EP1741775B1 - Composition d'entretien pour tissus - Google Patents
Composition d'entretien pour tissus Download PDFInfo
- Publication number
- EP1741775B1 EP1741775B1 EP06253469A EP06253469A EP1741775B1 EP 1741775 B1 EP1741775 B1 EP 1741775B1 EP 06253469 A EP06253469 A EP 06253469A EP 06253469 A EP06253469 A EP 06253469A EP 1741775 B1 EP1741775 B1 EP 1741775B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- particle
- vinyl
- monomers
- benefit agent
- methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/226—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
Definitions
- the polymer particles of the invention can comprise a wide range of monomeric units.
- monomer units as used herein is meant the monomeric units of the polymer chain, thus references to "a polymer particle comprising insoluble monomer units” as used herein means that the polymer particles is derived from insoluble monomers, and so forth.
- suitable lubricants are amino functional silicone oils such as Rhodorsil Oil Extrasoft supplied by Rhodia Silicones.
- Other silicones may be selected from those disclosed GB 1,549,180A , EP 459,821A2 and EP 459822A .
- Other suitable lubricants include any of those known for use as dye bath lubricants in the textile industry.
- the polysaccharide is present at levels of between 0.1% to 10% w/w by weight of the total amount of monomer in the core and the shell.
- the level of non-ionic surfactant is from 0 wt% to 30 wt%, preferably from 1 wt% to 25 wt%, most preferably from 2 wt% to 15 wt%, by weight of the total composition.
- Quaternary ammonium compounds having two long-chain aliphatic groups for example, distearyldimethyl ammonium chloride and di(hardened tallow alkyl) dimethyl ammonium chloride, are widely used in commercially available rinse conditioner compositions.
- Other examples of these cationic compounds are to be found in " Surfactants Science Series" volume 34 ed. Richmond 1990 , volume 37 ed. Rubingh 1991 and volume 53 eds. Cross and Singer 1994, Marcel Dekker Inc. New York ".
- Detergent compositions suitable for use in most automatic fabric washing machines generally contain anionic non-soap surfactant, or non-ionic surfactant, or combinations of the two in any suitable ratio, optionally together with soap.
- Detergency enzymes are commonly employed in granular form in amounts of from about 0.1 to about 3.0 wt%. However, any suitable physical form of enzyme may be used.
- the compositions of the invention may contain alkali metal, preferably sodium carbonate, in order to increase detergency and ease processing.
- Sodium carbonate may suitably be present in amounts ranging from 1 to 60 wt%, preferably from 2 to 40 wt%. However, compositions containing little or no sodium carbonate are also within the scope of the invention.
- Liquid detergent compositions can be prepared by admixing the essential and optional ingredients thereof in any desired order to provide compositions containing components in the requisite concentrations.
- Liquid compositions according to the present invention can also be in compact form which means it will contain a lower level of water compared to a conventional liquid detergent.
- the treatment will involve a washing or rinsing method such as treatment in the main wash or rinse cycle of a washing machine and involves contacting the substrate with an aqueous medium comprising the material of the invention.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Outer Garments And Coats (AREA)
Claims (23)
- Particule de polymère comprenant un noyau et une enveloppe, dans laquelle le noyau comprend un agent bénéfique qui est un lubrifiant et un polymère comprenant des motifs monomères qui comprennent au moins un groupe à insaturation éthylénique pouvant subir une polymérisation par addition et sont dérivés de monomères choisis dans le groupe constitué par :a) des monomères ayant une solubilité dans l'eau inférieure à 0,1 g/l, et/oub) des monomères ayant une solubilité dans l'eau de 0,1 à 30 g/l, etc) éventuellement, des monomères ayant une solubilité dans l'eau supérieure à 30 g/l, et/oud) éventuellement, des agents de réticulation, etdans laquelle l'enveloppe comprend des motifs monomères choisis parmi b) et éventuellement c) et/ou éventuellement d),
et dans laquelle la particule comprend un agent de dépôt qui est un polysaccharide cationique ou non ionique et qui est principalement attaché à la surface de la particule. - Particule selon la revendication 1, dans laquelle l'agent bénéfique est choisi parmi une silicone, une huile minérale, une huile végétale et un polyester de sucre.
- Particule selon la revendication 1 ou la revendication 2, dans laquelle l'agent bénéfique comprend un lubrifiant biodégradable.
- Particule selon la revendication 3, dans laquelle le lubrifiant est un polyester de sucre.
- Particule selon la revendication 4, dans laquelle le polyester de sucre est un polyester de saccharose, de préférence choisi parmi le tétrastéarate de saccharose, le tétraérucate de saccharose, le tétralaurate de saccharose, le tétraoléate de saccharose, le tétrapalmitate de saccharose et le tétrapalm kernal de saccharose.
- Particule selon la revendication 4, dans laquelle le noyau comprend de 0,1 à 99 %, de préférence de 50 à 99 % en poids de polyester de sucre.
- Particule selon la revendication 1, dans laquelle le noyau et/ou l'enveloppe comprend (comprennent) des motifs monomères qui sont dérivés de monomères choisis dans le groupe constitué par les oléfines, l'éthylène, les monomères vinylaromatiques, les esters d'alcool vinylique avec des acides mono- et dicarboxyliques, les esters d'acides mono- et dicarboxyliques à insaturation α,β-monoéthylénique avec des alcools, les nitriles d'acides carboxyliques à insaturation α,β-monoéthylénique, les diènes conjugués, les acides monocarboxyliques et dicarboxyliques à insat-ration α,β-monoéthylénique et leurs amides, l'acide méthacrylique et ses esters avec des alcools et des diols, l'acide acrylique et ses esters avec des alcools et des diols, le maléate de diméthyle ou di-n-butyle, et/ou l'acide vinylsulfonique et ses sels solubles dans l'eau et des mélanges de ceux-ci.
- Particule selon la revendication 1, dans laquelle les monomères a), b), c) et d) comprennent les composés suivants :a) octate de vinyle ; décanoate de vinyle, laurate de vinyle ; stéarate de vinyle ; esters d'acide acrylique, méthacrylique, maléique, fumarique ou itaconique avec un alcool décylique, dodécylique, tétradécylique, hexadécylique et octadécylique ;b) styrène ; α-méthylstyrène ; acétate de o-chlorostyrène vinyle ; propionate de vinyle ; n-butyrate de vinyle ; esters d'acide acrylique, méthacrylique, maléique, fumarique ou itaconique avec les alcools méthylique, éthylique, n-butylique, isobutylique, n-hexylique et 2-éthylhexylique ; 1,3-butadiène ; 2,3-diméthylbutadiène ; et isoprène ;c) acide acrylique, acide méthacrylique, acide maléique, acide fumarique, acide itaconique, monoacrylates et monométhacrylates de poly-(oxyde d'alkylène), N-vinylpyrrolidone, acides méthacrylique et acrylique, acrylates et méthacrylates de 2-hydroxyéthyle, acrylates et méthacrylates de glycérol, acrylates et méthacrylates de poly(éthylène glycol), n-vinylpyrrolidone, acryloylmorpholine, vinylformamide, n-vinylacétamide et vinylcaprolactone, acrylonitrile (71 g/l), acrylamide, et méthacrylamide à des taux inférieurs à 10 % en poids de la teneur en motif monomère de la particule ; méthacrylate de 2-(diméthylamino)éthyle, méthacrylate de 2-(diéthylamino)éthyle, méthacrylate de 2-(tert-butylamino)éthyle, méthacrylate de 2-aminoéthyle, méthacrylate de 2-(2-oxo-1-imidazolidinyl)éthyle, vinylpyridine, vinylcarbazole, vinylimidazole, vinylaniline, et leurs formes cationiques après traitement avec des halogénures d'alkyle ;d) vinyltoluènes, divinylbenzène, diacrylate d'éthylène glycol, diacrylate de 1,2-propylène glycol, diacrylate de 1,3-propylène glycol, diacrylate de 1,3-butylène glycol, diacrylates de 1,4-butylène glycol, diméthacrylate d'éthylène glycol, diméthacrylate de 1,2-propylène glycol, diacrylate de 1,3-propylène glycol, diméthacrylate de 1,3-butylène glycol, diméthacrylate de 1,4-butylène glycol, divinylbenzène, méthacrylate de vinyle, acrylate de vinyle, méthacrylate d'allyle, acrylate d'allyle, maléate de diallyle, fumarate de diallyle, méthylènebisacrylamide, acrylate de cyclopentadiényle, et cyanurate de triallyle.
- Particule selon la revendication 1, dans laquelle le noyau comprend des motifs monomères qui sont dérivés de monomères choisis dans le groupe constitué par l'acrylate de butyle, le méthacrylate de butyle, l'acrylate d'hexyle, le méthacrylate d'hexyle, l'acrylate de 2-éthylhexyle, le méthacrylate de 2-éthylhexyle, l'acrylate de dodécyle, le méthacrylate de dodécyle, l'acrylate d'octadécyle, le méthacrylate d'octadécyle, le styrène, l'acétate de vinyle et le divinylbenzène, ou des mélanges de ceux-ci.
- Particule selon la revendication 1, ayant une taille de particule inférieure à 1 micron, de préférence inférieure à 500 nm.
- Particule selon la revendication 1, dans laquelle l'agent de dépôt est un polysaccharide ayant des liaisons β-1,4.
- Particule selon la revendication 11, dans laquelle le polysaccharide est choisi dans le groupe constitué par un polymannane, un polyglucane, un polyglucomannane, un polyxyloglucane et un polygalactomannane ou des mélanges de ceux-ci.
- Particule selon la revendication 12, dans laquelle le polysaccharide est la gomme de caroube.
- Particule selon la revendication 11, dans laquelle le polysaccharide est choisi dans le groupe constitué par un polymannane cationiquement modifié, un polyglucane, un polyglucomannane, un polyxyloglucane et un polygalactomannane ou un mélange de ceux-ci.
- Particule selon la revendication 14, dans laquelle le polysaccharide est une cellulose ou un guar cationiquement modifié(e).
- Procédé de préparation de particules de polymère selon la revendication 1, dans lequel le procédé de préparation du noyau comprend une polymérisation en miniémulsion des monomères.
- Procédé selon la revendication 16, qui comprend les étapes de :(a) préparation d'une miniémulsion (comprenant des monomères, un agent bénéfique et un co-tensioactif), et(b) polymérisation de la miniémulsion de l'étape (a) pour former des particules de noyau de miniémulsion, et(c) ajout de monomères et polymérisation ultérieure pour former une enveloppe autour des particules de noyau de l'étape (b),dans lequel l'attachement de l'agent de dépôt aux particules de polymère' se produit dans l'étape (c) .
- Procédé selon la revendication 17, qui comprend les étapes de :(i) mélange des monomères et d'un agent bénéfique avec un co-tensioactif pour former un mélange (y),(ii) dissolution d'un mélange de tensioactifs dans de l'eau pour former un mélange (z),(iii) combinaison de (y) et (z) et soumission à un fort cisaillement pour former une miniémulsion,(iv) ajout d'un initiateur de sorte à initier la polymérisation, et(v) ajout de monomères, d'un agent de dépôt et d'initiateurs à une vitesse telle que les monomères polymérisent résultant en une enveloppe autour du noyau (avec un attachement simultané de l'agent de dépôt sur les particules de polymère).
- Composition de traitement du linge comprenant la particule selon l'une quelconque des revendications 1 à 15.
- Utilisation d'une composition de traitement du linge selon la revendication 19 dans le traitement d'un tissu.
- Utilisation selon la revendication 20, dans laquelle l'utilisation offre une garantie de protection à l'agent bénéfique par rapport aux tensioactifs pendant le procédé de lavage.
- Procédé de traitement d'un tissu, de préférence un coton, comprenant la mise en contact du tissu avec la particule de polymère selon l'une quelconque des revendications 11 à 15.
- Utilisation d'une particule selon l'une quelconque des revendications 1 à 15 dans le traitement d'un tissu afin d'offrir une garantie de protection à l'agent bénéfique par rapport aux tensioactifs pendant le procédé de lavage.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0513803.7A GB0513803D0 (en) | 2005-07-06 | 2005-07-06 | Fabric care composition |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1741775A1 EP1741775A1 (fr) | 2007-01-10 |
EP1741775B1 true EP1741775B1 (fr) | 2009-04-29 |
Family
ID=34856722
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06253469A Not-in-force EP1741775B1 (fr) | 2005-07-06 | 2006-06-30 | Composition d'entretien pour tissus |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1741775B1 (fr) |
AT (1) | ATE430190T1 (fr) |
DE (1) | DE602006006505D1 (fr) |
ES (1) | ES2326686T3 (fr) |
GB (1) | GB0513803D0 (fr) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8426353B2 (en) | 2008-06-16 | 2013-04-23 | Firmenich Sa | Process for preparing polyurea microcapsules |
US8636918B2 (en) | 2011-08-05 | 2014-01-28 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of controlling hard water scale |
US8674021B2 (en) | 2006-07-21 | 2014-03-18 | Akzo Nobel N.V. | Sulfonated graft copolymers |
US8679366B2 (en) | 2011-08-05 | 2014-03-25 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale |
US8778867B2 (en) | 2008-12-18 | 2014-07-15 | Firmenich Sa | Microcapsules and uses thereof |
US8841246B2 (en) | 2011-08-05 | 2014-09-23 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage |
US8853144B2 (en) | 2011-08-05 | 2014-10-07 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of improving drainage |
US8945314B2 (en) | 2012-07-30 | 2015-02-03 | Ecolab Usa Inc. | Biodegradable stability binding agent for a solid detergent |
US9034384B2 (en) | 2011-02-07 | 2015-05-19 | Firmenich Sa | Polyurea microcapsules |
US9051406B2 (en) | 2011-11-04 | 2015-06-09 | Akzo Nobel Chemicals International B.V. | Graft dendrite copolymers, and methods for producing the same |
US9109068B2 (en) | 2005-07-21 | 2015-08-18 | Akzo Nobel N.V. | Hybrid copolymer compositions |
US9334464B2 (en) | 2011-11-29 | 2016-05-10 | Firmenich Sa | Microcapsules and uses thereof |
US9365805B2 (en) | 2014-05-15 | 2016-06-14 | Ecolab Usa Inc. | Bio-based pot and pan pre-soak |
US9499769B2 (en) | 2011-06-28 | 2016-11-22 | Firmenich Sa | Process for preparing polyurea microcapsules |
US9968096B2 (en) | 2014-06-27 | 2018-05-15 | Firmenich Sa | Process for preparing antimicrobial microcapsules |
US9988526B2 (en) | 2011-11-04 | 2018-06-05 | Akzo Nobel Chemicals International B.V. | Hybrid dendrite copolymers, compositions thereof and methods for producing the same |
US10260022B2 (en) | 2015-02-06 | 2019-04-16 | Firmenich Sa | Microcapsules imparting intense vanilla odor note |
US10526567B2 (en) | 2015-01-23 | 2020-01-07 | Firmenich Sa | Process for the preparation of microcapsules free from melamine-formaldehyde |
US10646416B2 (en) | 2013-05-22 | 2020-05-12 | Firmenich Sa | Microcapsules containing a gas-releasing photolabile compound and uses thereof |
US11072766B2 (en) | 2011-12-22 | 2021-07-27 | Firmenich Sa | Process for preparing polyurea microcapsules |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0524665D0 (en) * | 2005-12-02 | 2006-01-11 | Unilever Plc | Laundry composition |
GB0710369D0 (en) * | 2007-06-01 | 2007-07-11 | Unilever Plc | Improvements relating to perfume particles |
GB0718532D0 (en) | 2007-09-22 | 2007-10-31 | Unilever Plc | Improvements relating to fabric treatment compositions |
WO2010012407A1 (fr) * | 2008-07-29 | 2010-02-04 | Ashland Licensing And Intellectual Property Llc. | Additifs modifiés pour supprimer la formation de poussières |
EP2321397B1 (fr) * | 2008-09-12 | 2013-03-06 | Unilever PLC | Ameliorations associees aux adoucissants textiles |
GB0904700D0 (en) | 2009-03-19 | 2009-04-29 | Unilever Plc | Improvements relating to benefit agent delivery |
US9271905B2 (en) | 2010-06-11 | 2016-03-01 | Firmenich S.A. | Process for preparing polyurea microcapsules |
WO2013107586A2 (fr) * | 2012-01-17 | 2013-07-25 | Unilever Plc | Particule d'administration d'agent bénéfique, procédé de préparation de ladite particule, compositions comprenant lesdites particules et procédé pour traiter des substrats |
ES2687370T3 (es) | 2013-05-22 | 2018-10-24 | Firmenich Sa | Microcápsulas que contienen un cetoácido o cetoéster fotolábil de generación de gas y usos de las mismas |
WO2015014603A2 (fr) * | 2013-07-30 | 2015-02-05 | Unilever Plc | Particule d'administration d'agent traitant |
JP6598781B2 (ja) | 2013-12-19 | 2019-10-30 | フイルメニツヒ ソシエテ アノニム | ハイブリッドマイクロカプセル |
WO2015091877A1 (fr) | 2013-12-19 | 2015-06-25 | Firmenich Sa | Microcapsules à particule stabilisée |
MX2016009095A (es) | 2014-01-27 | 2016-10-13 | Firmenich & Cie | Proceso para preparar microcapsulas aminoplasticas. |
BR112017010213A2 (pt) | 2014-11-24 | 2018-02-06 | Firmenich & Cie | microcápsulas que contêm um polímero fotoinstável gerador de gás e usos das mesmas |
WO2016162381A1 (fr) | 2015-04-07 | 2016-10-13 | Firmenich Sa | Procédé de préparation de microcapsules de polyurée |
CN110709056B (zh) | 2017-06-01 | 2022-12-13 | 弗门尼舍有限公司 | 水性微乳液 |
US11331639B2 (en) | 2017-10-19 | 2022-05-17 | Firmenich Sa | Hydrogel beads |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0117768D0 (en) * | 2001-07-20 | 2001-09-12 | Unilever Plc | Use of polymers in fabrics cleaning |
ES2272758T3 (es) * | 2001-08-02 | 2007-05-01 | Unilever N.V. | Tratamiento para sustratos. |
GB0229806D0 (en) * | 2002-12-20 | 2003-01-29 | Unilever Plc | Fabric care composition |
GB0412854D0 (en) * | 2004-06-09 | 2004-07-14 | Unilever Plc | Fabric care composition |
-
2005
- 2005-07-06 GB GBGB0513803.7A patent/GB0513803D0/en not_active Ceased
-
2006
- 2006-06-30 AT AT06253469T patent/ATE430190T1/de not_active IP Right Cessation
- 2006-06-30 ES ES06253469T patent/ES2326686T3/es active Active
- 2006-06-30 EP EP06253469A patent/EP1741775B1/fr not_active Not-in-force
- 2006-06-30 DE DE602006006505T patent/DE602006006505D1/de active Active
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9321873B2 (en) | 2005-07-21 | 2016-04-26 | Akzo Nobel N.V. | Hybrid copolymer compositions for personal care applications |
US9109068B2 (en) | 2005-07-21 | 2015-08-18 | Akzo Nobel N.V. | Hybrid copolymer compositions |
US8674021B2 (en) | 2006-07-21 | 2014-03-18 | Akzo Nobel N.V. | Sulfonated graft copolymers |
US8426353B2 (en) | 2008-06-16 | 2013-04-23 | Firmenich Sa | Process for preparing polyurea microcapsules |
US9498411B2 (en) | 2008-12-18 | 2016-11-22 | Firmenich Sa | Microcapsules and uses thereof |
US8778867B2 (en) | 2008-12-18 | 2014-07-15 | Firmenich Sa | Microcapsules and uses thereof |
US9034384B2 (en) | 2011-02-07 | 2015-05-19 | Firmenich Sa | Polyurea microcapsules |
US9499769B2 (en) | 2011-06-28 | 2016-11-22 | Firmenich Sa | Process for preparing polyurea microcapsules |
US8853144B2 (en) | 2011-08-05 | 2014-10-07 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of improving drainage |
US8679366B2 (en) | 2011-08-05 | 2014-03-25 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale |
US8636918B2 (en) | 2011-08-05 | 2014-01-28 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of controlling hard water scale |
US9309489B2 (en) | 2011-08-05 | 2016-04-12 | Ecolab Usa Inc | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage |
US8841246B2 (en) | 2011-08-05 | 2014-09-23 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage |
US9051406B2 (en) | 2011-11-04 | 2015-06-09 | Akzo Nobel Chemicals International B.V. | Graft dendrite copolymers, and methods for producing the same |
US9988526B2 (en) | 2011-11-04 | 2018-06-05 | Akzo Nobel Chemicals International B.V. | Hybrid dendrite copolymers, compositions thereof and methods for producing the same |
US9334464B2 (en) | 2011-11-29 | 2016-05-10 | Firmenich Sa | Microcapsules and uses thereof |
US11072766B2 (en) | 2011-12-22 | 2021-07-27 | Firmenich Sa | Process for preparing polyurea microcapsules |
US8945314B2 (en) | 2012-07-30 | 2015-02-03 | Ecolab Usa Inc. | Biodegradable stability binding agent for a solid detergent |
US10646416B2 (en) | 2013-05-22 | 2020-05-12 | Firmenich Sa | Microcapsules containing a gas-releasing photolabile compound and uses thereof |
US9365805B2 (en) | 2014-05-15 | 2016-06-14 | Ecolab Usa Inc. | Bio-based pot and pan pre-soak |
US10053652B2 (en) | 2014-05-15 | 2018-08-21 | Ecolab Usa Inc. | Bio-based pot and pan pre-soak |
US9968096B2 (en) | 2014-06-27 | 2018-05-15 | Firmenich Sa | Process for preparing antimicrobial microcapsules |
US10526567B2 (en) | 2015-01-23 | 2020-01-07 | Firmenich Sa | Process for the preparation of microcapsules free from melamine-formaldehyde |
US10260022B2 (en) | 2015-02-06 | 2019-04-16 | Firmenich Sa | Microcapsules imparting intense vanilla odor note |
Also Published As
Publication number | Publication date |
---|---|
ATE430190T1 (de) | 2009-05-15 |
GB0513803D0 (en) | 2005-08-10 |
DE602006006505D1 (de) | 2009-06-10 |
EP1741775A1 (fr) | 2007-01-10 |
ES2326686T3 (es) | 2009-10-16 |
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