EP1655749B1 - Contact pastille for a movable electrical contact of a circuit breaker, movable electrical contact with such a pastille and circuit breaker with such a contact - Google Patents

Contact pastille for a movable electrical contact of a circuit breaker, movable electrical contact with such a pastille and circuit breaker with such a contact Download PDF

Info

Publication number
EP1655749B1
EP1655749B1 EP05354035A EP05354035A EP1655749B1 EP 1655749 B1 EP1655749 B1 EP 1655749B1 EP 05354035 A EP05354035 A EP 05354035A EP 05354035 A EP05354035 A EP 05354035A EP 1655749 B1 EP1655749 B1 EP 1655749B1
Authority
EP
European Patent Office
Prior art keywords
contact
circuit breaker
contact pad
silver
movable contact
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP05354035A
Other languages
German (de)
French (fr)
Other versions
EP1655749A1 (en
Inventor
Marc Rival
Guy Gastaldin
Jean-Paul Favre-Tissot
Franck Pizot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Schneider Electric Industries SAS
Original Assignee
Schneider Electric Industries SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Schneider Electric Industries SAS filed Critical Schneider Electric Industries SAS
Publication of EP1655749A1 publication Critical patent/EP1655749A1/en
Application granted granted Critical
Publication of EP1655749B1 publication Critical patent/EP1655749B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/021Composite material
    • H01H1/027Composite material containing carbon particles or fibres
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/021Composite material
    • H01H1/023Composite material having a noble metal as the basic material
    • H01H1/0233Composite material having a noble metal as the basic material and containing carbides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/021Composite material
    • H01H1/025Composite material having copper as the basic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H3/00Mechanisms for operating contacts
    • H01H3/22Power arrangements internal to the switch for operating the driving mechanism
    • H01H3/30Power arrangements internal to the switch for operating the driving mechanism using spring motor

Definitions

  • the invention relates to a contact pad intended to be fixed on a low voltage circuit breaker movable contact intended to withstand short-circuit peak currents of between 200 and 600 amperes per square millimeter of pellet.
  • the pellet consists of an alloy of conducting material based on silver or copper, a fraction of refractory particles such as tungsten carbide, tungsten or titanium nitride and a fraction of carbon fibers.
  • Solutions include adding at the surface or contact area composite materials in the form of pellets of different thicknesses and different materials.
  • the pellets are usually made of silver or copper alloy. They are made in the usual manner by sintering a powder composed of a silver-based alloy, in particular silver and tungsten or silver and nickel. These contact materials have a high electrical conductivity, a high sufficient resistance to oxidation and good properties with regard to contact resistance.
  • the known silver-based contact materials show an undesirable tendency to weld. In addition, they tend to cause adhesion of the contact surfaces and / or migration of material between the contact elements. Finally, their use is generally associated with excessive wear of the contacts.
  • Carbon, in the form of fibers, can also be added to the alloy powder (document US4699763 ).
  • the resistance to erosion is then improved, but this improvement is achieved at the cost of an alteration of the behavior of the contact at the weld.
  • the carbon fibers are mixed with the metal powder with a wetting agent, lubricant and wet solvent, followed by drying, compression and sintering.
  • the disadvantage of such a method is that it involves complications inherent to a wet process.
  • EP0729162 is described a method of manufacturing powder-based electrical contacts of a good electrically conductive metal such as silver and crushed carbon fibers of average length less than 20 .mu.m.
  • a good electrically conductive metal such as silver and crushed carbon fibers of average length less than 20 .mu.m.
  • the contact surface keeps, after cutting under a short-circuit current, its fine, homogeneous and isotropic structure of fiber residues of variable length and any orientation in the matrix of money.
  • the weight proportions of crushed carbon fiber residues are between 2 and 5% with the silver powder.
  • the material thus obtained shows a low post contact resistance, good anti-weld qualities and acceptable erosion resistance.
  • the invention therefore aims to overcome the disadvantages of the state of the art, so as to provide a contact pad having a low contact resistance post cut, high erosion resistance and good anti-welding properties.
  • a contact pad according to the invention comprises a weight percentage of carbon fibers in the pellet strictly less than 2% of the total mass of said contact patch.
  • the weight percentage of carbon fibers in the contact pad is between 0.5% and 1.9% of the total mass of said contact pad.
  • the carbon fibers are crushed fibers with a length of less than 20 ⁇ m.
  • the carbon fibers consist of carbonized fibers containing at least 90% carbon, less than 10% nitrogen, substantially 1% oxygen and less than 1% hydrogen.
  • the contact patch is composed of 79% of the silver alloy, 20% of tungsten carbide (CW) and 1% of carbon fiber.
  • a mobile circuit breaker contact according to a development mode of the invention comprises a movable contact finger connected to a contact pad as defined above, the chip being connected to the movable contact finger via a thin layer of conductive material based on silver alloy.
  • the contact pad 3 is intended to be fixed on a moving contact 2 low-voltage circuit breaker 1 for supporting short-circuit currents of several kilo amperes.
  • a contact pad 3 according to the invention is intended to withstand short-circuit peak currents of between 200 and 600 amperes per square millimeter of pellet.
  • the contact pad 3 is composed of a conductive material such as silver (Ag) or copper (Cu) in which is inserted a fraction of carbon fibers and a fraction of refractory particles such as for example carbide tungsten (WC), tungsten (W), titanium nitride (TiN). These refractory particles have an average diameter of 1 to 10 microns.
  • a conductive material such as silver (Ag) or copper (Cu) in which is inserted a fraction of carbon fibers and a fraction of refractory particles such as for example carbide tungsten (WC), tungsten (W), titanium nitride (TiN). These refractory particles have an average diameter of 1 to 10 microns.
  • the carbon fibers consist of carbonized fibers containing at least 90% carbon, less than 10% nitrogen, substantially 1% oxygen and less than 1% hydrogen.
  • carbon fibers with an average length L1 of between approximately 100 ⁇ m and 800 ⁇ m and a diameter of between 4 and 20 ⁇ m are chosen. These fibers undergo a cold and dry mechanical treatment in a mechanical grinder. The conditions of intensity and duration of grinding make it possible to obtain fibers the length of which is statistically distributed around a mean value which is much lower than the initial average value. From the initial fibers, crushed fiber residues having an average length of less than 20 ⁇ m are thus obtained. The crushed fibers are then added to the conductive material containing the refractory fractions. The powder mixture of conductive material and the crushed carbon fibers is carried out dry in a mechanical mixer until a homogeneous mixture is obtained. Said mixture then undergoes a unitary compression and a sintering so as to obtain an isotropic material structure
  • the weight percentage of carbon fibers in the pellet is strictly less than 2%. It is preferably between 0.5% and 1.9% of the total mass of the pellet.
  • an ideal compromise in the choice of the proportions of materials for this type of application consists in using a pellet comprising 79% silver (Ag), 20% tungsten carbide (CW) and 1% of crushed carbon fibers.
  • this material having an appropriate homogeneous structure shows a low and stable post-cut contact resistance as well as a good resistance to erosion under a short circuit of several tens of kiloamperes.
  • this material develops anti-welding characteristics with respect to the steel balls present in the environment during the cut especially in the electric arc column.
  • An explosive phenomenon due to the degradation of the carbon fiber explains the anti-adhesion characteristics of this material with respect to molten steel balls.
  • a movable contact 2 circuit breaker 1 comprising a movable contact finger moving relative to a fixed contact 4 of the circuit breaker, has a contact pad 3 as defined above.
  • Said contact pad is connected to the movable contact finger by means of a thin layer of conductive material based on silver or a mixture of copper and silver. This intermediate layer makes it possible to block the propagation of cracks in the interface zone between the contact pad 3 and the finger.
  • a circuit breaker 1 comprising an opening mechanism 6 acting on at least one electric moving contact 2 as defined above.
  • Said at least one moving contact 2 is placed opposite a fixed contact 4.
  • Said fixed contact is made of an alloy, generally comprising a silver metal matrix in which a fraction of particles of graphite powder is inserted. Said fraction of particles constitutes 3 to 5% of the mass of the alloy.
  • the alloy may also comprise a certain amount of refractory elements (W, WC, Ni) of between 2 and 30% of the total mass.
  • the circuit breaker 1 according to a particular embodiment, is intended to accept nominal currents of 1600 amps and short-term currents of 42000 amps for one second.
  • the breaking chambers 10 comprise, by pole, five movable contacts 2 associated with a fixed contact area 4.
  • Filtering means 5 placed on the walls of the breaking chambers 10 are intended to strongly attenuate external manifestations of the gases present in said rooms at the time of opening contacts.
  • the filtering means 5 comprise filters having characteristics specific techniques as described in the applicant's patents ( EP-A-1115132 , EP-A-1251533 ).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Contacts (AREA)

Description

DOMAINE TECHNIQUE DE L'INVENTIONTECHNICAL FIELD OF THE INVENTION

L'invention est relative à une pastille de contact destinée à être fixée sur un contact mobile de disjoncteur basse tension destiné à supporter des courants crêtes de court-circuit compris entre 200 et 600 ampères par millimètre carré de pastille. La pastille est constituée d'un alliage de matériau conducteur à base d'argent ou de cuivre, d'une fraction de particules réfractaires telles que du carbure de tungstène, du tungstène ou du nitrure de titane et d'une fraction de fibres de carboneThe invention relates to a contact pad intended to be fixed on a low voltage circuit breaker movable contact intended to withstand short-circuit peak currents of between 200 and 600 amperes per square millimeter of pellet. The pellet consists of an alloy of conducting material based on silver or copper, a fraction of refractory particles such as tungsten carbide, tungsten or titanium nitride and a fraction of carbon fibers.

ETAT DE LA TECHNIQUESTATE OF THE ART

La présence de défauts électriques à l'intérieur de dispositifs de coupure tel que des disjoncteurs électriques provoque une brusque ouverture de leurs contacts électriques. Cette ouverture rapide est généralement accompagnée d'arcs électriques donnant naissance à des contraintes importantes au niveau desdits contacts, plus particulièrement au niveau de leurs surfaces ou zones de contact.The presence of electrical faults within cut-off devices such as electrical circuit breakers causes their electrical contacts to open abruptly. This rapid opening is generally accompanied by electric arcs giving rise to significant stresses at said contacts, more particularly at their surfaces or contact areas.

Afin d'augmenter la longévité des contacts électriques utilisés dans de tels dispositifs, il est connu de modifier la structure de la surface ou zone de contact des contacts électriques. Des solutions consistent à ajouter au niveau de la surface ou zone de contact des matériaux composites sous la forme de pastilles de différentes épaisseurs et de différents matériaux.In order to increase the life of the electrical contacts used in such devices, it is known to modify the structure of the surface or contact area of the electrical contacts. Solutions include adding at the surface or contact area composite materials in the form of pellets of different thicknesses and different materials.

Les pastilles sont généralement en alliage d'argent ou de cuivre. Elles sont réalisées de manière usuelle par frittage d'une poudre composée d'un alliage à base d'argent, notamment argent et tungstène ou argent et nickel. Ces matériaux de contact présentent une conductibilité électrique élevée, une résistance suffisante à l'oxydation et de bonnes propriétés en ce qui concerne la résistance de contact.The pellets are usually made of silver or copper alloy. They are made in the usual manner by sintering a powder composed of a silver-based alloy, in particular silver and tungsten or silver and nickel. These contact materials have a high electrical conductivity, a high sufficient resistance to oxidation and good properties with regard to contact resistance.

Cependant, les matériaux de contact connus à base d'argent montrent une tendance indésirable à la soudure. En outre, ils ont tendance à provoquer l'adhérence des surfaces de contact ou/et une migration de matière entre les éléments de contact. Enfin, leur utilisation est généralement associée à une usure trop important des contacts.However, the known silver-based contact materials show an undesirable tendency to weld. In addition, they tend to cause adhesion of the contact surfaces and / or migration of material between the contact elements. Finally, their use is generally associated with excessive wear of the contacts.

De nombreuses solutions consistent à ajouter à la poudre d'alliage un matériau conducteur tel que du graphite. De tels matériaux sont couramment utilisés pour réaliser les pastilles de contact des disjoncteurs. Le graphite présent dans la matrice métallique permet de réduire le risque de soudure des contacts. Toutefois, la présence du graphite entraîne une érosion mécanique accrue de la pastille.Many solutions consist in adding to the alloy powder a conductive material such as graphite. Such materials are commonly used to make the contact pads of the circuit breakers. The graphite present in the metal matrix makes it possible to reduce the risk of welding of the contacts. However, the presence of graphite causes increased mechanical erosion of the pellet.

Du carbone, sous forme de fibres peut être aussi apporté à la poudre d'alliage (document US4699763 ). La résistance à l'érosion est alors améliorée, mais cette amélioration est acquise au prix d'une altération du comportement du contact à la soudure. Les fibres de carbone sont mélangées à la poudre métallique avec un apport d'agent mouillant, lubrifiant et solvant par voie humide, puis on effectue un séchage, une compression et un frittage. L'inconvénient d'un tel procédé est qu'il implique des complications inhérentes à un processus conduit en voie humide.Carbon, in the form of fibers, can also be added to the alloy powder (document US4699763 ). The resistance to erosion is then improved, but this improvement is achieved at the cost of an alteration of the behavior of the contact at the weld. The carbon fibers are mixed with the metal powder with a wetting agent, lubricant and wet solvent, followed by drying, compression and sintering. The disadvantage of such a method is that it involves complications inherent to a wet process.

Pour trouver un compromis acceptable entre le comportement du matériau à l'érosion et son comportement anti-soudure, il est proposé d'après le document DE4111683 de mélanger des particules de graphite à des fibres de carbone, ce mélange étant incorporé à la poudre métallique. Cet apport hybride de carbone dans la matrice métallique, permet d'obtenir des comportements du matériau à l'érosion et à la soudure intermédiaires entre ceux qu'il aurait montrés avec un apport de particules de graphite seules ou avec un apport de fibres de carbone seules. Mais il s'avère que, sous de fortes sollicitations et en particulier sous de forts courants de court-circuit, les particules de graphite, de part leur parfaite structure cristalline, montrent une tendance à être expulsées de la surface du matériau. Cette expulsion détériore la surface du matériau d'une manière telle que les fibres de carbone en sont également expulsées à leur tour. Il en résulte un enrichissement de la surface en argent et donc une altération des qualités initialement recherchées par l'apport de graphite.To find an acceptable compromise between the behavior of the material with erosion and its anti-welding behavior, it is proposed according to the document DE4111683 mixing graphite particles with carbon fibers, this mixture being incorporated into the metal powder. This hybrid carbon contribution in the metal matrix makes it possible to obtain intermediate erosion and solder behaviors between those which it would have shown with a contribution of graphite particles alone or with a contribution of carbon fibers. alone. But it turns out that, under heavy loads and in particular under strong short-circuit currents, the graphite particles, because of their perfect crystalline structure, show a tendency to be expelled from the surface. of the material. This expulsion deteriorates the surface of the material in such a way that the carbon fibers are also expelled in turn. This results in an enrichment of the silver surface and thus an alteration of the qualities initially sought by the contribution of graphite.

Dans le document EP0171339 est décrit un procédé de fabrication de contacts électriques par imprégnation d'un substrat de fibres de carbone par un métal liquide sous pression, puis par filage à chaud du mélange ainsi obtenu. On constate que les contacts résultants montrent une trop forte propension au soudage.In the document EP0171339 is described a method of manufacturing electrical contacts by impregnating a carbon fiber substrate with a pressurized liquid metal and then hot-spinning the mixture thus obtained. It can be seen that the resulting contacts show an excessive propensity for welding.

Dans le document EP0729162 est décrit un procédé de fabrication de contacts électriques à base de poudre d'un métal bon conducteur électrique tel que l'argent et de fibres de carbone broyées de longueur moyenne inférieure à 20µm. Dans des applications courantes de coupure, on constate que la surface de contact garde, après coupure sous un courant de court-circuit, sa structure fine, homogène et isotrope de résidus de fibres de longueur variable et d'orientation quelconque dans la matrice d'argent. Les proportions pondérales de résidus de fibre de carbone broyées sont comprises entre 2 à 5% avec la poudre d'argent. Pour des disjoncteurs limiteurs utilisés pour des applications dans lesquelles l'arc stagne peu sur les contacts, le matériau ainsi obtenu montre une résistance de contact après coupure faible, de bonnes qualités d'anti-soudure et une résistance à l'érosion acceptable. Cependant, l'utilisation de ce matériau trouve ses limites dans des applications pour lesquelles on est présence de disjoncteurs sélectifs où le courant de défaut apparaissant sur les pastilles, a la valeur du courant présumé de court-circuit ; soit plusieurs dizaines de kilo ampères. La robustesse à l'érosion des pastilles de contact décrites ci-dessus n'est plus suffisante et des micro-soudures sont observées lors de passage de courant de plusieurs dizaines de kilo ampères pendant 1 seconde sans ouverture de l'appareil.In the document EP0729162 is described a method of manufacturing powder-based electrical contacts of a good electrically conductive metal such as silver and crushed carbon fibers of average length less than 20 .mu.m. In common breaking applications, it is found that the contact surface keeps, after cutting under a short-circuit current, its fine, homogeneous and isotropic structure of fiber residues of variable length and any orientation in the matrix of money. The weight proportions of crushed carbon fiber residues are between 2 and 5% with the silver powder. For limiting circuit breakers used for applications in which the arc stagnates little on the contacts, the material thus obtained shows a low post contact resistance, good anti-weld qualities and acceptable erosion resistance. However, the use of this material finds its limits in applications for which there is presence of selective circuit breakers where the fault current appearing on the chips, has the value of the presumed short-circuit current; that's several tens of kilo amps. The erosion resistance of the contact pads described above is no longer sufficient and micro-welds are observed when current passes several tens of kilo amperes for 1 second without opening the device.

Par ailleurs, lorsque la taille de ce type de disjoncteur est miniaturisée et lorsque l'adjonction d'éléments filtrants réduit de manière drastique les manifestations extérieures, le choix optimum de matériau de contact est encore plus draconien. En effet, l'énergie de coupure similaire à celle dégagée dans les disjoncteurs classiques doit être absorbée dans un volume miniaturisé et quasiment clos. Il s'ensuit un dépôt important de polluants sur les contacts. Ce dépôt est constitué en particulier d'acier fondu issu de l'ablation des ailettes de la chambre d'extinction d'arc.Moreover, when the size of this type of circuit breaker is miniaturized and when the addition of filter elements drastically reduces the external manifestations, the optimum choice of contact material is even more draconian. Indeed, the cutoff energy similar to that released in conventional circuit breakers must be absorbed in a miniaturized volume and almost closed. This results in a large deposit of pollutants on the contacts. This deposit consists in particular of molten steel resulting from the ablation of the fins of the arc extinction chamber.

EXPOSE DE L'INVENTIONSUMMARY OF THE INVENTION

L'invention vise donc à remédier aux inconvénients de l'état de la technique, de manière à proposer une pastille de contact ayant une faible résistance de contact post coupure, une forte résistance à l'érosion et de bonnes propriétés anti-soudure.The invention therefore aims to overcome the disadvantages of the state of the art, so as to provide a contact pad having a low contact resistance post cut, high erosion resistance and good anti-welding properties.

Une pastille de contact selon l'invention comprend un pourcentage pondéral de fibres de carbone dans la pastille strictement inférieur à 2% de la masse totale de ladite pastille de contactA contact pad according to the invention comprises a weight percentage of carbon fibers in the pellet strictly less than 2% of the total mass of said contact patch.

Le pourcentage pondéral de fibres de carbone dans la pastille de contact est compris entre 0,5% et 1.9% de la masse totale de ladite pastille de contact.The weight percentage of carbon fibers in the contact pad is between 0.5% and 1.9% of the total mass of said contact pad.

Avantageusement, les fibres de carbone sont des fibres broyées de longueur inférieure à 20 µm.Advantageously, the carbon fibers are crushed fibers with a length of less than 20 μm.

De préférence, les fibres de carbones sont constituées de fibres carbonisées contenant au moins 90% de carbone, moins de 10% d'azote, sensiblement 1 % d'oxygène et moins de 1 % d'hydrogène.Preferably, the carbon fibers consist of carbonized fibers containing at least 90% carbon, less than 10% nitrogen, substantially 1% oxygen and less than 1% hydrogen.

Selon un mode de développement de l'invention, la pastille de contact est composée de 79% de l'alliage d'argent, de 20% de carbure de tungstène (CW) et de 1 % de fibre de carbone.According to one embodiment of the invention, the contact patch is composed of 79% of the silver alloy, 20% of tungsten carbide (CW) and 1% of carbon fiber.

Un contact mobile de disjoncteur selon un mode développement de l'invention, comprend un doigt de contact mobile relié à une pastille de contact telle que définie ci-dessus, la pastille étant reliée au doigt de contact mobile par l'intermédiaire d'une fine couche de matériau conducteur à base d'alliage d'argent.A mobile circuit breaker contact according to a development mode of the invention comprises a movable contact finger connected to a contact pad as defined above, the chip being connected to the movable contact finger via a thin layer of conductive material based on silver alloy.

Un disjoncteur selon un mode développement de l'invention comprend une chambre de coupure comportant des moyens de filtrage destinés à atténuer des manifestations extérieures des gaz présents dans la chambre de coupure au moment des ouvertures, et comprend un mécanisme d'ouverture agissant sur au moins un contact mobile tel que défini ci-dessus et placé en vis à vis d'un contact fixe, lesdits contacts étant placés dans la chambre de coupure.A circuit breaker according to a development mode of the invention comprises an interrupting chamber comprising filtering means intended to attenuate external manifestations of the gases present in the breaking chamber at the time of the openings, and comprises an opening mechanism acting on at least a movable contact as defined above and placed opposite a fixed contact, said contacts being placed in the interrupting chamber.

BREVE DESCRIPTION DES FIGURESBRIEF DESCRIPTION OF THE FIGURES

D'autres avantages et caractéristiques ressortiront plus clairement de la description qui va suivre d'un mode particulier de réalisation de l'invention, donné à titre d'exemple non limitatif, et représenté au dessin annexé sur lequel :

  • la figure 1 représente une vue en coupe d'un disjoncteur comportant un contact mobile possédant une pastille de contact selon un mode de réalisation de l'invention.
Other advantages and features will emerge more clearly from the following description of a particular embodiment of the invention, given by way of non-limiting example, and represented in the accompanying drawing in which:
  • Figure 1 shows a sectional view of a circuit breaker having a movable contact having a contact pad according to one embodiment of the invention.

DESCRIPTION DETAILLEE D'UN MODE DE REALISATIONDETAILED DESCRIPTION OF AN EMBODIMENT

Selon le mode de réalisation préféré de l'invention, la pastille de contact 3 est destinée à être fixée sur un contact mobile 2 de disjoncteur basse-tension 1 destiné à supporter des courants de court-circuit de plusieurs kilo ampères. En exprimant la densité de courant électrique en ampères par unité de surface de pastille, une pastille de contact 3 selon l'invention est destinée à supporter des courants crêtes de court-circuit compris entre 200 et 600 ampères par millimètre carré de pastille.According to the preferred embodiment of the invention, the contact pad 3 is intended to be fixed on a moving contact 2 low-voltage circuit breaker 1 for supporting short-circuit currents of several kilo amperes. By expressing the electrical current density in amperes per pellet surface unit, a contact pad 3 according to the invention is intended to withstand short-circuit peak currents of between 200 and 600 amperes per square millimeter of pellet.

Les effets engendrés par le passage de ces forts courants de court-circuit se font encore plus ressentir lorsque l'énergie de coupure est absorbée dans une chambre de coupure 10 ayant un volume interne miniaturisé et quasiment clos ou étanche.The effects generated by the passage of these strong short-circuit currents are even more felt when the cut-off energy is absorbed in a breaking chamber 10 having a miniaturized internal volume and almost closed or sealed.

La pastille de contact 3 est composée d'un matériau conducteur tel que l'argent (Ag) ou le cuivre (Cu) dans lequel est insérée une fraction de fibres de carbone et une fraction de particules réfractaires telle que par exemple du carbure de tungstène (WC), du tungstène (W), du nitrure de titane (TiN). Ces particules réfractaires possèdent un diamètre moyen de 1 à 10 microns.The contact pad 3 is composed of a conductive material such as silver (Ag) or copper (Cu) in which is inserted a fraction of carbon fibers and a fraction of refractory particles such as for example carbide tungsten (WC), tungsten (W), titanium nitride (TiN). These refractory particles have an average diameter of 1 to 10 microns.

Les fibres de carbone sont constituées de fibres carbonisées contenant au moins 90% de carbone, moins de 10% d'azote, sensiblement 1% d'oxygène et moins de 1 % d'hydrogène.The carbon fibers consist of carbonized fibers containing at least 90% carbon, less than 10% nitrogen, substantially 1% oxygen and less than 1% hydrogen.

Dans le mode de réalisation présenté, on choisit des fibres de carbone de longueur moyenne L1 comprise entre environ 100µm et 800µm et de diamètre compris entre 4 et 20µm. Ces fibres subissent un traitement mécanique à froid et à sec dans un broyeur mécanique. Les conditions d'intensité et de durée du broyage permettent d'obtenir des fibres dont la longueur est répartie statistiquement autour d'une valeur moyenne très inférieure à la valeur moyenne initiale. On obtient ainsi à partir des fibres initiales des résidus de fibres broyées ayant une longueur moyenne inférieure à 20µm. Les fibres broyées sont ensuite ajoutées au matériau conducteur contenant les fractions réfractaires. Le mélange de poudre de matériau conducteur aux fibres de carbone broyées s'effectue par voie sèche dans un mélangeur mécanique jusqu'à obtenir un mélange homogène. Ledit mélange subit ensuite une compression unitaire et un frittage de manière à obtenir une structure de matériau isotropeIn the embodiment shown, carbon fibers with an average length L1 of between approximately 100 μm and 800 μm and a diameter of between 4 and 20 μm are chosen. These fibers undergo a cold and dry mechanical treatment in a mechanical grinder. The conditions of intensity and duration of grinding make it possible to obtain fibers the length of which is statistically distributed around a mean value which is much lower than the initial average value. From the initial fibers, crushed fiber residues having an average length of less than 20 μm are thus obtained. The crushed fibers are then added to the conductive material containing the refractory fractions. The powder mixture of conductive material and the crushed carbon fibers is carried out dry in a mechanical mixer until a homogeneous mixture is obtained. Said mixture then undergoes a unitary compression and a sintering so as to obtain an isotropic material structure

Un tel procédé de fabrication est décrit en détail dans le document EP-B-0729162 , dont la description est sur ces points incorporée ici par référence.Such a manufacturing process is described in detail in the document EP-B-0729162 , whose description is on these points incorporated herein by reference.

Dans le but de résister aux contraintes spécifiques observées dans les disjoncteurs sélectifs capables de supporter des courants dans les conditions décrites ci-dessus, il est nécessaire d'augmenter la résistance à l'érosion de la pastille ainsi obtenue. Pour ce faire, le pourcentage pondéral de fibres de carbone dans la pastille est strictement inférieur à 2%. Il est compris de préférence entre 0,5% et 1,9% de la masse totale de la pastille.In order to resist the specific stresses observed in selective circuit breakers capable of withstanding currents under the conditions described above, it is necessary to increase the erosion resistance of the pellet thus obtained. To do this, the weight percentage of carbon fibers in the pellet is strictly less than 2%. It is preferably between 0.5% and 1.9% of the total mass of the pellet.

Dans un exemple d'application de l'invention, un compromis idéal dans le choix des proportions des matériaux pour ce type d'application, consiste à utiliser une pastille comprenant 79% d'argent (Ag), 20% de carbure de tungstène (CW) et 1 % de fibres broyées de carbone.In an exemplary application of the invention, an ideal compromise in the choice of the proportions of materials for this type of application consists in using a pellet comprising 79% silver (Ag), 20% tungsten carbide ( CW) and 1% of crushed carbon fibers.

Finalement, ce matériau ayant structure homogène appropriée, montre une résistance de contact post coupure faible et stable ainsi qu'une bonne résistance à l'érosion sous court-circuit de plusieurs dizaines de kilo ampères. En outre, ce matériau développe des caractéristiques anti-soudure vis à vis des billes en acier présentes dans l'environnement lors de la coupure notamment dans la colonne d'arc électrique. Un phénomène explosif du à la dégradation de la fibre de carbone explique les caractéristiques anti-adhésion de ce matériau vis à vis des billes d'acier en fusion.Finally, this material having an appropriate homogeneous structure shows a low and stable post-cut contact resistance as well as a good resistance to erosion under a short circuit of several tens of kiloamperes. In addition, this material develops anti-welding characteristics with respect to the steel balls present in the environment during the cut especially in the electric arc column. An explosive phenomenon due to the degradation of the carbon fiber explains the anti-adhesion characteristics of this material with respect to molten steel balls.

Un contact mobile 2 de disjoncteur 1 comprenant un doigt de contact mobile se déplaçant par rapport à un contact fixe 4 du disjoncteur, possède une pastille de contact 3 tel que défini ci-dessus. Ladite pastille de contact est reliée au doigt de contact mobile par l'intermédiaire d'une fine couche de matériau conducteur à base d'argent ou d'un mélange de cuivre et d'argent. Cette couche intermédiaire permet de bloquer la propagation des fissures dans la zone d'interface entre la pastille de contact 3 et le doigt.A movable contact 2 circuit breaker 1 comprising a movable contact finger moving relative to a fixed contact 4 of the circuit breaker, has a contact pad 3 as defined above. Said contact pad is connected to the movable contact finger by means of a thin layer of conductive material based on silver or a mixture of copper and silver. This intermediate layer makes it possible to block the propagation of cracks in the interface zone between the contact pad 3 and the finger.

Un disjoncteur 1 comprenant un mécanisme d'ouverture 6 agissant sur au moins un contact mobile électrique 2 tel que défini ci-dessus. Ledit au moins un contact mobile 2 est placé en vis à vis d'un contact fixe 4. Ledit contact fixe est constitué d'un alliage, comportant généralement une matrice métallique d'argent où est insérée une fraction de particules de poudre de graphite. Ladite fraction de particules constitue 3 à 5 % de la masse de l'alliage. L'alliage peut également comprendre une certaine quantité d'éléments réfractaires (W ,WC, Ni) comprise entre 2 et 30% de la masse totale. Le disjoncteur 1 selon un mode particulier de réalisation, est destiné à accepter des courants nominaux de 1600 ampères et des courants de courte durée de 42000 ampères pendant une seconde. Les chambres de coupures 10 comportent, par pole, cinq contacts mobiles 2 associés à une plage de contacts fixes 4. Des moyens de filtrage 5 placés sur les parois des chambres de coupure 10 sont destinés à atténuer fortement des manifestations extérieures des gaz présents dans lesdites chambres au moment des ouvertures des contacts. A titre d'exemple non limitatif, les moyens de filtrage 5 comprennent des filtres possédant des caractéristiques techniques spécifiques telles que décrites dans les brevets de la demanderesse ( EP-A-1115132 , EP-A-1251533 ).A circuit breaker 1 comprising an opening mechanism 6 acting on at least one electric moving contact 2 as defined above. Said at least one moving contact 2 is placed opposite a fixed contact 4. Said fixed contact is made of an alloy, generally comprising a silver metal matrix in which a fraction of particles of graphite powder is inserted. Said fraction of particles constitutes 3 to 5% of the mass of the alloy. The alloy may also comprise a certain amount of refractory elements (W, WC, Ni) of between 2 and 30% of the total mass. The circuit breaker 1 according to a particular embodiment, is intended to accept nominal currents of 1600 amps and short-term currents of 42000 amps for one second. The breaking chambers 10 comprise, by pole, five movable contacts 2 associated with a fixed contact area 4. Filtering means 5 placed on the walls of the breaking chambers 10 are intended to strongly attenuate external manifestations of the gases present in said rooms at the time of opening contacts. By way of non-limiting example, the filtering means 5 comprise filters having characteristics specific techniques as described in the applicant's patents ( EP-A-1115132 , EP-A-1251533 ).

Claims (5)

  1. A contact pad (3) designed to be fixed onto a movable contact (2) of a low-voltage circuit breaker (1) designed to withstand peak short-circuit currents comprised between 200 and 600 amperes per square millimeter of pad, formed by an alloy of silver (Ag) or copper (Cu) based conducting material, a fraction of refractory particles such as tungsten carbide (CW), tungsten (W) or titanium nitride (TiN), and a fraction of carbon fibres, characterized in that the weight percentage of carbon fibres in the contact pad (3) is strictly less than 2% of the total weight of said contact pad, the carbon fibres being crushed fibres with a mean length of less than 20 µm and containing at least 90% of carbon, less than 10% of nitrogen, substantially 1% of oxygen and less than 1% of hydrogen.
  2. The contact pad (3) according to claim 1 characterized in that the weight percentage of carbon fibres in the contact pad (3) is comprised between 0.5% and 1.9% of the total weight of said contact pad.
  3. The contact pad (3) according to one of the foregoing claims characterized in that it is composed of 79% of silver, 20% of tungsten carbide (CW) and 1% of carbon fibre.
  4. A movable contact (2) of a circuit breaker (1) comprising a movable contact finger characterized in that a contact pad (3) according to the foregoing claims is connected to the movable contact finger by means of a thin layer of conducting material the base whereof is silver or a mixture of copper and silver.
  5. A circuit breaker (1) comprising an arc chute (10) comprising filtering means (5) designed to attenuate external manifestations of the gases present in the arc chute when openings take place, an opening mechanism (6) acting on at least one movable contact (2), characterized in that said movable contact (2) is a contact according to claim 6 placed facing a stationary contact (4), said contacts being placed in the arc chute.
EP05354035A 2004-11-08 2005-10-11 Contact pastille for a movable electrical contact of a circuit breaker, movable electrical contact with such a pastille and circuit breaker with such a contact Active EP1655749B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0411869A FR2877763B1 (en) 2004-11-08 2004-11-08 CONTACT BAG FOR A MOBILE ELECTRIC CONTACT OF A CIRCUIT BREAKER, MOBILE ELECTRICAL CONTACT HAVING SUCH A PASTILLE AND CIRCUIT BREAKER COMPRISING SUCH A CONTACT

Publications (2)

Publication Number Publication Date
EP1655749A1 EP1655749A1 (en) 2006-05-10
EP1655749B1 true EP1655749B1 (en) 2007-11-28

Family

ID=34950471

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05354035A Active EP1655749B1 (en) 2004-11-08 2005-10-11 Contact pastille for a movable electrical contact of a circuit breaker, movable electrical contact with such a pastille and circuit breaker with such a contact

Country Status (6)

Country Link
US (1) US7598832B2 (en)
EP (1) EP1655749B1 (en)
CN (1) CN1773647B (en)
DE (1) DE602005003537T2 (en)
ES (1) ES2297652T3 (en)
FR (1) FR2877763B1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009018035A1 (en) * 2009-04-18 2010-10-28 Moeller Gmbh Contact arrangement for low-voltage applications
IN2013CH05861A (en) * 2013-12-16 2015-06-19 Gen Electric
CN104532050A (en) * 2015-01-15 2015-04-22 潍坊学院 Titanium nitride reinforced sliver base contact material and preparation method thereof
FR3036841B1 (en) * 2015-05-28 2017-06-23 Schneider Electric Ind Sas MOBILE POLE AND CUTTING APPARATUS
US11798751B2 (en) * 2021-06-30 2023-10-24 Siemens Industry, Inc. Metal contact of a residential circuit breaker including ordered ceramic microparticles

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2057618A1 (en) * 1970-11-24 1972-06-15 Duerrwaechter E Dr Doduco Metal-carbon composite and process for its manufacture
FR2568417B1 (en) 1984-07-25 1986-11-28 Lorraine Carbone METHOD FOR MANUFACTURING ELECTRICAL CONTACTS AND CONTACTS OBTAINED.
US4689196A (en) * 1985-06-24 1987-08-25 Gte Products Corporation Silver-tungsten carbide-graphite electrical contact
US4699763A (en) * 1986-06-25 1987-10-13 Westinghouse Electric Corp. Circuit breaker contact containing silver and graphite fibers
US5199553A (en) * 1990-10-09 1993-04-06 Fuji Electric Co., Ltd. Sliding contactor for electric equipment
DE4111683A1 (en) * 1991-04-10 1992-10-22 Duerrwaechter E Dr Doduco MATERIAL FOR ELECTRICAL CONTACTS MADE OF SILVER WITH CARBON
FR2731106A1 (en) 1995-02-27 1996-08-30 Schneider Electric Sa METHOD FOR MANUFACTURING COMPOSITE ELECTRIC CONTACT MATERIAL
FR2803686B1 (en) 2000-01-07 2002-02-22 Schneider Electric Ind Sa POLE FOR ELECTRIC CIRCUIT BREAKER, PROVIDED WITH AN ARC EXTINGUISHING CHAMBER WITH DIELECTRIC SHIELDS
FR2823904B1 (en) 2001-04-19 2003-06-06 Schneider Electric Ind Sa MONOBLOCK DIFFUSER FOR ELECTRICAL SWITCHING APPARATUS
US20050153160A1 (en) 2004-01-12 2005-07-14 Yourong Liu Durable thermal barrier coating having low thermal conductivity

Also Published As

Publication number Publication date
CN1773647A (en) 2006-05-17
ES2297652T3 (en) 2008-05-01
US20060096846A1 (en) 2006-05-11
FR2877763B1 (en) 2007-03-16
US7598832B2 (en) 2009-10-06
DE602005003537T2 (en) 2008-10-23
FR2877763A1 (en) 2006-05-12
EP1655749A1 (en) 2006-05-10
CN1773647B (en) 2011-09-21
DE602005003537D1 (en) 2008-01-10

Similar Documents

Publication Publication Date Title
EP1655749B1 (en) Contact pastille for a movable electrical contact of a circuit breaker, movable electrical contact with such a pastille and circuit breaker with such a contact
EP0370897B1 (en) Method for the preparation of electrical contact material, and method of making a contact element incorporating such a material
EP0002550B1 (en) Process for making contacts on the surface of a semiconductor body by means of serigraphy, and device made by this process
CH679712A5 (en)
EP2681812B2 (en) Brush for contact
FR2613117A1 (en) COMPOSITE CONDUCTIVE MATERIAL, METHOD FOR MANUFACTURING THE SAME AND USE THEREOF IN A MATERIAL FOR ELECTRICAL CONTACTS
EP0290311B1 (en) Sintered composite material for electrical contacts, and contact discs using said material
FR2568417A1 (en) METHOD FOR MANUFACTURING ELECTRICAL CONTACTS AND CONTACTS OBTAINED
EP0729162B1 (en) Process for the fabrication of a material for electric contact composite
CA2426702C (en) Isolating nozzle for arc blow circuit breaker
EP2909849B1 (en) Current connection and/or cut-off device comprising permanent contacts with reduced wear
EP1381065A1 (en) Electrical contact material and its method of manufacture
EP2297757A1 (en) Use of an electrical contact material for blowing an electric arc
FR2655206A1 (en) FRITTE COMPOSITE MATERIAL FOR ELECTRIC CONTACT, AND CONTACT BAG USING THE MATERIAL.
FR2586142A1 (en) MATERIAL FOR STATE CHANGING CONTACTS IN ELECTRIC CIRCUIT SWITCHES
FR2644284A1 (en) NEW MATERIALS BASED ON SILVER AND TIN OXIDE FOR THE PRODUCTION OF ELECTRICAL CONTACTS; ELECTRIC CONTACTS SO PERFORMED
FR2673492A1 (en) HIGHLY ALLOYED REFRACTORY ALLOY ELECTRODE AND PRESSURE WAVE GENERATION APPARATUS INCLUDING APPLICATION.
EP1520282A2 (en) Arc contact element for an electrical apparatus, production method thereof, corresponding contact assembly and electrical apparatus
EP2827352B1 (en) Circuit breaker and method of manufacturing a circuit breaker
FR2933541A1 (en) Metal support and contact material assembling method for e.g. circuit breaker, involves applying current and compressive force, where sub-layer agent conductivity is increased irreversibly during current and force application time interval

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR MK YU

17P Request for examination filed

Effective date: 20061027

17Q First examination report despatched

Effective date: 20061129

AKX Designation fees paid

Designated state(s): DE ES GB IT

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE ES GB IT

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REF Corresponds to:

Ref document number: 602005003537

Country of ref document: DE

Date of ref document: 20080110

Kind code of ref document: P

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20080121

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2297652

Country of ref document: ES

Kind code of ref document: T3

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20080829

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20221020

Year of fee payment: 18

Ref country code: GB

Payment date: 20221018

Year of fee payment: 18

Ref country code: ES

Payment date: 20221117

Year of fee payment: 18

Ref country code: DE

Payment date: 20221028

Year of fee payment: 18

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602005003537

Country of ref document: DE

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20231011