EP1590064A4 - Milieu filtrant d'alcool polyvinylique - Google Patents

Milieu filtrant d'alcool polyvinylique

Info

Publication number
EP1590064A4
EP1590064A4 EP03800134A EP03800134A EP1590064A4 EP 1590064 A4 EP1590064 A4 EP 1590064A4 EP 03800134 A EP03800134 A EP 03800134A EP 03800134 A EP03800134 A EP 03800134A EP 1590064 A4 EP1590064 A4 EP 1590064A4
Authority
EP
European Patent Office
Prior art keywords
filter
water
soluble
polymer
polyvinyl alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03800134A
Other languages
German (de)
English (en)
Other versions
EP1590064A2 (fr
Inventor
Baosheng Lee
John B Steward
Jordan M Johnston
Youzhen Ding
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Microtek Medical Holdings Inc
Original Assignee
Microtek Medical Holdings Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Microtek Medical Holdings Inc filed Critical Microtek Medical Holdings Inc
Publication of EP1590064A2 publication Critical patent/EP1590064A2/fr
Publication of EP1590064A4 publication Critical patent/EP1590064A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
    • B01D39/1623—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/08—Filter cloth, i.e. woven, knitted or interlaced material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/08—Filter cloth, i.e. woven, knitted or interlaced material
    • B01D39/083—Filter cloth, i.e. woven, knitted or interlaced material of organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/18—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being cellulose or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04—Additives and treatments of the filtering material
    • B01D2239/0407—Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/065—More than one layer present in the filtering material
    • B01D2239/0654—Support layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/069—Special geometry of layers
    • B01D2239/0695—Wound layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/12—Special parameters characterising the filtering material
    • B01D2239/1216—Pore size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/40—Knit fabric [i.e., knit strand or strip material]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]

Definitions

  • the present invention relates generally to filter media produced from polyvinyl alcohol material.
  • a representative example is the medical industry, which generates millions of pounds of waste each year. Much of that waste is related to the use of disposable materials, such as personal protective clothing, equipment, and accessories necessary for patient care that become contaminated with body fluids, human waste, and/or chemicals that render them unsafe for reuse. To prevent the spread of disease, it is imperative, and required by law, that these materials be discarded and not reused, without consideration to the level of contamination of said article. hi addition, the nuclear industry also generates millions of pounds of waste each year. In the nuclear industry, much of the waste is similarly related to the use of disposable materials such as personal protective clothing, bags, mop heads, rags, and other accessories that become contaminated by even low levels of radioactive material, and are therefore unsafe or impractical for reuse. The waste disposal and landfilling practices of the nuclear industry are highly regulated, and nuclear burial ground space is becoming increasingly scarce and more expensive.
  • water-soluble products have been developed.
  • water-soluble products may be disposed of in a conventional water treatment facility or the like. Accordingly, in some cases, water-soluble products present a convenient and cost effective alternative to conventional waste disposal means.
  • Such articles provide a means to separate the contamination, and conveniently and cheaply dispose of the larger uncontaminated portion into municipal or regular waste streams, thus vastly decreasing the total volume of hazardous waste that must be dealt with by special regulated (and expensive) disposal methods.
  • Polyvinyl alcohol is a commonly used material for making disposable personal equipment, such as garments, apparel, linens, drapes, towels, sponges, gauze, utensils, rags, mops and other useful articles commonly used in industrial settings. These articles are often produced from non-woven, woven, knitted or otherwise formed thermoplastic polyvinyl alcohol polymer films, fabrics, and fibers that are water-soluble, giving these articles the disposal benefits described above.
  • What is needed in the art is a filter media that (1) eliminates one or more problems associated with conventional filter media, and (2) provides one or more possible benefits, such as (a) decreased hazardous and toxic waste generation, (b) decreased expense of waste treatment, (c) regulatory compliance for waste minimization, and (d) increased work place and personnel safety and exposure control.
  • the present invention addresses some of the difficulties and problems discussed above by the discovery of a new filter media comprising polyvinyl alcohol (PVA) material.
  • PVA polyvinyl alcohol
  • the filter media of the present invention provides one or more benefits including, but not limited to, (a) decreased hazardous and toxic waste generation, (b) decreased expense of waste treatment, (c) regulatory compliance for waste minimization, and (d) increased work place and personnel safety and exposure control.
  • the filter media may have a variety of filter configurations, and may comprise additional materials other than PVA. In one desired embodiment of the present invention, the filter media comprises as much as 90 percent by weight or greater of water-soluble PVA.
  • the present invention is also directed to methods of making and using the filter media comprising PVA material.
  • the filter media is used in a process for treating nuclear waste.
  • the filter media may be used to perform a particular purpose (i.e., filtering), and then disposed of by solubilizing the filter media.
  • Radioactive waste may be separated from the water-soluble components of the filter media, substantially reducing the amount of radioactive waste and volume of waste.
  • the present invention is further directed to a method of reducing an amount of radioactive waste generated by a contaminated filter, wherein the method comprises disposing of the filter by placing the filter in an aqueous bath under condition such that at least a portion of the filter becomes soluble.
  • the water-soluble component of the filter comprises PVA.
  • the method may further comprise one or more additional steps including, but not limited to, separating radioactive material from the solubilized portions of the filter in the aqueous bath.
  • the present invention is even further directed to a method of reducing an amount of radioactive waste generated by at least one contaminated product, wherein the method comprises (i) disposing of the at least one contaminated product by placing the at least one contaminated product in an aqueous bath under condition such that at least a portion of the product becomes soluble; and (ii) filtering any non- solubilized material from the aqueous bath using at least one filter comprising water- soluble polyvinyl alcohol material.
  • the at least one filter comprising water-soluble polyvinyl alcohol material may be disposed of by solubilizing the water-soluble components of the at least one filter, further reducing the amount of radioactive waste in the process.
  • the present invention is further directed to a process for treating a material comprising at least one polymer, comprising the steps (i) introducing at least one oxidizing agent and a material comprising at least one polymer into an aqueous environment, wherein said at least one polymer is a polymer capable of being reacted, degraded or broken down into at least one degradation product; (ii) reacting, degrading or breaking down at least a portion of the at least one polymer under conditions effective to provide at least one degradation product; and (iii) filtering the aqueous environment using a filter comprising water-soluble polyvinyl alcohol material.
  • the filter comprising water-soluble polyvinyl alcohol material may be disposed of by solubilizing the water-soluble components of the filter, further reducing the amount of radioactive waste generated in the process.
  • FIG. 1 depicts an exemplary filter media of the present invention having a wound-type cartridge design
  • FIG. 2 depicts an end view of the exemplary filter media of FIG. 1 as viewed along line A- A;
  • FIG. 3 depicts a cut-away view of the exemplary filter media of FIG. 1, wherein a portion of the wound fibrous material has been removed from the core;
  • FIG. 4 depicts an exemplary filter media of the present invention having a pleated filter design;
  • FIG. 5 is a schematic of an exemplary processing system for treating waste streams using one or more filter media of the present invention.
  • the present invention is directed to filter media comprising polyvinyl alcohol (PVA) material.
  • PVA polyvinyl alcohol
  • the present invention is also directed to methods of making and using the filter media comprising PVA material.
  • Polyvinyl alcohol exhibits several unique and positive physical and chemical characteristics for making filter media. The excellent resistance of polyvinyl alcohol to chemicals, acid and base, solvent and oil and grease makes PVA an excellent material for applications in nuclear, industrial and other environments.
  • the following table compares the impact of common oils and solvents on fully hydrolyzed PVA resin.
  • PVA resins are substantially unaffected by most ester, ethers, ketones, aliphatic, aromatic hydrocarbons and the higher monohydric alcohols. The lower monohydric alcohols have cause some swelling action on the resin, but the effect is negligible.
  • Conventional grades of PVA are unaffected by animal and vegetable oils, greases, and petroleum hydrocarbons, hi the table below, the percent gain in weight of molded and un-plasticized PVA resin was measured when they were immersed in a solvent for 10 days at 25-35 C. The lower the number, the better the resistance of PVA resin to the chemicals.
  • PVA fiber for use in the present invention is desirably produced from fully hydrolyzed PVA resin.
  • properties of the resulting fiber may be further enhanced by physical treatments such as heat and fiber orientation.
  • the chemical resistance of PVA fiber is even better that the PVA resin.
  • PVA fiber is unaffected by the levels of ionizing radiation normally seen in nuclear filtering operations, making it useful in both highly radioactive and low level nuclear filtering operations.
  • a PVA-based filter may be produced, used, and disposed of in the same manner as current filters.
  • PVA filter media has the distinct advantage of being able to change its form and be volume reduced using a chemical oxidation process or simply dissolving it. In both cases, the components would cease to exist in filter form; rather the filter media would be liquefied and discharged or filtered to remove the radioactivity or other contaminants. In nuclear and other industrial applications, this puts the filtered radioactive or hazardous contamination into a much more stable and desired waste form. The user would realize significant economic advantages since regulations governing the disposal of highly radioactive or filters containing hazardous materials would no longer apply. Facilities would no longer pay for the disposal of these filters in conventional form, saving a substantial amount of money in handling, packaging, shipping and disposal.
  • PVA filters may be produced to cover a wide range of filtering capabilities, for example, from about 0.1 to about 2500 microns.
  • PVA exhibits great efficiency in particle removal and retention.
  • PVA yarn is used on cord wound filters in lieu of conventional media (e.g., polypropylene, cotton, and/or polyester) and wound to the same specifications for a particular micron rating
  • PVA typically exceeds the design performance parameters that would be expected of the original media. This is due to the slight expansion of the PVA media when exposed to water, creating a tighter, more tortuous path for filterable particles, and therefore improved filtration efficiency.
  • the strength of PVA fiber makes it very resistant to failure from pressure surges or high differential pressure under high flow conditions.
  • the dissolution temperature of PVA may also be configured during the manufacturing process to ensure media integrity throughout the range of temperatures seen during filter operations. Capacity and throughput of PVA filters of the present invention may be identical to or very consistent with conventional filter media.
  • PVA filters of the present invention may be used in any water or air filtration application, including nuclear applications.
  • Other applications for the water filters of the present invention include, but are not limited to, electronic component production, medical, wastewater treatment, drinking water, industrial cooling water systems, and home use.
  • Air filters of the present invention include fibers used in applications including, but are not limited to, industrial gas filtration, respirators, building/home ventilation, and automotive.
  • Other applications of industrial use include the water or air filtration of asbestos or fiberglass.
  • PVA-containing filters of the present invention may be manufactured in an array of configurations and designs, suitable for both liquid and gas applications.
  • the filter has a wound- type cartridge design. Such a design is shown in FIGS. 1-3.
  • PVA fiber is spun into roving/yarn 11, which is then wound around a central support core 12.
  • the core 12 can be metal, plastic, or another material.
  • core 12 has perforations 13 therein to provide flow channels through filter 10.
  • This filter type is common to many types of existing water filter designs, such as home use. These same filters are used extensively in low-activity filtering applications at Boiling Water Reactors (BWR) throughout the nuclear industry.
  • Cord wound filters can be made in any length to accommodate any existing filter housing.
  • the filtering capability can be varied over a very wide range depending on manufacturing settings, such as yarn density and winding tension and winding pattern. Filtration ratings of about 0.1 microns and lower are achievable.
  • the central support core 12 may be prepared from a water-soluble, water-degradable or water-dispersible material. Suitable water-soluble materials include, but are not limited to, polyvinyl alcohols used to make the filtration component (e.g., roving/yarn 11 of filter media 10 shown in FIGS. 1-3) of the filters of the present invention.
  • the central support core 12 may be injection molded using a PVA material alone or in combination with one or more water-degradable or water- dispersible materials. Suitable water-degradable or water-dispersible materials include, but are not limited to, polymers disclosed in U.S. Patent No. 6,162,852 assigned to Microtek Medical Holdings, Inc., the entirety of which is hereby incorporated by reference.
  • the central support core 12 also solubilizes and/or disperses when exposed to alkaline having a water temperature above about 37°C further reducing the amount of waste resulting from the filter media.
  • filter 10 of FIGS. 1-3 has a cylindrical wound-type cartridge design
  • filter 10 may have any volumetric shape other than a cylindrical shape (e.g., a circular cross-sectional configuration).
  • Suitable cross-sectional configurations other than a circular cross-sectional configuration for the wound-type cartridge design include, but are not limited to, triangular, square, rectangular, oblong, oval, star, parallelogram, rhombus, hexagonal, and octagonal cross-sectional configurations.
  • the cross-sectional area through the wound-type cartridge design filter may be substantially constant along a length of the filter or may vary along a length of the filter.
  • the filter comprising PVA material is a pleated filter for use in both air and water applications.
  • Pleated filter 40 comprises a filter media 41 within housing 42.
  • These filters 40 may have a cage-type housing 42, wherein the filter media 41 is fully supported from all sides (or combinations of more than one side) to ensure filter integrity.
  • the housing 42 may be metal, plastic or another material.
  • the filter media 41 exists as a woven, knitted or nonwoven sheet, either single or multi-layered, which is pleated to enhance support and maximize filtering surface area.
  • the filter media 41 may also exist as an extruded, monofilament design.
  • HEP A High Efficiency Particulate Air
  • FIG. 1 A Variations of this filter are used in High Efficiency Particulate Air (HEP A) filters when venting radioactive systems, use in radioactive vacuum cleaners, or other applications where radioactive airborne contamination is a concern.
  • FIG. 1 A Variations of the pleated filter is used in water applications, such as purification systems in reactors, spent fuel pool clean up, and make-up water filtering.
  • Pleated filters are commonly used in home and industrial applications as listed above.
  • the housing 42 may be prepared from a water-soluble, water-degradable or water-dispersible material similar to the central support core 12 described above.
  • suitable water-soluble materials include, but are not limited to, polyvinyl alcohols used to make the filtration component (e.g., filter media 41 of pleated filter 40 shown in FIG. 4) of the filters of the present invention.
  • Suitable water-degradable or water- dispersible materials include, but are not limited to, polymers disclosed in U.S. Patent No. 6,162,852 assigned to Microtek Medical Holdings, Inc., the entirety of which is hereby incorporated by reference.
  • the housing 42 also solubilizes and/or disperses when exposed to alkaline having a water temperature above about 37°C further reducing the amount of waste resulting from the filter media.
  • filter 40 of FIG. 4 has a cylindrical housing design
  • filter 40 may have any volumetric shape other than a cylindrical shape (e.g., a circular cross-sectional configuration).
  • Suitable cross-sectional configurations other than a circular cross-sectional configuration for the pleated design include, but are not limited to, triangular, square, rectangular, oblong, oval, star, parallelogram, rhombus, hexagonal, and octagonal cross-sectional configurations.
  • the cross-sectional area through the pleated design filter may be substantially constant along a length of the filter or may vary along a length of the filter.
  • the filter may be a flat or pleated filter having any of the above-mentioned areal configurations.
  • the filter may have a circular, triangular, square, rectangular, oblong, oval, star, parallelogram, rhombus, hexagonal, or octagonal shape.
  • the filter may have a structural support in contact with the filter or may be self-supporting (i.e., the filter does not require a supporting structure).
  • Such filters are particularly useful for air filtration, wherein air passes through the filter by entering a first major surface and exiting a second major surface.
  • a non-limiting example of such a filter is a rectangular, pleated filter having a length of 60 cm, a height of 30 cm, and a thickness of about 3 cm.
  • Monolithic filter structures, membrane filters, and various other common forms of filters may be constructed using PVA as the filter material instead of conventional, water-insoluble materials.
  • the filter may comprise as much as 90 percent by weight (pbw) or more of water-soluble material, such as PVA. h one embodiment of the present invention, the filter comprises at least about 50 pbw of water-soluble material, such as PVA, based on a total weight of the filter.
  • the filter comprises more than 60 pbw (desirably, at least about 70 pbw; more desirably, at least about 80 pbw; even more desirably, at least about 90 pbw; even more desirably, at least about 95 pbw; and even more desirably, 100 pbw) of water-soluble material, such as PVA, based on a total weight of the filter.
  • the PVA filters of the present invention may comprise PVA alone or in combination with other water-soluble, water-degradable or water-dispersible materials as described above.
  • Suitable materials that may be used in combination with PVA include, but are not limited to, polyacrylic acid; polymethacrylic acid; polyacrylamide; water-soluble cellulose derivatives comprising methyl celluloses, ethyl celluloses, hydroxymethyl celluloses, hydroxypropyl methyl celluloses, and carboxymethyl celluloses; carboxymethylchitin; polyvinyl pyrrolidone; ester gum; water-soluble derivatives of starch comprising hydroxypropyl starch and carboxymethyl starch; water-soluble polyethylene oxides; alkali water-soluble materials comprising ethylene copolymers of acrylic acid (EAA) and methacrylic acid (EMAA), and salts thereof; and ionomers containing acrylic acid and/or methacrylic acid.
  • EAA acrylic acid
  • EAA methacrylic acid
  • the filter media of the filters comprises PVA material.
  • the PVA material comprises polyvinyl alcohol with or without acetyl groups, cross-linked or uncross-linked.
  • the filter media of the filters consists essentially of or consists of PVA material.
  • all of the components of the filter, including the filter media consist essentially of or consist of PVA material.
  • Processors for disposing of the filter media can be any desired size. As described below, some methods of disposal may include an oxidation step, wherein an oxidizer is used to degrade polymers within a treated waste stream. In the process steps describe below, oxidizer concentration may vary, effluents may be filtered or not, etc. Processing can be done at a users facility or taken to a remote location. Effluents may also be ion exchanged or not.
  • the filter of the present invention is placed into a small processor (60 gallon, nominal).
  • the processor may be located on top of a container housing used radioactive ion exchange resin that is being prepared for disposal.
  • the filter processor is filled with water and heated to a solubilizing temperature for the filter.
  • the solubilizing temperature may be (i) greater than about 37°C, (ii) greater than about 50°C, (iii) greater than about 75°C, (iv) greater than about 90°C, or (v) near boiling conditions depending on the water-solubility of the materials used.
  • the filter media will completely dissolve, leaving at most only the filter housing and/or support structures, although in some embodiments of the present invention, the filter housing and/or support structures may also dissolve.
  • the liquid mixture containing the dilute liquid PVA will be allowed to cool as appropriate then discharged.
  • the effluent may be directed to a vessel containing ion exchange resin.
  • the PVA and radioactive isotopes will be deposited in the resin matrix, attaching itself mechanically throughout the torturous path as well as adhering to ion exchange sites.
  • the filter housing and support structure will then be removed and disposed of as low-level radioactive, compactable waste.
  • the filter of the present invention is placed into a small processor (60 gallon, nominal).
  • the processor may be located on top of a container housing used radioactive resin that is being prepared for disposal.
  • the filter processor is filled with water, and any of the following components are added to the processor: a polymer degradation-enhancing reactant, a precursor to a polymer degradation-enhancing reactant, an oxidizer, ozone, or a combination thereof.
  • a chemical oxidizer e.g., hydrogen peroxide
  • an optional catalyst e.g., ferrous sulfate or a Fenton reagent
  • the aqueous bath may be heated to near boiling conditions as described above.
  • the filter media completely dissolves, and its chemical form altered into a dilute aqueous mixture of organic acids, leaving at most only the filter housing and support structures, although in some embodiments of the present invention, the filter housing and/or support structures may also dissolve.
  • the resulting liquid mixture containing organic acids will be allowed to cool as appropriate, then drained to the resin container.
  • the organic acids will be deposited in the resin matrix, where the radioactivity and the acids will attach to the ion exchange sites.
  • the filter housing and support structure will then be removed, when applicable, and disposed of as low-level radioactive, compactable waste.
  • the filter housing and/or core component may also comprise water-soluble and/or water- degradable polymeric material as described above.
  • Pleated cartridge filters are commonly used in nuclear utilities to maintain water purity in Refueling Pools and Spent Fuel Pools. These filters are housed in a filter housing and submersed in the appropriate pool. Water is pumped through the filter (by an integrally attached pump) to maintain the radioactivity concentration at an acceptable level. When the filter is taken out of service, it is moved out of the housing remotely and placed in an underwater disposal container. This container is removed from the pool and the filter transferred to a High Integrity Container (HIC) for storage until it can be processed for its final disposition.
  • HIC High Integrity Container Due to stringent regulations, only a small number of filters can be packaged in a HIC, a number based on total radioactivity, radioactive dose rates and physical geometry.
  • the filter media of the present invention eliminate many of the problems associated with conventional filters and methods of handling conventional filters.
  • the filter media of the present invention possess other advantages in that the filters may be utilized to take much higher dose rates. Since the filter media of the present invention do not need to be buried in filter form, a cap on dose rate is not necessary. This allows the utility to use less filters to do the same job, saving the cost of extra filters and more importantly, saving the downtime and labor of changing, handling and disposing of more filters.
  • the filter media of the present invention may be used in a number of applications including, but not limited to, the treatment of polymer(s), as well as, degradation-enhancing reactant(s) or precursors thereof, which may be present in an aqueous environment.
  • This type of process is described in U.S. Patent No. 6,623,643 and International Publication No. WO03/074432 Al, the subject matter of both of which is hereby incorporated in its entirety by reference.
  • U.S. Patent No. 6,623,643 and WO03/074432 Al processes are described, wherein a polymer is not completely solubilized in the aqueous environment.
  • the unsolubilized polymer can optionally be removed from the environment by a suitable means, such as filtration and then recycled or reused.
  • the filter media of the present invention may be used in this filtration step.
  • U.S . Patent No. 6,623,643 and WO03/074432 Al disclose embodiments, wherein polymer is solubilized prior to the introduction of a degradation-enhancing reactant or precursor thereof. In these embodiments, it may be desirable to filter non-solubilized material from the aqueous solution prior to introduction of the degradation-enhancing reactant or a precursor thereof using the filter media of the present invention.
  • the processes disclosed in U.S. Patent No. 6,623,643 and WO03/074432 Al may also include "post-treatment" of the aqueous environment.
  • the precise type of post-treatment can depend on the nature of the aqueous environment.
  • the acids can then be depleted through biodegrading the organic acids.
  • the pH should be adjusted to a value within the approximate range of about 3.0 to about 10.0 or, more preferably, within the approximate range of about 5.0 to about 8.0 or, even most preferably, within the approximate range of about 6.0 to about 7.0 It is desired to pass the aqueous waste stream through a reverse osmosis unit after the biodegradation.
  • Biodegradation may include inoculating the aqueous waste stream with microorganisms such as aerobic, heterotrophic bacteria or anaerobic bacteria.
  • the inoculated aqueous environment or waste stream may be exposed to an aerated, fluidized bed in a bioreactor which contains support materials such as pulverized, activated carbon or plastic bio beads.
  • the inoculated aqueous waste stream may also be exposed to a fixed media reactor or an activated sludge process.
  • Conventional extended aeration, step aeration, sequential batch reactions and contact stabilization may also be used to reduce the organic carbon content of the inoculated aqueous waste stream.
  • the biological activity of the microorganisms may be enhanced by injecting a nutrient containing nitrogen, phosphorus, potassium or a trace mineral, into the bioreactor.
  • the final resultant waste stream includes neutralized water depleted of organic carbon, which is suitable for delivery to a waste treatment facility or for reuse or recycling.
  • a filtration and or ion exchange process may be used to remove radioactive material from the solution.
  • the step of removing radioactive material may be accomplished by filtering the solution through a micron filter, which has a nominal pore size ranging between about 10 and about 100 microns to remove radioactive elements.
  • a second particulate filter having a nominal pore size between about 0.1 micron and about 1.0 micron, a reverse osmosis unit or an ion exchange unit consisting of an anion bed, a cation bed or an anion/cation combination bed that reduces depleted radioisotopes at an elemental level may also be used.
  • the filter media of the present invention may be used.
  • the waste stream may also be adjusted to a higher pH. More desirably, the pH adjusted waste stream can also be biodegraded to eliminate the organic acids. If the waste stream is to be biodegraded, it is desirable to neutralize the waste stream by adding sodium hydroxide until the pH is adjusted to within the approximate range of about 3.0 to about 10.0, preferably from about 5.0 to about 8.0 or, even more preferably from about 6.0 to about 7.0. h an embodiment disclosed in U.S. Patent No. 6,623,643 and WO03/074432 Al for treating materials that come from a source that may have been exposed to radioactivity, the potentially radioactive materials may be filtered using the filter media of the present invention.
  • the filtering step may occur at any point in the process, e.g., prior to adding the degradation-enhancing reactant (e.g., an oxidizing agent) to the aqueous waste stream, after producing the degradation products (e.g., organic acids) from the polymer, or after treatment of the degradation products, e.g., biodegrading the organic acids.
  • the degradation-enhancing reactant e.g., an oxidizing agent
  • Contaminated products may include, but are not limited to, at least one garment, protective clothing, coveralls, booties, face masks, gloves, apparel, linens, drapes, towels, fabrics, films, laminates containing at least one fabric or film, sponges, mop heads, webs, bags, gauze, pads, wipes, pillows, bandages, filters of the present invention, or combinations thereof.
  • Filters for removing potentially radioactive material include particulate filters of the present invention having a nominal pore size of about 10 microns to about 100 microns and optionally a second particulate filter of the present invention having a nominal pore size of from about 0.1 micron to about 1.0 micron through which the waste stream is circulated. Filtering may also comprise circulating the aqueous waste stream through an ion exchange bed.
  • the process includes: (a) filtering potentially radioactive material from the aqueous waste stream; (b) neutralizing the pH of the aqueous waste stream after producing organic acids; and (c) depleting organic acids from the aqueous waste stream after neutralizing the pH.
  • the filter media of the present invention may be used.
  • filtering material e.g., radioactive material from the aqueous environment
  • biodegrading the resulting degradation products in the aqueous environment e.g., organic acids form CO 2 , H 2 O and biomass;
  • the aqueous environment is desirably filtered through strainers to remove any undissolved polymer material and non-water-soluble polymer constituents in the solution.
  • the strainer may be prepared using the above-described PVA material for forming filter media of the present invention.
  • the strainers will have a mesh size in an approximate range of between about 20 and about 50 mesh. In a more desired embodiment, the strainers will have a mesh size of approximately about 30 mesh. Undissolved polymer material trapped in the strainers can be recirculated for final solubilization.
  • polymer material will constitute an approximate range of greater than 0% to about 10.0% by weight in the solution.
  • polymer material will constitute an approximate range of between about 4.0% to about 6.0% by weight in the solution, hi still a more desired embodiment, polymer material will be present in an amount of about 5.0% by weight in the solution. Additionally, in a more desired embodiment, the temperature of the solution during the filtration process step is maintained at or above about 150°F to prevent precipitation of the PVA out of solution prior to its destruction.
  • a filter media of the present invention may be used to filter and deplete radioactivity in solution.
  • This process step is optional and only applicable when the water-soluble polymer material contains potentially radioactive waste. This step may or may not be required, for example, at a nuclear facility. If the polymer material was exposed to radioactivity that affects the disposability of the solution, then this process step should be added. With the addition of this process step, a low-level radioactive waste management system is created. This waste management system can be used as an alternative approach to current dry active radioactive waste treatment methods. The process step of removal of radioactivity typically occurs prior to biological degradation. A more detailed desired embodiment of this process step includes the basic steps of:
  • radioactivity may be present in process fluids in both elemental and particulate form.
  • Filtration of the solution removes radioactive particulates.
  • the solution is passed through a particulate filter having a nominal pore size ranging approximately between about 10 and about 100 microns, hi a more desired embodiment, the solution is then passed through a second particulate filter having a nominal pore size ranging approximately between about 0.1 micron and about 1.0 micron.
  • a filter media of the present invention may be used in these filtration steps.
  • filtering material e.g., radioactive material
  • step (9) removing any insoluble components from the reactor.
  • This process differs from the previously discussed process in connection with steps (l)-(5), which involve solubilization of the polymer prior to introduction of the degradation-enhancing reactant/precursor and formation of the degradation-enhancing reactant from the precursor.
  • Formation of the degradation- enhancing reactant from the precursor may comprise irradiation of the solution with electromagnetic radiation, heat, or a combination thereof as explained in U.S. Patent No. 6,623,643 and WO03/074432 Al.
  • filter media of the present invention may be used in steps (2) and (6) of this particular process.
  • solution vessel 100 is an autoclave.
  • Solution vessel 100 is desirably made of stainless steel or similarly corrosively resistant material.
  • Solution vessel 100 is connected by a plumbing line 102 to a filter system 104.
  • Filter system 104 is connected by plumbing line 106 to a pump 108.
  • a plumbing line 112 intersects and connects plumbing line 110 to a heat exchanger 114.
  • Heat exchanger 114 is connected by a plumbing line 116 back to solution vessel 100 to form a recirculating communication.
  • Photochemical reaction vessel 200 is desirably made of stainless steel or similarly corrosively resistant material.
  • photochemical reaction vessel 200 is comprised of a bank of individual photochemical reactors (not shown) arranged in an array within the reaction vessel.
  • a mechanical mixer (not shown) is located within reaction vessel 200 to provide circulation of the contents.
  • Each of the reactors comprising at least one high-intensity ultraviolet lighting element.
  • the photochemical reactors within reaction vessel 200 generate ultraviolet radiation in the wavelengths between about 185 and about 250 nanometers.
  • An oxidative agent injection system 300 is connected by a plumbing line 302 to reaction vessel 200. h a desired embodiment, oxidative agent injection system 300 comprising a programmable logic controller, sensor, recorder, and dispensing mechanism, such as is well known in industrial chemistry.
  • Photochemical reaction vessel 200 is connected by a plumbing line 202 to a pump 204.
  • Pump 204 is connected by a plumbing line 206 to a neutralization vessel 400.
  • a plumbing line 208 intersects plumbing line 206 and is connected to reaction vessel 200 to permit pump operated re-circulating photochemical treatment of the solution.
  • a pH neutralizing system 402 is connected by a plumbing line 404 to neutralization vessel 400.
  • pH neutralizing system 402 comprising an automatic pH controller.
  • Neutralization vessel 400 is connected by a plumbing line 406 to a pump 408.
  • Pump 408 is connected by a plumbing line 410 back to neutralization vessel 400 to form a recirculating communication.
  • Neutralization vessel 400 is connected by a plumbing line 412 to bio cells 500.
  • Bio cells 500 are desirably of the fixed media aerobic type or activated sludge processes. Entrance accommodations are made for administration of air, microbes and nutrients to the bio cells by any means well known in the industry.
  • Bio cells 500 are connected by a plumbing line 502 to a pump 504.
  • Radioactive material filtration system 600 is connected by a plumbing line 606 back to bio cells 500 to form a recirculating communication.
  • Bio cells 500 are connected by a plumbing line 508 for discharge.
  • a plumbing line 602 intersects and connects plumbing line 206 to a radioactive material filtration system 600.
  • Radioactive material filtration system 600 is connected by a plumbing line 604 back to plumbing line 206 to form a circulating communication.
  • radioactive material filtration system 600 is connected by a plumbing line 606 back to reaction vessel 200 to form a recirculating communication by which depletion of radioactivity in solution can be performed coincident with oxidation-reduction of the solution.
  • Radioactive material filtration system 600 may alternatively be connected within the disclosed system at any position between solution vessel 100 and neutralization vessel 400.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Filtering Materials (AREA)
  • Multicomponent Fibers (AREA)
  • External Artificial Organs (AREA)
  • Woven Fabrics (AREA)
  • Filtration Of Liquid (AREA)

Abstract

La présente invention a trait à des filtres comprenant un matériau d'alcool polyvinylique hydrosoluble. L'invention a également trait à des procédés de fabrication et d'utilisation de filtres formés à partir de matériau d'alcool polyvinylique hydrosoluble.
EP03800134A 2002-12-24 2003-12-24 Milieu filtrant d'alcool polyvinylique Withdrawn EP1590064A4 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US43631802P 2002-12-24 2002-12-24
US436318P 2002-12-24
PCT/US2003/041099 WO2004058374A2 (fr) 2002-12-24 2003-12-24 Milieu filtrant d'alcool polyvinylique

Publications (2)

Publication Number Publication Date
EP1590064A2 EP1590064A2 (fr) 2005-11-02
EP1590064A4 true EP1590064A4 (fr) 2007-11-21

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EP03800134A Withdrawn EP1590064A4 (fr) 2002-12-24 2003-12-24 Milieu filtrant d'alcool polyvinylique

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US (1) US20040192135A1 (fr)
EP (1) EP1590064A4 (fr)
JP (1) JP2006521911A (fr)
KR (1) KR20050085868A (fr)
CN (1) CN1732036A (fr)
AU (1) AU2003299860A1 (fr)
CA (1) CA2507041A1 (fr)
RU (1) RU2327507C2 (fr)
UA (1) UA81651C2 (fr)
WO (1) WO2004058374A2 (fr)

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CA2639666A1 (fr) * 2007-09-21 2009-03-21 Ambio Biofiltration Ltd. Materiau biofiltrant et dispositif de biofiltration y faisant appel
BR112012011241B1 (pt) * 2009-11-17 2021-10-26 Hana Inspection & Engineering Co., Ltd Método para o tratamento de produtos protetores fabricados por álcool polivinílico e aparelho para o tratamento de produtos protetores de pva
CA3085086C (fr) 2011-12-06 2023-08-08 Delta Faucet Company Distribution d'ozone dans un robinet
KR101313714B1 (ko) 2012-02-15 2013-10-01 송원숙 수 처리용 섬유 여재를 갖는 드럼형 필터
JP2014032066A (ja) * 2012-08-02 2014-02-20 Japan Vilene Co Ltd 放射性物質吸着材
TW201546830A (zh) * 2014-01-27 2015-12-16 3M Innovative Properties Co 用於如變壓器之電氣設備之電性絕緣材料及導體包覆材
CN105934801B (zh) * 2014-01-27 2019-03-29 3M创新有限公司 电绝缘材料和变压器
US11458214B2 (en) 2015-12-21 2022-10-04 Delta Faucet Company Fluid delivery system including a disinfectant device
RU2616972C1 (ru) * 2016-02-12 2017-04-19 Общество с ограниченной ответственностью Научно-производственное предприятие "Эксорб" Способ очистки жидких радиоактивных отходов
CN107010775A (zh) * 2017-04-28 2017-08-04 杭州卧特松环保科技有限公司 多材质复合滤芯
JP7368167B2 (ja) * 2019-10-04 2023-10-24 株式会社ディスコ 集塵処理装置
CN112442771B (zh) * 2020-11-13 2022-03-08 浙江羊绒世家服饰股份有限公司 一种水溶性纤维和高支羊绒纱纺制工艺
CN113073416A (zh) * 2021-05-11 2021-07-06 李昌荣 一种基于可降解纤维生产的面料及其生产工艺
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Also Published As

Publication number Publication date
KR20050085868A (ko) 2005-08-29
EP1590064A2 (fr) 2005-11-02
WO2004058374A2 (fr) 2004-07-15
RU2327507C2 (ru) 2008-06-27
UA81651C2 (ru) 2008-01-25
AU2003299860A1 (en) 2004-07-22
RU2005123383A (ru) 2006-01-20
US20040192135A1 (en) 2004-09-30
CA2507041A1 (fr) 2004-07-15
AU2003299860A8 (en) 2004-07-22
JP2006521911A (ja) 2006-09-28
WO2004058374A3 (fr) 2004-10-07
CN1732036A (zh) 2006-02-08

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