EP1753889B1 - Push belt and manufacturing method therefor - Google Patents
Push belt and manufacturing method therefor Download PDFInfo
- Publication number
- EP1753889B1 EP1753889B1 EP04748593.3A EP04748593A EP1753889B1 EP 1753889 B1 EP1753889 B1 EP 1753889B1 EP 04748593 A EP04748593 A EP 04748593A EP 1753889 B1 EP1753889 B1 EP 1753889B1
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- EP
- European Patent Office
- Prior art keywords
- ring
- rings
- hardening
- mass
- maraging steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 238000000034 method Methods 0.000 claims description 58
- 239000000463 material Substances 0.000 claims description 28
- 229910001240 Maraging steel Inorganic materials 0.000 claims description 27
- 230000032683 aging Effects 0.000 claims description 20
- 238000005121 nitriding Methods 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 9
- 239000010936 titanium Substances 0.000 claims description 9
- 229910052750 molybdenum Inorganic materials 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- 229910000069 nitrogen hydride Inorganic materials 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims 1
- 238000003483 aging Methods 0.000 description 23
- 239000002344 surface layer Substances 0.000 description 17
- 239000011162 core material Substances 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- 238000004881 precipitation hardening Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000005452 bending Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004320 controlled atmosphere Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910000734 martensite Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/40—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rings; for bearing races
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/10—Ferrous alloys, e.g. steel alloys containing cobalt
- C22C38/105—Ferrous alloys, e.g. steel alloys containing cobalt containing Co and Ni
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
Definitions
- the present invention relates to a manufacturing method for push belts.
- the push belt is mainly used as the means for power transmission between two adjustable pulleys of the well-known continuously variable transmission applied in motor vehicles.
- Such push belts which are generally composed of transverse metal elements that are slidably incorporated along one or more laminated set of radially nested metal rings or hoops, are generally known.
- the rings of such belts are produced from maraging steel, which kind of steel combines a/o the characteristic of great tensile strength and good resistance against bending and/or tensile stress fatigue with a relatively favourable possibility to process the material towards the desired shape and characteristics.
- These shape and characteristics should not vary along the circumference of the rings in the end product, i.e. should for example not show any weaker spot at a welding seam where the ends of a strip of base material are welded together to form the endless ring shape.
- These characteristics comprise a fair hardness of the core material for realising the properties of good tensile, yield and bending strength combined with a high resistance against metal fatigue and a wear resistant outer surface layer, which is provided with a maximum thickness such that bending of the ring is not hampered by cracking and such that the core material of the ring retains sufficient strength and elasticity.
- Resistance against fatigue is a significant feature of the rings because of the numerous number of load and bending cycles the belt is subjected to during its service lifetime.
- the manufacturing method for producing such belts, at least for such rings thereof, as applied by Applicant during several decades by now, is disclosed in general terms by the European patent application EP-A-1 055 738 .
- the metal rings are aged in a separate and well known precipitation hardening process by heat treatment in the presence of a controlled atmosphere predominantly composed of nitrogen (N2), during which ageing process intermetallic precipitates are formed throughout the ring material, and, subsequently, in a separate and well known gas -soft- nitriding process, a narrow surface layer is additionally hardened in this so-called case hardening process by heat treatment in the presence of a controlled atmosphere predominantly composed of ammonia (NH3) and nitrogen (N2), during which nitriding process non-metallic particles, i.e. nitrides, are formed predominantly in a superficial or i.e. thin surface layer of the ring material.
- NH3 ammonia
- N2 nitrogen
- the thickness or depth dimension of the case hardened surface layer in the above handbook example largely corresponds to the entire thickness of the metal rings involved in the present type belts. It has been the experience of Applicant that the known combined hardening process is quite difficult if not virtually impossible to apply, at least with the Titanium (Ti) containing alloys of maraging steel that are used up to now for the belt rings.
- Ti Titanium
- the goal of the invention is to provide other means, i.e. outside said known solutions, enabling the production of maraging steel rings for push belts by said single and combined hardening process, while resulting in the desired, i.e. required material properties for the surface layer and core material of said rings.
- JP01142021 discloses a seamless metallic belt excellent in workability, material strength, fatigue strength, and wear resistance by forming a metallic belt from a seamless steel pipe made of Ni-Co-Mo steel having a composition consisting of, by weight, ⁇ 0.01% C, ⁇ 0.05% Si, ⁇ 0.05% Mn, ⁇ 0.01% P, ⁇ 0.01% S, 16-19% Ni, 8-15% Co, 3-6% Mo, ⁇ 0.01% Ti, ⁇ 0.15%Al, ⁇ 0.003% N, ⁇ 0.0015% O, and the balance Fe.
- the material should be of a type showing the feature of relatively rapid ageing, such that within the short time required for nitriding process part for forming the hardened surface layer of desired thickness (case hardening) also a sufficient precipitation or age hardening of the core material would be realised.
- Figure 1 illustrates the relevant part of the known process as practised since the early years of metal push belt production. It comprises a first oven 1 for ageing or precipitation hardening of a ring 10 for the belt, which process predominantly determines the hardness of the ring core material, and a second oven 2 for surface layer or case hardening of the ring 10, which process predominantly determines the hardness of the ring surface layer material.
- Ageing mainly adds to the tensile and yield strength of the ring 10, while a hardened surface layer is required as a means of protection against wear of the rings 10, due to for instance mutual friction between the rings and friction with a contacting surface of transverse elements of the belt.
- the known rings 10 are made of Titanium (Ti) containing maraging steel, which steel is further mainly composed of Nickel (Ni), Molybdenum (Mo), Cobalt (Co) and balance Iron (Fe).
- This type of maraging steel has the unique combination of features of high tensile and yield strength, high resistance against metal fatigue and also has other properties, such as good weldability, that make it suited for the production process used in push belt production.
- a ring 10 For ageing of the ring material, it is subjected to a heat treatment in a controlled atmosphere predominantly composed of nitrogen (N2), which treatment is performed in the first oven 1. Subsequently, a ring 10 is heat treated for case hardening, which is performed in the second oven 2, in a controlled nitrogen (N2) and -gaseous-ammonia (NH3) environment, which treatment is known as the gas soft nitriding process.
- N2 controlled nitrogen
- NH3 environment which treatment is known as the gas soft nitriding process.
- the latter heat treatment is performed to form a surface layer of typically 25-35 microns of extreme hardness, due to the formation of a nitrided surface layer in the ring material. This surface layer thickness compares to a total ring thickness in the range between 150 and 200 microns, typically about equal to 185 microns. In-between these two heat treatments the rings 10 are transported between the ovens 1, 2 and, as a consequence, cool down.
- Figure 2 indicates that both the above-mentioned hardening processes are performed during a certain period of time t, whereby the processing time for the ageing process is indicated by 'H' and for the nitriding process by 'N'.
- a typical value for H may be 60 minutes at a processing temperature T between about 450 to 500 °C.
- the nitriding process may, typically, be performed for a somewhat shorter period and lasts between 45 to 60 minutes at a processing temperature T similar to that of the age hardening process.
- the resulting hardness of the ring core material typically is around 600 Hv (Vickers hardness), while the surface hardness of the rings 10 is typically around 900 Hv.
- Figure 3 illustrates a recent prior art improvement disclosed by EP-A-1 055 738 of the above-mentioned separate hardening processes.
- the rings 10 are transferred from the first oven 1 to the second oven 2 through an intermediate space 3 by sequentially opening and closing intermediate doors 4 and 5 of such oven system 1-5 and by simultaneously moving the rings 10 between the subsequent (oven) spaces 1, 3 and 2. In-between cooling down and subsequent re-heating of rings 10 may in this way be omitted.
- Figure 4 illustrates the singleness of the improved prior art process and shows a timesaving effect thereof in that at least a part of the cooling down and re-heating time between the ageing and nitriding processes is saved. However, because of the ultimately small thickness of the rings 10 and the constant operation of the ovens 1, 2, such effect is minimal.
- the solution is found in selected a new ring material, i.e. a maraging steel composition that is characterised by the Titanium element being largely, if not almost entirely omitted from the steel, i.e. a Titanium content that amounts to less than 0.1 mass-%, while at the same time the Cobalt content of the maraging steel is increased to 16.5 mass-%, preferably to within a range of 85% to 100% of the Nickel content.
- the rings 10 could be aged and nitrided simultaneously in a single one oven 6 in a combined hardening process with while obtaining the required mechanical and other material properties as discussed in the above.
- a preferred material in this respect further satisfies the requirement that the product of mass-% Cobalt and mass-% Molybdenum is equal to or lager than 50, but preferably smaller than 200.
- the maraging steel M2 used here as an example is according to the invention consisting of less than 0.1 mass-% Ti, 18 mass-% Ni, 5 mass-% Mo, 16.5 mass-% Co and balance Fe, which compares to the conventional maraging steel M1 that is provided with about 0.45 mass-% Ti, 18 mass-% Ni, 5 mass-% Mo, 9 mass-% Co and balance Fe.
- the strengthening effect of Cobalt in association with Molybdenum is used in an advantageous manner. It is considered that Cobalt will lower the solubility of Molybdenum in the martensite matrix of the steel, enhancing precipitation of Mo-rich intermetallic phases during ageing, and enhancing, i.e.
- the required age hardening processing time H of the maraging steel M2 With this specific example of the composition of the maraging steel M2, a case hardened (nitrided) surface layer of the rings 10 of 28 microns was realised in the combined hardening, i.e. ageing and nitriding processes, at a total ring thickness of 185 microns. Moreover the additional advantage of an increased (i.e. with respect to the conventional maraging steel M1) ring core hardness of about 640 Hv was surprisingly realised with this maraging steel composition M2, while otherwise completely satisfying the required mechanical material properties.
- the maraging steel composition may be fine-tuned within the ranges and requirements defined by the invention to reach the desired nitrided surface layer thickness in relation to the total ring thickness.
- the graph shows that even at 480 °C the maximum (core) hardness level Hv of rings 10 of conventional maraging steel M1, i.e. as a result of age or precipitation hardening is reached only after a significantly long processing time t of up to 120 min. or 2 hours, whereas the newly selected maraging steel M2 reaches the same hardness level Hv must faster even at the lower processing temperature of 440°C. Moreover, the maximum hardness level Hv of the newly selected maraging steel M2 is considerably higher than that of M1, which is considered an advantageous feature for the belt rings 10.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Heat Treatment Of Articles (AREA)
Description
- The present invention relates to a manufacturing method for push belts. The push belt is mainly used as the means for power transmission between two adjustable pulleys of the well-known continuously variable transmission applied in motor vehicles.
- Such push belts, which are generally composed of transverse metal elements that are slidably incorporated along one or more laminated set of radially nested metal rings or hoops, are generally known. The rings of such belts are produced from maraging steel, which kind of steel combines a/o the characteristic of great tensile strength and good resistance against bending and/or tensile stress fatigue with a relatively favourable possibility to process the material towards the desired shape and characteristics. These shape and characteristics should not vary along the circumference of the rings in the end product, i.e. should for example not show any weaker spot at a welding seam where the ends of a strip of base material are welded together to form the endless ring shape.
- These characteristics comprise a fair hardness of the core material for realising the properties of good tensile, yield and bending strength combined with a high resistance against metal fatigue and a wear resistant outer surface layer, which is provided with a maximum thickness such that bending of the ring is not hampered by cracking and such that the core material of the ring retains sufficient strength and elasticity. Resistance against fatigue is a significant feature of the rings because of the numerous number of load and bending cycles the belt is subjected to during its service lifetime.
- The manufacturing method for producing such belts, at least for such rings thereof, as applied by Applicant during several decades by now, is disclosed in general terms by the European patent application
EP-A-1 055 738 .
As a part of the known preparatory process, the metal rings are aged in a separate and well known precipitation hardening process by heat treatment in the presence of a controlled atmosphere predominantly composed of nitrogen (N2), during which ageing process intermetallic precipitates are formed throughout the ring material, and, subsequently, in a separate and well known gas -soft- nitriding process, a narrow surface layer is additionally hardened in this so-called case hardening process by heat treatment in the presence of a controlled atmosphere predominantly composed of ammonia (NH3) and nitrogen (N2), during which nitriding process non-metallic particles, i.e. nitrides, are formed predominantly in a superficial or i.e. thin surface layer of the ring material. - It may be considered a general aim, and in the field of ring manufacture for push belts it has been a long standing desire, to combine the fore-mentioned separate preparatory hardening processes into one. Such combined ageing and nitriding is as such well known for the base material, i.e. maraging steel, of which the belt rings are made as is e.g. illustrated by the Metals Handbook, Vol. 1, 1978 of the American Society for Metals (ASM). In this respect a particular example is given (chapter "Maraging Steels", page 448) in which it is provided that considerable surface hardening of up to 65 to 70 HRC can be achieved at depths of up to 0.15 mm after nitriding for 48 hours at 455 °C. Where such typical example is suitable for many applications requiring extensive surface hardening, the example also demonstrates a problem encountered within the field of continuously variable transmission, i.e. the manufacture of the rings of the metal belts therefor.
- The thickness or depth dimension of the case hardened surface layer in the above handbook example largely corresponds to the entire thickness of the metal rings involved in the present type belts. It has been the experience of Applicant that the known combined hardening process is quite difficult if not virtually impossible to apply, at least with the Titanium (Ti) containing alloys of maraging steel that are used up to now for the belt rings. It has been found that in dependency on the duration of such combined hardening process either the nitriding process part thereof is too severe, resulting in the hardened surface layer of the rings becoming too thick so that the resulting rings are too brittle, or that the ageing process part thereof is too mild, resulting in the core hardness of the rings not reaching the required level, so that the resulting rings have insufficient yield and tensile strength.
- This finding is also confirmed by the above mentioned
EP-A-1 055 738 application, where the invention sought to improve the hardening process of the rings, by indicating that such combined ageing and nitriding process is problematic in that it would be "difficult to adjust the atmosphere in order to achieve an appropriate ageing hardness and a nitride layer of suitable depth". - Yet it is still an aim of the current invention to arrive at a single hardening process for rings for the push belt in which ageing and nitriding are performed simultaneously, thereby considerably reducing costs of and time required for the production of the rings. Therefore, the goal of the invention is to provide other means, i.e. outside said known solutions, enabling the production of maraging steel rings for push belts by said single and combined hardening process, while resulting in the desired, i.e. required material properties for the surface layer and core material of said rings.
- According to the invention, such can be done by the feature provided in the characterising portion of
claim 1. As a feature underlying the present invention it was conceived that, where for so long a time it was sought to treat maraging steel in a single heating chamber or oven both for ageing and nitriding and where it could not be found satisfactorily adapt the process settings such as temperature, duration and atmospheric composition, such that material properties could be retrieved for the ring that were suitable for push belt application in a continuously variable transmission, it might be an option to turn around the direction wherein the solution to the above-described problem is sought, i.e. to adapt the material rather than or in addition to adapting the process settings.
JP01142021 - For successfully implementing the above idea, it was further conceived that the material should be of a type showing the feature of relatively rapid ageing, such that within the short time required for nitriding process part for forming the hardened surface layer of desired thickness (case hardening) also a sufficient precipitation or age hardening of the core material would be realised.
- The above basic principle according to the invention will now be elucidated by way of example, along a drawing in which:
-
Figure 1 figuratively represents the basic prior art ring age and case hardening processes; -
Figure 2 graphically represents the temperature T (Y-axis) and time t (X-axis) involved in the prior art processes according tofigure 1 ; -
Figure 3 represents another prior art solution, avoiding a cooling down of the ring material in-between the age and case hardening processes. -
Figure 4 graphically represents the temperature T (Y-axis) and time t (X-axis) involved in the prior art processes according tofigure 2 ; -
Figure 5 represents the solution according to the invention, in which the process parts of the known overall hardening process are combined into one, whereby the process duration and effort are significantly reduced; -
Figure 6 graphically represents the temperature T (Y-axis) and time t (X-axis) involved in the proposed combined hardening process according tofigure 5 ; and in which; -
Figure 7 represents the feature of the material core hardness Hv (Y-axis) of two ring material compositions M1 and M2 versus the duration of the ageing or precipitation hardening process. -
Figure 1 illustrates the relevant part of the known process as practised since the early years of metal push belt production. It comprises afirst oven 1 for ageing or precipitation hardening of aring 10 for the belt, which process predominantly determines the hardness of the ring core material, and asecond oven 2 for surface layer or case hardening of thering 10, which process predominantly determines the hardness of the ring surface layer material. Ageing mainly adds to the tensile and yield strength of thering 10, while a hardened surface layer is required as a means of protection against wear of therings 10, due to for instance mutual friction between the rings and friction with a contacting surface of transverse elements of the belt. In the so-called push belt such transverse elements are incorporated mounted on and freely slidably along one or two sets of mutuallynested rings 10. The knownrings 10 are made of Titanium (Ti) containing maraging steel, which steel is further mainly composed of Nickel (Ni), Molybdenum (Mo), Cobalt (Co) and balance Iron (Fe). This type of maraging steel has the unique combination of features of high tensile and yield strength, high resistance against metal fatigue and also has other properties, such as good weldability, that make it suited for the production process used in push belt production. - For ageing of the ring material, it is subjected to a heat treatment in a controlled atmosphere predominantly composed of nitrogen (N2), which treatment is performed in the
first oven 1. Subsequently, aring 10 is heat treated for case hardening, which is performed in thesecond oven 2, in a controlled nitrogen (N2) and -gaseous-ammonia (NH3) environment, which treatment is known as the gas soft nitriding process. The latter heat treatment is performed to form a surface layer of typically 25-35 microns of extreme hardness, due to the formation of a nitrided surface layer in the ring material. This surface layer thickness compares to a total ring thickness in the range between 150 and 200 microns, typically about equal to 185 microns. In-between these two heat treatments therings 10 are transported between theovens -
Figure 2 indicates that both the above-mentioned hardening processes are performed during a certain period of time t, whereby the processing time for the ageing process is indicated by 'H' and for the nitriding process by 'N'. A typical value for H may be 60 minutes at a processing temperature T between about 450 to 500 °C. The nitriding process may, typically, be performed for a somewhat shorter period and lasts between 45 to 60 minutes at a processing temperature T similar to that of the age hardening process. The resulting hardness of the ring core material typically is around 600 Hv (Vickers hardness), while the surface hardness of therings 10 is typically around 900 Hv. -
Figure 3 illustrates a recent prior art improvement disclosed byEP-A-1 055 738 of the above-mentioned separate hardening processes. In this improvement and immediately after the first heat treatment, therings 10 are transferred from thefirst oven 1 to thesecond oven 2 through anintermediate space 3 by sequentially opening and closingintermediate doors rings 10 between the subsequent (oven)spaces rings 10 may in this way be omitted. -
Figure 4 illustrates the singleness of the improved prior art process and shows a timesaving effect thereof in that at least a part of the cooling down and re-heating time between the ageing and nitriding processes is saved. However, because of the ultimately small thickness of therings 10 and the constant operation of theovens - According to a well-known principle, indicated by the above-mentioned ASM Metals Handbook of 1978, a significant gain in required total process time of the hardening processes may be achieved by the simultaneous core and case hardening, i.e. within a
single oven 6. This principle and effect are indicated byfigures 5, 6 and 7 . - The principle illustrated by
figures 5 and 6 has long been striven for, however has never been reached in the field of ring manufacture for push belt. The focus for realising this principle has been on fine-tuning process time, temperature and atmosphere for realising the required mechanical material properties that can be obtained in the prior art separated hardening processes. However, this has never been realised with satisfying results: either the nitrided ring surface layer proved to be too thick and brittle, or the ring core hardness was insufficient. - In the solution according to the invention, surprisingly, a novel and entirely different approach has been taken in that not the settings of the hardening processes have been studied per se, but rather the ring material composition that is to be treated thereby. The idea underlying the invention is to provide a maraging steel composition that allows a considerable reduction of the processing time H for the ageing process, such that the required ring core hardness can be achieved within the processing time N required for the nitriding process, preferably at otherwise ordinary, i.e. known process settings. At doing so, it was conceived that rather than striving for the general aim of lowering the cost price of the maraging steel, a slight cost price increase could be accepted when the benefits of the combined hardening process would at the same time be realised.
- According to the invention the solution is found in selected a new ring material, i.e. a maraging steel composition that is characterised by the Titanium element being largely, if not almost entirely omitted from the steel, i.e. a Titanium content that amounts to less than 0.1 mass-%, while at the same time the Cobalt content of the maraging steel is increased to 16.5 mass-%, preferably to within a range of 85% to 100% of the Nickel content. With such a new type of maraging steel, it was realised in accordance with the aim underlying the invention that the
rings 10 could be aged and nitrided simultaneously in a single oneoven 6 in a combined hardening process with while obtaining the required mechanical and other material properties as discussed in the above. A preferred material in this respect further satisfies the requirement that the product of mass-% Cobalt and mass-% Molybdenum is equal to or lager than 50, but preferably smaller than 200. - The maraging steel M2 used here as an example, is according to the invention consisting of less than 0.1 mass-% Ti, 18 mass-% Ni, 5 mass-% Mo, 16.5 mass-% Co and balance Fe, which compares to the conventional maraging steel M1 that is provided with about 0.45 mass-% Ti, 18 mass-% Ni, 5 mass-% Mo, 9 mass-% Co and balance Fe. With such a new ring material M2, the strengthening effect of Cobalt in association with Molybdenum is used in an advantageous manner. It is considered that Cobalt will lower the solubility of Molybdenum in the martensite matrix of the steel, enhancing precipitation of Mo-rich intermetallic phases during ageing, and enhancing, i.e. shortening, the required age hardening processing time H of the maraging steel M2. With this specific example of the composition of the maraging steel M2, a case hardened (nitrided) surface layer of the
rings 10 of 28 microns was realised in the combined hardening, i.e. ageing and nitriding processes, at a total ring thickness of 185 microns. Moreover the additional advantage of an increased (i.e. with respect to the conventional maraging steel M1) ring core hardness of about 640 Hv was surprisingly realised with this maraging steel composition M2, while otherwise completely satisfying the required mechanical material properties. - Of course, the maraging steel composition may be fine-tuned within the ranges and requirements defined by the invention to reach the desired nitrided surface layer thickness in relation to the total ring thickness.
- The feature enabling the combined hardening process for belt rings 10 is illustrated along the graph of
figure 7 . Infigure 7 , the development over time t of the material hardness Hv due to ageing (precipitation hardening) has been indicated for both the conventional maraging steel M1 for belt rings 10 and the new maraging steel M2 at certain processing temperatures T. - The graph, in first place, shows that even at 480 °C the maximum (core) hardness level Hv of
rings 10 of conventional maraging steel M1, i.e. as a result of age or precipitation hardening is reached only after a significantly long processing time t of up to 120 min. or 2 hours, whereas the newly selected maraging steel M2 reaches the same hardness level Hv must faster even at the lower processing temperature of 440°C. Moreover, the maximum hardness level Hv of the newly selected maraging steel M2 is considerably higher than that of M1, which is considered an advantageous feature for the belt rings 10. - The processing time t range between 45 and 65 minutes and temperature T range between 440°C and 480°C that, according to the graph of
figure 7 , are at least allowable for realising the preferred material core hardness Hv of about 640 Hv, where indeed found to also allow the known nitriding process to be simultaneously performed in a combined hardening process, while obtaining the desired ring surface layer of required thickness and hardness. Such would clearly not be the case for the conventional maraging steel M1 that, according to the graph offigure 7 , requires the ageing process to be performed for 2 hours at 480 °C (or for an even longer period at a lowered temperature, or at an even higher temperature for a shortened period), which latter process settings do not conform to those required by the desired nitriding process. - The invention will no be defined further along a set of claims and, apart from the preceding description, also relates to all details therein, and to all details and aspects in the discussed drawing which are directly and unambiguously derivable there from, at least by a man skilled in the art.
Claims (1)
- Method of manufacturing an endless ring of a push belt for continuously variable transmissions, in which the material of the ring is a maraging steel and in which said ring is subjected to a first heat treatment for realising a core hardening of the ring material through ageing and to a second heat treatment under the presence of ammonia gas (NH3) for realising a case hardening of the ring material through nitriding, characterised in that the first and second heat treatments are performed in a combined hardening process, simultaneously and in a single heating chamber for 45 to 65 minutes at 440°C to 480 °C and in that the maraging steel used has a composition consisting of less than 0.1 mass-% Titanium, 18 mass-% Nickel, 5 mass-% Molybdenum, 16.5 mass-% Cobalt and balance Iron.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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PCT/NL2004/000357 WO2005111253A1 (en) | 2004-05-19 | 2004-05-19 | Push belt and manufacturing method therefor |
Publications (2)
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EP1753889A1 EP1753889A1 (en) | 2007-02-21 |
EP1753889B1 true EP1753889B1 (en) | 2017-04-12 |
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EP04748593.3A Expired - Lifetime EP1753889B1 (en) | 2004-05-19 | 2004-05-19 | Push belt and manufacturing method therefor |
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EP (1) | EP1753889B1 (en) |
WO (1) | WO2005111253A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL1043487B1 (en) | 2019-11-28 | 2021-08-31 | Bosch Gmbh Robert | Ring component of a drive belt for a continuously variable transmission |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101842502B (en) * | 2007-10-31 | 2012-10-03 | 罗伯特·博世有限公司 | Drive belt ring component and manufacturing method therefor |
CN102016348B (en) * | 2008-04-28 | 2016-01-20 | 罗伯特·博世有限公司 | Drive belt ring parts and manufacture method and martensite ag(e)ing steel substrate thereof |
WO2012083974A1 (en) | 2010-12-20 | 2012-06-28 | Robert Bosch G.M.B.H. | Heat treatment process for a manufacturing process of a drive belt metal ring component |
WO2012083975A1 (en) | 2010-12-20 | 2012-06-28 | Robert Bosch G.M.B.H. | Heat treatment process for a manufacturing process of a drive belt metal ring component |
JP6008976B2 (en) | 2011-11-30 | 2016-10-19 | ローベルト ボツシユ ゲゼルシヤフト ミツト ベシユレンクテル ハフツングRobert Bosch Gmbh | Heat treatment process in manufacturing method of drive belt metal ring element |
NL1040571C2 (en) * | 2013-12-24 | 2015-06-26 | Bosch Gmbh Robert | Metal ring component for a drive belt for a continuously variable transmission. |
NL1041102B1 (en) | 2014-12-17 | 2016-10-11 | Bosch Gmbh Robert | Flexible steel ring for a drive belt for a continuously variable transmission and method for producing such. |
NL1041468B1 (en) * | 2015-09-08 | 2017-03-22 | Bosch Gmbh Robert | Metal ring component of a drive belt for a continuously variable transmisson. |
Family Cites Families (3)
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JPH01142021A (en) * | 1987-11-27 | 1989-06-02 | Sumitomo Metal Ind Ltd | Manufacture of seamless metallic belt |
JPH01142052A (en) * | 1987-11-27 | 1989-06-02 | Sumitomo Metal Ind Ltd | Seamless metallic belt and its production |
EP1055738B1 (en) * | 1999-05-28 | 2009-09-30 | Honda Giken Kogyo Kabushiki Kaisha | Method of manufacturing laminated ring and heat treatment apparatus for use in such method |
-
2004
- 2004-05-19 EP EP04748593.3A patent/EP1753889B1/en not_active Expired - Lifetime
- 2004-05-19 WO PCT/NL2004/000357 patent/WO2005111253A1/en active Application Filing
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NL1043487B1 (en) | 2019-11-28 | 2021-08-31 | Bosch Gmbh Robert | Ring component of a drive belt for a continuously variable transmission |
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EP1753889A1 (en) | 2007-02-21 |
WO2005111253A1 (en) | 2005-11-24 |
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