EP1851498B1 - Slotted tube with reversible usage for heat exchangers - Google Patents
Slotted tube with reversible usage for heat exchangers Download PDFInfo
- Publication number
- EP1851498B1 EP1851498B1 EP03743918.9A EP03743918A EP1851498B1 EP 1851498 B1 EP1851498 B1 EP 1851498B1 EP 03743918 A EP03743918 A EP 03743918A EP 1851498 B1 EP1851498 B1 EP 1851498B1
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- European Patent Office
- Prior art keywords
- tubes
- use according
- ribs
- ranging
- tube
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
- F28F1/34—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending obliquely
- F28F1/36—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending obliquely the means being helically wound fins or wire spirals
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/40—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only inside the tubular element
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C37/00—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
- B21C37/06—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
- B21C37/15—Making tubes of special shape; Making tube fittings
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B39/00—Evaporators; Condensers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
Definitions
- the invention relates to the field of tubes for heat exchangers, and more particularly the field of heat exchangers operating in evaporation / condensation and in reversible mode.
- the invention relates to the use of heat exchangers defined in claim 1.
- Japanese demand no. 57-58088 discloses V-grooved tubes, with H between 0.02 and 0.2 mm, and with an angle ⁇ between 4 and 15 °. Neighboring tubes are described in Japanese Application No. 57-58094 .
- Japanese demand no. 52-38663 discloses tubes with V or U grooves, with H between 0.02 and 0.2 mm, a pitch P between 0.1 and 0.5 mm and an angle ⁇ between 4 and 15 °.
- the patent U.S. 4,044,797 describes grooved tubes in V or U adjacent to the preceding tubes.
- Japanese utility model no. 55-180186 describes tubes with trapezoidal grooves and triangular ribs, with a height H of 0.15 to 0.25 mm, a pitch P of 0.56 mm, an apex angle ⁇ (angle called ⁇ in this document) typically equal to 73 °, an angle ⁇ of 30 °, and an average thickness of 0.44 mm.
- Licences U.S. Patent No. 4,545,428 and no 4480684 describe tubes with V-grooves and triangular ribs, with the height H between 0.1 and 0.6 mm, a pitch P between 0.2 and 0.6 mm, an apex angle ⁇ of between 50 and 100 °, a helix angle ⁇ between 16 and 35 °.
- Japanese Patent No. 62-25959 describes tubes with trapezoidal grooves and ribs, with a groove depth H of between 0.2 and 0.5 mm, a pitch P of between 0.3 and 1.5 mm, the average width of the grooves being at least equal to the average width of the ribs.
- the pitch P is 0.70 mm and the helix angle ⁇ is 10 °.
- the European patent EP-B1-701 680 in the name of the applicant, describes grooved tubes, with grooves typically flat bottom and with ribs of different height H, helix angle ⁇ between 5 and 50 °, apex angle ⁇ between 30 and 60 °, to obtain better performances after the crimping of the tubes and assembly in the exchangers.
- the object of the present invention relates to the use of tubes for reversible heat exchangers, that is to say a use where tubes or exchangers are used with refrigerants with change of applications.
- phase sometimes in evaporation, sometimes in condensation, that is to say either to cool, for example as air conditioners, or to heat, for example as heating means, typically air or a secondary fluid.
- the present invention relates to the use of tubes which not only have an excellent compromise between thermal performance in evaporative and refrigerant condensation mode, but which, moreover, intrinsically have high performance as well. in evaporation only in condensation.
- the applicant has therefore sought economic tubes and exchangers, with a relatively low weight per meter, and high heat exchange performance, both in evaporation and in condensation.
- the characteristic defined under a) defines the outer diameter range of tubes in the range of application targeted by the tubes according to the invention.
- the characteristic under d), relative to the apex angle ⁇ , provides that this angle must be chosen in a relatively narrow range (20 ° - 28 °) and with relatively low ⁇ -apex angle values.
- a low ⁇ -angle value is preferable for improving the heat transfer performance to decrease the pressure drop and to decrease the weight of the tube / m. It is with trapezoidal ribs that the angle ⁇ may be the weakest.
- the lower limit is essentially related to the manufacture of grooved tubes according to the invention to maintain a high rate of production.
- the thickness Tf of the tube at the bottom of the groove may vary according to the diameter De, so as to have both sufficient mechanical properties, including resistance to internal pressure, a maximum saving in material, and therefore optimized material cost, and a weight per meter as low as possible.
- This thickness Tf is 0.28 mm for a 9.55 mm diameter tube De, and 0.35 mm for a tube 12.7 mm in diameter De.
- the different curves of the figure 4 give, in condensation at 30 ° C with fluid R22, the exchange coefficient Hi (in W / m 2 .K) in ordinate as a function of the fluid flow G, in abscissa (in Kg / m 2 .s).
- the different curves of the figure 5 give, in evaporation at 0 ° C of the fluid R22, the exchange coefficient Hi (in W / m 2 .K) in ordinate as a function of the fluid flow G, in abscissa (in Kg / m 2 .s).
- the Figures 6 and 7 indicate, on the ordinate, the exchange refrigeration power measured in watts of a battery of tubes and fins as a function, on the abscissa of the frontal velocity of the air which circulates between the fins expressed in m / s.
- the figure 6 is relative to the condensation measurements on the same battery as before, with an air inlet temperature of 23.5 ° C and a condensing temperature of 36 ° C of the refrigerant R22.
- the figure 7 is relative to the evaporation measurements on the same battery, with an inlet temperature of 26.5 ° C, and an evaporation temperature of 6 ° C of the refrigerant R22.
- the figure 8 is a schematic perspective view of the battery (4) of tubes (1) with fins (5) used for testing.
- the figure 9 graphically represents on the ordinate the cooling capacity gain in evaporation of the batteries, according to the figure 7 , with a reference air speed of 1.25 m / s, as a function of the Cavallini factor on the abscissa for the various tubes tested: smooth tube S, tube E according to the invention, and tubes A and B according to FIG. state of the art.
- the figure 10 is a graph indicating, on the ordinate, the heat exchange coefficient Hi (W / m 2 .K) on evaporation tubes with the refrigerant R407C, as a function of the weight percentage of vapor in the refrigerant, on the abscissa, the temperature evaporation rate of 5 ° C.
- the measurements were made with a heat flux of 12 kW / m 2 and a mass flow rate of 100 or 200 kg / m 2 .s of refrigerant R407C, as shown in the figure, on tubes of diameter D equal to 9 52mm.
- the figure 11 is a view of an inner surface portion of a grooved tube according to the invention provided with an axial counter-groove (30), with, below, its schematic representation.
- said succession may be an alternation of ribs of height H1 and ribs of height H2 separated by a generally flat groove bottom.
- the grooved tubes according to the invention do not necessarily include such an alternation of differentially height ribs as on the Figures 2a to 2c , the ribs may have substantially the same height.
- a range according to the invention of the apex angle ⁇ ranges from 20 ° to 28 °, an even more restricted range from 22 ° to 25 ° ensuring the best compromise. between the technical performance requirements and those related to the expansion of the tubes for attachment to the fins of the batteries.
- a preferred range of the helix angle ⁇ can range from 22 ° to 30 °, a still more restricted range from 25 ° to 28 ° ensuring the best compromise between technical performance requirements and those related to pressure drop.
- This angle can vary with the inner diameter Di: it has been found advantageous to have a ⁇ / Di ratio greater than 2.40 ° / mm, and preferably greater than 3 ° / mm.
- said ribs have a "trapezium" type profile with a base of width L N and a vertex, connected by lateral edges forming between them said apex angle ⁇ , as illustrated in FIG. Figure 2c said apex comprising a substantially flat central portion, typically parallel to said base, but possibly sloping with respect to said base.
- said vertex of said rib forming a short side of the trapezium may have rounded edges or not, that is to say, very small radius of curvature, these edges forming a connection of said vertex audits side edges.
- Said rounded edges may have a radius of curvature typically ranging from 40 .mu.m to 100 .mu.m, and preferably ranging from 50 .mu.m to 80 .mu.m, as illustrated in FIGS. Figures 2a to 2c .
- These ranges of radius of curvature correspond to a compromise between the thermal performance of the tubes and the feasibility of the tubes, the tools for making the tubes with the smallest radii of curvature having the most tendency to wear out.
- the radius of: curvature can be typically less than 50 microns, and even less than 20 microns.
- said ribs and said flat bottom of said grooves may be connected with a radius of curvature less than 50 microns, and preferably less than 20 microns. In this case, it seems that there is better separation of the liquid refrigerant film from the inner wall of the tube, which promotes heat exchange.
- the tubes used according to the invention have even in the absence of axial grooving, a Cavallini factor of at least 3.5. They may advantageously have a Cavallini factor of at least 4.0.
- the tubes according to the invention may further comprise an axial groove (30) creating in said ribs notches with a typically triangular profile with a rounded top, said top having an angle ⁇ ranging from 25 to 65 °, said lower part or top is at a distance h from the bottom of said grooves from 0 to 0.2 mm.
- Such axial grooving can be obtained once formed said ribs by passage of a grooving wheel in the axial direction.
- the grooved tubes according to the invention may be made of copper and alloys of copper, aluminum and aluminum alloys. These tubes can be obtained typically by grooving tubes, or possibly by flat grooving of a metal strip and forming a welded tube.
- the tests were carried out on copper tubes of 8.0 mm or 9.52 mm of external diameter.
- the "E” tube of the invention was manufactured according to the Figures 2a to 2c with a diameter of 8.0 mm, and according to the figure 3 with a diameter of 9.52 mm, as well as comparative "S” or smooth, "C", “D”, tubes which have a high ⁇ helix angle (at least equal to 20 °), intended for the condensation according to the state of the art, and comparative tubes "A” and “B”, which have a high apex angle ⁇ (at least equal to 40 °) and a low helix angle ⁇ (at most equal at 18 °), intended for evaporation according to the state of the art.
- the tubes E, A, B, C were made by grooving a smooth copper tube - S tube, while the D tube was manufactured by flat grooving a metal band and then forming a welded tube.
- Tube type H in mm angle ⁇ angle ⁇ NOT Rib type Tf mm L R / L N E Fig.3 0.20 25 25 66 V 0.30 2.3 B from 0.20 to 0.17 40 16 74 Alternating triangles 0.30 1.88 AT 0.20 50 18 60 triangular 0.30 2.00 VS 0.20 40 30 60 triangular 0.30 1.94 D 0.20 15 20 72 Double crossed ribs * 0.30 3.66 s ------- ------- ------- -- -- -- -- -- Smooth tube 0.30 ------- * 72 main ribs of helix angle ⁇ equal to + 20 ° interspersed with secondary grooves inclined at an angle of -20 ° relative to the axis of the tube, the depth of the grooves being substantially equal to the height of the ribs main.
- Winged batteries were manufactured according to the figure 8 from these tubes, placing the tubes in the flanges of the fins and then pressing the tube against the flange of the flanges by expansion of the tube with a conical mandrel.
- These batteries form a block of dimensions: 400 mm x 400 mm x 65 mm, with a density of 12 fins per 25.4 mm, the battery comprising 3 rows of 16 tubes, and the refrigerant being the R22.
- the tubes and exchangers or batteries of tubes according to the invention have properties superior to the analogous products of the state of the art, both in evaporation and in condensation.
- the tubes according to the invention do not only constitute a good compromise of performance in evaporation and condensation, but also have, in absolute terms, excellent performance compared to the tubes of the state. of the technique used in evaporation and those used in condensation, which is of great interest in practice.
- the values obtained with the tubes according to the invention correspond to a gain ranging from 3.7 to 6.7% compared to the tubes according to the state of the art, taken from same diameter and same thickness Tf, which is considered very important.
- the tubes according to the invention of the type E can be advantageously manufactured by high-speed grooving of smooth non-grooved copper tube, typically at a grooving speed close to that used for the type B tubes, namely at least 80 m / min.
- the invention has great advantages. Indeed, on the one hand, the tubes and batteries used according to the invention have high intrinsic performances. On the other hand, these performances are high in both evaporation and condensation, which allows the use of the same tube for these two applications. In addition, the tubes have a relatively low weight per meter, which is very advantageous both from a practical point of view and from the economic point of view with a relatively low material cost.
- tubes used according to the invention do not require specific manufacturing means. They can be manufactured with standard equipment and especially with the usual production rates.
Description
L'invention concerne le domaine des tubes pour échangeurs de chaleur, et plus spécialement le domaine des échangeurs de chaleur fonctionnant en évaporation/condensation et en mode réversible. L'invention se rapporte à l'utilisation d'échangeurs de chaleur définie la revendication 1.The invention relates to the field of tubes for heat exchangers, and more particularly the field of heat exchangers operating in evaporation / condensation and in reversible mode. The invention relates to the use of heat exchangers defined in
Le document
- a) De= 9,52nm; b) N= 60;
- c) H= 0,2 mm;
- d) 30°<d<60°;
- e) β= 18°;
- f) le facteur de cavallini est égal a 3.15.
- a) De = 9.52nm; (b) N = 60;
- c) H = 0.2 mm;
- d) 30 ° <d <60 °;
- e) β = 18 °;
- f) the cavallini factor is equal to 3.15.
De plus, l'on connaît un grand nombre de documents décrivant la géométrie de tubes rainurés utilisés dans les échangeurs de chaleur.In addition, there is a large number of documents describing the geometry of grooved tubes used in heat exchangers.
A titre d'exemple, on peut citer la demande de brevet
- un rapport H/Di compris entre 0,02 et 0,03, H désignant la profondeur des rainures (ou la hauteur des nervures), et Di le diamètre intérieur du tube rainuré,
- un angle d'hélice β par rapport à l'axe de tube compris entre 7 et 30°,
- un rapport S/H compris entre 0,15 et 0,40, avec S désignant la section transversale de la rainure,
- un angle d'apex α des nervures compris entre 30 et 60°.
- an H / Di ratio of between 0.02 and 0.03, H denoting the depth of the grooves (or the height of the ribs), and Di the inside diameter of the grooved tube,
- a helix angle β with respect to the tube axis of between 7 and 30 °,
- a S / H ratio of between 0.15 and 0.40, with S denoting the cross section of the groove,
- an apex angle α of ribs between 30 and 60 °.
La demande japonaise n°
Des tubes voisins sont décrits dans la demande japonaise n°
Neighboring tubes are described in Japanese Application No.
La demande japonaise n°
Le brevet
The patent
Le modèle d'utilité japonais n°
Les brevets
Le brevet japonais n°
Enfin, le brevet européen
D'une manière générale, les performances techniques et économiques des tubes, qui résultent du choix de la combinaison de moyens définissant les tubes (H, P, α, β, forme des rainures et nervures, etc...), doivent satisfaire à quatre exigences concernant :
- d'une part, les caractéristiques relatives au transfert de chaleur (coefficient d'échange thermique), domaine dans lequel les tubes rainurés sont très supérieurs aux tubes non rainurés, de sorte qu'à échange thermique équivalent, la longueur de tube rainuré nécessaire sera moindre que celle de tube non rainuré,
- d'autre part, les caractéristiques relatives aux pertes de charge, de faibles pertes de charge permettant d'utiliser des pompes ou compresseurs de plus faible puissance, encombrement et coût,
- en outre, les caractéristiques relatives aux propriétés mécaniques des tubes, typiquement en relation avec la nature des alliages utilisés ou avec l'épaisseur moyenne des tubes, épaisseur qui conditionne le poids du tube par unité de longueur, et donc influe sur son prix de revient.
- enfin, la faisabilité industrielle des tubes et la vitesse de production qui conditionne le prix de revient du tube chez le fabricant de tubes.
- on the one hand, the characteristics relating to the heat transfer (heat exchange coefficient), area in which the grooved tubes are much higher than the non-grooved tubes, so that equivalent heat exchange, the length of grooved tube necessary will be less than that of ungrooved tube,
- on the other hand, the characteristics relating to pressure drops, low pressure drops allowing the use of pumps or compressors of lower power, size and cost,
- in addition, the characteristics relating to the mechanical properties of the tubes, typically in relation to the nature of the alloys used or the average thickness of the tubes, which thickness determines the weight of the tube per unit length, and thus influences its cost price .
- finally, the industrial feasibility of the tubes and the speed of production which conditions the cost price of the tube at the tube manufacturer.
D'une part, comme cela résulte de l'état de la technique, il y a un grand nombre et une très grande diversité d'enseignements en ce qui concerne les tubes rainurés, sachant qu'ils visent généralement l'optimisation de l'échange thermique et la diminution de perte de charge.
D'autre part, chacun de ces enseignements offre lui-même le plus souvent une large étendue de possibilités, les paramètres étant généralement définis par des plages de valeurs relativement larges.
Enfin, ces enseignements concernent, quand cela est spécifié, les échanges avec fluide frigorigène, fluide qui, typiquement, s'évapore ou se condense dans le circuit frigorifique, le fluide ayant un comportement différent en évaporation et en condensation. Jusqu'à présent, ces enseignements concernent des tubes rainurés pour échangeurs fonctionnant soit en condensation, soit en évaporation.On the one hand, as is the result of the state of the art, there is a great number and a great diversity of teachings with regard to grooved tubes, knowing that they generally aim at the optimization of the heat exchange and reduction of pressure loss.
On the other hand, each of these teachings itself usually offers a wide range of possibilities, the parameters being generally defined by relatively wide ranges of values.
Finally, these teachings concern, where specified, exchanges with refrigerant fluid which typically evaporates or condenses in the refrigerant circuit, the fluid having a different behavior in evaporation and condensation. So far, these teachings relate to grooved tubes for exchangers operating either in condensation or in evaporation.
En définitive, l'homme du métier a déjà beaucoup de difficultés pour tirer la quintessence de l'état de la technique, parmi un si grand nombre de données, parfois contradictoires.
L'homme du métier sait par contre qu'un tube typique du commerce, à nervures triangulaires comme représenté à la
On the other hand, a person skilled in the art knows that a typical commercial tube with triangular ribs as shown in FIG.
De manière à répondre à une demande du marché, l'objet de la présente invention concerne l'utilisation de tubes pour échangeurs à applications réversibles, c'est à dire une utilisation oú des tubes ou échangeurs sont utilisés avec des fluides frigorigènes à changement de phase, tantôt en évaporation, tantôt en condensation, c'est-à-dire soit pour refroidir, par exemple comme climatiseurs, soit pour réchauffer, par exemple comme moyens de chauffage, typiquement de l'air ou un fluide secondaire.In order to meet a market demand, the object of the present invention relates to the use of tubes for reversible heat exchangers, that is to say a use where tubes or exchangers are used with refrigerants with change of applications. phase, sometimes in evaporation, sometimes in condensation, that is to say either to cool, for example as air conditioners, or to heat, for example as heating means, typically air or a secondary fluid.
Plus particulièrement, la présente invention a pour objet l'utilisation de tubes qui, non seulement présentent un excellent compromis entre les performances thermiques en mode évaporation et en mode condensation de fluide frigorigène, mais qui, de plus, présentent intrinsèquement des performances élevées aussi bien en évaporation qu'en condensation.More particularly, the present invention relates to the use of tubes which not only have an excellent compromise between thermal performance in evaporative and refrigerant condensation mode, but which, moreover, intrinsically have high performance as well. in evaporation only in condensation.
La demanderesse a donc recherché des tubes et échangeurs à la fois économiques, avec un poids par mètre relativement peu élevé, et des performances d'échange thermique élevées, à la fois en évaporation et en condensation.The applicant has therefore sought economic tubes and exchangers, with a relatively low weight per meter, and high heat exchange performance, both in evaporation and in condensation.
Selon l'invention, les tubes métalliques rainurés, d'épaisseur Tf en fond de rainure, de diamètre extérieur De, typiquement destinés à la fabrication d'échangeurs de chaleur fonctionnant en évaporation ou en condensation ou en mode réversible et utilisant un fluide frigorigène à changement de phase, rainurés intérieurement par N nervures hélicoïdales d'angle d'apex α, de hauteur H, de largeur de base LN et d'angle d'hélice β, deux nervures consécutives étant séparées par une rainure typiquement à fond plat de largeur LR, avec un pas P égal LR + LN , sont tels que,
- a) le diamètre extérieur De est compris entre 4 et 20 mm,
- b) le nombre N de nervures va de 46 à 98, en fonction notamment du diamètre De,
- c) la hauteur H des nervures va de 0,18 mm à 0,40 mm, en fonction notamment du diamètre De,
- d) l'angle d'apex α tel que 20° ≤ α < 28°,
- e) l'angle d'hélice β va de 18° à 35°, ledit tube présentant un facteur de Cavalini au moins égal à 3.5,
- a) the outer diameter De is between 4 and 20 mm,
- b) the number N of ribs ranges from 46 to 98, in particular according to the diameter De,
- c) the height H of the ribs ranges from 0.18 mm to 0.40 mm, depending in particular on the diameter De,
- d) the apex angle α such that 20 ° ≤ α <28 °,
- e) the helix angle β is from 18 ° to 35 °, said tube having a Cavalini factor of at least 3.5,
Suite à ses travaux de recherche, la demanderesse a réussi à résoudre les problèmes posés par la combinaison de moyens et l'ensemble de caractéristiques qui précèdent.As a result of her research, the Applicant has successfully solved the problems posed by the combination of means and the preceding set of features.
La caractéristique définie sous a) définit la plage de diamètre extérieur De des tubes dans le domaine d'application visé par les tubes selon l'invention.The characteristic defined under a) defines the outer diameter range of tubes in the range of application targeted by the tubes according to the invention.
La caractéristique sous b), relative au nombre N de rainures, et donc au pas P correspondant, spécifie que ce nombre doit être relativement élevé. Les essais de la demanderesse avec des batteries à ailettes ont montré que ce nombre de rainures a une grande influence sur la performance thermique des échangeurs.The characteristic under b), relative to the number N of grooves, and therefore to the corresponding pitch P, specifies that this number must be relatively high. The applicant's tests with finned batteries have shown that this number of grooves has a great influence on the heat performance of the exchangers.
Ainsi, par exemple, pour un diamètre de tube De 9,52 mm :
- quand le nombre N est inférieur à 46, il a été observé que la performance de l'échangeur chutait considérablement.
- en ce qui concerne la limite supérieure du nombre N, elle est essentiellement d'ordre technologique et pratique, et dépend des possibilités technique de fabrication des tubes rainurés, cette limite supérieure varie donc, et augmente avec le diamètre De du tube.
- when the number N is less than 46, it was observed that the performance of the exchanger fell considerably.
- as regards the upper limit of the number N, it is essentially of a technological and practical nature, and depends on the technical possibilities of manufacture of the grooved tubes, this upper limit therefore varies, and increases with the diameter De of the tube.
En ce qui concerne la caractéristique sous c), relative à la hauteur H des nervures ou profondeur des rainures, les limites de H résultent des observations suivantes :
- pour des valeurs de H supérieures à 0,40 mm, il a été noté une faisabilité technique moindre, car il n'est pas aisé de fabriquer des nervures de très grande hauteur, et il a été noté en outre une augmentation de la perte de charge,
- pour des valeurs de H inférieures à 0,20 mm, il a été noté que la performance d'échange thermique diminue trop et devient insuffisante.
- for values of H greater than 0.40 mm, a lower technical feasibility was noted, as it is not easy to make very high ribs, and there was also an increase in the loss of charge,
- for values of H less than 0.20 mm, it was noted that the heat exchange performance decreases too much and becomes insufficient.
La caractéristique sous d), relative à l'angle d'apex α, prévoit que cet angle doit être choisi dans une plage relativement étroite (20° - 28°) et avec de valeurs d'angle d'apex α relativement faibles.
D'une part, une faible valeur d'angle α est préférable pour améliorer la performance du transfert de chaleur pour diminuer la perte de charge et pour diminuer le poids du tube / m. C'est avec des nervures trapézoïdales que l'angle α peut être le plus faible. Cependant, la limite inférieure est essentiellement lié à la fabrication de tubes rainurés selon l'invention pour conserver une haute cadence de production.The characteristic under d), relative to the apex angle α, provides that this angle must be chosen in a relatively narrow range (20 ° - 28 °) and with relatively low α-apex angle values.
On the one hand, a low α-angle value is preferable for improving the heat transfer performance to decrease the pressure drop and to decrease the weight of the tube / m. It is with trapezoidal ribs that the angle α may be the weakest. However, the lower limit is essentially related to the manufacture of grooved tubes according to the invention to maintain a high rate of production.
La caractéristique sous e), relative à l'angle d'hélice β, montre que cet angle doit être au moins égal à 18° pour résoudre les problèmes de l'invention, et au plus égal à 35° à cause de l'augmentation significative des pertes de charge, notamment avec certains fluides frigorigènes, par exemple le fluide frigorigène R134a.The characteristic under e), relative to the helix angle β, shows that this angle must be at least equal to 18 ° to solve the problems of the invention, and at most equal to 35 ° to because of the significant increase in pressure losses, especially with certain refrigerants, for example R134a refrigerant.
En ce qui concerne l'épaisseur Tf du tube en fond de rainure, elle peut varier en fonction du diamètre De, de manière à avoir à la fois des propriétés mécaniques suffisantes, notamment une résistance à la pression interne, une économie de matière maximum, et donc un coût matière optimisé, et un poids au mètre le plus faible possible. Cette épaisseur Tf est de 0,28 mm pour un tube de 9,55 mm de diamètre De, et de 0,35 mm pour un tube de 12,7 mm de diamètre De.Regarding the thickness Tf of the tube at the bottom of the groove, it may vary according to the diameter De, so as to have both sufficient mechanical properties, including resistance to internal pressure, a maximum saving in material, and therefore optimized material cost, and a weight per meter as low as possible. This thickness Tf is 0.28 mm for a 9.55 mm diameter tube De, and 0.35 mm for a tube 12.7 mm in diameter De.
L'ensemble de ces moyens permet de définir une sélection de tubes, tubes spécifiques particulièrement adaptés aux échangeurs avec fluides frigorigènes à changement de phase, de manière à avoir simultanément un coefficient d'échange thermique élevé en évaporation et en condensation, une faible perte de charge et un tube le plus léger possible.All of these means make it possible to define a selection of tubes, specific tubes particularly adapted to exchangers with phase-change refrigerants, so as to simultaneously have a high heat exchange coefficient in evaporation and condensation, a small loss of charge and a tube as light as possible.
-
Les
figures 1a et 1b sont destinées à illustrer la signification des différents paramètres utilisés pour définir les tubes utilisés dans la méthode selon l'invention.TheFigures 1a and 1b are intended to illustrate the meaning of the various parameters used to define the tubes used in the method according to the invention. -
La
figure 1a représente une vue partielle d'un tube rainuré (1), en coupe partielle selon l'axe du tube, de manière à illustrer l'angle d'hélice β.Thefigure 1a is a partial view of a grooved tube (1), in partial section along the axis of the tube, so as to illustrate the helix angle β. -
La
figure 1b représente une vue partielle d'un tube rainuré (1), en coupe partielle perpendiculairement à l'axe du tube, de manière à illustrer le cas d'un tube comprenant une succession de nervures (2) de hauteur H, nervures de forme sensiblement triangulaire, de largeur LN à la base et d'angle d'apex α, séparées par des rainures (3) de forme sensiblement trapézoïdale et de largeur LR, LR étant la distance entre deux rainures nervures. Ce tube a une épaisseur Tf, un diamètre extérieur De, un diamètre intérieur Di et un pas P égal LR + LN.Thefigure 1b represents a partial view of a grooved tube (1), in partial section perpendicular to the axis of the tube, so as to illustrate the case of a tube comprising a succession of ribs (2) of height H, substantially shaped ribs triangular, of width L N at the base and apex angle α, separated by grooves (3) of substantially trapezoidal shape and width L R , L R being the distance between two grooves ribs. This tube has a thickness Tf, an outside diameter De, an inner diameter Di and a pitch P equal to L R + L N. -
Les
figures 2a à 2c sont des coupes partielles d'un tube de 8 mm de diamètre De et de 0,26 mm d'épaisseur Tf, selon un exemple de réalisation de l'invention, dans lequel les nervures forment une alternance de nervures trapézoïdales de hauteur H1 et de hauteur H2 < H1, à différentes échelles.TheFigures 2a to 2c are partial sections of a tube 8 mm in diameter and 0.26 mm thick Tf, according to an exemplary embodiment of the invention, in which the ribs form an alternation of trapezoidal ribs of height H1 and height H2 <H1, at different scales. -
La
figure 2a représente 3 nervures (2) complètes et 2 nervures partielles, espacées par des rainures (3), et porte une échelle "200 µm".Thefigure 2a represents 3 complete ribs (2) and 2 partial ribs, spaced by grooves (3), and carries a "200 μm" scale. -
La
figure 2b représente 2 nervures complètes et porte une échelle "100 µm".Thefigure 2b represents 2 complete ribs and carries a scale "100 μm". -
La
figure 2c représente 1 seule nervure (2) et porte une échelle "50 µm".TheFigure 2c represents 1 single rib (2) and carries a scale "50 μm". -
La
figure 3 représente une coupe partielle d'un tube de 9,52 mm de diamètre De et de 0,30 mm d'épaisseur Tf selon l'invention.Thefigure 3 represents a partial section of a 9.52 mm diameter tube De and 0.30 mm thick Tf according to the invention.
Les différentes courbes de la
Les différentes courbes de la
Ces courbes correspondent à une tube selon l'invention - noté E selon la
The different curves of the
These curves correspond to a tube according to the invention - noted E according to the
Les
Ces courbes correspondent à une tube selon l'invention - noté E, selon les
La batterie (4), schématisée sur la
La
La
These curves correspond to a tube according to the invention - noted E, according to
The battery (4), schematized on the
The
The
La
La
The
La
La
Selon une modalité de l'invention illustrée sur les
Typiquement, et comme illustré sur ces figures, ladite succession peut être une alternance de nervures de hauteur H1 et de nervures de hauteur H2 séparées par un fond de rainure typiquement plat.
Cependant, comme illustré sur la
Typically, and as illustrated in these figures, said succession may be an alternation of ribs of height H1 and ribs of height H2 separated by a generally flat groove bottom.
However, as shown on the
Typiquement, dans le cas de tubes de 9,52 mm de diamètre De, on peut avoir :
- H allant de 0,18 à 0,3 mm,
- et/ou N inférieur à 75, et allant de préférence de 64 à 70.
- H allant de 0,25 à 0,40 mm,
- N allant de 70 à 98.
- H ranging from 0.18 to 0.3 mm,
- and / or N less than 75, and preferably from 64 to 70.
- H ranging from 0.25 to 0.40 mm,
- N ranging from 70 to 98.
En ce qui concerne l'angle d'apex α, une plage selon l'invention de l'angle d'apex α va de 20° à 28°, une plage encore plus restreinte allant de 22° à 25° assurant le meilleur compromis entre les exigences en matière de performance technique et celles liées à l'expansion des tubes en vue de leur solidarisation aux ailettes des batteries.With regard to the apex angle α, a range according to the invention of the apex angle α ranges from 20 ° to 28 °, an even more restricted range from 22 ° to 25 ° ensuring the best compromise. between the technical performance requirements and those related to the expansion of the tubes for attachment to the fins of the batteries.
En ce qui concerne l'angle d'hélice β, une plage préférée de l'angle d'hélice β peut aller de 22° à 30°, une plage encore plus restreinte allant de 25° à 28° assurant le meilleur compromis entre les exigences en matière de performance technique et celles liées à la perte de charge. Cet angle peut varier avec le diamètre intérieur Di : il a été trouvé avantageux d'avoir un rapport β/Di supérieur à 2,40 °/mm, et de préférence supérieur à 3 °/mm.With regard to the helix angle β, a preferred range of the helix angle β can range from 22 ° to 30 °, a still more restricted range from 25 ° to 28 ° ensuring the best compromise between technical performance requirements and those related to pressure drop. This angle can vary with the inner diameter Di: it has been found advantageous to have a β / Di ratio greater than 2.40 ° / mm, and preferably greater than 3 ° / mm.
De préférence, lesdites nervures ont un profil de type "trapèze" avec une base de largeur LN et un sommet, raccordés par des bords latéraux faisant entre eux ledit angle d'apex α, comme illustré sur la
Quelle que soit le cas, ledit sommet de ladite nervure formant un petit côté du trapèze peut présenter des bords arrondis ou non, c'est-à-dire à très faible rayon de courbure, ces bords formant un raccordement dudit sommet audits bords latéraux.
Lesdits bords arrondis peuvent présenter un rayon de courbure allant typiquement de 40µm à 100 µm, et allant de préférence de 50 µm à 80µm, comme illustré sur les
Lorsque les bords ne sont pas arrondis, comme illustré sur la
Whatever the case, said vertex of said rib forming a short side of the trapezium may have rounded edges or not, that is to say, very small radius of curvature, these edges forming a connection of said vertex audits side edges.
Said rounded edges may have a radius of curvature typically ranging from 40 .mu.m to 100 .mu.m, and preferably ranging from 50 .mu.m to 80 .mu.m, as illustrated in FIGS.
When the edges are not rounded, as shown on the
Selon l'invention, la largeur LR du fond plat de ladite rainure et la largeur LN de la base de ladite nervure peuvent être telles que LR = b.LN avec b allant de 1 à 2, et de préférence de 1,1 à 1,8, de manière à avoir un tube présentant un poids par mètre relativement bas.According to the invention, the width L R of the flat bottom of said groove and the width L N of the base of said rib may be such that L R = bL N with b ranging from 1 to 2, and preferably 1.1 at 1.8, so as to have a tube having a relatively low weight per meter.
Typiquement, et comme illustré sur les
Les tubes utilisés selon l'invention présentent même en l'absence de rainurage axial, un facteur de Cavallini au moins égal à 3,5. Ils peuvent présenter avantageusement un facteur de Cavallini au moins égal à 4,0.The tubes used according to the invention have even in the absence of axial grooving, a Cavallini factor of at least 3.5. They may advantageously have a Cavallini factor of at least 4.0.
Le facteur de Cavallini Rx^2 (Rx .Rx) qui intervient dans les modèles d'évaluation du coefficient d'échange, est un facteur purement géométrique égal à :
De manière à augmenter encore le facteur de Cavallini, et comme illustré sur la
Un tel rainurage axial peut être obtenu une fois formées lesdites nervures par passage d'une molette de rainurage dans le sens axial.In order to further increase the Cavallini factor, and as illustrated on the
Such axial grooving can be obtained once formed said ribs by passage of a grooving wheel in the axial direction.
Les tubes rainurés selon l'invention peuvent être en cuivre et alliages de cuivre, aluminium et alliages d'aluminium. Ces tubes peuvent être obtenus typiquement par rainurage de tubes, ou éventuellement, par rainurage à plat d'une bande métallique puis formation d'un tube soudé.The grooved tubes according to the invention may be made of copper and alloys of copper, aluminum and aluminum alloys. These tubes can be obtained typically by grooving tubes, or possibly by flat grooving of a metal strip and forming a welded tube.
Les essais ont été réalisés sur tubes de cuivre de 8,0 mm ou de 9,52 mm de diamètre extérieur.
On a fabriqué le tube "E" de l'invention selon les
Les tubes E, A, B, C ont été fabriqués par rainurage d'un tube de cuivre lisse - tube S, alors que la tube D a été fabriqué par rainurage à plat d'une bande métallique puis formation d'un tube soudé.The tests were carried out on copper tubes of 8.0 mm or 9.52 mm of external diameter.
The "E" tube of the invention was manufactured according to the
The tubes E, A, B, C were made by grooving a smooth copper tube - S tube, while the D tube was manufactured by flat grooving a metal band and then forming a welded tube.
Un certain nombre d'essais ont été réalisés sur des tubes de cuivre de 9,52 mm de diamètre extérieur De. Ces tubes présentent les caractéristiques suivantes :
Un certain nombre d'autres essais ont été réalisés sur des tubes de cuivre de 8,0 mm de diamètre extérieur. Ces tubes présentent les caractéristiques suivantes :
On a fabriqué des batteries à ailettes selon la
Les
A) Résultats obtenus en condensation avec fluide frigorigène R22 sur tubes de De égal à 9,52 mm :
** en Pa/m mesurée pour un débit de fluide G égal à 350 kg/m2.s
B) Résultats obtenus en évaporation avec fluide frigorigène R22 sur tubes de De égal à 8,0 mm :
** en Pa/m mesurée pour un débit de fluide G égal à 200 kg/m2.s
C) Résultats obtenus en évaporation avec fluide frigorigène R407C sur tubes de De égal à 9,52 mm :
* Coefficient d'échange Hi en W/m2.K et perte de charge dP en Pa/m prises à un débit de fluide G égal à 100 Kg/m2.s et avec un titre moyen de vapeur de 0,6.
** Coefficient d'échange Hi en W/m2.K et perte de charge dP en Pa/m prises à un débit de fluide G égal à 200 Kg/m2.s et avec un titre moyen de vapeur de 0,3.
A) Results obtained in condensation with refrigerant R22 on De tubes equal to 9.52 mm:
** in Pa / m measured for a fluid flow G equal to 350 kg / m 2 .s
B) Results obtained in evaporation with refrigerant R22 on De tubes equal to 8.0 mm:
** in Pa / m measured for a fluid flow G equal to 200 kg / m 2 .s
C) Results obtained in evaporation with refrigerant R407C on De tubes equal to 9.52 mm:
* Exchange coefficient Hi in W / m 2 .K and pressure drop dP in Pa / m taken at a fluid flow rate G equal to 100 Kg / m 2 .s and with an average vapor head of 0.6.
** Coefficient of exchange Hi in W / m 2 .K and pressure drop dP in Pa / m taken at a flow rate of fluid G equal to 200 Kg / m 2 .s and with an average vapor head of 0.3 .
** pour une vitesse frontale de l'air prise égale à 1,5 m/s* for a frontal air speed of 2.8 m / s.
** for a frontal air speed of 1.5 m / s
Tous ces résultats montrent que les tubes et échangeurs ou batteries de tubes selon l'invention présentent des propriétés supérieures aux produits analogues de l'état de la technique, à la fois en évaporation et en condensation.
En conséquence, et de manière surprenante, les tubes selon l'invention ne constituent pas seulement un bon compromis de performances en évaporation et en condensation, mais présentent aussi, dans l'absolu, d'excellentes performances par rapport aux tubes de l'état de la technique utilisés en évaporation et ceux utilisés en condensation, ce qui est d'un grand intérêt en pratique.
En outre, en ce qui concerne le poids au mètre, les valeurs obtenues avec les tubes selon l'invention correspondent à un gain allant de 3,7 à 6,7 % par rapport aux tubes selon l'état de la technique, pris à même diamètre et à même épaisseur Tf , ce qui est considéré comme très important.
Enfin, les tubes selon l'invention de type E peuvent être fabriqués avantageusement par rainurage à haute cadence de tube de cuivre non rainuré lisse, typiquement à une vitesse de rainurage voisine de celle utilisée pour les tubes de type B, à savoir au moins 80 m/min.All these results show that the tubes and exchangers or batteries of tubes according to the invention have properties superior to the analogous products of the state of the art, both in evaporation and in condensation.
As a result, and surprisingly, the tubes according to the invention do not only constitute a good compromise of performance in evaporation and condensation, but also have, in absolute terms, excellent performance compared to the tubes of the state. of the technique used in evaporation and those used in condensation, which is of great interest in practice.
In addition, as regards the weight per meter, the values obtained with the tubes according to the invention correspond to a gain ranging from 3.7 to 6.7% compared to the tubes according to the state of the art, taken from same diameter and same thickness Tf, which is considered very important.
Finally, the tubes according to the invention of the type E can be advantageously manufactured by high-speed grooving of smooth non-grooved copper tube, typically at a grooving speed close to that used for the type B tubes, namely at least 80 m / min.
L'invention présente de grands avantages.
En effet, d'une part, les tubes et batteries utilisés selon l'invention présentent des performances intrinsèques élevées.
D'autre part, ces performances sont élevées à la fois en évaporation et en condensation, ce qui permet l'utilisation d'un même tube pour ces deux applications.
En outre, les tubes sont d'un poids au mètre relativement faible, ce qui est très avantageux à la fois d'un point de vue pratique, et du point de vue économique avec un coût matière relativement bas.The invention has great advantages.
Indeed, on the one hand, the tubes and batteries used according to the invention have high intrinsic performances.
On the other hand, these performances are high in both evaporation and condensation, which allows the use of the same tube for these two applications.
In addition, the tubes have a relatively low weight per meter, which is very advantageous both from a practical point of view and from the economic point of view with a relatively low material cost.
Enfin, les tubes utilisés selon l'invention ne nécessitent pas de moyens de fabrication spécifiques. Ils peuvent être fabriqués avec les équipements standards et notamment avec les cadences de production habituelles.Finally, the tubes used according to the invention do not require specific manufacturing means. They can be manufactured with standard equipment and especially with the usual production rates.
Claims (18)
- Use of a heat exchanger operating in reversible mode, in evaporation or in condensation using a phrase-change refrigeration fluid, said exchanger comprising grooved metal tubes (1), of thickness Tf at the bottom of the groove, with an outside diameter De, said tubes being grooved internally by N helical grooves (2) of apex angle α, height H, base width LN and helix angle β, two consecutive ribs being separated by a groove (3) typically with a flat bottom of width LR, with a pitch P equal to LR + LN.a) the outside diameter De being between 4 and 20 mm,b) the number N of ribs ranging from 46 to 98, depending in particular on the diameter De,c) the height H of the ribs ranging from 0.18 mm to 0.40 mm, depending in particular on the diameter De,d) the apex angle α such that 20° ≤ α < 28°,e) the helix angle β ranging from 18° to 35°,f) said tube having a Cavallini factor of at least 3.5,so as to obtain simultaneously a high heat exchange coefficient in evaporation and condensation, a low pressure drop and a tube as lightweight as possible.
- Use according to claim 1, in which said ribs form a succession of ribs of height H1 = H and height H2 = a.H1, with a between 0.6 and 0.9.
- Use according to any one of claims 1 to 2, in which said succession is an alternation of ribs of height H1 and ribs of height H2 separated by a typically flat groove bottom.
- Use according to any one of claims 1 to 3, in which, when De is less than or equal to 9.55 mm, this gives:- H ranging 0.18 to 0.3 mm, and preferably 0.20 to 0.25 mm,- and/or N less than 75, and preferably ranging from 64 to 70.
- Use according to any one of claims 1 to 3, in which, when De is at least equal to 9.55 mm, this gives:- H ranging from 0.25 to 0.40 mm,- N ranging from 70 to 98.
- Use according to one of claims 1 to 5, in which the angle α ranges from 22° to 25°.
- Use according to any one of claims 1 to 6, in which the helix angle β ranges from 22° to 30°.
- Use according to any one of claims 1 to 7, in which the helix angle β ranges from 25° to 28°.
- Use according to any one of claims 1 to 8, in which said ribs have a profile of the "trapezium type with a base and vertex, said vertex comprising a substantially flat central part, and optionally a slope with respect to said base.
- Use according to claim 9, in which the vertex of said rib forming a small side of the trapezium has rounded edges.
- Use according to claim 10, in which said rounded vertex or said rounded edges have a radius of curvature ranging typically from 40 µm to 100 µm, and preferably 50 µm to 80 µm.
- Use according to any one of claims 1 to 11, in which the width LR of the flat bottom of said groove and the width LN of the base of said rib are such that LR = b.LN with b ranging from 1 to 2, and preferably 1.10 to 1.8.
- Use according to any one of claims 1 to 12, in which said ribs and said flat bottom of said grooves are connected with a radius of curvature typically less than 50 µm and preferable less than 20 µm.
- Use according to any one of claims 1 to 13, in which the Cavallini factor is at least 4.0.
- Use according to any one of claims 1 to 14, in which the tubes further comprise an axial grooving creating in said ribs recesses with a typically triangular profile with a rounded vertex, said vertex having an angle γ ranging from 25° to 65°, said bottom part or vertex is at a distance h from the bottom of said grooves ranging from 0 to 0.2 mm.
- Use according to any one of claims 1 to 15, in which the tubes are made from copper and copper alloys, aluminium and aluminium alloys.
- Use according to any one of claims 1 to 16, in which the tubes have typically been obtained by the grooving of tubes, or optionally by flat grooving of a metal strip and then formation of a welded tube.
- Use according to any one of claims 1 to 17, for reversible hair conditioners and multi-tube exchangers as coolers.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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FR0203067A FR2837270B1 (en) | 2002-03-12 | 2002-03-12 | GROOVED TUBES FOR REVERSIBLE USE FOR HEAT EXCHANGERS |
PCT/FR2003/000760 WO2003076861A1 (en) | 2002-03-12 | 2003-03-10 | Slotted tube with reversible usage for heat exchangers |
Publications (2)
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EP1851498A1 EP1851498A1 (en) | 2007-11-07 |
EP1851498B1 true EP1851498B1 (en) | 2013-05-15 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP03743918.9A Expired - Lifetime EP1851498B1 (en) | 2002-03-12 | 2003-03-10 | Slotted tube with reversible usage for heat exchangers |
Country Status (21)
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US (1) | US7048043B2 (en) |
EP (1) | EP1851498B1 (en) |
JP (1) | JP2005526945A (en) |
KR (1) | KR100980755B1 (en) |
CN (1) | CN1636128A (en) |
AU (1) | AU2003242811B2 (en) |
BR (1) | BR0308372A (en) |
CA (1) | CA2474558C (en) |
ES (1) | ES2449091T3 (en) |
FR (1) | FR2837270B1 (en) |
HR (1) | HRP20040819B1 (en) |
IL (2) | IL162942A0 (en) |
MX (1) | MXPA04007907A (en) |
MY (1) | MY135526A (en) |
NO (1) | NO338468B1 (en) |
PL (1) | PL201843B1 (en) |
PT (1) | PT1851498E (en) |
RU (1) | RU2289076C2 (en) |
WO (1) | WO2003076861A1 (en) |
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JPH0237292A (en) * | 1989-06-07 | 1990-02-07 | Sumitomo Light Metal Ind Ltd | Condensing heat transmission pipe |
JPH04302999A (en) * | 1991-03-29 | 1992-10-26 | Sumitomo Light Metal Ind Ltd | Heat transfer tube with inner surface groove |
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JP2730824B2 (en) * | 1991-07-09 | 1998-03-25 | 三菱伸銅株式会社 | Heat transfer tube with inner groove and method of manufacturing the same |
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FR2706197B1 (en) | 1993-06-07 | 1995-07-28 | Trefimetaux | Grooved tubes for heat exchangers of air conditioning and refrigeration equipment, and corresponding exchangers. |
US6164370A (en) * | 1993-07-16 | 2000-12-26 | Olin Corporation | Enhanced heat exchange tube |
JP2912826B2 (en) * | 1994-08-04 | 1999-06-28 | 住友軽金属工業株式会社 | Heat transfer tube with internal groove |
DE19510124A1 (en) * | 1995-03-21 | 1996-09-26 | Km Europa Metal Ag | Exchanger tube for a heat exchanger |
JPH0921594A (en) * | 1995-07-04 | 1997-01-21 | Hitachi Ltd | Heat transfer pipe for mixed refrigerant and method for producing the same |
JPH0924594A (en) * | 1995-07-12 | 1997-01-28 | Iwatsu Electric Co Ltd | Digital plate making machine |
DE19612470A1 (en) * | 1996-03-28 | 1997-10-02 | Km Europa Metal Ag | Exchanger tube |
US6176301B1 (en) * | 1998-12-04 | 2001-01-23 | Outokumpu Copper Franklin, Inc. | Heat transfer tube with crack-like cavities to enhance performance thereof |
FR2837270B1 (en) | 2002-03-12 | 2004-10-01 | Trefimetaux | GROOVED TUBES FOR REVERSIBLE USE FOR HEAT EXCHANGERS |
-
2002
- 2002-03-12 FR FR0203067A patent/FR2837270B1/en not_active Expired - Fee Related
- 2002-04-12 US US10/120,782 patent/US7048043B2/en not_active Expired - Fee Related
-
2003
- 2003-03-10 IL IL16294203A patent/IL162942A0/en not_active IP Right Cessation
- 2003-03-10 KR KR1020047014125A patent/KR100980755B1/en not_active IP Right Cessation
- 2003-03-10 BR BR0308372-1A patent/BR0308372A/en not_active Application Discontinuation
- 2003-03-10 PT PT37439189T patent/PT1851498E/en unknown
- 2003-03-10 WO PCT/FR2003/000760 patent/WO2003076861A1/en active Application Filing
- 2003-03-10 JP JP2003575041A patent/JP2005526945A/en active Pending
- 2003-03-10 AU AU2003242811A patent/AU2003242811B2/en not_active Ceased
- 2003-03-10 PL PL370690A patent/PL201843B1/en not_active IP Right Cessation
- 2003-03-10 EP EP03743918.9A patent/EP1851498B1/en not_active Expired - Lifetime
- 2003-03-10 MY MYPI20030822A patent/MY135526A/en unknown
- 2003-03-10 RU RU2004130315/06A patent/RU2289076C2/en not_active IP Right Cessation
- 2003-03-10 MX MXPA04007907A patent/MXPA04007907A/en active IP Right Grant
- 2003-03-10 YU YU76804A patent/YU76804A/en unknown
- 2003-03-10 CN CNA038041820A patent/CN1636128A/en active Pending
- 2003-03-10 CA CA2474558A patent/CA2474558C/en not_active Expired - Fee Related
- 2003-03-10 ES ES03743918.9T patent/ES2449091T3/en not_active Expired - Lifetime
- 2003-05-20 YU YU101804A patent/YU101804A/en unknown
-
2004
- 2004-07-08 IL IL162942A patent/IL162942A/en unknown
- 2004-07-22 ZA ZA200405864A patent/ZA200405864B/en unknown
- 2004-09-10 HR HRP20040819AA patent/HRP20040819B1/en not_active IP Right Cessation
- 2004-10-11 NO NO20044299A patent/NO338468B1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JP2005526945A (en) | 2005-09-08 |
WO2003076861A1 (en) | 2003-09-18 |
CA2474558A1 (en) | 2003-09-18 |
YU76804A (en) | 2006-01-16 |
AU2003242811B2 (en) | 2009-05-28 |
ES2449091T3 (en) | 2014-03-18 |
BR0308372A (en) | 2005-01-11 |
NO20044299L (en) | 2004-10-11 |
PL370690A1 (en) | 2005-05-30 |
HRP20040819B1 (en) | 2017-12-01 |
CA2474558C (en) | 2011-03-08 |
MXPA04007907A (en) | 2004-10-15 |
RU2004130315A (en) | 2005-06-10 |
PL201843B1 (en) | 2009-05-29 |
KR20040101283A (en) | 2004-12-02 |
YU101804A (en) | 2006-01-16 |
PT1851498E (en) | 2013-07-04 |
IL162942A0 (en) | 2005-11-20 |
FR2837270A1 (en) | 2003-09-19 |
MY135526A (en) | 2008-05-30 |
HRP20040819A2 (en) | 2004-12-31 |
US7048043B2 (en) | 2006-05-23 |
EP1851498A1 (en) | 2007-11-07 |
CN1636128A (en) | 2005-07-06 |
NO338468B1 (en) | 2016-08-22 |
US20030173071A1 (en) | 2003-09-18 |
KR100980755B1 (en) | 2010-09-07 |
AU2003242811A1 (en) | 2003-09-22 |
ZA200405864B (en) | 2005-06-21 |
IL162942A (en) | 2008-06-05 |
RU2289076C2 (en) | 2006-12-10 |
FR2837270B1 (en) | 2004-10-01 |
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