EP1896178A4 - Catalyseur a oxyde metallique pour la production d'hydrogene et procede d'elaboration - Google Patents

Catalyseur a oxyde metallique pour la production d'hydrogene et procede d'elaboration

Info

Publication number
EP1896178A4
EP1896178A4 EP06769101A EP06769101A EP1896178A4 EP 1896178 A4 EP1896178 A4 EP 1896178A4 EP 06769101 A EP06769101 A EP 06769101A EP 06769101 A EP06769101 A EP 06769101A EP 1896178 A4 EP1896178 A4 EP 1896178A4
Authority
EP
European Patent Office
Prior art keywords
producing
same
metal oxide
oxide catalyst
hydrogen generation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06769101A
Other languages
German (de)
English (en)
Other versions
EP1896178A1 (fr
Inventor
Myong-Hoon Lim
Tae-Hee Park
Jae-Hoi Gu
Yongho Yu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Samsung Engineering Co Ltd
Original Assignee
Samsung Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/160,571 external-priority patent/US7309479B2/en
Application filed by Samsung Engineering Co Ltd filed Critical Samsung Engineering Co Ltd
Publication of EP1896178A1 publication Critical patent/EP1896178A1/fr
Publication of EP1896178A4 publication Critical patent/EP1896178A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/745Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847Vanadium, niobium or tantalum or polonium
    • B01J23/8472Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/94Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/086Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/344Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electromagnetic wave energy
    • B01J37/346Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of electromagnetic wave energy of microwave energy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/065Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/68Vanadium, niobium, tantalum or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Electromagnetism (AREA)
  • Optics & Photonics (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
EP06769101A 2005-06-29 2006-06-29 Catalyseur a oxyde metallique pour la production d'hydrogene et procede d'elaboration Withdrawn EP1896178A4 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/160,571 US7309479B2 (en) 2005-06-29 2005-06-29 Cobalt oxide catalysts
US11/162,108 US7566440B2 (en) 2005-06-29 2005-08-29 Metal oxide catalysts
PCT/KR2006/002532 WO2007001164A1 (fr) 2005-06-29 2006-06-29 Catalyseur a oxyde metallique pour la production d'hydrogene et procede d'elaboration

Publications (2)

Publication Number Publication Date
EP1896178A1 EP1896178A1 (fr) 2008-03-12
EP1896178A4 true EP1896178A4 (fr) 2011-10-05

Family

ID=37595368

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06769101A Withdrawn EP1896178A4 (fr) 2005-06-29 2006-06-29 Catalyseur a oxyde metallique pour la production d'hydrogene et procede d'elaboration

Country Status (3)

Country Link
EP (1) EP1896178A4 (fr)
KR (1) KR100724555B1 (fr)
WO (1) WO2007001164A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2168188A4 (fr) * 2007-05-18 2012-04-04 Enerfuel Inc Obtention d'hydrogène à partir hydrure de bore et de glycérol
KR100917697B1 (ko) * 2007-12-13 2009-09-21 한국과학기술원 질소를 함유하는 전이금속―탄소나노튜브 혼성촉매, 그의제조방법 및 이를 이용하여 수소를 생산하는 방법
KR100930790B1 (ko) * 2009-02-18 2009-12-09 황부성 수소산소 발생용 전극판 및 그를 제조하기 위한 제조방법
KR101144107B1 (ko) 2009-11-25 2012-05-24 서울대학교산학협력단 탄소에 담지된 니켈 또는 팔라듐 나노입자 제조방법
US10435343B2 (en) 2016-04-13 2019-10-08 Northwestern University Efficient catalytic greenhouse gas-free hydrogen and aldehyde formation from alcohols
CN110639542B (zh) * 2019-09-06 2021-04-09 华南理工大学 一种原位杂化室温除甲醛催化剂、复合凝胶及其制备方法与应用
CN110586116B (zh) * 2019-09-25 2021-08-17 广西师范大学 一种析氢电催化剂的MoO2-Ni/CC复合材料及制备方法
CN113477252B (zh) * 2021-06-30 2023-06-30 常州大学 一种同时含钛及其它过渡金属的复合多孔催化剂的制备方法和应用
CN114291979A (zh) * 2022-01-25 2022-04-08 江苏方洋水务有限公司 一种石化废水处理用系统及方法及臭氧催化氧化催化剂
CN115403008B (zh) * 2022-09-16 2023-07-28 重庆大学 一种MgH2-Co3V2O8复合储氢材料及其制备方法
CN116237030A (zh) * 2022-12-26 2023-06-09 安徽理工大学 一种镍-钌-锆/凹凸棒石基类分子筛催化剂及其应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1320204A (en) * 1969-07-25 1973-06-13 Inst Francais Du Petrole Catalytic process for producing hydrogen from carbon monoxide and steam
US3948699A (en) * 1974-11-08 1976-04-06 The United States Of America As Represented By The Secretary Of The Army Hydrogen gas generators for use in chemical lasers
JPH0741313A (ja) * 1993-07-27 1995-02-10 Tokyo Gas Co Ltd 一酸化炭素の選択的酸化方法および該方法に用いられる触媒
WO1999000326A1 (fr) * 1997-06-26 1999-01-07 Sri International Procede de preparation d'oxydes de metal et d'oxydes de metaux melanges
WO2001051410A1 (fr) * 2000-01-07 2001-07-19 Millennium Cell, Llc Systeme servant a produire de l'hydrogene
US20010022960A1 (en) * 2000-01-12 2001-09-20 Kabushiki Kaisha Toyota Chuo Kenkyusho Hydrogen generating method and hydrogen generating apparatus
EP1496014A1 (fr) * 2003-06-25 2005-01-12 Massimo De Francesco Dispositif de confinement magnétique pour la production d'hydrogène à partir de borohydrures alcalins

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NO137541C (no) * 1974-05-03 1978-03-15 Siemens Ag Fremgangsmaate til fremstilling av hydrogen
JPS5930134B2 (ja) * 1977-08-31 1984-07-25 トヨタ自動車株式会社 炭化水素改質用触媒
JPS58119345A (ja) * 1982-01-06 1983-07-15 Hitachi Ltd 水素富化ガス製造用触媒組成物及びその使用方法
RU2048909C1 (ru) * 1993-07-13 1995-11-27 Научно-производственная фирма "Химтэк" Катализатор паровой конверсии углеводородов
US5804329A (en) * 1995-12-28 1998-09-08 National Patent Development Corporation Electroconversion cell
JP2001224963A (ja) * 2000-02-16 2001-08-21 Nissan Motor Co Ltd 触媒組成物、その製造方法及びその使用方法
ES2208490T3 (es) 2000-04-27 2004-06-16 Haldor Topsoe A/S Procedimiento de produccion de un gas rico en hidrogeno.
US6509000B1 (en) 2000-08-31 2003-01-21 Council Of Scientific And Industrial Research Low temperature process for the production of hydrogen
EP1369176A1 (fr) 2002-06-03 2003-12-10 Paul Scherrer Institut Méthode pour la préparation d'un catalyseur pour la production de l'hydrogène, procédé pour la production de l'hydrogène et une méthode pour le fonctionnement d'une pile à combustible
KR20030053476A (ko) * 2002-12-20 2003-06-28 콘세호수페리오르데인베스티가시오네스시엔티피카스 메탄올의 부분적인 산화를 통한 수소 제조 방법
EP1581456A2 (fr) * 2002-12-20 2005-10-05 Honda Giken Kogyo Kabushiki Kaisha Preparations catalysantes de ruthenium-cobalt exemptes de platine destinees a la production d'hydrogene

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1320204A (en) * 1969-07-25 1973-06-13 Inst Francais Du Petrole Catalytic process for producing hydrogen from carbon monoxide and steam
US3948699A (en) * 1974-11-08 1976-04-06 The United States Of America As Represented By The Secretary Of The Army Hydrogen gas generators for use in chemical lasers
JPH0741313A (ja) * 1993-07-27 1995-02-10 Tokyo Gas Co Ltd 一酸化炭素の選択的酸化方法および該方法に用いられる触媒
WO1999000326A1 (fr) * 1997-06-26 1999-01-07 Sri International Procede de preparation d'oxydes de metal et d'oxydes de metaux melanges
WO2001051410A1 (fr) * 2000-01-07 2001-07-19 Millennium Cell, Llc Systeme servant a produire de l'hydrogene
US20010022960A1 (en) * 2000-01-12 2001-09-20 Kabushiki Kaisha Toyota Chuo Kenkyusho Hydrogen generating method and hydrogen generating apparatus
EP1496014A1 (fr) * 2003-06-25 2005-01-12 Massimo De Francesco Dispositif de confinement magnétique pour la production d'hydrogène à partir de borohydrures alcalins

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
KOJIMA Y ET AL: "Hydrogen generation using sodium borohydride solution and metal catalyst coated on metal oxide", INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, ELSEVIER SCIENCE PUBLISHERS B.V., BARKING, GB, vol. 27, no. 10, 1 October 2002 (2002-10-01), pages 1029 - 1034, XP004366829, ISSN: 0360-3199, DOI: 10.1016/S0360-3199(02)00014-9 *
See also references of WO2007001164A1 *

Also Published As

Publication number Publication date
WO2007001164A1 (fr) 2007-01-04
EP1896178A1 (fr) 2008-03-12
KR100724555B1 (ko) 2007-06-04
KR20070001831A (ko) 2007-01-04

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