EP1597343B1 - Wäscheweichspülmittel - Google Patents

Wäscheweichspülmittel Download PDF

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Publication number
EP1597343B1
EP1597343B1 EP04713130A EP04713130A EP1597343B1 EP 1597343 B1 EP1597343 B1 EP 1597343B1 EP 04713130 A EP04713130 A EP 04713130A EP 04713130 A EP04713130 A EP 04713130A EP 1597343 B1 EP1597343 B1 EP 1597343B1
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EP
European Patent Office
Prior art keywords
composition
fabric
water
weight
fabric softening
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Revoked
Application number
EP04713130A
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English (en)
French (fr)
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EP1597343A1 (de
Inventor
Mark Laing
Laura Roscioli
Roberto Vanin
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Reckitt Benckiser NV
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Reckitt Benckiser NV
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742—Nitrogen containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/384—Animal products
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/15—Proteins or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/02—Wool

Definitions

  • the present invention relates to fabric softening compositions that not only provide excellent fabric softening benefit but also protect the fabric, especially wool fabric, from felting.
  • the fabric softening composition contains, in addition to common ingredients found in such compositions, at least one derivatised carbohydrate thickener that is substantive to the fabric, a fabric softening silicone compound and at least one protein or derivative thereof.
  • WO-A-00/40687 describes a fabric softener including a cationic softening active, a water soluble protein, a fabric fibre-substantive thickener, a fabric softening silicone and water.
  • the object of the present invention is to provide a fabric conditioner composition which not only provides excellent fabric softening benefit but also protects the fabric, especially wool fabric, from felting.
  • Felting is the process whereby fibres, in particular wool fibres, become impossibly matted. In particular it can be a problem with the use of warm/hot "soapy water" during the washing process, which opens up the wool fibre structure. When the wool fibres are cooled in the rinse cycle this can lock the fibre structure into a matted state.
  • Clearly a product that can protect against felting, especially during the rinse cycle has a major benefit in helping garments retain their original size and finish.
  • compositions preferably have a medium to high viscosity (by medium to high viscosity we mean from 50 to 50,000 cps, preferably from 100 to 1,500 cps, as measured using a Brookfield LVT viscometer, spindle no. 2 at 12 rpm and at 20°C.
  • medium to high viscosity we mean from 50 to 50,000 cps, preferably from 100 to 1,500 cps, as measured using a Brookfield LVT viscometer, spindle no. 2 at 12 rpm and at 20°C.
  • the present invention may suitably be used for fabric comprising natural and/or man-made/synthetic fibres.
  • Such fibres can be comprised of protein (for example wool, silk), cellulose (for example linen, cotton, jute), regenerated cellulose (for example viscose, lyocell), a cellulose derivative (for example acetate, triacetate), an acrylic, a polyamide or a polyester.
  • protein for example wool, silk
  • cellulose for example linen, cotton, jute
  • regenerated cellulose for example viscose, lyocell
  • a cellulose derivative for example acetate, triacetate
  • acrylic for example acetate, triacetate
  • composition comprising:
  • a cationic fabric softening active is an essential ingredient of the invention.
  • Typical levels within the compositions are from 3 to 45%, preferably from 4 to 20%, ideally from 4 to 15%, by weight of the composition.
  • the preferred, typical, cationic fabric softening actives include the water-dispersible quaternary-ammonium fabric softeners or amine precursors thereof:
  • Preferred quaternary ammonium compounds herein have the formula (I) or (Ia), and include a mixture thereof; [R'-(CO)-O-R-N + (R")(-(RO) n H)(R-O-(CO)-R')]X - (I) [R'-(CO)-NH-R-N + (-R 1 )(-(RO n H)(-R-NH-(CO)-R')]X - (Ia) wherein:
  • Non-limiting examples of softener-compatible anions include chloride, formate, nitrate, sulfate or C1-4alkyl sulfate, preferably methyl sulfate.
  • the alkyl or alkenyl R' ideally must contain at least 10 carbon atoms, preferably at least 14 carbon atoms, more preferably at least 16 carbon atoms.
  • the group may be straight or branched.
  • Unsaturated fatty acid and partially hydrogenated fatty acid derived from vegetable oils are usually convenient and relatively inexpensive sources of long chain alkyl and alkenyl material.
  • the preferred compounds wherein R' represents these mixtures of long chain materials includes, but is not limited to, rape-seed oil, canola oil, peanut oil and sunflower oil.
  • a preferred, non-vegetable sourced, R' group is tallow.
  • a specific example of quaternary ammonium compounds suitable for use in the invention is di-(tallow carboxyethyl)hydroxyethylmethyl ammoniumX - .
  • the softener compatible anion (X - ) is merely present as a counterion of the positively charged quaternary ammonium compound.
  • the nature of the counterion anion is not critical at all to the practice of the present invention.
  • the scope of this invention is not considered limited to any particular anion.
  • amine precursors thereof is meant the secondary or tertiary amines corresponding to the above quaternary ammonium compounds, said amines being substantially protonated in the compositions due to the pH values of the composition.
  • One or more of, at total levels of up to 20%, 10% or 5% by weight of the composition the following may also be added alongside the cationic fabric softener as a co-softening ingredient;
  • the thickener is a derivatised carbohydrate.
  • the thickener is present in the composition in amounts of from 0.01% to 10%, preferably from 0.05% to 8%, and even more preferably from 0.1% to 5%, by weight.
  • the thickener is substantive to the fibre of the fabric being treated, this means that the thickener associates with the fibre of the fabric treated, remaining, at least in part, on the fibre after rinsing and drying. It will be appreciated that the thickener selected will not necessarily be substantive to all possible types of fabric fibre, especially synthetic fibre. It is preferred that the thickener selected is one that is substantive to natural fibres, especially cotton or wool. Therefore, the thickener is preferably positively charged at the pH of the composition.
  • Examples of derivatised carbohydrates are water soluble polymers.
  • water-soluble we mean that the thickener is found in the majority, greater than 90%, in the water phase rather at 25°C than the oil phase of the composition.
  • Quaternary ammonium derivatives of carbohydrates especially of chitins and guar gums, are of particular interest, such as, quaternary ammonium guar gums.
  • a preferred derivative includes those modified with a cationic group, which additionally may also be modified with a nonionic group first.
  • a preferred cationic group is quartenary ammonium, ideally selected from one of the following; [N(R1)(R2)(R3)(R4)] + X - wherein R1 is a monohydroxylated or polyhydroxylated C1-6alkyl; R2 and R3 are independently, C1-6alkyl; R4 is a C1-24alkyl group; and X - is a counterion, as defined above.
  • Representative classes include quaternary ammonium group-containing glycogen, gum or chitin polysaccharides.
  • the composition comprises of at least one type of water-soluble protein or chemically modified derivative.
  • the protein may be derived from either animal or vegetable sources or by fermentation. Ideally the protein is not an enzyme. Preferably the protein has been dematured.
  • the term protein is used to include both native and hydrolysed proteins comprising proteins properly so-called and polypeptides, peptides and peptones (the latter can all be categorised as hydrolysed proteins).
  • the protein source is selected from; wheat, cotton, silk, keratin, collagen, elastin, casein, and soya.
  • water-soluble we mean that the material is found in the majority, greater than 90%, in the water phase at 25°C rather than the oil phase of the composition.
  • Preferred chemical modification to produce the derivative includes, esterification or etherification of hydroxy or carboxy groups, acylation of amino groups, quartenisation of amino groups or covalent bonding to the amino groups of the protein.
  • the Mw of the protein or chemically modified derivatives is preferably from 500 to 500,000 Daltons, ideally from 1,000 to 20,000 Daltons.
  • Preferred derivatives are alkyl quaternary derivatives or silicone derivatives.
  • quaternary ammonium derivatives which may be useful in the present invention include quaternary ammonium derivatives of wheat protein, keratin, silk, elastin and collagen, including as the starting materials natural materials per se , natural materials which have been hydrolysed, chemically modified, and fully synthetic materials.
  • Preferred derivatised proteins are :
  • Preferred silicone derivatives are the examples described in EP0540357 and US5679819 .
  • a preferred feature of the invention is the addition of a fabric softening silicone, preferably an aminosilicone or methicone based compounds, present in the formulation in an amount of from 0.1% to 15%, preferably from 0.2% to 10%, and even more preferably from 0.3% to 8%, by weight.
  • a fabric softening silicone preferably an aminosilicone or methicone based compounds
  • silicone has become a generic term which encompasses a variety of relatively high molecular weight polymers containing siloxane units and hydrocarbyl groups of various types.
  • silicones for softening fabrics, i.e., providing lubrication between fibres and yarns so they move over one another more easily, has been well known for quite some time.
  • organomodified silicones for textile treatments has also been well documented over the years (See U.S. Pat. Nos.: 4,620,878, Gee, issued Nov. 4, 1986 ; 4,705,704, Lane et al., issued Nov. 10, 1987 ; 4,800,026, Coffindaffer et al., issued Jan.
  • Silicones of this type are typically delivered to textiles in the form of an aqueous emulsion, either as a macro emulsion or a microemulsion.
  • Preferred fabric softening silicone are of the formula
  • the silicone may be of any structure that gives rise to one or more of the desired benefits in use of the fabric softener formulation.
  • the silicone is linear, but it also may be cyclic, such as the cyclic methicones.
  • a preferred class of silicones are the methicones (methylsiloxane), preferably the di or trimethicones, and their derivatives, such as, amodimethicone.
  • the silicone is emulsified by the one or more surfactants, such as a non-ionic surfactant.
  • the silicone is pre-emulsified prior to addition to the composition.
  • the weight ratio of total fabric softening agent to total fabric softening silicone is from 1:1 to 50:1, more preferably from 1.2:1 to 20:1, more preferably 1.5:1 to 10:1.
  • deionised water is used. Preferred amounts of water are "to balance”. Preferably there is at least 50%, 60%, 70% or 80%, by weight of water.
  • the pH of the liquid compositions herein is a preferred parameter of the present invention. Indeed, it influences the stability of the quaternary ammonium compounds, especially in prolonged storage conditions.
  • the pH as defined in the present context, is measured in the neat compositions at 20°C.
  • the neat pH measured in the above-mentioned conditions, must be in the range of from 2 to 5.
  • the pH of these compositions herein can be regulated by the addition of a Bronsted acid.
  • suitable acids for adjusting the pH of the composition include inorganic mineral acids, carboxylic acids, in particular the low molecular weight (C 1- C 5 ) carboxylic acids.
  • suitable inorganic acids include HCl, H 2 SO 4 , HNO 3 and H 3 PO 4 .
  • Suitable organic acids include formic, acetic, citric, tartaric. Preferred acids are citric, hydrochloric, phosphoric, formic, and benzoic acids.
  • the products herein can also contain from 0 % to 10 %, preferably from 0.1 % to 5 %, more preferably from 0.2 to 4% by weight of the finished composition of perfume.
  • Fabric softening products typically contain perfume to provide an olfactory aesthetic benefit and/or to serve as a signal that the product is effective.
  • Stabilisers may also optionally be added. When used, said stabiliser will help achieve the desired finished product viscosity as well as stabilising the finished product upon storage.
  • Stabilisers are typically selected from inorganic sulfites, single long chain alkyl cationic surfactants, non-ionic alkoxylated surfactants, amine oxides, fatty acids, and mixtures thereof, typically used at a level of from 0 to 15 % by weight of the composition.
  • Inorganic viscosity control agents which can also act like or augment the effect of the stabilisers, include water-soluble, ionisable salts which can also optionally be incorporated into the compositions of the present invention.
  • ionisable salts can be used.
  • suitable salts are the halides of the Group IA and IIA metals of the Periodic Table of the Elements, e.g., calcium chloride, magnesium chloride, sodium chloride, potassium bromide, and lithium chloride.
  • the ionisable salts are particularly useful during the process of mixing the ingredients to make the compositions herein, and later to obtain the desired viscosity.
  • the amount of ionisable salts used depends on the amount of active ingredients used in the compositions and can be adjusted according to the desires of the formulator. Typical levels of salts used to control the composition viscosity are from 20 to 2000 parts per million (ppm), preferably from 20 to 1100 ppm, by weight of the composition.
  • Alkylene polyammonium salts can be incorporated into the composition to give viscosity control in addition to or in place of the water-soluble, ionisable salts above.
  • these agents can act as scavengers, forming ion pairs with anionic detergent carried over from the main wash, in the rinse, and on the fabrics, and may improve softness performance. These agents may stabilise the viscosity over a broader range of temperature, especially at low temperatures, compared to the inorganic electrolytes.
  • alkylene polyammonium salts include 1-lysine monohydrochloride and 1,5-diammonium 2-methyl pentane dihydrochloride.
  • the composition may also contain one or more optional components conventionally included in fabric conditioning compositions such as, surfactant concentration aids, emulsifiers, colourants, preservatives, optical brighteners, antifoam agents, chelating agents, natural and/or synthetic extracts, fluorescers, hydrotropes, anti-redeposition agents, anti-shrinking agents, anti-wrinkle agents, anti-spotting agents, anti-corrosion agents, drape imparting agents, anti-static agents, ironing aids and mixtures thereof.
  • optional components conventionally included in fabric conditioning compositions such as, surfactant concentration aids, emulsifiers, colourants, preservatives, optical brighteners, antifoam agents, chelating agents, natural and/or synthetic extracts, fluorescers, hydrotropes, anti-redeposition agents, anti-shrinking agents, anti-wrinkle agents, anti-spotting agents, anti-corrosion agents, drape imparting agents, anti-static agents, ironing aids and mixtures thereof.
  • the amount of optional ingredients that may be included in the composition is less than 15%, ideally less than 3%, by weight.
  • any solvents used are low molecular weight water-soluble or water-miscible solvents, preferably with MW ⁇ 350, ideally less than 200MW .
  • the solvents may be an organic solvent selected from, lower alcohol such as ethanol, propanol, isopropanol or butanol, other low molecular weight alcohols include monohydric, dihydric (such as glycol) trihydric (such as glycerol) or a polyhydric (polyol) alcohol.
  • the solvent may also have the following formula: R 1 -O-[CH 2 -CH(R)-(CH 2 ) a -O] n -H wherein:
  • Non-limiting preferred solvents and levels are from 5% to 15% by weight of the total composition, as follows:
  • compositions of the present invention optionally comprise from about 0% to about 0.5%, preferably from about 0.01 % to about 0.4%, more preferably from about 0.05% to about 0.2% by weight of the composition, of a silicone antifoam agent.
  • a silicone antifoam agent present is in addition to the presence of any fabric softening silicone added to the composition.
  • the antifoam component of the present invention comprises a silicone.
  • the silicone materials employed as the antifoam agents herein can be alkylated polysiloxane materials of several types, either singly or in combination with various solid materials such as silica aerogels and xerogels and hydrophobic silicas of various types.
  • the present invention also encompasses a method for treating fabric, especially wool or mixed wool fabric, which comprises the step of contacting said fabric in a rinse cycle of a fabric washing machine with an aqueous medium containing a composition as defined hereinbefore.
  • the aqueous medium is at a temperature between 2 to 40 °C, more preferably between 5 to 25 °C.
  • the present invention also comprises the use of a composition as defined hereinbefore in the prevention of felting of wool or mixed wool fabric during the rinse cycle of a fabric washing process.
  • N.B. examples 1,2,4,6 and 7 are outside the scope of the invention and are comparative examples.
  • Viscosity between 100 and 1,500 cps (at 20°C) with a Brookfield LVT Spindle 2 at 12rpm.
  • test machines of the same model are used for the test.
  • the test conditions described are controlled before to start the test for each of the four washing machines.
  • the towels are changed between the machines so that each product is used equally in each of the four washing machines. In this way all test swatches undergo the same treatment.
  • the washing machines are loaded with ballast and test swatches, paying attention to use the same procedure for all the products.
  • the detergent is added as normal, according to the label instructions.
  • the test fabric conditioner added into the rinse cycle.
  • test swatches are line dried.
  • the other test swatches which undergo more than one wash are line dried between each wash cycles before the assessments.
  • test swatches which undergo more than one kind of assessments the order of the evaluation must be the following: instrumental evaluation, visual evaluation and lastly feel of fabrics.
  • the softness evaluation (feel of fabrics) is measured by means of a panel test. A panel of at least five trained technicians was used. Softness evaluations are carried out after three, five, ten, fifteen and twenty repeated wash cycles.
  • % reduction 100 ⁇ L uw - L w ⁇ ( W uw - W w ) / ( L uw ⁇ W uw )
  • the degree of felting is measured by means of a panel test. A panel of at least five trained technicians is used obtain reliable result. The samples washed were compared to each other, using the corresponding unwashed fabric sample as a reference, according to the following scale:

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Zoology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)

Claims (17)

  1. Zusammensetzung, umfassend:
    a) einen kationischen gewebeweichmachenden Wirkstoff in einer Menge von 3 bis 45 Gew.-%;
    b) 0,1 bis 20 Gew.-% eines wasserlöslichen Proteins oder eines chemisch modifizierten Derivats;
    c) 0,01 bis 10 Gew.-% eines Andickungsmittels, das für die Fasern eines Gewebes substantiell ist, wobei das Andickungsmittel ein derivatisiertes Kohlenhydrat ist;
    d) 0,1 bis 15% eines gewebeweichmachenden Silicons; und
    e) Wasser
  2. Zusammensetzung nach Anspruch 1, wobei der kationische gewebeweichmachende Wirkstoff eine Verbindung der Formel (I) oder (Ia) oder ein Gemisch davon ist:

            [R'-(CO)-O-R-N+(-R")(-(RO)nH)(-R-C(CO)-R')]X-     (I)

            [R'-(CO)-NH-R-N+(-R1)(-(RO)nH)(-R-NH(CO)-R')]X-     (Ia)

    wobei
    R eine Alkylen- oder Alkenylengruppe mit 2 bis 4 Kohlenstoffatomen ist;
    R' eine Alkyl- oder Alkenylgruppe mit 8 bis 22 Kohlenstoffatomen ist;
    n eine ganze Zahl mit einem Wert von 1 bis 4 ist;
    R" eine Alkylgruppe mit 1 bis 4 Kohlenstoffatomen ist;
    R1 eine Alkylgruppe mit 1 bis 4 Kohlenstoffatomen oder Wasserstoff ist; und
    X- ein weichmacherverträgliches Anion ist.
  3. Zusammensetzung nach Anspruch 1 oder 2, enthaltend 4 bis 20 Gew.-% eines kationischen gewebeweichmachenden Wirkstoffs.
  4. Zusammensetzung nach Anspruch 3, enthaltend 4 bis 15 Gew.-% eines kationischen gewebeweichmachenden Wirkstoffs.
  5. Zusammensetzung nach einem der Ansprüche 1 bis 3, enthaltend ein Andickungsmittel, das ein wasserlösliches Polymer ist.
  6. Zusammensetzung nach einem der Ansprüche 1 bis 5, enthaltend 0,1 bis 5 Gew.-%, wobei die Proteinquelle ausgewählt ist aus Weizen, Baumwolle, Seide, Keratin, Collagen, Elastin, Casein und Soja.
  7. Zusammensetzung nach einem der Ansprüche 1 bis 6, wobei das gewebeweichmachende Silicon eine Verbindung auf Aminosilicon- oder Methicon-Basis ist.
  8. Zusammensetzung nach einem der vorangehenden Ansprüche, wobei der Rest der Zusammensetzung Wasser ist.
  9. Zusammensetzung nach Anspruch 2, wobei der kationische gewebeweichmachende Wirkstoff Di(talgcarboxyethyl)hydroxyethylmethylammonium-X- ist.
  10. Zusammensetzung nach einem der vorangehenden Ansprüche, wobei die Zusammensetzung zusätzlich einen oder mehrere der folgenden mitweichmachenden Inhaltsstoffe umfasst:
    i. Fettaminverbindung;
    ii. Fettamidverbindung;
    iii. Fettsäure;
    iv. Fettalkohol.
  11. Zusammensetzung nach Anspruch 10, wobei die Gesamtgehalte an mitweichmachendem (mitweichmachenden) Inhaltsstoff(en) bis zu 20 Gew.-% der Zusammensetzung betragen.
  12. Zusammensetzung nach einem der vorangehenden Ansprüche, wobei das derivatisierte Kohlenhydrat eines ist, das kationisch modifiziert worden ist.
  13. Zusammensetzung nach Anspruch 12, wobei das Kohlenhydrat Guargummi ist.
  14. Zusammensetzung nach Anspruch 12, wobei das Kohlenhydrat mit einer kationischen Gruppe, ausgewählt aus einer primären Amino-, sekundären Amino-, tertiären Amino- quartären Amino-, Sulfonium- oder Phosphoniumgruppe, modifiziert ist.
  15. Zusammensetzung nach Anspruch 14, wobei das Kohlenhydrat mit einer Kationischen Gruppe der Formel

            [N(R1)(R2)(R3)(R4)]+X-

    modifiziert ist, wobei R1 ein monohydroxyliertes oder polyhydroxyliertes C1-6-Alkyl ist; R2 und R3 unabhängig voneinander C1-6-Alkyl sind; R4 eine C1-24-Alkylgruppe ist und X- ein Gegenion ist.
  16. Verfahren zum Behandeln von Geweben, insbesondere von Woll- oder Wollmischgeweben, das den Schritt des Inkontaktbringens der Gewebe in einem Spülzyklus einer Gewebewaschmaschine mit einem wässrigen Medium, enthaltend eine wie in einem der Ansprüche 1 bis 15 definierte Zusammensetzung, umfasst.
  17. Verwendung einer wie in einem der Ansprüche 1 bis 15 definierten Zusammensetzung bei der Verhinderung des Verfilzens von Woll- oder Wollmischgeweben während des Spülzyklus eines Gewebewaschvorgangs.
EP04713130A 2003-02-22 2004-02-20 Wäscheweichspülmittel Revoked EP1597343B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0304091A GB2398577A (en) 2003-02-22 2003-02-22 Fabric softening composition
GB0304091 2003-02-22
PCT/GB2004/000700 WO2004074418A1 (en) 2003-02-22 2004-02-20 Fabric softening composition

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EP1597343A1 EP1597343A1 (de) 2005-11-23
EP1597343B1 true EP1597343B1 (de) 2008-07-02

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EP (1) EP1597343B1 (de)
KR (1) KR101077800B1 (de)
AT (1) ATE399841T1 (de)
DE (1) DE602004014731D1 (de)
ES (1) ES2305731T3 (de)
GB (1) GB2398577A (de)
PL (1) PL203995B1 (de)
WO (1) WO2004074418A1 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102471735A (zh) * 2009-07-09 2012-05-23 高露洁-棕榄公司 应用织物护理组合物减少皱褶的方法
EP3953443A1 (de) * 2019-04-10 2022-02-16 Unilever Global Ip Limited Weichspülerzusammensetzungen

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2682462A1 (en) * 2007-04-02 2008-10-09 The Procter & Gamble Company Fabric care composition
GB0822823D0 (en) * 2008-12-15 2009-01-21 Dow Corning Silicone oi-in-water emulsions
WO2010115664A2 (en) * 2009-03-30 2010-10-14 Unilever Nv Fabric conditioning composition
BR112014003551B1 (pt) * 2011-08-26 2023-12-05 Colgate-Palmolive Company Composição para redução de vincos em tecidos e método para redução de vincos em tecido
US20150197708A1 (en) 2012-06-18 2015-07-16 Rhodia Operations Fabric Conditioning Composition And Use Thereof
SE543907C2 (en) * 2019-12-13 2021-09-21 Organoclick Ab Non-rewetting o/w (oil in water) emulsification system for hydrophobic compounds
PL4204532T3 (pl) * 2020-08-27 2024-06-17 Unilever Ip Holdings B.V. Środek do kondycjonowania tkanin odzieży sportowej
US20240010946A1 (en) * 2020-09-09 2024-01-11 Conopco, Inc., D/B/A Unilever Laundry composition
IT202000023929A1 (it) * 2020-10-12 2022-04-12 Alberto PESTELLI Metodo di finissaggio di un prodotto tessile laniero e relativo prodotto tessile

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Publication number Priority date Publication date Assignee Title
US4818421A (en) * 1987-09-17 1989-04-04 Colgate-Palmolive Co. Fabric softening detergent composition and article comprising such composition
MA24178A1 (fr) * 1996-05-13 1997-12-31 Procter & Gamble Composition detergente comprenant un enzyme cellulase et un enzyme laccase
AU2452599A (en) * 1999-01-07 2000-07-24 Procter & Gamble Company, The Fabric care composition containing a protein
US6271192B1 (en) * 1999-11-10 2001-08-07 National Starch And Chemical Investment Holding Company Associative thickener for aqueous fabric softener
US6903061B2 (en) * 2000-08-28 2005-06-07 The Procter & Gamble Company Fabric care and perfume compositions and systems comprising cationic silicones and methods employing same
DE10061280A1 (de) * 2000-12-08 2002-06-13 Novaprot Gmbh Reinigungswirksame, grenzflächenaktive Kombination aus nachwachsenden Rohstoffen mit hoher Fettlösekraft

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102471735A (zh) * 2009-07-09 2012-05-23 高露洁-棕榄公司 应用织物护理组合物减少皱褶的方法
EP3953443A1 (de) * 2019-04-10 2022-02-16 Unilever Global Ip Limited Weichspülerzusammensetzungen

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Publication number Publication date
PL203995B1 (pl) 2009-11-30
WO2004074418A1 (en) 2004-09-02
GB0304091D0 (en) 2003-03-26
KR101077800B1 (ko) 2011-10-31
GB2398577A (en) 2004-08-25
EP1597343A1 (de) 2005-11-23
PL378205A1 (pl) 2006-03-20
ATE399841T1 (de) 2008-07-15
DE602004014731D1 (de) 2008-08-14
ES2305731T3 (es) 2008-11-01
KR20050106445A (ko) 2005-11-09

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