EP1638151B1 - Method for producing a superconductive element - Google Patents
Method for producing a superconductive element Download PDFInfo
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- EP1638151B1 EP1638151B1 EP04021982A EP04021982A EP1638151B1 EP 1638151 B1 EP1638151 B1 EP 1638151B1 EP 04021982 A EP04021982 A EP 04021982A EP 04021982 A EP04021982 A EP 04021982A EP 1638151 B1 EP1638151 B1 EP 1638151B1
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- bronze
- elongated
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N60/00—Superconducting devices
- H10N60/01—Manufacture or treatment
- H10N60/0184—Manufacture or treatment of devices comprising intermetallic compounds of type A-15, e.g. Nb3Sn
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49014—Superconductor
Definitions
- the invention relates to a method for producing a superconductive element, in particular a multifilament wire, starting from a composite comprising a bronze matrix containing Cu and Sn, in which at least one elongated structure containing Nb or an Nb alloy, in particular NbTa, is embedded, the concentration of Sn in the bronze matrix being between 16 % and 30% by weight, preferably up to 27%, the balance being Cu, whereby in a first step the composite is extruded at a temperature between 300°C and 750°C, followed by cold or hot working and annealing steps in which the composite is elongated in parallel to the elongated structure and softened by a temperature treatment, called intermediate annealing further on, followed by a stacking step, in which a multitude of elongated composites from the preceding cold or hot working steps are bundled, the steps of extruding, elongating, annealing and stacking being repeated one or more times, followed by a final elongating process, including intermediate
- Superconductive wires containing a superconductive Nb 3 Sn phase are typically produced by the powder in tube process (PIT-process), by the internal Sn diffusion method, or by the bronze route.
- Nb niobium
- Cu copper
- Sn tin
- bronze bronze matrix
- a ductile wire with numerous Nb fibers embedded in a bronze matrix is obtained.
- Some pure copper is also introduced into the wire in order to improve its thermal conductivity.
- the wire is then brought into the desired shape, e.g. by winding the wire into a coil. Subsequently, the wire is annealed at a temperature of about 600-700°C.
- Sn originating form the bronze diffuses into the Nb fibers and forms Nb 3 Sn, which has superconductive characteristics.
- the superconductive Nb 3 Sn phase is also called A15 phase.
- Nb 3 Sn with low Sn content exhibits inferior superconductive properties, in particular a low critical temperature T c and low upper critical magnetic field strength B c2 . Therefore, high and homogeneous Sn contents in the Nb 3 Sn phase are desired.
- the described Bronze route process is well established at the present day for bronzes containing up to -16 wt.% Sn (9.1 at.% Sn) in the unreacted wire, the fabrication method covering the largest part of the market.
- the "Internal Sn" process and the Powder-In-Tube (or PIT) process has created a new situation: a further improvement of the critical current densities of bronze route Nb 3 Sn wires is mandatory to remain competitive in the market.
- US 3,918,988 a method of manufacturing a superconducting wire comprising quenching steps and a final thermal treatment step is disclosed.
- US 3,918,988 does not define the temperature or cooling rate characteristics of the quenching steps.
- the method of US 3,918,988 does not disclose stacking or bandling steps.
- This object is achieved, in accordance with the invention as defined by claim 1 by a method in which at least part of the cold or hot working and annealing steps are performed by cold working preceded by an intermediate annealing between 520°C and 750°C, i. e. above the normal Cu-Sn recrystallization temperature, and by a fast cooling within less than 30 s to 100°C or below.
- This new method is further on denoted Rapid Intermediate Quenching (RIQ).
- a composite softened by heat treatment is used. This heat treatment is normally done at the recrystallization temperature of the bronze matrix followed by a slow cooling to room temperature. If this method is applied on a bronze consisting of more than 15.8 wt.% Sn, the annealed bronze matrix contains a considerable fraction of hard ⁇ phase which makes the composite brittle and impossible to cold work.
- RIQ Rapid Intermediate Quenching
- Superconductive Nb 3 Sn wires produced by the inventive method show high mechanical stability, small effective filament diameter and high homogeneity for very long lengths (well above 3 km).
- the final wire diameter is of the order of 1 mm.
- the Nb filament is around 5 ⁇ m, the total number of filaments reaching up to 10.000 or more.
- the temperature of the intermediate anneal can be chosen between 520 and 590°C, but preferably between 590 and 750°C.
- the fast cooling from a temperature between 590 and 750°C causes a higher ductility of the bronze in the composite.
- the composites undergo a pre-heating step at temperatures preferably between 300 and 520°C prior to the intermediate annealing step. This reduces the exposure time of the composite to temperatures above 520°C to a minimum and reduces therefore the danger of pre-reaction between Nb and Sn.
- the intermediate annealing treatment is done in a heating fluid.
- a heating fluid permits a precise control of the temperature and duration of the intermediate anneal.
- the heating fluid can be for example a liquid metal bath, which does not dissolve the composite, or a liquid salt bath.
- the cooling rate at the end of the RIQ is chosen to be less than 10 s.
- a fast cooling rate retains the high temperature phases ⁇ or ⁇ , avoiding the formation of hard ⁇ phase, especially bronzes with high tin contents above 15.8 wt.%.
- a preferred further variant is characterized in that the end temperature after the fast cooling is below 100°C. If the end temperature is higher than 100°C, the ductility of the fast cooled bronze may be worsened again.
- the fast cooling is actively performed by using a cooling fluid.
- a cooling fluid water may be used.
- cold working is done on the composites performed preferably within the next about 2 hours after the fast cooling. If the cold working is done much later, the ductility of the fast cooled bronze may be worse again.
- a further preferred variant is characterized in that part of the cold work is done by cold drawing using cassette roller dies. This can enhance the reduction in cross section that can be applied on the composite between two intermediate anneals using the RIQ method.
- the bronze matrix of the superconductive element contains at least one of the following additives with up to 5% weight: Ga, Al, Mg, Ti, Zr, Zn, Hf, In. These additives improve the properties of the superconductive element and/or the workability of the composite during production.
- the Nb alloy of the elongated structure contains at least one of the following additives with up to 10% weight, preferably up to 8% weight: Ta, V, Ti, Mo. These additives improve properties of the superconductive Nb 3 Sn phase of the superconductive element.
- an elongated hollow pipe having an inner surface and an outer surface, wherein the outer surface and the inner surface are in close contact with the bronze matrix.
- Such a composite structure is used in the conventional double bronze route.
- the double bronze route can be improved by enclosing an elongated core consisting of a metallic material in the central region of the composite, as described in European Patent Application Nr. 04004605.4 .
- an elongated rod having an outer surface is used, wherein the outer surface is in close contact with the bronze matrix.
- Such a composite structure is used in the conventional bronze route.
- An improved method for producing a superconductive element makes use of an intermediate anneal followed by a fast cooling, denoted as Rapid intermediate Quenching (RIQ) as illustrated in Fig. 2, which shows a schematic view of a composite 1 which may be structured according to the single bronze route as described in connection with Fig. 3 or according to the improved double bronze route as described in connection with Fig. 4.
- the composite 1 is heated by a heating liquid 2 and fast cooled by a cooling liquid 3.
- the heating liquid is brought to a temperature between 520 and 750°C and the composite 1 is brought to a temperature between 300 and 520°C by a pre-heating process prior to the intermediate anneal.
- the temperature of the composite 1 after the fast cooling by the cooling liquid 3 is at 100°C or below, such that the ductility of the bronze is enhanced. Performing intermediate annealing in this way allows cold working without damaging of the composite 1 even if the bronze possesses a high Sn content.
- Fig. 1 shows a Cu-Sn equilibrium phase diagram with the most important thermodynamic stable phases near the copper-rich side:
- the ⁇ phase bronze is conventionally used for Nb 3 Sn bronze route conductor fabrication. It is a one phase alloy, if one neglects problems of Sn-segregation which can be solved using a spray deposition process (Osprey) for the bronze fabrication. Applying recrystallization anneals between - 450°C and - 550°C, cold drawing is possible obtaining cross sectional reductions up to 65 % limited by the strong work hardening of the ⁇ phase. In the ⁇ phase, the maximum content of Sn in the bronze is limited to 15.8 % of weight (9.1 atomic %). In order to increase superconductive properties of superconducting wires by increasing the Sn content of the bronze, it is therefore necessary to study the workability of other bronzes.
- the two-phase ⁇ / ⁇ - bronze with 15.8 to 24.6 wt. % Sn contains a certain amount of intermetallic phases ⁇ , ⁇ or ⁇ , depending on temperature and alloy composition.
- the presence of hard intermetallic phases is an additional limitation for the cold workability. Deformation experiences with a spray deposited Cu 18 wt. % Sn bronze reveal still a somehow restricted workability under certain conditions: If the recrystallization is carried out at 620°C (in the ⁇ / ⁇ - domain) and water quenched, cold drawing allows cross sectional reduction up to approx. 40 %. If the recrystallization happens at 550°C ( ⁇ / ⁇ - domain), the possible reduction is much smaller.
- the workability depends therefore strongly on the thermodynamic state during the recrystallization anneal, and also on the quenching speed at the end of the recrystallization anneal.
- One possible approach to improve workability is therefore to use intermediate anneals in the ⁇ / ⁇ - domain or ⁇ / ⁇ - domain, followed by a fast cooling (RIQ) and cold working.
- RIQ fast cooling
- the fast cooled bronze has a higher ductility compared to a slowly cooled bronze due to the properties of the retained ⁇ - or ⁇ - phase, respectively.
- the ⁇ - bronze (Cu 24.6 wt.% Sn) is again a one phase alloy, if the temperature is held between 586 and about 750°C.
- eutectoid decomposition generates ⁇ and ⁇ or ⁇ phase.
- a cast bronze with Cu 24 wt.% Sn is homogenised, hot rolled from 50 to 5 mm in the ⁇ -domain between 650 and 700°C and water quenched from 700°C.
- the wrought products are «quite machinable» at room temperature, which cannot be expected from an as-cast or slowly cooled bronze of the same alloy composition. It was found that quenching from the ⁇ - or ⁇ / ⁇ -domain produces a relatively ductile metastable material, but the quenched alloy ages at room temperature, enhancing its hardness and lowering both its ductility and tensile strength. For the production of a superconductive element using a ⁇ - bronze it is therefore necessary to perform all intermediate anneals by the RIQ - method.
- Fig. 3 shows a composite 4 of an usual single bronze route for fabrication of Nb 3 Sn wires with diameters of 4 to 5 ⁇ m.
- a typical superconductive wire there are some thousands of superconductive filaments, typically grouped in bundles. The bundles are usually grouped around a pure copper core or arranged within a pure copper tube (not shown).
- the composite 4 comprises an elongated rod 5 surrounded by a bronze matrix 6.
- the elongated rod 5 consists of ductile Nb (or NbTa), which reacts gradually with Sn (from the Cu-Sn bronze matrix 6) to Nb 3 Sn by annealing it at an elevated reaction temperature in order to induce a solid state diffusion reaction.
- the Nb content of the elongated rod 5 does not completely react to Nb 3 Sn, but some Nb remains unreacted.
- a concentration gradient is varying from 25 atomic % Sn content near the boundary to the bronze matrix 6 to a content of 18% Sn near the unreacted Nb core.
- the double bronze route is used.
- Fig. 4 shows a composite 7 according to the double bronze route.
- the main difference between the usual bronze route and the double bronze route consists in the fact that the elongated rod 5 is replaced by an elongated pipe 8.
- the material of the elongated pipe 8 contains Nb.
- the Nb is present as a substantially pure metal, or as a Nb containing mixed crystal.
- the atomic concentration of Nb in the elongated pipe 8 is about 50% or more.
- a Nb-7,5% Ta alloy is used.
- the elongated pipe 8 has an inner surface and an outer surface.
- the inner surface is in close contact with an inner Cu-Sn bronze matrix 9 .
- the outer surface of the elongated pipe 8 is in contact with a surrounding, outer bronze matrix 10 .
- the outer bronze matrix 10 typically consists of the same material as the inner bronze matrix 9.
- the outer bronze matrix 10 can be ring-shaped in cross-section, but may also stretch along a wide area. In particular, the outer bronze matrix of a first composite structure may verge into an outer bronze matrix of a second, neighbouring composite structure (not shown).
- the double bronze technique allows a variation of the Nb 3 Sn wall thickness from 2 ⁇ m down to values well below 1 ⁇ m with the same number of extrusions.
- the overall filament diameter of double bronze wires can be varied within a wide range between 5 and 15 ⁇ m. This depends on the initial dimensions and does not require additional deformation steps.
- the thin A15 wall thickness allows to obtain shorter reaction times, and thus smaller grain sizes. This is expected to considerably enhance the critical current density values, in particular at the industrially interesting intermediate field range of 12 to 16 T.
- the wires produced by the conventional double bronze route do not exhibit higher j c values because of mechanical instabilities.
- the inner Cu-Sn bronze matrix 9 shrinks when cooled down. Not only there is no precompression effect, but in addition, radial stresses are introduced, finally leading to a damage of the A15 layer.
- the present invention presents an improved production process for manufacturing superconducting elements in which the advantages of fast cooled intermediate anneals may be combined with the improved double bronze process and high mechanical stability and increased j c values of the superconducting elements are obtained.
- Superconducting elements produced by the inventive method therefore constitute promising components for future use in superconducting applications, e.g. for NMR solenoids, accelerator or fusion magnets etc.
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Description
- The invention relates to a method for producing a superconductive element, in particular a multifilament wire, starting from a composite comprising a bronze matrix containing Cu and Sn, in which at least one elongated structure containing Nb or an Nb alloy, in particular NbTa, is embedded, the concentration of Sn in the bronze matrix being between 16 % and 30% by weight, preferably up to 27%, the balance being Cu, whereby in a first step the composite is extruded at a temperature between 300°C and 750°C, followed by cold or hot working and annealing steps in which the composite is elongated in parallel to the elongated structure and softened by a temperature treatment, called intermediate annealing further on, followed by a stacking step, in which a multitude of elongated composites from the preceding cold or hot working steps are bundled, the steps of extruding, elongating, annealing and stacking being repeated one or more times, followed by a final elongating process, including intermediate annealing processes, in which the composite is elongated to its final length, the superconductive phase being obtained by a heat treatment including a solid state diffusion reaction.
- A method of this type is described in the article "Fabrication Technology of Superconducting Material" by H. Hillmann in "Superconductor Materials Science: Metallurgy, Fabrication and Applications", ed. by S. Foner and B. Schwartz, NATO advanced study institutes series, B-Physics, Vol. 68, pp. 275-388, Plenum Press, New York/London, 1981.
- Superconductive wires containing a superconductive Nb3Sn phase are typically produced by the powder in tube process (PIT-process), by the internal Sn diffusion method, or by the bronze route.
- In the bronze route, a number of niobium (Nb) rods are inserted into a copper (Cu) and tin (Sn) containing bronze matrix. By repeated extruding, bundling and insertion into further bronze cans, a ductile wire with numerous Nb fibers embedded in a bronze matrix is obtained. Some pure copper is also introduced into the wire in order to improve its thermal conductivity. The wire is then brought into the desired shape, e.g. by winding the wire into a coil. Subsequently, the wire is annealed at a temperature of about 600-700°C. During this solid state diffusion reaction, Sn originating form the bronze diffuses into the Nb fibers and forms Nb3Sn, which has superconductive characteristics. The superconductive Nb3Sn phase is also called A15 phase.
- Nb3Sn with low Sn content exhibits inferior superconductive properties, in particular a low critical temperature Tc and low upper critical magnetic field strength Bc2. Therefore, high and homogeneous Sn contents in the Nb3Sn phase are desired. The Sn content in the Nb3Sn phase can be increased by increasing the annealing temperature (=reaction temperature) and/or the annealing time (=reaction time). However, this also induces accelerated grain growth, which deteriorates the superconductive properties of the filament again.
- The described Bronze route process is well established at the present day for bronzes containing up to -16 wt.% Sn (9.1 at.% Sn) in the unreacted wire, the fabrication method covering the largest part of the market. However, recent important progress in the two other techniques, the "Internal Sn" process and the Powder-In-Tube (or PIT) process has created a new situation: a further improvement of the critical current densities of bronze route Nb3Sn wires is mandatory to remain competitive in the market.
- In
US 3,918,988 , a method of manufacturing a superconducting wire comprising quenching steps and a final thermal treatment step is disclosed. However,US 3,918,988 does not define the temperature or cooling rate characteristics of the quenching steps. Furthermore, the method ofUS 3,918,988 does not disclose stacking or bandling steps. - In
US 5,228,928 , a method of manufacturing a Nb3Sn superconducting wire is described in which the Sn content of the bronze matrix is increased leading to an increased amount of the Nb3Sn phase thus improving the superconducting properties of the wire. The workability of the wire with increased Sn content is improved by dividing an intermetallic compound phase in the bronze into small pieces by cold or warm working at temperatures below the recrystallization temperature of the bronze matrix. - It is the object of the invention to provide a method for producing a superconductive element which has improved superconductive properties in a large volume fraction of its superconductive filaments, in particular a high critical temperature Tc and a high upper critical magnetic field strength Bc2, and which is mechanically stable enough for commercial applications such as magnet coils.
- This object is achieved, in accordance with the invention as defined by
claim 1 by a method in which at least part of the cold or hot working and annealing steps are performed by cold working preceded by an intermediate annealing between 520°C and 750°C, i. e. above the normal Cu-Sn recrystallization temperature, and by a fast cooling within less than 30 s to 100°C or below. This new method is further on denoted Rapid Intermediate Quenching (RIQ). - In an elongation process by cold working, normally a composite softened by heat treatment is used. This heat treatment is normally done at the recrystallization temperature of the bronze matrix followed by a slow cooling to room temperature. If this method is applied on a bronze consisting of more than 15.8 wt.% Sn, the annealed bronze matrix contains a considerable fraction of hard δ phase which makes the composite brittle and impossible to cold work. In the Rapid Intermediate Quenching (RIQ) method, the softening treatment (=intermediate anneal) is performed at temperatures between 520 and 750°C followed by a fast cooling. By this fast cooling, the formation of δ phase is suppressed and the composite is quite ductile which can be subjected to elongation by cold working.
- Superconductive Nb3Sn wires produced by the inventive method show high mechanical stability, small effective filament diameter and high homogeneity for very long lengths (well above 3 km). The final wire diameter is of the order of 1 mm. At this point, the Nb filament is around 5 µm, the total number of filaments reaching up to 10.000 or more.
- In a preferred variant of this method, the temperature of the intermediate anneal can be chosen between 520 and 590°C, but preferably between 590 and 750°C. The fast cooling from a temperature between 590 and 750°C causes a higher ductility of the bronze in the composite.
- In another preferred variant of this method, the composites undergo a pre-heating step at temperatures preferably between 300 and 520°C prior to the intermediate annealing step. This reduces the exposure time of the composite to temperatures above 520°C to a minimum and reduces therefore the danger of pre-reaction between Nb and Sn.
- In a further preferred variant of this method, the intermediate annealing treatment is done in a heating fluid. The use of a heating fluid permits a precise control of the temperature and duration of the intermediate anneal. The heating fluid can be for example a liquid metal bath, which does not dissolve the composite, or a liquid salt bath.
- In another variant, the cooling rate at the end of the RIQ is chosen to be less than 10 s. A fast cooling rate retains the high temperature phases γ or β, avoiding the formation of hard δ phase, especially bronzes with high tin contents above 15.8 wt.%.
- A preferred further variant is characterized in that the end temperature after the fast cooling is below 100°C. If the end temperature is higher than 100°C, the ductility of the fast cooled bronze may be worsened again.
- In another preferred variant the fast cooling is actively performed by using a cooling fluid. As a cooling fluid, water may be used.
- In another preferred variant cold working is done on the composites performed preferably within the next about 2 hours after the fast cooling. If the cold working is done much later, the ductility of the fast cooled bronze may be worse again.
- A further preferred variant is characterized in that part of the cold work is done by cold drawing using cassette roller dies. This can enhance the reduction in cross section that can be applied on the composite between two intermediate anneals using the RIQ method.
- In a preferred variant, the bronze matrix of the superconductive element contains at least one of the following additives with up to 5% weight: Ga, Al, Mg, Ti, Zr, Zn, Hf, In. These additives improve the properties of the superconductive element and/or the workability of the composite during production.
- In a further preferred variant, the Nb alloy of the elongated structure contains at least one of the following additives with up to 10% weight, preferably up to 8% weight: Ta, V, Ti, Mo. These additives improve properties of the superconductive Nb3Sn phase of the superconductive element.
- In a highly preferred variant of the inventive method for the elongated structure of the superconductive element an elongated hollow pipe is used having an inner surface and an outer surface, wherein the outer surface and the inner surface are in close contact with the bronze matrix. Such a composite structure is used in the conventional double bronze route. The double bronze route can be improved by enclosing an elongated core consisting of a metallic material in the central region of the composite, as described in
European Patent Application Nr. 04004605.4 - In an alternative preferred variant for the elongated structure of the superconductive element an elongated rod having an outer surface is used, wherein the outer surface is in close contact with the bronze matrix. Such a composite structure is used in the conventional bronze route.
- Further advantages can be extracted from the description and the enclosed drawing. The features mentioned above and below can be used in accordance with the invention either individually or collectively in any combination. The embodiments mentioned are not to be understood as exhaustive enumeration but rather have exemplary character for the description of the invention.
- The invention is shown in the drawings.
- Fig. 1
- shows a Cu-Sn equilibrium phase diagram with the most important thermodynamic stable phases near the copper-rich side,
- Fig. 2
- shows a schematic view of a composite heated by a heated liquid and cooled by a cooling liquid,
- Fig. 3
- shows a schematic cross-sectional view of a composite according to the single bronze route, and
- Fig. 4
- shows a schematic cross-sectional view of a composite according to an improved double bronze route.
- An improved method for producing a superconductive element makes use of an intermediate anneal followed by a fast cooling, denoted as Rapid intermediate Quenching (RIQ) as illustrated in Fig. 2, which shows a schematic view of a composite 1 which may be structured according to the single bronze route as described in connection with Fig. 3 or according to the improved double bronze route as described in connection with Fig. 4. The
composite 1 is heated by aheating liquid 2 and fast cooled by a coolingliquid 3. The heating liquid is brought to a temperature between 520 and 750°C and thecomposite 1 is brought to a temperature between 300 and 520°C by a pre-heating process prior to the intermediate anneal. The temperature of the composite 1 after the fast cooling by the coolingliquid 3 is at 100°C or below, such that the ductility of the bronze is enhanced. Performing intermediate annealing in this way allows cold working without damaging of the composite 1 even if the bronze possesses a high Sn content. - For a better understanding of the different possibilities of producing superconductive elements making use of the Rapid Intermediate Quench (RIQ) described in Fig. 2, studying the thermodynamic properties of Cu-Sn bronze is mandatory. Therefore, Fig. 1 shows a Cu-Sn equilibrium phase diagram with the most important thermodynamic stable phases near the copper-rich side:
- the α phase (Cu-Sn, fcc) with a range of stability from 0 to 15.8 wt.% Sn and a maximal solubility of 15.8 wt.% Sn at about 520°C,
- The β phase (Cu-Sn, bcc) with a range of stability from 22.0 to 26.0 wt.% Sn and an eutectoid point at 586°C and 24.6 wt.% Sn,
- the γ phase (Cu3Sn, cubic) with a range of stability from 25.5 to 41.5 wt.% Sn and an eutectoid point at 520°C and 27.0 wt.% Sn, and
- the δ phase (Cu41Sn11, cubic) with a range of stability from 31.8 to 33.2 wt.% Sn and an eutectoid point at about 350°C and 32.6 wt.% Sn.
- The following three groups of bronzes relevant for the production of superconductive wires may be distinguished:
- The α phase bronze is conventionally used for Nb3Sn bronze route conductor fabrication. It is a one phase alloy, if one neglects problems of Sn-segregation which can be solved using a spray deposition process (Osprey) for the bronze fabrication. Applying recrystallization anneals between - 450°C and - 550°C, cold drawing is possible obtaining cross sectional reductions up to 65 % limited by the strong work hardening of the α phase. In the α phase, the maximum content of Sn in the bronze is limited to 15.8 % of weight (9.1 atomic %). In order to increase superconductive properties of superconducting wires by increasing the Sn content of the bronze, it is therefore necessary to study the workability of other bronzes.
- The two-phase α/β - bronze with 15.8 to 24.6 wt. % Sn contains a certain amount of intermetallic phases β, γ or δ, depending on temperature and alloy composition. The presence of hard intermetallic phases is an additional limitation for the cold workability. Deformation experiences with a spray deposited Cu 18 wt. % Sn bronze reveal still a somehow restricted workability under certain conditions: If the recrystallization is carried out at 620°C (in the α/β - domain) and water quenched, cold drawing allows cross sectional reduction up to approx. 40 %. If the recrystallization happens at 550°C (α/γ - domain), the possible reduction is much smaller. The workability depends therefore strongly on the thermodynamic state during the recrystallization anneal, and also on the quenching speed at the end of the recrystallization anneal. One possible approach to improve workability is therefore to use intermediate anneals in the α/γ - domain or α/β - domain, followed by a fast cooling (RIQ) and cold working. Indeed, the fast cooled bronze has a higher ductility compared to a slowly cooled bronze due to the properties of the retained γ - or β - phase, respectively.
- Finally, the β - bronze (Cu 24.6 wt.% Sn) is again a one phase alloy, if the temperature is held between 586 and about 750°C. Below, eutectoid decomposition generates α and γ or δ phase. In the article "The Decompositon of the Beta Phase in the Copper-Tin system" by M.B. Cortie, C. E. Mavrocordatos, Metallurgical Transactions A, Vol. 22 A, 1991, pp. 11-18, a cast bronze with Cu 24 wt.% Sn is homogenised, hot rolled from 50 to 5 mm in the β-domain between 650 and 700°C and water quenched from 700°C. The wrought products are «quite machinable» at room temperature, which cannot be expected from an as-cast or slowly cooled bronze of the same alloy composition. It was found that quenching from the β- or α/β -domain produces a relatively ductile metastable material, but the quenched alloy ages at room temperature, enhancing its hardness and lowering both its ductility and tensile strength. For the production of a superconductive element using a β - bronze it is therefore necessary to perform all intermediate anneals by the RIQ - method.
- Fig. 3 shows a
composite 4 of an usual single bronze route for fabrication of Nb3Sn wires with diameters of 4 to 5 µm. In a typical superconductive wire, there are some thousands of superconductive filaments, typically grouped in bundles. The bundles are usually grouped around a pure copper core or arranged within a pure copper tube (not shown). Thecomposite 4 comprises anelongated rod 5 surrounded by a bronze matrix 6. Theelongated rod 5 consists of ductile Nb (or NbTa), which reacts gradually with Sn (from the Cu-Sn bronze matrix 6) to Nb3Sn by annealing it at an elevated reaction temperature in order to induce a solid state diffusion reaction. - Typically the Nb content of the
elongated rod 5 does not completely react to Nb3Sn, but some Nb remains unreacted. Within the Nb3Sn phase, a concentration gradient is varying from 25 atomic % Sn content near the boundary to the bronze matrix 6 to a content of 18% Sn near the unreacted Nb core. In order to increase the amount of Nb reacting to Nb3Sn, the double bronze route is used. - Fig. 4 shows a composite 7 according to the double bronze route. The main difference between the usual bronze route and the double bronze route consists in the fact that the
elongated rod 5 is replaced by anelongated pipe 8. The material of theelongated pipe 8 contains Nb. The Nb is present as a substantially pure metal, or as a Nb containing mixed crystal. Preferably, the atomic concentration of Nb in theelongated pipe 8 is about 50% or more. In the present case, a Nb-7,5% Ta alloy is used. - The
elongated pipe 8 has an inner surface and an outer surface. The inner surface is in close contact with an inner Cu-Sn bronze matrix 9. The outer surface of theelongated pipe 8 is in contact with a surrounding,outer bronze matrix 10. Theouter bronze matrix 10 typically consists of the same material as theinner bronze matrix 9. Theouter bronze matrix 10 can be ring-shaped in cross-section, but may also stretch along a wide area. In particular, the outer bronze matrix of a first composite structure may verge into an outer bronze matrix of a second, neighbouring composite structure (not shown). - In contrast to the conventional bronze route wires which show a filament diameter close to 5 µm and an effective diffusion length of the order of 2 - 2.5 µm, the double bronze technique allows a variation of the Nb3Sn wall thickness from 2 µm down to values well below 1 µm with the same number of extrusions. The overall filament diameter of double bronze wires can be varied within a wide range between 5 and 15 µm. This depends on the initial dimensions and does not require additional deformation steps. Further, in analogy to "in situ" wires with very thin filament diameters, the thin A15 wall thickness allows to obtain shorter reaction times, and thus smaller grain sizes. This is expected to considerably enhance the critical current density values, in particular at the industrially interesting intermediate field range of 12 to 16 T.
- However, the wires produced by the conventional double bronze route do not exhibit higher jc values because of mechanical instabilities. The inner Cu-
Sn bronze matrix 9 shrinks when cooled down. Not only there is no precompression effect, but in addition, radial stresses are introduced, finally leading to a damage of the A15 layer. - An improvement of the double bronze route is described in
European Patent Application Nr. 04004605.4 inner bronze matrix 9 surrounds an innermetallic core 11 which consists of tantalum, being chemically inert and having a thermal expansion coefficient smaller than the surroundinginner bronze matrix 9. Thetantalum core 11 shrinks less than theinner bronze matrix 9, lessening tensile stress exerted by the inner bronze matrix onto theelongated pipe 8 and thus avoiding mechanical instabilities, leading to higher values of the superconducting current jc. - The present invention presents an improved production process for manufacturing superconducting elements in which the advantages of fast cooled intermediate anneals may be combined with the improved double bronze process and high mechanical stability and increased jc values of the superconducting elements are obtained. Superconducting elements produced by the inventive method therefore constitute promising components for future use in superconducting applications, e.g. for NMR solenoids, accelerator or fusion magnets etc.
Claims (10)
- Method for producing a superconductive element, in particular a multifilament wire,
starting from a composite (1; 4; 7) comprising a bronze matrix (6; 9, 10) containing Cu and Sn, in which at least one elongated structure containing Nb or an Nb alloy, in particular NbTa, is embedded, the concentration of Sn in the bronze matrix (6; 9, 10) being between 16 % and 30% by weight, preferably up to 27%, the balance being Cu,
whereby in a first step the composite (1; 4; 7) is extruded at a temperature between 300°C and 750°C,
followed by cold or hot working and annealing steps in which the composite (1; 4; 7) is elongated in parallel to the elongated structure and softened by a temperature treatment called "intermediate annealing",
followed by a stacking step, in which a multitude of elongated composites (1; 4; 7) from the preceding cold or hot working steps are bundled,
the steps of extruding, elongating, annealing and stacking being repeated one or more times,
followed by a final elongating process, including intermediate annealing processes, in which the composite (1; 4; 7) is elongated to its final length, the superconductive phase being obtained by a heat treatment including a solid state diffusion reaction,
characterized in that
at least part of the elongating steps and annealing steps are performed by cold working preceded by an intermediate annealing between 520°C and 750°C, i. e. above the normal Cu-Sn recrystallization temperature, and by a fast cooling within less than 30 s to 100°C or below called "Rapid Intermediate Quenching [RIQ]". - Method according to claim 1, characterized in that the temperature of the intermediate anneal is chosen between 590°C and 750°C.
- Method according to claim 1 or 2, characterized in that the intermediate annealing treatment is done in a heated fluid (2).
- Method according to anyone of the preceding claims, characterized in that the fast cooling rate is chosen to be less than 10 s.
- Method according to anyone of the preceding claims, characterized in that the fast cooling is actively performed by using a cooling fluid (3).
- Method according to anyone of the preceding claims, characterized in that part of the cold working is performed by cold drawing using cassette roller dies.
- Method according to anyone of the preceding claims, characterized in that the bronze matrix (6; 9, 10) contains at least one of the following additives with up to 5% weight: Ga, Al, Mg, Ti, Zr, Zn, Hf, In.
- Method according to anyone of the preceding claims, characterized in that the Nb alloy of the elongated structure contains at least one of the following additives with up to 10% weight, preferably up to 8% weight: Ta, V, Ti, Mo.
- Method according to anyone of the preceding claims, characterized in that for the elongated structure an elongated rod (5) is used having an outer surface, wherein the outer surface is in close contact with the bronze matrix (6).
- Method according to anyone of claims 1 through 8, characterized in that for the elongated structure an elongated hollow pipe (8) is used having an inner surface and an outer surface, wherein the outer surface and the inner surface are in close contact with the bronze matrix (9, 10).
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE602004010118T DE602004010118T2 (en) | 2004-09-16 | 2004-09-16 | Method for producing a superconducting element |
EP04021982A EP1638151B1 (en) | 2004-09-16 | 2004-09-16 | Method for producing a superconductive element |
US11/223,053 US7476281B2 (en) | 2004-09-16 | 2005-09-12 | Method for producing a superconductive element |
JP2005270176A JP5065582B2 (en) | 2004-09-16 | 2005-09-16 | Superconducting device and manufacturing method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04021982A EP1638151B1 (en) | 2004-09-16 | 2004-09-16 | Method for producing a superconductive element |
Publications (2)
Publication Number | Publication Date |
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EP1638151A1 EP1638151A1 (en) | 2006-03-22 |
EP1638151B1 true EP1638151B1 (en) | 2007-11-14 |
Family
ID=34926557
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Application Number | Title | Priority Date | Filing Date |
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EP04021982A Not-in-force EP1638151B1 (en) | 2004-09-16 | 2004-09-16 | Method for producing a superconductive element |
Country Status (4)
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US (1) | US7476281B2 (en) |
EP (1) | EP1638151B1 (en) |
JP (1) | JP5065582B2 (en) |
DE (1) | DE602004010118T2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE602005005044T2 (en) | 2005-07-19 | 2009-02-26 | Bruker Biospin Ag | Superconducting elements with Nb3Sn filaments containing copper, as well as a composite material and a process for their production |
US8876990B2 (en) * | 2009-08-20 | 2014-11-04 | Massachusetts Institute Of Technology | Thermo-mechanical process to enhance the quality of grain boundary networks |
JP6078501B2 (en) * | 2014-07-18 | 2017-02-08 | ジャパンスーパーコンダクタテクノロジー株式会社 | Precursor for manufacturing Nb3Sn superconducting wire |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3665595A (en) * | 1968-10-31 | 1972-05-30 | Tohoku University The | Method of manufacturing superconductive materials |
US3918998A (en) * | 1973-03-19 | 1975-11-11 | Airco Inc | Method for producing superconducting wire and products of the same |
GB1543149A (en) * | 1976-04-14 | 1979-03-28 | Imp Metal Ind Kynoch Ltd | Superconductors |
JPS5539144A (en) * | 1978-09-14 | 1980-03-18 | Nat Res Inst Metals | Method of fabricating nb3sn composite superconductor |
DE3035220A1 (en) * | 1980-09-18 | 1982-04-29 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | SUPER-CONDUCTIVE WIRE BASED ON BRONZE-NB (DOWN ARROW) 3 (DOWN ARROW) SN AND METHOD FOR THE PRODUCTION THEREOF |
JPS6097514A (en) * | 1983-10-31 | 1985-05-31 | 株式会社東芝 | Method of producing composite superconductive conductor |
DE3718258A1 (en) * | 1987-05-30 | 1988-12-15 | Kernforschungsz Karlsruhe | Method for the fabrication of multifilament superconductor wires from Nb3Sn filaments or V3Ga filaments, embedded in a matrix of Cu or Cu alloy |
US5228928A (en) * | 1991-02-07 | 1993-07-20 | The Furukawa Electric Co., Ltd. | Method of manufacturing Nb3 Sn superconducting wire |
JPH08167336A (en) * | 1994-12-12 | 1996-06-25 | Furukawa Electric Co Ltd:The | Manufacture of nb3sn superconducting wire |
JP2001236836A (en) * | 2000-02-21 | 2001-08-31 | Hitachi Cable Ltd | Nb3Sn SUPERCONDUCTING WIRE MATERIAL |
US6836955B2 (en) * | 2000-03-21 | 2005-01-04 | Composite Materials Technology, Inc. | Constrained filament niobium-based superconductor composite and process of fabrication |
US6918172B2 (en) * | 2000-03-21 | 2005-07-19 | Composite Materials Technology, Inc. | Process for manufacturing Nb3Sn superconductor |
JP3588628B2 (en) * | 2000-04-06 | 2004-11-17 | 独立行政法人物質・材料研究機構 | Method for producing Nb3Al ultrafine multicore superconducting wire |
WO2002081192A1 (en) * | 2001-04-09 | 2002-10-17 | Composite Materials Technology, Inc. | Nb3Al SUPERCONDUCTOR AND METHOD OF MANUFACTURE |
EP1719190B1 (en) * | 2004-02-19 | 2010-05-19 | Oxford Superconducting Technology | Improving critical current density in Nb3Sn superconducting wire |
-
2004
- 2004-09-16 EP EP04021982A patent/EP1638151B1/en not_active Not-in-force
- 2004-09-16 DE DE602004010118T patent/DE602004010118T2/en active Active
-
2005
- 2005-09-12 US US11/223,053 patent/US7476281B2/en not_active Expired - Fee Related
- 2005-09-16 JP JP2005270176A patent/JP5065582B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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US20070227622A1 (en) | 2007-10-04 |
DE602004010118T2 (en) | 2008-09-04 |
JP5065582B2 (en) | 2012-11-07 |
US7476281B2 (en) | 2009-01-13 |
JP2006147535A (en) | 2006-06-08 |
EP1638151A1 (en) | 2006-03-22 |
DE602004010118D1 (en) | 2007-12-27 |
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