pulses in the range between 1700 ns and 2100 ns achieved optimum printing results on different non-absorbent surfaces. The pulse width of the stem pulses was 2800ns.
Es kann besonders vorteilhaft sein, die Impulsbreite der Adressimpulse durch eine entsprechende Impulsbreitensteuerung und/oder eine Amplitudensteuerung auf gewünschte Werte zur Anpassung an besondere Anwendungen einstellen zu können.It may be particularly advantageous to be able to set the pulse width of the address pulses to desired values for adaptation to special applications by means of a corresponding pulse width control and / or amplitude control.
Weiterhin wurde festgestellt, dass es für gute Druckergebnisse wesentlich sein kann, dass die Versorgungsspannungen zur Erzeugung der Adressimpulse und der Stammimpulse aus separaten und jeweils geregelten Spannungsquellen abgeleitet werden. Auf diese Weise wird eine gegenseitige Beeinflussung der Signale sicher ausgeschlossen.Furthermore, it has been found that it can be essential for good printing results that the supply voltages for generating the address pulses and the master pulses are derived from separate and respectively regulated voltage sources. In this way, a mutual influence of the signals is safely excluded.
Besonders vorteilhaft ist es, wenn die verwendete Druckerpatrone mit Druckkopf eine herkömmliche Druckerpatrone ist, die an sich für Druckertinte auf Wasserbasis vorgesehen ist. Derartige Druckerpatronen mit integriertem Druckkopf sind sehr betriebssicher und als Massenprodukt entsprechend preiswert in der Anschaffung.It is particularly advantageous if the printer cartridge with printhead used is a conventional printer cartridge, which is itself provided for water-based printer ink. Such printer cartridges with integrated printhead are very reliable and inexpensive as a mass product in the purchase.
Wird eine solche herkömmliche Druckerpatrone verwendet, so kann die erfindungsgemäße Druckvorrichtung ggf auch als eine Anpassungsschnittstelle zwischen einer herkömmlichen Steuerung und den zugehörigen herkömmlichen Druckerpatronen ausgebildet sein.If such a conventional printer cartridge is used, the printing device according to the invention can optionally also be designed as an adaptation interface between a conventional controller and the associated conventional printer cartridges.
Es wird außerdem vorgeschlagen, dass die Druckertinte zur Verwendung in einer Druckerpatrone des erfindungsgemäßen Drucksystems einen Alkoholvolumenanteil von über 70 % hat. Vorzugsweise sind der Druckertinte auf Ethanolbasis ein oder mehrer Additive beigefügt, welche die Verwendung der Druckertinte in einer herkömmlichen Druckerpatrone ermöglichen und/oder die Eigenschaften z.B. bezüglich Untergrundbenetzung, Haftung, Eintrocknungsverhalten der Tinte verbessern.It is also proposed that the printing ink for use in a printing cartridge of the printing system according to the invention has an alcohol volume fraction of more than 70%. Preferably, the ethanol-based printing ink is accompanied by one or more additives which enable the use of the printing ink in a conventional printer cartridge and / or the properties, for example with respect to background wetting, adhesion, drying behavior of the ink.
Die Erfindung wird nachfolgend anhand eines in der Zeichnung dargestellten Ausführungsbeispiels näher erläutert.The invention will be explained in more detail with reference to an embodiment shown in the drawing.
Es zeigen:
-
Figur 1 die Druckvorrichtung in Form eines Blockdiagramms, -
Figur 2 einen Ausschnitt aus einer Matrixanordnung der den Druckkopf bildenden Tintenausstoßelemente und -
Figur 3 eine Darstellung der Adressimpulse und der Stammimpulse.
-
FIG. 1 the printing device in the form of a block diagram, -
FIG. 2 a section of a matrix arrangement of the printhead forming ink ejection elements and -
FIG. 3 a representation of the address pulses and the master pulses.
Der in
Eine derart angesteuerte Druckerpatrone, die mit einer Druckertinte auf Alkoholbasis mit einem Alkoholvolumenanteil von weit über 70 % , vorzugsweise im Bereich zwischen 80% und 95%, befüllt ist, ist zum Bedrucken nicht saugender Oberflächen sehr gut geeignet, wobei selbstverständlich auch saugende Oberflächen problemlos bedruckt werden können.Such a controlled printer cartridge, which is filled with an alcohol-based ink with an alcohol volume fraction of well over 70%, preferably in the range between 80% and 95%, is very well suited for printing non-absorbent surfaces, of course, printed on absorbing surfaces easily can be.
Eine Spannungsreduzierung der Einzelimpulse des Stammsignals in Verbindung mit einem nur in der Impulsbreite reduzierten Adresssignal hat die besten wischfesten Druckergebnisse erbracht.A voltage reduction of the individual pulses of the master signal in conjunction with an address signal reduced only in the pulse width has yielded the best smear-resistant printing results.
Die Matrixanordnung von
Um beispielsweise das oben links dargestellte Heizelement R1 für einen Tintenausstoß anzusteuern, ist es erforderlich, dass der Stammleitung SS21 und der Adressleitung AS 11 jeweils ein Stammsignal SS2 mit geringerer Spannung und ein Adresssignal AS 1 mit geringerer Impulsbreite gleichzeitig zugeführt werden, wobei zu gewährleisten ist, dass der Adressimpuls innerhalb des größeren Zeitfensters des zugehörigen Stammimpulses des Stammsignals SS2 am Feldeffekttransistor FT1 anliegt.For example, in order to drive the heating element R1 shown at the top left for ink ejection, it is necessary to simultaneously supply a master signal SS2 with a lower voltage and an address signal AS1 with a smaller pulse width to the master line SS21 and the address line AS11, it being necessary to ensure the address pulse is applied to the field effect transistor FT1 within the larger time window of the associated master pulse of the master signal SS2.
Je nach Beschaffenheit der verwendeten Druckertinte kann eine individuelle Einstellung der Impulsbreiten und der Impulsspannungen zweckmäßig sein.Depending on the nature of the printer ink used, an individual adjustment of the pulse widths and the pulse voltages may be expedient.
In
Claims (14)
- Printing system having a conventional printer cartridge (5) for triggering the print head of the printer cartridge (5),
which is intended per se for water-based printing ink, and whose printer head has ink ejector elements arranged in a matrix, wherein the printing ink in the printer cartridge (5) has a proportion of alcohol and the particular heating element to be actuated of an ink ejector element is activated by means of an address signal functioning as line signal and by means of a master signal functioning as a column signal
characterised in that
the master pulses of the master signal (SS2) have a lesser signal amplitude than the address pulses of the address signal (AS1). - Printing system as defined by claim 1, characterised in that
the address pulses of the address signal (AS1) have a lesser pulse width than the master pulses of the master signal (SS2). - Printing system as defined by claim 1, characterised in that
the master pulses of the master signal (SS2) have a lesser pulse width than the address pulses of the address signal (AS1). - Printing system as defined by one of the claims 1 or 2, characterised in that
the address pulses of the address signal (AS1) have a pulse width in the range between 1700ns and 2100ns, wherein master pulses of the master signal (SS2) have a pulse width of approximately 2800ns. - Printing system as defined by one of the foregoing claims, characterised in that
the signal amplitude of the master pulses is in the range 6 Volts and 9 Volts. - Printing system as defined by one of the foregoing claims , characterized in that
the signal amplitude of the address signal (AS1) is approximately 12 Volts. - Printing system as defined by one of the foregoing claims, characterised in that
the pulse width and/or the signal amplitude of the master pulses and/or address pulses is individually adjustable. - Printing system as defined by one of the foregoing claims, characterised in that
the address signals (AS1) on the one hand and the master signals on the other are generated by means of separate, regulated supply voltages. - Printing system as defined by one of the foregoing claims, characterised in that
the printing system acts as an adapting interface between a conventional print head controler and the associated conventional printer cartridges (5) with integrated print heads, and it includes signal regulators (SR1, SR2) for varying the mastes pulses and/or adress pulses. - Printing system as defined by one of the foregoing claims, characterised in that
the printing ink has a volumetric proportion of alcohol of over 70%. - Printing system as defined by one of the foregoing claims, characterised in that
the alcohol base of the printing ink comprise one, two, or more different types of alcohol. - Printing system as defined by one of the foregoing claims, characterised in that
one or more additives, which makes it possible to use the printing ink in a conventional printer cartridge and/or improve the properties, for instance with regard to background moistening, adhesion, and drying performance of the ink, are added to the printing ink. - Printing system as defined by one of the foregoing claims, characterised in that
the alcohol-based printing ink contains dye or pigment and binders. - Printing system as defined by one of the foregoing claims, characterised in that
the printing ink contains ethanol as the alcohol.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005030778 | 2005-07-01 | ||
PCT/DE2006/001146 WO2007003174A1 (en) | 2005-07-01 | 2006-06-30 | Printing system for controlling the printing head of a printing cartridge |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1910087A1 EP1910087A1 (en) | 2008-04-16 |
EP1910087B1 true EP1910087B1 (en) | 2010-06-23 |
Family
ID=37076045
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06761748A Not-in-force EP1910087B1 (en) | 2005-07-01 | 2006-06-30 | Printing apparatus for controlling the printing head of a printing cartridge |
Country Status (8)
Country | Link |
---|---|
US (1) | US7794033B2 (en) |
EP (1) | EP1910087B1 (en) |
JP (1) | JP4987863B2 (en) |
AT (1) | ATE471821T1 (en) |
DE (1) | DE502006007269D1 (en) |
ES (1) | ES2350421T3 (en) |
PT (1) | PT1910087E (en) |
WO (1) | WO2007003174A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8142558B2 (en) * | 2008-03-31 | 2012-03-27 | Videojet Technologies Inc. | Thermal ink jet ink composition |
US8142559B2 (en) | 2008-03-31 | 2012-03-27 | Casey Robertson | Thermal ink jet ink composition |
US8778074B2 (en) * | 2009-07-20 | 2014-07-15 | Markem-Imaje Corporation | Solvent-based inkjet ink formulations |
WO2011041364A1 (en) | 2009-09-30 | 2011-04-07 | Videojet Technologies Inc. | Thermal ink jet ink composition |
WO2011041368A1 (en) | 2009-09-30 | 2011-04-07 | Videojet Technologies Inc. | Thermal ink jet ink composition |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5874974A (en) * | 1992-04-02 | 1999-02-23 | Hewlett-Packard Company | Reliable high performance drop generator for an inkjet printhead |
US5635968A (en) * | 1994-04-29 | 1997-06-03 | Hewlett-Packard Company | Thermal inkjet printer printhead with offset heater resistors |
US6439697B1 (en) * | 1999-07-30 | 2002-08-27 | Hewlett-Packard Company | Dynamic memory based firing cell of thermal ink jet printhead |
TW514604B (en) * | 2001-08-10 | 2002-12-21 | Int United Technology Co Ltd | Recognition circuit for an ink jet printer |
US20030142159A1 (en) | 2002-01-31 | 2003-07-31 | Askeland Ronald A. | Estimating local ejection chamber temperature to improve printhead performance |
US6908186B2 (en) * | 2003-03-26 | 2005-06-21 | Eastman Kodak Company | Inkjet ink composition and an ink/receiver combination |
JP2005007594A (en) * | 2003-06-16 | 2005-01-13 | Canon Inc | Recording head and its element substrate |
-
2006
- 2006-06-30 DE DE502006007269T patent/DE502006007269D1/en active Active
- 2006-06-30 WO PCT/DE2006/001146 patent/WO2007003174A1/en active Application Filing
- 2006-06-30 US US11/917,858 patent/US7794033B2/en not_active Expired - Fee Related
- 2006-06-30 PT PT06761748T patent/PT1910087E/en unknown
- 2006-06-30 ES ES06761748T patent/ES2350421T3/en active Active
- 2006-06-30 AT AT06761748T patent/ATE471821T1/en active
- 2006-06-30 JP JP2008518621A patent/JP4987863B2/en not_active Expired - Fee Related
- 2006-06-30 EP EP06761748A patent/EP1910087B1/en not_active Not-in-force
Also Published As
Publication number | Publication date |
---|---|
EP1910087A1 (en) | 2008-04-16 |
DE502006007269D1 (en) | 2010-08-05 |
PT1910087E (en) | 2010-09-24 |
US20080198190A1 (en) | 2008-08-21 |
US7794033B2 (en) | 2010-09-14 |
ES2350421T3 (en) | 2011-01-21 |
JP2008544880A (en) | 2008-12-11 |
WO2007003174A1 (en) | 2007-01-11 |
JP4987863B2 (en) | 2012-07-25 |
ATE471821T1 (en) | 2010-07-15 |
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