EP1827291A1 - Procede de production d'une restauration dentaire - Google Patents
Procede de production d'une restauration dentaireInfo
- Publication number
- EP1827291A1 EP1827291A1 EP04809107A EP04809107A EP1827291A1 EP 1827291 A1 EP1827291 A1 EP 1827291A1 EP 04809107 A EP04809107 A EP 04809107A EP 04809107 A EP04809107 A EP 04809107A EP 1827291 A1 EP1827291 A1 EP 1827291A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tool
- dental
- center
- tci
- curve
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
- A61C13/00—Dental prostheses; Making same
- A61C13/0003—Making bridge-work, inlays, implants or the like
- A61C13/0004—Computer-assisted sizing or machining of dental prostheses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
- A61C13/00—Dental prostheses; Making same
- A61C13/0003—Making bridge-work, inlays, implants or the like
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
- A61C5/00—Filling or capping teeth
- A61C5/70—Tooth crowns; Making thereof
- A61C5/77—Methods or devices for making crowns
Definitions
- the present invention relates to a method for preparing a dental restoration with at least one rotating material removing tool.
- Such a production typically include automated acquiring of topographic data from a model made from a bite impression from a dental patient, computer based design of a dental restoration, and automated manufacturing of the dental restoration.
- CAD/CAM based systems from the design and manufactur- ing of dental restorations are known from:
- suitable tools such as cutting tools
- suitable tools are used to form the restoration from a blank, the tools following paths according to a manufacturing program based on a digital model of the dental restoration.
- industrial ceramics such as dense sintered high purity aluminium or yttrium stabilized zirconium, are used as material for the restoration.
- Such materials present, despite their advantages concerning the esthetical result of the res- toration, a number of problems in the manufacturing process.
- Their hardness result in a high rate of wear on the tools used, which, besides being costly, can result in vibrations in the manufacturing process, in turn causing deviations from tolerance requirements.
- the nature of the ceramic materials used is such that they are relatively brittle, and therefore caution has to be taken when the tool paths are de- termined, in order not to avoid the risk of failure in the material.
- restriction on the cutting parameters of the tools during the manufacturing process are introduced to decrease tool wear and avoid failure in the blank, which in turn lengthens the process causing a slow production.
- the working grinding surface of the tool should have a high speed in relation to the material.
- the speed of the grinding surface of the tool due to the rotation of the latter, is zero at the axis of rotation, which is usually at the tip of the tool.
- the area on the grinding surface of the tool having no or little speed will move parallel to the surface of the dental mate- rial piece. Therefore, this area will not be substantially involved in the material removal process. Instead, areas of the tool further from the axis of rotation, having a high speed will be involved in the process.
- An advantage of the invention is that the high speed of working surfaces of the tool will reduce wear of the tool itself.
- movements of the tool in a direction having a component parallel to the rotational axis, causing low speed areas of the tool to take part of the material removing process can be limited and concentrated to a step of forming an initial, central cavity, and a substantial part of the material removal procedure can be performed by moving the tool perpendicular to the rotational axis.
- the step of providing an initial cavity includes moving the tool so that the direction of the movement of the tool forms an angle to a rotational axis of the tool.
- the surface of the tool has a velocity component due to the tool rotation in a direction which is tangential to the local work piece surface.
- a surface area of the tool close to or at the center of rotation has only a small velocity component or no velocity component due to the rotation of the tool in the tangential direction of the local surface of the work piece.
- the angle between tool movement direction and the rotational axis of the tool is between 80 and 89.5 degrees.
- a high processing speed is allowed with risks of material failure kept low.
- a suitable value for said angle is around 89 degrees, and said angle can be decreased to about 85 degrees when working in softer dental restoration materials, giving a high processing speed with little risk of material failure, excessive tool wear or tool failure.
- hard dental restoration materials include aluminium oxides and fully sintered yttrium stabilised zirconiumdioxide, and the exceptionally hard, hot isostatic pressed zirconiumdioxide.
- Relatively soft dental restoration materials include magnesium stabilised zirconiumdioxides.
- the tool path in the step of providing an initial cavity, forms a closed loop.
- the tool path could be helical, or present a screw form having an elliptic, rectangular, square, or triangular cross-section.
- the tool path, as projected in a plane perpendicular to the rotational axis of the tool could present a closed curve of any suitable, alternative shape.
- the size of the tool surface in contact with the work piece can be controlled so that it does not exceed a desired level, and is kept, at least substantially, constant.
- the method comprises
- a tool center boundary curve which represents the outer limit of the movements of the rotational axis of the tool, at a plane perpendicular to the axis of rotation of the tool, based on - the intended final cavity surface in a region in the vicinity of an intersection between said intended final cavity surface and said plane perpendicular to the axis of rotation of the tool, and
- the method comprises - determining a tool center curve at each level, of a plurality of levels, at, under and/or above said plane being perpendicular to the axis of rotation of the tool, by offsetting inwards the intersection between the intended final cavity surface and the respective level by an amount corresponding to the radius of the tool at the respective level, and - determining the tool center boundary curve as the most inwardly located of the tool center curves.
- the location, in a plane perpendicular to the rotational axis of the tool, of a center of the initial cavity is determined as the location of the center of the largest circle that can be fitted within a boundary curve in a plane perpendicular to the axis of rotation of the tool.
- the step of removing material outside the initial cavity is advantageously performed by moving the tool, from the initial cavity towards the boundary curve, along circular paths or a spiral shaped path. Determining the largest circle, that can be fitted within a boundary curve in a plane perpendicular to the axis of rotation of the tool, has the result that the length of circular paths or a spiral path inside the largest circle is maximized. In turn, this is advantageous since the effective grinding area of the tool can be controlled and variations in the effec- tive grinding area can be kept at a minimum.
- At least one tool path is determined by creating at least one offset curve by offsetting outwards a curve, and trimming the at least one offset curve against a tool boundary curve.
- this has the advantages that the cutting depth of the tool can be controlled, and that it is easy to check if the tool paths result in extraordinary movements that are undesired from a material processing point of view, e.g. due to a risk of damaging the material or the tool.
- - fig. 1, 4, and 9-17 show cross-sections of a dental material piece from which a dental restoration is to be prepared, in different stages of a method according to one embodiment of the invention
- - fig. 2 shows a perspective view depicting a tool and its movement
- - fig. 3 shows a side view of the tool in fig. 2 in action
- - fig. 5 shows a view of a detail of the tool and a detail of the dental material piece
- - fig. 7 shows a sectioned view of the dental material piece, whereby the section is oriented perpendicular to a rotational axis of the tool, and
- - fig. 8a, 8b, and 8c show tool paths projected in a plane perpendicular to a rota- tional axis of the tool.
- Fig. 1 shows a cross-section of a dental material piece 1 from which the dental res- toration is to be prepared.
- the dental restoration could be a crown, a part-crown, an inlay, an onlay, a bridge, a stump reconstruction, a veneer, also referred to as a ligament, a facette, a filling or a connector.
- the dental restoration could be formed according to a digital model, in turn obtained by scanning of a model, obtained from a bite impression, and a computer aided design process based on the scanning data, known in the art.
- the dental material piece 1 could be a blank, or the result of an al- ready initiated material removal process on a blank.
- an exterior surface of the dental restoration could be at least partly finished, before commencing the steps of the method according to the invention.
- the dental material of the piece 1 could be a ceramic material based on zirconium oxide, aluminium oxide or any other suitable material.
- the dental material piece 1 is mounted in a machine with at least one holder (not shown in fig. 1).
- any suitable material removing tool 2 can be arranged, such as a milling tool or a cutting tool, suitable for working on the material for the restoration, whereby the tool is adapted to move automatically in relation to the dental material piece 1 according to instructions in a program file run in a computer program.
- the rotational axis of the tool 2 is indicated in fig. 1 with a line R.
- the tool presents a cylindrical grinding surface 4, and an essentially flat grinding surface 3' at the tip region 3, which flat grinding surface is oriented essentially perpendicular to the rotational axis R.
- a radius 5 is provided at the intersection of the flat grinding surface 3' and the cylindrical grinding surface 4.
- the grinding part of the tool could have another shape, e.g. of a truncated cone or a sphere.
- the tool is to be used in a process of removing material to obtain a cavity of the dental restoration.
- the dental material piece 1 is shown sectioned parallel to the rotational axis R of the tool 2.
- a contour of the intended cavity is indicated with the broken line 6.
- an initial cavity is formed in the dental material piece, by moving the tool 2 while in rotation, wherein the tool follows a helical path.
- the helical path is indicated as a path followed by a center of the tool 2, and indicated by a curved arrow P.
- the path P forms an imaginary screw.
- the diameter of this screw is less than the diameter of the tool itself.
- the helical path described results in the effective working surface of the tool being substantially constant during this step of the method.
- the shape of the path projected in a plane perpendicular to the rotational axis R of the tool could be elliptic, rectangular, square or trian- gular.
- the path P formed in this step of the method is not closed when projected in a plane perpendicular to the rotational axis R, whereby it is simply a curved or straight declining path.
- the tool 2 is moved so that the direction of the movement P forms an angle ⁇ to the rotational axis R of the tool 2.
- the angle ⁇ is suitably about 89 degrees for hard dental restoration materials, and down to 85 degrees for less hard dental restoration materials.
- Fig. 4 shows the result of the step described above with reference to fig. 2 and 3.
- An initial substantially cylindrical central cavity C has been formed with a diameter es- sentially equal to the diameter of the screw of the helical path P added to the tool diameter.
- Material has been removed from a first level LI of the dental material piece 1 to a second level L2 thereof, the first and the second level LI, L2 being separated by a distance d2 in a direction parallel to the rotational axis of the tool.
- level means an imaginary flat plane perpendicular to the rota- tional axis R.
- a tool center boundary curve TCBC is determined, which represents the outer limit of the movements of the rotational axis R of the tool, at the second level L2.
- the determination of the tool center boundary curve TCBC is based on the intended final cavity surface 6 (fig. 4) in a region in the vicinity of an intersection between said intended final cavity surface 6 and the second level L2, and also the shape of the tool.
- a tool center curve TCi, TCi-1, TCi-2, TCi-3 is determined at each level, of a plurality of levels, in this example four levels, i, i-1, i- 2, i-3.
- the levels, i, i-1, i-2, i-3 which can be of any suitable number, can be located at, under and/or above the level L2, but in this example, one level, i, is identical to the second level L2, and the remaining levels, i-1, i-2, i-3, is distributed above the second level L2.
- a line formed by the intersection be- tween the intended final cavity surface 6 and the respective level i, i-1, i-2, i-3 is offset inwards by an amount corresponding to the radius Ri, Ri-1, Ri-2, Ri-3 of the tool 2 at the respective level, i, i-1, i-2, i-3, whereby a tool center curve, TCi, TCi-1, TCi-2, TCi-3, is determined at each level, i, i-1, i-2, i-3.
- the tool center boundary curve TCBC is determined as the most inwardly located at each segment of the tool center curves, TCi, TCi-1, TCi-2, TCi-3.
- a step of removing material outside the initial cavity C by moving the tool 2 essentially in a plane perpendicular to the rotational axis R of the tool 2, includes moving the tool 2 along concentric circular paths.
- a center H (see fig. 4) of the initial cavity C described above with reference to fig. 2 and 3 is determined in the following way: Referring to fig. 6, the center H of the initial cavity C is determined as the location of the center of the largest circle C9 that can be fitted within a the tool center boundary curve TCBC. Alternatively, the center H of the initial cavity C can be determined as the location of the center of the largest circle that can be fitted within some other boundary curve, for example, the intersection between the second level L2 and the intended cavity surface 6, (see fig. 4).
- the center of this circle C9 is the lateral position of the center of the screw formed by the helical path P described above with reference to fig. 2. Accordingly, preferably, the tool center boundary curve TCBC at the second level L2 is determined before creating the initial cavity C.
- material is removed between the first and the second level LI, L2 by moving the tool 2 while in rotation essentially in a plane perpendicular to the rotational axis R of the tool 2. Material is to be removed approximately until the intended cavity surface at the second level L2.
- Fig. 7 shows, in a cross-section perpendicular to the rotational axis of the tool, a step following the step of providing an initial cavity.
- the movements of a center position of the tool 2 at the rotational axis R thereof, are indicated with lines with arrows.
- the movements have directions essentially perpendicular to the rotational axis R of the tool 2.
- the movements follow circular tracks 11 essentially centered on the center H of the initial cavity C, and presenting suitable differences in radiuses, whereby an orbit of the center position of the tool 2 following one circular track is followed by a step 12 outwards to a larger circular track.
- the tool could, at least at an early phase of the step of removing material between the first and the second level LI, L2, follow a track shaped as a spiral, at which the tool is gradually moved outwards from the starting point, so that a suitable amount of material is removed at each orbit of the tool.
- the movements of the tool 2 essentially in a plane perpendicular to the rotational axis R has the following advantage: Since the grinding surface 4 of the tool 2 is at a radial distance from the rotational axis R, and since the grinding surface 4, due to the lateral movement of the tool, takes part in the material removing process, it is accomplished that essentially all of the working grinding surface of the tool 2 has a high velocity. This results in a high material removal rate.
- the nature of dental restoration materials i.e. dental ceramic materials, includes a relatively small elastic deformation and essentially no plastic deformation before a breaking stress of the material is reached.
- the method according to the invention drastically reduces the risk of damages on materials or tools by making it possible to prevent the cutting depths from becoming too large, (discussed closer below), to avoid or minimise movements mainly in the axial direction of the tool, and to prevent a contact surface between the tool and the material from becoming too large, (discussed closer below).
- the tool center boundary curve TCBC has an irregular shape.
- the movements of the tool is limited outwards by the TCBC, and tool paths in the area enclosed by the tool center boundary curve TCBC are deter- mined in the following way:
- a curve, in this example the circle C9 is offset outwards to form tool paths CIO, Cl 1 outside this curve C9, which paths has shapes corresponding to the shape of said curve C9.
- the outwards offsetting could be made from any suitable curve, with any shape.
- the tool paths can be determined as outwardly offsetting curves of a predetermined shape, for example circles or circle segments, from a point with a suitable location.
- the distance between the offset curves CIO, Cl 1 corresponds to a suitable radial cutting depth of the tool 2.
- Curves created by outwards offsetting can intersect the tool center boundary curve TCBC. Additional outer tool paths are created by outwards offsetting, until created curves do not intersect the tool center boundary curve TCBC, i.e. are located outside the latter.
- the offset curves are trimmed against the tool center boundary curve TCBC, removing curve parts outside the latter, so that segments CIO, Cl 1 of closed curves or circles are created.
- Such segments, or clusters of segments form sections SI, S2, S3 of the processing region, which sections are formed in pockets inside the tool center boundary curve TCBC, where the latter presents a more abrupt curvature than the curves CIO, Cll created by outwards offsetting.
- Each section (for example SI in fig. 8a), can present subsections Sl-1, Sl-2 which are smaller sections or pockets, each with their own curve segments.
- the curve segments CIO, Cl 1 are interconnected to form a continuous tool path.
- the interconnection between the segments are formed by interconnecting segments of the TCBC, or by linear segments taking into account a suitable clearance towards the TCBC.
- a precision cut following the tool center boundary curve TCBC is made to clean the contour.
- An advantage with the technique of determining tool paths by offsetting outwards a curve, and trimming offset curves against a boundary curve TCBC is that the cutting depth of the tool can be controlled.
- Another advantage is that it is easy to check if the tool paths result in extraordinary movements that are undesired from a material processing point of view, e.g. due to a risk of damaging the material or the tool.
- a tool path stretches into a "shaded" area, e.g. behind a "peninsula” 21 or an island 22 formed by the tool center boundary curve TCBC.
- Such a shaded tool path is marked with "SX" in fig. 8b and 8c. Since material has not been removed inside of the shaded tool path the contact surface of the material and the tool becomes very large. The appearance of the shaded path as such is easy to detect, when using the technique of offsetting a curve outwards.
- a tool path is found to be undesired according to predetermined requirements, e.g. regarding the size of the contact surface of the material and the tool, the tool path is rejected.
- a region 23 is defined including an area covered by the rejected tool path SX, and a set of curved, preferably part-circular, tool paths 24 are defined with a suitable center of curvature and radiuses. Alternatively, such tool paths 24 can be straight.
- Fig. 9 shows, in a view of the dental material piece 1 sectioned as in fig. 1 and 4, a result of the step described above, to remove material between the first and the second level LI, L2, in the form of a cavity 15. It can be seen that material has been removed approximately up to the contour 6 of the intended final cavity, at the second level L2. It can be seen that a portion 16 of the dental material piece 1, outside the cavity 15, and between the cavity 15 and the contour 6 remains to be removed. Preferably, this is done by introducing a number of sublevels between the first and second levels LI, L2, and, starting from the lowest sublevel and raising the tool in a stepwise manner, removing material at each sublevel. Similar to what was described above with reference to fig.
- a tool center boundary curve, TCBCi-1, TCBCi-2, TCBCi-3 is determined.
- tool paths are created by offsetting outwards the tool center boundary curve TCBCi-1 from the sublevel below, i-1, towards the tool center boundary curve TCBCi-2 at the sublevel i-2. The result is shown in fig. 10.
- the processing of the dental restoration continues with similar steps as those described above.
- fig. 11 in a step corresponding to the step described above with reference to fig. 2, 3, and 4, material is removed from the dental material piece 1 from a first level LI of the dental material piece 1 to a second level L2 thereof, the first and the second level LI, L2 being separated by a distance d2 in a direction parallel to the rotational axis of the tool.
- the first level LI in the step described with reference to fig. 11, is the same as the second level L2 in the step described with reference to fig. 4.
- material is removed between the first and the second level LI, L2 by moving the tool 2 while in rotation essentially in a plane perpendicular to the rotational axis R of the tool 2, the result of which is shown in fig. 12.
- This is done in the same manner as described above with reference to fig. 7 and 8a. Similar to what has been described with reference to fig. 9, it can be seen that a portion 16 of the dental material piece 1, outside the cavity 15, and between the cavity 15 and the contour 6 remains to be removed.
- this is done by introducing a number of sublevels between the first and second levels LI, L2, and, starting from the lowest sublevel and raising the tool in a stepwise manner, removing material at each sublevel. The result is shown in fig. 13.
- a step according to the invention material is removed from the dental material piece 1 from a first level LI of the dental material piece 1 to a second level L2 thereof.
- the first level LI in the step described with reference to fig. 14 is the same as the second level L2 in the step de- scribed with reference to fig. 11.
- a subsequent step material is removed between the first and the second level LI, L2 by moving the tool while in rotation essentially in a plane perpendicular to the rotational axis R of the tool 2, the result of which is shown in fig. 15.
- Fig. 16 shows the result of removing a portion 16, shown in fig. 15, outside the cavity 15, and between the cavity 15 and the contour 6.
- the lowest level for using the tool 2, used in the steps described above is a level that permits creating an initial cavity C of a predetermined minimum diameter, so that it is ensured, during the creation of the initial cavity C, that the direction of the movement of the tool 2 forms an angle ⁇ to a rotational axis R of the tool.
- Fig. 17 shows the dental material piece 1 after removing further material in a similar manner to what has been described above, whereby a cavity 15 is obtained. A portion 17 at the bottom of the cavity 15 can be removed by a suitable tool.
- Levels processed by the relatively large tool 2 are analysed regarding areas not processed due to the size of the tool 2. Preferably, this analysis is performed from the bottom and up. At each level an inner curve is determined based on the processed area. The inner curve is expanded outwards similarly to what has been described above with reference to fig. 8a, to create tool paths to remove remaining ar- eas. This is done with a suitable tool with smaller dimensions.
- the cavity in the dental material piece 1 has been described as being created by two steps being repeted alternately, namely: providing an initial cavity C in the material dental piece 1, and removing material outside the initial cavity C. It should be noted that these steps can be carried out using the same or different tools.
- a step of providing an initial cavity C in the material dental piece 1 can be followed by repeated steps of removing material outside the initial cavity C, whereby the initial cavity C is relatively deep and material is removed outside of the initial cavity at a plurality of levels.
- initial cavities or pre-cavities can be pre-made in dental restoration blanks or work pieces.
- the initial cavity C can advantageously be formed before sintering of the material, or, when compression moulding the blanks, the initial cavity C can be formed by providing a protruding part in the mould.
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Dentistry (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)
Abstract
L'invention concerne un procédé permettant de préparer une restauration dentaire à l'aide d'au moins un outil (2) d'enlèvement de matériau tournant, qui consiste à fournir une pièce de matériau dentaire (1) à partir de laquelle on prépare la restauration dentaire, à fournir une cavité initiale (C) dans la pièce de matériau dentaire (1), et enlever le matériau hors de la cavité initiale (C) par déplacement de l'outil (2) dans un plan perpendiculaire à l'axe de rotation (R) de l'outil (2). En ce qui concerne les matériaux de restauration dentaire durs et fragiles, les risques de défaillance du matériau, d'usure excessive et de défaillance de l'outil sont réduits, ce qui rend possible des vitesses d'exécution plus élevées.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/SE2004/001934 WO2005058184A1 (fr) | 2003-12-19 | 2004-12-20 | Procede de production d'une restauration dentaire |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1827291A1 true EP1827291A1 (fr) | 2007-09-05 |
Family
ID=36992810
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04809107A Withdrawn EP1827291A1 (fr) | 2004-12-20 | 2004-12-20 | Procede de production d'une restauration dentaire |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1827291A1 (fr) |
CA (1) | CA2633248A1 (fr) |
WO (1) | WO2005058184A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3797733A1 (fr) * | 2019-09-24 | 2021-03-31 | DENTSPLY SIRONA Inc. | Procédé de planification de trajets d'outils de forme libre pour usinage simultané sur deux faces avec couplage d'axe cinématique |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2525103B1 (fr) * | 1982-04-14 | 1985-09-27 | Duret Francois | Dispositif de prise d'empreinte par des moyens optiques, notamment en vue de la realisation automatique de protheses |
US4707793A (en) * | 1985-09-30 | 1987-11-17 | The Boeing Company | Method of determining feed rate and cutting speed for cutting metal and of predicting cutting effects |
US5257203A (en) * | 1989-06-09 | 1993-10-26 | Regents Of The University Of Minnesota | Method and apparatus for manipulating computer-based representations of objects of complex and unique geometry |
DE19930859A1 (de) * | 1999-07-05 | 2001-01-18 | Sirona Dental Systems Gmbh | Verfahren zur Erstellung von medizinischen, insbesondere zahnmedizinischen Paßkörpern |
DE10104287B4 (de) * | 2001-01-30 | 2006-08-24 | Sirona Dental Systems Gmbh | Verfahren zur Bestimmung aktueller Positionsdaten eines Bearbeitungswerkzeuges und Vorrichtung hierzu |
SE523022C3 (sv) * | 2001-03-23 | 2004-04-14 | Cad Esthetics Ab | Förfarande och anordning för en dental restauration |
DE10156156B4 (de) * | 2001-11-15 | 2005-04-21 | 3M Espe Ag | Verfahren zur Herstellung von Zahnersatz |
-
2004
- 2004-12-20 CA CA002633248A patent/CA2633248A1/fr not_active Abandoned
- 2004-12-20 WO PCT/SE2004/001934 patent/WO2005058184A1/fr active Application Filing
- 2004-12-20 EP EP04809107A patent/EP1827291A1/fr not_active Withdrawn
Non-Patent Citations (1)
Title |
---|
See references of WO2005058184A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2005058184A1 (fr) | 2005-06-30 |
WO2005058184A8 (fr) | 2006-08-24 |
CA2633248A1 (fr) | 2005-06-30 |
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