EP1741775B1 - Fabric care composition - Google Patents

Fabric care composition Download PDF

Info

Publication number
EP1741775B1
EP1741775B1 EP06253469A EP06253469A EP1741775B1 EP 1741775 B1 EP1741775 B1 EP 1741775B1 EP 06253469 A EP06253469 A EP 06253469A EP 06253469 A EP06253469 A EP 06253469A EP 1741775 B1 EP1741775 B1 EP 1741775B1
Authority
EP
European Patent Office
Prior art keywords
particle
vinyl
monomers
benefit agent
methacrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP06253469A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1741775A1 (en
Inventor
Paul Unilever R&D Port Sunlight Ferguson
Robert Alan Unilever R&D Port Sunlight Hunter
David R. A. Unilever R&D Port Sunlight Mealing
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Publication of EP1741775A1 publication Critical patent/EP1741775A1/en
Application granted granted Critical
Publication of EP1741775B1 publication Critical patent/EP1741775B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/667Neutral esters, e.g. sorbitan esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039Coated compositions or coated components in the compositions, (micro)capsules
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/226Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers

Definitions

  • the polymer particles of the invention can comprise a wide range of monomeric units.
  • monomer units as used herein is meant the monomeric units of the polymer chain, thus references to "a polymer particle comprising insoluble monomer units” as used herein means that the polymer particles is derived from insoluble monomers, and so forth.
  • suitable lubricants are amino functional silicone oils such as Rhodorsil Oil Extrasoft supplied by Rhodia Silicones.
  • Other silicones may be selected from those disclosed GB 1,549,180A , EP 459,821A2 and EP 459822A .
  • Other suitable lubricants include any of those known for use as dye bath lubricants in the textile industry.
  • the polysaccharide is present at levels of between 0.1% to 10% w/w by weight of the total amount of monomer in the core and the shell.
  • the level of non-ionic surfactant is from 0 wt% to 30 wt%, preferably from 1 wt% to 25 wt%, most preferably from 2 wt% to 15 wt%, by weight of the total composition.
  • Quaternary ammonium compounds having two long-chain aliphatic groups for example, distearyldimethyl ammonium chloride and di(hardened tallow alkyl) dimethyl ammonium chloride, are widely used in commercially available rinse conditioner compositions.
  • Other examples of these cationic compounds are to be found in " Surfactants Science Series" volume 34 ed. Richmond 1990 , volume 37 ed. Rubingh 1991 and volume 53 eds. Cross and Singer 1994, Marcel Dekker Inc. New York ".
  • Detergent compositions suitable for use in most automatic fabric washing machines generally contain anionic non-soap surfactant, or non-ionic surfactant, or combinations of the two in any suitable ratio, optionally together with soap.
  • Detergency enzymes are commonly employed in granular form in amounts of from about 0.1 to about 3.0 wt%. However, any suitable physical form of enzyme may be used.
  • the compositions of the invention may contain alkali metal, preferably sodium carbonate, in order to increase detergency and ease processing.
  • Sodium carbonate may suitably be present in amounts ranging from 1 to 60 wt%, preferably from 2 to 40 wt%. However, compositions containing little or no sodium carbonate are also within the scope of the invention.
  • Liquid detergent compositions can be prepared by admixing the essential and optional ingredients thereof in any desired order to provide compositions containing components in the requisite concentrations.
  • Liquid compositions according to the present invention can also be in compact form which means it will contain a lower level of water compared to a conventional liquid detergent.
  • the treatment will involve a washing or rinsing method such as treatment in the main wash or rinse cycle of a washing machine and involves contacting the substrate with an aqueous medium comprising the material of the invention.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Manufacturing Of Micro-Capsules (AREA)
  • Outer Garments And Coats (AREA)
EP06253469A 2005-07-06 2006-06-30 Fabric care composition Not-in-force EP1741775B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB0513803.7A GB0513803D0 (en) 2005-07-06 2005-07-06 Fabric care composition

Publications (2)

Publication Number Publication Date
EP1741775A1 EP1741775A1 (en) 2007-01-10
EP1741775B1 true EP1741775B1 (en) 2009-04-29

Family

ID=34856722

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06253469A Not-in-force EP1741775B1 (en) 2005-07-06 2006-06-30 Fabric care composition

Country Status (5)

Country Link
EP (1) EP1741775B1 (es)
AT (1) ATE430190T1 (es)
DE (1) DE602006006505D1 (es)
ES (1) ES2326686T3 (es)
GB (1) GB0513803D0 (es)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8426353B2 (en) 2008-06-16 2013-04-23 Firmenich Sa Process for preparing polyurea microcapsules
US8636918B2 (en) 2011-08-05 2014-01-28 Ecolab Usa Inc. Cleaning composition containing a polysaccharide hybrid polymer composition and methods of controlling hard water scale
US8674021B2 (en) 2006-07-21 2014-03-18 Akzo Nobel N.V. Sulfonated graft copolymers
US8679366B2 (en) 2011-08-05 2014-03-25 Ecolab Usa Inc. Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale
US8778867B2 (en) 2008-12-18 2014-07-15 Firmenich Sa Microcapsules and uses thereof
US8841246B2 (en) 2011-08-05 2014-09-23 Ecolab Usa Inc. Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage
US8853144B2 (en) 2011-08-05 2014-10-07 Ecolab Usa Inc. Cleaning composition containing a polysaccharide graft polymer composition and methods of improving drainage
US8945314B2 (en) 2012-07-30 2015-02-03 Ecolab Usa Inc. Biodegradable stability binding agent for a solid detergent
US9034384B2 (en) 2011-02-07 2015-05-19 Firmenich Sa Polyurea microcapsules
US9051406B2 (en) 2011-11-04 2015-06-09 Akzo Nobel Chemicals International B.V. Graft dendrite copolymers, and methods for producing the same
US9109068B2 (en) 2005-07-21 2015-08-18 Akzo Nobel N.V. Hybrid copolymer compositions
US9334464B2 (en) 2011-11-29 2016-05-10 Firmenich Sa Microcapsules and uses thereof
US9365805B2 (en) 2014-05-15 2016-06-14 Ecolab Usa Inc. Bio-based pot and pan pre-soak
US9499769B2 (en) 2011-06-28 2016-11-22 Firmenich Sa Process for preparing polyurea microcapsules
US9968096B2 (en) 2014-06-27 2018-05-15 Firmenich Sa Process for preparing antimicrobial microcapsules
US9988526B2 (en) 2011-11-04 2018-06-05 Akzo Nobel Chemicals International B.V. Hybrid dendrite copolymers, compositions thereof and methods for producing the same
US10260022B2 (en) 2015-02-06 2019-04-16 Firmenich Sa Microcapsules imparting intense vanilla odor note
US10526567B2 (en) 2015-01-23 2020-01-07 Firmenich Sa Process for the preparation of microcapsules free from melamine-formaldehyde
US10646416B2 (en) 2013-05-22 2020-05-12 Firmenich Sa Microcapsules containing a gas-releasing photolabile compound and uses thereof
US11072766B2 (en) 2011-12-22 2021-07-27 Firmenich Sa Process for preparing polyurea microcapsules

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0524665D0 (en) * 2005-12-02 2006-01-11 Unilever Plc Laundry composition
GB0710369D0 (en) * 2007-06-01 2007-07-11 Unilever Plc Improvements relating to perfume particles
GB0718532D0 (en) 2007-09-22 2007-10-31 Unilever Plc Improvements relating to fabric treatment compositions
WO2010012407A1 (en) * 2008-07-29 2010-02-04 Ashland Licensing And Intellectual Property Llc. Modified additives for suppressing dust formation
ES2412265T3 (es) * 2008-09-12 2013-07-10 Unilever N.V. Mejoras que se refieren a acondicionadores de material textil
GB0904700D0 (en) 2009-03-19 2009-04-29 Unilever Plc Improvements relating to benefit agent delivery
CN102939151B (zh) 2010-06-11 2015-05-20 弗门尼舍有限公司 聚脲微胶囊的制备方法
WO2013107586A2 (en) * 2012-01-17 2013-07-25 Unilever Plc Benefit delivery particle, process for preparing said particle, compositions comprising said particles and a method for treating substrates
CN105228587B (zh) 2013-05-22 2018-08-07 弗门尼舍有限公司 含有产生气体的对光不稳定的酮酸或酮酯的微胶囊及其用途
WO2015014603A2 (en) * 2013-07-30 2015-02-05 Unilever Plc Benefit delivery particle
US9849435B2 (en) 2013-12-19 2017-12-26 Firmenich Sa Maleic anhydride polymer-stabilized microcapsules
ES2653560T3 (es) 2013-12-19 2018-02-07 Firmenich Sa Microcápsulas híbridas
EP3099404B1 (en) 2014-01-27 2018-03-21 Firmenich SA Process for preparing aminoplast microcapsules
CN106999891B (zh) 2014-11-24 2020-05-19 弗门尼舍有限公司 含有气体发生性光不稳定聚合物的微胶囊及其用途
JP6934816B2 (ja) 2015-04-07 2021-09-15 フイルメニツヒ ソシエテ アノニムFirmenich Sa ポリウレアマイクロカプセルを製造するための方法
JP7254718B2 (ja) 2017-06-01 2023-04-10 フイルメニツヒ ソシエテ アノニム 水性マイクロエマルション
JP2021500351A (ja) 2017-10-19 2021-01-07 フイルメニツヒ ソシエテ アノニムFirmenich Sa ヒドロゲルビーズ

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0117768D0 (en) * 2001-07-20 2001-09-12 Unilever Plc Use of polymers in fabrics cleaning
CA2443446C (en) * 2001-08-02 2011-04-26 Unilever Plc Treatment for substrates
GB0229806D0 (en) * 2002-12-20 2003-01-29 Unilever Plc Fabric care composition
GB0412854D0 (en) * 2004-06-09 2004-07-14 Unilever Plc Fabric care composition

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9321873B2 (en) 2005-07-21 2016-04-26 Akzo Nobel N.V. Hybrid copolymer compositions for personal care applications
US9109068B2 (en) 2005-07-21 2015-08-18 Akzo Nobel N.V. Hybrid copolymer compositions
US8674021B2 (en) 2006-07-21 2014-03-18 Akzo Nobel N.V. Sulfonated graft copolymers
US8426353B2 (en) 2008-06-16 2013-04-23 Firmenich Sa Process for preparing polyurea microcapsules
US9498411B2 (en) 2008-12-18 2016-11-22 Firmenich Sa Microcapsules and uses thereof
US8778867B2 (en) 2008-12-18 2014-07-15 Firmenich Sa Microcapsules and uses thereof
US9034384B2 (en) 2011-02-07 2015-05-19 Firmenich Sa Polyurea microcapsules
US9499769B2 (en) 2011-06-28 2016-11-22 Firmenich Sa Process for preparing polyurea microcapsules
US8853144B2 (en) 2011-08-05 2014-10-07 Ecolab Usa Inc. Cleaning composition containing a polysaccharide graft polymer composition and methods of improving drainage
US8679366B2 (en) 2011-08-05 2014-03-25 Ecolab Usa Inc. Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale
US8636918B2 (en) 2011-08-05 2014-01-28 Ecolab Usa Inc. Cleaning composition containing a polysaccharide hybrid polymer composition and methods of controlling hard water scale
US9309489B2 (en) 2011-08-05 2016-04-12 Ecolab Usa Inc Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage
US8841246B2 (en) 2011-08-05 2014-09-23 Ecolab Usa Inc. Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage
US9051406B2 (en) 2011-11-04 2015-06-09 Akzo Nobel Chemicals International B.V. Graft dendrite copolymers, and methods for producing the same
US9988526B2 (en) 2011-11-04 2018-06-05 Akzo Nobel Chemicals International B.V. Hybrid dendrite copolymers, compositions thereof and methods for producing the same
US9334464B2 (en) 2011-11-29 2016-05-10 Firmenich Sa Microcapsules and uses thereof
US11072766B2 (en) 2011-12-22 2021-07-27 Firmenich Sa Process for preparing polyurea microcapsules
US8945314B2 (en) 2012-07-30 2015-02-03 Ecolab Usa Inc. Biodegradable stability binding agent for a solid detergent
US10646416B2 (en) 2013-05-22 2020-05-12 Firmenich Sa Microcapsules containing a gas-releasing photolabile compound and uses thereof
US9365805B2 (en) 2014-05-15 2016-06-14 Ecolab Usa Inc. Bio-based pot and pan pre-soak
US10053652B2 (en) 2014-05-15 2018-08-21 Ecolab Usa Inc. Bio-based pot and pan pre-soak
US9968096B2 (en) 2014-06-27 2018-05-15 Firmenich Sa Process for preparing antimicrobial microcapsules
US10526567B2 (en) 2015-01-23 2020-01-07 Firmenich Sa Process for the preparation of microcapsules free from melamine-formaldehyde
US10260022B2 (en) 2015-02-06 2019-04-16 Firmenich Sa Microcapsules imparting intense vanilla odor note

Also Published As

Publication number Publication date
ATE430190T1 (de) 2009-05-15
GB0513803D0 (en) 2005-08-10
DE602006006505D1 (de) 2009-06-10
EP1741775A1 (en) 2007-01-10
ES2326686T3 (es) 2009-10-16

Similar Documents

Publication Publication Date Title
EP1741775B1 (en) Fabric care composition
EP1954793B1 (en) Laundry composition
EP1954796B1 (en) Improvements relating to fabric treatment compositions
GB2432852A (en) Laundry composition including polymer particles containing perfume and a cationic deposition aid
GB2432851A (en) Laundry composition including polymer particles containing perfume and a non-ionic deposition aid
EP1753785B1 (en) Process for preparation of polysaccharide-grafted polymer particles
EP2155847B1 (en) Improvements relating to perfume particles
GB2432850A (en) Polymeric particle comprising perfume and benefit agent, in particular a laundry composition
GB2432844A (en) Laundry composition
US20050273942A1 (en) Fabric care composition
GB2432843A (en) Perfume carrying polymeric particle
EP1572767B1 (en) Fabric care composition
US7357987B2 (en) Fabric care composition comprising a polysaccharide-grafted polymer particle
EP1753786B1 (en) Fabric care composition
GB2428043A (en) Benefit agent delivery systems
WO2005121197A1 (en) Laundry composition
WO2006002749A1 (en) Granule and process for its manufacture

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR MK YU

17P Request for examination filed

Effective date: 20070629

AKX Designation fees paid

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

17Q First examination report despatched

Effective date: 20071023

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: UNILEVER PLC

Owner name: UNILEVER N.V.

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REF Corresponds to:

Ref document number: 602006006505

Country of ref document: DE

Date of ref document: 20090610

Kind code of ref document: P

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

NLV1 Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2326686

Country of ref document: ES

Kind code of ref document: T3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090829

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090729

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090829

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090630

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090729

26N No opposition filed

Effective date: 20100201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090730

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090630

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100630

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090630

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20091030

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090429

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20160621

Year of fee payment: 11

Ref country code: DE

Payment date: 20160621

Year of fee payment: 11

Ref country code: ES

Payment date: 20160614

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20160627

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20160627

Year of fee payment: 11

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602006006505

Country of ref document: DE

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20170630

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20180228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180103

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170630

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170630

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20181107

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170701