EP2751247B1 - Verfahren zum schnellen trocknen eines gewebes - Google Patents

Verfahren zum schnellen trocknen eines gewebes Download PDF

Info

Publication number
EP2751247B1
EP2751247B1 EP12773138.8A EP12773138A EP2751247B1 EP 2751247 B1 EP2751247 B1 EP 2751247B1 EP 12773138 A EP12773138 A EP 12773138A EP 2751247 B1 EP2751247 B1 EP 2751247B1
Authority
EP
European Patent Office
Prior art keywords
fabric
composition
drying
weight
amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP12773138.8A
Other languages
English (en)
French (fr)
Other versions
EP2751247A1 (de
Inventor
Juan Antonio Leon NAVARRO
Jose Javier Tovar Pescador
Amit Sachdev
Oscar BAUTISTA CID
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Publication of EP2751247A1 publication Critical patent/EP2751247A1/de
Application granted granted Critical
Publication of EP2751247B1 publication Critical patent/EP2751247B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753—Polyvinylalcohol; Ethers or esters thereof

Definitions

  • the present invention relates to a method for providing fast dry property to fabric.
  • Drying can be done by line drying or dryer drying. In a dryer, the longer the drying time, the more energy that is used to dry the fabric. It would be desirable to reduce the time needed to dry fabric.
  • WO01/27232A1 discloses a fabric care composition
  • a fabric care composition comprising a polymeric material that is capable of self cross-linking and/or of reacting with cellulose together with one or more textile compatible carriers, wherein the polymeric material comprises one or more poly(oxyalkylene) groups having an end group which comprises one or more amino groups or derivatives of said amino groups.
  • the compositions may be used to treat fabric as part of a laundering process and improve the surface color definition of the fabric following multiple washings.
  • US2003/0162689A1 discloses a liquid fabric conditioner for fabric care and to the use of the conditioner in a washing or laundry drying process, to a conditioning substrate containing a liquid fabric conditioner, and to a conditioning process using the conditioning substrate in a laundry drying process.
  • the liquid fabric conditioner and conditioning substrate are used to reduce fluff formation and pilling.
  • US2007/0021315A1 discloses that hard water is softened by a composition comprising a fatty acid and/or an alkali salt thereof, a dispersing agent and a precipitation softener thereby simultaneously forming and dispersing an insoluble calcium salt of the fatty acid.
  • GB2378960A discloses a fabric care composition
  • a fabric care composition comprises a fluorocarbon stain-blocking agent and a cationic cross-linking polymeric material which is capable of self cross-linking and/or of reacting with cellulose together with one or more textile compatible carriers, wherein the cationic cross-linking polymeric material comprises one or more poly(oxyalkylene) groups having an end group which comprises one or more amino groups or derivatives of said amino groups.
  • Use of the composition improves the surface color definition and stain repellency of a fabric after multiple washings and imparts pill and/or fuzz resistance.
  • EP372848A2 discloses an aqueous emulsion of a perfluoropolyether having a molecular weight in the range 3000 to 8000 is made by agitating the perfloropolyether with a non-ionic non-fluorine-containing surfactant having an HLB value in the range 11.5 to 17.
  • the emulsions may be used in fabric conditioners.
  • a method according to claim 1 for reducing time needed for drying fabric comprising laundering the fabric at least 3 times with a composition comprising a linear polyether having a weight average molecular weight less than 5000 that is terminated with -N-(-CH 2 -CH(OH)-CH 2 -Cl) 2 , wherein the linear polyether is deposited on the fabric and reduces the time needed for drying.
  • Preferred features are defined in the dependent claims.
  • the molecular weight is less than 2000.
  • a method for reducing time needed for drying fabric comprising laundering the fabric at least 3 times with a composition comprising a linear polyether having a weight average molecular weight less than 5000 that is terminated with -N-(-CH 2 -CH(OH)-CH 2 -Cl) 2 , wherein the linear polyether is deposited on the fabric and reduces the time needed for drying.
  • the laundering can start with machine washing or hand washing. Washing typically includes using a detergent in a wash cycle. Washing is usually followed by a rinse cycle. After washing and rinsing, fabrics can be dried by hanging on a line or in a dryer. The fabric can be ironed after drying.
  • the method can be used on any type of fabric.
  • the fabric is in need of a reduced time for drying.
  • Typical fabrics include any fabric used to make clothing, such as cotton, polyester, elastane, or denim.
  • the fabric is denim.
  • the composition used in the method can be used during any step of the laundering method. In one embodiment, the composition is added during the wash cycle. In one embodiment, the composition is added during the rinse cycle. It has been found that multiple launderings can increase the reduction of the time needed for drying.
  • the fabric can be laundered with the composition for at least 3 times, at least 4 times, or at least 5 times.
  • the composition contains a linear polyether having a weight average molecular weight less than 5000 that is terminated with -N-(-CH 2 -CH(OH)-CH 2 -Cl) 2 .
  • the molecular weight is less than 4000, less than 3000, or less than 2000.
  • the polymer has a molecular weight less than 2000.
  • This polymer having a molecular weight less than 2000 is available from Devan Chemical under the PasserelleTM trademark as DP5270 or DFD.
  • DP5270 is sold as an aqueous composition that contains 20% polymer with a total solids of 23-24%, with the other solids being surfactants.
  • the DFD product contains 82% of the DP5270 product and further contains ethoxylated fatty-quaternary softeners.
  • the amount of the polymer in the composition is 0.08 to 0.4% by weight of the composition. In certain embodiments, the amount is 0.1, 0.2, 0.3, or 0.4 % by weight of the composition.
  • the DP5270 composition can be used in an amount of 0.5 to 1.5 % by weight of the composition, optionally at 0.5, 1, or 1.5 % by weight.
  • the DFD composition can be used in an amount of 0.5 to 2 % by weight of the composition, optionally at 0.5, 1, 1.5, or 2 % by weight.
  • the PasserelleTM polyethers are used to treat fabrics during the manufacture of the fabrics by direct application of the polyethers to the fabric to provide fast dry to the fabrics.
  • the method of the invention allows the polyether to be added to fabrics that were never treated or to reapply the polyethers during home use.
  • the polyether is included in a fabric conditioner.
  • a fabric conditioner composition contains a fabric softener material.
  • the softener is a cationic softener selected from among esterquats, imidazolinium quats, difatty diamide ammonium methyl sulfate, ditallow dimethyl ammonium chloride, and mixtures thereof.
  • the cationic fabric softener is an esterquat.
  • the esterquat is produced by reacting about 1.65 (1.5 to 1.75) moles of fatty acid methyl ester with one mole of alkanol amine followed by quaternization with dimethyl sulfate (further details on this preparation method are disclosed in US-A-3,915,867 ). Using this ratio controls the amount of each of monoesterquat, diesterquat, and triesterquat in the composition.
  • the alkanol amine comprises triethanolamine.
  • Monoesterquat is more soluble in water than triesterquat. Depending on the AI, more or less monoesterquat is desired. At higher AI levels (usually at least 7%), more monoesterquat as compared to triesterquat is desired so that the esterquat is more soluble in the water so that the esterquat can be delivered to fabric during use. At lower AI levels (usually up to 3%), less monoesterquat is desired because during use, it is desired for the esterquat to leave solution and deposit on fabric to effect fabric softening. Depending on the AI, the amount of monoesterquat and triesterquat are adjusted to balance solubility and delivery of the esterquat.
  • the reaction products are 50-65 weight% diesterquat, 20-40 weight% monoester, and 25 weight% or less triester, which are shown below:
  • the amount of diesterquat is 52-60, 53-58, or 53-55 weight %.
  • the amount of monoesterquat is 30-40 or 35-40 weight%.
  • the amount of triesterquat is 1-12 or 8-11 weight %.
  • the percentages, by weight, of mono, di, and tri esterquats, as described above are determined by the quantitative analytical method described in the publication " Characterisation of quaternized triethanolamine esters (esterquats) by HPLC, HRCGC and NMR" A.J. Wilkes, C. Jacobs, G. Walraven and J.M. Talbot - Colgate Palmolive R&D Inc. - 4th world Surfactants Congress, Barcelone, 3-7 VI 1996, page 382 .
  • the percentages, by weight, of the mono, di and tri esterquats measured on dried samples are normalized on the basis of 100%.
  • the normalization is required due to the presence of 10% to 15%, by weight, of non-quaternized species, such as ester amines and free fatty acids. Accordingly, the normalized weight percentages refer to the pure esterquat component of the raw material. In other words, for the weight % of each of monoesterquat, diesterquat, and triesterquat, the weight % is based on the total amount of monoesterquat, diesterquat, and triesterquat in the composition.
  • the percentage of saturated fatty acids based on the total weight of fatty acids is 45 to 75%. Esterquat compositions using this percentage of saturated fatty acids do not suffer from the processing drawbacks of 100% saturated materials. When used in fabric softening, the compositions provide good consumer perceived fabric softness while retaining good fragrance delivery.
  • the amount is at least 50, 55, 60, 65 or 70 up to 75%. In other embodiments, the amount is no more than 70, 65, 60, 55, or 50 down to 45%. In other embodiments, the amount is 50 to 70%, 55 to 65%, or 57.5 to 67.5%. In one embodiment, the percentage of the fatty acid chains that are saturated is about 62.5% by weight of the fatty acid. In this embodiment, this can be obtained from a 50:50 ratio of hard:soft fatty acid.
  • a ratio of hard fatty acid to soft fatty acid is 70:30 to 40:60. In other embodiments, the ratio is 60:40 to 40:60 or 55:45 to 45:55.
  • the ratio is about 50:50. Because in these specific embodiments, each of the hard fatty acid and soft fatty acid cover ranges for different levels of saturation (hydrogenation), the actual percentage of fatty acids that are fully saturated can vary. In certain embodiments, soft tallow contains approximately 47% saturated chains by weight.
  • the percentage of saturated fatty acids can be achieved by using a mixture of fatty acids to make the esterquat, or the percentage can be achieved by blending esterquats with different amounts of saturated fatty acids.
  • the fatty acids can be any fatty acid that is used for manufacturing esterquats for fabric softening.
  • fatty acids include, but are not limited to, coconut oil, palm oil, tallow, rape oil, fish oil, or chemically synthesized fatty acids.
  • the fatty acid is tallow.
  • esterquat can be provided in solid form, it is usually present in a solvent in liquid form. In solid form, the esterquat can be delivered from a dryer sheet in the laundry. In certain embodiments, the solvent comprises water.
  • Delivered AI refers to the active weight of the combined amounts for monoesterquat, diesterquat, and triesterquat.
  • Delivered AI refers to the mass (in grams) of esterquat used in a laundry load.
  • a load is 3.5 kilograms of fabric in weight.
  • the delivered AI adjusts proportionally.
  • the delivered AI is 2.8 to 8 grams per load.
  • the delivered AI is 2.8 to 7, 2.8 to 6, 2.8 to 5, 3 to 8, 3 to 7, 3 to 6, 3 to 5,4 to 8,4 to 7, 4 to 6, or 4 to 5 grams per load.
  • the composition can be provided as a fragrance free composition, or it can contain a fragrance.
  • the amount of fragrance can be any desired amount depending on the preference of the user. In certain embodiments, the total amount of fragrance oil is 0.3 to 3 weight % of the composition.
  • the fragrance can be in free form, encapsulated, or both.
  • Fragrance refers to odoriferous materials that are able to provide a desirable fragrance to fabrics, and encompasses conventional materials commonly used in detergent compositions to provide a pleasing fragrance and/or to counteract a malodor.
  • the fragrances are generally in the liquid state at ambient temperature, although solid fragrances can also be used.
  • Fragrance materials include, but are not limited to, such materials as aldehydes, ketones, esters and the like that are conventionally employed to impart a pleasing fragrance to laundry compositions. Naturally occurring plant and animal oils are also commonly used as components of fragrances.
  • the composition can contain any material that can be added to fabric softeners.
  • materials include, but are not limited to, surfactants, thickening polymers, colorants, clays, buffers, silicones, fatty alcohols, and fatty esters.
  • the fabric conditioners may additionally contain a thickener.
  • the thickening polymer is the FLOSOFTTM DP200 polymer from SNF Floerger that is described in United States Patent No. 6,864,223 to Smith et al. , which is sold as FLOSOFTTM DP200, which as a water soluble cross-linked cationic polymer derived from the polymerization of from 5 to 100 mole percent of cationic vinyl addition monomer, from 0 to 95 mole percent of acrylamide, and from 70 to 300 ppm of a difunctional vinyl addition monomer cross-linking agent.
  • a suitable thickener is a water-soluble cross-linked cationic vinyl polymer which is cross-linked using a cross-linking agent of a difunctional vinyl addition monomer at a level of from 70 to 300 ppm, preferably from 75 to 200 ppm, and most preferably of from 80 to 150 ppm.
  • a cross-linking agent of a difunctional vinyl addition monomer at a level of from 70 to 300 ppm, preferably from 75 to 200 ppm, and most preferably of from 80 to 150 ppm.
  • the most preferred thickener is a cross-linked copolymer of a quaternary ammonium acrylate or methacrylate in combination with an acrylamide comonomer.
  • the thickener in accordance provides fabric softening compositions showing long term stability upon storage and allows the presence of relatively high levels of electrolytes without affecting the composition stability. Besides, the fabric softening compositions remain stable when shear is applied thereto.
  • the amount of this thickening polymer is at least 0.001 weight %. In other embodiments, the amount is 0.001 to 0.35 weight %.
  • the fabric conditioner may further include a chelating compound.
  • Suitable chelating compounds are capable of chelating metal ions and are present at a level of at least 0.001%, by weight, of the fabric softening composition, preferably from 0.001% to 0.5%, and more preferably 0.005% to 0.25%, by weight.
  • the chelating compounds which are acidic in nature may be present either in the acidic form or as a complex/salt with a suitable counter cation such as an alkali or alkaline earth metal ion, ammonium or substituted ammonium ion or any mixtures thereof.
  • the chelating compounds are selected from among amino carboxylic acid compounds and organo aminophosphonic acid compounds, and mixtures of same.
  • Suitable amino carboxylic acid compounds include: ethylenediamine tetraacetic acid (EDTA); N-hydroxyethylenediamine triacetic acid; nitrilotriacetic acid (NTA); and diethylenetriamine pentaacetic acid (DEPTA).
  • Suitable organo aminophosphonic acid compounds include: ethylenediamine tetrakis (methylenephosphonic acid); 1-hydroxyethane 1,1-diphosphonic acid (HEDP); and aminotri (methylenephosphonic acid).
  • the composition can include amino tri methylene phosphonic acid, which is available as DequestTM 2000 from Monsanto.
  • the composition can include glutamic acid, N,N-diacetic acid, tetra sodium salt, which is available as DissolvineTM GL from AkzoNobel.
  • the composition can include a C 13 -C 15 Fatty Alcohol EO 20:1, which is a nonionic surfactant with an average of 20 ethoxylate groups. In certain embodiments, the amount is 0.05 to 0.5 weight%.
  • the composition can contain a silicone as a defoamer, such as Dow CorningTM 1430 defoamer.
  • a silicone such as Dow CorningTM 1430 defoamer.
  • the amount is 0.05 to 0.8 weight%.
  • the composition can be an aqueous composition that contains the linear polyether and water.
  • the linear polyether can be added directly to the laundering method.
  • the method reduces the time needed for drying by at least 5, at least 10, or at least 20% as compared to a time for drying without the use of the linear polyether.
  • the amounts of material are based on the as supplied weight of the material. For each of the examples, the amount of water is reduced by the amount of polyether added.
  • Material (weight %) Comparative Example TetranylTM AHT5090 Esterquat from Kao 7.8 7.8 Lactic acid (80% active) 0.0625 0.0625 DequestTM 2000 amino trimethyl phosphonic acid 0.05 0.05 FLOSOFTTM DP200 thickening polymer 0.135 0.135 DPD or DP5270 linear polyether having a weight average molecular weight less than 2000 that is terminated with -N-(-CH 2 -CH(OH)-CH 2 -Cl) 2 0 0.5, 1, 1.5, or 2 Water and minors (fragrance, preservative, color) about 85.5% water for the comparative Q.S. to 100 Q.S. to 100
  • All the garments treated are rinsed and hung to dry without wriggling.
  • the garment are allowed to hang for 5 Minutes to drip the excess of water and then weighed. Once completed, they are weighed each at fixed time interval (every 30 minutes) in order to assess the speed of drying.
  • 35 cm denim swatches are evaluated during the experiment (35 cm x 35 cm). Up to 5 denim swatches are evaluated per treatment as repetitions in order to avoid the experimental error. The following treatments are tested during the experiment:
  • the Passerelle TM DFD polymer is tested at 0.5, 1, 1.5, and 2 weight % as supplied in the fabric conditioner composition. The percent water retained is shown below compared to a fabric conditioner without the polymer. Polymer Weight % Water Retention (%) 0.5 % 105.767 1.5 % 106.47 1 % 107.689 2 % 108.767 Control without polymer 111.831
  • the Passerelle TM DP5270 polymer is tested at 0.5, 1, 1.5, and 2 weight % as supplied in the fabric conditioner composition. The percent water retained is shown below compared to a fabric conditioner without the polymer. Polymer Weight % Water Retention (%) 1 % 105.452 1.5 % 105.62 2 % 106.822 Control without polymer 107.1 0.5 % 108.563
  • the reduction of drying time in a tumble drier is determined by measuring the % water retention of denim swatches during drying.
  • % Water Retention WeightWet ⁇ WeightDry WeightDry ⁇ 100
  • the % Water Retention is plotted during the time of the experiment (Every 30 min).
  • ranges are used as shorthand for describing each and every value that is within the range. Any value within the range can be selected as the terminus of the range.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Claims (15)

  1. Verfahren zur Verringerung der Zeit, die zum Trocknen von Gewebe erforderlich ist, wobei das Verfahren das Reinigen des Gewebes mindestens 3 Mal mit einer Zusammensetzung umfasst, die einen linearen Polyether mit einem gewichtsmittleren Molekulargewicht von weniger als 5000 umfasst, der mit -N-(-CH2-CH(OH)-CH2-Cl)2 abgeschlossen ist, wobei der lineare Polyether auf dem Gewebe abgeschieden wird und die zum Trocknen erforderliche Zeit verringert.
  2. Verfahren nach Anspruch 1, wobei das Molekulargewicht weniger als 4000 oder gegebenenfalls weniger als 3000 beträgt.
  3. Verfahren nach einem vorhergehenden Anspruch, wobei das Molekulargewicht weniger als 2000 beträgt.
  4. Verfahren nach einem vorhergehenden Anspruch, wobei das Gewebe mindestens 5 Mal gereinigt wird.
  5. Verfahren nach einem vorhergehenden Anspruch, wobei die Zusammensetzung eine wässrige Zusammensetzung ist.
  6. Verfahren nach einem vorhergehenden Anspruch, wobei die Zusammensetzung während eines Spülzyklus während des Reinigens zugegeben wird.
  7. Verfahren nach einem vorhergehenden Anspruch, wobei das Reinigen das Waschen des Gewebes und das Spülen des Gewebes umfasst.
  8. Verfahren nach einem vorhergehenden Anspruch, das weiterhin das Trocknen des Gewebes umfasst.
  9. Verfahren nach Anspruch 8, wobei das Trocknen ein Trocknen auf der Wäscheleine ist.
  10. Verfahren nach Anspruch 8, wobei das Trocknen ein Trocknen im Wäschetrockner ist.
  11. Verfahren nach einem vorhergehenden Anspruch, wobei der Polyether in der Zusammensetzung in einer Menge von 0,08 bis 0,4 % bezogen auf das Gewicht der Zusammensetzung vorliegt.
  12. Verfahren nach einem vorhergehenden Anspruch, wobei die Zusammensetzung weiterhin einen Weichspüler umfasst.
  13. Verfahren nach Anspruch 12, wobei der Weichspüler in einer Menge für ein abgegebenes AI von 2,8 bis 8 Gramm pro Ladung, gegebenenfalls 2,8 bis 7, 2,8 bis 6, 2,8 bis 5, 3 bis 8, 3 bis 7, 3 bis 6, 3 bis 5, 4 bis 8, 4 bis 7, 4 bis 6 oder 4 bis 5 Gramm pro Ladung vorliegt.
  14. Verfahren nach einem vorhergehenden Anspruch, wobei die Zusammensetzung weiterhin ein Tensid umfasst.
  15. Verfahren nach einem vorhergehenden Anspruch, wobei das Verfahren die zum Trocknen erforderliche Zeit um mindestens 5, mindestens 10 oder mindestens 20 % im Vergleich zu einer Zeit zum Trocknen ohne Reinigen mit dem linearen Polyether verringert.
EP12773138.8A 2011-09-01 2012-08-31 Verfahren zum schnellen trocknen eines gewebes Active EP2751247B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PCT/US2011/050113 WO2013032479A1 (en) 2011-09-01 2011-09-01 Method for providing fast dry to fabric
PCT/US2012/053300 WO2013033508A1 (en) 2011-09-01 2012-08-31 Method for providing fast dry to fabric

Publications (2)

Publication Number Publication Date
EP2751247A1 EP2751247A1 (de) 2014-07-09
EP2751247B1 true EP2751247B1 (de) 2016-04-20

Family

ID=44741705

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12773138.8A Active EP2751247B1 (de) 2011-09-01 2012-08-31 Verfahren zum schnellen trocknen eines gewebes

Country Status (13)

Country Link
US (1) US20140201930A1 (de)
EP (1) EP2751247B1 (de)
CN (1) CN103764811A (de)
AU (1) AU2012301742C1 (de)
BR (1) BR112014004547B1 (de)
CA (1) CA2847381C (de)
IL (1) IL231020A0 (de)
MX (1) MX351099B (de)
MY (1) MY166809A (de)
RU (1) RU2014112351A (de)
SG (1) SG2014012017A (de)
WO (2) WO2013032479A1 (de)
ZA (1) ZA201401489B (de)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160017261A1 (en) * 2013-03-11 2016-01-21 Colgate-Palmolive Company Fabric conditioner
MX368217B (es) * 2014-08-18 2019-09-24 Colgate Palmolive Co Productos para el cabello que contienen polieteramina.
DE102016211702A1 (de) 2016-06-29 2018-01-04 Henkel Ag & Co. Kgaa Beschleunigung der Wäschetrocknung
DE102016211700A1 (de) 2016-06-29 2018-01-04 Henkel Ag & Co. Kgaa Beschleunigung der Wäschetrocknung
DE102016211701A1 (de) 2016-06-29 2018-01-04 Henkel Ag & Co. Kgaa Beschleunigung der Wäschetrocknung
DE102016212309A1 (de) 2016-07-06 2018-01-11 Henkel Ag & Co. Kgaa Beschleunigung der Wäschetrocknung
DE102016212312A1 (de) 2016-07-06 2018-01-11 Henkel Ag & Co. Kgaa Beschleunigung der Wäschetrocknung
DE102016217291A1 (de) 2016-09-12 2018-03-15 Henkel Ag & Co. Kgaa Beschleunigung der Wäschetrocknung
DE102016217294A1 (de) 2016-09-12 2018-03-15 Henkel Ag & Co. Kgaa Beschleunigung der Wäschetrocknung
CN113249176B (zh) * 2021-05-18 2022-03-15 纳爱斯浙江科技有限公司 一种织物快干添加剂组合物及包含该组合物的织物洗涤剂

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4049557A (en) * 1972-07-17 1977-09-20 Colgate-Palmolive Company Fabric conditioning compositions
US3915867A (en) 1973-04-24 1975-10-28 Stepan Chemical Co Domestic laundry fabric softener
US4806345C1 (en) 1985-11-21 2001-02-06 Johnson & Son Inc C Cross-linked cationic polymers for use in personal care products
EP0372848A3 (de) 1988-12-02 1991-07-10 The British Petroleum Company P.L.C. Emulsion und diese Emulsionen enthaltende Wäscheweichmacherzusammensetzung für Gewebe
GB8909069D0 (en) 1989-04-21 1989-06-07 Bp Chem Int Ltd Fabric conditioners
GB8917628D0 (en) * 1989-08-02 1989-09-20 Quest Int Perfumed fabric softening compositions
GB9923921D0 (en) * 1999-10-08 1999-12-08 Unilever Plc Fabric care composition
GB2366304A (en) * 2000-09-01 2002-03-06 Unilever Plc Fabric care composition
US6864223B2 (en) 2000-12-27 2005-03-08 Colgate-Palmolive Company Thickened fabric conditioners
GB2378960A (en) 2001-08-22 2003-02-26 Unilever Plc Fabric care composition
ATE362513T1 (de) 2002-01-25 2007-06-15 Henkel Kgaa Konditioniermittel zur textilschonung
US20030162689A1 (en) * 2002-01-25 2003-08-28 Tatiana Schymitzek Conditioning preparation for fabric care
DE102004003286A1 (de) * 2004-01-22 2005-09-29 Henkel Kgaa System zur Wasserenthärtung durch Fällenthärtung
US7776813B2 (en) * 2004-09-15 2010-08-17 The Procter & Gamble Company Fabric care compositions comprising polyol based fabric care materials and deposition agents

Also Published As

Publication number Publication date
RU2014112351A (ru) 2015-10-10
CN103764811A (zh) 2014-04-30
BR112014004547A2 (pt) 2017-04-04
EP2751247A1 (de) 2014-07-09
WO2013032479A1 (en) 2013-03-07
MX2014002262A (es) 2014-04-30
AU2012301742C1 (en) 2015-02-26
WO2013033508A1 (en) 2013-03-07
CA2847381A1 (en) 2013-03-07
AU2012301742B2 (en) 2014-07-10
US20140201930A1 (en) 2014-07-24
AU2012301742A1 (en) 2014-03-06
MX351099B (es) 2017-10-02
IL231020A0 (en) 2014-03-31
MY166809A (en) 2018-07-23
BR112014004547B1 (pt) 2021-04-20
CA2847381C (en) 2015-12-08
ZA201401489B (en) 2016-02-24
SG2014012017A (en) 2014-06-27

Similar Documents

Publication Publication Date Title
EP2751247B1 (de) Verfahren zum schnellen trocknen eines gewebes
US10428295B2 (en) Fabric wrinkle reduction composition
EP2935551B1 (de) Weichspüler mit einem aminfunktionalen silikon
AU2013382220B2 (en) Fabric conditioner
US9783764B2 (en) Fabric conditioner
EP2751246B1 (de) Verfahren für leichteres bügeln
US9758927B2 (en) Method for ease of ironing
AU2012301739B2 (en) Method for increased fragrance release during ironing
US20140223668A1 (en) Method for increased fragrance release during ironing

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20140227

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

DAX Request for extension of the european patent (deleted)
GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20151020

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 792478

Country of ref document: AT

Kind code of ref document: T

Effective date: 20160515

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602012017390

Country of ref document: DE

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 5

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 792478

Country of ref document: AT

Kind code of ref document: T

Effective date: 20160420

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20160420

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160720

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20160824

Year of fee payment: 5

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160822

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160721

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602012017390

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

26N No opposition filed

Effective date: 20170123

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160831

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160831

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160831

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 602012017390

Country of ref document: DE

Representative=s name: WUESTHOFF & WUESTHOFF, PATENTANWAELTE PARTG MB, DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20120831

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: MT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160831

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160420

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230528

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20240828

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20240827

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20240826

Year of fee payment: 13