EP1771266A1 - Zirconia refractories for making steel - Google Patents
Zirconia refractories for making steelInfo
- Publication number
- EP1771266A1 EP1771266A1 EP05749395A EP05749395A EP1771266A1 EP 1771266 A1 EP1771266 A1 EP 1771266A1 EP 05749395 A EP05749395 A EP 05749395A EP 05749395 A EP05749395 A EP 05749395A EP 1771266 A1 EP1771266 A1 EP 1771266A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- steel
- strip
- percent
- making steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 71
- 239000010959 steel Substances 0.000 title claims abstract description 71
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 239000011819 refractory material Substances 0.000 title claims abstract description 38
- 238000005266 casting Methods 0.000 claims abstract description 56
- 229910052751 metal Inorganic materials 0.000 claims abstract description 48
- 239000002184 metal Substances 0.000 claims abstract description 48
- 238000009749 continuous casting Methods 0.000 claims abstract description 28
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 19
- 235000006708 antioxidants Nutrition 0.000 claims abstract description 19
- 230000007704 transition Effects 0.000 claims abstract description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000000395 magnesium oxide Substances 0.000 claims description 10
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 10
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 10
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 9
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 9
- 239000004571 lime Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 6
- 150000001247 metal acetylides Chemical class 0.000 abstract description 2
- 238000009628 steelmaking Methods 0.000 abstract description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000002893 slag Substances 0.000 description 6
- 229910001208 Crucible steel Inorganic materials 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 230000005499 meniscus Effects 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 229910052580 B4C Inorganic materials 0.000 description 2
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 2
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-IGMARMGPSA-N Carbon-12 Chemical compound [12C] OKTJSMMVPCPJKN-IGMARMGPSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/50—Pouring-nozzles
- B22D41/52—Manufacturing or repairing thereof
- B22D41/54—Manufacturing or repairing thereof characterised by the materials used therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0622—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by two casting wheels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0637—Accessories therefor
- B22D11/064—Accessories therefor for supplying molten metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/02—Linings
Definitions
- This invention relates to making of steel, and more particularly to making of steel by continuous casting.
- the invention has application in making steel by casting steel strip.
- molten steel is delivered to a caster from a ladle through a tundish and melt delivery system including a shroud, a delivery nozzle and sometimes a transition piece. ..
- These metal delivery components deliver molten steel at 1500 to 1600 °C, or more, to the caster through refractories which are capable of withstanding the high temperatures in the process of casting molten steels. These refractories may also be preheated to the delivery temperature to avoid thermal shock when the molten steel is introduced through the delivery system.
- These metal delivery components are used in continuous casting by, among others, thick slab casters, thin slab casters and thin strip casters.
- refractory materials for such metal delivery components particularly useful in thin strip casting are those described in U.S. Patent Nos . 5,924,476 and 6,257, 315.
- molten metal is typically introduced between a pair of counter rotated horizontally positioned casting rolls to form a nip between them.
- the casting rolls are internally cooled so that metal shells solidify on the moving roll surfaces and are brought together at the nip to produce a cast strip delivered downwardly from the nip.
- nip is used herein to refer to the general region at which the casting rolls are closest together .
- the molten metal may be poured from a ladle into a smaller vessel from which the metal flows through a delivery nozzle located above the nip to form a casting pool supported on the casting surfaces .
- the casting pool is supported on the casting rolls adjacent the nip and extending along the length of the nip .
- the casting pool is usually confined between side plates or dams held in sliding engagement with end surfaces of the casting rolls so as to dam the two ends of the casting pool against outflow.
- a problem in such metal delivery systems is that the molten slag tends to stick to the refractories of the delivery system. This has been known to occur even when the refractories are pre-heated to the temperature of the molten steel .
- the build up of slag that occurs on the refractories from the molten steel has a tendency to break away, and cause defects to form in the cast steel and on the surface of the cast steel . This is particularly true of the build up that occurs at the meniscus of the casting pool in thin strip casters .
- the refractory material or such thin strip steelmaking is comprised of 50 to 85% zirconia (Zr02) , 0 to 35% of silica (Si02) , 5 to 35% carbon (C) , less than 5% alumina (A1203) and an anti-oxidant (all percentages are stated percent by weight) .
- the purity of the carbon used may be greater than 99.5%.
- the refractory material may be stabilized with lime or magnesium oxide, and typically in an amount less than about 28%.
- the refractory material has application in making delivery nozzles and transition piece nozzle blocks for use in making steel by continuous casting of steel strip.
- the refractory material may by used, for example, in making a delivery nozzle for use in making steel by continuous casting of steel strip.
- Also disclosed is a method of continuous casting of steel strip comprising the steps of: a. assembling a pair of cooled casting rolls having a nip between them and with confining closure adjacent the ends of the nip; b. assembling a metal delivery system for delivering a molten steel between the casting rolls to form a casting pool supported therebetween comprised of at least some refractory material for contacting the molten steel, the refractory material comprised of 50 to 85% zirconia, 0 to 35% silica, 5 to 35% carbon, less than 5 % alumina and an anti-oxidant, and c. counter rotating the casting rolls to form metal shells on the surfaces of the casting rolls and solidified thin steel strip delivered downwardly through the nip between the casting rolls .
- the refractory material may have a zirconia (Zr02) content between 60 and 85 %, and more specifically between 70 and 80% by weight.
- the refractory material may have a carbon content between 8 and 30%, and more specifically between 10 and 20% by weight.
- the zirconia may be stabilized or unstabilized, but again the refractory material may be stabilized with lime or magnesium oxide or a combination thereof to reduce wear on the refractory material during use .
- the anti-oxidant inhibits oxidation of the other components of the refractory material, and may be any one or a combination of such materials that inhibits oxidation in the refractory material system.
- the anti-oxidant may be present in an amount up to about 10% by weight. Examples of an ioxidants are, without limitation, Si metal , Al metal , silicon aluminum alloy and carbides such as boron carbide and silicon carbide .
- Figure 1 illustrates the flow of molten steel through a metal delivery system into a twin-roll caster.
- a twin-roll caster 11 comprises a main machine frame 21 which supports a pair of internally cooled casting rolls 22 having casting surfaces 22A.
- the casting rolls 22 are positioned laterally adjacent each other to form a nip 27 between them and through which cast steel strip may be formed.
- the twin-roll caster may be as illustrated in US Patent Nos . 5,184,668, 5,277,243 and 5,488,988, to which reference can be made for more detail .
- Molten metal is supplied for the continuous casting of strip from the ladle (not shown) to a tundish 23.
- transition piece nozzle block 25 is configured to generally enclose the molten metal from exposure to the outside atmosphere, with an overflow 19 through which molten metal can flow should the metal in the transition piece reach a point of overflowing.
- the molten metal is delivered from the shroud 24 into transition piece 25 usually below the fill-line 16 of the molten metal in the transition piece to minimize exposure of the molten metal to air.
- the molten metal is delivered to the casting pool 30 through a delivery nozzle 26 made of refractory material.
- the upper surface 31 of the casting pool 30 (generally referred to as the meniscus level) may rise above the lower end of the delivery nozzle 26 so that the lower end of the delivery nozzle is immersed within the casting pool 30 , which is confined at the ends of the rolls by a pair of side closure dams or plates 28.
- Casting pool 30 is positioned above the nip 27 between the casting rolls 22 supported on the casting roll surfaces 22A.
- the casting rolls 22 are driven to counter- rotate, and the casting rolls 22 are cooled internally, usually with circulation of water. As the casting rolls rotate, shells of metal solidify from the casting pool 30 on the moving casting roll surfaces 22A. The shells are in turn brought together at the nip 27 between casting rolls 22 to produce solidified strip 12 delivered downwardly from the nip 27.
- the transition piece nozzle block 25 and the delivery nozzle 26 may be made of the refractory material of the present invention.
- the refractory material is comprised of 50 to 85% by weight zirconia, 0 to 35% by weight of silica, less than 5% by weight alumina, 5 to 35% by weight carbon and an anti-oxidant.
- the remainder of the chemical composition of the refractory may be other materials such as lime (e.g. 3%) which are purposefully added for stabilization, and impurities .
- the refractory in any case is a carbon bonded silica graphite .
- Typical physical properties of the refractory of the specific composition are as follows :
- the advantage of the refractory as described is that molten metal does not stick to the refractory and form slag as the molten metal flows through in contact with the refractory.
- Such slag usually collects at the meniscus of the casting pool 30 , from where the slag breaks off and goes into the shells formed during solidification and into the strip 12 to produce defects in the strip and surface defects in the strip.
- zirconia carbon refractories of the present invention such slag formation is inhibited and strip quality is improved in continuously making strip by the twin-roll caster.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Continuous Casting (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/869,362 US20050280192A1 (en) | 2004-06-16 | 2004-06-16 | Zirconia refractories for making steel |
PCT/AU2005/000870 WO2005123301A1 (en) | 2004-06-16 | 2005-06-16 | Zirconia refractories for making steel |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1771266A1 true EP1771266A1 (en) | 2007-04-11 |
EP1771266A4 EP1771266A4 (en) | 2007-09-26 |
Family
ID=35479820
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05749395A Withdrawn EP1771266A4 (en) | 2004-06-16 | 2005-06-16 | Zirconia refractories for making steel |
Country Status (8)
Country | Link |
---|---|
US (1) | US20050280192A1 (en) |
EP (1) | EP1771266A4 (en) |
JP (1) | JP2008502481A (en) |
KR (1) | KR20070051785A (en) |
CN (1) | CN101014431A (en) |
AU (1) | AU2005254119A1 (en) |
RU (1) | RU2007101388A (en) |
WO (1) | WO2005123301A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20100080938A (en) * | 2007-12-05 | 2010-07-13 | 신닛뽄세이테쯔 카부시키카이샤 | Immersion nozzle and method of continuous casting |
JP2013043811A (en) * | 2011-08-25 | 2013-03-04 | Asahi Glass Co Ltd | Stabilized zirconia sintered refractory and manufacturing method therefor |
CN105983667B (en) * | 2015-01-29 | 2020-04-21 | 边仁杰 | Belt furnace mold |
CN107399761A (en) * | 2017-08-22 | 2017-11-28 | 汉川市石金科技有限公司 | A kind of zirconium oxide waste recovery technique and recovery zirconium powder |
CN107445614A (en) * | 2017-08-22 | 2017-12-08 | 汉川市石金科技有限公司 | A kind of compound zirconium oxide powder and preparation method thereof |
Citations (3)
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US4540675A (en) * | 1983-05-02 | 1985-09-10 | Vesuvius Crucible Company | Carbon-containing refractories with superior erosion and oxidation resistance |
JPH01183460A (en) * | 1988-01-14 | 1989-07-21 | Nippon Cement Co Ltd | Production of sintered ceramic material |
DE4109375A1 (en) * | 1991-03-22 | 1992-09-24 | Dolomitwerke Gmbh | METHOD FOR PRODUCING A FIRE-RESISTANT COMPOSITE MATERIAL |
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GB1477632A (en) * | 1973-08-16 | 1977-06-22 | Foseco Int | Containers for molten metal |
JPS591229B2 (en) * | 1978-04-26 | 1984-01-11 | 明知耐火煉瓦株式会社 | Immersion nozzle for continuous casting of molten steel |
JPS55158858A (en) * | 1979-05-30 | 1980-12-10 | Akechi Ceramic Kk | Immersion nozzle for continuous casting of molten steel |
JPS5732858A (en) * | 1980-08-07 | 1982-02-22 | Nippon Kokan Kk <Nkk> | Immersion nozzle for continuous casting of molten steel |
JPS5921574A (en) * | 1982-07-28 | 1984-02-03 | 品川白煉瓦株式会社 | Immersion nozzle for continuous casting |
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JPS6424069A (en) * | 1987-07-15 | 1989-01-26 | Kurosaki Refractories Co | Brick of sliding nozzle plate for special steel |
AU593997B2 (en) * | 1987-09-03 | 1990-02-22 | Sumitomo Metal Industries Ltd. | A nozzle for discharging molten metal used in a casting device |
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-
2004
- 2004-06-16 US US10/869,362 patent/US20050280192A1/en not_active Abandoned
-
2005
- 2005-06-16 JP JP2007515740A patent/JP2008502481A/en not_active Withdrawn
- 2005-06-16 RU RU2007101388/02A patent/RU2007101388A/en not_active Application Discontinuation
- 2005-06-16 WO PCT/AU2005/000870 patent/WO2005123301A1/en active Application Filing
- 2005-06-16 EP EP05749395A patent/EP1771266A4/en not_active Withdrawn
- 2005-06-16 KR KR1020067026484A patent/KR20070051785A/en not_active Application Discontinuation
- 2005-06-16 CN CNA2005800201368A patent/CN101014431A/en active Pending
- 2005-06-16 AU AU2005254119A patent/AU2005254119A1/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US4540675A (en) * | 1983-05-02 | 1985-09-10 | Vesuvius Crucible Company | Carbon-containing refractories with superior erosion and oxidation resistance |
JPH01183460A (en) * | 1988-01-14 | 1989-07-21 | Nippon Cement Co Ltd | Production of sintered ceramic material |
DE4109375A1 (en) * | 1991-03-22 | 1992-09-24 | Dolomitwerke Gmbh | METHOD FOR PRODUCING A FIRE-RESISTANT COMPOSITE MATERIAL |
Non-Patent Citations (1)
Title |
---|
See also references of WO2005123301A1 * |
Also Published As
Publication number | Publication date |
---|---|
RU2007101388A (en) | 2008-07-27 |
EP1771266A4 (en) | 2007-09-26 |
JP2008502481A (en) | 2008-01-31 |
CN101014431A (en) | 2007-08-08 |
WO2005123301A1 (en) | 2005-12-29 |
KR20070051785A (en) | 2007-05-18 |
US20050280192A1 (en) | 2005-12-22 |
AU2005254119A1 (en) | 2005-12-29 |
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