EP1903127A1 - Process of manufacturing of workpieces by cold gas spraying and turbine workpiece - Google Patents

Process of manufacturing of workpieces by cold gas spraying and turbine workpiece Download PDF

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Publication number
EP1903127A1
EP1903127A1 EP06090174A EP06090174A EP1903127A1 EP 1903127 A1 EP1903127 A1 EP 1903127A1 EP 06090174 A EP06090174 A EP 06090174A EP 06090174 A EP06090174 A EP 06090174A EP 1903127 A1 EP1903127 A1 EP 1903127A1
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EP
European Patent Office
Prior art keywords
base material
core
component
turbine component
sprayed onto
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06090174A
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German (de)
French (fr)
Inventor
Rene Jabado
Jens Dahl Dr. Jensen
Ursus Dr. Krüger
Daniel Körtvelyessy
Volkmar Dr. Lüthen
Ralph Reiche
Michael Rindler
Raymond Ullrich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Priority to EP06090174A priority Critical patent/EP1903127A1/en
Publication of EP1903127A1 publication Critical patent/EP1903127A1/en
Withdrawn legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D23/00Casting processes not provided for in groups B22D1/00 - B22D21/00
    • B22D23/003Moulding by spraying metal on a surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/009Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of turbine components other than turbine blades
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/06Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
    • B22F7/08Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools with one or more parts not made from powder
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/02Coating starting from inorganic powder by application of pressure only
    • C23C24/04Impact or kinetic deposition of particles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D5/00Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
    • F01D5/12Blades
    • F01D5/28Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
    • F01D5/284Selection of ceramic materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D5/00Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
    • F01D5/12Blades
    • F01D5/28Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
    • F01D5/288Protective coatings for blades
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2230/00Manufacture
    • F05D2230/30Manufacture with deposition of material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2230/00Manufacture
    • F05D2230/30Manufacture with deposition of material
    • F05D2230/31Layer deposition
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2230/00Manufacture
    • F05D2230/90Coating; Surface treatment
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2260/00Function
    • F05D2260/95Preventing corrosion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2300/00Materials; Properties thereof
    • F05D2300/20Oxide or non-oxide ceramics
    • F05D2300/21Oxide ceramics
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05DINDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
    • F05D2300/00Materials; Properties thereof
    • F05D2300/60Properties or characteristics given to material by treatment or manufacturing
    • F05D2300/611Coating

Definitions

  • the invention relates to a method for producing components, in particular turbine components.
  • Turbine components today typically consist of a base body on which a layer system is often still applied.
  • a method for producing a layer system is for example EP 1 382 707 A1 known.
  • an intermediate layer and a thermal barrier coating are applied to a substrate by atmospheric plasma spraying or cold gas spraying.
  • the substrate which forms the base body here is, for example, a nickel- or cobalt-based superalloy.
  • the intermediate layer serves as a corrosion, oxidation, or adhesion-promoting layer and consists, for example, of MCrAlY, where M is an element of the group iron (Fe), cobalt (Co) or nickel (Ni).
  • the thermal barrier coating is, for example, ceramic and consists, for example, of partially or fully stabilized zirconium oxide with up to 8% yttrium oxide or other rare earth oxides.
  • the layer system described can be used in particular in turbine blades.
  • Turbine blades and other turbine components are cast from the nickel or cobalt based superalloys and then coated. This requires several process steps and offers only a small degree of flexibility, since the casting molds have to be changed to change the component geometry. In addition, due to the high temperatures during casting, oxidation processes can occur on the superalloy material, so that it is not always possible to achieve the theoretically possible optimum result.
  • the invention has for its object to provide a method for the manufacture of components, in particular of turbine components, available, in which the above-mentioned problem does not occur.
  • Another object is to provide a turbine component with improved component properties.
  • the object is achieved in a method for producing components which consist of a base material in which powdered base material is sprayed onto a core by means of a cold gas spraying process and the spraying is carried out in such a way that the contour of the component is worked out during spraying.
  • components consisting of a base material for example turbine components such as blades or transition pieces
  • turbine components such as blades or transition pieces
  • inert gas eg helium or nitrogen
  • the spray parameters such. Particle velocity or mass flow can be varied.
  • the powder parameters e.g. the powder composition can be varied. This makes it possible to produce layered components and components with varying material properties (e.g., graded material composition).
  • a porous region may be formed as a porous layer. This can form the surface of the component, but it can also be arranged between two dense layers.
  • a heat-insulating material may be sprayed onto the base material to provide better protection against high temperatures.
  • the heat-insulating material can either be designed so that it forms a porous layer after spraying, or so that it forms a dense layer after spraying. Porosity can improve the thermal insulation properties of the layer.
  • a corrosion- and / or oxidation-inhibiting material can be sprayed on between the base material and the heat-insulating material, so that additional protection of the base material against corrosion and / or oxidation is ensured.
  • a corrosion and / or oxidation-inhibiting material for example, a MCrAlX material can be used.
  • MCrAlX M stands for at least one element of the group iron, cobalt or nickel and X for an active element such as yttrium (Y) and / or silicon (Si) and / or at least one element of the rare earths or hafnium (Hf).
  • Such alloys are, for example, from EP 0 486 489 B1 .
  • EP 0 412 397 B1 or EP 1 306 454 A1 known.
  • the corrosion and / or oxidation-inhibiting material can also be added as sacrificial anodes acting particles.
  • a base material in particular a superalloy on nickel, cobalt or iron base can be sprayed, which is a high-temperature resistant material.
  • a ceramic material can be sprayed as a base material, which offers a high corrosion and temperature resistance. It may then be possible to dispense with corrosion-inhibiting / oxidation-inhibiting coatings and thermal barrier coatings altogether.
  • a ceramic core for example, can be used, which can be rinsed after completion of the component by means of a strong acid, such as hydrofluoric acid.
  • a strong acid such as hydrofluoric acid.
  • HASTELLOY ® C-2000 or INCONEL ® Super alloys are resistant to strong acids such as sulfurous acid, hydrochloric acid or hydrofluoric acid.
  • a further advantageous development consists in a turbine component which is produced by the method according to the invention and comprises a material which has regions of different porosity.
  • the areas of different porosity may possibly serve for the passage of cooling air.
  • the material of the turbine component with the regions of different porosity can be coating material, ie the regions of different porosity are present in a coating. But it is also possible that the material is present with the areas of different porosity base material. In other words, the regions of different porosity are already present in the uncoated turbine component. Of course, also base materials with areas different porosity mut coatings, which have areas of different porosity combined.
  • FIG. 1 schematically shows the production of a turbine component 28 by a method according to the invention.
  • Base material 24 is sprayed onto a ceramic core 26 by a cold gas spray nozzle 22.
  • the spray parameters can be varied, in particular the mass flow, the particle velocity, the particle size and the particle composition.
  • the particle size determines the porosity properties of the sprayed base material.
  • the turbine component is formed by the relative movement between the ceramic core 26 and spray nozzle 22.
  • the base material is sprayed, for example, a Ni, Co or Fe based superalloy.
  • Suitable superalloys are e.g., those known under the designations HASTELLOY ® or INCONEL ® superalloys.
  • the composition of the spray powder is, for example, changed to a MCrAlX composition and a primer layer (not shown in Fig. 1) applied to the base material.
  • a further change in the composition of the spray powder for example to Y-stabilized zirconium oxide (ZrO 2 )
  • ZrO 2 Y-stabilized zirconium oxide
  • a thermal thermal barrier coating is finally sprayed onto the MCrAlX layer.
  • the ceramic core 26 is leached, for example by hydrofluoric acid (HF).
  • HF hydrofluoric acid
  • the leaching of the ceramic core 26 can be carried out either after the completion of the turbine component or after the spraying of the base material, but before completion of the entire turbine component 28, for example, before the application of a coating.
  • the advantage of premature leaching is that it can avoid possible damage to a ceramic coating (eg, ceramic thermal barrier coating, TBC) during the leaching process.
  • a ceramic material is sprayed as a base material for the turbine component 28 instead of a superalloy.
  • the core may, for example, consist of a burn-out material.
  • the material of the core should be chosen so that removal of the core is possible without attacking the ceramic base material.
  • FIG. 2 shows a perspective view of a blade 12 as an example of a component made by cold gas spraying on a core which is leached.
  • the rotor blade 12 has a fastening region 14, a blade platform 18 and an airfoil region 16.
  • a blade root 20 is formed, which is for fastening the blade 12 to a shaft of a turbomachine, also not shown, in particular a gas turbine.
  • the turbine blade 12, particularly in its airfoil region 16, has a complex geometry which can be produced by a method according to the invention, with a high degree of flexibility with respect to changes in the geometry of the rotor blade.
  • a section through the wall of a turbine component 28 according to a first embodiment variant is shown in highly schematic form in FIG.
  • a core 26 is a applied by cold gas spraying dense layer 2, which consists of a base material and forms the inside of the component wall.
  • the dense layer 2 may consist of a superalloy or of a ceramic material as the base material.
  • the core 26 may be made in a superalloy as a dense layer 2, for example. Made of ceramic.
  • the pores 7 of the porous layer 3 can be traversed by a cooling air flow 5, which serves to cool the turbine component 28.
  • the size of the pores can be adjusted by choosing the size of the spattered particles.
  • this dense layer 4 is also applied by cold gas spraying.
  • This dense layer 4 may be wholly or partly made of a thermally insulating or of a corrosion and / or oxidation-inhibiting material, such as e.g. MCrA1X exist.
  • a part of the dense layer 4 can also form the outer surface of the turbine component 28 as a thermal barrier coating (TBC). It is also possible to spray the thermal barrier coating directly onto the base material.
  • FIG. 4 shows a schematic cross section through a turbine component 28, for example a turbine blade, with a central one Air duct 6, which consists of a dense portion 8 and a porous portion 10 with pores 7.
  • the central air channel is created by leaching the ceramic core after spraying the base material.
  • a cooling air flow 5 flows in through the central air duct 6 and out through the pores 7 of the porous section 10, thus cooling the porous section 10.
  • the two sections are as well as the dense layers 2 and 4 and the porous layer 3 in FIG Cold gas spraying made.
  • Porous sections are preferably formed where the thermal loading of the turbine component 28 is greatest. By suitable position of the porous sections in the turbine component 28 and by suitable shaping and dimensioning of these sections, the generation of cooling air films over the outer surface of the turbine component 28 can also be achieved.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Composite Materials (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)

Abstract

Production of a turbine component (28) comprises spraying a powdered base material (24) onto a core (26) using cold gas spraying so that the contour of the component is produced during the spraying operation. An independent claim is also included for a turbine component produced by the above process.

Description

Hintergrund der ErfindungBackground of the invention

Die Erfindung betrifft ein Verfahren zum Herstellen von Bauteilen, insbesondere Turbinenbauteilen.The invention relates to a method for producing components, in particular turbine components.

Turbinenbauteile bestehen heutzutage typischerweise aus einem Grundkörper, auf dem häufig noch ein Schichtsystem aufgebracht ist. Ein Verfahren zum Herstellen eines Schichtsystems ist beispielsweise aus EP 1 382 707 A1 bekannt. Bei diesem Verfahren werden eine Zwischenschicht und eine Wärmedämmschicht durch atmosphärisches Plasmaspritzen oder durch Kaltgasspritzen auf ein Substrat aufgebracht. Das Substrat, das hier den Grundkörper bildet, ist bspw. eine nickel- oder kobaltbasierte Superlegierung. Die Zwischenschicht dient als Korrosions-, Oxidations-, oder Haftvermittlungsschicht und besteht bspw. aus MCrAlY, wobei M ein Element der Gruppe Eisen (Fe), Kobalt (Co) oder Nickel (Ni) ist. Die Wärmedämmschicht ist beispielsweise keramisch und besteht bspw. aus teil- oder vollstabilisiertem Zirkonoxid mit bis zu 8% Yttriumoxid oder anderen Seltenerdoxiden. Das beschriebene Schichtsystem kann insbesondere bei Turbinenschaufeln Verwendung finden.Turbine components today typically consist of a base body on which a layer system is often still applied. A method for producing a layer system is for example EP 1 382 707 A1 known. In this method, an intermediate layer and a thermal barrier coating are applied to a substrate by atmospheric plasma spraying or cold gas spraying. The substrate which forms the base body here is, for example, a nickel- or cobalt-based superalloy. The intermediate layer serves as a corrosion, oxidation, or adhesion-promoting layer and consists, for example, of MCrAlY, where M is an element of the group iron (Fe), cobalt (Co) or nickel (Ni). The thermal barrier coating is, for example, ceramic and consists, for example, of partially or fully stabilized zirconium oxide with up to 8% yttrium oxide or other rare earth oxides. The layer system described can be used in particular in turbine blades.

Turbinenschaufeln und andere Turbinenkomponenten wie bspw. Übergangsstücke werden aus den nickel- oder kobaltbasierten Superlegierungen gegossen und anschließend beschichtet. Dies erfordert mehrere Verfahrensschritte und bietet nur einen geringen Grad an Flexibilität, da für eine Änderung der Komponentengeometrie die Gießformen zu ändern sind. Zusätzlich können auf Grund der hohen Temperaturen beim Gießen Oxidationsprozesse am Superlegierungsmaterial auftreten, so dass sich nicht immer das theoretisch mögliche optimale Ergebnis erzielen lässt.Turbine blades and other turbine components, such as adapters, are cast from the nickel or cobalt based superalloys and then coated. This requires several process steps and offers only a small degree of flexibility, since the casting molds have to be changed to change the component geometry. In addition, due to the high temperatures during casting, oxidation processes can occur on the superalloy material, so that it is not always possible to achieve the theoretically possible optimum result.

Zugrundeliegende AufgabeUnderlying task

Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren zum Herstellen von Bauteilen, insbesondere von Turbinenbauteilen, zur Verfügung zu stellen, bei dem die oben genannte Problematik nicht auftritt.The invention has for its object to provide a method for the manufacture of components, in particular of turbine components, available, in which the above-mentioned problem does not occur.

Eine weitere Aufgabe besteht darin, ein Turbinenbauteil mit verbesserten Bauteileigenschaften zur Verfügung zu stellen.Another object is to provide a turbine component with improved component properties.

Erfindungsgemäße LösungInventive solution

Diese Aufgaben werden erfindungsgemäß durch ein Verfahren mit den Merkmalen des Anspruchs 1 bzw. durch ein Turbinenbauteil nach Anspruch 13 gelöst. Die abhängigen Ansprüche enthalten vorteilhafte Weiterbildungen der Erfindung.These objects are achieved by a method with the features of claim 1 and by a turbine component according to claim 13. The dependent claims contain advantageous developments of the invention.

Erfindungsgemäß besteht die Lösung der Aufgabe in einem Verfahren zum Herstellen von Bauteilen, welche aus einem Grundwerkstoff bestehen, in dem pulverförmiger Grundwerkstoff mittels eines Kaltgasspritzverfahrens auf einen Kern aufgespritzt wird und das Spritzen so erfolgt, dass während des Spritzens die Kontur des Bauteils herausgearbeitet wird.According to the invention, the object is achieved in a method for producing components which consist of a base material in which powdered base material is sprayed onto a core by means of a cold gas spraying process and the spraying is carried out in such a way that the contour of the component is worked out during spraying.

Dadurch können aus einem Grundwerkstoff bestehende Bauteile, bspw. Turbinenbauteile wie etwa Schaufeln oder Übergangsstücke, mit komplexen Strukturen hergestellt werden, und es ist kein sonst zur Herstellung von Turbinenbauteilen eingesetzter aufwendiger Gussvorgang mehr nötig. Aufgrund der Verwendung von Inertgas (bspw. Helium oder Stickstoff) als Treibgas beim Kaltgasspritzen kann die Oxidation des Grundwerkstoffes vermieden werden.As a result, components consisting of a base material, for example turbine components such as blades or transition pieces, can be manufactured with complex structures, and there is no longer any need for a complex casting operation otherwise used for the production of turbine components. Due to the use of inert gas (eg helium or nitrogen) as a propellant in cold gas spraying, the oxidation of the base material can be avoided.

Bei einer vorteilhaften Weiterbildung der Erfindung ist das Herausarbeiten der Kontur durch Verwendung eines konturierten Kerns vereinfacht.In an advantageous embodiment of the invention, the working out of the contour by using a contoured core is simplified.

Eine andere vorteilhafte Weiterbildung besteht darin, dass auch während des Spritzvorgangs die Spritzparameter wie z.B. Partikelgeschwindigkeit oder Massenstrom variiert werden können. Außerdem können die Pulverparameter, z.B. die Pulverzusammensetzung, variiert werden. Dadurch wird das Herstellen von geschichteten Bauteilen und von Bauteilen mit variierenden Materialeigenschaften (z.B. gradierte Werkstoffzusammensetzung) möglich.Another advantageous development is that even during the injection process, the spray parameters such. Particle velocity or mass flow can be varied. In addition, the powder parameters, e.g. the powder composition can be varied. This makes it possible to produce layered components and components with varying material properties (e.g., graded material composition).

Es kann auch die Partikelgröße im pulverförmigen Werkstoff variiert werden. Dies ermöglicht das Herstellen von Bauteilen, die Bereiche mit unterschiedlicher Porosität aufweisen. So können beispielsweise Turbinenschaufeln mit porösen Bereichen erzeugt werden. Insbesondere kann ein poröser Bereich als poröse Schicht ausgebildet sein. Diese kann die Oberfläche des Bauteils bilden, sie kann aber auch zwischen zwei dichten Schichten angeordnet werden.It is also possible to vary the particle size in the powdery material. This makes it possible to produce components having regions with different porosity. For example, turbine blades with porous regions can be produced. In particular, a porous region may be formed as a porous layer. This can form the surface of the component, but it can also be arranged between two dense layers.

Zusätzlich dazu kann nach dem Aufspritzen des Grundwerkstoffs auf den Kern ein wärmedämmender Werkstoff auf dem Grundwerkstoff aufgespritzt werden, um einen besseren Schutz gegen hohe Temperaturen zu gewährleisten. Der wärmedämmender Werkstoff kann entweder so ausgestaltet sein, dass er nach dem Aufspritzen eine poröse Schicht bildet, oder so, dass er nach dem Aufspritzen eine dichte Schicht bildet. Durch eine Porosität können die Wärmeisolationseigenschaften der Schicht verbessert werden.Additionally, after spraying the base material onto the core, a heat-insulating material may be sprayed onto the base material to provide better protection against high temperatures. The heat-insulating material can either be designed so that it forms a porous layer after spraying, or so that it forms a dense layer after spraying. Porosity can improve the thermal insulation properties of the layer.

Optional kann zwischen dem Grundwerkstoff und dem wärmedämmenden Werkstoff ein korrosions- und/oder oxidationshemmender Werkstoff aufgespritzt werden, so dass ein zusätzlicher Schutz des Grundwerkstoffs gegen Korrosion und/oder Oxidation gewährleistet wird.Optionally, a corrosion- and / or oxidation-inhibiting material can be sprayed on between the base material and the heat-insulating material, so that additional protection of the base material against corrosion and / or oxidation is ensured.

Als korrosions- und/oder oxidationshemmender Werkstoff kann z.B. ein MCrAlX-Werkstoff verwendet werden. In MCrAlX steht M für zumindest ein Element der Gruppe Eisen, Kobalt oder Nickel und X für ein Aktivelement wie Yttrium (Y) und/oder Silizium (Si) und/oder zumindest ein Element der Seltenen Erden bzw. Hafnium (Hf). Solche Legierungen sind bspw. aus EP 0 486 489 B1 , EP 0 786 017 B1 , EP 0 412 397 B1 oder EP 1 306 454 A1 bekannt. Dem korrosions- und/oder oxidationshemmenden Werkstoff können auch als Opferanoden fungierende Partikel zugesetzt werden.As a corrosion and / or oxidation-inhibiting material, for example, a MCrAlX material can be used. In MCrAlX M stands for at least one element of the group iron, cobalt or nickel and X for an active element such as yttrium (Y) and / or silicon (Si) and / or at least one element of the rare earths or hafnium (Hf). Such alloys are, for example, from EP 0 486 489 B1 . EP 0 786 017 B1 . EP 0 412 397 B1 or EP 1 306 454 A1 known. The corrosion and / or oxidation-inhibiting material can also be added as sacrificial anodes acting particles.

Als Grundwerkstoff kann insbesondere eine Superlegierung auf Nickel-, Kobalt- oder Eisenbasis verspritzt werden, die einen hochwarmfesten Werkstoff darstellt. Alternativ kann aber auch ein Keramikwerkstoff als Grundwerkstoff verspritzt werden, der eine hohe Korrosions- und Temperaturfestigkeit bietet. Auf korrosionshemmende/oxidationshemmende Beschichtungen und auf Wärmedämmbeschichtungen kann dann eventuell ganz verzichtet werden.As a base material, in particular a superalloy on nickel, cobalt or iron base can be sprayed, which is a high-temperature resistant material. Alternatively, however, a ceramic material can be sprayed as a base material, which offers a high corrosion and temperature resistance. It may then be possible to dispense with corrosion-inhibiting / oxidation-inhibiting coatings and thermal barrier coatings altogether.

Als Kern kann bspw. ein Keramikkern Verwendung finden, der nach dem Fertigstellen des Bauteils mittels einer starken Säure, etwa mittels Flusssäure, ausgespült werden kann. Bspw. die unter dem Namen HASTELLOY® C-2000 oder INCONEL® bekannte Superlegierungen sind gegenüber starken Säuren wie schwefelhaltige Säure, Salzsäure oder Flusssäure resistent.As a core, for example, a ceramic core can be used, which can be rinsed after completion of the component by means of a strong acid, such as hydrofluoric acid. For example. known under the name HASTELLOY ® C-2000 or INCONEL ® Super alloys are resistant to strong acids such as sulfurous acid, hydrochloric acid or hydrofluoric acid.

Eine weitere vorteilhafte Weiterbildung besteht in einem Turbinenbauteil, welches nach dem erfindungsgemäßen Verfahren hergestellt ist und einen Werkstoff umfasst, welcher Bereiche unterschiedlicher Porosität besitzt. Die Bereiche unterschiedlicher Porosität können eventuell zur Durchleitung von Kühlluft dienen.A further advantageous development consists in a turbine component which is produced by the method according to the invention and comprises a material which has regions of different porosity. The areas of different porosity may possibly serve for the passage of cooling air.

Der Werkstoff des Turbinenbauteils mit den Bereichen unterschiedlicher Porosität kann Beschichtungswerkstoff sein, d.h. die Bereiche unterschiedlicher Porosität liegen in einer Beschichtung vor. Es ist aber auch möglich, dass als Werkstoff mit den Bereichen unterschiedlicher Porosität Grundwerkstoff vorhanden ist. Mit anderen Worten, die Bereiche unterschiedlicher Porosität sind bereits im unbeschichteten Turbinenbauteil vorhanden. Natürlich können auch Grundwerkstoffe mit Bereichen unterschiedlicher Porosität mut Beschichtungen, welche Bereiche unterschiedlicher Porosität aufweisen, kombiniert werden.The material of the turbine component with the regions of different porosity can be coating material, ie the regions of different porosity are present in a coating. But it is also possible that the material is present with the areas of different porosity base material. In other words, the regions of different porosity are already present in the uncoated turbine component. Of course, also base materials with areas different porosity mut coatings, which have areas of different porosity combined.

Kurzbeschreibung der ZeichnungenBrief description of the drawings

Weitere Merkmale, Eigenschaften und Vorteile der Erfindung ergeben sich aus der nachfolgenden Beschreibung von Ausführungsbeispielen unter Bezugnahme auf die beiliegenden Figuren. Es zeigt:

Fig. 1
einen Querschnitt durch ein Turbinenbauteil mit Kern während der Herstellung.
Fig. 2
ein Turbinenbauteil, das nach dem erfindungsgemäßen Verfahren hergestellt ist.
Fig. 3
eine Beschichtung eines Turbinenbauteils, das nach dem erfindungsgemäßen Verfahren hergestellt ist, und bei dem sich eine poröse Schicht zwischen zwei dichten Schichten befindet.
Fig. 4
ein Turbinenbauteil, das nach dem erfindungsgemäßen Verfahren hergestellt ist, und bei dem ein poröser Abschnitt an einen dichten Abschnitt angrenzt.
Further features, properties and advantages of the invention will become apparent from the following description of embodiments with reference to the accompanying figures. It shows:
Fig. 1
a cross section through a turbine component with core during manufacture.
Fig. 2
a turbine component, which is produced by the method according to the invention.
Fig. 3
a coating of a turbine component made by the method of the invention and having a porous layer between two dense layers.
Fig. 4
a turbine component made according to the method of the invention, wherein a porous portion is adjacent to a dense portion.

Detaillierte Beschreibung des AusführungsbeispielsDetailed description of the embodiment

In Figur 1 ist die Herstellung eines Turbinenbauteiles 28 durch ein erfindungsgemäßes Verfahren schematisch dargestellt. Grundwerkstoff 24 wird durch eine Kaltgasspritzdüse 22 auf einen Keramikkern 26 aufgespritzt. Die Spritzparameter können variiert werden, insbesondere der Massenstrom, die Partikelgeschwindigkeit, die Partikelgröße und die Partikelzusammensetzung. Die Partikelgröße bestimmt dabei die Porositätseigenschaften des aufgespritzten Grundwerkstoffes.FIG. 1 schematically shows the production of a turbine component 28 by a method according to the invention. Base material 24 is sprayed onto a ceramic core 26 by a cold gas spray nozzle 22. The spray parameters can be varied, in particular the mass flow, the particle velocity, the particle size and the particle composition. The particle size determines the porosity properties of the sprayed base material.

Das Turbinenbauteil entsteht durch die Relativbewegung zwischen Keramikkern 26 und Spritzdüse 22. Zuerst wird das Grundwerkstoffmaterial verspritzt, bspw. eine Superlegierung auf Ni-, Co- oder Fe-Basis. Geeignete Superlegierungen sind bspw. die unter den Bezeichnungen HASTELLOY® oder INCONEL® bekannten Superlegierungen.The turbine component is formed by the relative movement between the ceramic core 26 and spray nozzle 22. First, the base material is sprayed, for example, a Ni, Co or Fe based superalloy. Suitable superalloys are e.g., those known under the designations HASTELLOY ® or INCONEL ® superalloys.

Danach wird die Zusammensetzung des Spritzpulvers bspw. zu einer MCrAlX-Zusammensetzung geändert und eine Haftvermittlerschicht (in Fig. 1 nicht gezeigt) auf den Grundwerkstoff aufgebracht. Nach einer neuerlichen Änderung der Zusammensetzung des Spritzpulvers, bspw. zu mit Y stabilisiertemZirkonoxid (ZrO2) wird schließlich eine thermische Wärmedämmschicht auf die MCrA1X-Schicht aufgespritzt. Nach dem Spritzen des Turbinenbauteils 28 wird der Keramikkern 26 ausgelaugt, bspw. durch Flusssäure (HF). Das Auslaugen des Keramikkerns 26 kann entweder nach der Fertigstellung des Turbinenbauteils oder nach dem Aufspritzen des Grundwerkstoffs, aber vor Fertigstellen des gesamten Turbinenbauteils 28, z.B. vor dem Aufbringen einer Beschichtung, erfolgen. Der Vorteil des frühzeitigen Auslaugens besteht darin, dass dadurch eine eventuelle Beschädigung einer keramischen Beschichtung (z.B. keramische Wärmedämmschicht, TBC) während des Auslaugprozesses vermieden werden kann.Thereafter, the composition of the spray powder is, for example, changed to a MCrAlX composition and a primer layer (not shown in Fig. 1) applied to the base material. After a further change in the composition of the spray powder, for example to Y-stabilized zirconium oxide (ZrO 2 ), a thermal thermal barrier coating is finally sprayed onto the MCrAlX layer. After spraying the turbine component 28, the ceramic core 26 is leached, for example by hydrofluoric acid (HF). The leaching of the ceramic core 26 can be carried out either after the completion of the turbine component or after the spraying of the base material, but before completion of the entire turbine component 28, for example, before the application of a coating. The advantage of premature leaching is that it can avoid possible damage to a ceramic coating (eg, ceramic thermal barrier coating, TBC) during the leaching process.

In einer alternativen Ausgestaltung des Verfahrens wird statt einer Superlegierung ein Keramikmaterial als Grundwerkstoff für das Turbinenbauteil 28 verspritzt. In diesem Fall kann der Kern bspw. aus einem ausbrennbaren Material bestehen. Auf jeden Fall sollte das Material des Kerns so gewählt sein, dass ein Entfernen des Kerns möglich ist, ohne den keramischen Grundwerkstoff anzugreifen.In an alternative embodiment of the method, a ceramic material is sprayed as a base material for the turbine component 28 instead of a superalloy. In this case, the core may, for example, consist of a burn-out material. In any case, the material of the core should be chosen so that removal of the core is possible without attacking the ceramic base material.

Figur 2 zeigt eine perspektivische Ansicht einer Laufschaufel 12 als Beispiel für ein Bauteil, das durch Kaltgasspritzen auf einen Kern, der ausgelaugt wird, hergestellt ist. Die Laufschaufel 12 weist einen Befestigungsbereich 14, eine Schaufelplattform 18 sowie einen Schaufelblattbereich 16 auf.Figure 2 shows a perspective view of a blade 12 as an example of a component made by cold gas spraying on a core which is leached. The rotor blade 12 has a fastening region 14, a blade platform 18 and an airfoil region 16.

Im Befestigungsbereich 14 ist ein Schaufelfuß 20 gebildet, der zur Befestigung der Laufschaufel 12 an einer Welle einer ebenfalls nicht dargestellten Strömungsmaschine, insbesondere einer Gasturbine, darstellt. Die Turbinenschaufel 12 weist besonders in ihrem Schaufelblattbereich 16 eine komplexe Geometrie auf, die durch ein erfindungsgemäßes Verfahren hergestellt werden kann, wobei eine hohe Flexibilität gegenüber Änderungen der Geometrie der Laufschaufel gegeben ist.In the mounting region 14, a blade root 20 is formed, which is for fastening the blade 12 to a shaft of a turbomachine, also not shown, in particular a gas turbine. The turbine blade 12, particularly in its airfoil region 16, has a complex geometry which can be produced by a method according to the invention, with a high degree of flexibility with respect to changes in the geometry of the rotor blade.

In Figur 3 ist, stark schematisiert, ein Schnitt durch die Wand eines Turbinenbauteils 28 gemäß einer ersten Ausführungsvariante dargestellt. Auf einem Kern 26 befindet sich eine durch Kaltgasspritzen aufgetragene dichte Schicht 2, die aus einem Grundwerkstoff besteht und die Innenseite der Bauteilwand bildet. Die dichte Schicht 2 kann aus einer Superlegierung oder aus einem Keramikwerkstoff als Grundwerkstoff bestehen. Der Kern 26 kann bei einer Superlegierung als dichter Schicht 2 bspw. aus Keramik hergestellt sein.A section through the wall of a turbine component 28 according to a first embodiment variant is shown in highly schematic form in FIG. On a core 26 is a applied by cold gas spraying dense layer 2, which consists of a base material and forms the inside of the component wall. The dense layer 2 may consist of a superalloy or of a ceramic material as the base material. The core 26 may be made in a superalloy as a dense layer 2, for example. Made of ceramic.

Auf der dichten Schicht 2 befindet sich eine poröse Schicht 3 mit Poren 7, die ebenfalls durch Kaltgasspritzen aufgebracht ist. Die Poren 7 der porösen Schicht 3 können von einem Kühlluftstrom 5 durchströmt werden, das zur Kühlung des Turbinenbauteils 28 dient. Die Größe der Poren kann durch Wahl der Größe der verspritzten Partikel eingestellt werden.On the dense layer 2 is a porous layer 3 with pores 7, which is also applied by cold gas spraying. The pores 7 of the porous layer 3 can be traversed by a cooling air flow 5, which serves to cool the turbine component 28. The size of the pores can be adjusted by choosing the size of the spattered particles.

Auf der porösen Schicht 3 ist eine weitere dichte Schicht 4 ebenfalls durch Kaltgasspritzen aufgebracht. Diese dichte Schicht 4 kann vollständig oder teilweise aus einem wärmedämmenden oder aus einem korrosions- und/oder oxidationshemmenden Werkstoff wie z.B. MCrA1X bestehen. Ein Teil der dichten Schicht 4 kann auch als Wärmedämmschicht (Thermal Barrier Coating, TBC) die Außenfläche des Turbinenbauteils 28 bilden. Es ist auch möglich, die Wärmedämmschicht direkt auf den Grundwerkstoff aufzuspritzen.On the porous layer 3, another dense layer 4 is also applied by cold gas spraying. This dense layer 4 may be wholly or partly made of a thermally insulating or of a corrosion and / or oxidation-inhibiting material, such as e.g. MCrA1X exist. A part of the dense layer 4 can also form the outer surface of the turbine component 28 as a thermal barrier coating (TBC). It is also possible to spray the thermal barrier coating directly onto the base material.

Fig. 4 zeigt einen schematischen Querschnitt durch ein Turbinenbauteil 28, bspw. eine Turbinenschaufel, mit einem zentralen Luftkanal 6, das aus einem dichten Abschnitt 8 und einem porösen Abschnitt 10 mit Poren 7 besteht. Der zentrale Luftkanal entsteht durch Auslaugen des Keramikkerns nach dem Aufspritzen des Grundwerkstoffs. Ein Kühlluftstrom 5 strömt durch den zentralen Luftkanal 6 ein und durch die Poren 7 des porösen Abschnitts 10 wieder aus und kühlt so den porösen Abschnitt 10. Die beiden Abschnitte sind ebenso wie die dichten Schichten 2 und 4 und die poröse Schicht 3 in Figur 3 durch Kaltgasspritzen hergestellt. Poröse Abschnitte sind vorzugsweise dort gebildet, wo die thermische Belastung des Turbinenbauteils 28 am größten ist. Durch geeignete Position der porösen Abschnitte im Turbinenbauteil 28 sowie durch geeignete Form und Dimensionierung dieser Abschnitte kann auch das Erzeugen von Kühlluftfilmen über der äußeren Oberfläche des Turbinenbauteils 28 erreicht werden.4 shows a schematic cross section through a turbine component 28, for example a turbine blade, with a central one Air duct 6, which consists of a dense portion 8 and a porous portion 10 with pores 7. The central air channel is created by leaching the ceramic core after spraying the base material. A cooling air flow 5 flows in through the central air duct 6 and out through the pores 7 of the porous section 10, thus cooling the porous section 10. The two sections are as well as the dense layers 2 and 4 and the porous layer 3 in FIG Cold gas spraying made. Porous sections are preferably formed where the thermal loading of the turbine component 28 is greatest. By suitable position of the porous sections in the turbine component 28 and by suitable shaping and dimensioning of these sections, the generation of cooling air films over the outer surface of the turbine component 28 can also be achieved.

Abschließend sei angemerkt, dass sämtlichen Merkmalen, die in den Anmeldungsunterlagen und insbesondere in den abhängigen Ansprüchen genannt sind, trotz des vorgenommenen formalen Rückbezugs auf einen oder mehrere bestimmte Ansprüche, auch einzeln oder in beliebiger Kombination eigenständiger Schutz zukommen soll.Finally, it should be noted that all the features that are mentioned in the application documents and in particular in the dependent claims, despite the formal reference to one or more specific claims, even individually or in any combination should receive independent protection.

Claims (15)

Verfahren zum Herstellen von Bauteilen (28), welche aus einem Grundwerkstoff (24) bestehen, in dem pulverförmiger Grundwerkstoff (24) mittels eines Kaltgasspritzverfahrens auf einen Kern (26) aufgespritzt wird und das Spritzen so erfolgt, dass während des Spritzens die Kontur des Bauteils (28) herausgearbeitet wird.Method for producing components (28), which consist of a base material (24) in which powdered base material (24) is sprayed onto a core (26) by means of a cold gas spraying process and the spraying is carried out so that the contour of the component during spraying (28) is worked out. Verfahren nach Anspruch 1, in dem als Kern (26) ein konturierter Kern (26) Verwendung findet, dessen Kontur der Kontur des Bauteils (28) nahe kommt.Method according to Claim 1, in which the core (26) used is a contoured core (26) whose contour approximates the contour of the component (28). Verfahren nach Anspruch 1 oder 2, in dem die Spritzparameter im Laufe des Kaltgasspritzverfahrens variiert werden.A method according to claim 1 or 2, wherein the spray parameters are varied during the cold gas spraying process. Verfahren nach einem der vorangehenden Ansprüche, in dem die Pulverparameter im Laufe des Kaltgasspritzverfahrens variiert werden.Method according to one of the preceding claims, in which the powder parameters are varied during the cold gas spraying process. Verfahren nach Anspruch 4, in dem als Pulverparameter die Partikelgröße im pulverförmigen Werkstoff variiert wird.A method according to claim 4, in which the particle size in the powdery material is varied as a powder parameter. Verfahren nach einem der Ansprüche 1 bis 5, in dem als Bauteil (28) ein Turbinenbauteil hergestellt wird, indem zuerst der Grundwerkstoff (24) auf den Kern (26) aufgespritzt wird und danach ein wärmedämmender Werkstoff auf den Grundwerkstoff (24) aufgespritzt wird.Method according to one of claims 1 to 5, in which as component (28) a turbine component is produced by first the base material (24) is sprayed onto the core (26) and then a heat-insulating material is sprayed onto the base material (24). Verfahren nach einem der Ansprüche 1 bis 5, in dem als Bauteil (28) ein Turbinenbauteil hergestellt wird indem zuerst der Grundwerkstoff (24) auf den Kern (26) aufgespritzt wird, ein korrosions- und/oder oxidationshemmender Werkstoff auf den Grundwerkstoff (24) aufgespritzt wird und wärmedämmender Werkstoff auf den korrosions- und/oder oxidationshemmenden Werkstoff aufgespritzt wird.Method according to one of claims 1 to 5, in which as a component (28) a turbine component is produced by first the base material (24) is sprayed onto the core (26), a corrosion and / or oxidation-inhibiting material on the base material (24). is sprayed on and the heat-insulating material is sprayed onto the corrosion and / or oxidation-inhibiting material. Verfahren nach Anspruch 7, in dem als korrosions- und/oder oxidationshemmender Werkstoff ein MCrA1X-Werkstoff auf den Grundwerkstoff (24) aufgespritzt wird.A method according to claim 7, in which a MCrA1X material is sprayed onto the base material (24) as corrosion and / or oxidation-inhibiting material. Verfahren nach Anspruch 7, in dem auf den Grundwerkstoff (24) weiterer Grundwerkstoff als korrosions- und/oder oxidationshemmender Werkstoff (24) aufgespritzt wird, wobei dem weiteren Grundwerkstoff (24) als Opferanoden fungierende Partikel zugesetzt sind.Method according to claim 7, in which further base material is sprayed onto the base material (24) as corrosion-inhibiting and / or oxidation-inhibiting material (24), particles acting as sacrificial anodes being added to the further base material (24). Verfahren nach einem der vorangehenden Ansprüche, in dem als Grundwerkstoff (24) eine Superlegierung auf Nickel-, Kobalt- oder Eisenbasis verspritzt wird.Method according to one of the preceding claims, in which a base material (24) is sprayed on a nickel, cobalt or iron base superalloy. Verfahren nach einem der vorangehenden Ansprüche, in dem als Grundwerkstoff (24) ein Keramikwerkstoff verspritzt wird.Method according to one of the preceding claims, in which a ceramic material is sprayed as base material (24). Verfahren nach einem der vorangehenden Ansprüche, in dem als Kern (26) ein Keramikkern Verwendung findet.Method according to one of the preceding claims, in which a ceramic core is used as the core (26). Turbinenbauteil (28), welches gemäß dem Verfahren nach einem der Ansprüche 1 bis 10 hergestellt ist und einen Werkstoff umfasst, welcher Bereiche unterschiedlicher Porosität (2, 3, 4, 8, 10) besitzt.A turbine component (28) made according to the method of any one of claims 1 to 10 and comprising a material having regions of different porosity (2, 3, 4, 8, 10). Turbinenbauteil (28) nach Anspruch 13, in dem als Werkstoff mit den Bereichen unterschiedlicher Porosität (2, 3, 4) ein Beschichtungswerkstoff vorhanden ist.Turbine component (28) according to claim 13, in which a coating material is present as material with the regions of different porosity (2, 3, 4). Turbinenbauteil nach Anspruch 13 oder 14, in dem als Werkstoff mit den Bereichen unterschiedlicher Porosität (2, 3, 4, 8, 10) Grundwerkstoff vorhanden ist.Turbine component according to Claim 13 or 14, in which base material is present as material with the regions of different porosity (2, 3, 4, 8, 10).
EP06090174A 2006-09-21 2006-09-21 Process of manufacturing of workpieces by cold gas spraying and turbine workpiece Withdrawn EP1903127A1 (en)

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