EP1795629A2 - Nettoyage dýoxyde et revêtement de composants métalliques - Google Patents
Nettoyage dýoxyde et revêtement de composants métalliques Download PDFInfo
- Publication number
- EP1795629A2 EP1795629A2 EP06125537A EP06125537A EP1795629A2 EP 1795629 A2 EP1795629 A2 EP 1795629A2 EP 06125537 A EP06125537 A EP 06125537A EP 06125537 A EP06125537 A EP 06125537A EP 1795629 A2 EP1795629 A2 EP 1795629A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- oxide
- component
- coating
- acidic solution
- alkaline cleaner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/02—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/18—Solid state diffusion of only metal elements or silicon into metallic material surfaces using liquids, e.g. salt baths, liquid suspensions
- C23C10/20—Solid state diffusion of only metal elements or silicon into metallic material surfaces using liquids, e.g. salt baths, liquid suspensions only one element being diffused
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/20—Other heavy metals
Definitions
- This invention relates generally to repair and overhaul of metallic components and more particularly to removal of oxide layers from engine-run components.
- Gas turbine components such as turbine nozzle segments are exposed during operation to a high temperature, corrosive gas stream, both externally and internally.
- Prior art turbine nozzles show excessive degradation in the internal passages due to oxidation and/or hot corrosion after multiple repairs, and service usage, as shown in Figure 1.
- This situation primarily occurs when in new part manufacturing the internal passages are not coated by oxidation resistant aluminide coating.
- the wall degradation takes place from inside due to oxidation of the unprotected interior walls, and from outside by operations such as grit blasting, and gaseous treatment during various service repair operations.
- the part wall thickness is excessively low (thin wall), the part has to be scrapped, resulting in added cost for long term engine maintenance.
- nozzle segments are complex in design, are made of relatively expensive materials, and are expensive to manufacture, it is generally desirable to extend their operating lives as long as possible.
- Vapor phase aluminiding (VPA) to apply aluminide coatings has been found to be ineffective to provide oxidation protection to internal passages, as aluminide vapors cannot reach inside stagnant internal surfaces.
- known types of internal coatings can not be effectively applied over an internal oxide layers in an engine-run component.
- the present invention which according to one aspect provides a method of removing an oxide layer from a surface of a metallic component, including: (a) contacting the surface with an alkaline cleaner adapted to modify the oxide to make it more easily removable without causing significant attack to the metallic component ; (b) contacting the surface with an acidic solution adapted to remove the treated oxide without causing significant attack to the metallic component; and (c) repeating steps (a) and (b) in the order stated until a preselected amount of the oxide layer is removed.
- a method of coating an engine-run metallic component having at least one surface with an oxide layer thereupon includes: (a) contacting the surface with an alkaline cleaner adapted to modify the oxide to make it more easily removable without causing significant attack to the metallic component; (b) contacting the surface with an acidic solution adapted to remove the treated oxide without causing significant attack to the metallic component; (c) disposing a slurry comprising an aluminum source on the surface; (d) heating the component to transport aluminum from the slurry to the surface, thereby producing an aluminide coating on the surface; and (e) removing the residue of the slurry from the surface.
- Figure 1 depicts a prior art turbine nozzle segment 10 having first and second nozzle vanes 12. It is noted that the present invention is equally applicable to other types of hollow metallic components, non-limiting examples of which include rotating turbine blades, internally cooled turbine shrouds, and the like.
- the vanes 12 are disposed between an arcuate outer band 14 and an arcuate inner band 16.
- the vanes 12 define airfoils configured so as to optimally direct the combustion gases to a turbine rotor (not shown) located downstream thereof.
- the outer and inner bands 14 and 16 define the outer and inner radial boundaries, respectively, of the gas flow through the nozzle segment 10.
- Each of the vanes 12 has a hollow interior cavity 18 disposed therein which receives relatively cool air to cool the vane.
- the spent cooling air is directed through exits such as cooling holes 20 and trailing edge slots 22.
- the nozzle segment 10 is typically made of a high quality superalloy, such as a cobalt or nickel-based superalloy, and may be coated with a corrosion resistant or "environmental" coating and/or a thermal barrier coating. Often, the interior cavities 18 are not coated with environmental coatings.
- the interior cavities 18 are subjected to oxygen-rich, high-temperature, e.g. 538° C (1000° F) air flow, causing them to experience formation of oxides as shown in Figure 2.
- oxygen-rich, high-temperature e.g. 538° C (1000° F) air flow
- oxides as shown in Figure 2.
- NDE non-destructive evaluation
- aluminide coatings applied over existing oxide layers exhibit a poor microstructure (see Figure 3) which is prone to detachment and spalling and does not generally provide the desired level of protection.
- the present invention provides a chemical cleaning sequence for removing these oxides, which begins by subjecting the interior cavity 18 to a scale conditioning cycle.
- the nozzle segment 10 is placed inside a cleaning.
- the working fluid for this first cycle is an alkaline cleaner which is capable of modifying oxide scale to make it more easily removable without causing significant attack to the base material of the nozzle segment 10.
- a suitable alkaline cleaner is a 2-part liquid alkaline solution comprising sodium hydroxide and sodium permanganate, sold under the designation
- TURCO 4338 available from Henkel Surface Technologies, Madson Heights, Michigan, 48071 USA. Other aggressive permanganate solutions may be substituted therefor.
- the alkaline cleaner is heated to an appropriate working temperature, for example about 80° C (175° F) to about 93°C (200° F).
- the nozzle segment 10 may be subjected to ultrasonic agitation during this cleaning cycle, using ultrasonic cleaning equipment of a known type.
- the cycle continues for a preselected time, for example about 30 minutes to about 60 minutes.
- the rate of depth penetration of the scale conditioning effect decays exponentially with time, and so extended treatment with the alkaline cleaner is neither necessary nor desirable.
- the nozzle segment 10 is rinsed with water to remove any remaining alkaline cleaner.
- the interior cavity 18 is then subjected to an oxide scale removal cycle. This may be done in the same cleaning tank or in a separate unit to speed the process.
- the working fluid for this second cycle is an acidic solution which is capable of removing the modified scale without causing significant attack to the base material of the nozzle segment 18.
- a suitable acidic solution is an aqueous solution of 75% by volume nitric acid.
- Other suitable acids may include phosphoric acid, sulfuric acid, or hydrochloric acid.
- a relatively high concentration of acid actually avoids pitting and attack on the base material of the nozzle segment 10 that may occur with lower concentrations of acid. While the precise acid concentration may be varied, base material attack is best avoided if the acid concentration is greater than about 25% by volume.
- the acidic solution is heated to an appropriate working temperature, for example about 77° C (170° F) to about 82° C (180° F). Ultrasonic agitation may optionally be applied as described above. It has been found that base material attack is best avoided if the temperature of the acid solution is greater than about 24°C (75°F).
- the cycle continues for a preselected time, for example about 30 minutes to about 60 minutes. The oxide layer is relatively rapidly removed to the depth at which it has been conditioned, and so extended treatment with the acidic solution is neither necessary nor desirable.
- the nozzle segment 10 is rinsed with water to remove any remaining acidic solution.
- the sequence of treatment in an alkaline cleaner followed by acidic solution is repeated as many times as necessary to remove the desired amount of the oxide build-up.
- the chemical cleaning sequence may have to be repeated four times or more to remove the total oxide thickness.
- substantially all of the oxides may be removed without degradation of the base material, in contrast to mechanical methods or other chemical methods.
- the internal cleaning method described above will typically be performed at the same time the nozzle segment 10 is undergoing a repair cycle, either because of time-in-service limits, or external conditions that warrant overhaul. Therefore, other processes such as crack repair and renewal of external coatings will often be performed at the same time.
- an appropriate exterior preparation process is carried out, for example a light grit blast with 240 grit media and about 207 kPA (30) to about 276 kPa (40 psi) air pressure.
- the exterior preparation process is controlled to assure that minimum amount of parent material is removed from the nozzle segment 10.
- a slurry for pack aluminide coating which includes a known type of powder mixture for producing an aluminide coating, and a binder.
- One suitable slurry consists essentially of, by weight, about 40% to about 80% of a powder mixture of an aluminum source, such as FeAl 2 , FeAl 3 , or Fe 2 Al 5 , and an inert material such as alumina, about 0.5% to about 1% of a carrier such as NH 4 F, and the balance of a slurry-forming binder.
- suitable powder mixtures, slurries and coating techniques are described in U.S. Patent 3,871,930 issued to Seybolt and assigned to the assignee of the present invention. This type of powder mixture and the coating process using this mixture have become known as a "CODAL" within the art.
- the slurry is applied to the interior cavity 18 so that it is uniformly covered.
- Metallic tape or other masking materials are applied as needed to openings such as the cooling holes 20 and trailing edge slots 22, to assure that slurry remains in the internal cavity 18.
- the slurry is dried, either at room temperature or in a low-temperature, i.e. about 43° C (110°
- the nozzle segment 10 is ready for the internal coating cycle. This may be done by heating the nozzle segment 10 in a nonoxidizing atmosphere, e.g., a gas such as helium or argon, and typically in a vacuum, to a temperature of from about 500° C (930° F) to about 800° C (1000° F), to diffuse the aluminum into the substrate and form an aluminide coating on the interior surfaces of the nozzle segment 10.
- a nonoxidizing atmosphere e.g., a gas such as helium or argon
- this coating cycle may occur over a wide range in time, e.g., from about 10 minutes to about 24 hours.
- the resulting coating is illustrated in Figure 5.
- the internal coating cycle may also be combined with a known vapor phase aluminide (VPA) coating process by heating the nozzle segment 10 in an oven or chamber containing an aluminide coating source material and provided with a nonoxidizing atmosphere at appropriate times and temperatures, for example about four hours at about 1080° C (1975° F).
- VPA vapor phase aluminide
- the finished nozzle segment 10 has both internal and external oxidation-resistant coatings, as shown in Figure 6.
- the microstructure of both the base material and the coatings are substantially the same as a new-make component, and the nozzle segment 10 will meet all of the metallurgical requirements of a new component.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Cleaning By Liquid Or Steam (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/296,165 US20070125459A1 (en) | 2005-12-07 | 2005-12-07 | Oxide cleaning and coating of metallic components |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1795629A2 true EP1795629A2 (fr) | 2007-06-13 |
EP1795629A3 EP1795629A3 (fr) | 2011-01-12 |
Family
ID=37831693
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06125537A Withdrawn EP1795629A3 (fr) | 2005-12-07 | 2006-12-06 | Nettoyage dýoxyde et revêtement de composants métalliques |
Country Status (6)
Country | Link |
---|---|
US (1) | US20070125459A1 (fr) |
EP (1) | EP1795629A3 (fr) |
JP (1) | JP2007186786A (fr) |
BR (1) | BRPI0605554A (fr) |
CA (1) | CA2570408A1 (fr) |
SG (2) | SG133513A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2241727A4 (fr) * | 2008-02-14 | 2016-06-22 | Mitsubishi Hitachi Power Sys | Procédé de régénération d'aube de turbine à gaz et appareil de régénération d'aube de turbine à gaz |
US11926905B2 (en) | 2019-03-14 | 2024-03-12 | Rolls-Royce Plc | Method of removing a ceramic coating from a ceramic coated metallic article |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1978129A3 (fr) * | 2007-03-29 | 2014-12-17 | Ebara Corporation | Procédé de formation de film résistant à la corrosion et élément d'appareil haute température |
JP2012111622A (ja) * | 2010-11-26 | 2012-06-14 | Bando Chemical Industries Ltd | コンベヤベルトの製造方法、及び、コンベヤベルト |
JP2014163261A (ja) * | 2013-02-22 | 2014-09-08 | Mitsubishi Heavy Ind Ltd | 酸性水溶液の使用可否判断方法 |
US9844799B2 (en) * | 2015-12-16 | 2017-12-19 | General Electric Company | Coating methods |
JP6685722B2 (ja) * | 2015-12-28 | 2020-04-22 | 三菱日立パワーシステムズ株式会社 | タービン翼の補修方法 |
JP6101832B2 (ja) * | 2016-02-16 | 2017-03-22 | 三菱重工業株式会社 | 酸性水溶液の使用可否判断方法 |
US10053779B2 (en) * | 2016-06-22 | 2018-08-21 | General Electric Company | Coating process for applying a bifurcated coating |
US11247249B2 (en) * | 2017-04-18 | 2022-02-15 | General Electric Company | Method for removing oxide materials from a crack |
US10377968B2 (en) | 2017-06-12 | 2019-08-13 | General Electric Company | Cleaning compositions and methods for removing oxides from superalloy substrates |
US10830093B2 (en) * | 2017-06-13 | 2020-11-10 | General Electric Company | System and methods for selective cleaning of turbine engine components |
CN110339978A (zh) * | 2018-04-08 | 2019-10-18 | 金东纸业(江苏)股份有限公司 | 一种清洗方法以及清洗装置 |
US11136674B2 (en) | 2018-12-21 | 2021-10-05 | Raytheon Technologies Corporation | Turbine blade internal hot corrosion oxide cleaning |
WO2023203797A1 (fr) * | 2022-04-21 | 2023-10-26 | 株式会社Ihi | Procédé de retrait de film de traitement de surface de décharge |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3000829A (en) * | 1958-06-12 | 1961-09-19 | Purex Corp Ltd | Composition and process for descaling metal parts |
FR1292467A (fr) * | 1960-05-27 | 1962-05-04 | Gen Electric | Procédé de nettoyage chimique des articles métalliques |
US3598638A (en) * | 1968-11-29 | 1971-08-10 | Gen Electric | Diffusion metallic coating method |
US3833414A (en) * | 1972-09-05 | 1974-09-03 | Gen Electric | Aluminide coating removal method |
US4004047A (en) * | 1974-03-01 | 1977-01-18 | General Electric Company | Diffusion coating method |
US4327134A (en) * | 1979-11-29 | 1982-04-27 | Alloy Surfaces Company, Inc. | Stripping of diffusion treated metals |
US4347267A (en) * | 1979-10-31 | 1982-08-31 | Alloy Surfaces Company, Inc. | Diffusion coating through restrictions |
US4655383A (en) * | 1984-05-17 | 1987-04-07 | Societe Nationale D'etude Et De Construction De Moteurs D'aviation | Method of repairing heat resistant alloy parts |
US4707191A (en) * | 1984-03-09 | 1987-11-17 | Societe Nationale D'etude Et De Construction De Moteurs D'aviation (Snecma) | Pickling process for heat-resistant alloy articles |
EP1013797A1 (fr) * | 1998-12-22 | 2000-06-28 | General Electric Company | Procédé d'enlèvement de produits de corrosion à haute température d'un revêtement d'une aluminure par diffusion |
EP1065296A1 (fr) * | 1999-06-30 | 2001-01-03 | General Electric Company | Procédé de formation d'un revêtement métallique |
EP1507019A1 (fr) * | 2003-08-11 | 2005-02-16 | General Electric Aviation Service Operation (PTE) Ltd. | Valorisation d'un revêtement d'aluminures d'un component usé de moteur à turbine |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3129069A (en) * | 1956-10-11 | 1964-04-14 | Gen Motors Corp | Oxidation-resistant turbine blades |
US3837901A (en) * | 1970-08-21 | 1974-09-24 | Gen Electric | Diffusion-coating of nickel-base superalloy articles |
US4332843A (en) * | 1981-03-23 | 1982-06-01 | General Electric Company | Metallic internal coating method |
US5217757A (en) * | 1986-11-03 | 1993-06-08 | United Technologies Corporation | Method for applying aluminide coatings to superalloys |
US5366765A (en) * | 1993-05-17 | 1994-11-22 | United Technologies Corporation | Aqueous slurry coating system for aluminide coatings |
US5685917A (en) * | 1995-12-26 | 1997-11-11 | General Electric Company | Method for cleaning cracks and surfaces of airfoils |
US5938855A (en) * | 1998-01-20 | 1999-08-17 | General Electric Company | Method for cleaning a turbine component |
US6497920B1 (en) * | 2000-09-06 | 2002-12-24 | General Electric Company | Process for applying an aluminum-containing coating using an inorganic slurry mix |
US6586052B2 (en) * | 2001-09-21 | 2003-07-01 | Rolls-Royce Corporation | Method for coating internal surfaces |
US6454870B1 (en) * | 2001-11-26 | 2002-09-24 | General Electric Co. | Chemical removal of a chromium oxide coating from an article |
US6878215B1 (en) * | 2004-05-27 | 2005-04-12 | General Electric Company | Chemical removal of a metal oxide coating from a superalloy article |
-
2005
- 2005-12-07 US US11/296,165 patent/US20070125459A1/en not_active Abandoned
-
2006
- 2006-12-06 EP EP06125537A patent/EP1795629A3/fr not_active Withdrawn
- 2006-12-06 CA CA002570408A patent/CA2570408A1/fr not_active Abandoned
- 2006-12-07 BR BRPI0605554-0A patent/BRPI0605554A/pt not_active IP Right Cessation
- 2006-12-07 SG SG200608507-0A patent/SG133513A1/en unknown
- 2006-12-07 JP JP2006330463A patent/JP2007186786A/ja not_active Withdrawn
- 2006-12-07 SG SG200903768-0A patent/SG154426A1/en unknown
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3000829A (en) * | 1958-06-12 | 1961-09-19 | Purex Corp Ltd | Composition and process for descaling metal parts |
FR1292467A (fr) * | 1960-05-27 | 1962-05-04 | Gen Electric | Procédé de nettoyage chimique des articles métalliques |
US3598638A (en) * | 1968-11-29 | 1971-08-10 | Gen Electric | Diffusion metallic coating method |
US3833414A (en) * | 1972-09-05 | 1974-09-03 | Gen Electric | Aluminide coating removal method |
US4004047A (en) * | 1974-03-01 | 1977-01-18 | General Electric Company | Diffusion coating method |
US4347267A (en) * | 1979-10-31 | 1982-08-31 | Alloy Surfaces Company, Inc. | Diffusion coating through restrictions |
US4327134A (en) * | 1979-11-29 | 1982-04-27 | Alloy Surfaces Company, Inc. | Stripping of diffusion treated metals |
US4707191A (en) * | 1984-03-09 | 1987-11-17 | Societe Nationale D'etude Et De Construction De Moteurs D'aviation (Snecma) | Pickling process for heat-resistant alloy articles |
US4655383A (en) * | 1984-05-17 | 1987-04-07 | Societe Nationale D'etude Et De Construction De Moteurs D'aviation | Method of repairing heat resistant alloy parts |
EP1013797A1 (fr) * | 1998-12-22 | 2000-06-28 | General Electric Company | Procédé d'enlèvement de produits de corrosion à haute température d'un revêtement d'une aluminure par diffusion |
EP1065296A1 (fr) * | 1999-06-30 | 2001-01-03 | General Electric Company | Procédé de formation d'un revêtement métallique |
EP1507019A1 (fr) * | 2003-08-11 | 2005-02-16 | General Electric Aviation Service Operation (PTE) Ltd. | Valorisation d'un revêtement d'aluminures d'un component usé de moteur à turbine |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2241727A4 (fr) * | 2008-02-14 | 2016-06-22 | Mitsubishi Hitachi Power Sys | Procédé de régénération d'aube de turbine à gaz et appareil de régénération d'aube de turbine à gaz |
US11926905B2 (en) | 2019-03-14 | 2024-03-12 | Rolls-Royce Plc | Method of removing a ceramic coating from a ceramic coated metallic article |
Also Published As
Publication number | Publication date |
---|---|
EP1795629A3 (fr) | 2011-01-12 |
SG154426A1 (en) | 2009-08-28 |
US20070125459A1 (en) | 2007-06-07 |
CA2570408A1 (fr) | 2007-06-07 |
SG133513A1 (en) | 2007-07-30 |
JP2007186786A (ja) | 2007-07-26 |
BRPI0605554A (pt) | 2007-10-16 |
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Legal Events
Date | Code | Title | Description |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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