Classifications

• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
  • C25B9/60—Constructional parts of cells
  • C25B9/65—Means for supplying current; Electrode connections; Electric inter-cell connections
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
  • C25B9/60—Constructional parts of cells
  • C25B9/65—Means for supplying current; Electrode connections; Electric inter-cell connections
  • C25B9/66—Electric inter-cell connections including jumper switches

Definitions

• the invention relates to electrolyzers with bipolar electrodes, and especially to the electric power supply of such electrolyzers.
• the invention especially relates to an electric circuit for supplying rectified electric power to an electrolyzer with bipolar electrodes.
• Electrolyzers with bipolar electrodes supplied with DC power, are commonly used in the electrochemical industry. Such electrolyzers are commonly used to electrolyze aqueous solutions of sodium chloride, in order to produce chlorine, aqueous sodium hydroxide solutions or aqueous solutions of sodium chlorate.
• rectified AC power is generally substituted for DC power. Rectified AC power normally presents pulses of which the frequency and amplitude depend on the rectifier used.
• the electromagnetic field produced by the rectified AC power is likely to generate induced currents which may be relatively strong in certain industrial applications, particularly with bipolar electrolyzers for the continuous production of chlorine and of aqueous sodium hydroxide solutions. It is also well known that under extreme conditions, high electromagnetic fields can have detrimental effects on the human organism, especially those produced by rectified AC power, because of the induced currents that they are liable to generate. It is consequently important to take measures to protect the personnel in the neighbourhood of the industrial installations or to reduce the strength of the electromagnetic fields. Standards have moreover been set in this sense, requiring the limitation of the strength of electromagnetic fields in industrial premises. Among these standards, European standard 89/391/EEC is particularly stringent.
• the invention relates to an electric circuit of an electrolyzer with bipolar electrodes, comprising at least one electric current line that is placed outside the electrolyzer, characterized in that the electric current line comprises at least one busbar which is placed below andor above the electrolyzer.
• the invention relates more specifically to electrolyzers with substantially vertical bipolar electrodes.
• electrolyzers are well known in the art, where they are widely used for the electrolysis of aqueous solutions of metal halides, particularly sodium chloride.
• These electrolyzers are generally formed from a succession of metal frames each comprising a bipolar electrode, these frames being juxtaposed as in a filter press (Moderne Chlor-alkali technology, Volume 3, SCI, 1986, chapter 13 "Operating experience gained with the bipolar Hoechst-Uhde membrane cell” ; Modern Chlor-alkali Technology, Volume 4, SCI, 1990, chapter 20 ' ⁇ oechst-Uhde single element membrane electrolyzer : concept-experiences-applications").
• the frames usually have a square or rectangular profile, so tha when they are juxtaposed, as in a filter press, they form an upper wall, a lower or bottom wall, and two side walls of the electrolyzer.
• the electrolyzer is normally supplied with DC power or, more generally, with rectified AC power.
• the DC or rectified AC power flows from a terminal of the DC source or of the rectifier, through the bipolar electrodes, and then returns to the other terminal of the DC source or the rectifier, via an electric current line located outside the electrolyzer.
• the said return electric current line comprises at least one busbar that is placed below or above the electrolyzer.
• the choice of placing the busbar below or above the electrolyzer is dictated by considerations related to the construction of the electrolyzer and the method of assembling the bipolar electrodes.
• the abovementioned electric current line may comprise a busbar placed below the electrolyzer and another busbar placed above the electrolyzer.
• the electrolyzer may also comprise a plurality of busbars below the electrolyzer and/or a plurality of busbars above the electrolyzer. In practice, for considerations related to the assembly and maintenance of the electrolyzer, it is generally preferable for the abovementioned electric current line not to comprise a busbar above the electrolyzer.
• the electric circuit according to the invention significantly reduces the electromagnetic field in the neighbourhood of the electrolyzer with bipolar electrodes, chiefly along its side walls, especially on walkways that are normally installed along the side walls and are used by the operating and maintenance personnel.
• the expression "in the neighbourhood of the electrolyzer” means the space along the side walls of the electrolyzer, where the walkways used by the operating and maintenance personnel of the electrolyzer are normally installed.
• the material of the busbar is not a critical factor for the definition of the invention. It is generally made from copper, aluminium or aluminium alloy.
• the profile of the cross section of the busbar is not a critical factor for the definition of the invention.
• the busbar has a rectangular profile and is oriented so that its large sides are substantially horizontal. It has been observed, all other things remaining equal, that the selection of a rectangular section busbar, placed horizontally below and/or above the electrolyzer, minimises the strength of the electromagnetic field in the neighbourhood of the electrolyzer. I has also been observed that the decrease in the electromagnetic field in the neighbourhood of the electrolyzer is greater if the ratio of the thickness to the width of the busbar is smaller. In practice, it is consequently preferable to use a metal flat for the busbar.
• a plurality of metal flats can be used, placed side by side below and/or above the electrolyzer. It has further been observed, all other things remaining equal, that the ' strength of the electromagnetic field in the neighbourhood of the electrolyzer decreases as the busbar is brought closer to the wall of the electrolyzer.
• the busbar is placed immediately next to a wall of the electrolyzer.
• the said wall of the electrolyzer is the lower or bottom wall of the electrolyzer or its upper wall, depending on whether the busbar is positioned below or above the electrolyzer.
• the expression “immediately next to the wall of the electrolyzer” means that the distance between this wall and the busbar is not more than five times (preferably three times) the thickness of the busbar. Preferably, this distance does not exceed the thickness of the busbar.
• the busbar is attached to the said wall of the electrolyzer.
• the busbar is advantageously a metal flat of which one of the large sides is attached to the said wall, separated from the wall only by the thickness of the necessary electrical insulation.
• the metal flat may be attached to a portion of the surface of the said wall. It is preferable for the metal flat to be attached to substantially the entire surface of the said wall.
• the abovementioned electric line further comprises two additional busbars, that are placed respectively immediately next to two side walls of the electrolyzer.
• the expression "immediately next to” is identical to the definition of this expression given in the second embodiment discussed above. All other things remaining equal, the presence of the additional busbars reduces the strength of the electromagnetic field in the neighbourhood of the electrolyzer.
• the additional busbars may have any shape compatible with the construction of the electrolyzer. They may, for example, have a square, rectangular, polygonal, oval or circular profile. The additional busbars may also have the same profile or different profiles and they may have the same dimensions or different dimensions.
• the additional busbars have the same profile and the same dimensions. It is also preferable for the additional busbars to have a rectangular profile and that they be attached by their large side respectively to the two side walls of the electrolyzer.
• the respective dimensions of the additional busbars and those of the or each busbar that is placed below and/or above the electrolyzer are determined according to the way in which the electric current is to be distributed to all these busbars. In practice, it is recommended that the strength of the electric current in the busbar positioned below and/or above the electrolyzer differ by no more than 30% (preferably no more than 20%) from the strength of the electric current in each of the additional busbars.
• the strength of the electric current is substantially identical in the busbar that is positioned below and/or above the electrolyzer and in each of the additional busbars.
• the return electric current line of the electric circuit is positioned so as to generate an electromagnetic field that is substantially symmetrical about the median vertical plane of the electrolyzer.
• the aim (to generate an electromagnetic field that is substantially symmetrical about the median vertical plane of the electrolyzer) is achieved by adequately dimensioning and positioning the or each busbar.
• the choice of the optimal dimensions and the optimal position is determined by a person skilled in the art, particularly according to the shape and dimensions of the electrolyzer.
• the electric circuit according to the invention significantly reduces the electromagnetic field in the neighbourhood of the electrolyzer with bipolar electrodes.
• the invention further relates to the use of the electric circuit according to the invention, to reduce the electromagnetic field in the neighbourhood of the electrolyzer.
• the electric circuit according to the invention applies specially to electrolyzers for the continuous electrolysis of water or of aqueous solutions such as aqueous solutions of alkali metal halides, especially of sodium chloride.
• the electrolyzer comprises a line for the continuous intake of an aqueous electrolyte and a line for the continuous removal of an aqueous electrolyte.
• the invention applies in particular to electrolyzers for the production of sodium chlorate by the electrolysis of aqueous solutions of sodium chloride.
• the invention applies especially to electrolyzers for the production of chlorine and of aqueous sodium hydroxide solutions, by the electrolysis of aqueous solutions of sodium chloride, these electrolyzers comprising membranes that are selectively permeable to cations, and which are inserted between the bipolar electrodes.
• the electric circuit according to the invention applies to any electrolysis installation incorporating at least one electrolyzer with vertical bipolar electrodes.
• the invention further relates to an electrolysis installation comprising at least one electrolyzer with bipolar electrodes, connected to an electric circuit according to the invention.
• the installation according to the invention may comprise a single electrolyzer or a plurality of electrolyzers connected in electrical series.
• the invention relates in particular to the use of this installation for the production of chlorine and of aqueous sodium hydroxide solutions.
• Figure 1 shows an overall plan view of an electrolysis installation prior to the invention.
• Figure 2 shows a schematic longitudinal elevation view of a particular embodiment of the electrolysis installation according to the invention.
• Figure 3 shows a vertical cross section on the plane ni-LU of Figure 2.
• FIG 4 is a view similar to that of Figure 3, of another embodiment of the installation according to the invention.
• Figure 5 is a preferred variant of the installation in Figure 4.
• the electrolysis installation shown in Figure 1 is prior to the invention and does not conform to it. It comprises three electrolyzers 1, 2 and 3 designed for the production of chlorine, hydrogen and sodium hydroxide by the electrolysis of an aqueous solution of sodium chloride.
• the electrolyzers 1, 2 and 3 are of the vertical bipolar electrode type. They are formed by the juxtaposition of vertical rectangular frames 4, each containing a vertical bipolar electrode (not shown). The frames 4 are juxtaposed as in a filter press.
• Membranes that are selectively permeable to cations are inserted between the frames 4 to form alternating anode and cathode chambers.
• the anode chambers of the electrolyzers 1, 2 and 3 communicate with a line (not shown) for the continuous intake of an aqueous solution of sodium chloride. They also communicate with a manifold (not shown) for the continuous removal of chlorine.
• the cathode chambers of the electrolyzers 1, 2 and 3 communicate with two manifolds (not shown) that serve respectively for the continuous extraction of hydrogen, on the one hand, and of an aqueous sodium hydroxide solutions, on the other.
• the electrolyzers 1 , 2 and 3 are coupled in electrical series with a rectifier 5 of an AC power source, via an electric circuit comprising, on the one hand, busbars 6 inserted between the electrolyzers 1, 2 and 3 and, on the other, a return electric current line 7, placed outside the electrolyzers 1, 2 and 3.
• the electric circuit further comprises a bipolar switch 8.
• the return electric current line 7 consists of a long busbar running along a longitudinal side wall of the electrolyzers 1, 2 and 3.
• each of the three electrolyzers 1, 2, and 3 may, for example, comprise 30 to 40 elementary electrolysis cells and the electric power supply comprises, for example, a 520 V DC rectifier, capable of delivering a current of between 8 and 20 kA. Depending on the surface area of the electrodes, this may result in an anodic current density of 2.5 to 6 kA/m 2 of anode area.
• the bipolar switch When the bipolar switch is closed, rectified electric current flows successively in the electrolyzers 1, 2, and 3, through the bipolar electrodes and in the return line 7. This electric current generates an electromagnetic field in the environment of the installation.
• the return electric current line 7 comprises two busbars 9 and 10 that are placed below the bottom wall 11 of the electrolyzer 3.
• the busbars 9 and 10 are prismatic bars of a metal that is a good electrical conductor (preferably copper or aluminium). These busbars are placed symmetrically on each side of the median vertical plane X-X of the electrolyzer.
• the busbars 9 and 10 are further placed in the neighbourhood of the bottom wall 11 of the electrolyzer 3,
• the layout of the busbars 9 and 10 in the way shown in Figure 3 has the effect of reducing the strength of the electromagnetic field on the walkways 12 running along the side walls 13 of the electrolyzer 3 and which are intended for the electrolyzer maintenance personnel. All other things remaining equal, it has been found that the strength of the electromagnetic field on the walkways 12 is reduced more if the busbars 9 and 10 are closer to the mid-plane X-X and to the bottom wall 11. It has also been observed that the strength of the electromagnetic field on the walkways 12 is reduced by decreasing the ratio of the thickness to the width of the busbars 9 and 10. It is accordingly preferable to use flats or horizontal strips for the busbars 9 and 10.
• the return electric current line 7 comprises a metal flat or strip 14 that is attached to the bottom wall 11 of the electrolyzer and that substantially covers this entire wall.
• the electric current line 7 comprises a metal flat 14 that is applied against the bottom wall 11 of the electrolyzer 3 and two additional busbars 15 and 16 positioned respectively along the two side walls 13 of the electrolyzer 3.
• the two additional busbars 15 and 16 are advantageously metal flats or strips that are attached to the side walls 13.

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• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Electrochemistry (AREA)
• Materials Engineering (AREA)
• Metallurgy (AREA)
• Organic Chemistry (AREA)
• Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
• Water Treatment By Electricity Or Magnetism (AREA)
• Electrolytic Production Of Metals (AREA)

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• 2004
  • 2004-06-10 FR FR0406278A patent/FR2871479B1/fr not_active Expired - Fee Related
• 2005
  • 2005-06-08 CA CA002568833A patent/CA2568833A1/en not_active Abandoned
  • 2005-06-08 WO PCT/EP2005/052653 patent/WO2005121410A2/en active Application Filing
  • 2005-06-08 CN CNA2005800188151A patent/CN101048534A/zh active Pending
  • 2005-06-08 US US11/628,988 patent/US20070205110A1/en not_active Abandoned
  • 2005-06-08 JP JP2007526429A patent/JP2008501864A/ja active Pending
  • 2005-06-08 BR BRPI0511955-3A patent/BRPI0511955A/pt not_active IP Right Cessation
  • 2005-06-08 EP EP05752677A patent/EP1769104A2/en not_active Withdrawn
  • 2005-06-08 EA EA200700005A patent/EA011603B1/ru not_active IP Right Cessation
  • 2005-06-13 AR ARP050102384A patent/AR052970A1/es not_active Application Discontinuation

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