EP1631860A1 - Strukturierte transflektoren für flüssigkristallanzeigen - Google Patents

Strukturierte transflektoren für flüssigkristallanzeigen

Info

Publication number
EP1631860A1
EP1631860A1 EP04750696A EP04750696A EP1631860A1 EP 1631860 A1 EP1631860 A1 EP 1631860A1 EP 04750696 A EP04750696 A EP 04750696A EP 04750696 A EP04750696 A EP 04750696A EP 1631860 A1 EP1631860 A1 EP 1631860A1
Authority
EP
European Patent Office
Prior art keywords
recited
structured
display unit
light
transflector
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04750696A
Other languages
English (en)
French (fr)
Inventor
Keith M. c/o 3M Center Kotchick
Kenneth A. c/o 3M Center Epstein
Patrick H. c/o 3M Center Marushin
Donald J. c/o 3M Center McClure
Andrew J. c/o 3M Center Ouderkirk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/429,601 external-priority patent/US7088405B2/en
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of EP1631860A1 publication Critical patent/EP1631860A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/10Beam splitting or combining systems
    • G02B27/14Beam splitting or combining systems operating by reflection only
    • G02B27/142Coating structures, e.g. thin films multilayers
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/10Beam splitting or combining systems
    • G02B27/14Beam splitting or combining systems operating by reflection only
    • G02B27/147Beam splitting or combining systems operating by reflection only using averaging effects by spatially variable reflectivity on a microscopic level, e.g. polka dots, chequered or discontinuous patterns, or rapidly moving surfaces
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133553Reflecting elements
    • G02F1/133555Transflectors

Definitions

  • This invention relates generally to displays, and particularly to transflective displays that operate under ambient lighting and also with backlighting.
  • LCDs may be classified based upon the source of illumination. Reflective displays are illuminated by ambient light entering the display from the front. A reflective surface, such as a brushed metal reflector placed behind the LCD returns light that has been transmitted through the LCD while preserving the polarization orientation of the light incident on the reflective surface.
  • a reflective surface such as a brushed metal reflector placed behind the LCD returns light that has been transmitted through the LCD while preserving the polarization orientation of the light incident on the reflective surface.
  • reflective displays meet the need for low power consumption, the displays are only useful under good ambient lighting conditions. Under low levels of ambient light, the display often appears dark and is difficult to read. Therefore, the purely reflective display has limited utility.
  • the backlight assembly includes a light source, such as a light-emitting diode (LED), a fluorescent lamp, or other device that emits light, and some optical elements to direct the light from the light emitter to the LCD.
  • a light source such as a light-emitting diode (LED), a fluorescent lamp, or other device that emits light, and some optical elements to direct the light from the light emitter to the LCD.
  • Backlighting may also be used to supplement a reflective display so that it can be used over a wide range of ambient light conditions.
  • the introduction of a backlit assembly increases the power drain on the battery, significantly reducing the useful battery life, or the time between battery chargings.
  • the combination of backlighting with an ambient reflective display introduces the need for a "transflective" film.
  • the transflective film is placed between the LCD and the light source, and is used for reflecting ambient light that has been transmitted through the LCD and transmitting light from the light source to illuminate the LCD.
  • a transflective film Under ambient lighting conditions, however, a transflective film often gives rise to a specular reflection of the incident light overlapping the image, thus making the image harder to view. This is particularly the case when the display is a color display operating in the backlit mode, and there are high levels of ambient light. Accordingly, there is a need for an improved transflector that improves the viewability of the image of a color display when operating with high levels of ambient light.
  • the transflector reflects and transmits light with reduced color shift and may be structured so as to spread the reflected ambient light over a desired angular range.
  • the invention is directed to a transflective display device that comprises a transmissive display unit having a viewing side and a back side and defining picture elements.
  • a light source is disposed to the back side of the transmissive display unit.
  • a structured transflector is disposed between the transmissive display unit and the light source.
  • the structured transflector includes a structured surface and a layered dielectric reflector disposed over the structured surface.
  • the invention is directed to a transflective display device that comprises a color transmissive display unit having a viewing side and a back side, and a structured transflector disposed to the backside of the color display unit.
  • the structured transflector comprises a structured substrate having a structured surface and a dielectric partial reflector disposed on the structured surface. Ambient light incident on the display unit produces glare light in a glare direction and the structured transflector reflects image light over a range of direction substantially surrounding the glare direction.
  • FIG. 1 schematically illustrates an embodiment of a transflective display according to principles of the present invention
  • FIGs. 2A - 2C schematically illustrate cross-sections through different embodiments of transflector according to principles of the present invention
  • FIG. 3 schematically illustrates a display and co-ordinates used in describing optical paths relative to the display
  • FIG. 4 presents plots showing calculated optical responses of different transflectors as illustrated in FIG. 2A, for various values of base angle from 6° to 20°;
  • FIG. 5A schematically illustrates a portion of another embodiment of a transflector according to principles of the present invention
  • FIG. 5B schematically illustrates a' portion of another embodiment of a transflector according to principles of the present invention
  • FIG. 6 presents a plot showing a calculated optical response of a transflector having reflectors disposed at a range of angles from 6° to 20°, according to principles of the present invention
  • FIGs. 7A and 7B schematically illustrate embodiments of a transflector having non-linear reflecting facets, according to principles of the present invention
  • FIG. 7C presents a plot showing a calculated optical response of a transflector having curved reflectors, curving over a range of angles from 6° to 20°, according to principles of the present invention
  • FIGs. 8A and 8B schematically illustrate embodiments of reflectors that provide for lateral light spreading, according to principles of the present invention
  • FIG. 9 presents a graph showing the optical effect of transflectors having different combinations of reflectors at different angles, according to principles of the present invention.
  • FIG. 10 presents a graph showing experimental results of a spot light test for reflective displays having three different types of transflector
  • FIG. 11 presents a graph showing color characteristics for ambient light reflected at different angles, for reflective displays having four different types of transflector
  • FIG. 12 presents a graph showing color shift in backlight operation for reflective displays having three different types of transflector.
  • FIG. 13A schematically illustrates another embodiment of a structured transflector according to principles of the present invention
  • FIG. 13B schematically illustrates the substrate of the structured transflector illustrated in FIG. 13A
  • FIG. 14A schematically illustrates another embodiment of a structured transflector according to principles of the present invention
  • FIGs. 14B and 14C schematically illustrate cross-sections through the substrate of the structured transflector illustrated in FIG. 14A.
  • FIG. 15 presents a conoscopic plot showing the calculated distribution of light reflected from a structured transflector fabricated according to principles of the present invention
  • FIG. 16 schematically illustrates a display and co-ordinates used in describing an experiment to determine the reflective properties of a structured transflector
  • FIG. 17 presents experimental results showing the distribution of reflected light from a structured transflector.
  • the present invention is applicable to transflective displays and is believed to be particularly useful for color transflective displays in which the reflected image light is separated from ambient glare, thus improving the viewability of the image seen by the viewer.
  • a schematic representation of a transflective display 100 is illustrated in FIG. 1.
  • a display unit 102 typically a liquid crystal display (LCD) or the like, is connected to a controller 104 which controls the information displayed on the display 102.
  • a transflector 106 formed from one or more layers of optical film, is positioned below the display unit 102.
  • a power supply 108 may supply power to the display controller 104, to the display unit 102, and also to a light source 110.
  • the light source 110 may be any suitable type of light source, for example one or more fluorescent tubes, one or more light emitting diodes or the like.
  • the light source 110 may include an optional reflector 111 to aid in directing the light in a preferred direction.
  • the power supply 108 may be a battery, a rechargeable battery, or other source of electrical power.
  • the display unit 102 typically includes an upper absorbing polarizer 112 and a lower absorbing polarizer 114.
  • a liquid crystal layer 116 is sandwiched between the upper and lower absorbing polarizers 112 and 114. Glass layers (not shown) may be disposed between the absorbing polarizers 112 and 114 and the liquid crystal layer 116.
  • the display unit 102 operates by changing the polarization of certain portions of the light passing therethrough.
  • a color filter 118 is typically used to provide specific color to specific' pixels of the display unit 102. Color displays normally operate in the backlit mode. Under conditions of strong ambient light such as strong sunlight, however, color displays are difficult to view and the image appears washed out.
  • the transflector 106 reflects ambient light that has passed through the display unit 102 and it transmits light to the display unit 102 that has been generated by the backlight.
  • the display 100 is able to operate using either backlight, ambient light, or both.
  • Ambient light 120 in a polarization state that is transmitted through the absorbing polarizer 112 is transmitted through the liquid crystal layer 116 to the lower absorbing polarizer 114.
  • the light that has passed through the liquid crystal layer 116 is in a polarization state passed by the lower absorbing polarizer 114, the light is transmitted through to the transflector 106.
  • the light reflected 122 from the transflector 106 passes back through the display unit 102 and is viewed by the viewer.
  • the light 124 passing into the liquid crystal layer reaches the lower absorbing polarizer 114 in a polarization state that is absorbed.
  • the backlight optics unit 126 may comprise a light guide 128 for guiding light across the display 100 from the light source 110, which may be provided with a reflector, and for emitting light upwards towards the display unit 102.
  • the light guide 128 may comprise a transmissive wedge having its thick end 130 illuminated by the light source 110. Diffusive or diffusely reflective pads 132, 134 along one or both the upper and lower surface of the light guide 128 may be used to extract light from the light guide 128 towards the display unit 102.
  • the backlight unit 126 may also include a reflector 136 below the light guide 128, to reflect light that is transmitted through the lower surface of the light guide 128.
  • the reflector 136 may be a diffuse reflector or a specular reflector.
  • the backlight unit 126 may also include one or more light management optical films 138 for managing the light passing to the display unit 102.
  • the light management optical films may include one or more prismatically ribbed brightness enhancing films for steering the light more closely to the display axis 140.
  • One approach is to use two layers of prismatic brightness enhancing film, with the direction of the prismatic ribs one layer oriented approximately perpendicular to those of the other layer, so as to steer the light in two dimensions towards the display axis 140.
  • the backlight unit 126 may also include a reflective polarizer for reflecting light back to the diffuse reflector 136 that would otherwise be absorbed in the lower absorbing polarizer 114. Some light 142 emitted towards the transflector 106 is transmitted through the lower absorbing polarizer 114 and through the liquid crystal layer 116.
  • the polarization of the light emitted from the liquid crystal layer 116 into the upper absorbing polarizer 112 is in a polarization state that is passed by the upper absorbing polarizer 112, and is emitted as image light 144 towards the user.
  • Other light 146 transmitted towards the display unit 102 is transmitted through the lower absorbing polarizer 114 and is incident on a different portion of the liquid crystal layer 116. In this case, the light 146 reaches the upper absorbing polarizer 112 in a polarization state that is absorbed by the upper absorbing polarizer 112, and is not viewed by the user.
  • spatially selective polarization control of the light passing through the display unit 102 from the backlight unit 126 results in the user viewing an image formed by light emitted from the light source 110.
  • the transflector 106 may not reflect 100% of the incident ambient light, and may not transmit 100% of the incident backlight. This permits the display 100 to operate as a non-inverting display in which, for example, a lit blue pixel remains a lit blue pixel for both ambient and backlit illumination.
  • Monochromatic displays are commonly used in portable devices such as watches, cell phones and the like.
  • the type of information displayed on monochromatic displays is often alphanumeric in character, with little in the way of graphical information.
  • Such information does not need high spatial or gray scale resolution, or require constant color characteristics, and so the large variations in the characteristics of ambient light, for example when experienced by moving among sunlight, fluorescent lighting, and incandescent lighting, have little effect on the quality of the images produced by a monochromatic display.
  • the common default mode of operating a monochromatic display is under ambient illumination and, to increase battery lifetime, the backlight is only used as a supplement when there is insufficient ambient light.
  • the transflector in monochrome displays has commonly had a reflectivity in the range of 60% - 90%. Furthermore, the use of a backlight in monochromatic systems sometimes results in an inversion of the color of the image: what appeared to be dark on light under ambient lighting becomes light on dark under backlighting. For a monochromatic display, such inversion may be inconvenient to the user, but still maintains a viewable image.
  • Color displays have requirements that are much more exacting than for a monochromatic display.
  • One application where color displays have become commonly used is in laptop computers. Displays in laptop computers are usually transmissive displays, using only backlight illumination to form the image. This ensures constant color balance and gray scale. Under conditions of strong ambient light, for example direct sunlight, the image on a purely transmissive display becomes washed out because of a lack of contrast between the image and the ambient light reflected from the display screen. Therefore, under some lighting conditions, the purely transmissive display becomes unusable.
  • a transflector to a color display provides for image formation using the incident ambient light, in addition to the backlight.
  • the color display is able to operate in a wider variety of lighting conditions.
  • the transflector 106 transmits a significantly higher fraction of the backlight than in a monochromatic display.
  • the transmission through the transflector is in the range from about 10% - 99%, with a preferred range being from about 70% to about 90%. Assuming that there is no absorption in the transflector 106, this leads to a transflector reflectivity in the range from about 10% to about 30%.
  • color inversion in a color display results in the production of an image that looks like the color negative produced by photographic film.
  • non-inverting transflectors Such images are usually unacceptable to the user, and so the types of transflector usable with a color display are non-inverting transflectors.
  • a non-inverting transflector such as a partial reflector/partial transmitter, permits the addition of the ambient image to the backlit image, which permits the display to be used under a combination of both ambient and backlit illumination.
  • a transflector layer 210 comprises a first microstructured layer 212 and a second microstructured layer 214. Between the two microstructured layers 212 and 214 is a partial dielectric reflector 216, that fits to the forms of the microstructured layer 212 and 214.
  • the microstructured layers 212 and 214 are typically formed from optically transparent polymer materials.
  • metallic partial reflectors find widespread use for transflectors in monochromatic displays, metallic transflectors are less well suited to use with color displays.
  • the reflectivity of the transflector is relatively high, for example in the range from 60% - 90%.
  • the metallic transflector is fabricated from a relatively thick layer of metal.
  • the reflectivity of the partial reflector is lower, and may be in the range 10% - 30%.
  • a metallic partial reflector having a reflectivity ih this range has a number of disadvantages.
  • the reflectivity of a metallic layer is dependent on its thickness: such a low reflectivity requires a very thin metal film, which is difficult to deposit uniformly.
  • the color of a metallic partial reflector having low reflectivity is different from one having higher reflectivity. For example, a thin silver coating with low reflectivity transmits a higher fraction of blue light than a higher reflectivity coating, giving an overall yellow appearance to a reflected image.
  • a thin metallic layer is lossy, with a few percent of the light being lost due to absorption.
  • Pearlescent and pigment reflectors are also not well suited for use with color LC displays.
  • the levels of reflectivity and diffusivity are generally linked, and so the design parameters of the display unit are severely constrained.
  • the polarization of the scattered light may not be preserved, thus introducing further losses into the polarization-dependent LC display.
  • a preferred approach to providing the partial dielectric reflector 216 is to provide a layered dielectric structure.
  • a layered dielectric structure includes a number of dielectric layers having a different refractive index.
  • One example of a layered dielectric reflector 216 is a single layer of a relatively high refractive index material disposed over a lower refractive index structured surface.
  • an overlayer of a material having a relatively low refractive index may be on the other side of the relatively high refractive index layer from the lower refractive index structured surface.
  • overlayers include a layer of air, or a planarization layer such as layer 214.
  • multiple pairs of alternating high and low refractive index material may be provided to form the dielectric reflector.
  • the different layers For reflection optimized for a particular wavelength, ⁇ , the different layers have an optical thickness that is an odd number of quarter wavelengths, ⁇ /4.
  • the thicknesses of the layers For reflection optimized over a wavelength range, the thicknesses of the layers may be varied. The number, thickness and refractive index of the layers may be selected so as to provide a partial reflector having a desired reflectivity over a selected wavelength range.
  • the reflectivity of the partial reflector may be tailored to suit a particular angle of incidence on the partial reflector.
  • any suitable materials may be used in the layers of high and low refractive index.
  • polymers may be used for the different layers.
  • fluorinated polymers generally have a low refractive index and may be particularly advantageous for use in the low index layer or layers.
  • Polymers that have dispersed nano-ceramics may have a high refractive index and may be particularly advantageous for use in the high refractive index layer or layers.
  • Non-polymeric, dielectric materials may also be used.
  • Some metallic-based materials useful for the layer or layers of high refractive index include titanium dioxide, tin oxide, indium tin oxide and zinc sulfide.
  • Some non-polymeric materials that may be useful for the relatively low refractive index layer include magnesium fluoride, silicon dioxide and the like.
  • the refractive index of the substrate may lie in the range from approximately 1.3 - 1.8, and the refractive index of the dielectric reflector lies in the range from approximately 1.8 - 2.3. If no planarization layer is present, then the refractive index of the material above the dielectric reflector is about 1 if the reflector lies in air. Where a planarization layer is present, the refractive index of the material above the dielectric reflector may lie in the range from approximately 1.3 - 1.8.
  • the layered dielectric reflector may include a number of layers of dielectric material, whose thicknesses are not necessarily selected so that the optical thicknesses are an odd integer multiple of a particular quarter wavelength. In such a case, reflection between such layers is not necessarily coherent, as is the case for a quarter wavelength stack.
  • a dielectric reflector layer unlike the metallic reflector, the color qualities are not directly linked to the value of reflectivity. Instead, the value of reflectivity is related to the refractive index difference between layers and the number of layers. Also, a dielectric reflector does not introduce absorption loss.
  • diffusive particles may be introduced to the transflector, for example in the reflective layer or layers, or in adjacent layers. The diffusive particles may be formed of a material having a small difference in the refractive index from the host material, and so the size of the scatter angle may be reduced and the amount of depolarization also reduced.
  • the level of reflectivity of the dielectric transflector is not linked to the amount of diffusion, thus affording greater design flexibility.
  • the transflector 206 is to first form one of the microstructured layers 212 and 214 using a suitable technique for forming a microstructured surface.
  • the lower microstructured layer 212 may be formed by using a patterned tool for molding the microstructured layer 212 on the substrate 218.
  • the lower microstructured layer 212 may be thermally embossed on the substrate 218.
  • the lower microstructured layer 212 may be made from the same material as the substrate 218, or may be made from a different material from the substrate 218.
  • the substrate 218 may be formed from a relatively flexible material, such as a polyester film, a polycarbonate (PC) film, a tri-acetate cellulose (TAC) film, or the like, or may be formed from a relatively rigid substrate, such as a thick PC layer, an acrylic layer, a glass layer or the like.
  • the substrate 218 may be separate from other components in the display, or may comprise another display component.
  • the substrate 218 may be the lower surface of the display unit, for example a glass layer or absorbing polarizer.
  • the substrate 218 may be a layer from the backlight optics unit 138, such as a reflective polarizer, for example, a multi-layer reflective polarizer or a cholesteric polarizer.
  • the reflective polarizer may form part of the backlight optics unit 138.
  • the remaining microstructured layer 214 may then be formed using a planarization process, such as knife coating or calendering roll.
  • the planarization process may use materials such as radiation cured acrylates, or solvent-cast polymers.
  • the upper microstructured layer 214 may be formed with a material that is compatible with long useful life of the partial reflector 216.
  • Optional layer 220 is an additional adhesive layer that may be used for attaching the transflector 206 to another element, for example the lower absorbing polarizer of the display unit.
  • layer 220 may be omitted and layer 214 formed from an adhesive material, so that the planarization layer 214 is also an adhesive layer that is capable of attaching the transflector 206 to the lower surface of the display unit 102.
  • the pitch, P the length of the angled reflector 224 of the microstructured partial reflector 216, may be selected to reduce Moire effects formed between the transflector and the display unit 102.
  • the pitch may be selected so that more than one angled reflector 224 is associated with each picture element of the display unit.
  • the base angle of the angled reflector 224 is labeled as ⁇ .
  • the partial reflector 216 may be constructed to provide selective angular control of the direction of the reflected light 228 from the incident light 226. In this way, incident ambient light passing through the display unit 102 may be directed along a preferred direction and away from glare. Glare tends to arise from specular reflections of the incident ambient light from other surfaces in the display.
  • Transmitted light 230 for example from a backlight, passes through the transflector 206 and, where the refractive indices of the layers 212 and 214 are the same, may pass through the transflector 206 without being refracted.
  • the base angle, ⁇ is typically in the range 2° - 20°, and is more preferably in the range 6° - 10°.
  • FIG. 2B shows a substrate 248 attached, via an adhesive layer 250, to the lower layer 252 of the display unit 102.
  • the dielectric reflector 246 is deposited on the substrate 248 and a planarization layer 242 provides a substantially planar lower surface 243 for light passing form the light source to the display unit.
  • a holographic surface 262 is formed on a substrate 264.
  • the holographic surface 262 is covered with a dielectric reflector 266.
  • the dielectric reflector 266 takes on the surface structure of the holographic surface, and functions as a holographic reflector.
  • the dielectric reflector 266 may, because of the shape of the underlying holographic surface, be structured to preferentially reflect light into a direction other than a specular direction.
  • the dielectric reflector 266 may be structured to reflect ambient light 270 incident in a direction of -30° in a direction 272 normal to the transflector 260, rather than in a direction of +30°.
  • the transflector 260 may be provided with a planarization layer 268, which may be an adhesive layer and which may include diffusive particles.
  • the display 300 lies in an x-y plane.
  • the line 302 normal to the display 300 is referred to as the center line, and is parallel to the z-axis.
  • Directions having a component in the +y direction are referred to as down, and directions having a component in the -y direction are referred to as up.
  • Directions having a component in the +x direction are referred to as left, and directions having a component in the -x direction are referred to as right. It is useful under some circumstances for the reflected image light to be separated from the glare, in which case the base angle, ⁇ , is not equal to zero.
  • the base angle, ⁇ is approximately 10° (light is reflected at an angle approximately equal to 2 n ⁇ , where n is the refractive index of the material in which the light is propagating before and after it is reflected by the reflector).
  • the adhesive layer 220 may provide diffusion.
  • the adhesive layer 220 may be provided with diffusing particles in an adhesive matrix. This, however, is typically a rotationally symmetric diffusion, producing the same diffusion angle in the left-right direction as in the up-down direction. In some circumstances, it may be preferred to spread the image light along preferred viewing directions, rather than to have a rotationally symmetric diffusion. In this way, high reflected brightness may be achieved while maintaining high backlight transmission.
  • ambient light is typically incident from above, in the up- center plane, exemplified as beam 310.
  • the ambient light is incident on the display 300 at an angle of ⁇ g .
  • the resulting glare which may have some degree of angular spreading due to a small degree of diffusion, is typically centered around the beam 312, also at an angle ⁇ g .
  • transflector 506 One particular approach to providing selective angular reflective control without relying on a diffuser that scatters light symmetrically in all directions is to use a transflector having angled reflectors at different angles to the plane of the transflector.
  • a transflector 506 is schematically illustrated in FIG. 5. Only one microstructured layer 508 of the transflector is illustrated, for clarity. It will be appreciated that the partial reflector is disposed to fit the form of the microstructured layer 508, and that a planarization layer may be provided over the partial reflector.
  • the transflector 506 comprises sets 509 of three angled reflectors 510, 512 and 514 having respectively different base angles ⁇ 1 , ⁇ 2, and ⁇ 3.
  • Such a structure may be used to control the spread of the reflected image light in a plane perpendicular to the axis of the prisms that form the reflectors, through the selection of an appropriate range of prism base angles.
  • the pattern of reflectors may be made to have a unit cell of repetition that is equal to or smaller than the dimension, d, of a display picture element (pixel) of the display unit 502.
  • the set of reflectors 509 may have some other number of reflectors, for example two, four or more.
  • the set of reflectors 509 may include the reflectors in any desired order.
  • the reflectors may be arranged in order of increasing base angle (as illustrated), decreasing base angle or in a randomized order.
  • the reflectors forming the set of reflectors 509 may all have the same pitch, or may have different pitches, for example as illustrated in FIG. 5B.
  • FIG. 6 shows a plot similar to that of FIG. 4, but where the unit cell was formed from a number of angled reflectors whose base angles ranged from 6° to 20° in steps of 1 °.
  • the viewing angle response is spread primarily in the center-to-up range. Some diffusion was assumed to accommodate some lateral light spread. If, instead, it were preferred to fill in the center-to-down viewing direction, then angled reflectors having base angles in the range of less than 10° may be used.
  • FIG. 7A shows a microstructured layer 702.
  • the partial reflector layer 704 is deposited over the microstructured layer 702 to have the same form as the microstructured layer 702.
  • a planarized layer (not shown) may be added over the partial reflector.
  • the reflectors 706 have nonlinear facets 708.
  • the facets 708 may have a radius of curvature, may be non-spherical, or may be a series of discrete linear segments 718, as shown in FIG. 7B.
  • a number of reflectors 706 may be associated with a pixel of the display unit.
  • the reflectors 706 associated with one pixel may have the same non-linear shape, or may have different non-linear shapes.
  • FIG. 7C A plot showing the calculated performance of a transflector having curved facets covering a range of facet angles from 6° to 20° is shown in FIG. 7C.
  • the filling along the center-to-up direction is evident, with diffusion added only to accommodate a slight lateral spread. Filling of a different range of viewing angles may be achieved using facets with different non-linear profiles.
  • the amount of lateral spreading may be relatively small relative to the amount of center-up spreading.
  • the facets of the reflectors may be modulated to provide some lateral spreading.
  • Such lateral spreading may be provided along with rotationally symmetric diffusion, for example from a bulk diffuser or may be provided without any rotationally symmetric diffusion.
  • FIG. 8A shows a reflector facet 804 having a generally curved surface 806.
  • FIG. 8B shows a reflector facet 814 having a randomly, or pseudo-randomly curved surface 816.
  • Such surface modulation provides for lateral spreading of the reflected light in a direction perpendicular to the tilt of the reflector facet.
  • the modulation of the reflector facet may be provided by modulating the depth of the cutting tool when creating the master mold or embossing tool.
  • the modulation may be registered from facet to facet, or may be misaligned, or may be random or pseudo-random from facet to facet. It will be appreciated that lateral diffusion may also be introduced using other approaches, for example using a bulk diffuser layer.
  • a certain subset angular viewing range is more preferred over other angles.
  • a user may desire that the display brightness be highest near the center and correspondingly less as more extreme down positions are sampled.
  • the resulting structure may be different from those illustrated above.
  • the frequency of the base angles or facet curvatures that provide ambient reflectance near center viewing direction are selected to have a higher frequency than those of base angles/curvatures providing ambient reflectance contributing to the extreme down viewing direction. This is described with reference to FIG. 9, which shows the predicted performance of several constructions based on changing the base angle frequency of a collection of flat reflector facets. In the graph, several sets of different base angle frequencies are shown.
  • Curve 902 shows a microstructured surface having 10° reflector facets only. In this case, the groove frequency is 1.0, or 100% for 10° facets. The resulting normalized axial flux of 1.0 is shown by data point 910. Other patterns are compared against this baseline performance.
  • Curve 904 denotes a microstructured surface with 60% 10°facets, 30% 9° facets and 10% 8° facets.
  • Curve 906 denotes a different frequency of facets with base angles ranging from 10° to 7°. Providing facets at an angle of less than 10° generates a light spread along the down viewing direction. If, however, the frequency of facets having a base angle of less than 10° is reduced relative to the frequency of those facets with a higher base angle, then the axial brightness may be increased.
  • the respective axial brightness values are given by data points 920 and 930.
  • curve 908 denotes the uniform case where the facets of base angles ranging from 6° to 20° have equal frequency.
  • the corresponding axial performance is denoted by point 940.
  • the resulting axial brightness about 30%, significantly lower than in the other cases described.
  • the reflected angular output of the microstructured transflector may be tuned or optimized along a preferred viewing direction, independent of added symmetric diffusion, to meet the specific requirements of the particular viewing device being used.
  • the microstructured transflectors described so far operate in a "grooves up" orientation.
  • the ambient light first strikes the facet side of the microstructured construction while a piano-surface is on the opposite side.
  • Any or all of the described embodiments may be oriented in a "grooves down" configuration, in which the ambient light first passes through the piano-surface of the transflector before incidence on the microstructured surface.
  • any layer between the display unit's lower polarizer and the transflector be polarization preserving so as to maintain as large a portion of the incident ambient light as possible.
  • Candidate substrates for a "grooves down" configuration may be an isotropic film such as polycarbonate or an absorbing or reflective polarizer. Incorporation of a reflective polarizer can provide the added benefit of polarization recycling for enhanced backlight operation.
  • a transflector like the transflector 206 shown in Fig. 2, was fabricated using a single indium tin oxide (ITO) reflective layer 216 over a first microstructured layer 212 formed on a polyester substrate 218.
  • the microstructured layer 212 had a composition of 74 wt.% aliphatic urethane, 25 wt. % hexanediol diacrylate and 1 wt. % Darocur 1173, 2 hydroxy-2-methyl-1phenyl-propan-1-one.
  • the microstructured layer 212 had a refractive index of 1.49.
  • the reflective layer 216 had a quarter-wave thickness at about 550 nm, and had a refractive index of 1.9.
  • the planarization layer 214 was formed from a layer of butyl acrylate adhesive having a refractive index of 1.47. Styrene beads were disposed within the planarization layer 214 to provide some diffusion.
  • the base angle, ⁇ , of the structured layer 212 was 6°.
  • sample A The example, referred to as sample A, was tested in comparison with two other displays.
  • Sample B was a commercially available transmissive color LC display and
  • Sample C was a commercially available transflective color LC display, A3013T, used in Toshiba cell phones, that had a partial metal reflector positioned within the LC unit itself.
  • Table I The different samples are summarized in Table I
  • a spot light measurement was performed, in which the display was illuminated with a collimated light beam incident on the surface at an angle of 30° to normal, and a detector on a goniometric mount was swept over an angle to measure the light reflected from the display as a function of reflection angle.
  • the goniometric spot light results for the three samples outlined Table I are provided in FIG. 10. All samples showed a large reflection peak centered around +30°, off to the right of the graph, corresponding to specular reflection of the illumination light. The width of this reflection peak was affected by such factors as divergence of the illuminating light and amount of diffusion of the light when reflected. The results are normalized against reflection off a standard white diffuse reflector, Model No. SRS-99-020 manufactured by Labsphere, North Sutton, New Hampshire.
  • the backlit performance of samples A, B and C were tested using the same backlight assembly.
  • the backlight assembly used an edge-lit lightguide using 3 LEDs, a diffuser sheet, and two brightness enhancing films.
  • a luminance ratio calculation of the display under test to the bare backlight yielded the effective transmission of the display system. The results are shown in Table II.
  • Sample A with a 6° structured transflector, preserved over 86% of the original backlight output, compared to the transmissive display of sample B. This compared very favorably to the transflective display with the internal transflector, sample C. Sample A provided almost 2.4 times the backlight brightness of sample C.
  • the different components in each sample that contribute to the transmissive losses should be considered to explain the measured difference in backlight transmission.
  • the major components of loss include: absorbing polarizers, aperture ratio (transmissive area through the patterned mirror or around the black matrix), color filters, and LC polarization response. It is assumed that the front and rear absorbing polarizers in Samples A, B and C provide similar transmission, even though sample C uses an anti-reflection treated front polarizer. This AR treatment will only provide a few percent transmission difference, however.
  • the color of the light reflected during the spot light test was measured, as a function of angle. The color was determined for each angle measured, and the color of the light reflected at each angle is plotted in the color diagram in FIG. 11 as an (x, y) co-ordinate. Curves 11-A, 11-B, 11-C, are shown for each sample, along with a set of (mostly superimposed) points for reflection off a white diffuse reflection standard, shown as 11-D. There is very little shift in the color of light reflected from the reflection standard, as the angle of detection is varied.
  • the point that corresponds to a measurement made at 24°, approaching the glare peak at 30° is marked.
  • the measurements were made at 1° intervals over the range -6° - 24°, corresponding to the measurements made to produce FIG. 10.
  • the spread of the points for sample A is relatively small, apart from the two points closest to 24°, indicating that there is little color shift in the ambient image over the range.
  • the spread in the points in curve 11-A may be reduced further with optimization of the thickness of the single ITO layer and/or with the addition of further layers in the dielectric partial reflector.
  • the color of the light transmitted through the different sample displays was measured. For these measurements, the color of the backlight, operating without a display module, was first measured, thus establishing a color standard against which the different display samples compared. A chromaticity meter was positioned along the display normal, and the color of the light transmitted through the different sample displays was recorded. The axial color difference was calculated using the 1931 CIE chromaticity space. The results are shown in FIG. 12
  • samples A and B provided very little change as evidenced by the small change in both x and y color coordinates from the bare backlight baseline (points 12-A and 12-B respectively).
  • Sample C the internal mirror display, showed the largest color shift (point 12-C).
  • the reflected light is angularly separated from the glare asymmetrically.
  • the image light reflected by the transflector is preferentially directed to one side of the glare peak. This approach is particularly useful, although it not limited to, a situation where the positions of the viewer and the ambient light source relative to the display are substantially constant.
  • the reflected image light may be directed so as to substantially surround the glare peak.
  • the image light reflected by the transflector propagates in different directions about the glare peak.
  • the viewer is able to view the reflected image from a wider range of azimuthal angles about the normal to the display.
  • This approach is useful, but is not limited to, a situation where the positions of the viewer and the ambient light source relative to the display are not known, or are variable.
  • the display 1300 has a display unit 1302, such as a liquid crystal display, disposed over a transflector 1306.
  • the transflector 1306 comprises a substrate 1310 that has a structured surface 1312.
  • a dielectric partial reflector layer 1316 is disposed on the surface 1312 and substantially adopts the shape of the structured surface 1312.
  • the dielectric partial reflector layer 1316 may be formed using any of the dielectric approaches described above.
  • An overlayer 1318 may be placed over the partial reflector layer 1316.
  • the overlayer 1318 may be a planarization layer.
  • Light ravs 1320 and 1322 represent light from the ambient light source.
  • Ray 1324 is reflected by the display unit 1302 at an angle of ⁇ 1 relative to the display normal 1330.
  • Ray 1324 represents undesirable glare that interferes with the visibility of the image caused by the display 1300.
  • Ravs 1326 and 1328 are reflected by the structured partial reflector layer 1316 and represent light that has passed through the display unit 1302. Therefore, ravs 1326 and 1328 contain image information.
  • Ray 1326 reflects off an "uphill" portion of the partial reflector 1316, and so is directed closer to the normal 1330 to the display, at an angle ⁇ 2.
  • Ray 1328 reflects of a "downhill" position of the partial reflector 1316. and so is directed further away from the normal 1330. at an angle ⁇ 3.
  • the substrate 1310 and the structured surface 1312 are shown in greater detail in FIG. 13B.
  • the range of angles over which the ravs 1326 and 1328 maV be reflected by the partial reflector 1316 depends on the shape of the structured surface 1312.
  • the structured surface 1312 comprises a number of scallops 1332 whose surfaces form a maximum angle of ⁇ relative to the plane 1334. Where the angle ⁇ is larger, the light reflected by the transflector 1306 is spread over a larger range of angles.
  • the scallops 1332 are defined by known curves, for example where the scallops 1332 are arcuate, the angle ⁇ may be determined from the pitch. P. and the depth, d. of the scallops.
  • the structured surface 1312 may be provided with other types of profiles.
  • the structured surface may be convex, rather than concave, or may employ a curve different from a scallop, for example a continuous curve such as a sine curve.
  • the structured surface may be formed as a regular pattern or an irregular pattern.
  • An irregular pattern may include, for example, an irregularity in pitch, feature height or both.
  • the structured surface 1312 may be considered to comprise a number of reflecting units, where each reflecting unit includes a surface that varies over a range of angles.
  • each scallop 1332 has portions of the surface ranging in angle between - ⁇ and + ⁇ . and may be considered to be a reflecting unit.
  • the size of a reflecting unit may be less than the size of a pixel of the display unit 1302. in which case each pixel of the display unit 1302 may be associated with more than one respective reflecting units of the transflector 1306.
  • FIG. 14A An example of a structured surface that may be used with a transflector is schematically presented in FIG. 14A.
  • the surface 1400 is characterized as having a x-axis and a y-axis, as shown.
  • FIG. 14B A cross-section along the x-direction is schematically illustrated in FIG. 14B.
  • the structured surface 1412 is scalloped, with an arrangement of neighboring bumps.
  • the spacing or pitch of the bumps may be selected to avoid Moire effects that result from an interaction with other periodic structure present in the display, such as the pixellated structure of the liquid crystal display unit.
  • the pitch of the bumps may be selected to form an irrational number when divided by the period of the other structure.
  • the pitch of the bumps themselves may be varied across the surface.
  • the height of the adjacent bumps on the surface 1412 may be different.
  • the surface 1412 was also scalloped along the y-direction.
  • the shape of the cross-sections in the x- and y-directions need not be the same and need not be scalloped.
  • the cross-section in one or more directions may be sinusoidal, as is schematically illustrated in FIG. 14C, or may include another shape.
  • the pitch of the surface 1412 in each direction may also be selected to be avoid Moire effects or other arising from an interaction with another periodic structure in the display.
  • the structured surface 1412 may also be positioned relative to the other periodic structure with a small rotation about a normal to the transflector, so the x and y-axes of the transflector are not aligned with the axes of the periodic structure.
  • An advantage of using a structured transflector, such as that shown in FIG. 14A, over using a plane, diffusive partial reflector is that the structured transflector provides spreading of the reflected image light over a particular viewing cone angle, while providing the ability to avoid significantly changing the angular distribution of the image light from the backlight.
  • a plane, diffusive partial reflector spreads both reflected ambient light and backlight. The preservation of backlight collimation is important where high axial gain is desired.
  • the calculated viewing cone response for a transflector as illustrated in FIG. 14A is presented in FIG. 15.
  • the model assumed that the pitch in the x-direction was 29.2 ⁇ m and had a radius of 245 ⁇ m, leading to a maximum slope angle of 3.41 ° and a depth, or sag, of 0.43 ⁇ m.
  • the surface 1412 was scalloped, with a pitch of 87.6 ⁇ m, and a radius of 502.5 ⁇ m, leading to a maximum slope of 5° and sag of 1.91 ⁇ m.
  • the model is explained with reference to FIG. 16.
  • a nearly-collimated light ray 1610 is directed, at a polar angle, ⁇ , of -30° along the 180° azimuth direction (in the y-z plane, from the +ve y side), to the structured surface of the transflector sample 1600.
  • the glare peak arising from specular reflection of the incoming light, is found at a polar angle, ⁇ , of +30°, along the 0° azimuth direction, light ray 1612.
  • the primary reflected light distribution from the structured transflector is shown in FIG. 15 as the gray square surrounding the glare peak (darker point in the center of gray area at a polar angle of + 30° and azimuth angle of 0°).
  • the reflected light distribution is nearly symmetric in angular extent along both vertical and horizontal directions.
  • Adjusting the maximum slope of the structured surface results in a change in the angular extent of the reflected light distribution shown in FIG. 15.
  • Providing a higher slope increases the angular extent of the reflected viewing cone, while a smaller slope reduces the cone size.
  • separate slope profiles are provided in two orthogonal directions, the x-direction and the y- direction.
  • the angular extent of the output reflected light distribution is also controlled along these two directions.
  • orthogonal slope profiles to create symmetric or asymmetric reflected light distributions. It will be appreciated, however, that the slope need not be defined only along two orthogonal directions
  • the structured surface may have a number of randomly positioned round bumps: each round bump reflects light symmetrically in azimuth, and there is no preferred direction for reflection.
  • a slightly diffuse layer may be provided between the structured surface and the liquid crystal display for fine tuning of the viewing cone or for improving the cosmetic appearance of the display.
  • the transflector may be bonded to the liquid crystal display device using a pressure sensitive adhesive or other suitable adhesive, or may be associated with the liquid crystal display as a free-floating or other component element of the backlighting system. Example.
  • a molding tool for molding a structured surface was formed by diamond turning a copper drum. The drum was rotated and a thread cut around the drum surface. Design parameters for the tool were that the thread had a pitch of 39.8 ⁇ m and a nominal depth of 0.53 ⁇ m, to give a maximum expected slope of 3°.
  • the thread was cut with a diamond tool having a cutting edge with a radius of 375 ⁇ m.
  • the depth of the thread cut was varied by driving the depth of the cutting tool with a predetermined sinusoidal variation of 1.16 ⁇ m, to produce a pitch of 87.6 ⁇ m.
  • the maximum expected slope of the sinusoidal cut was 3°.
  • the tool was used to form a structured surface on a substrate using the following method.
  • a resin was distributed between a layer of polyester and part of the molding tool.
  • the resin was 74 wt.% aliphatic urethane, 25 wt. % hexanediol diacrylate and 1 wt. % Darocur 1173, 2 hydroxy-2-methyl-1 phenyl-propan-1-one.
  • the resin was UV cured by directing UV light through the polyester layer.
  • the polyester layer/cured resin sheet was removed from the molding tool.
  • the cured resin sheet had a structured surface having a sinusoidal cross-section in the down- thread direction, like that shown in FIG. 14C and a convex lenticular cross-section in the cross-thread direction, like that shown in FIG. 14B.
  • the back surface of the substrate was blackened so that only a reflection form the structured front surface would be detected.
  • FIG. 16 shows a test surface 1600. Nearly- collimated light 1610 is directed to the surface 1600 and the reflected light is detected by moving a detector in the y-z plane. The specularly reflected light 1612 is detected at a polar angle, ⁇ g , that is equal to the polar angle of the incident light 1610.
  • ⁇ g a polar angle
  • the reflection was measured off a flat sheet of black polymethylmethacrylate (PMMA).
  • PMMA polymethylmethacrylate
  • the PMMA only produced specular reflection.
  • the distribution of the detected light is shown as curve 1702 in FIG. 17.
  • the cone angle of the incident light was approximately 5.5°, full width half maximum (FWHM).
  • the uncoated structured surface was substituted as the test surface 1600.
  • the fiduciary mark shown as an arrow 1614 points in a direction parallel to the y-axis (referred to as the 12 o'clock position).
  • the reflected light distribution is shown as curve 1704, which has a significantly broader peak than the incident light, about 13° (FWHM).
  • the sample was then rotated about the normal 1602 through an angle of 90°, so that the fiduciary mark 1614 pointed in a direction parallel to the x-axis (referred to as the three o'clock position).
  • the distribution of reflected light, when the sample was in the three o'clock position, is shown as curve 1706.
  • the width of the reflected light distribution in the three o'clock position was about 11 ° (FWHM).
  • the sample was rotated through another 90°, so that the fiduciary mark 1614 pointed in the -ve y-direction (referred to as the six o'clock position).
  • the distribution of reflected light, when the sample was in the six o'clock position, is shown as curve 1708.
  • the width of the reflected light distribution in the six o'clock position was about 13° (FWHM).
  • the sample was rotated through another 90°, so that the fiduciary mark 1614 pointed in the -ve x-direction (referred to as the nine o'clock position).
  • the distribution of reflected light, when the sample was in the nine o'clock position, is shown as curve 1710.
  • the width of the reflected light distribution in the nine o'clock position was about 9.5° (FWHM).
  • Curves 1704 and 1708 corresponding to the structured surface in the 12 o'clock and 6 o'clock positions, almost exactly overlap, which shows that the structure in this direction was fairly symmetrical about the surface normal. These two curves correspond to the grooves formed on the surface structure in a direction along the thread cut of the tool.
  • Curves 1706 and 1710 correspond to the surface structure in a direction across the thread cut of the tool. Curves 1706 and 1710, corresponding to the structured surface in the 3 o'clock and 9 o'clock positions are close, but do not overlap as well as curves 1704 and 1708. This suggests that the shape of the structured surface across the thread cut, for this particular example, is less symmetrical than along the thread cut.
  • the present invention is applicable to transflective liquid crystal displays and is believed to be particularly useful for reducing the specular reflection of ambient light that overlaps the image.
  • the present invention should not be considered limited to the particular examples described above, but rather should be understood to cover all aspects of the invention as fairly set out in the attached claims. Various modifications, equivalent processes, as well as numerous structures to which the present invention may be applicable will be readily apparent to those of skill in the art to which the present invention is directed upon review of the present specification. The claims are intended to cover such modifications and devices.
EP04750696A 2003-05-05 2004-04-27 Strukturierte transflektoren für flüssigkristallanzeigen Withdrawn EP1631860A1 (de)

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US10/429,601 US7088405B2 (en) 2003-05-05 2003-05-05 Structured transflectors for enhanced ambient and backlight operation of transmissive liquid crystal displays
US10/828,693 US7385659B2 (en) 2003-05-05 2004-04-21 Structured transflectors for enhanced ambient and backlight operation of transmissive liquid crystal displays
PCT/US2004/012866 WO2004099869A1 (en) 2003-05-05 2004-04-27 Structured transflectors for liquid crystal displays

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JP5608385B2 (ja) * 2010-02-08 2014-10-15 デクセリアルズ株式会社 光学体およびその製造方法、窓材、建具、ならびに日射遮蔽装置
JP5508946B2 (ja) * 2010-06-16 2014-06-04 デクセリアルズ株式会社 光学体、窓材、建具、日射遮蔽装置、および建築物
JP4888585B2 (ja) 2010-06-16 2012-02-29 ソニー株式会社 光学体、壁材、建具、および日射遮蔽装置
JP5454443B2 (ja) * 2010-09-30 2014-03-26 カシオ計算機株式会社 液晶表示装置
JP2012018424A (ja) * 2011-10-18 2012-01-26 Sony Corp 光学体、壁材、建具、および日射遮蔽装置
JP2014222359A (ja) * 2014-07-10 2014-11-27 デクセリアルズ株式会社 光学体およびその製造方法、窓材、建具、ならびに日射遮蔽装置
JPWO2018190434A1 (ja) * 2017-04-13 2020-05-14 コニカミノルタ株式会社 スクリーン及び画像表示装置
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