EP1655749B1 - Pastille de contact destinée à un contact électrique mobile de disjoncteur, contact électrique mobile possédant une telle pastille et disjoncteur comportant un tel contact - Google Patents
Pastille de contact destinée à un contact électrique mobile de disjoncteur, contact électrique mobile possédant une telle pastille et disjoncteur comportant un tel contact Download PDFInfo
- Publication number
- EP1655749B1 EP1655749B1 EP05354035A EP05354035A EP1655749B1 EP 1655749 B1 EP1655749 B1 EP 1655749B1 EP 05354035 A EP05354035 A EP 05354035A EP 05354035 A EP05354035 A EP 05354035A EP 1655749 B1 EP1655749 B1 EP 1655749B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- contact
- circuit breaker
- contact pad
- silver
- movable contact
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 235000010603 pastilles Nutrition 0.000 title description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 17
- 239000004332 silver Substances 0.000 claims description 15
- 229910052709 silver Inorganic materials 0.000 claims description 14
- 239000000835 fiber Substances 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 239000004020 conductor Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 7
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- 229910001316 Ag alloy Inorganic materials 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 230000007246 mechanism Effects 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 19
- 239000004917 carbon fiber Substances 0.000 description 19
- 239000000463 material Substances 0.000 description 16
- 239000008188 pellet Substances 0.000 description 12
- 230000003628 erosive effect Effects 0.000 description 9
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- 229910002804 graphite Inorganic materials 0.000 description 7
- 239000010439 graphite Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000003466 welding Methods 0.000 description 5
- 230000006399 behavior Effects 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 230000004075 alteration Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/021—Composite material
- H01H1/027—Composite material containing carbon particles or fibres
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/021—Composite material
- H01H1/023—Composite material having a noble metal as the basic material
- H01H1/0233—Composite material having a noble metal as the basic material and containing carbides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/02—Contacts characterised by the material thereof
- H01H1/021—Composite material
- H01H1/025—Composite material having copper as the basic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H3/00—Mechanisms for operating contacts
- H01H3/22—Power arrangements internal to the switch for operating the driving mechanism
- H01H3/30—Power arrangements internal to the switch for operating the driving mechanism using spring motor
Definitions
- the invention relates to a contact pad intended to be fixed on a low voltage circuit breaker movable contact intended to withstand short-circuit peak currents of between 200 and 600 amperes per square millimeter of pellet.
- the pellet consists of an alloy of conducting material based on silver or copper, a fraction of refractory particles such as tungsten carbide, tungsten or titanium nitride and a fraction of carbon fibers.
- Solutions include adding at the surface or contact area composite materials in the form of pellets of different thicknesses and different materials.
- the pellets are usually made of silver or copper alloy. They are made in the usual manner by sintering a powder composed of a silver-based alloy, in particular silver and tungsten or silver and nickel. These contact materials have a high electrical conductivity, a high sufficient resistance to oxidation and good properties with regard to contact resistance.
- the known silver-based contact materials show an undesirable tendency to weld. In addition, they tend to cause adhesion of the contact surfaces and / or migration of material between the contact elements. Finally, their use is generally associated with excessive wear of the contacts.
- Carbon, in the form of fibers, can also be added to the alloy powder (document US4699763 ).
- the resistance to erosion is then improved, but this improvement is achieved at the cost of an alteration of the behavior of the contact at the weld.
- the carbon fibers are mixed with the metal powder with a wetting agent, lubricant and wet solvent, followed by drying, compression and sintering.
- the disadvantage of such a method is that it involves complications inherent to a wet process.
- EP0729162 is described a method of manufacturing powder-based electrical contacts of a good electrically conductive metal such as silver and crushed carbon fibers of average length less than 20 .mu.m.
- a good electrically conductive metal such as silver and crushed carbon fibers of average length less than 20 .mu.m.
- the contact surface keeps, after cutting under a short-circuit current, its fine, homogeneous and isotropic structure of fiber residues of variable length and any orientation in the matrix of money.
- the weight proportions of crushed carbon fiber residues are between 2 and 5% with the silver powder.
- the material thus obtained shows a low post contact resistance, good anti-weld qualities and acceptable erosion resistance.
- the invention therefore aims to overcome the disadvantages of the state of the art, so as to provide a contact pad having a low contact resistance post cut, high erosion resistance and good anti-welding properties.
- a contact pad according to the invention comprises a weight percentage of carbon fibers in the pellet strictly less than 2% of the total mass of said contact patch.
- the weight percentage of carbon fibers in the contact pad is between 0.5% and 1.9% of the total mass of said contact pad.
- the carbon fibers are crushed fibers with a length of less than 20 ⁇ m.
- the carbon fibers consist of carbonized fibers containing at least 90% carbon, less than 10% nitrogen, substantially 1% oxygen and less than 1% hydrogen.
- the contact patch is composed of 79% of the silver alloy, 20% of tungsten carbide (CW) and 1% of carbon fiber.
- a mobile circuit breaker contact according to a development mode of the invention comprises a movable contact finger connected to a contact pad as defined above, the chip being connected to the movable contact finger via a thin layer of conductive material based on silver alloy.
- the contact pad 3 is intended to be fixed on a moving contact 2 low-voltage circuit breaker 1 for supporting short-circuit currents of several kilo amperes.
- a contact pad 3 according to the invention is intended to withstand short-circuit peak currents of between 200 and 600 amperes per square millimeter of pellet.
- the contact pad 3 is composed of a conductive material such as silver (Ag) or copper (Cu) in which is inserted a fraction of carbon fibers and a fraction of refractory particles such as for example carbide tungsten (WC), tungsten (W), titanium nitride (TiN). These refractory particles have an average diameter of 1 to 10 microns.
- a conductive material such as silver (Ag) or copper (Cu) in which is inserted a fraction of carbon fibers and a fraction of refractory particles such as for example carbide tungsten (WC), tungsten (W), titanium nitride (TiN). These refractory particles have an average diameter of 1 to 10 microns.
- the carbon fibers consist of carbonized fibers containing at least 90% carbon, less than 10% nitrogen, substantially 1% oxygen and less than 1% hydrogen.
- carbon fibers with an average length L1 of between approximately 100 ⁇ m and 800 ⁇ m and a diameter of between 4 and 20 ⁇ m are chosen. These fibers undergo a cold and dry mechanical treatment in a mechanical grinder. The conditions of intensity and duration of grinding make it possible to obtain fibers the length of which is statistically distributed around a mean value which is much lower than the initial average value. From the initial fibers, crushed fiber residues having an average length of less than 20 ⁇ m are thus obtained. The crushed fibers are then added to the conductive material containing the refractory fractions. The powder mixture of conductive material and the crushed carbon fibers is carried out dry in a mechanical mixer until a homogeneous mixture is obtained. Said mixture then undergoes a unitary compression and a sintering so as to obtain an isotropic material structure
- the weight percentage of carbon fibers in the pellet is strictly less than 2%. It is preferably between 0.5% and 1.9% of the total mass of the pellet.
- an ideal compromise in the choice of the proportions of materials for this type of application consists in using a pellet comprising 79% silver (Ag), 20% tungsten carbide (CW) and 1% of crushed carbon fibers.
- this material having an appropriate homogeneous structure shows a low and stable post-cut contact resistance as well as a good resistance to erosion under a short circuit of several tens of kiloamperes.
- this material develops anti-welding characteristics with respect to the steel balls present in the environment during the cut especially in the electric arc column.
- An explosive phenomenon due to the degradation of the carbon fiber explains the anti-adhesion characteristics of this material with respect to molten steel balls.
- a movable contact 2 circuit breaker 1 comprising a movable contact finger moving relative to a fixed contact 4 of the circuit breaker, has a contact pad 3 as defined above.
- Said contact pad is connected to the movable contact finger by means of a thin layer of conductive material based on silver or a mixture of copper and silver. This intermediate layer makes it possible to block the propagation of cracks in the interface zone between the contact pad 3 and the finger.
- a circuit breaker 1 comprising an opening mechanism 6 acting on at least one electric moving contact 2 as defined above.
- Said at least one moving contact 2 is placed opposite a fixed contact 4.
- Said fixed contact is made of an alloy, generally comprising a silver metal matrix in which a fraction of particles of graphite powder is inserted. Said fraction of particles constitutes 3 to 5% of the mass of the alloy.
- the alloy may also comprise a certain amount of refractory elements (W, WC, Ni) of between 2 and 30% of the total mass.
- the circuit breaker 1 according to a particular embodiment, is intended to accept nominal currents of 1600 amps and short-term currents of 42000 amps for one second.
- the breaking chambers 10 comprise, by pole, five movable contacts 2 associated with a fixed contact area 4.
- Filtering means 5 placed on the walls of the breaking chambers 10 are intended to strongly attenuate external manifestations of the gases present in said rooms at the time of opening contacts.
- the filtering means 5 comprise filters having characteristics specific techniques as described in the applicant's patents ( EP-A-1115132 , EP-A-1251533 ).
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Contacts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0411869A FR2877763B1 (fr) | 2004-11-08 | 2004-11-08 | Pastille de contact destinee a un contact electrique mobile de disjoncteur, contact electrique mobile possedant une telle pastille et disjoncteur comportant un tel contact |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1655749A1 EP1655749A1 (fr) | 2006-05-10 |
EP1655749B1 true EP1655749B1 (fr) | 2007-11-28 |
Family
ID=34950471
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05354035A Active EP1655749B1 (fr) | 2004-11-08 | 2005-10-11 | Pastille de contact destinée à un contact électrique mobile de disjoncteur, contact électrique mobile possédant une telle pastille et disjoncteur comportant un tel contact |
Country Status (6)
Country | Link |
---|---|
US (1) | US7598832B2 (zh) |
EP (1) | EP1655749B1 (zh) |
CN (1) | CN1773647B (zh) |
DE (1) | DE602005003537T2 (zh) |
ES (1) | ES2297652T3 (zh) |
FR (1) | FR2877763B1 (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009018035A1 (de) * | 2009-04-18 | 2010-10-28 | Moeller Gmbh | Kontaktanordnung für Schwachstromanwendungen |
IN2013CH05861A (zh) * | 2013-12-16 | 2015-06-19 | Gen Electric | |
CN104532050A (zh) * | 2015-01-15 | 2015-04-22 | 潍坊学院 | 一种氮化钛增强银基触头材料及其制备方法 |
FR3036841B1 (fr) * | 2015-05-28 | 2017-06-23 | Schneider Electric Ind Sas | Pole mobile et appareil de coupure |
US11798751B2 (en) * | 2021-06-30 | 2023-10-24 | Siemens Industry, Inc. | Metal contact of a residential circuit breaker including ordered ceramic microparticles |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2057618A1 (de) * | 1970-11-24 | 1972-06-15 | Duerrwaechter E Dr Doduco | Metall-Kohlenstoff-Verbundwerkstoff und Verfahren zu seiner Herstellung |
FR2568417B1 (fr) | 1984-07-25 | 1986-11-28 | Lorraine Carbone | Procede de fabrication de contacts electriques et contacts obtenus. |
US4689196A (en) * | 1985-06-24 | 1987-08-25 | Gte Products Corporation | Silver-tungsten carbide-graphite electrical contact |
US4699763A (en) * | 1986-06-25 | 1987-10-13 | Westinghouse Electric Corp. | Circuit breaker contact containing silver and graphite fibers |
US5199553A (en) * | 1990-10-09 | 1993-04-06 | Fuji Electric Co., Ltd. | Sliding contactor for electric equipment |
DE4111683A1 (de) * | 1991-04-10 | 1992-10-22 | Duerrwaechter E Dr Doduco | Werkstoff fuer elektrische kontakte aus silber mit kohlenstoff |
FR2731106A1 (fr) | 1995-02-27 | 1996-08-30 | Schneider Electric Sa | Procede de fabrication d'un materiau de contact electrique composite |
FR2803686B1 (fr) | 2000-01-07 | 2002-02-22 | Schneider Electric Ind Sa | Pole pour disjoncteur electrique, muni d'une chambre d'extinction d'arc a ecrans dielectriques |
FR2823904B1 (fr) | 2001-04-19 | 2003-06-06 | Schneider Electric Ind Sa | Diffuseur monobloc pour un appareillage electrique de coupure |
US20050153160A1 (en) | 2004-01-12 | 2005-07-14 | Yourong Liu | Durable thermal barrier coating having low thermal conductivity |
-
2004
- 2004-11-08 FR FR0411869A patent/FR2877763B1/fr active Active
-
2005
- 2005-10-11 ES ES05354035T patent/ES2297652T3/es active Active
- 2005-10-11 DE DE602005003537T patent/DE602005003537T2/de active Active
- 2005-10-11 EP EP05354035A patent/EP1655749B1/fr active Active
- 2005-11-01 US US11/262,984 patent/US7598832B2/en active Active
- 2005-11-04 CN CN2005101201210A patent/CN1773647B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN1773647A (zh) | 2006-05-17 |
ES2297652T3 (es) | 2008-05-01 |
US20060096846A1 (en) | 2006-05-11 |
FR2877763B1 (fr) | 2007-03-16 |
US7598832B2 (en) | 2009-10-06 |
DE602005003537T2 (de) | 2008-10-23 |
FR2877763A1 (fr) | 2006-05-12 |
EP1655749A1 (fr) | 2006-05-10 |
CN1773647B (zh) | 2011-09-21 |
DE602005003537D1 (de) | 2008-01-10 |
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