EP1890986A1 - Pyrotechnic agent - Google Patents

Pyrotechnic agent

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Publication number
EP1890986A1
EP1890986A1 EP06763483A EP06763483A EP1890986A1 EP 1890986 A1 EP1890986 A1 EP 1890986A1 EP 06763483 A EP06763483 A EP 06763483A EP 06763483 A EP06763483 A EP 06763483A EP 1890986 A1 EP1890986 A1 EP 1890986A1
Authority
EP
European Patent Office
Prior art keywords
agent according
pyrotechnic agent
pyrotechnic
nitrate
azotetrazolate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP06763483A
Other languages
German (de)
French (fr)
Other versions
EP1890986B1 (en
Inventor
Ulrich Bley
Rainer Hagel
Julia Havlik
Aleksej Hoschenko
Peter Simon Lechner
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RWS GmbH
Original Assignee
RUAG Ammotec GmbH
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Publication of EP1890986A1 publication Critical patent/EP1890986A1/en
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Publication of EP1890986B1 publication Critical patent/EP1890986B1/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
    • C06C9/00—Chemical contact igniters; Chemical lighters
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
    • C06D5/00—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
    • C06D5/06—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more solids

Definitions

  • the subject of the present invention is a pyrotechnic agent.
  • Pyrotechnic agents in the context of the invention are substances or mixtures of substances which can develop a pyrotechnic effect.
  • the subject of the present invention is a pyrotechnic agent which can be used as a thermal ignition agent.
  • thermal pre-ignition agents are, for example, safety systems, preferably thermal fuses in gas generators or separating elements for batteries.
  • security systems are again preferably used in motor vehicles.
  • Thermal preignition agents are pyrotechnic substances or mixtures which, inter alia, have the task of controlling the generally very thermally stable gas-generating mixtures of the gas generator in the event of a vehicle fire.
  • thermal preignition agents are the use as a pyrotechnic set in separators, preferably for battery terminals. These separators should interrupt the power supply in case of fire, especially a vehicle fire, or in a motor vehicle accident in which the gas generator is triggered.
  • Nitrocellulose, propellant powder derived therefrom or the mixtures based on nitrotriazolone and guanidine nitrate described in the patent application DE 197 30 873 A1 are used as thermal premature igniters, for example. These mixtures show ignition temperatures of about 160 0 C and are insufficiently long-term stability in the case of nitrocellulose.
  • Another object of the present invention was to provide a pyrotechnic agent that can be used in battery terminal isolators.
  • azotetrazolates are used as component according to the invention.
  • the azotetrazolate component employed here is amino guanandine 5,5'-azotetrazolate (C 4 H 4 Ni ā‡ ), AGATZ for short, and guanidine 5,5'-azotetrazolate (C 41 Hi 2 Ni 6 ), GATZ for short.
  • the azotetrazolate components may be used either alone or in mixtures with each other and / or with other components.
  • the structural formulas of AGATZ and GATZ are as follows:
  • Aminoguanine 5,5'-azotetrazolate (C 4 Hi 4 Ni ā‡ , AGATZ).
  • Guanidine 5,5'-azotetrazolate (C 4 , Hi 2 Ni 6 , GATZ).
  • the deflagration point of the pure AGATZ is 209 Ā° C, that of the GATZ is 24O 0 C.
  • the deflagration temperatures in the range of 165 Ā° C to 195 Ā° C can be controlled and the deflagration temperatures of the mixtures can be lower than that of the individual components.
  • additives can be used:
  • Oxidizing agents (individually or in mixtures)
  • Nitrates of alkali or alkaline earth metals or ammonium such as sodium, potassium or ammonium nitrate, perchlorates of alkali or alkaline earth metals or of ammonium, peroxides of alkali or alkaline earth metals or zinc.
  • Nitrogen-containing compounds (individually or in mixtures)
  • diamidine nitrate diaminoguanidine azotetrazolate, triaminoguanidine azotetrazolate or ammonium azotetrazolate.
  • High-energy additives (singly or in mixtures) Hexogen, octogen, nitrocellulose.
  • Binders (individually or in mixtures)
  • Burn-off moderators, stabilizers and processing aids (individually or in mixtures)
  • Ferrocene and derivatives acetonyl acetates, salicylates, barium carbonate, strontium carbonate, magnesium carbonate, melamine, zinc oxide, zinc carbonate, silicates, silica gels, silicas, for example Aerosil (Degussa), boron nitride.
  • the production and processing takes place according to known and customary methods. These include, for example, kneading, extrusion, extrusion, tableting or granulation.
  • pyrotechnic agent containing as component one or more azotetrazolates
  • azotetrazolate component is selected from amino guanandine 5,5'-azotetrazolate (AGATZ) and guanidine 5,5'-azotetrazolate (GATZ) or mixtures of both;
  • a pyrotechnic agent wherein the proportion of the azotetrazolate component is 100% by weight
  • K ā‡ ausland ā‡ OZ05026 doc a pyrotechnic agent, the proportion of the azotetrazolate component being from 10 to 99% by weight, preferably from 15 to 60% by weight, particularly preferably from 20 to 50% by weight;
  • a pyrotechnic agent containing 1 to 90 wt .-%, preferably 40 to 85 wt .-%, particularly preferably 50 to 80 wt .-% of an additive or mixtures of several additives;
  • a pyrotechnic composition the additives being selected from: ammonium picrate, aminoguanidinium picrate, guanidinium picrate, aminoguanidinium stannate, guanidinium typhnate, nitroguanidine, nitroaminoguanidine, nitrotriazolone, derivatives of tetrazole and / or salts thereof, nitraminotetrazole and / or its salts, aminoguanidine nitrate, diamino guanidine nitrate, Triaminoguanidine nitrate, guanidine nitrate, dicyandiamide nitrate, diaminoguanidine azotetrazolate, triaminoguanidine azotetrazolate, ammonium azotetrazolate; Nitrates of the alkali and / or alkaline earth metals and / or ammonium, perchlorates of the alkali and / or alkaline earth metal
  • the oxidizing agent is selected from one or more of the nitrates of the alkali and / or alkaline earth metals and / or ammonium, the perchlorates of the alkali and / or alkaline earth metals and / or ammonium, the peroxides of the alkali and / or alkaline earth metals and / or zinc;
  • a pyrotechnic agent wherein the nitrogen-containing compound is selected from one or more of ammonium picrate, aminoguanidinium picrate,
  • a pyrotechnic agent wherein the energetic additives are selected from one or more of hexogen, octogen and / or nitrocellulose;
  • a pyrotechnic agent wherein the reducing agent is selected from one or more of aluminum, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black;
  • binder is selected from one or more of cellulose and its derivatives, polyvinyl butyrals, Polynitopolyphen- nylen, Polynitrophenylether, Plexigum, polyvinyl acetate and copolymers;
  • the Abbrandmoderatoren and processing aids are selected from one or more of ferrocene and its derivatives, acetonyl acetates, salicylates, barium carbonate, strontium carbonate, magnesium carbonate, melamine, zinc oxide, zinc carbonate, silicates, silica gel, silicic acids, for example Aerosil (Degussa), and / or boron nitride;
  • Table 1 lists the compositions of 27 different pyrotechnic agent blends. The components were weighed in the stated weight ratios (in percent by weight (% by weight)) in plastic containers and homogenized for 30 minutes in a tumble mixer.
  • Table 2 shows the deflagration points, friction and impact sensitivities of the mixtures.
  • the measurement of the friction and impact sensitivities was carried out according to methods of the Federal Institute for Materials Research (BAM), while the measurement of the deflagration points with the thermogravimetric analysis (Mettler) was carried out at a heating rate of 10 Ā° C. per minute.
  • K ā‡ ausland ā‡ OZ05026 doc Table 3 summarizes the weight losses and detonation after thermal exposure (24 h, 125 Ā° C and 400 h, 1 1 0 O C) summarized a number of selected mixtures of Examples.
  • the weight loss was measured analogously to the Holland test.
  • the measurement of the deflagration points was carried out by thermal gravimetric analysis (Mettler) at a heating rate of 10 Ā° C. per minute.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Air Bags (AREA)

Abstract

The invention relates to a pyrotechnic agent containing at least one azotetrazolate as a component thereof.

Description

Pyrotechnisches MittelĀ Pyrotechnic agent
Gegenstand der vorliegenden Erfindung ist ein pyrotechnisches Mittel.The subject of the present invention is a pyrotechnic agent.
Pyrotechnische Mittel im Sinne der Erfindung sind Stoffe oder Stoffgemische, die eine pyrotechnische Wirkung entfalten kƶnnen.Pyrotechnic agents in the context of the invention are substances or mixtures of substances which can develop a pyrotechnic effect.
Insbesondere Gegenstand der vorliegenden Erfindung ist ein pyrotechnisches Mittel, das als thermisches FrĆ¼hzĆ¼ndmittel eingesetzt werden kann.In particular, the subject of the present invention is a pyrotechnic agent which can be used as a thermal ignition agent.
Anwendungsbereiche solcher thermischen FrĆ¼hzĆ¼ndmittel sind beispielsweise Sicherheitssysteme, vorzugsweise thermische Sicherungen in Gasgeneratoren oder Trennelemente fĆ¼r Batterien. Solche Sicherheitssysteme werden wiederum vorzugsweise in Kraftfahrzeugen eingesetzt.Areas of application of such thermal pre-ignition agents are, for example, safety systems, preferably thermal fuses in gas generators or separating elements for batteries. Such security systems are again preferably used in motor vehicles.
Thermische FrĆ¼hzĆ¼ndmittel sind pyrotechnische Substanzen bzw. Mischungen, die unter anderem die Aufgabe haben, die in der Regel thermisch sehr stabilen Gas erzeugenden Mischungen des Gasgenerators im Falle eines Fahrzeugbrandes kontrolliert anzuzĆ¼nden.Thermal preignition agents are pyrotechnic substances or mixtures which, inter alia, have the task of controlling the generally very thermally stable gas-generating mixtures of the gas generator in the event of a vehicle fire.
Ein anderes Anwendungsbeispiel thermischer FrĆ¼hzĆ¼ndmittel ist die Verwendung als pyrotechnischer Satz in Trennelementen, vorzugsweise fĆ¼r Batterieklemmen. Diese Trennelemente sollen im Falle eines Brandes, insbesondere eines Fahrzeugbrandes, oder bei einem Kraftfahrzeugunfall, bei dem der Gasgenerator ausgelƶst wird, die Stromversorgung unterbrechen.Another application of thermal preignition agents is the use as a pyrotechnic set in separators, preferably for battery terminals. These separators should interrupt the power supply in case of fire, especially a vehicle fire, or in a motor vehicle accident in which the gas generator is triggered.
Als thermische FrĆ¼hzĆ¼ndmittel werden beispielsweise Nitrocellulose, daraus abgeleitete Treibladungspulver oder die in der Patentanmeldung DE 197 30 873 A1 beschriebenen Mischungen auf Basis von Nitrotriazolon und Guanidinnitrat eingesetzt. Diese Mischungen zeigen EntzĆ¼ndungstemperaturen von ca. 1600C und sind im Falle der Nitrocellulose nur unzureichend langzeitstabil.Nitrocellulose, propellant powder derived therefrom or the mixtures based on nitrotriazolone and guanidine nitrate described in the patent application DE 197 30 873 A1 are used as thermal premature igniters, for example. These mixtures show ignition temperatures of about 160 0 C and are insufficiently long-term stability in the case of nitrocellulose.
Aufgabe der vorliegenden Erfindung war die Bereitstellung eines pyrotechnischen Mittels mit einer EntzĆ¼ndungstemperatur um 180Ā°C und ausreichender LangzeitstabilitƤt. Eine weitere Aufgabe der vorliegenden Erfindung war die Bereitstellung eines pyrotechnischen Mittels, das als thermisches FrĆ¼hzĆ¼ndmittel fĆ¼r Gasgeneratoren in Kraftfahrzeugsicherheitssystemen eingesetzt werden kann. EineObject of the present invention was to provide a pyrotechnic agent having an ignition temperature of 180 Ā° C and sufficient long-term stability. Another object of the present invention was to provide a pyrotechnic agent that can be used as a thermal ignition agent for gas generators in automotive safety systems. A
K \ausland\OZ05026 doc weitere Aufgabe der vorliegenden Erfindung war die Bereitstellung eines pyrotechnischen Mittels, das in Trennelementen fĆ¼r Batterieklemmen eingesetzt werden kann.K \ ausland \ OZ05026 doc Another object of the present invention was to provide a pyrotechnic agent that can be used in battery terminal isolators.
ErfindungsgemƤƟ wird diese Aufgabe Ć¼berraschenderweise durch die Merkmale des Hauptanspruchs gelƶst. Vorzugsweise Ausgestaltungen finden sich in den UnteransprĆ¼chen. Dabei werden erfindungsgemƤƟ Azotetrazolate als Komponente eingesetzt. Insbesondere werden dabei als Azotetrazolatkomponente Aminoguandin- 5,5'-azotetrazolat (C4H-Ī¹4NiĪ²), kurz AGATZ, und Guanidin-5,5'-azotetrazolat (C41Hi2Ni6), kurz GATZ, eingesetzt.According to the invention, this object is surprisingly achieved by the features of the main claim. Preferred embodiments can be found in the subclaims. In this case, azotetrazolates are used as component according to the invention. In particular, the azotetrazolate component employed here is amino guanandine 5,5'-azotetrazolate (C 4 H 4 NiĪ²), AGATZ for short, and guanidine 5,5'-azotetrazolate (C 41 Hi 2 Ni 6 ), GATZ for short.
Die Azotetrazolatkomponenten kƶnnen entweder alleine oder in Mischungen untereinander und/oder mit weiteren Komponenten verwendet werden. Die Strukturformeln von AGATZ und GATZ sind wie folgt:The azotetrazolate components may be used either alone or in mixtures with each other and / or with other components. The structural formulas of AGATZ and GATZ are as follows:
NH, Īø NH2 NH, Īø NH 2
IlIl
C c / \C c / \
H2N NH H2N NH iH 2 N NH 2 H NH i
NH, NH,NH, NH,
Aminoguandin-5,5'-azotetrazolat (C4Hi4NiĪ², AGATZ).Aminoguanine 5,5'-azotetrazolate (C 4 Hi 4 NiĪ², AGATZ).
K \ausland\OZ05026 doc K \ ausland \ OZ05026 doc
Guanidin-5,5'-azotetrazolat (C4, Hi2Ni6, GATZ).Guanidine 5,5'-azotetrazolate (C 4 , Hi 2 Ni 6 , GATZ).
Der Verpuffungspunkt des reinen AGATZ betrƤgt 209Ā°C, der des GATZ betrƤgt 24O0C.The deflagration point of the pure AGATZ is 209 Ā° C, that of the GATZ is 24O 0 C.
Ɯberraschenderweise wurde gefunden, dass sich bei Mischungen von AGATZ und/oder GATZ und/oder ausgewƤhlten Komponenten die Verpuffungstemperaturen im Bereich von 165Ā°C bis 195Ā°C steuern lassen und die Verpuffungstemperaturen der Mischungen tiefer liegen kƶnnen als die der Einzelkomponenten.Surprisingly, it has been found that in blends of AGATZ and / or GATZ and / or selected components, the deflagration temperatures in the range of 165 Ā° C to 195 Ā° C can be controlled and the deflagration temperatures of the mixtures can be lower than that of the individual components.
FĆ¼r FrĆ¼hzĆ¼ndmittel sind Verpuffungstemperaturen unter 200Ā°C besonders interessant. Die erfindungsgemƤƟen pyrotechnischen Mittel erfĆ¼llen diese Forderung bei ausgezeichneter LangzeitstabilitƤt.For FrĆ¼hzĆ¼ndmittel deflagration temperatures below 200 Ā° C are particularly interesting. The pyrotechnic compositions according to the invention meet this requirement with excellent long-term stability.
Als Zusatzstoffe kƶnnen verwendet werden:As additives can be used:
1. Oxidationsmittel (einzeln oder in Mischungen)1. Oxidizing agents (individually or in mixtures)
Nitrate der Alkali- oder Erdalkalimetalle oder des Ammoniums wie Natrium-, Kalium- oder Ammoniumnitrat, Perchlorate der Alkali- oder Erdalkalimetalle oder des Ammoniums, Peroxide der Alkali- oder Erdalkalimetalle oder des Zinks.Nitrates of alkali or alkaline earth metals or ammonium such as sodium, potassium or ammonium nitrate, perchlorates of alkali or alkaline earth metals or of ammonium, peroxides of alkali or alkaline earth metals or zinc.
2. Stickstoffhaltige Verbindungen (einzeln oder in Mischungen)2. Nitrogen-containing compounds (individually or in mixtures)
Ammoniumpikrat, Aminoguanidiniumpikrat, Guanidiniumpikrat, Aminoguani- diniumstyphnat, Guanidiniumstyphnat, Nitroguanidin, Nitroaminoguanidin, Nitrotriazolon, Derivate des Tetrazols wie 5-Aminotetrazol, Ditetrazolylamin, Ditetrazol und dessen Salze, Nitraminotetrazol und dessen Salze wie Ammonium- Nitraminotetrazolat und Aminoguanidinium-Nitraminotetrazolat, Aminoguanidin- nitrat, Diaminoguanidinnitrat, Triaminoguanidinnitrat, Guanidinnitrat, Dicyan-Ammonium picrate, aminoguanidinium picrate, guanidinium picrate, aminoguanidinium styrenate, guanidinium styrenate, nitroguanidine, nitroaminoguanidine, nitrotriazolone, derivatives of tetrazole such as 5-aminotetrazole, ditetrazolylamine, ditetrazole and its salts, nitraminotetrazole and its salts such as ammonium nitramine tetrazolate and aminoguanidinium nitraminotetrazolate, aminoguanidine nitrate, Diaminoguanidine nitrate, triaminoguanidine nitrate, guanidine nitrate, dicyan
K \ausland\OZ05026 doc - A -K \ ausland \ OZ05026 doc - A -
diamidinnitrat, Diaminoguanidin-Azotetrazolat, Triaminoguanidin-Azotetrazolat oder Ammonium-Azotetrazolat.diamidine nitrate, diaminoguanidine azotetrazolate, triaminoguanidine azotetrazolate or ammonium azotetrazolate.
3. Energiereiche ZuschlƤge (einzeln oder in Mischungen) Hexogen, Oktogen , Nitrocellulose.3. High-energy additives (singly or in mixtures) Hexogen, octogen, nitrocellulose.
4. Reduktionsmittel (einzeln oder in Mischungen)4. Reducing agents (individually or in mixtures)
Aluminium, Titan, Titanhydrid, Bor, Borhydrid, Zirkon, Zirkonhydrid, Silicium, Graphit, Aktivkohle, RuƟ.Aluminum, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black.
5. Bindemittel (einzeln oder in Mischungen)5. Binders (individually or in mixtures)
Cellulose sowie deren Derivate, Polyvinylbutyrale, Polynitropolyphenylen, Polyni- trophenylether, Plexigum, Polyvinylacetat, Copolymere.Cellulose and derivatives thereof, polyvinyl butyrals, Polynitropolyphenylen, Polyni- trophenylether, Plexigum, polyvinyl acetate, copolymers.
6. Abbrandmoderatoren, Stabilisatoren und Verarbeitungshilfen (einzeln oder in Mischungen)6. Burn-off moderators, stabilizers and processing aids (individually or in mixtures)
Ferrocen und Derivate, Acetonylacetate, Salicylate, Bariumcarbonat, Strontiumcarbonat, Magnesiumcarbonat, Melamin, Zinkoxid, Zinkcarbonat, Silikate, Kieselgele, KieselsƤuren, beispielsweise Aerosil (Fa. Degussa), Bornitrid.Ferrocene and derivatives, acetonyl acetates, salicylates, barium carbonate, strontium carbonate, magnesium carbonate, melamine, zinc oxide, zinc carbonate, silicates, silica gels, silicas, for example Aerosil (Degussa), boron nitride.
Die Herstellung und Verarbeitung findet nach an sich bekannten und Ć¼blichen Verfahren statt. Hierzu zƤhlen beispielsweise Kneten, Extrudieren, Strangpressen, Tablettieren oder Granulieren.The production and processing takes place according to known and customary methods. These include, for example, kneading, extrusion, extrusion, tableting or granulation.
Gegenstand der vorliegenden Erfindung ist im Einzelnen:The subject of the present invention is in detail:
- ein pyrotechnisches Mittel, das als Komponente ein oder mehrere Azotetrazolate enthƤlt;- a pyrotechnic agent containing as component one or more azotetrazolates;
- ein pyrotechnisches Mittel, wobei die Azotetrazolatkomponente ausgewƤhlt ist aus Aminoguandin-5,5'-azotetrazolat (AGATZ) und Guanidin-5,5'-azotetrazolat (GATZ) oder Mischungen aus beiden;a pyrotechnic agent, wherein the azotetrazolate component is selected from amino guanandine 5,5'-azotetrazolate (AGATZ) and guanidine 5,5'-azotetrazolate (GATZ) or mixtures of both;
- ein pyrotechnisches Mittel, wobei der Anteil der Azotetrazolatkomponente 100 Gew.-% betrƤgt;a pyrotechnic agent, wherein the proportion of the azotetrazolate component is 100% by weight;
K \ausland\OZ05026 doc - ein pyrotechnisches Mittel, wobei der Anteil der Azotetrazolatkomponente 10 bis 99 Gew.-%, bevorzugt 15 bis 60 Gew.-%, besonders bevorzugt 20 bis 50 Gew.-% betrƤgt;K \ ausland \ OZ05026 doc a pyrotechnic agent, the proportion of the azotetrazolate component being from 10 to 99% by weight, preferably from 15 to 60% by weight, particularly preferably from 20 to 50% by weight;
- ein pyrotechnisches Mittel, das 1 bis 90 Gew.-%, bevorzugt 40 bis 85 Gew.-%, besonders bevorzugt 50 bis 80 Gew.-% eines Zusatzstoffes oder Mischungen mehrerer Zusatzstoffe enthƤlt;- A pyrotechnic agent containing 1 to 90 wt .-%, preferably 40 to 85 wt .-%, particularly preferably 50 to 80 wt .-% of an additive or mixtures of several additives;
- ein pyrotechnisches Mittel, wobei die Zusatzstoffe ausgewƤhlt sind aus: Ammoniumpikrat, Aminoguanidiniumpikrat, Guanidiniumpikrat, Aminoguanidiniumstyphnat, Guanidiniumstyphnat, Nitroguanidin, Nitroaminoguanidin, Nitrotriazolon, Derivate des Tetrazols und/oder deren Salze, Nitraminotetrazol und/oder dessen Salze, Aminoguanidinnitrat, Diamino- guanidinnitrat, Triaminoguanidinnitrat, Guanidinnitrat, Dicyandiamidinnitrat, Diaminoguanidin-Azotetrazolat, Triaminoguanidin-Azotetrazolat, Ammonium- Azotetrazolat; Nitrate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, Perchlorate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, Peroxide der Alkali- und/oder der Erdalkalimetalle und/oder des Zinks; Aluminium, Titan, Titanhydrid, Bor, Borhydrid, Zirkon, Zirkonhydrid, Silicium, Graphit, Aktivkohle, RuƟ; Cellulose und/oder deren Derivate, Polyvinylbutyrale, Polynitropolyphenylen, Polynitrophenylether, Plexigum, Polyvinylacetat und Copolymere; Hexogen, Oktogen; Ferrocen und/oder deren Derivate, Acetonylacetate, Salicylate, Bariumcarbonat, Strontiumcarbonat, Magnesium- carbonat, Melamin, Zinkoxid, Zinkcarbonat, Silikate, Kieselgele, KieselsƤuren, beispielsweise Aerosil (Fa. Degussa), Bornitrid;a pyrotechnic composition, the additives being selected from: ammonium picrate, aminoguanidinium picrate, guanidinium picrate, aminoguanidinium stannate, guanidinium typhnate, nitroguanidine, nitroaminoguanidine, nitrotriazolone, derivatives of tetrazole and / or salts thereof, nitraminotetrazole and / or its salts, aminoguanidine nitrate, diamino guanidine nitrate, Triaminoguanidine nitrate, guanidine nitrate, dicyandiamide nitrate, diaminoguanidine azotetrazolate, triaminoguanidine azotetrazolate, ammonium azotetrazolate; Nitrates of the alkali and / or alkaline earth metals and / or ammonium, perchlorates of the alkali and / or alkaline earth metals and / or ammonium, peroxides of the alkali and / or alkaline earth metals and / or zinc; Aluminum, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black; Cellulose and / or derivatives thereof, polyvinyl butyrals, polynitropolyphenylene, polynitrophenyl ethers, plexigum, polyvinyl acetate and copolymers; Hexogen, octogen; Ferrocene and / or derivatives thereof, acetonylacetates, salicylates, barium carbonate, strontium carbonate, magnesium carbonate, melamine, zinc oxide, zinc carbonate, silicates, silica gels, silicic acids, for example Aerosil (Degussa), boron nitride;
- ein pyrotechnisches Mittel, das 10 bis 90 Gew.-%, bevorzugt 20 bis 70 Gew.-%, besonders bevorzugt 30 bis 60 Gew.-% eines Oxidationsmittels enthƤlt;- A pyrotechnic agent containing 10 to 90 wt .-%, preferably 20 to 70 wt .-%, particularly preferably 30 to 60 wt .-% of an oxidizing agent;
- ein pyrotechnisches Mittel, wobei das Oxidationsmittel ausgewƤhlt ist aus einem oder mehreren der Nitrate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, der Perchlorate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, der Peroxide der Alkali- und/oder Erdalkalimetalle und/oder des Zinks;- A pyrotechnic agent, wherein the oxidizing agent is selected from one or more of the nitrates of the alkali and / or alkaline earth metals and / or ammonium, the perchlorates of the alkali and / or alkaline earth metals and / or ammonium, the peroxides of the alkali and / or alkaline earth metals and / or zinc;
K \ausland\OZ05026 doc - ein pyrotechnisches Mittel, das 10 bis 90 Gew.-%, bevorzugt 10 bis 60 Gew.-%, besonders bevorzugt 15 bis 40 Gew.-% einer stickstoffhaltigen Verbindung enthƤlt;K \ ausland \ OZ05026 doc - A pyrotechnic agent containing 10 to 90 wt .-%, preferably 10 to 60 wt .-%, particularly preferably 15 to 40 wt .-% of a nitrogen-containing compound;
- ein pyrotechnisches Mittel, wobei die stickstoffhaltige Verbindung ausgewƤhlt ist aus einem oder mehreren von Ammoniumpikrat, Aminoguanidiniumpikrat,a pyrotechnic agent, wherein the nitrogen-containing compound is selected from one or more of ammonium picrate, aminoguanidinium picrate,
Guanidiniumpikrat, Aminoguanidiniumstyphnat, Guanidiniumstyphnat,Guanidinium picrate, aminoguanidinium typhnate, guanidinium typhnate,
Nitroguanidin, Nitroaminoguanidin, Nitrotriazolon, Derivate des Tetrazols und/oder deren Salze, Nitraminotetrazol und/oder dessen Salze, Aminoguanidinnitrat, Diaminoguanidinnitrat, Triaminoguanidinnitrat, Guanidinnitrat, Dicyandi- amidinnitrat, Diaminoguanidin-azotetrazolat, Triaminoguanidin-Azotetrazolat, Ammonium-Azotetrazolat;Nitroguanidine, nitroaminoguanidine, nitrotriazolone, derivatives of tetrazole and / or salts thereof, nitraminotetrazole and / or its salts, aminoguanidine nitrate, diaminoguanidine nitrate, triaminoguanidine nitrate, guanidine nitrate, dicyandiamide nitrate, diaminoguanidine azotetrazolate, triaminoguanidine azotetrazolate, ammonium azotetrazolate;
- ein pyrotechnisches Mittel, das 1 bis 90 Gew.-%, bevorzugt 1 bis 60 Gew.-%, besonders bevorzugt 1 bis 40 Gew.-% energetische ZusƤtze enthƤlt;- A pyrotechnic agent containing 1 to 90 wt .-%, preferably 1 to 60 wt .-%, particularly preferably 1 to 40 wt .-% of energetic additives;
- ein pyrotechnisches Mittel, wobei die energetischen ZusƤtze ausgewƤhlt sind aus einem oder mehreren von Hexogen, Oktogen und/oder Nitrocellulose;a pyrotechnic agent, wherein the energetic additives are selected from one or more of hexogen, octogen and / or nitrocellulose;
- ein pyrotechnisches Mittel, das 1 bis 80 Gew.-%, bevorzugt 1 bis 40 Gew.-%, besonders bevorzugt 1 bis 15 Gew.-% eines Reduktionsmittel enthƤlt;- A pyrotechnic agent containing 1 to 80 wt .-%, preferably 1 to 40 wt .-%, particularly preferably 1 to 15 wt .-% of a reducing agent;
- ein pyrotechnisches Mittel, wobei das Reduktionsmittel ausgewƤhlt ist aus einem oder mehreren von Aluminium, Titan, Titanhydrid, Bor, Borhydrid, Zirkon, Zirkonhydrid, Silicium, Graphit, Aktivkohle, RuƟ;a pyrotechnic agent, wherein the reducing agent is selected from one or more of aluminum, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black;
- ein pyrotechnisches Mittel, das 1 bis 80 Gew.-%, bevorzugt 1 bis 40 Gew.-%, besonders bevorzugt 1 bis 20 Gew.-% eines Bindemittels enthƤlt;- A pyrotechnic agent containing 1 to 80 wt .-%, preferably 1 to 40 wt .-%, particularly preferably 1 to 20 wt .-% of a binder;
- ein pyrotechnisches Mittel, wobei das Bindemittel ausgewƤhlt ist aus einem oder mehreren von Cellulose und deren Derivaten, Polyvinylbutyrale, Polynitropolyphe- nylen, Polynitrophenylether, Plexigum, Polyvinylacetat und Copolymeren;- A pyrotechnic agent, wherein the binder is selected from one or more of cellulose and its derivatives, polyvinyl butyrals, Polynitopolyphen- nylen, Polynitrophenylether, Plexigum, polyvinyl acetate and copolymers;
- ein pyrotechnisches Mittel, das 0,1 bis 20 Gew.-%, bevorzugt 0,1 bis 15 Gew.-%, besonders bevorzugt 1 bis 10 Gew.-% Abbrandmoderatoren, Stabilisatoren und Verarbeitungshilfen enthƤlt;- A pyrotechnic agent containing 0.1 to 20 wt .-%, preferably 0.1 to 15 wt .-%, particularly preferably 1 to 10 wt .-% Abbrandmoderatoren, stabilizers and processing aids;
K \ausland\OZ05026 doc - ein pyrotechnisches Mittel, wobei die Abbrandmoderatoren und Verarbeitungshilfen ausgewƤhlt sind aus einem oder mehreren von Ferrocen und dessen Derivaten, Acetonylacetaten, Salicylate, Bariumcarbonat, Strontium- carbonat, Magnesiumcarbonat, Melamin, Zinkoxid, Zinkcarbonat, Silikate, Kiesel- gele, KieselsƤuren, beispielsweise Aerosil (Fa. Degussa), und/oder Bornitrid;K \ ausland \ OZ05026 doc - A pyrotechnic agent, the Abbrandmoderatoren and processing aids are selected from one or more of ferrocene and its derivatives, acetonyl acetates, salicylates, barium carbonate, strontium carbonate, magnesium carbonate, melamine, zinc oxide, zinc carbonate, silicates, silica gel, silicic acids, for example Aerosil (Degussa), and / or boron nitride;
- Verwendung des erfindungsgemƤƟen pyrotechnischen Mittels als thermisches FrĆ¼hzĆ¼ndmittel;- Use of the pyrotechnic agent according to the invention as a thermal FrĆ¼hzĆ¼ndmittel;
- Verwendung des erfindungsgemƤƟen pyrotechnischen Mittels als thermische Sicherung;- Use of the pyrotechnic agent according to the invention as a thermal fuse;
- Verwendung des erfindungsgemƤƟen pyrotechnischen Mittels in Kraftfahrzeugsicherheitssystemen;Use of the pyrotechnic agent according to the invention in motor vehicle safety systems;
- Verwendung des erfindungsgemƤƟen pyrotechnischen Mittels in Gasgeneratoren;- Use of the pyrotechnic agent according to the invention in gas generators;
- Verwendung des erfindungsgemƤƟen pyrotechnischen Mittels in Trennelementen, vorzugsweise fĆ¼r Batterieklemmen.Use of the pyrotechnic agent according to the invention in separating elements, preferably for battery terminals.
Die Erfindung wird durch die folgenden Beispiele nƤher erlƤutert, ohne sie darauf einzuschrƤnken:The invention is explained in more detail by the following examples, without limiting them:
In Tabelle 1 sind die Zusammensetzungen von 27 verschiedenen Mischungen des pyrotechnischen Mittels aufgefĆ¼hrt. Die Komponenten wurden in den angegebenen GewichtsverhƤltnissen (Angaben in Gewichtsprozent (Gew.-%)) in PlastikbehƤlter eingewogen und 30 Minuten im Taumelmischer homogenisiert.Table 1 lists the compositions of 27 different pyrotechnic agent blends. The components were weighed in the stated weight ratios (in percent by weight (% by weight)) in plastic containers and homogenized for 30 minutes in a tumble mixer.
K \ausland\OZ05026 doc Tabelle 1 : MischungenK \ ausland \ OZ05026 doc Table 1: Mixtures
AGSt: AminoguanidiniumstyphnatAGSt: aminoguanidinium typhnate
GPik: GuanidiniumpikratGPik: guanidinium picrate
Nigu: NitroguanidinNigu: nitroguanidine
APik: AmmoniumpikratAPik: ammonium picrate
K \ausland\OZ05026 doc In Tabelle 2 sind die Verpuffungspunkte, Reib- und Schlagempfindlichkeiten der Mischungen dargestellt. Die Messung der Reib- und Schlagempfindlichkeiten erfolgte nach Methoden der Bundesanstalt fĆ¼r Materialforschung (BAM), wƤhrend die Messung der Verpuffungspunkte mit der Thermogravimetrie-Analyse (Fa. Mettler) bei einer Aufheizrate von 100C pro Minute erfolgte.K \ ausland \ OZ05026 doc Table 2 shows the deflagration points, friction and impact sensitivities of the mixtures. The measurement of the friction and impact sensitivities was carried out according to methods of the Federal Institute for Materials Research (BAM), while the measurement of the deflagration points with the thermogravimetric analysis (Mettler) was carried out at a heating rate of 10 Ā° C. per minute.
K \ausland\OZ05026 doc Tabelle 2: Ɯbersicht der Verpuffungstemperaturen, Reib- und SchlagempfindlichkeitenK \ ausland \ OZ05026 doc Table 2: Overview of the deflagration temperatures, friction and impact sensitivities
K \ausland\OZ05026 doc In Tabelle 3 sind die Gewichtsverluste und Verpuffungspunkte nach thermischer Belastung (24 h, 125Ā°C und 400 h, 1 1 O0C) einiger aus den Beispielen ausgewƤhlter Mischungen zusammengefasst. Die Messung des Gewichtsverlustes erfolgte analog dem Holland Test. Die Messung der Verpuffungspunkte erfolgte mit der Thermo- gravimetrie-Analyse (Fa. Mettler) bei einer Aufheizrate von 100C pro Minute.K \ ausland \ OZ05026 doc Table 3 summarizes the weight losses and detonation after thermal exposure (24 h, 125 Ā° C and 400 h, 1 1 0 O C) summarized a number of selected mixtures of Examples. The weight loss was measured analogously to the Holland test. The measurement of the deflagration points was carried out by thermal gravimetric analysis (Mettler) at a heating rate of 10 Ā° C. per minute.
Man erkennt nach 400 h nur geringe Gewichtsverluste von 0,1 bis 0,7 Gew.-% und keine signifikante Ƅnderung der Verpuffungstemperatur nach thermischer Belastung.It can be seen after 400 h only small weight losses of 0.1 to 0.7 wt .-% and no significant change in the deflagration temperature after thermal stress.
Tabelle 3: Ɯbersicht der Gewichtsverluste und VerpuffungstemperaturenTable 3: Overview of weight losses and deflagration temperatures
Die Ergebnisse zeigen, dass die erfindungsgemƤƟ definierten pyrotechnischen Mittel Verpuffungstemperaturen im Bereich von 172 bis 1910C aufweisen und gemƤƟ den Forderungen der Automobilindustrie als stabil anzusehen sind.The results show that the pyrotechnic means defined according to the invention have deflagration temperatures in the range from 172 to 191 Ā° C. and can be regarded as stable according to the requirements of the automotive industry.
Als besonders vorteilhaft, insbesondere auch fĆ¼r die Verwendung in Trennelementen fĆ¼r Batterieklemmen, haben sich daneben folgende Mischungen herausgestellt:As particularly advantageous, especially for use in separating elements for battery terminals, next to the following mixtures have been found:
30 Gew.-% Aminoguanidin-5,5'-azotetrazolat, 27,5 Gew.-% Guanidiniumpikrat, 40 Gew.-% Natriumnitrat, 2 Gew.-% Titan und 0,5 Gew.-% Grafit;30% by weight of aminoguanidine-5,5'-azotetrazolate, 27.5% by weight of guanidinium picrate, 40% by weight of sodium nitrate, 2% by weight of titanium and 0.5% by weight of graphite;
29 Gew.-% Aminoguanidin-5,5'-azotetrazolat, 29 Gew.-% Guanidiniumpikrat, 40 Gew.-% Natriumnitrat, 1 ,5 Gew.-% Bariumcarbonat und 0,5 Gew.-% Aerosil;29% by weight of aminoguanidine-5,5'-azotetrazolate, 29% by weight of guanidinium picrate, 40% by weight of sodium nitrate, 1.5% by weight of barium carbonate and 0.5% by weight of Aerosil;
K \ausland\OZ05026 doc 24 Gew.-% Aminoguanidin-5,5'-azotetrazolat, 24 Gew.-% Guanidiniumpikrat, 50 Gew.-% Natriumnitrat, 1 ,5 Gew.-% Bariumcarbonat und 0,5 Gew.-% Aerosil;K \ ausland \ OZ05026 doc 24% by weight of aminoguanidine-5,5'-azotetrazolate, 24% by weight of guanidinium picrate, 50% by weight of sodium nitrate, 1.5% by weight of barium carbonate and 0.5% by weight of Aerosil;
29 Gew.-% Aminoguanidin-5,5'-azotetrazolat, 29 Gew.-% Guanidiniumpikrat, 40 Gew.-% Natriumnitrat, 1 ,5 Gew.-% Strontiumcarbonat und 0,5 Gew.-% Aerosil.29% by weight of aminoguanidine-5,5'-azotetrazolate, 29% by weight of guanidinium picrate, 40% by weight of sodium nitrate, 1.5% by weight of strontium carbonate and 0.5% by weight of Aerosil.
K \ausland\OZ05026 doc K \ ausland \ OZ05026 doc

Claims

PatentansprĆ¼che claims
1 . Pyrotechnisches Mittel, das als Komponente ein oder mehrere Azotetrazolate enthƤlt.1 . Pyrotechnic agent containing as component one or more azotetrazolates.
2. Pyrotechnisches Mittel nach Anspruch 1 , dadurch gekennzeichnet, dass die Azotetrazolatkomponente ausgewƤhlt ist aus Aminoguandin-5,5'-azotetrazolat2. Pyrotechnic agent according to claim 1, characterized in that the Azotetrazolatkomponente is selected from Aminoguandin-5,5'-azotetrazolat
(AGATZ) und Guanidin-5,5'-azotetrazolat (GATZ) oder Mischungen aus beiden.(AGATZ) and guanidine 5,5'-azotetrazolate (GATZ) or mixtures of both.
3. Pyrotechnisches Mittel nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass der Anteil der Azotetrazolatkomponente 10 bis 99 Gew.-%, bevorzugt 15 bis 60 Gew.-%, besonders bevorzugt 20 bis 50 Gew.-% betrƤgt.3. Pyrotechnic agent according to claim 1 or 2, characterized in that the proportion of Azotetrazolatkomponente 10 to 99 wt .-%, preferably 15 to 60 wt .-%, particularly preferably 20 to 50 wt .-% is.
4. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 3, dadurch gekennzeichnet, dass es 1 bis 90 Gew.-%, bevorzugt 40 bis 85 Gew.-%, besonders bevorzugt 50 bis 80 Gew.-% eines Zusatzstoffes oder Mischungen mehrerer Zusatzstoffe enthƤlt.4. Pyrotechnic agent according to one or more of claims 1 to 3, characterized in that it is 1 to 90 wt .-%, preferably 40 to 85 wt .-%, particularly preferably 50 to 80 wt .-% of an additive or mixtures of several Contains additives.
5. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 4, dadurch gekennzeichnet, dass die Zusatzstoffe ausgewƤhlt sind aus:5. Pyrotechnic agent according to one or more of claims 1 to 4, characterized in that the additives are selected from:
Ammoniumpikrat, Aminoguanidiniumpikrat, Guanidiniumpikrat, Aminoguanidi- niumstyphnat, Guanidiniumstyphnat, Nitroguanidin, Nitroaminoguanidin, Nitrotriazolon, Derivate des Tetrazols und/oder deren Salze, Nitraminotetrazol und/oder dessen Salze, Aminoguanidinnitrat, Diaminoguanidinnitrat, Triaminoguanidinnitrat, Guanidinnitrat, Dicyandiamidinnitrat, Diaminoguanidin-Ammonium picrate, aminoguanidinium picrate, guanidinium picrate, aminoguanidinium tithnate, guanidinium typhnate, nitroguanidine, nitroaminoguanidine, nitrotriazolone, derivatives of tetrazole and / or salts thereof, nitraminotetrazole and / or its salts, aminoguanidine nitrate, diaminoguanidine nitrate, triaminoguanidine nitrate, guanidine nitrate, dicyandiamide nitrate, diaminoguanidine
Azotetrazolat; Nitrate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, Perchlorate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, Peroxide der Alkali- und/oder der Erdalkalimetalle und/oder des Zinks; Aluminium, Titan, Titanhydrid, Bor, Borhydrid, Zirkon, Zirkonhydrid, Silicium, Graphit, Aktivkohle, RuƟ; Cellulose und/oder deren Derivate,azotetrazolate; Nitrates of the alkali and / or alkaline earth metals and / or ammonium, perchlorates of the alkali and / or alkaline earth metals and / or ammonium, peroxides of the alkali and / or alkaline earth metals and / or zinc; Aluminum, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black; Cellulose and / or derivatives thereof,
Polyvinylbutyrale, Polynitropolyphenylen, Polynitrophenylether, Plexigum, Polyvinylacetat und Copolymere; Hexogen, Oktogen; Ferrocen und/oder deren Derivate, Acetonylacetate, Salicylate, Silikate, Kieselgele, Bornitrid.Polyvinyl butyrals, polynitropolyphenylene, polynitrophenyl ethers, plexigums, polyvinyl acetate and copolymers; Hexogen, octogen; Ferrocene and / or derivatives thereof, acetonyl acetates, salicylates, silicates, silica gels, boron nitride.
6. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 5, dadurch gekennzeichnet, dass es 10 bis 90 Gew.-%, bevorzugt 20 bis 706. Pyrotechnic agent according to one or more of claims 1 to 5, characterized in that it is 10 to 90 wt .-%, preferably 20 to 70
Gew.-%, besonders bevorzugt 30 bis 60 Gew.-% eines Oxidationsmittels enthƤlt.Wt .-%, particularly preferably 30 to 60 wt .-% of an oxidizing agent.
K \ausland\OZ05026 doc K \ ausland \ OZ05026 doc
7. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 6, dadurch gekennzeichnet, dass das Oxidationsmittel ausgewƤhlt ist aus einem oder mehreren der Nitrate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, der Perchlorate der Alkali- und/oder Erdalkalimetalle und/oder des Ammoniums, der Peroxide der Alkali- und/oder Erdalkalimetalle und/oder des7. Pyrotechnic agent according to one or more of claims 1 to 6, characterized in that the oxidizing agent is selected from one or more of the nitrates of the alkali and / or alkaline earth metals and / or ammonium, the perchlorates of the alkali and / or alkaline earth metals and / or the ammonium, the peroxides of the alkali and / or alkaline earth metals and / or of the
Zinks.Zinc.
8. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 7, dadurch gekennzeichnet, dass es 10 bis 90 Gew.-%, bevorzugt 10 bis 60 Gew.-%, besonders bevorzugt 15 bis 40 Gew.-% einer stickstoffhaltigen Verbindung enthƤlt.8. Pyrotechnic agent according to one or more of claims 1 to 7, characterized in that it contains 10 to 90 wt .-%, preferably 10 to 60 wt .-%, particularly preferably 15 to 40 wt .-% of a nitrogen-containing compound.
9. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 8, dadurch gekennzeichnet, dass die stickstoffhaltige Verbindung ausgewƤhlt ist aus einem oder mehreren von Ammoniumpikrat, Aminoguanidiniumpikrat, Guanidiniumpikrat, Aminoguanidiniumstyphnat, Guanidiniumstyphnat, Nitrogua- nidin, Nitroaminoguanidin, Nitrotriazolon, Derivate des Tetrazols und/oder deren9. Pyrotechnic agent according to one or more of claims 1 to 8, characterized in that the nitrogen-containing compound is selected from one or more of ammonium picrate, Aminoguanidiniumpikrat, Guanidiniumpikrat, Aminoguanidiniumstyphnat, Guanidiniumstyphnat, nitroguanidine, nitroaminoguanidine, nitrotriazolone, derivatives of tetrazole and / or theirs
Salze, Nitraminotetrazol und/oder dessen Salze, Aminoguanidinnitrat, Diamino- guanidinnitrat, Triaminoguanidinnitrat, Guanidinnitrat, Dicyandiamidinnitrat, Diaminoguanidin-azotetrazolat.Salts, nitraminotetrazole and / or its salts, aminoguanidine nitrate, diamino guanidine nitrate, triaminoguanidine nitrate, guanidine nitrate, dicyandiamide nitrate, diaminoguanidine azotetrazolate.
10. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 9, dadurch gekennzeichnet, dass es 1 bis 90 Gew.-%, bevorzugt 1 bis 60 Gew.-%, besonders bevorzugt 1 bis 40 Gew.-% energetische ZusƤtze enthƤlt.10. Pyrotechnic agent according to one or more of claims 1 to 9, characterized in that it contains 1 to 90 wt .-%, preferably 1 to 60 wt .-%, particularly preferably 1 to 40 wt .-% of energetic additives.
1 1 . Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 10, dadurch gekennzeichnet, dass die energetischen ZusƤtze ausgewƤhlt sind aus einem oder mehreren von Hexogen, Oktogen und/oder Nitrocellulose.1 1. Pyrotechnic agent according to one or more of claims 1 to 10, characterized in that the energetic additives are selected from one or more of hexogen, octogen and / or nitrocellulose.
12. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 1 1 , dadurch gekennzeichnet, dass es 1 bis 80 Gew.-%, bevorzugt 1 bis 40 Gew.-%, besonders bevorzugt 1 bis 15 Gew.-% eines Reduktionsmittel enthƤlt.12. Pyrotechnic agent according to one or more of claims 1 to 1 1, characterized in that it contains 1 to 80 wt .-%, preferably 1 to 40 wt .-%, particularly preferably 1 to 15 wt .-% of a reducing agent.
13. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 12, dadurch gekennzeichnet, dass das Reduktionsmittel ausgewƤhlt ist aus einem oder mehreren von Aluminium, Titan, Titanhydrid, Bor, Borhydrid, Zirkon, Zirkon- hydrid, Silicium, Graphit, Aktivkohle, RuƟ.13. Pyrotechnic agent according to one or more of claims 1 to 12, characterized in that the reducing agent is selected from one or more of aluminum, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black ,
K \ausland\OZ05026 doc K \ ausland \ OZ05026 doc
14. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 13, dadurch gekennzeichnet, dass es 1 bis 80 Gew.-%, bevorzugt 1 bis 40 Gew.-%, besonders bevorzugt 1 bis 20 Gew.-% eines Bindemittels enthƤlt.14. Pyrotechnic agent according to one or more of claims 1 to 13, characterized in that it contains 1 to 80 wt .-%, preferably 1 to 40 wt .-%, particularly preferably 1 to 20 wt .-% of a binder.
15. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 14, dadurch gekennzeichnet, dass das Bindemittel ausgewƤhlt ist aus einem oder mehreren von Cellulose und deren Derivaten, Polyvinylbutyrale, Polynitropolyphe- nylen, Polynitrophenylether, Plexigum, Polyvinylacetat und Copolymeren.15. Pyrotechnic agent according to one or more of claims 1 to 14, characterized in that the binder is selected from one or more of cellulose and its derivatives, polyvinyl butyrals, Polynitopolyphe- nylen, Polynitrophenylether, Plexigum, polyvinyl acetate and copolymers.
16. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 15, dadurch gekennzeichnet, dass es 0,1 bis 20 Gew.-%, bevorzugt 0,1 bis 15 Gew.-%, besonders bevorzugt I bis 10 Gew.-% Abbrandmoderatoren und16. Pyrotechnic agent according to one or more of claims 1 to 15, characterized in that it contains 0.1 to 20 wt .-%, preferably 0.1 to 15 wt .-%, particularly preferably I to 10 wt .-% Abbrandmoderatoren and
Verarbeitungshilfen enthƤlt.Processing aids contains.
17. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 16, dadurch gekennzeichnet, dass die Abbrandmoderatoren und Verarbeitungshilfen ausgewƤhlt sind aus einem oder mehreren von Ferrocen und dessen Derivaten, Acetonylacetaten, Salicylaten, Silikaten, Kieselgelen und/oder Bornitrid.17. Pyrotechnic agent according to one or more of claims 1 to 16, characterized in that the Abbrandmoderatoren and processing aids are selected from one or more of ferrocene and its derivatives, acetonyl acetates, salicylates, silicates, silica gels and / or boron nitride.
18. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 17, dadurch gekennzeichnet, dass es 30 Gew.-% Aminoguanidin-5,5'-azotetrazolat, 27,5 Gew.-% Guanidiniumpikrat, 40 Gew.-% Natriumnitrat, 2 Gew.-% Titan und 0,5 Gew.-% Grafit enthƤlt.18. Pyrotechnic agent according to one or more of claims 1 to 17, characterized in that it contains 30% by weight of aminoguanidine-5,5'-azotetrazolate, 27.5% by weight of guanidinium picrate, 40% by weight of sodium nitrate, 2 Wt .-% titanium and 0.5 wt .-% graphite.
19. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 17, dadurch gekennzeichnet, dass es 29 Gew.-% Aminoguanidin-5,5'-azotetrazolat, 29 Gew.-% Guanidiniumpikrat, 40 Gew.-% Natriumnitrat, 1 ,5 Gew.-% Bariumcarbonat und 0,5 Gew.-% Aerosil enthƤlt.19. Pyrotechnic agent according to one or more of claims 1 to 17, characterized in that it contains 29% by weight of aminoguanidine-5,5'-azotetrazolate, 29% by weight of guanidinium picrate, 40% by weight of sodium nitrate, 1, 5 Wt .-% barium carbonate and 0.5 wt .-% Aerosil contains.
20. Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 17, dadurch gekennzeichnet, dass es 24 Gew.-% Aminoguanidin-5,5"-azotetrazolat,20. Pyrotechnic agent according to one or more of claims 1 to 17, characterized in that it contains 24% by weight of aminoguanidine-5,5 "-azotetrazolate,
24 Gew.-% Guanidiniumpikrat, 50 Gew.-% Natriumnitrat, 1 ,5 Gew.-% Bariumcarbonat und 0,5 Gew.-% Aerosil enthƤlt.24 wt .-% guanidinium, 50 wt .-% sodium nitrate, 1, 5 wt .-% barium carbonate and 0.5 wt .-% Aerosil contains.
21 . Pyrotechnisches Mittel nach einem oder mehreren der AnsprĆ¼che 1 bis 17, dadurch gekennzeichnet, dass es 29 Gew.-% Aminoguanidin-5,5'-azotetrazolat,21. Pyrotechnic agent according to one or more of Claims 1 to 17, characterized in that it contains 29% by weight of aminoguanidine-5,5'-azotetrazolate,
K \ausland\OZ05026 doc 29 Gew.-% Guanidiniumpikrat, 40 Gew.-% Natriumnitrat, 1 ,5 Gew.-% Strontiumcarbonat und 0,5 Gew.-% Aerosil enthƤlt.K \ ausland \ OZ05026 doc 29 wt .-% guanidinium, 40 wt .-% sodium nitrate, 1, 5 wt .-% strontium carbonate and 0.5 wt .-% Aerosil contains.
22. Pyrotechnisches Mittel nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass der Anteil der Azotetrazolatkomponente 100 Gew.-% betrƤgt.22. Pyrotechnic agent according to claim 1 or 2, characterized in that the proportion of azotetrazolate component is 100 wt .-%.
23. Verwendung eines pyrotechnischen Mittels nach einem oder mehreren der AnsprĆ¼che 1 bis 22 als thermisches FrĆ¼hzĆ¼ndmittel.23. Use of a pyrotechnic agent according to one or more of claims 1 to 22 as a thermal ignition agent.
24. Verwendung eines pyrotechnischen Mittels nach einem oder mehreren der AnsprĆ¼che 1 bis 22 als thermische Sicherung.24. Use of a pyrotechnic agent according to one or more of claims 1 to 22 as a thermal fuse.
25. Verwendung eines pyrotechnischen Mittels nach einem oder mehreren der AnsprĆ¼che 1 bis 22 in Kraftfahrzeugsicherheitssystemen.25. Use of a pyrotechnic agent according to one or more of claims 1 to 22 in motor vehicle safety systems.
26. Verwendung eines pyrotechnischen Mittels nach einem oder mehreren der AnsprĆ¼che 1 bis 22 in Gasgeneratoren.26. Use of a pyrotechnic agent according to one or more of claims 1 to 22 in gas generators.
27. Verwendung eines pyrotechnischen Mittels nach einem oder mehreren der AnsprĆ¼che 1 bis 22 in Trennelementen, vorzugsweise fĆ¼r Batterieklemmen.27. Use of a pyrotechnic agent according to one or more of claims 1 to 22 in separating elements, preferably for battery terminals.
K \ausland\OZ05026 doc K \ ausland \ OZ05026 doc
EP06763483A 2005-06-02 2006-06-02 Pyrotechnic agent Not-in-force EP1890986B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005025746 2005-06-02
DE102006013622 2006-03-22
PCT/EP2006/062862 WO2006128910A1 (en) 2005-06-02 2006-06-02 Pyrotechnic agent

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WO2006128910A1 (en) 2006-12-07
US20090133787A1 (en) 2009-05-28
JP2008542175A (en) 2008-11-27
JP5388573B2 (en) 2014-01-15
US10968147B2 (en) 2021-04-06
EP1890986B1 (en) 2013-01-16

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