EP1662012A1 - Bande d'acier micro-allié laminé à chaud pour obtenir les morceaux finis par le froid serrant et cisaillant - Google Patents
Bande d'acier micro-allié laminé à chaud pour obtenir les morceaux finis par le froid serrant et cisaillant Download PDFInfo
- Publication number
- EP1662012A1 EP1662012A1 EP04425879A EP04425879A EP1662012A1 EP 1662012 A1 EP1662012 A1 EP 1662012A1 EP 04425879 A EP04425879 A EP 04425879A EP 04425879 A EP04425879 A EP 04425879A EP 1662012 A1 EP1662012 A1 EP 1662012A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- micro
- strip
- steel strip
- hot rolled
- ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000742 Microalloyed steel Inorganic materials 0.000 title claims description 7
- 238000003825 pressing Methods 0.000 title claims description 3
- 238000010008 shearing Methods 0.000 title 1
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 12
- 239000010959 steel Substances 0.000 claims abstract description 12
- 229910001209 Low-carbon steel Inorganic materials 0.000 claims abstract description 3
- 238000005275 alloying Methods 0.000 claims description 8
- 238000005096 rolling process Methods 0.000 claims description 7
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 238000007792 addition Methods 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000005098 hot rolling Methods 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000010955 niobium Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005261 decarburization Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000009661 fatigue test Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
Definitions
- the present invention relates to a low carbon micro-alloyed steel strip that shows such features that it can replace, in producing finished pieces being stamped or cut, the cold rolled strips till now used to obtain structures of reduced weight and good mechanical strength.
- Said micro-alloyed or HSLA "High Strength Low Alloy" steels owe their name to the fact of including an addition of small quantities of niobium, vanadium, titanium and boron which hardly exceed the total quantity of 0.2%.
- These elements instead of entering as alloying agents in the iron crystal lattice, carry out their action being combined with carbon and nitrogen in the matrix, thus forming finely dispersed carbides, nitrides and carbonitrides. These compounds contribute to the grain refining and cause the matrix hardening with their precipitation in the ferritic grains.
- Object of the present invention is that of providing a strip of hot rolled, micro-alloyed low carbon steel with thickness ⁇ 0.7 mm which, particularly upon pickling and skinpassing, shows substantially the same metallurgical and geometrical features, as well as relating to planarity and deformability, of a cold rolled strip for producing stamped or sheared finished pieces, such as to be used as a valid substitute thereof.
- the strip according to the present invention is preferably, although not exclusively, manufactured with in-line plants of the thin-slab type, as disclosed e.g. in WO2004/026497 in the name of the present applicant, which is schematically represented in Fig. 1 and is characterized, as set forth in claim 1, by a grain fineness better than grade 10 of ASTM E 112 standard in a percentage > 90% of the whole structure, with a ratio between yield point and breaking load ⁇ 70%.
- the strip of micro-alloyed steel according to the present invention is preferably, although not exclusively, produced in thin-slab plants as schematically represented in Fig. 1, where references is made in particular to the plant being the object of the international publication WO2004/026497.
- the following operating steps can be observed, downstream of the casting step: a) liquid core reduction; b) roughing step directly adjoining the continuous casting; c) heating in an induction furnace; e) finishing rolling; f) compact controlled cooling; g) coiling on a reel.
- Such a plant is able to keep the temperature of the pre-strip (d) above 900°C in the steps preceding the final rolling.
- the pre-strip rolling above preceding 900°C allows to keep solute in the ⁇ iron (austenitic phase) most of the micro-alloying agents by completely exploiting their function of limiting the growth of the austenitic grain and enhancing the hardening by precipitation in ferritic phase during the cooling step after the final rolling.
- micro-alloyed steel strip according to the present invention shows a ratio between yield and breaking load equal or higher than 70%, as well as a good capability of being formed and cut under cold conditions.
- the ratio between the breaking point under strain due to plain flexure ( ⁇ FP ) and the yield point ⁇ FP /R p0,2 is near to 1 and equal to 0.96, thereby constantly higher than that relating to the reference hot rolled material, comprised between 0.88 and 0.90, practically corresponding to the value of the same ratio as detected for cold rolled strips of the same grade.
- the particular fine microstructure of these strips cause the same to be suitable for being finally cut and forming holes therein by punching, as well as the cold forming of complex shapes, in particular folds at 180° with bending radius equal to the thickness, for high strength steels having minimum warranted yield load comprised between 275 and 700N/mm 2 .
- the cold forming of pieces having a complex shape is made easier also by the constant profile of the strip and its parallelism with deviation of less than 0.05 mm.
- the various steel grades have a chemical analysis comprised within the limits listed in the following Table 1: Element Content (%) C 0.04-0.08 Mn 0.15-2.0 Si 0.06-0.60 P 0.010 max S 0.010 max Cr 0.35 max Ni 0.20 max Mo 0.25 max Cu 0.20 max Nb 0.012-0.070 V 0.02-0.03 Ti ⁇ 0.11 Al 0.025-0.050 N 0.0115 max
- the total sum of micro-alloying elements (V, Ti and Nb) does not exceed 0.2%.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Coating With Molten Metal (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04425879A EP1662012B1 (fr) | 2004-11-24 | 2004-11-24 | Bande d'acier micro-allié laminé à chaud pour obtenir les morceaux finis par le froid serrant et cisaillant |
| DE602004027147T DE602004027147D1 (de) | 2004-11-24 | 2004-11-24 | Streifen des warm gewalzten Mikro-legierten Stahls für das Erhalten der fertigen Stücke durch die betätigende und scherende Kälte |
| ES04425879T ES2343460T3 (es) | 2004-11-24 | 2004-11-24 | Fleje de acero microaleado laminado en caliente para la obtencion de piezas acabadas mediante prensado en frio y cizallado. |
| AT04425879T ATE467691T1 (de) | 2004-11-24 | 2004-11-24 | Streifen des warm gewalzten mikro-legierten stahls für das erhalten der fertigen stücke durch die betätigende und scherende kälte |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04425879A EP1662012B1 (fr) | 2004-11-24 | 2004-11-24 | Bande d'acier micro-allié laminé à chaud pour obtenir les morceaux finis par le froid serrant et cisaillant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1662012A1 true EP1662012A1 (fr) | 2006-05-31 |
| EP1662012B1 EP1662012B1 (fr) | 2010-05-12 |
Family
ID=34932908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04425879A Revoked EP1662012B1 (fr) | 2004-11-24 | 2004-11-24 | Bande d'acier micro-allié laminé à chaud pour obtenir les morceaux finis par le froid serrant et cisaillant |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP1662012B1 (fr) |
| AT (1) | ATE467691T1 (fr) |
| DE (1) | DE602004027147D1 (fr) |
| ES (1) | ES2343460T3 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007086086A1 (fr) * | 2006-01-26 | 2007-08-02 | Giovanni Arvedi | Feuillard d'acier micro-allie lamine a chaud permettant de produire des pieces finies par emboutissage et cisaillement a froid |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3943210A1 (fr) | 2020-07-23 | 2022-01-26 | Primetals Technologies Austria GmbH | Installation composite de coulée et de laminage destinée à la fabrication d'une bande finie laminée à chaud à partir d'un acier fondu |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1275096A (en) * | 1968-08-28 | 1972-05-24 | Inland Steel Co | Tough, high strength steel article and method for producing same |
| US6488790B1 (en) * | 2001-01-22 | 2002-12-03 | International Steel Group Inc. | Method of making a high-strength low-alloy hot rolled steel |
| JP2003253381A (ja) * | 2002-03-01 | 2003-09-10 | Mitsubishi Heavy Ind Ltd | 高強度低合金鋼 |
| WO2003087414A1 (fr) * | 2002-03-29 | 2003-10-23 | Nippon Steel Corporation | Acier a haute resistance presentant une excellente resistance aux temperatures elevees et procede de production de celui-ci |
| WO2004026497A1 (fr) * | 2002-09-19 | 2004-04-01 | Giovanni Arvedi | Process and production line for manufacturing ultrathin hot rolled strips based n the thin slab technique |
-
2004
- 2004-11-24 AT AT04425879T patent/ATE467691T1/de active
- 2004-11-24 ES ES04425879T patent/ES2343460T3/es not_active Expired - Lifetime
- 2004-11-24 DE DE602004027147T patent/DE602004027147D1/de not_active Expired - Lifetime
- 2004-11-24 EP EP04425879A patent/EP1662012B1/fr not_active Revoked
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1275096A (en) * | 1968-08-28 | 1972-05-24 | Inland Steel Co | Tough, high strength steel article and method for producing same |
| US6488790B1 (en) * | 2001-01-22 | 2002-12-03 | International Steel Group Inc. | Method of making a high-strength low-alloy hot rolled steel |
| JP2003253381A (ja) * | 2002-03-01 | 2003-09-10 | Mitsubishi Heavy Ind Ltd | 高強度低合金鋼 |
| WO2003087414A1 (fr) * | 2002-03-29 | 2003-10-23 | Nippon Steel Corporation | Acier a haute resistance presentant une excellente resistance aux temperatures elevees et procede de production de celui-ci |
| WO2004026497A1 (fr) * | 2002-09-19 | 2004-04-01 | Giovanni Arvedi | Process and production line for manufacturing ultrathin hot rolled strips based n the thin slab technique |
Non-Patent Citations (5)
| Title |
|---|
| DATABASE INSPEC [online] THE INSTITUTION OF ELECTRICAL ENGINEERS, STEVENAGE, GB; 19 April 2002 (2002-04-19), HUMBERT M ET AL: "Modelling of the variant selection mechanism in the phase transformation of HSLA steel produced by compact strip production", XP002324000, Database accession no. 7303672 * |
| DATABASE INSPEC [online] THE INSTITUTION OF ELECTRICAL ENGINEERS, STEVENAGE, GB; 20 July 2004 (2004-07-20), LEVY B S, VAN TYNE J, STRINGFIELD J M: "Characterizing steel tube for hydroforming applications", XP002323999, Database accession no. 8172068 * |
| HUMBERT M, GARDIOLA B, ESLING C, FLEMMING G, HENSGER KE: "Modelling of the variant selection mechanism in the phase transformation of HSLA steel produced by compact strip production", ACTA MATERIALIA, vol. 50, no. 7, 19 April 2002 (2002-04-19), UK, pages 1741 - 1747, ISSN: 1359-6454 * |
| LEVY BS, VAN TYNE J, STRINGFIELDS: "Characterizing steel tube for hydroforming applications", JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, vol. 150, no. 3, 10 July 2004 (2004-07-10), SWITZERLAND, pages 280 - 289, ISSN: 0924-0136 * |
| PATENT ABSTRACTS OF JAPAN vol. 2003, no. 12 5 December 2003 (2003-12-05) * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007086086A1 (fr) * | 2006-01-26 | 2007-08-02 | Giovanni Arvedi | Feuillard d'acier micro-allie lamine a chaud permettant de produire des pieces finies par emboutissage et cisaillement a froid |
| US8257647B2 (en) | 2006-01-26 | 2012-09-04 | Giovanni Arvedi | Strip of hot rolled micro-alloyed steel for obtaining finished pieces by cold pressing and shearing |
Also Published As
| Publication number | Publication date |
|---|---|
| DE602004027147D1 (de) | 2010-06-24 |
| ES2343460T3 (es) | 2010-08-02 |
| ATE467691T1 (de) | 2010-05-15 |
| EP1662012B1 (fr) | 2010-05-12 |
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