EP1714772A1 - Thermoplastisch verarbeitbarer Verbundwerkstoff - Google Patents

Thermoplastisch verarbeitbarer Verbundwerkstoff Download PDF

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Publication number
EP1714772A1
EP1714772A1 EP05008635A EP05008635A EP1714772A1 EP 1714772 A1 EP1714772 A1 EP 1714772A1 EP 05008635 A EP05008635 A EP 05008635A EP 05008635 A EP05008635 A EP 05008635A EP 1714772 A1 EP1714772 A1 EP 1714772A1
Authority
EP
European Patent Office
Prior art keywords
layer
composite material
fibers
material according
reinforcing fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05008635A
Other languages
German (de)
English (en)
French (fr)
Inventor
Burak Baser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Quadrant Plastic Composites AG
Original Assignee
Quadrant Plastic Composites AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Quadrant Plastic Composites AG filed Critical Quadrant Plastic Composites AG
Priority to EP05008635A priority Critical patent/EP1714772A1/de
Priority to PL06721917T priority patent/PL1901912T3/pl
Priority to ES06721917T priority patent/ES2366571T3/es
Priority to AT06721917T priority patent/ATE510681T1/de
Priority to EP06721917A priority patent/EP1901912B1/de
Priority to PCT/CH2006/000215 priority patent/WO2006111037A1/de
Publication of EP1714772A1 publication Critical patent/EP1714772A1/de
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/465—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating by melting a solid material, e.g. sheets, powders of fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/504—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands
    • B29C70/506—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC] using rollers or pressure bands and impregnating by melting a solid material, e.g. sheet, powder, fibres
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    • B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
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    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/245—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00—Other non-woven fabrics
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    • B32B2307/70—Other properties
    • B32B2307/718—Weight, e.g. weight per square meter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2459/00—Nets, e.g. camouflage nets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/08—Cars

Definitions

  • the invention relates to a thermoplastically processable composite material comprising at least one nonwoven fabric layer A of thermoplastic fibers and a fabric or scrim layer B of reinforcing fibers.
  • Thermoplastics are increasingly used because of their low weight for the production of moldings, especially automotive parts. To give them sufficient strength and rigidity, they are usually bonded with reinforcing fibers.
  • GMT semi-finished products flat semi-finished products made of glass mat-reinforced thermoplastics
  • this procedure requires a lot of energy because the viscous melt at pressures far above 1 bar must be pressed into the mat.
  • only semi-finished products and thus also finished parts with a weight per unit area of more than 1500 g / m 2 can be produced by this method in practice.
  • DE-A 36 14 533 is a method for the production of moldings from thermoplastic materials containing a reinforcing insert described.
  • a mixed fleece made of thermoplastic fibers and reinforcing fibers is produced by the carding or Airlay process and solidified by needling. Blanks from this mixed fleece are heated and pressed directly to moldings. Between two heated blanks, another flat substrate, for example a mesh fabric or a fabric, can be placed and co-pressed.
  • a mesh fabric or a fabric can be placed and co-pressed.
  • the invention was based on the object to provide a thermoplastically processable composite material that can be produced easily and with little expenditure of energy and easy to handle, and can be processed into a semi-finished or equal to finished parts, even with low basis weight.
  • the EP-A 697 275 describes a rigid, flat composite fiber material of a thermoplastic matrix and reinforcing fibers, consisting of two cover layers A of glass fiber fabric, which is embedded in a thermoplastic matrix, and a core layer B of the thermoplastic matrix, which may contain glass fibers with undirected fiber orientation.
  • Suitable thermoplastic fibers for the nonwoven layer A are all spinnable thermoplastics, preferably polypropylene with an MFI (230 ° C., 2.16 kp) of 25 to 150 g / 10 min, but also polyamides and linear polyesters.
  • the thermoplastic fibers generally have an average length of 20 to 100 mm.
  • the layer A preferably consists of 100% thermoplastic fibers, but mixed nonwovens with up to 90% by weight, in particular with 40 to 70% by weight, of reinforcing fibers are also suitable.
  • Preferred reinforcing fibers are glass fibers, but also natural fibers, aramid fibers and fibers of higher melting polymers are suitable.
  • the reinforcing fibers in the layer A generally have an average length of 20 to 200 mm.
  • the nonwoven fabric of layer A is produced by the carding or airlay method. This results in a pure thermoplastic fiber fleece or a mixed fiber fleece with a basis weight of 100 to 2000 g / m 2 , preferably from 300 to 1000 g / m 2 .
  • the layer B is preferably a textile fabric, eg a linen fabric, a twill fabric or a leno fabric; In addition, scrims made of parallel fibers are also suitable.
  • the reinforcing fibers are again preferably glass fibers, but also aramid fibers, natural fibers, carbon fibers, basalt fibers and fibers of higher melting polymers are suitable, as well as hybrid fibers, such as glass fibers and polypropylene fibers.
  • the fibers of the textile fabric or fabric are preferably present as fiber bundles with a titer between 300 and 3000 tex.
  • the layer B has a basis weight of 100 to 1000 g / m 2 , preferably from 200 to 800 g / m 2 .
  • the preferred layer sequence is A - B - A, whereby the two layers A can also have different thicknesses.
  • the layer sequence A - B is possible. It is essential that the layers A and B are pinned together, so that during transport and during subsequent processing, the layers do not slip and when inserting into the mold only a single layer must be inserted.
  • the fiber bundles of the layer B are opened by the needling, so that a better impregnation with the thermoplastic melt of the layer A can take place during hot pressing of the composite material.
  • the needling can be done on conventional needle chairs with felting needles.
  • the nonwoven layer A is produced by the carding or airlay method, whereby an endless strip is obtained.
  • the layer A is then continuously merged with the layer B and pinned together, either a position B is introduced between two layers A or a layer A and a layer B are merged.
  • the composites can be pressed directly into three-dimensional finished parts in a mold at temperatures above the softening point of the thermoplastic. But you can also produce a semi-finished by the composite is continuously consolidated by hot pressing. This is preferably done on a double belt press; but you can also use a calender or a laminator.
  • the semi-finished product preferably has a thickness of 0.5 to 5.0, in particular of 1.0 to 2.0 mm and a basis weight of 200 to 3000, in particular from 300 to 1500 g / m 2 . It can be stored, transported and further processed to finished parts if required.
  • the finished parts produced from the composite materials according to the invention are characterized by a high strength and rigidity, as well as by a low weight. They are preferably used in the automotive field, e.g. as reinforcement for spare wheel wells, rear doors, bumpers or subfloors. Sandwich weights are particularly light and highly rigid. You can e.g. used as loading floors in trucks.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Nonwoven Fabrics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
EP05008635A 2005-04-20 2005-04-20 Thermoplastisch verarbeitbarer Verbundwerkstoff Withdrawn EP1714772A1 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP05008635A EP1714772A1 (de) 2005-04-20 2005-04-20 Thermoplastisch verarbeitbarer Verbundwerkstoff
PL06721917T PL1901912T3 (pl) 2005-04-20 2006-04-20 Przetwarzalny termoplastycznie materiał warstwowy
ES06721917T ES2366571T3 (es) 2005-04-20 2006-04-20 Material compuesto que se puede procesar de modo termoplástico.
AT06721917T ATE510681T1 (de) 2005-04-20 2006-04-20 Thermoplastisch verarbeitbarer verbundwerkstoff
EP06721917A EP1901912B1 (de) 2005-04-20 2006-04-20 Thermoplastisch verarbeitbarer verbundwerkstoff
PCT/CH2006/000215 WO2006111037A1 (de) 2005-04-20 2006-04-20 Thermoplastisch verarbeitbarer verbundwerkstoff

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP05008635A EP1714772A1 (de) 2005-04-20 2005-04-20 Thermoplastisch verarbeitbarer Verbundwerkstoff

Publications (1)

Publication Number Publication Date
EP1714772A1 true EP1714772A1 (de) 2006-10-25

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EP05008635A Withdrawn EP1714772A1 (de) 2005-04-20 2005-04-20 Thermoplastisch verarbeitbarer Verbundwerkstoff
EP06721917A Active EP1901912B1 (de) 2005-04-20 2006-04-20 Thermoplastisch verarbeitbarer verbundwerkstoff

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP06721917A Active EP1901912B1 (de) 2005-04-20 2006-04-20 Thermoplastisch verarbeitbarer verbundwerkstoff

Country Status (5)

Country Link
EP (2) EP1714772A1 (pl)
AT (1) ATE510681T1 (pl)
ES (1) ES2366571T3 (pl)
PL (1) PL1901912T3 (pl)
WO (1) WO2006111037A1 (pl)

Cited By (8)

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EP1923192A1 (en) * 2005-07-29 2008-05-21 The Doshisha Method for molding fiber-reinforced thermoplastic composite material, intermediate thereof and composite sheet
US20140011415A1 (en) * 2011-03-18 2014-01-09 Quadrant Plastic Composites Ag Thermoplastically deformable composite material
EP2716435A1 (de) * 2012-10-02 2014-04-09 Reifenhäuser GmbH & Co. KG Maschinenfabrik Verfahren und Halbzeug zur Herstellung eines Verbundformteils, insbesondere eines Faserverbundformteils und Verbundformteil, insbesondere Faserverbundformteil
EP2796603A1 (en) * 2011-12-21 2014-10-29 Fairtech Investment Limited Needle-punched non-woven fabric, manufacturing method thereof and filter and sound absorbing material formed thereby
CN104160081A (zh) * 2012-03-09 2014-11-19 奎德兰特塑料合成股份公司 平面复合材料
WO2015192948A1 (en) * 2014-06-19 2015-12-23 Imballaggi Protettivi S.R.L. Honeycomb sandwich sheet or panel, based on thermoplastic polypropylene
EP3385069A1 (de) * 2017-04-03 2018-10-10 Quadrant Plastic Composites AG Verfahren zur herstellung eines flächigen verbundbauteils und damit hergestelltes verbundbauteil
EP4053350A1 (de) 2021-03-04 2022-09-07 Hauraton GmbH & Co. KG Lastabtragende halbzeugstruktur

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US20090309260A1 (en) * 2008-06-12 2009-12-17 Kenneth Herbert Keuchel Method of delivering a thermoplastic and/or crosslinking resin to a composite laminate structure
DE102009039185A1 (de) * 2009-08-28 2011-03-03 Röchling Automotive AG & Co. KG Mehrschichtiges Material, etwa zur Herstellung von Fahrzeugverkleidungsteilen, insbesondere zur Herstellung von Radhaus- oder Motorraumverkleidungsteilen
EP2626200A1 (de) * 2012-02-08 2013-08-14 Quadrant Plastic Composites AG Flächiger Verbundwerkstoff
WO2015020999A2 (en) * 2013-08-06 2015-02-12 Neenah Technical Materials, Inc. A scrimless, rigid composite material
DE102016122145A1 (de) * 2016-11-17 2018-05-17 Cqlt Saargummi Technologies S.À.R.L. Bahnmaterial zur Bildung von Dachbelägen
CN106677129B (zh) * 2016-12-28 2018-11-02 上海蓝坤环境科技有限公司 一种点状针刺复合表层热熔抗冲刷的网络结构的加工方法
EP3606744B1 (de) * 2017-04-03 2021-03-03 Teijin Carbon Europe GmbH Verfahren zur herstellung eines textilen unidirektionalgewebes
DE102019119389A1 (de) * 2019-07-17 2021-01-21 Dr. Ing. H.C. F. Porsche Aktiengesellschaft Bauteil
EP3792044A1 (en) 2019-09-16 2021-03-17 Mitsubishi Chemical Advanced Materials AG Method of manufacturing a lightweight, structurally reinforced object of thermoplastic material

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Cited By (23)

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EP1923192A4 (en) * 2005-07-29 2010-09-15 Doshisha METHOD FOR MOLDING FIBER REINFORCED THERMOPLASTIC COMPOSITE MATERIAL, CORRESPONDING INTERMEDIATE MATERIAL, AND COMPOSITE SHEET
EP1923192A1 (en) * 2005-07-29 2008-05-21 The Doshisha Method for molding fiber-reinforced thermoplastic composite material, intermediate thereof and composite sheet
US20140011415A1 (en) * 2011-03-18 2014-01-09 Quadrant Plastic Composites Ag Thermoplastically deformable composite material
EP2796603A1 (en) * 2011-12-21 2014-10-29 Fairtech Investment Limited Needle-punched non-woven fabric, manufacturing method thereof and filter and sound absorbing material formed thereby
EP2796603A4 (en) * 2011-12-21 2015-09-02 Fairtech Invest Ltd NEEDLE-CARBURIZED NONWOVER, MANUFACTURING METHOD AND FILTER AND SOUND SUBSTANCE MANUFACTURED THEREFROM
CN104160081A (zh) * 2012-03-09 2014-11-19 奎德兰特塑料合成股份公司 平面复合材料
US10974481B2 (en) 2012-03-09 2021-04-13 Quadrant Plastic Composites Ag Planar composite material
US20150044438A1 (en) * 2012-03-09 2015-02-12 Quadrant Plastic Composites Ag Planar composite material
CN104160081B (zh) * 2012-03-09 2018-04-10 奎德兰特塑料合成股份公司 平面复合材料
CN104853893A (zh) * 2012-10-02 2015-08-19 赖芬豪泽机械工厂有限及两合有限公司 制备半成品的方法和用于制备复合模塑件、尤其是纤维复合模塑件的半成品以及复合模塑件、尤其是纤维复合模塑件
WO2014053566A1 (de) * 2012-10-02 2014-04-10 Reifenhäuser GmbH & Co. KG Maschinenfabrik Verfahren zur erzeugung eines halbzeugs und halbzeug zur herstellung eines verbundformteils, insbesondere eines faserverbundformteils und verbundformteil, insbesondere faserverbundformteil
EP2716435A1 (de) * 2012-10-02 2014-04-09 Reifenhäuser GmbH & Co. KG Maschinenfabrik Verfahren und Halbzeug zur Herstellung eines Verbundformteils, insbesondere eines Faserverbundformteils und Verbundformteil, insbesondere Faserverbundformteil
EP3263303A1 (de) * 2012-10-02 2018-01-03 Reifenhäuser GmbH & Co. KG Maschinenfabrik Verfahren zur erzeugung eines halbzeugs zur herstellung eines verbundformteils, insbesondere eines faserverbundformteils
KR101834052B1 (ko) 2012-10-02 2018-03-02 라이펜호이저 게엠베하 운트 코. 카게 마쉬넨파브릭 복합 성형품, 특히 복합 섬유 성형품의 제조를 위한 반제품의 제조 방법 및 반제품, 및 복합 성형품, 특히 복합 섬유 성형품
WO2015192948A1 (en) * 2014-06-19 2015-12-23 Imballaggi Protettivi S.R.L. Honeycomb sandwich sheet or panel, based on thermoplastic polypropylene
US10596777B2 (en) 2014-06-19 2020-03-24 Imballaggi Protettivi S.R.L. Honeycomb sandwich panel
WO2018185090A1 (de) * 2017-04-03 2018-10-11 Quadrant Plastic Composites Ag Verfahren zur herstellung eines flächigen verbundbauteils und damit hergestelltes verbundbauteil
CN111201132A (zh) * 2017-04-03 2020-05-26 三菱化学先进材料塑料复合材料公司 制造面状复合构件的方法和由此制造的复合构件
EP3385069A1 (de) * 2017-04-03 2018-10-10 Quadrant Plastic Composites AG Verfahren zur herstellung eines flächigen verbundbauteils und damit hergestelltes verbundbauteil
CN111201132B (zh) * 2017-04-03 2022-10-25 三菱化学先进材料塑料复合材料公司 制造面状复合构件的方法和由此制造的复合构件
EP3606742B1 (de) 2017-04-03 2023-03-22 Quadrant Plastic Composites AG Verfahren zur herstellung eines flächigen verbundbauteils und damit hergestelltes verbundbauteil
US11633939B2 (en) 2017-04-03 2023-04-25 Quadrant Plastic Composites, AG Method for producing a planar composite component and composite component produced thereby
EP4053350A1 (de) 2021-03-04 2022-09-07 Hauraton GmbH & Co. KG Lastabtragende halbzeugstruktur

Also Published As

Publication number Publication date
EP1901912A1 (de) 2008-03-26
PL1901912T3 (pl) 2011-12-30
ATE510681T1 (de) 2011-06-15
WO2006111037A1 (de) 2006-10-26
EP1901912B1 (de) 2011-05-25
ES2366571T3 (es) 2011-10-21

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