EP1542809A2 - Support recevant des molecules presentant une activite et procede pour assurer la presence de telles molecules sur un tel support - Google Patents
Support recevant des molecules presentant une activite et procede pour assurer la presence de telles molecules sur un tel supportInfo
- Publication number
- EP1542809A2 EP1542809A2 EP03780273A EP03780273A EP1542809A2 EP 1542809 A2 EP1542809 A2 EP 1542809A2 EP 03780273 A EP03780273 A EP 03780273A EP 03780273 A EP03780273 A EP 03780273A EP 1542809 A2 EP1542809 A2 EP 1542809A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- support
- molecules
- active molecules
- composition
- polymerizable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000694 effects Effects 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims description 25
- 239000000203 mixture Substances 0.000 claims abstract description 54
- 239000000126 substance Substances 0.000 claims abstract description 48
- 238000004132 cross linking Methods 0.000 claims description 13
- 238000006116 polymerization reaction Methods 0.000 claims description 13
- 230000001747 exhibiting effect Effects 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 241000238876 Acari Species 0.000 claims description 6
- 238000004040 coloring Methods 0.000 claims description 6
- 230000005855 radiation Effects 0.000 claims description 6
- 241000255925 Diptera Species 0.000 claims description 5
- 241000238631 Hexapoda Species 0.000 claims description 5
- 241000894006 Bacteria Species 0.000 claims description 4
- 241000196324 Embryophyta Species 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000010186 staining Methods 0.000 claims description 4
- 241000195940 Bryophyta Species 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 238000009109 curative therapy Methods 0.000 claims description 3
- 201000010099 disease Diseases 0.000 claims description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 3
- 239000000077 insect repellent Substances 0.000 claims description 3
- 238000011321 prophylaxis Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000002917 insecticide Substances 0.000 claims description 2
- 239000004753 textile Substances 0.000 claims description 2
- 238000011282 treatment Methods 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229960000490 permethrin Drugs 0.000 description 2
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- ZEYUSQVGRCPBPG-UHFFFAOYSA-N 4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one Chemical compound OCN1C(O)C(O)N(CO)C1=O ZEYUSQVGRCPBPG-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000005874 Bifenthrin Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- VGGLHLAESQEWCR-UHFFFAOYSA-N N-(hydroxymethyl)urea Chemical compound NC(=O)NCO VGGLHLAESQEWCR-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000012550 audit Methods 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000002925 chemical effect Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000009193 crawling Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- -1 wool Polymers 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
Definitions
- the present invention relates, on the one hand, to a support device receiving molecules having an activity, either against organisms or undesirable phenomena, or in favor of a desired phenomenon, on the other hand, to a process consisting in ensuring the presence of these molecules at the level of such a support and, on the other hand, to a composition intended to implement this process and / or to be associated with said support.
- the invention relates to the field of the treatment of supports and will find its application when it is a question of producing supports which have particular properties, in particular within the framework of the protection of this support or of an element receiving such a support, against undesirable effects.
- a first method consists in ensuring the attachment of molecules to a support by making a covalent bond between this support and these molecules. This is, for example, the case when it comes to fixing coloring molecules on a support, in particular cellulosic.
- Such a method has a certain number of drawbacks consisting in the fact that the production of a covalent bond, on the one hand, requires the intervention of specific chemicals as well as a substantial supply of energy and, on the other hand and above all, causes an irreversible chemical modification of the support as well as of the structure and the activity of the molecules which is not admissible.
- Another method consists in ensuring the attachment of molecules to a support by bonding these molecules using a binder.
- Such bonding is in fact carried out by polymerization of this binder at high temperature, which has a certain number of drawbacks consisting, on the one hand, in stiffening the support and, on the other hand, by flooding the molecules within the binder, which makes these molecules completely inactive.
- the present invention seeks to overcome the drawbacks of the devices and methods of the prior art.
- the invention relates to a process consisting in ensuring the presence, at the level of a support, of molecules exhibiting an activity, in particular chemical, bio-chemical or similar, either against organisms or undesirable phenomena. , either in favor of a desired phenomenon, characterized by the fact that:
- a composition is produced containing, on the one hand, active molecules and, on the other hand, a substance constituted by molecules of the polymerizable and / or crosslinkable type capable of forming a network having at least one amorphous zone; - It ensures the presence of this composition at this support; at least part of said active molecules are trapped in at least one amorphous zone defined by the polymerizable and / or crosslinkable molecules contained in the composition present at said support, this while maintaining the activity of these trapped active molecules.
- the invention also relates to a support device receiving molecules having an activity, in particular chemical, biochemical or similar, either against organisms or undesirable phenomena, or in favor of a desired phenomenon, characterized by fact that audit support are associated means arranged to ensure trapping, at the level of this support, of at least part of the active molecules while maintaining the activity of the trapped active molecules.
- the trapping means consist of a substance containing molecules of the polymerizable and / or crosslinkable type forming a network having at least one amorphous zone at the level of which at least a portion of the active molecules are trapped .
- the trapping means are defined at the level of a superposition of several layers, on the one hand, adsorbed on the surface of said support, on the other hand, each consisting of a substance containing polymerizable and / or crosslinkable molecules and, furthermore, each comprising at least one amorphous zone between which and / or inside which said active molecules are trapped.
- the invention also relates to a composition intended to implement the method mentioned above and / or intended to be associated with a support with a view to obtaining the support device described above, this composition being characterized by the fact that it contains, on the one hand, active molecules and, on the other hand, a substance constituted by molecules of the polymerizable and / or crosslinkable type capable of forming a network having at least one amorphous zone.
- the advantages of the present invention consist in that the active molecules are made integral with the support by means of trapping means, on the one hand, ensuring an effective fixing of these molecules on the support and, on the other hand, n '' in no way affecting the activity of these active molecules.
- Another advantage relates to the fact that the implementation of the method for producing a support receiving active molecules is easy.
- Yet another advantage of the invention is that this process makes it possible to envisage, without destruction or inhibition, the fixation of many different types of molecules exhibiting activity in many fields, this on a large quantity of supports of diverse and varied nature.
- An additional advantage relates to the fact that the active molecules can be arranged in the form of superimposed layers which can be removed successively (in particular by mechanical or chemical effect such as, for example, by washing, by friction or other of the support) which, d on the one hand, makes it possible to maintain the activity of the support and, on the other hand, authorizes a successive activation of identical or even different molecules (for example for a different action) trapped at the level of said support.
- Figure 1 is a schematic view corresponding to a step of the method according to the invention consisting in ensuring the presence of a composition containing active molecules and polymerizable and / or crosslinkable molecules at the support, this according to a particular embodiment of this invention.
- Figure 2 is a schematic view corresponding to a support device according to the invention at which the presence has been ensured of a composition containing active molecules and polymerizable and / or crosslinkable molecules.
- FIG. 3 is a diagrammatic view of a support device according to the invention having amorphous zones at the level of which active molecules are trapped.
- the present invention relates to the field of treatment of supports and will find its application when it is a question of producing supports which have particular properties, for example when it is a question of ensuring the protection of this support or of a element receiving such support, this against undesirable effects.
- a support 1 In order to confer such properties on a support 1, it is necessary to ensure the presence, at the level of this support 1, of molecules 2, 2 ′ having an activity, in particular chemical, biochemical or similar. According to a first type of support 1, such an activity can be exercised against organisms (micro-organisms, animals, plants, etc.) or undesirable phenomena (radiation, etc.), or even and according to another type of support 1, exercising in favor of desired phenomena (coloring, etc.).
- the invention therefore relates to a support device 1 to which are associated means 3 arranged to ensure trapping, at the level of this support 1, of at least part 2 of said active molecules 2, 2 ′ present at this level. support 1.
- These trapping means 3 are, moreover and despite their trapping function, designed capable of maintaining the activity of said active molecules 2, as the case may be, against undesirable organisms / phenomena or in favor of the desired phenomena.
- the support device 1 receives, at its surface 4 and / or in its volume 5, a substance 6 containing molecules of the polymerizable and / or crosslinkable type capable of to form a network having at least one amorphous zone 7 as well as at least one crystalline zone 8.
- these active molecules 2 ′ can be trapped, as the case may be, within a crystalline zone 8 or between such a crystalline zone 8 and said support 1 (FIG. 3). Due to their imprisonment, such active molecules 2 ′ are inhibited and lose their activity against undesirable organisms / phenomena or in favor of the desired phenomena. However, as shown in FIG. 3, other active molecules 2 are find at least one amorphous zone 7 constituting said trapping means 3 of these molecules 2 ensuring the joining of the latter 2 of said support 1 while maintaining their activity, as the case may be, against undesirable organisms / phenomena or in favor of the desired phenomena.
- substance 4 contains molecules of polymerizable and / or crosslinkable type which, by incomplete polymerization and / or crosslinking, are capable of constituting at least one amorphous zone 7.
- the amorphous zone 7, at the level of which are trapped said active molecules 2 is constituted by a polymerization and / or incomplete crosslinking of the polymerizable and / or crosslinkable molecules entering into the composition of substance 6 defining said trapping means 3.
- the realization such an amorphous zone 7 can be ensured in different ways such as, for example, by subjecting said substance 6 to radiation (in particular UV or other) for a determined period.
- such an amorphous zone 7, at the level of which said active molecules 2 are trapped is constituted by a dried portion of the substance 6 containing the polymerizable and / or crosslinkable molecules.
- the trapping means 3 are defined at the level of at least one layer, on the one hand, adsorbed on the surface 4 of said support 1 and, on the other hand, constituted by a substance 6 containing polymerizable and / or crosslinkable molecules.
- a layer comprises at least one amorphous zone 7 behind which and / or inside which said active molecules are trapped 2.
- said active molecules 2 can be trapped at the rear of such an amorphous zone 7.
- the polymerizable and / or crosslinkable molecules are capable of forming a network having openings whose cross section is smaller than that of an active molecule 2 so that the latter 2 is trapped through the network, to the rear of the latter, while remaining active with respect to the external environment.
- said active molecules 2 can be trapped inside such an amorphous zone 7.
- the polymerizable and / or crosslinkable molecules are capable of forming a network constituted by channels or the like. inside which said active molecules 2 are trapped while remaining active with respect to the external environment.
- said trapping means 3 are defined at the level of a superposition of several layers, on the one hand, adsorbed on the surface 4 of said support 1, on the other hand, constituted , each by a substance 6 containing polymerizable and / or crosslinkable molecules and, on the other hand, also, each comprising at least one amorphous zone 7 between which and / or inside which said active molecules 2 are trapped.
- Such layers preferably adopt a structure of the aforementioned type (network with openings or channels).
- a preferred embodiment of the invention consists in that the amorphous zones 7 of several superimposed layers are themselves superimposed.
- an amorphous zone 7 has greater brittleness than a crystalline zone 8. Also and through an appropriate treatment, it is possible to remove part of a layer of substance 6 corresponding to an amorphous zone 7 of this layer. Such an embodiment advantageously makes it possible to remove from the support 1 active molecules 2 trapped by an upper layer and having lost their activity in order to bring the active molecules 2 trapped by a lower layer close to the surface having only had little or no activity.
- an appropriate treatment may consist of a mechanical and / or chemical treatment.
- a treatment can consist of friction, abrasion, washing of said support 1, this under particular conditions (in particular of temperature).
- the amorphous zone or zones 7 and / or the active molecules 2 may be liable to undergo a deformation allowing such an active molecule 2 to pass through or s 'extract from a layer of substance 6 to be released into the outside environment.
- the deformation of an active molecule 2 can, for example, be caused by an insect or the like (for example a mosquito) coming into contact with such a molecule 2.
- the deformation of such a molecule 2 and / or an amorphous zone 7 can also result from voluntary contact with an element external to the support 1, in particular contact with the skin (for example for active molecules of the drug type with transcutaneous diffusion) or d 'a contact by friction, buffering or the like, this in the context of a treatment aimed at ensuring, voluntarily, a release of such active molecules 2.
- these 2, 2 ′ may be in an emulsifiable, dispersible form or soluble in a solvent, in particular water.
- such active molecules 2 exhibit activity against insects (crawling, flying or otherwise) and can be of the insecticide, insect repellant or similar type.
- insect repellent molecules such as permethrin, deltamethrine or the like.
- insecticidal and repellant molecules such as, for example, bifenthrin or ethophen prox.
- Another category of active molecules 2 consists of those exhibiting activity against bacteria, microbes (molecule of the isothiazolinone type or the like), mites (molecule of the triclosan type or the like) or the like.
- Yet another category relates to active molecules 2 exhibiting activity against plants, in particular mosses.
- active molecules 2 which have activity in the prophylaxis or curative treatment of a disease.
- active molecules 2 have an activity against the fixing of staining products on the support 1 which receives them.
- Another category concerns that of the active molecules 2 which exhibit activity against radiation, in particular Ultra-violet.
- the latter 1 can be of different types.
- this support 1 can be constituted, at least in part, by a textile material.
- a textile material can be of the knitted, woven, non-woven or other type and consist of natural, artificial or synthetic fibers and / or filaments such as, for example, polyester, viscose, cotton, wool, polyamide. , silk, or a mixture of different fibers and / or filaments.
- a particular embodiment consists in that the support is a clothing element (a shirt, a sweater, pants, a jacket or the like).
- an application of the invention may consist in ensuring the presence, at the level of such a clothing element, of molecules exhibiting an activity against insects (for example mosquitoes), bacteria , microbes, mites (for example ticks), staining products or even radiation.
- Such a clothing element can also receive molecules designed capable of coloring the support 1 or having an activity in the prophylaxis or curative treatment of a disease to which the wearer of this garment may be subject.
- molecules 2 exhibiting activity against insects for example mosquitoes
- bacteria, microbes, mites for example ticks
- staining products or radiation can also be associated with a support 1 defined by a fabric in the form of a curtain (more particularly a mosquito net, curtains, double curtains or the like).
- Molecules 2 exhibiting such activities as well as molecules exhibiting activity, either against plants (in particular mosses or the like), or in favor of coloring, can be combined with a support 1 constituted by a constituent element of '' a building, such as, for example, a wall, a closing device (in particular a door, a window, a shutter or the like), a blind, a roof, a balcony, a terrace, paving stones or, again, a covering reported on such a constituent element.
- a support 1 constituted by a constituent element of '' a building, such as, for example, a wall, a closing device (in particular a door, a window, a shutter or the like), a blind, a roof, a balcony, a terrace, paving stones or, again, a covering reported on such a constituent element.
- any support 1 made of any material (wood, concrete, fabric , metal, leather, ceramic ...), any kind of active molecules 2 or any kind of mixture of active molecules 2 (of similar, identical, different, complementary activity) according to the type or types of activities that one wishes to confer on this support 1.
- any support 1 made of any material (wood, concrete, fabric , metal, leather, ceramic ).
- any kind of active molecules 2 or any kind of mixture of active molecules 2 of similar, identical, different, complementary activity
- these can be of the polymerizable and / or crosslinkable type.
- polymerizable molecule an acrylic derivative, styrene butadiene, polyurethane, vinyl acetate, urethane or the like.
- crosslinkable molecules these may, without limitation, be constituted by resins of the melamine formaldehyde, methylol-urea, dimethyloldihydroxyethylene urea, formalin urea or other type.
- substance 4 can contain any of these molecules, or even a mixture of several of these molecules.
- this substance 4 may also contain at least one catalyst consisting, for example, of an acid type catalyst such as acetic acid, formic acid or the like or a mixture of such acids.
- an acid type catalyst such as acetic acid, formic acid or the like or a mixture of such acids.
- the present invention also relates to a method consisting in ensuring the presence, at the level of a support 1, of molecules 2, 2 ′ exhibiting an activity, in particular chemical, bio-chemical or similar, of the type mentioned above, this either against organisms or undesirable phenomena, or in favor of a desired phenomenon.
- composition 9 is produced containing, on the one hand, active molecules 2, 2 ′ and, on the other hand, a substance 4 consisting of molecules of the polymerizable and / or crosslinkable type capable of forming a network having at minus an amorphous zone 7;
- composition 9, containing the active molecules 2, 2 ′ as well as the polymerizable and / or crosslinkable molecules is usually produced in the presence of a solvent which can be, for example, water .
- the polymerizable and / or crosslinkable molecules may require the presence of a catalyst to polymerize and / or crosslink as it is, for example, the case for molecules which can be polymerized and / or crosslinkable at high temperature.
- composition 9 containing a substance 4 consisting of polymerizable and / or crosslinkable molecules at high temperature, a catalyst is added to this composition 9.
- a catalyst is added to this composition 9.
- the composition 9 is produced containing a substance 4 consisting of polymerizable and / or crosslinkable molecules at high temperature.
- a substance 4 consisting of molecules capable of polymerizing and / or of crosslinking in the absence of catalyst, more particularly, by self-polymerization or self-crosslinking.
- this composition 9 is ensured at the level of said support 1.
- this support 1 can be immersed in a bath 10 containing such a composition 9, such a bath 10 being, for example, produced in a tank, in particular of a washing machine.
- a bath 10 being, for example, produced in a tank, in particular of a washing machine.
- Such an embodiment can be envisaged in the case of a support 1 adopting the form of a fabric or the like.
- this composition 9 is sprayed on said support 1, this by means of a sprayer adopting, for example, the shape of at least one nozzle.
- a sprayer adopting, for example, the shape of at least one nozzle.
- Such an embodiment can, for example, be envisaged in the context of a support 1 adopting the form of a roof, a blind or the like.
- Yet another embodiment consists in applying such a composition 9 to said support 1, this by means of a brush or a roller. This can be so when this support 1 takes the form of a terrace, a wall or the like.
- a thickener as the case may be, of synthetic type (such as for example an acrylate or other) or natural (such as for example a sodium alginate or other).
- the active molecules 2 are trapped in at least one amorphous zone 7 of the substance 6 contained in said composition 9. In fact, such trapping is ensured by carrying out a polymerization and / or an incomplete crosslinking of the polymerizable and / or crosslinkable molecules contained in this composition 9.
- this trapping of the active molecules 2 in an amorphous zone 7 can be carried out by drying said composition 9 at a temperature significantly below the polymerization and / or crosslinking temperature of the polymerizable molecules and / or crosslinkable contained in the composition. In fact, through such drying, polymerization and / or incomplete crosslinking of these molecules is ensured, leaving room for an unstructured network having amorphous zones 7 where active molecules 2 are trapped.
- drying is ensured at a low temperature in comparison with the polymerization and / or crosslinking temperature of the molecules contained in substance 6.
- such drying of the composition 9 takes place at a temperature below 70 ° C, preferably below 50 ° C, this, preferably, in the open air, in an oven or the like.
- the present invention also relates to a chemical composition 9 intended to implement the method described above and / or intended to be associated with a support 1 with a view to obtaining the above-mentioned support device 1.
- a composition 9 then contains, on the one hand, active molecules 2, 2 ′ and, on the other hand, a substance 4 constituted by molecules of polymerizable and / or crosslinkable ype capable of forming a network having at least one amorphous zone 7.
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
- Catching Or Destruction (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0211729 | 2002-09-23 | ||
FR0211729A FR2844730B1 (fr) | 2002-09-23 | 2002-09-23 | Dispositif support de molecules actives, procede pour assurer la presence de ces molecules sur ledit dispositif et composition pour la mise en oeuvre du procede et l'obtention d'un tel dispositif |
PCT/FR2003/050060 WO2004026492A2 (fr) | 2002-09-23 | 2003-09-23 | Support recevant des molecules presentant une activite et procede pour assurer la presence de telles molecules sur un tel support |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1542809A2 true EP1542809A2 (fr) | 2005-06-22 |
EP1542809B1 EP1542809B1 (fr) | 2008-07-09 |
Family
ID=31970893
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03780273A Expired - Lifetime EP1542809B1 (fr) | 2002-09-23 | 2003-09-23 | Support recevant des molecules presentant une activite et procede pour assurer la presence de telles molecules sur un tel support |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP1542809B1 (fr) |
AT (1) | ATE400371T1 (fr) |
AU (1) | AU2003288363A1 (fr) |
DE (1) | DE60322080D1 (fr) |
ES (1) | ES2310253T3 (fr) |
FR (1) | FR2844730B1 (fr) |
PT (1) | PT1542809E (fr) |
WO (1) | WO2004026492A2 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103341461B (zh) * | 2013-07-25 | 2015-08-19 | 无锡市群征干燥设备有限公司 | 喷雾干燥机的软管清洗装置 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5252387A (en) * | 1991-04-01 | 1993-10-12 | Graniteville Company | Fabrics with insect repellent and a barrier |
US5631072A (en) * | 1995-03-10 | 1997-05-20 | Avondale Incorporated | Method and means for increasing efficacy and wash durability of insecticide treated fabric |
CA2343529C (fr) * | 1998-09-08 | 2004-11-23 | Microban Products Company | Matiere acrylique antimicrobienne |
-
2002
- 2002-09-23 FR FR0211729A patent/FR2844730B1/fr not_active Expired - Fee Related
-
2003
- 2003-09-23 AU AU2003288363A patent/AU2003288363A1/en not_active Abandoned
- 2003-09-23 WO PCT/FR2003/050060 patent/WO2004026492A2/fr active IP Right Grant
- 2003-09-23 AT AT03780273T patent/ATE400371T1/de not_active IP Right Cessation
- 2003-09-23 DE DE60322080T patent/DE60322080D1/de not_active Expired - Lifetime
- 2003-09-23 ES ES03780273T patent/ES2310253T3/es not_active Expired - Lifetime
- 2003-09-23 EP EP03780273A patent/EP1542809B1/fr not_active Expired - Lifetime
- 2003-09-23 PT PT03780273T patent/PT1542809E/pt unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2004026492A3 * |
Also Published As
Publication number | Publication date |
---|---|
FR2844730B1 (fr) | 2005-07-15 |
PT1542809E (pt) | 2008-10-09 |
ATE400371T1 (de) | 2008-07-15 |
AU2003288363A1 (en) | 2004-04-08 |
FR2844730A1 (fr) | 2004-03-26 |
WO2004026492A3 (fr) | 2004-05-06 |
EP1542809B1 (fr) | 2008-07-09 |
WO2004026492A2 (fr) | 2004-04-01 |
ES2310253T3 (es) | 2009-01-01 |
DE60322080D1 (de) | 2008-08-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102926201B (zh) | 一种除蚊缓释布的整理方法 | |
CN103649409B (zh) | 用于浸渍纺织品的组合物 | |
Oliver et al. | Evaluation of a single application of neonicotinoid and multi-application contact insecticides for flatheaded borer management in field grown red maple cultivars | |
Muñoz et al. | Electrospun ethylcellulose-based nanofibrous mats with insect-repellent activity | |
JP2018535944A5 (fr) | ||
EP1542809B1 (fr) | Support recevant des molecules presentant une activite et procede pour assurer la presence de telles molecules sur un tel support | |
Kamari et al. | A mini review of materials used as improvers for insect and arthropod pest repellent textiles | |
EP1432866B1 (fr) | Procede de traitement anti-acarien et anti-microbien de materiaux textiles | |
WO1997024484A1 (fr) | Article de recouvrement pour des lits et analogues, et procede pour sa confection | |
FR3071421B1 (fr) | Procede pour la fabrication d'un support active et support ainsi obtenu | |
JPH08245324A (ja) | 防虫組成物及び防虫布帛 | |
KR100993633B1 (ko) | 참나무시들음병 예방 및 방제방법 | |
FR3068373A1 (fr) | Textile repulsif anti-moustique a effet longue duree | |
JPH032101A (ja) | 防虫性布帛 | |
CA2734294A1 (fr) | Procede pour la fixation de molecules actives sur un support, element actif obtenu par ce procede et composition chimique pour la mise en oeuvre de ce procede | |
CN106702734A (zh) | 一种包含杀虫剂和/或驱虫剂的浸渍纺织品 | |
JPH05311509A (ja) | 防虫性アクリル系合成繊維並びにその製造法 | |
JP2013100269A (ja) | 抗菌性を有する潅水マット | |
JPH02200602A (ja) | 防虫繊維およびその製造方法 | |
Hebeish et al. | Bioallethrin–based cotton finishing to impart long–lasting toxic activity against mosquitoes | |
EP2213786B1 (fr) | Matériau filamenteux ou fibreux imprégné de substances actives | |
WO2004065024A1 (fr) | Support pour molecules actives, procede pour la fixation de molecules actives sur ce support et compositions pour la mise en oeuvre de ce procede | |
WO2012080616A1 (fr) | Procède de fixation de molécules actives sur un support cationique par liaisons ionique et covalente, élément actif comportant un support cationique et des molécules actives fixées par liaisons ionique et covalente sur ce support cationique, support cationique et procède de fabrication d'un tel support cationique | |
Devi et al. | Sustainable moth repellent finishing for wool | |
OA16451A (fr) | Procédé de fixation de molécules actives sur un support cationique par liaisons ionique et covalente, élément actif comportant un support cationique et des molécules actives fixées par liaisons ionique et covalente sur ce support cationique, support cationique et procédé de fabrication d'un tel support cationique. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20050317 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL LT LV MK |
|
DAX | Request for extension of the european patent (deleted) | ||
17Q | First examination report despatched |
Effective date: 20060908 |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: CHT R. BEITLICH GMBH |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: FAFET, JEAN-FRANCOIS Inventor name: WIPF, DENIS |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REF | Corresponds to: |
Ref document number: 60322080 Country of ref document: DE Date of ref document: 20080821 Kind code of ref document: P |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: PT Ref legal event code: SC4A Free format text: AVAILABILITY OF NATIONAL TRANSLATION Effective date: 20080930 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2310253 Country of ref document: ES Kind code of ref document: T3 |
|
NLV1 | Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20081009 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FD4D |
|
BERE | Be: lapsed |
Owner name: CHT R. BEITLICH G.M.B.H. Effective date: 20080930 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080930 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: IE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
26N | No opposition filed |
Effective date: 20090414 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080930 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080930 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080930 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20081009 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20090110 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080923 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20081010 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 14 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 15 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 16 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20180920 Year of fee payment: 16 Ref country code: FR Payment date: 20180925 Year of fee payment: 16 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20180919 Year of fee payment: 16 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: PT Payment date: 20180913 Year of fee payment: 16 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20181022 Year of fee payment: 16 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 60322080 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200401 Ref country code: PT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200424 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20190923 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190930 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190923 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20210129 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190924 |