EP1596655A1 - Produit agricole contenant des copolymeres - Google Patents

Produit agricole contenant des copolymeres

Info

Publication number
EP1596655A1
EP1596655A1 EP04710829A EP04710829A EP1596655A1 EP 1596655 A1 EP1596655 A1 EP 1596655A1 EP 04710829 A EP04710829 A EP 04710829A EP 04710829 A EP04710829 A EP 04710829A EP 1596655 A1 EP1596655 A1 EP 1596655A1
Authority
EP
European Patent Office
Prior art keywords
alkyl
optionally
polyglycerol
alkenyl
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04710829A
Other languages
German (de)
English (en)
Inventor
Ralf Zerrer
Franz-Xaver Scherl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Produkte Deutschland GmbH
Original Assignee
Clariant GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant GmbH filed Critical Clariant GmbH
Publication of EP1596655A1 publication Critical patent/EP1596655A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants

Definitions

  • WO 01/08481 advertises the use of polyglycerol derivatives in plant protection products and the influence of polyglycerol esters on the herbicidal action of glyphosate is disclosed.
  • the polyglycerol derivatives are added to herbicide formulations.
  • Suitable herbicides are, without restricting the invention to these, in particular glyphosates, in particular its water-soluble salts, for example as alkali metal, ammonium, alkylamine, alkylsulfonium, alkylphosphonium, mono (isopropylammonium, mono (trimethylsulfonium), sulfonylamine or aminoguanidine salt.
  • Polyglycerol is first copolymerized (crosslinked) with the dicarboxylic acid and then copolymerized with the fatty alcohol or alkoxylated fatty alcohol or fatty alcohol derivative:
  • the molten polyglycerol is mixed in a stirred tank with a water separator with the dicarboxylic acid or polycarboxylic acid in the desired molar ratio and heated to 200-240 ° C. for 2 hours with stirring.
  • the resulting product is clear and homogeneous.
  • the fatty alcohol or alkoxylated fatty alcohol or the fatty alcohol derivative is then added and esterified at 200-240 ° C. for 5 hours.
  • Polysilicones are suitable as defoamers.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne des produits agricoles comprenant: A) un pesticide ou un régulateur de croissance végétale; B) un copolymère contenant a) un polyglycérine éther, b) un ou plusieurs acides dicarboxyliques et/ou acides polycarboxyliques, les polyglycérine éthers ayant la formule (I). Dans la formule (I), les radicaux Rl, R2 et R3 sont identiques ou différents et représentent indépendamment l'un de l'autre: hydrogène; alkyle en (C1-C30) éventuellement substitué par 1 à 3 alkyles en (C1-C4) ou groupes alcoxy en (C1-C4); alcényle en (C2-C30) éventuellement sulfoné ou éventuellement substitué par 1 à 3 alkyles en (C1-C4) ou groupes alcoxy en (C1-C4); phényle éventuellement substitué par 1 à 3 alkyles en (C1-C4) ou groupes alcoxy en (C1-C4); naphthyle éventuellement substitué par 1 à 3 alkyles en (C1-C4) ou groupes alcoxy en (C1-C4); des groupes de formule R4R5N-(CH2)Y-, HO-(CH2)y-, -(AO)ZH, -SO3H, -SO3-X+, -PO3H2, -PO32-X+, -CR2-COOR`, -CR2-COO-X+, -CO-R6-COOH, -CO-R6-COO-X+, -C(R)2C(R)2C(R)2-N(R)2, -C(R)2C(R)2C(R)2-N((AO)ZH)2, -[CH2CH(O(AO)ZH)CH2O]n- Rl, -(CH2CHR(O(AO)Z)CH2O)n-R, R représentant H et/ou alkyle en (C1-C4), R` représentant H ou alkyle en (C1-C10), alcényle en (C2-C30) éventuellement sulfoné, R4 et R5 étant identiques ou différents et représentant hydrogène, alkyle en (C1-C10), alcényle en (C2-C30) éventuellement sulfoné, ou un groupe de formule -(AO)ZH, R6 étant alkylène en (C1-C10), alcénylène en (C2-C30) éventuellement sulfoné, X+ étant Na+, K+, Ca2+ ou N(R7)4+, R7 étant H ou alkyle en (C1-C10), de préférence alkyle en (C1-C4), x étant un nombre de 0 à 15, y étant un nombre de 4 à 6, z étant un nombre de 0 à 30, de préférence de 1 à 5, A étant un groupe alkylène, de préférence un groupe -C2H4-, -C3H6- ou -C4H8-, n étant un nombre de 4 à 40, de préférence de 5 à 20, en particulier de 10 à 20, et les indices p1, q1, r1, p2, q2, r2, p3, q3 et r3 étant des nombres de 0 à 500, à la conditions que les composés de formule (I) ne comprennent pas de groupes OH et qu'au moins l'un des radicaux R1, R2 et R3 soit un groupe hydrocarbure, de préférence alkyle en (C1-C30).
EP04710829A 2003-02-20 2004-02-13 Produit agricole contenant des copolymeres Withdrawn EP1596655A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10307171 2003-02-20
DE10307171A DE10307171B4 (de) 2003-02-20 2003-02-20 Copolymere enthaltende landwirschaftliche Mittel
PCT/EP2004/001350 WO2004073404A1 (fr) 2003-02-20 2004-02-13 Produit agricole contenant des copolymeres

Publications (1)

Publication Number Publication Date
EP1596655A1 true EP1596655A1 (fr) 2005-11-23

Family

ID=32841734

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04710829A Withdrawn EP1596655A1 (fr) 2003-02-20 2004-02-13 Produit agricole contenant des copolymeres

Country Status (11)

Country Link
US (1) US20060264330A1 (fr)
EP (1) EP1596655A1 (fr)
JP (1) JP4564484B2 (fr)
CN (1) CN100358420C (fr)
BR (1) BRPI0407703A (fr)
CA (1) CA2516694A1 (fr)
DE (1) DE10307171B4 (fr)
HK (1) HK1087593A1 (fr)
MX (1) MXPA05008881A (fr)
MY (1) MY136187A (fr)
WO (1) WO2004073404A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10342870A1 (de) 2003-09-15 2005-05-12 Clariant Gmbh Flüssige Zusammensetzungen enthaltend oxalkylierte Polyglycerinester
EP2384624B1 (fr) * 2010-05-08 2015-04-15 Cognis IP Management GmbH Compositions biocides comportant des esters d'oligoglycérol alkoxylés
KR20150021554A (ko) * 2012-06-06 2015-03-02 다우 아그로사이언시즈 엘엘씨 고강도 제초제 현탁액 농축물
ITBO20130206A1 (it) * 2013-05-08 2014-11-09 Bam Di Benazzi E Uttini S N C Una composizione antideriva, bagnante ed adesivante per trattamenti antiparassitari
EP3106033B1 (fr) 2015-06-16 2017-04-26 Evonik Degussa GmbH Trisiloxane organomodifié bodégradable à effet super étalant
MX2020001994A (es) * 2017-08-30 2020-09-07 Evonik Operations Gmbh Uso de polioleteres para la produccion de revestimientos plasticos porosos.
EP3758482A1 (fr) 2018-02-26 2021-01-06 Evonik Operations GmbH Compositions à base de siloxanes cycliques utilisées en tant qu'agents mouillants à diffusion étendue et lente pour la protection phytosanitaire
CN112889820B (zh) * 2021-01-22 2022-11-18 海韵一剑大卫生科技有限公司 复配型季铵盐消毒剂及其制备方法和使用方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2679520A (en) * 1952-01-09 1954-05-25 Petrolite Corp Oxypropylated esters of polycarboxylic acids
US4265774A (en) * 1976-10-29 1981-05-05 Basf Wyandotte Corporation Oxyalkylated polyglycerols and water-based lubricants prepared therefrom
DE3302465C2 (de) * 1982-03-03 1984-10-11 Akzo Gmbh, 5600 Wuppertal Verdickungsmittel auf der Basis Polyätherderivate
DE3239564C1 (de) * 1982-10-26 1984-05-10 Goldschmidt Ag Th Mit Fettsaeure und/oder Isostearinsaeure veresterte Polyoxyalkylenether des Glycerins oder 1.2-Propandiols,deren Herstellung sowie Verwendung als Verdickungs- oder Solubilisierungsmittel
DE3614788A1 (de) * 1986-05-02 1987-11-05 Hoechst Ag Herbizide emulsionen
DE3744857C2 (fr) * 1986-08-05 1991-02-14 Ricoh Co., Ltd., Tokio/Tokyo, Jp
DE3636086A1 (de) * 1986-10-23 1988-04-28 Henkel Kgaa Fettsaeureester von polyglycerinpolyglykolethern, ihre herstellung und ihre verwendung
TW201758B (fr) * 1988-06-28 1993-03-11 Catalyst co ltd
US5192462A (en) * 1989-03-21 1993-03-09 Croda Inc. Thickening agents for topical preparations
CA2081652C (fr) * 1991-10-31 2002-09-10 Yuichi Hioki Melange de produits chimiques agricoles
JP3228571B2 (ja) * 1991-10-31 2001-11-12 花王株式会社 農薬用効力増強剤及び農薬組成物
US5597551A (en) * 1995-01-05 1997-01-28 Isp Investments Inc. Low VOC hair spray composition
US5750468A (en) * 1995-04-10 1998-05-12 Monsanto Company Glyphosate formulations containing etheramine surfactants
US5710103A (en) * 1996-04-03 1998-01-20 Albemarle Corporation Glyphosate compositions comprising hydrocarbyl dimethyl amine oxide and quaternary ammonium halide
DE20005808U1 (de) * 1999-05-28 2000-07-20 Wella Ag, 64295 Darmstadt Haarstylingöl
WO2001008481A1 (fr) * 1999-07-30 2001-02-08 Clariant Gmbh Preparations pesticides contenant des polyglycerines ou des derives de polyglycerine
WO2002000055A1 (fr) * 2000-06-27 2002-01-03 Pearl Science Laboratory Coffret a bijou
DE10117993A1 (de) * 2001-04-10 2002-10-17 Clariant Gmbh Pestizidzubereitungen enthaltend Copolymere
DE10124547A1 (de) * 2001-05-19 2002-11-28 Clariant Gmbh Verwendung von Estern des Polyglycerins und deren alkoxylierten und anionischen Derivaten als Emulgatoren in der Emulsionspolymerisation
DE10130357A1 (de) * 2001-06-23 2003-01-02 Clariant Gmbh Pestizidzubereitungen enthaltend Copolymere
DE10211801B4 (de) * 2002-03-16 2004-09-30 Clariant Gmbh Kosmetische und pharmazeutische Zubereitungen enthaltend einen oxalkylierten Polyglycerinester
EP1499353A4 (fr) * 2002-04-15 2006-04-05 Human Genome Sciences Inc Anticorps se liant specifiquement au tl5

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2004073404A1 *

Also Published As

Publication number Publication date
MXPA05008881A (es) 2005-10-05
CN1750756A (zh) 2006-03-22
US20060264330A1 (en) 2006-11-23
JP4564484B2 (ja) 2010-10-20
MY136187A (en) 2008-08-29
BRPI0407703A (pt) 2006-02-14
HK1087593A1 (en) 2006-10-20
CA2516694A1 (fr) 2004-09-02
CN100358420C (zh) 2008-01-02
DE10307171B4 (de) 2009-04-16
JP2006518349A (ja) 2006-08-10
DE10307171A1 (de) 2004-09-09
WO2004073404A1 (fr) 2004-09-02

Similar Documents

Publication Publication Date Title
EP1379129B1 (fr) Preparations pesticides contenant des copolymeres
EP2914108B1 (fr) Compositions aqueuses adjuvantes
EP1401274B1 (fr) Preparations pesticides contenant des copolymeres
EP2475248B1 (fr) Compositions pesticides contenant des copolymeres et des agents tensio-actifs amphoteriques
EP1799036B1 (fr) Composition agrochimique contenant de l'ester phosphorique
DE202014008420U1 (de) Zusammensetzungen agrochemischer Wirkstoffe, deren Herstellung und Verwendung
DE10307171B4 (de) Copolymere enthaltende landwirschaftliche Mittel
WO2001008481A1 (fr) Preparations pesticides contenant des polyglycerines ou des derives de polyglycerine
WO2004107862A1 (fr) Preparations contenant des oxydes d'amine et des tensioactifs anioniques
WO2019149514A1 (fr) Compositions contenant des herbicides solubles dans l'eau, et leur utilisation
EP2809155B1 (fr) Compositions pesticides
DE19936092A1 (de) Polyglycerinester enthaltende Pestizidzubereitungen
DE10023153A1 (de) Pestizidzubereitungen enthaltend Polyglycerine oder Polyglycerinderivate
KR20050103235A (ko) 공중합체를 함유하는 농약 제제
WO2009121476A2 (fr) Formulations de pesticide contenant des oligoamines alcoxylées et des mono et/ou diamines alcoxylées

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20050920

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL LT LV MK

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: CLARIANT PRODUKTE (DEUTSCHLAND) GMBH

DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN

18W Application withdrawn

Effective date: 20100828