EP1843895A2 - Method of applying an anti-freeze film to a transparent substrate - Google Patents
Method of applying an anti-freeze film to a transparent substrateInfo
- Publication number
- EP1843895A2 EP1843895A2 EP06709457A EP06709457A EP1843895A2 EP 1843895 A2 EP1843895 A2 EP 1843895A2 EP 06709457 A EP06709457 A EP 06709457A EP 06709457 A EP06709457 A EP 06709457A EP 1843895 A2 EP1843895 A2 EP 1843895A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- substrate
- film
- temperature
- flexible film
- atmosphere
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 76
- 238000000034 method Methods 0.000 title claims abstract description 20
- 230000002528 anti-freeze Effects 0.000 title claims description 9
- 108010053481 Antifreeze Proteins Proteins 0.000 title description 2
- 239000007788 liquid Substances 0.000 claims abstract description 32
- 239000012298 atmosphere Substances 0.000 claims abstract description 19
- -1 polyethylene Polymers 0.000 claims description 21
- 229920001577 copolymer Polymers 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 9
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 6
- 239000012790 adhesive layer Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 230000001681 protective effect Effects 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 5
- 230000002209 hydrophobic effect Effects 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- 238000002425 crystallisation Methods 0.000 claims description 4
- 230000008025 crystallization Effects 0.000 claims description 4
- 238000006073 displacement reaction Methods 0.000 claims description 4
- 230000002085 persistent effect Effects 0.000 claims description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 239000004417 polycarbonate Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 229940095095 2-hydroxyethyl acrylate Drugs 0.000 claims description 3
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 230000001699 photocatalysis Effects 0.000 claims description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 3
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- 239000004065 semiconductor Substances 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 230000004888 barrier function Effects 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 229920001477 hydrophilic polymer Polymers 0.000 claims description 2
- 239000011229 interlayer Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 2
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 230000000475 sunscreen effect Effects 0.000 claims 1
- 239000000516 sunscreening agent Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 description 11
- 230000001070 adhesive effect Effects 0.000 description 11
- 239000011521 glass Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 229920000459 Nitrile rubber Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000005340 laminated glass Substances 0.000 description 3
- 229920006289 polycarbonate film Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002313 adhesive film Substances 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 102000005686 Serum Globulins Human genes 0.000 description 1
- 108010045362 Serum Globulins Proteins 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- SFFFIHNOEGSAIH-UHFFFAOYSA-N bicyclo[2.2.1]hept-2-ene;ethene Chemical compound C=C.C1C2CCC1C=C2 SFFFIHNOEGSAIH-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003093 cationic surfactant Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- NLCKLZIHJQEMCU-UHFFFAOYSA-N cyano prop-2-enoate Chemical class C=CC(=O)OC#N NLCKLZIHJQEMCU-UHFFFAOYSA-N 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000004833 fish glue Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical class C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 150000004693 imidazolium salts Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- HQVFKSDWNYVAQD-UHFFFAOYSA-N n-hydroxyprop-2-enamide Chemical compound ONC(=O)C=C HQVFKSDWNYVAQD-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229920006173 natural rubber latex Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920002113 octoxynol Polymers 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 230000010399 physical interaction Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3405—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
- B29C63/0047—Preventing air-inclusions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10321—Laminated safety glass or glazing containing liquid layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/0038—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving application of liquid to the layers prior to lamination, e.g. wet laminating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
- B29C63/48—Preparation of the surfaces
- B29C2063/483—Preparation of the surfaces by applying a liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
- B29C63/02—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/406—Bright, glossy, shiny surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2405/00—Adhesive articles, e.g. adhesive tapes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/0007—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality
- B32B37/003—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality to avoid air inclusion
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/355—Temporary coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249994—Composite having a component wherein a constituent is liquid or is contained within preformed walls [e.g., impregnant-filled, previously void containing component, etc.]
- Y10T428/249995—Constituent is in liquid form
Definitions
- the present invention relates to substrates which are, occasionally or permanently, at temperatures below 0 ° C., especially transparent.
- anti-ice for preserving transparency
- hydrophobic hydrophilic
- antifouling-self-cleaning photocatalytic
- reflecting light or heat radiation colored at least in part
- electroconductive-heating semi -conductor
- antistatic electroluminescent
- the coating formation process is adapted to ensure the desired adhesion and mechanical strength and, in particular, as little scratchability as possible or self-healing ability of the coating scratches, when the substrate is transparent. .
- the coating is regenerated when necessary.
- one or more functions can be provided by an adhesive film, having the advantage of the ease of its replacement by an identical film or carrying different functions.
- a method may consist in interposing a sufficient quantity of a liquid, in particular water mixed with a surfactant, to allow all the bubbles to be expelled by applying pressure to the film, for example its central part. towards its periphery, by means of a squeegee.
- the object of the invention is therefore to provide a method of assembling a flexible film to a substrate that guarantees a perfect interface between the two and, in particular, the absence of trapped air bubbles and the formation of frosted.
- the subject of the invention is a process for adhesion of a flexible film to a substrate, comprising the interposition between film and substrate of a sufficient quantity of a liquid, so that no bubbles trapped between the film and the substrate after the film has been applied to the substrate by means of a squeegee, characterized in that the liquid does not freeze at a substrate temperature below 0 ° C., especially at most -5 0 C and in particular at most -1O 0 C, and also at least -25 0 C, occasionally or permanently.
- the substrate is freed from any particles that are adhered to, cleaned and wiped, prior to the interposition of a sufficient amount of a liquid between film and substrate.
- the face of the flexible film to be adhered to the substrate is wetted with said sufficient amount of a liquid.
- Any suitable liquid deposition techniques such as flow coating, spraying, spray or the like may be employed.
- the face of the flexible film to be adhered to the substrate comprises an adhesive layer optionally provided with a protective film to be removed before the setting adhesion on the substrate.
- an adhesive can be integrated with the liquid interposed between film and substrate.
- the adhesives can be chosen from:
- thermoplastic polymers heated thermoplastic polymers to obtain a liquid having the appropriate viscosity to be deposited and then cooled to obtain a solid (polyethylene, ethylene-vinyl acetate copolymer, polyamide, polyester, etc.);
- adhesives in the form of ready-to-use films epoxy, phenolic, nitrile rubber, polyamide, polyvinyl butyral, polyvinyl chloride, ethylene-carboxylic acid copolymer;
- - pressure-sensitive adhesives do not change their physical state before and after application, remain permanently deformable and have a certain stickiness at ambient temperature: tackified elastomers (natural rubber - latex), ethylene-acetate copolymer vinyl, thermoplastic elastomer (polyurethane ...), styrene - diene block copolymer (styrene - butadiene - styrene, styrene - isoprene - styrene), polyaryl arylate), silicones;
- - elastomers natural rubber, styrene - butadiene rubber, polychloroprene, neoprene, nitrile rubber, butyl rubber;
- Inorganic adhesives soluble silicates with different silica - alkali proportions. According to preferred embodiments of the method of the invention:
- the face of the flexible film opposite that to be adhered to the substrate is wetted with an effective amount of liquid so that the squeegee slides easily on the film during the operation of applying the film to the substrate;
- the face of the flexible film opposite to that to be adhered to the substrate is provided with a protective film to be removed after adhesion of the flexible film to the substrate; this protective film is particularly likely to be wet to facilitate the sliding of the squeegee as indicated above;
- the liquid interposed between the film and the substrate comprises an effective amount of an antifreeze compound lowering the crystallization temperature such as a salt, in particular KCl, NaCl or equivalent in solution and / or alcohol and / or a polymer, copolymer, prepolymer or hydrophilic oligomer suitable, optionally in water, and optionally one or more surfactants.
- an antifreeze compound lowering the crystallization temperature such as a salt, in particular KCl, NaCl or equivalent in solution and / or alcohol and / or a polymer, copolymer, prepolymer or hydrophilic oligomer suitable, optionally in water, and optionally one or more surfactants.
- alcohols are particularly used ethanol, isopropanol.
- hydrophilic polymers, copolymers, prepolymers or oligomers constituting the interposed liquid are especially based on polyvinylpyrrolidone of the poly (n-vinyl-2-pyrrolidone) or poly (1-vinylpyrrolidone) type, polyvinylpyrridine of the poly (n-vinyl-2 pyridine) type. ), poly type
- poly (N ', N-hydroxyacrylamide) polyacrylamide polyacrylamide
- polyvinylacetate polyacrylonitrile
- polyvinylalcohol polyacrylonitrile
- polyacrolein polyethylene glycol
- polypropylene glycol polyoxyethylene.
- the copolymers are based on at least one of the monomers constituting these polymers.
- surfactants there may be mentioned compounds comprising a lipophilic part Y, which may be a linear, branched or unsaturated aliphatic chain or an aromatic or alkylaromatic chain, and an ionic hydrophilic head or not.
- anionic surfactants Y - CO 2 M + ; Y - OSO 3 M + ; Y - SO 3 M + ; dodecylbenzene sulfonate; alkyl sufonate; fatty acid and sulphonated fatty acid ester; alkylarylsulfonate; cationic surfactants: Y - (R) n NH + ( 4-n ), X " ; Y - R 4 N + , X " ; alkyltrimethylammonium; alkylbenzyldimethylammonium; imidazolinium salts; amine salts;
- Y - OR Y - OH; Y - CO 2 R; Y - CONHR; Y - (CH 2 CH 2 ⁇ - O) n -; polyol; alcohol; acid; ester; polyethoxylated fatty alcohol.
- Another object of the invention is constituted by a substrate and flexible film in mutual adhesion obtained with the interposition of a sufficient quantity of a liquid in the absence of any imprisoned bubble, characterized by the persistent absence of frost in case of displacement of the substrate and the film in an atmosphere where their temperature will be below 0 ° C., respectively at most -5 ° C. and -10 ° C., from an atmosphere with a temperature at least equal to 0, preferably between 10 and 35, in particular 15 and 30 and in particular 23 and 27 0 C and residual moisture of at least 25%.
- the substrate and flexible film form a transparent assembly.
- the substrate is made of glass or a plastic material such as polycarbonate, polypropylene, poly (methyl methacrylate), ethylene / vinyl acetate copolymer, polyethylene terephthalate, polybutylene terephthalate, polyurethane, polyvinyl butyral , cycloolefinic copolymer such as ethylene / norbornene or ethylene / cyclopentadiene, polycarbonate / polyester copolymer, ionomer resin such as ethylene / polyamine-neutralized (meth) acrylic acid copolymer and the like, alone or in mixtures.
- a plastic material such as polycarbonate, polypropylene, poly (methyl methacrylate), ethylene / vinyl acetate copolymer, polyethylene terephthalate, polybutylene terephthalate, polyurethane, polyvinyl butyral , cycloolefinic copolymer such as
- the film is anti-freeze and / or hydrophobic and / or hydrophilic and / or antifouling-self-cleaning (photocatalytic) and / or reflecting light or heat radiation, antisolar, low-emissive, and / or colored at least in part and / or electroconductive-heating and / or semiconductor and / or antistatic and / or electroluminescent;
- the film is anti-icing and, when at a temperature of at most -1 0 ° C., respectively -15 ° C. and -20 ° C., it is placed in an atmosphere at a temperature of at least 0, preferably between 10 and 35, in particular 15 and 30 and in particular 23 and 27 ° C.
- the film is based on a support made of polyamide, polyester, polyolefin such as polyethylene, polypropylene, cellulose, polystyrene, ethylene / vinyl acetate copolymer, polyvinyl alcohol, polyvinyl chloride, poly (terephthalate), ethylene), poly (methyl methacrylate), polycarbonate, polyvinylburyral, polyurethane, polyvinylpyrrolidone, polyvinylpyrridine, poly-2-hydroxyethylacrylate polyacrylate), polyacrylamide, polyvinyl acetate, polyacrylonitrile, polyacrolein, polyethylene glycol, polyoxyethylene; it may also be a copolymer or a mixture based on at least one of the polymers mentioned above; -
- the film is anti-icing in that it comprises an antifreeze compound
- the antifreeze compound As the antifreeze compound, the same as described above can be used for said interposed liquid. However, it is sought a durability of the anti-frost function of the film, which may require improving the mechanical strength of the layer incorporating the antifreeze compound, particularly when it is likely to be subjected to occasional mechanical contact, or
- the antifreeze compound may be crosslinked and / or combined with at least one compound that is physically interacting with it and / or dispersed in a solid, inorganic, for example, or mixed matrix of the ORMOCER (Organically Modified Ceramics) type. ).
- the anti-icing function can be integrated in the film itself or in a coating formed on the support of the film.
- the invention furthermore relates to a glazing unit comprising a substrate and flexible film as described above, as well as possibly other transparent sheets to which they are connected via adhesive layer (s) interlayer (s) or gas blade (s). From this glazing, said flexible film advantageously constitutes an outer face, thus functionalized.
- the glazing consists in particular of a monolithic glazing, laminated, multiple, insulating, vacuum.
- Such multiple glazing, insulating comprises for example two or three sheets of monolithic or laminated glass, separated two by two by a gas blade.
- the interest may be the thermal insulation of a refrigerated chamber vis-à-vis the outside atmosphere (a store .).
- This thermal insulation is obtained alternately by a vacuum glazing comprising at least two sheets of monolithic or laminated glass separated by a vacuum or a gas blade at reduced pressure. These two sheets may be associated with a third of which they are separated by a gas strip at reduced pressure or not.
- Such structures may comprise one or more low-emissive layers reflecting the heat radiated from outside the refrigerated enclosure.
- the thermal conductivity of its barrier that is to say all the elements through which the various sheets of monolithic or laminated glass constituent are held together and spaced two by two, is at most 1, 46 W / mK
- the polycarbonate film is provided with an adhesive layer oriented towards the insulating glazing unit, to which the film is fixed with the interposition of a liquid specified below.
- the polycarbonate film is coated, on the side opposite to that of the adhesive layer, with an anti-ice adsorbent layer forming a three-dimensional polymeric network based on polyvinylpyrrolidone and polyurethane.
- the thickness of the anti-icing layer is equal to 14.5 ⁇ m.
- Tests are carried out on doors installed on refrigerated sales cabinets in which a temperature of -25.5 ° C is maintained. The temperature measured on the inside of the door is -22 ° C. The furniture is placed in an atmosphere at a temperature of 25 ° C. and 60% residual humidity.
- the cabinet door is opened 10 min before the film is laid to prevent frosting on the glass.
- the inner face of the door is wetted with a sprayer filled with a washing composition (soapy water).
- the glass is scraped off with a scraper to remove any particles that are stuck, then with a rubber squeegee to wipe off the water. There must be no more frost on the door. If necessary wipe the edges with a cloth.
- the protective film of the adhesive is removed from the polycarbonate film and the liquid indicated in the table below is sprayed onto the adhesive.
- the liquid between the glass and the film is removed.
- the center of the glazing is scraped outwards. If necessary, cut the film so as to leave a game of a few mm between the amounts of the door and the film to promote the evacuation of the liquid.
- the table below shows the presence or absence of frost at different times after closing the door, as well as bubbles between the glass and the film.
- Mir is a detergent composition marketed by Henkel.
- Triton X is a mixture of polyethoxylated octylphenols (nonionic surfactant) marketed by Union Carbide.
- PEG 200 is a polyethylene glycol marketed by Merck (Art 807483).
- This table illustrates the possibility of reducing the formation of frost to prevent it, and thus obtain a permanent absence of frost.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Combustion & Propulsion (AREA)
- Laminated Bodies (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to: a method of adhering a flexible film to a substrate, in which a sufficient quantity of a liquid is disposed between the film and the substrate such that no bubbles are trapped therebetween once the film has been applied to the substrate with the aid of a scraper, said method being characterised in that the liquid does not freeze at a substrate temperature of less than 0 °C; the mutually-adhered substrate and flexible film which is characterised by the continued absence of frost in the event of the substrate and film being moved into an atmosphere in which the temperature thereof is less than 0 °C, from an atmosphere having a temperature that is at least equal to 0 °C and residual moisture of at least 25 %; glazing comprising same; and the applications of said glazing, including for example exposure to temperatures of less than 0 °C.
Description
POSE DE FILM ANTIGIVRE SUR SUBSTRAT TRANSPARENT APPLICATION OF ANTI-FREEZING FILM ON TRANSPARENT SUBSTRATE
La présente invention est relative à des substrats se trouvant, occasionnellement ou en permanence, à des températures inférieures à 0 0C, notamment transparents.The present invention relates to substrates which are, occasionally or permanently, at temperatures below 0 ° C., especially transparent.
Diverses fonctionnalités sont susceptibles d'être données à de tels substrats : antigivre permettant de préserver la transparence, hydrophobe, hydrophile, antisalissure-autonettoyant (photocatalytique), réfléchissant la lumière ou le rayonnement thermique, coloré au moins en partie, électroconducteur-chauffant, semi-conducteur, antistatique, électroluminescentVarious functionalities are likely to be given to such substrates: anti-ice for preserving transparency, hydrophobic, hydrophilic, antifouling-self-cleaning (photocatalytic), reflecting light or heat radiation, colored at least in part, electroconductive-heating, semi -conductor, antistatic, electroluminescent
Plusieurs de ces fonctions peuvent être associées sur le substrat, par exemple sous forme d'un revêtement. Dans ce cas, le procédé de formation du revêtement est adapté afin de garantir l'adhésion et la tenue mécanique désirées et, en particulier, une rayabilité aussi faible que possible ou une aptitude d'autocicatrisation des rayures du revêtement, quand le substrat est transparent. Bien entendu, le revêtement est régénéré lorsque nécessaire.Several of these functions can be associated on the substrate, for example in the form of a coating. In this case, the coating formation process is adapted to ensure the desired adhesion and mechanical strength and, in particular, as little scratchability as possible or self-healing ability of the coating scratches, when the substrate is transparent. . Of course, the coating is regenerated when necessary.
D'autre part, une ou plusieurs fonctions peuvent être apportées par un film adhésif, présentant l'avantage de la facilité de son remplacement par un film identique ou portant des fonctions différentes.On the other hand, one or more functions can be provided by an adhesive film, having the advantage of the ease of its replacement by an identical film or carrying different functions.
On essaie alors évidemment d'obtenir une qualité d'adhésion parfaite du film sur le substrat, en évitant en particulier l'emprisonnement de bulles d'air entre les deux. Pour ce faire, un procédé peut consister à interposer une quantité suffisante d'un liquide, notamment de l'eau en mélange avec un tensioactif, pour permettre de chasser toutes les bulles en appliquant sur le film une pression, par exemple de sa partie centrale vers sa périphérie, au moyen d'une raclette.We then obviously try to obtain a quality of perfect adhesion of the film on the substrate, avoiding in particular the imprisonment of air bubbles between the two. To do this, a method may consist in interposing a sufficient quantity of a liquid, in particular water mixed with a surfactant, to allow all the bubbles to be expelled by applying pressure to the film, for example its central part. towards its periphery, by means of a squeegee.
Ce procédé ne donne cependant pas satisfaction pour les substrats se trouvant, occasionnellement ou en permanence, à des températures inférieures à O0C. En effet pour ceux-ci, la fraction de liquide qui reste entre le substrat et le film après qu'ils ont été assemblés, est susceptible de cristalliser en formant du givre. Ainsi quand le film adhésif fonctionnel est appliqué sur une face intérieure de porte transparente d'enceinte réfrigérée, dont la température peut être comprise par exemple entre -28 et O0C, le givre se forme de telle manière
qu'on ne puisse plus voir à travers la porte. En raison de la perméabilité du film et de la relative sécheresse de l'atmosphère réfrigérée, le givre est susceptible de disparaître, au moins quatre jours à plus d'une semaine après sa formation. Une telle gêne interdit une utilisation comme porte verticale d'enceinte réfrigérée de magasin à grande surface, dont la fréquence d'ouverture par les clients ou pour le réapprovisionnement a pour conséquence la permanence du gel, tandis que le maintien d'une parfaite transparence est indispensable dans le domaine de la grande distribution.This method does not, however, give satisfaction for substrates which are occasionally or permanently at temperatures below 0 ° C. In fact for these, the fraction of liquid which remains between the substrate and the film after they have been assembled, is likely to crystallize forming frost. Thus, when the functional adhesive film is applied to an inner face of a transparent refrigerated enclosure door, the temperature of which may be, for example, between -28 and 0 ° C., the frost is formed in such a way that we can no longer see through the door. Due to the permeability of the film and the relative dryness of the chilled atmosphere, the frost is likely to disappear, at least four days to more than a week after its formation. Such discomfort prohibits use as a vertical door of refrigerated storehouse large area, whose frequency of opening by customers or for replenishment results in the permanence of the gel, while maintaining a perfect transparency is indispensable in the field of mass distribution.
L'invention a donc pour but la mise à disposition d'un procédé d'assemblage d'un film souple à un substrat garantissant une parfaite interface entre les deux et, notamment, l'absence de bulles d'air emprisonnées et de formation de givre.The object of the invention is therefore to provide a method of assembling a flexible film to a substrate that guarantees a perfect interface between the two and, in particular, the absence of trapped air bubbles and the formation of frosted.
A cet effet, l'invention a pour objet un procédé de mise en adhésion d'un film souple sur un substrat, comprenant l'interposition entre film et substrat d'une quantité suffisante d'un liquide, de manière qu'aucune bulle ne soit emprisonnée entre film et substrat après que le film a été appliqué sur le substrat à l'aide d'une raclette, caractérisé en ce que le liquide ne gèle pas à une température du substrat inférieure à O0C, notamment d'au plus -50C et en particulier d'au plus -1O0C, et également d'au moins -250C, occasionnellement ou en permanence.For this purpose, the subject of the invention is a process for adhesion of a flexible film to a substrate, comprising the interposition between film and substrate of a sufficient quantity of a liquid, so that no bubbles trapped between the film and the substrate after the film has been applied to the substrate by means of a squeegee, characterized in that the liquid does not freeze at a substrate temperature below 0 ° C., especially at most -5 0 C and in particular at most -1O 0 C, and also at least -25 0 C, occasionally or permanently.
Avantageusement, le substrat est débarrassé de toutes particules qui y sont collées, nettoyé et essuyé, préalablement à l'interposition d'une quantité suffisante d'un liquide entre film et substrat.Advantageously, the substrate is freed from any particles that are adhered to, cleaned and wiped, prior to the interposition of a sufficient amount of a liquid between film and substrate.
De préférence, la face du film souple à mettre en adhésion sur le substrat est mouillée de ladite quantité suffisante d'un liquide. Toutes techniques adaptées de dépôt du liquide, telles que flow coating, pulvérisation, spray ou équivalent peuvent être employées. Il n'est d'autre part pas exclu de mouiller la face du substrat sur laquelle le film est à mettre en adhésion de ladite quantité suffisante d'un liquide, ni de mouiller à la fois lesdites faces du film et du substrat.Preferably, the face of the flexible film to be adhered to the substrate is wetted with said sufficient amount of a liquid. Any suitable liquid deposition techniques such as flow coating, spraying, spray or the like may be employed. On the other hand, it is not excluded to wet the face of the substrate on which the film is to adhere to said sufficient quantity of a liquid, or to wet both said faces of the film and the substrate.
Selon une autre caractéristique préférée du procédé de l'invention, la face du film souple à mettre en adhésion sur le substrat comprend une couche adhésive munie éventuellement d'un film protecteur à retirer avant la mise en
adhésion sur le substrat. Alternativement, un adhésif peut être intégré au liquide interposé entre film et substrat.According to another preferred characteristic of the process of the invention, the face of the flexible film to be adhered to the substrate comprises an adhesive layer optionally provided with a protective film to be removed before the setting adhesion on the substrate. Alternatively, an adhesive can be integrated with the liquid interposed between film and substrate.
Les adhésifs peuvent être choisis parmi :The adhesives can be chosen from:
- les adhésifs dits « hot melt » : polymères thermoplastiques chauffés pour obtenir un liquide ayant la viscosité appropriée pour être déposé puis refroidi pour obtenir un solide (polyéthylène, copolymère éthylène - acétate de vinyle, polyamide, polyester ...) ;- The so-called "hot melt" adhesives: heated thermoplastic polymers to obtain a liquid having the appropriate viscosity to be deposited and then cooled to obtain a solid (polyethylene, ethylene-vinyl acetate copolymer, polyamide, polyester, etc.);
- les adhésifs en solution ou dispersion aqueuse ou organique, dont le solvant est évaporé après dépôt pour obtenir un solide : en solution aqueuse : phénolique, poly (vinyl méthyl éther), polyadhesives in solution or aqueous or organic dispersion, the solvent of which is evaporated after deposition to obtain a solid: in aqueous solution: phenolic, poly (vinyl methyl ether), poly
(alcool vinylique), dextrine, produit naturel tel que caséine, colle à base de sang (albumine et globuline de sérum), colle de poisson (dérivé de collagène) ; en solution organique : caoutchouc naturel, acrylique, polyuréthane, polyamide, poly (vinylacétal), phénoxy ; en dispersion : polyuréthane, époxy, silicone, certains élastomères (caoutchouc nitrile ...) ;(vinyl alcohol), dextrin, natural product such as casein, blood-based glue (albumin and serum globulin), fish glue (derived from collagen); in organic solution: natural rubber, acrylic, polyurethane, polyamide, polyvinyl acetal, phenoxy; in dispersion: polyurethane, epoxy, silicone, certain elastomers (nitrile rubber, etc.);
- adhésifs sous forme de films prêts à l'emploi : époxy, phénolique, caoutchouc nitrile, polyamide, poly (vinylbutyral), poly (chlorure de vinyle), copolymère éthylène - acide carboxylique ;adhesives in the form of ready-to-use films: epoxy, phenolic, nitrile rubber, polyamide, polyvinyl butyral, polyvinyl chloride, ethylene-carboxylic acid copolymer;
- adhésifs mettant en jeu des réactions de polymérisation in situ : cyanoacrylates, certains acryliques réactifs ;adhesives involving in situ polymerization reactions: cyanoacrylates, certain reactive acrylics;
- adhésifs sensibles à la pression : ne changent pas d'état physique avant et après application, restent déformables en permanence et présentent un certain caractère collant (tack) à température ambiante : élastomères tackifiés (caoutchouc naturel - latex), copolymère éthylène-acétate de vinyle, élastomère thermoplastique (polyuréthane ...), copolymère séquence styrène - diène (styrène - butadiène - styrène, styrène - isoprène - styrène), poly (arylate d'alkyle), silicones ;- pressure-sensitive adhesives: do not change their physical state before and after application, remain permanently deformable and have a certain stickiness at ambient temperature: tackified elastomers (natural rubber - latex), ethylene-acetate copolymer vinyl, thermoplastic elastomer (polyurethane ...), styrene - diene block copolymer (styrene - butadiene - styrene, styrene - isoprene - styrene), polyaryl arylate), silicones;
- élastomères : caoutchouc naturel, caoutchouc styrène - butadiène, polychloroprène, néoprène, caoutchouc nitrile, caoutchouc butyle ;- elastomers: natural rubber, styrene - butadiene rubber, polychloroprene, neoprene, nitrile rubber, butyl rubber;
- adhésifs inorganiques : silicates solubles à différentes proportions silice - alcalins.
Selon des réalisations préférées du procédé de l'invention :Inorganic adhesives: soluble silicates with different silica - alkali proportions. According to preferred embodiments of the method of the invention:
- la face du film souple opposée à celle à mettre en adhésion sur le substrat, est mouillée d'une quantité efficace de liquide pour que la raclette glisse facilement sur le film au cours de l'opération consistant à appliquer le film sur le substrat ;the face of the flexible film opposite that to be adhered to the substrate, is wetted with an effective amount of liquid so that the squeegee slides easily on the film during the operation of applying the film to the substrate;
- la face du film souple opposée à celle à mettre en adhésion sur le substrat est munie d'un film protecteur à retirer après la mise en adhésion du film souple sur le substrat ; ce film protecteur est notamment susceptible d'être mouillé pour faciliter le glissement de la raclette comme indiqué précédemment ;the face of the flexible film opposite to that to be adhered to the substrate is provided with a protective film to be removed after adhesion of the flexible film to the substrate; this protective film is particularly likely to be wet to facilitate the sliding of the squeegee as indicated above;
- le liquide interposé entre film et substrat comprend une quantité efficace d'un composé antigel abaissant la température de cristallisation tel qu'un sel, notamment KCI, NaCI ou équivalent en solution et/ou d'alcool et/ou d'un polymère, copolymère, prépolymère ou oligomère hydrophile approprié, éventuellement dans l'eau, et éventuellement un ou plusieurs tensioactifs.the liquid interposed between the film and the substrate comprises an effective amount of an antifreeze compound lowering the crystallization temperature such as a salt, in particular KCl, NaCl or equivalent in solution and / or alcohol and / or a polymer, copolymer, prepolymer or hydrophilic oligomer suitable, optionally in water, and optionally one or more surfactants.
En tant qu'alcools sont notamment employés l'éthanol, l'isopropanol.As alcohols are particularly used ethanol, isopropanol.
Les polymères, copolymères, prépolymères ou oligomères hydrophiles constituants du liquide interposé sont notamment à base de polyvinylpyrrolidone du type poly (n-vinyl-2 pyrrolidone) ou poly (1-vinyl pyrrolidone), polyvinylpyrridine du type poly (n-vinyl-2 pyrridine), du type polyThe hydrophilic polymers, copolymers, prepolymers or oligomers constituting the interposed liquid are especially based on polyvinylpyrrolidone of the poly (n-vinyl-2-pyrrolidone) or poly (1-vinylpyrrolidone) type, polyvinylpyrridine of the poly (n-vinyl-2 pyridine) type. ), poly type
(n-vinyl-3-pyrridine), du type poly (n-vinyl-4-pyrridine), polyacrylate du type poly(n-vinyl-3-pyridine), of the poly (n-vinyl-4-pyridine) type, polyacrylate of the poly type
(2-hydroxyethylacrylate), polyacrylamide du type poly (N',N-hydroxyacrylamide), polyvinylacétate, polyacrylonitrile, polyvinylalcool, polyacroléine, polyéthylène glycol, polypropylène glycol, polyoxyéthylène. En particulier, les copolymères sont à base de l'un au moins des monomères constituant ces polymères.(2-hydroxyethylacrylate), poly (N ', N-hydroxyacrylamide) polyacrylamide, polyvinylacetate, polyacrylonitrile, polyvinylalcohol, polyacrolein, polyethylene glycol, polypropylene glycol, polyoxyethylene. In particular, the copolymers are based on at least one of the monomers constituting these polymers.
Comme tensioactifs peuvent être cités des composés comprenant une partie lipophile Y, qui peut être une chaîne aliphatique linéaire, ramifiée ou insaturée ou une chaîne aromatique ou alkylaromatique, et une tête hydrophile ionique ou non.As surfactants there may be mentioned compounds comprising a lipophilic part Y, which may be a linear, branched or unsaturated aliphatic chain or an aromatic or alkylaromatic chain, and an ionic hydrophilic head or not.
Des exemples en sont :Examples are:
- tensioactifs anioniques : Y - CO2 M+ ; Y - OSO3 M+ ; Y - SO3 M+ ; sulfonate de dodécylbenzène ; alkyl sufonate ; acide gras et ester d'acide gras sulfoné ; alkylarylsulfonate ;
- tensioactifs cationiques : Y - (R)n NH+(4-n), X" ; Y - R4 N+, X" ; alkyltriméthylammonium ; alkylbenzyldiméthylammonium ; sels d'imidazolinium ; sels d'aminé ;anionic surfactants: Y - CO 2 M + ; Y - OSO 3 M + ; Y - SO 3 M + ; dodecylbenzene sulfonate; alkyl sufonate; fatty acid and sulphonated fatty acid ester; alkylarylsulfonate; cationic surfactants: Y - (R) n NH + ( 4-n ), X " ; Y - R 4 N + , X " ; alkyltrimethylammonium; alkylbenzyldimethylammonium; imidazolinium salts; amine salts;
- zwitterioniques : Y - N+ CO2 " ; Y - N+ SO3 " ; bétaïnes ; sulfobétaïnes ; sels d'imidazolium ;- zwitterionic: Y - N + CO 2 " ; Y - N + SO 3 " ; betaines; sulfobetaines; imidazolium salts;
- non ioniques : Y - OR ; Y - OH ; Y - CO2R ; Y - CONHR ; Y - (CH2 ~ CH2 - O)n - ; polyol ; alcool ; acide ; ester ; alcool gras polyéthoxylé.- nonionic: Y - OR; Y - OH; Y - CO 2 R; Y - CONHR; Y - (CH 2 CH 2 ~ - O) n -; polyol; alcohol; acid; ester; polyethoxylated fatty alcohol.
Un autre objet de l'invention est constitué par un substrat et film souple en adhésion mutuelle obtenue avec interposition d'une quantité suffisante d'un liquide en l'absence de toute bulle emprisonnée, caractérisés par l'absence persistante de givre en cas de déplacement du substrat et du film dans une atmosphère où leur température sera inférieure à O0C, respectivement d'au plus -50C et -1O0C, à partir d'une atmosphère à température au moins égale à O, de préférence comprise entre 10 et 35, notamment 15 et 30 et en particulier 23 et 270C et humidité résiduelle d'au moins 25 %.Another object of the invention is constituted by a substrate and flexible film in mutual adhesion obtained with the interposition of a sufficient quantity of a liquid in the absence of any imprisoned bubble, characterized by the persistent absence of frost in case of displacement of the substrate and the film in an atmosphere where their temperature will be below 0 ° C., respectively at most -5 ° C. and -10 ° C., from an atmosphere with a temperature at least equal to 0, preferably between 10 and 35, in particular 15 and 30 and in particular 23 and 27 0 C and residual moisture of at least 25%.
Selon une caractéristique préférée, les substrat et film souple forment un ensemble transparent. Le substrat est constitué de verre ou d'une matière plastique telle que polycarbonate, polypropylène, poly(méthacrylate de méthyle), copolymère éthylène/acétate de vinyle, poly(téréphtalate d'éthylène), poly(téréphtalate de butylène), polyuréthane, polyvinylbutyral, copolymère cyclooléfinique tel qu'éthylène/norbomène ou éthylène/cyclopentadiène, copolymère polycarbonate/polyester, résine ionomère telle que copolymère éthylène/acide (méth)acrylique neutralisé par une polyamine et similaires, seuls ou en mélanges. Selon d'autres caractéristiques avantageuses du substrat et film souple de l'invention :According to a preferred feature, the substrate and flexible film form a transparent assembly. The substrate is made of glass or a plastic material such as polycarbonate, polypropylene, poly (methyl methacrylate), ethylene / vinyl acetate copolymer, polyethylene terephthalate, polybutylene terephthalate, polyurethane, polyvinyl butyral , cycloolefinic copolymer such as ethylene / norbornene or ethylene / cyclopentadiene, polycarbonate / polyester copolymer, ionomer resin such as ethylene / polyamine-neutralized (meth) acrylic acid copolymer and the like, alone or in mixtures. According to other advantageous features of the substrate and flexible film of the invention:
- le film est antigivre et/ou hydrophobe et/ou hydrophile et/ou antisalissure - autonettoyant (photocatalytique) et/ou réfléchissant la lumière ou le rayonnement thermique, antisolaire, bas-émissif, et/ou coloré au moins en partie et/ou électroconducteur-chauffant et/ou semi-conducteur et/ou antistatique et/ou électroluminescent ;the film is anti-freeze and / or hydrophobic and / or hydrophilic and / or antifouling-self-cleaning (photocatalytic) and / or reflecting light or heat radiation, antisolar, low-emissive, and / or colored at least in part and / or electroconductive-heating and / or semiconductor and / or antistatic and / or electroluminescent;
- le film est antigivre et, lorsqu'à une température d'au plus -1O0C, respectivement -150C et -2O0C, il est placé dans une atmosphère à température au moins égale à 0, de préférence comprise entre 10 et
35, notamment 15 et 30 et en particulier 23 et 270C et au moins 25 % d'humidité résiduelle, aucun givre ne se forme pendant 12 s au moins, de préférence 1 min au moins, en particulier 2 min au moins, voire aussi longtemps que 3 min au moins ; - le film est à base d'un support en polyamide, polyester, polyoléfine telle que polyéthylène, polypropylène, cellulosique, polystyrène, copolymère éthylène/acétate de vinyle, poly(alcool vinylique), poly(chlorure de vinyle), poly(téréphtalate d'éthylène), poly(méthacrylate de méthyle), polycarbonate, polyvinylburyral, polyuréthane, polyvinylpyrrolidone, polyvinylpyrridine, polyacrylate du type poly-2-hydroxyéthylacrylate), polyacrylamide, poly(acétate de vinyle), polyacrylonitrile, polyacroléine, polyéthylèneglycol, polyoxyéthylène ; il peut encore s'agir d'un copolymère ou d'un mélange à base de l'un au moins des polymères cités ci-dessus ; - le film est antigivre par le fait qu'il comporte un composé antigel abaissant la température de cristallisation et présente, éventuellement, un caractère hydrophobe sur une partie de sa surface. En tant que composé antigel, on peut utiliser les mêmes que décrits ci-dessus pour ledit liquide interposé. Cependant on recherche une durabilité de la fonctionnalité antigivre du film, ce qui peut nécessiter d'améliorer la tenue mécanique de la couche intégrant le composé antigel, en particulier quand celle-ci est susceptible d'être soumise à un contact mécanique occasionnel, ou à un nettoyage... A cette fin, le composé antigel peut être réticulé et/ou associé à au moins un composé à interaction physique avec lui et/ou dispersé dans une matrice solide, minérale par exemple ou mixte du type ORMOCER (Organically Modified Ceramics).the film is anti-icing and, when at a temperature of at most -1 0 ° C., respectively -15 ° C. and -20 ° C., it is placed in an atmosphere at a temperature of at least 0, preferably between 10 and 35, in particular 15 and 30 and in particular 23 and 27 ° C. and at least 25% residual moisture, no frost is formed for at least 12 s, preferably at least 1 min, in particular at least 2 min, or even as long as 3 min at least; the film is based on a support made of polyamide, polyester, polyolefin such as polyethylene, polypropylene, cellulose, polystyrene, ethylene / vinyl acetate copolymer, polyvinyl alcohol, polyvinyl chloride, poly (terephthalate), ethylene), poly (methyl methacrylate), polycarbonate, polyvinylburyral, polyurethane, polyvinylpyrrolidone, polyvinylpyrridine, poly-2-hydroxyethylacrylate polyacrylate), polyacrylamide, polyvinyl acetate, polyacrylonitrile, polyacrolein, polyethylene glycol, polyoxyethylene; it may also be a copolymer or a mixture based on at least one of the polymers mentioned above; - The film is anti-icing in that it comprises an antifreeze compound lowering the crystallization temperature and optionally has a hydrophobic character on a portion of its surface. As the antifreeze compound, the same as described above can be used for said interposed liquid. However, it is sought a durability of the anti-frost function of the film, which may require improving the mechanical strength of the layer incorporating the antifreeze compound, particularly when it is likely to be subjected to occasional mechanical contact, or For this purpose, the antifreeze compound may be crosslinked and / or combined with at least one compound that is physically interacting with it and / or dispersed in a solid, inorganic, for example, or mixed matrix of the ORMOCER (Organically Modified Ceramics) type. ).
Par interaction physique, on entend ici une liaison hydrogène, une interaction polaire du type Van der WaIs ou une interaction hydrophobe aptes à réaliser un renforcement mécanique assimilable à une réticulation.By physical interaction, here is meant a hydrogen bond, a polar interaction of the Van der WaIs type or a hydrophobic interaction capable of achieving a mechanical reinforcement comparable to a crosslinking.
La fonction antigivre peut être intégrée dans le film lui-même ou dans un revêtement formé sur le support du film.The anti-icing function can be integrated in the film itself or in a coating formed on the support of the film.
L'invention a d'autre part pour objet un vitrage comprenant un substrat et film souple tels que décrits précédemment, ainsi qu'éventuellement d'autres
feuilles transparentes auxquelles ils sont reliés par l'intermédiaire de couche(s) adhésive(s) intercalaire(s) ou de lame(s) de gaz. De ce vitrage, ledit film souple constitue avantageusement une face extérieure, ainsi fonctionnalisée.The invention furthermore relates to a glazing unit comprising a substrate and flexible film as described above, as well as possibly other transparent sheets to which they are connected via adhesive layer (s) interlayer (s) or gas blade (s). From this glazing, said flexible film advantageously constitutes an outer face, thus functionalized.
Le vitrage consiste notamment en un vitrage monolithique, feuilleté, multiple, isolant, sous-vide.The glazing consists in particular of a monolithic glazing, laminated, multiple, insulating, vacuum.
Un tel vitrage multiple, isolant, comporte par exemple deux ou trois feuilles de verre monolithique ou feuilleté, séparées deux à deux par une lame de gaz. L'intérêt peut en être l'isolation thermique d'une enceinte réfrigérée vis- à-vis de l'atmosphère extérieure (d'un magasin ....). Cette isolation thermique est obtenue alternativement par un vitrage sous-vide comprenant au moins deux feuilles de verre monolithique ou feuilleté séparées par un vide ou une lame de gaz à pression réduite. Ces deux feuilles peuvent être associées à une troisième dont elles sont séparées par une lame de gaz à pression réduite ou non. De telles structures peuvent comprendre une ou plusieurs couches bas- émissives réfléchissant la chaleur rayonnée par l'extérieur de l'enceinte réfrigérée.Such multiple glazing, insulating, comprises for example two or three sheets of monolithic or laminated glass, separated two by two by a gas blade. The interest may be the thermal insulation of a refrigerated chamber vis-à-vis the outside atmosphere (a store ....). This thermal insulation is obtained alternately by a vacuum glazing comprising at least two sheets of monolithic or laminated glass separated by a vacuum or a gas blade at reduced pressure. These two sheets may be associated with a third of which they are separated by a gas strip at reduced pressure or not. Such structures may comprise one or more low-emissive layers reflecting the heat radiated from outside the refrigerated enclosure.
Selon une caractéristique avantageuse de ce vitrage, la conductivité thermique de sa barrière, c'est-à-dire tous les éléments par l'intermédiaire desquels les différentes feuilles de verre monolithique ou feuilleté constitutives sont maintenues ensemble et espacées deux à deux, est d'au plus 1 ,46 W/m.K.According to an advantageous characteristic of this glazing, the thermal conductivity of its barrier, that is to say all the elements through which the various sheets of monolithic or laminated glass constituent are held together and spaced two by two, is at most 1, 46 W / mK
Enfin, l'invention a pour objet l'application d'un tel vitrageFinally, the subject of the invention is the application of such a glazing unit
- comme porte d'enceinte réfrigérée ;- as refrigerated enclosure door;
- pour le bâtiment, le mobilier urbain ou les panneaux d'affichage, les miroirs routiers, les éléments d'enceinte réfrigérée autres que la porte, tels que tablettes ... ;- for the building, street furniture or billboards, road mirrors, refrigerated enclosure elements other than the door, such as shelves ...;
- pour un véhicule de transport terrestre, aérien ou aquatique (pare- brise, vitrage latéral, lunette arrière, partie de toit, rétroviseur, phare) ;- for a land, air or water transport vehicle (windshield, side glazing, rear window, roof part, rearview mirror, lighthouse);
- pour un élément de vision (lunettes, casque). L'invention est en effet particulièrement mise à profit dans des produits soumis, au moins occasionnellement, à des températures inférieures à O0C, et a un intérêt accru dans les applications en extérieur en climat rigoureux. L'invention sera mieux comprise à la lumière de l'exemple suivant.
EXEMPLE- for a vision element (glasses, helmet). The invention is indeed particularly used in products subjected, at least occasionally, to temperatures below 0 ° C, and has an increased interest in outdoor applications in severe climate. The invention will be better understood in the light of the following example. EXAMPLE
On reprend le premier exemple de la demande WO 00/71481 à l'exception de ce queWe repeat the first example of the application WO 00/71481 except that
- l'on utilise un triple vitrage isolant au lieu d'un vitrage isolant sous vide, et, de ce que- triple insulation glazing is used instead of vacuum insulating glazing, and that
- le film polycarbonate est muni d'une couche adhésive orientée vers le vitrage isolant, auquel le film est fixé avec interposition d'un liquide précisé ci-dessous.the polycarbonate film is provided with an adhesive layer oriented towards the insulating glazing unit, to which the film is fixed with the interposition of a liquid specified below.
Le film polycarbonate est revêtu, du côté opposé à celui de la couche adhésive, d'une couche adsorbante antigivre formant un réseau tridimensionnel polymérique à base de polyvinylpyrrolidone et de polyuréthane. L'épaisseur de la couche antigivre est égale à 14,5 μm.The polycarbonate film is coated, on the side opposite to that of the adhesive layer, with an anti-ice adsorbent layer forming a three-dimensional polymeric network based on polyvinylpyrrolidone and polyurethane. The thickness of the anti-icing layer is equal to 14.5 μm.
Des essais sont réalisés sur des portes installées sur des meubles de vente frigorifiques au sein desquels une température de -25,50C est maintenue. La température mesurée sur la face interne de la porte est de -220C. Les meubles sont placés dans une atmosphère à une température de 250C et 60 % d'humidité résiduelle.Tests are carried out on doors installed on refrigerated sales cabinets in which a temperature of -25.5 ° C is maintained. The temperature measured on the inside of the door is -22 ° C. The furniture is placed in an atmosphere at a temperature of 25 ° C. and 60% residual humidity.
On procède de la manière suivante.The procedure is as follows.
On ouvre la porte du meuble 10 min avant la pose du film afin d'éviter la formation de givre sur le verre.The cabinet door is opened 10 min before the film is laid to prevent frosting on the glass.
On mouille la face interne de la porte à l'aide d'un pulvérisateur rempli d'une composition de lavage (eau savonneuse).The inner face of the door is wetted with a sprayer filled with a washing composition (soapy water).
On racle le verre avec un grattoir afin d'enlever toutes les particules qui sont collées, puis avec une raclette en caoutchouc pour essuyer l'eau. Il ne doit plus rester de givre sur la porte. Si nécessaire on essuie les bords avec un chiffon.The glass is scraped off with a scraper to remove any particles that are stuck, then with a rubber squeegee to wipe off the water. There must be no more frost on the door. If necessary wipe the edges with a cloth.
On retire le film protecteur de l'adhésif du film polycarbonate et on pulvérise le liquide indiqué dans le tableau ci-dessous sur l'adhésif.The protective film of the adhesive is removed from the polycarbonate film and the liquid indicated in the table below is sprayed onto the adhesive.
On pose la face adhésive du film sur le verre. On mouille l'autre face du film par pulvérisation du même liquide que sur l'adhésif, afin que la raclette en caoutchouc glisse facilement sur le film.We put the adhesive side of the film on the glass. The other side of the film is wetted by spraying the same liquid as the adhesive, so that the rubber squeegee slides easily onto the film.
A l'aide de la raclette en caoutchouc, on chasse le liquide se trouvant entre le verre et le film. Pour une évacuation parfaite du liquide, on effectue le raclage du centre du vitrage vers l'extérieur.
Si nécessaire, on découpe le film de façon à laisser un jeu de quelques mm entre les montants de la porte et le film afin de favoriser l'évacuation du liquide.Using the rubber squeegee, the liquid between the glass and the film is removed. For a perfect evacuation of the liquid, the center of the glazing is scraped outwards. If necessary, cut the film so as to leave a game of a few mm between the amounts of the door and the film to promote the evacuation of the liquid.
On répète l'opération de raclage, et l'on ferme la porte du meuble.We repeat the scraping operation, and we close the door of the furniture.
On évalue dans le tableau ci-dessous la présence ou l'absence de givre à différents moments après la fermeture de la porte, ainsi que de bulles entre le verre et le film.The table below shows the presence or absence of frost at different times after closing the door, as well as bubbles between the glass and the film.
TABLEAUBOARD
Les pourcentages sont indiqués en masse.The percentages are indicated in mass.
Mir est une composition détergente commercialisée par la société Henkel.Mir is a detergent composition marketed by Henkel.
Triton X est un mélange d'octylphénols polyéthoxylés (tensioactif non ionique) commercialisé par la société Union Carbide.Triton X is a mixture of polyethoxylated octylphenols (nonionic surfactant) marketed by Union Carbide.
PEG 200 est un polyéthylène glycol commercialisé par la société Merck (Art. 807483).PEG 200 is a polyethylene glycol marketed by Merck (Art 807483).
Ce tableau illustre la possibilité de réduire la formation de givre jusqu'à l'empêcher, et obtenir ainsi une absence permanente de givre.
This table illustrates the possibility of reducing the formation of frost to prevent it, and thus obtain a permanent absence of frost.
Claims
1. Procédé de mise en adhésion d'un film souple sur un substrat, comprenant l'interposition entre film et substrat d'une quantité suffisante d'un liquide, de manière qu'aucune bulle ne soit emprisonnée entre film et substrat après que le film a été appliqué sur le substrat à l'aide d'une raclette, caractérisé en ce que le liquide ne gèle pas à une température du substrat inférieure à O0C.A method of adhering a flexible film to a substrate, comprising interposing a sufficient amount of liquid between the film and the substrate so that no bubbles are trapped between the film and the substrate after the film was applied to the substrate using a squeegee, characterized in that the liquid does not freeze at a substrate temperature below 0 ° C.
2. Procédé selon la revendication 1 , caractérisé en ce que le liquide ne gèle pas à une température du substrat d'au plus -50C. 2. Method according to claim 1, characterized in that the liquid does not freeze at a substrate temperature of at most -5 0 C.
3. Procédé selon la revendication 2, caractérisé en ce que le liquide ne gèle pas à une température du substrat d'au plus -1O0C.3. Method according to claim 2, characterized in that the liquid does not freeze at a substrate temperature of at most -1O 0 C.
4. Procédé selon l'une des revendications 1 à 3, caractérisé en ce que préalablement à l'interposition entre film et substrat d'une quantité suffisante d'un liquide, le substrat est débarrassé de toutes particules qui y sont collées, nettoyé et essuyé.4. Method according to one of claims 1 to 3, characterized in that prior to the interposition between film and substrate of a sufficient amount of a liquid, the substrate is freed from any particles which are adhered to, cleaned and wiped.
5. Procédé selon l'une des revendications 1 ou 4, caractérisé en ce que la face du film souple à mettre en adhésion sur le substrat est mouillée de ladite quantité suffisante d'un liquide.5. Method according to one of claims 1 or 4, characterized in that the face of the flexible film to be adhered to the substrate is wetted with said sufficient amount of a liquid.
6. Procédé selon l'une des revendications 1 à 5, caractérisé en ce que la face du film souple à mettre en adhésion sur le substrat comprend une couche adhésive munie éventuellement d'un film protecteur à retirer avant la mise en adhésion sur le substrat.6. Method according to one of claims 1 to 5, characterized in that the face of the flexible film to be adhered to the substrate comprises an adhesive layer optionally provided with a protective film to be removed before adhesion to the substrate .
7. Procédé selon l'une des revendications 1 à 6, caractérisé en ce que la face du film souple opposée à celle à mettre en adhésion sur le substrat, est mouillée d'une quantité efficace de liquide pour que la raclette glisse facilement sur le film au cours de l'opération consistant à appliquer le film sur le substrat.7. Method according to one of claims 1 to 6, characterized in that the face of the flexible film opposite to that to be adhered to the substrate, is wet with an effective amount of liquid so that the squeegee slides easily on the film during the operation of applying the film to the substrate.
8. Procédé selon l'une des revendications 1 à 7, caractérisé en ce que la face du film souple opposée à celle à mettre en adhésion sur le substrat est munie d'un film protecteur à retirer après la mise en adhésion du film souple sur le substrat.8. Method according to one of claims 1 to 7, characterized in that the face of the flexible film opposite to that to be adhered to the substrate is provided with a protective film to be removed after adhesion of the flexible film on the substrate.
9. Procédé selon l'une des revendications 1 à 8, caractérisé en ce que le liquide interposé entre film et substrat comprend une quantité efficace d'un composé antigel abaissant la température de cristallisation tel qu'un sel, notamment KCI, NaCI ou équivalent en solution et/ou d'alcool, et/ou d'un polymère, copolymère, prépolymère ou oligomère hydrophile approprié, éventuellement dans l'eau, et éventuellement un ou plusieurs tensioactifs.9. Method according to one of claims 1 to 8, characterized in that the liquid interposed between film and substrate comprises an effective amount of an antifreeze compound lowering the crystallization temperature such as a salt, in particular KCl, NaCl or equivalent in solution and / or alcohol, and / or a suitable hydrophilic polymer, copolymer, prepolymer or oligomer, optionally in water, and optionally one or more surfactants.
10. Substrat et film souple en adhésion mutuelle obtenue avec interposition d'une quantité suffisante d'un liquide en l'absence de toute bulle emprisonnée, caractérisés par l'absence persistante de givre en cas de déplacement du substrat et du film dans une atmosphère où leur température sera inférieure à O0C, à partir d'une atmosphère à température au moins égale à O0C et humidité résiduelle d'au moins 25 %. 10. Substrate and flexible film in mutual adhesion obtained with interposition of a sufficient quantity of a liquid in the absence of any trapped bubble, characterized by the persistent absence of frost in case of displacement of the substrate and the film in an atmosphere where their temperature will be lower than 0 ° C, from an atmosphere with a temperature of at least 0 ° C and residual moisture of at least 25%.
11. Substrat et film souple selon la revendication 10, caractérisés par l'absence persistante de givre en cas de déplacement du substrat et du film dans une atmosphère où leur température sera d'au plus -50C, à partir d'une atmosphère à température au moins égale à O0C et humidité résiduelle d'au moins 25 %. 11. Substrate and flexible film according to claim 10, characterized by the persistent absence of frost in case of displacement of the substrate and the film in an atmosphere where their temperature will be at most -5 ° C., from an atmosphere at a temperature of at least 0 ° C and residual moisture of at least 25%.
12. Substrat et film souple selon la revendication 11 , caractérisés par l'absence persistante de givre en cas de déplacement du substrat et du film dans une atmosphère où leur température sera d'au plus -1O0C, à partir d'une atmosphère à température au moins égale à O0C et humidité résiduelle d'au moins 25 %. 12. Substrate and flexible film according to claim 11, characterized by the persistent absence of frost in case of displacement of the substrate and the film in an atmosphere where their temperature will be at most -1O 0 C, from an atmosphere. at a temperature of at least 0 ° C and residual moisture of at least 25%.
13. Substrat et film souple selon l'une des revendications 10 à 12, caractérisés en ce que ladite atmosphère est à une température comprise entre 10 et 35, notamment 15 et 30 et en particulier 23 et 270C.13. Substrate and flexible film according to one of claims 10 to 12, characterized in that said atmosphere is at a temperature between 10 and 35, in particular 15 and 30 and in particular 23 and 27 0 C.
14. Substrat et film souple selon l'une des revendications 10 à 13, caractérisés en ce qu'ils forment un ensemble transparent. 14. Substrate and flexible film according to one of claims 10 to 13, characterized in that they form a transparent assembly.
15. Substrat et film souple selon l'une des revendications 10 à 14, caractérisés en ce que le film est antigivre et/ou hydrophobe et/ou hydrophile et/ou antisalissure-autonettoyant (photocatalytique) et/ou réfléchissant la lumière ou le rayonnement thermique, antisolaire, bas-émissif et/ou coloré au moins en partie et/ou électroconducteur-chauffant et/ou semi-conducteur et/ou antistatique et/ou électroluminescent.15. Substrate and flexible film according to one of claims 10 to 14, characterized in that the film is anti-icing and / or hydrophobic and / or hydrophilic and / or anti-fouling-self-cleaning (photocatalytic) and / or reflecting light or radiation thermal, sunscreen, low-emissive and / or at least partly colored and / or electroconductive-heating and / or semiconductor and / or antistatic and / or electroluminescent.
16. Substrat et film souple selon l'une des revendications 10 à 15, caractérisés en ce que le film est antigivre et que lorsqu'à une température d'au plus -1O0C, il est placé dans une atmosphère à température au moins égale à O0C et au moins 25 % d'humidité résiduelle, aucun givre ne se forme pendant 12 s au moins.16. Substrate and flexible film according to one of claims 10 to 15, characterized in that the film is anti-icing and that when at a temperature of at most -1O 0 C, it is placed in an atmosphere at least at temperature equal to At 0 ° C and at least 25% residual moisture, no frost forms for at least 12 seconds.
17. Substrat et film souple selon la revendication 16, caractérisés en ce que le film est antigivre et que lorsqu'à une température d'au plus -150C, il est placé dans une atmosphère à température au moins égale à O0C et au moins17. Substrate and flexible film according to claim 16, characterized in that the film is anti-icing and that when at a temperature of at most -15 ° C., it is placed in an atmosphere at a temperature of at least 0 ° C. and at least
25 % d'humidité résiduelle, aucun givre ne se forme pendant 12 s au moins.25% residual moisture, no frost forms for at least 12 seconds.
18. Substrat et film souple selon la revendication 17, caractérisés en ce que le film est antigivre et que lorsqu'à une température d'au plus -2O0C, il est placé dans une atmosphère à température au moins égale à O0C et au moins 25 % d'humidité résiduelle, aucun givre ne se forme pendant 12 s au moins.18. Substrate and flexible film according to claim 17, characterized in that the film is anti-icing and that when at a temperature of at most -2O 0 C, it is placed in an atmosphere at a temperature of at least 0 ° C. and at least 25% residual moisture, no frost forms for at least 12 seconds.
19. Substrat et film souple selon l'une des revendications 16 à 18, caractérisés en ce que ladite atmosphère est à une température comprise entre 10 et 35, notamment 15 et 30 et en particulier 23 et 270C.19. Substrate and flexible film according to one of claims 16 to 18, characterized in that said atmosphere is at a temperature between 10 and 35, especially 15 and 30 and in particular 23 and 27 0 C.
20. Substrat et film souple selon l'une des revendications 16 à 19, caractérisés en ce qu'aucun givre ne se forme pendant 1 min au moins.20. Substrate and flexible film according to one of claims 16 to 19, characterized in that no frost is formed for at least 1 min.
21. Substrat et film souple selon la revendication 20, caractérisés en ce qu'aucun givre ne se forme pendant 2 min au moins.21. Substrate and flexible film according to claim 20, characterized in that no frost is formed for at least 2 min.
22. Substrat et film souple selon la revendication 21 , caractérisés en ce qu'aucun givre ne se forme pendant 3 min au moins. 22. Substrate and flexible film according to claim 21, characterized in that no frost is formed for at least 3 minutes.
23. Substrat et film souple selon l'une des revendications 10 à 22, caractérisés en ce que le film est à base d'un support en polyamide, polyester, polyoléfine telle que polyéthylène, polypropylène, cellulosique, en polystyrène, copolymère éthylène/acétate de vinyle, poly (alcool vinylique), poly (chlorure de vinyle), poly (téréphtalate d'éthylène), poly (méthacrylate de méthyle), polycarbonate, polyvinylbutyral, polyuréthane, polyvinylpyrrolidone, polyvinylpyrridine, polyacrylate du type poly (2-hydroxyéthylacrylate), polyacrylamide, poly (acétate de vinyle), polyacrylonitrile, polyacrolèine, polyéthylèneglycol, polyoxyéthylène, copolymère ou mélange d'un au moins de ces polymères. 23. Substrate and flexible film according to one of claims 10 to 22, characterized in that the film is based on a support of polyamide, polyester, polyolefin such as polyethylene, polypropylene, cellulose, polystyrene, ethylene / acetate copolymer vinyl, polyvinyl alcohol, polyvinyl chloride, polyethylene terephthalate, poly (methyl methacrylate), polycarbonate, polyvinylbutyral, polyurethane, polyvinylpyrrolidone, polyvinylpyrridine, polyacrylate of the poly (2-hydroxyethylacrylate) type polyacrylamide, polyvinyl acetate, polyacrylonitrile, polyacrolein, polyethylene glycol, polyoxyethylene, copolymer or mixture of at least one of these polymers.
24. Substrat et film souple selon l'une des revendications 10 à 23, caractérisés en ce que le film est antigivre par le fait qu'il comporte un composé antigel abaissant la température de cristallisation.24. Substrate and flexible film according to one of claims 10 to 23, characterized in that the film is anti-icing in that it comprises an antifreeze compound lowering the crystallization temperature.
25. Vitrage comprenant un substrat et film souple selon l'une des revendications 10 à 24, ainsi qu'éventuellement d'autres feuilles transparentes auxquelles ils sont reliés par l'intermédiaire de couche(s) adhésive(s) intercalaire(s) ou de lame(s) de gaz. 25. Glazing comprising a substrate and flexible film according to one of claims 10 to 24, and optionally other transparent sheets to which they are connected by means of adhesive layer (s) interlayer (s) or gas blade (s).
26. Vitrage selon la revendication 25, dont ledit film souple constitue une face extérieure. 26. Glazing according to claim 25, wherein said flexible film constitutes an outer face.
27. Vitrage selon la revendication 25 ou 26, dont la conductivité thermique de la barrière est d'au plus 1 ,46 W/m.K.27. Glazing according to claim 25 or 26, the thermal conductivity of the barrier is at most 1.46 W / m.K.
28. Application d'un vitrage selon l'une des revendications 25 à 27 comme porte d'enceinte réfrigérée.28. Application of a glazing according to one of claims 25 to 27 as a refrigerated enclosure door.
29. Application d'un vitrage selon l'une des revendications 25 à 27 pour le bâtiment, le mobilier urbain ou les panneaux d'affichage, les miroirs routiers, les éléments d'enceinte réfrigérée autres que la porte.29. Application of a glazing according to one of claims 25 to 27 for the building, street furniture or billboards, road mirrors, refrigerated enclosure elements other than the door.
30. Application d'un vitrage selon l'une des revendications 25 à 27 pour un véhicule de transport terrestre, aérien ou aquatique.30. Application of a glazing according to one of claims 25 to 27 for a land, air or water transport vehicle.
31. Application d'un vitrage selon l'une des revendications 25 à 27 pour un élément de vision. 31. Application of a glazing unit according to one of claims 25 to 27 for a vision element.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0550271A FR2881422B1 (en) | 2005-01-31 | 2005-01-31 | APPLICATION OF ANTI-FREEZING FILM ON TRANSPARENT SUBSTRATE |
PCT/FR2006/050073 WO2006079763A2 (en) | 2005-01-31 | 2006-01-30 | Method of applying an anti-freeze film to a transparent substrate |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1843895A2 true EP1843895A2 (en) | 2007-10-17 |
Family
ID=35840147
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06709457A Withdrawn EP1843895A2 (en) | 2005-01-31 | 2006-01-30 | Method of applying an anti-freeze film to a transparent substrate |
Country Status (10)
Country | Link |
---|---|
US (2) | US20080138603A1 (en) |
EP (1) | EP1843895A2 (en) |
JP (1) | JP5160900B2 (en) |
KR (3) | KR101364041B1 (en) |
CN (1) | CN101111369A (en) |
BR (1) | BRPI0607050A2 (en) |
CA (1) | CA2595977C (en) |
FR (1) | FR2881422B1 (en) |
MX (1) | MX2007008994A (en) |
WO (1) | WO2006079763A2 (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2910117A1 (en) * | 2006-12-18 | 2008-06-20 | Saint Gobain | Detecting a door malfunction in a refrigerated enclosure, e.g. freezer, comprises depositing an anti-icing adsorbent layer on a window in the door |
NL1036681C2 (en) * | 2009-03-09 | 2010-09-13 | Zeffex Ventures B V | SELF-ADHESIVE, OPTICALLY TRANSPARENT ANTI-CONDENSE FILM. |
GB2500368A (en) | 2012-02-22 | 2013-09-25 | C G I Internat Ltd | Fire resistant glazing unit with hydrogel interlayer |
JP6502265B2 (en) * | 2013-02-05 | 2019-04-17 | スリーエム イノベイティブ プロパティズ カンパニー | Graphic goods |
US10315399B2 (en) | 2013-12-31 | 2019-06-11 | Entrotech, Inc. | Methods for application of polymeric film and related assemblies |
EP3089858B1 (en) * | 2013-12-31 | 2018-11-14 | AERO Advanced Paint Technology, Inc. | Method for application of polymeric film |
FR3027596A1 (en) * | 2014-10-24 | 2016-04-29 | Saint Gobain | MONOLITHIC TRANSPARENT SUBSTRATE ANTI-CONDENSATION |
EP3347183B1 (en) | 2015-09-07 | 2020-12-16 | SABIC Global Technologies B.V. | Plastic glazing for a tailgate of a vehicle having a light assembly |
EP3347220B1 (en) | 2015-09-07 | 2021-04-14 | SABIC Global Technologies B.V. | Surfaces of plastic glazing of tailgates |
WO2017042697A1 (en) | 2015-09-07 | 2017-03-16 | Sabic Global Technologies B.V. | Aerodynamic features of plastic glazing of tailgates |
US11267173B2 (en) | 2015-09-07 | 2022-03-08 | Sabic Global Technologies B.V. | Molding of plastic glazing of tailgates |
EP3380361B1 (en) | 2015-11-23 | 2021-12-22 | SABIC Global Technologies B.V. | Lighting systems for windows having plastic glazing |
US11559147B2 (en) | 2019-05-07 | 2023-01-24 | Carrier Corporation | Refrigerated display cabinet utilizing a radial cross flow fan |
US11116333B2 (en) | 2019-05-07 | 2021-09-14 | Carrier Corporation | Refrigerated display cabinet including microchannel heat exchangers |
US11675111B2 (en) | 2020-07-17 | 2023-06-13 | Ford Global Technologies, Llc | Vehicle sensor assembly |
CN112430900A (en) * | 2020-11-26 | 2021-03-02 | 吉林大学 | Anti-frost light-transmitting electrostatic spinning film and preparation method and application thereof |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2471718A (en) * | 1948-10-11 | 1949-05-31 | Lawrence W Breck | Antifreeze appliance |
US3977930A (en) * | 1975-06-25 | 1976-08-31 | Hunter John C | Oil based adhesion of film to window |
JPS612784A (en) * | 1984-06-14 | 1986-01-08 | Toyoda Gosei Co Ltd | Spray can packed with water-repellent surface treatment |
FR2635319B1 (en) * | 1988-07-20 | 1992-07-24 | Saint Gobain Vitrage | GLAZING WITH AN ANTI-FROST LAYER |
CN1048053A (en) * | 1990-07-30 | 1990-12-26 | 肖振三 | Frostproof agent for windshield of vehicle |
EP0498005A1 (en) * | 1991-02-06 | 1992-08-12 | Melitta Haushaltsprodukte GmbH & Co. Kommanditgesellschaft | Anti-fogging composition |
CS113591A3 (en) * | 1991-04-22 | 1992-11-18 | Pavol Ing Kovac | Antifreeze ingredient into bituminous wearing courses of roads andpavements |
CN1068545C (en) * | 1997-01-30 | 2001-07-18 | 中国科学院上海光学精密机械研究所 | Curtain wall glass without white light pollution |
US6144017A (en) * | 1997-03-19 | 2000-11-07 | Libbey-Owens-Ford Co. | Condensation control system for heated insulating glass units |
JPH10264249A (en) * | 1997-03-28 | 1998-10-06 | Somar Corp | Film affixing device |
US6180245B1 (en) * | 1998-10-28 | 2001-01-30 | 3M Innovative Properties Company | Method of repairing scratched and/or abraded transparent substrates and the repaired substrates |
FR2787350B1 (en) * | 1998-12-21 | 2002-01-04 | Saint Gobain Vitrage | GLASS WITH FUNCTIONAL MESOPOROUS COATING, ESPECIALLY HYDROPHOBIC |
FR2794225B3 (en) * | 1999-05-25 | 2001-06-15 | Saint Gobain Vitrage | REFRIGERATED ENCLOSURE DOOR WITH VACUUM WINDOWS |
KR100448723B1 (en) * | 2002-01-10 | 2004-10-12 | 백순기 | Frost-melting and frost-preventing composition |
US7375349B2 (en) * | 2003-11-19 | 2008-05-20 | Fujifilm Corporation | Radiation-image conversion panel and process of producing the same |
-
2005
- 2005-01-31 FR FR0550271A patent/FR2881422B1/en not_active Expired - Fee Related
-
2006
- 2006-01-30 KR KR1020127029734A patent/KR101364041B1/en not_active IP Right Cessation
- 2006-01-30 US US11/815,049 patent/US20080138603A1/en not_active Abandoned
- 2006-01-30 WO PCT/FR2006/050073 patent/WO2006079763A2/en active Application Filing
- 2006-01-30 CA CA 2595977 patent/CA2595977C/en not_active Expired - Fee Related
- 2006-01-30 JP JP2007552704A patent/JP5160900B2/en not_active Expired - Fee Related
- 2006-01-30 CN CNA2006800036473A patent/CN101111369A/en active Pending
- 2006-01-30 MX MX2007008994A patent/MX2007008994A/en active IP Right Grant
- 2006-01-30 BR BRPI0607050-7A patent/BRPI0607050A2/en active Search and Examination
- 2006-01-30 EP EP06709457A patent/EP1843895A2/en not_active Withdrawn
- 2006-01-30 KR KR1020077017455A patent/KR101362793B1/en not_active IP Right Cessation
- 2006-01-30 KR KR1020127029728A patent/KR101364233B1/en not_active IP Right Cessation
-
2010
- 2010-01-21 US US12/690,967 patent/US8057615B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO2006079763A2 * |
Also Published As
Publication number | Publication date |
---|---|
CA2595977A1 (en) | 2006-08-03 |
CN101111369A (en) | 2008-01-23 |
KR101364233B1 (en) | 2014-02-14 |
FR2881422B1 (en) | 2007-03-16 |
JP5160900B2 (en) | 2013-03-13 |
KR20070102692A (en) | 2007-10-19 |
KR20120128170A (en) | 2012-11-26 |
KR101364041B1 (en) | 2014-02-26 |
FR2881422A1 (en) | 2006-08-04 |
WO2006079763A2 (en) | 2006-08-03 |
CA2595977C (en) | 2013-03-19 |
BRPI0607050A2 (en) | 2009-12-01 |
US20080138603A1 (en) | 2008-06-12 |
JP2008528329A (en) | 2008-07-31 |
MX2007008994A (en) | 2007-09-18 |
KR101362793B1 (en) | 2014-02-21 |
US8057615B2 (en) | 2011-11-15 |
US20100116416A1 (en) | 2010-05-13 |
WO2006079763A3 (en) | 2006-10-19 |
KR20120140259A (en) | 2012-12-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2595977C (en) | Method of applying an anti-freeze film to a transparent substrate | |
EP1890575B1 (en) | Insulating glazing, in particular for refrigerated chamber door | |
CA2374636C (en) | Transparent glazing and use thereof in a chilling chamber door comprising in particular a glazing under vacuum | |
CA3016268C (en) | Method for manufacturing self-adhesive mineral wool pads | |
EP3344838B1 (en) | Refrigerated chamber unit door | |
BE1009959A5 (en) | Multiple glazed | |
EP0130886B1 (en) | Safety glass, in particular bullet-proof safety glass | |
CA2963196A1 (en) | One-piece, transparent anti-condensation substrate | |
CH684352A5 (en) | Composite windows with high sound attenuation. | |
JPS61286803A (en) | Anti-clouding mirror | |
WO2004016561A1 (en) | Safety glass provided with a coating comprising a polymer | |
JPH0683689B2 (en) | Window frame for frozen storage case | |
FR2702073A1 (en) | Display device without glue. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20070724 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR |
|
17Q | First examination report despatched |
Effective date: 20071219 |
|
DAX | Request for extension of the european patent (deleted) | ||
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 20160422 |