EP1518000A1 - Alliage al-cu-mg-ag avec si, produit semi-fini realise a partir de cet alliage, et procede de realisation d'un produit semi-fini de ce type - Google Patents

Alliage al-cu-mg-ag avec si, produit semi-fini realise a partir de cet alliage, et procede de realisation d'un produit semi-fini de ce type

Info

Publication number
EP1518000A1
EP1518000A1 EP02751094A EP02751094A EP1518000A1 EP 1518000 A1 EP1518000 A1 EP 1518000A1 EP 02751094 A EP02751094 A EP 02751094A EP 02751094 A EP02751094 A EP 02751094A EP 1518000 A1 EP1518000 A1 EP 1518000A1
Authority
EP
European Patent Office
Prior art keywords
alloy
weight
semi
finished product
content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP02751094A
Other languages
German (de)
English (en)
Other versions
EP1518000B1 (fr
Inventor
Gernot Fischer
Dieter Sauer
Gregor Terlinde
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Otto Fuchs KG
Original Assignee
FUCHS FA OTTO
Otto Fuchs KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FUCHS FA OTTO, Otto Fuchs KG filed Critical FUCHS FA OTTO
Publication of EP1518000A1 publication Critical patent/EP1518000A1/fr
Application granted granted Critical
Publication of EP1518000B1 publication Critical patent/EP1518000B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/057Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with copper as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/14Alloys based on aluminium with copper as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/16Alloys based on aluminium with copper as the next major constituent with magnesium

Definitions

  • the invention relates to an Al-Cu-Mg-Mn alloy for the production of semi-finished products with high static and dynamic strength properties. Furthermore, the invention relates to a semi-finished product made of such an alloy with high static and dynamic strength properties and a method for producing such a semi-finished product.
  • Aluminum alloys AA 2014, AA 2214 which can withstand high static and dynamic loads, are, for example, die forgings for aircraft wheel and brake systems made from these AI alloys in the heat-hardened state. While the stated strength properties of the semi-finished products made from such an alloy are inherent in the semi-finished product, especially at lower temperatures, these properties decrease more rapidly at temperatures of more than 100 ° C. than in the case of alloys of group AA 2618. Semi-finished products made from such alloys have a higher Heat resistance and are used, for example, as compressor wheels for rechargeable diesel engines or for rotors in ultracentrifuges. At temperatures below 100 ° C, however, the aluminum alloys of groups AA 2014 and AA 2214 can withstand higher loads.
  • Compressor wheels have started to use titanium alloys so that the compressor wheels made from them are given the necessary static and dynamic strength properties even at higher temperatures.
  • titanium is expensive and in particular also not suitable for the production of aircraft wheels for this reason.
  • titanium is less suitable as a wheel material due to its limited thermal conductivity.
  • the alloy has the following composition:
  • zirconium (Zr) 0.1 - 0.25% by weight of zirconium (Zr)
  • the claimed alloy has a higher static and dynamic heat resistance and an improved creep resistance with very good fracture mechanical properties. These are achieved in particular with a copper-magnesium ratio between 5 and 9.5, in particular with a ratio between 6.3 and 9.3.
  • the cup The content is preferably between 3.8 and 4.2% by weight and the magnesium content between 0.45 and 0.6% by weight.
  • the copper content is significantly below the maximum solubility for copper in the presence of the claimed magnesium content. As a result, the proportion of insoluble, copper-containing phases is very low, taking into account the other alloying and accompanying elements. This results in an improvement in the dynamic properties and the fracture toughness of the semi-finished products made from such an alloy.
  • part of the claimed alloy is silver with contents between 0.3 and 0.7% by weight, preferably 0.45 and 0.6% by weight.
  • silicon (0.3-0.7% by weight, preferably 0.4-0.6% by weight)
  • curing takes place using the same mechanisms as in silver-free Al-Cu-Mg alloys.
  • the addition process is different for smaller silicon contents due to the addition of silver.
  • the semi-finished products made from such an alloy do have good heat resistance and creep resistance in cooler conditions; however, they do not yet meet the desired requirements. Only silicon contents above 0.3% by weight suppress the otherwise typical change in the precipitation behavior of Al-Cu-Mg-Ag alloys, so that surprisingly higher strength values without sacrificing heat resistance and creep resistance in the Cu and Mg contents according to the invention are achievable.
  • the manganese content of the claimed alloy is 0.1 to 0.5% by weight, preferably 0.2-0.4% by weight.
  • the manganese content is limited to 0.4% by weight.
  • manganese is an alloy component required for structural control.
  • the zirconium alloy contains between 0.10 - 0.25% by weight.
  • aluminides are even more finely dispersed than man- gan aluminides.
  • zirconium aluminides contribute to the thermal stability of the alloy.
  • titanium for grain refining, 0.05-0.15% by weight, preferably 0.10-0.15% by weight, of titanium is added to the alloy.
  • the titanium is expediently added to the alloy in the form of an Al-5Ti-1 B master alloy, as a result of which the alloy automatically contains boron. This forms finely divided, insoluble titanium diborides. These contribute to the thermal stability of the alloy.
  • the alloy can have a maximum of 0.15% iron, preferably 0.10% iron.
  • Fig. 1 A diagram showing the 0.2% proof stress and the
  • Fig. 3 a diagram showing the 0.2% proof stress and the
  • 4a, 4b Diagrams illustrating the fatigue strength of the alloy according to the invention in comparison to a previously known alloy in the state T6 at room temperature and at a temperature of 200 ° C.
  • Table 1 below gives the chemical composition of four alloys according to the invention (B, C, D, E) and the composition of the comparatively examined alloys AA 2214 and AA 2618 again (data in% by weight) (nb: not determined):
  • Semi-finished products were produced from these alloys by the process steps given below: a) casting an ingot from an alloy, b) homogenizing the cast ingot at a temperature which is as close as possible to the melting point of the alloy for a time which is sufficiently long In order to achieve the most uniform possible distribution of the alloy elements in the cast structure, c) hot forming of the homogenized ingot by forging at a block temperature of about 420 ° C, d) solution annealing of the semi-finished product formed by forging at temperatures that are sufficiently high to allow for the Bring the necessary alloying elements evenly distributed in the structure in solution, whereby the solution annealing takes place in a temperature range at 505 ° C over a period of 3 hours, e) quenching the solution-annealed semi-finished product in water at room temperature, f) cold forming the quenched halves euge by cold upsetting by 1 to 2% and g) heat-curing the quenched semi-finished product at temperatures at 170 ° C over a
  • L longitudinal direction: parallel to the main direction of deformation
  • LT long transverse direction: parallel to the width direction
  • ST short transverse direction: parallel to the thickness direction.
  • the improved strengths of the alloy according to the invention can be clearly seen from Tables 2 and 3.
  • the previously known alloy AA 2214 shows good strength values at room temperature, but not at higher temperatures.
  • the creep resistance and the fracture toughness are not only better at room temperature but in particular also at higher temperatures with the claimed alloy than with the previously known alloys.
  • This comparison also shows that the previously known alloys examined only have good properties with respect to individual strength parameters. In no case do they have good properties at all relevant strength values both at room temperature and at elevated temperatures. Just like the fatigue properties, the creep resistance of this previously known alloy is unsatisfactory. All of the strength parameters examined have very good properties and can only be determined in the alloy according to the invention.
  • alloy E alloy according to the invention
  • AA 2214 and AA 2618 previously known alloys
  • the hot-forming step is carried out at a block temperature between 320 ° C and 460 ° C.
  • the step of quenching the solution-annealed semifinished product can take place in a temperature range between room temperature and 100 ° C. (boiling) in water. It is also possible to use a water-glycol mixture for quenching, but the temperature of which should not exceed 50 ° C.
  • thermosetting can be carried out over a period of 5 to 35 hours, preferably between 10 and 25 hours, in a temperature window between 170 ° C. and 210 ° C.
  • continuous cast ingots were produced as described above and aircraft wheels were die-forged in the fore and finished dies at a temperature of 410 to 430 ° C. These wheels were then solution annealed at 505 ° C, quenched in a water-glycol mixture at room temperature and aged for 20 hours at 170 ° C.
  • Fatigue tests on comparable samples of the two alloys mentioned also show that the wheels made from the claimed alloy achieve significantly better values than those made from the wheels made with the AA 2214 alloy. This applies to fatigue tests carried out at room temperature (cf. FIG. 4a) and to fatigue tests which were carried out at a test temperature of 200 ° C. (cf. FIG. 4b).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Forging (AREA)
  • Conductive Materials (AREA)
  • Powder Metallurgy (AREA)

Abstract

La présente invention concerne un alliage Al-Cu-Mg-Mn utilisé pour la réalisation de produits semi-finis à propriétés de rigidité statique et dynamique élevées, ledit alliage ayant la composition suivante: 0,3 - 0,7 % en poids de silicium (Si); max. 0,15 % en poids de fer (Fe); 3,5 - 4,5 % en poids de cuivre (Cu); 0,1 - 0,5 % en poids de manganèse (Mn); 0,3 - 0,8 % en poids de magnésium (Mg); 0,05 - 0,15 % en poids de titane (Ti); 0,1 - 0,25 % en poids de zircon (Zr); 0,3 - 0,7 % en poids d'argent (Ag); max. 0,05 % en poids d'autres éléments pris individuellement; max. 0,15 % en poids d'autres éléments pris globalement; les % en poids restants étant de l'aluminium (Al). L'invention a également pour objet un produit semi-fini réalisé à partir de cet alliage et un procédé de réalisation d'un produit semi-fini à partir de cet alliage.
EP02751094A 2002-06-29 2002-06-29 Alliage al-cu-mg-ag avec si, produit semi-fini realise a partir de cet alliage, et procede de realisation d'un produit semi-fini de ce type Expired - Lifetime EP1518000B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2002/007193 WO2004003244A1 (fr) 2002-06-29 2002-06-29 Alliage al-cu-mg-ag avec si, produit semi-fini realise a partir de cet alliage, et procede de realisation d'un produit semi-fini de ce type

Publications (2)

Publication Number Publication Date
EP1518000A1 true EP1518000A1 (fr) 2005-03-30
EP1518000B1 EP1518000B1 (fr) 2005-08-31

Family

ID=29797107

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02751094A Expired - Lifetime EP1518000B1 (fr) 2002-06-29 2002-06-29 Alliage al-cu-mg-ag avec si, produit semi-fini realise a partir de cet alliage, et procede de realisation d'un produit semi-fini de ce type

Country Status (6)

Country Link
US (1) US7214279B2 (fr)
EP (1) EP1518000B1 (fr)
AT (1) ATE303457T1 (fr)
AU (1) AU2002368060A1 (fr)
DE (1) DE50204136D1 (fr)
WO (1) WO2004003244A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2559779A1 (fr) * 2011-08-17 2013-02-20 Otto Fuchs KG Alliage d'Al-Cu-Mg-Ag résistant à la chaleur et procédé de fabrication d'un demi-produit ou d'un produit à partir d'un tel alliage d'aluminium

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7547366B2 (en) * 2004-07-15 2009-06-16 Alcoa Inc. 2000 Series alloys with enhanced damage tolerance performance for aerospace applications
US7449073B2 (en) * 2004-07-15 2008-11-11 Alcoa Inc. 2000 Series alloys with enhanced damage tolerance performance for aerospace applications
US8083871B2 (en) 2005-10-28 2011-12-27 Automotive Casting Technology, Inc. High crashworthiness Al-Si-Mg alloy and methods for producing automotive casting
CN101438063A (zh) * 2006-04-29 2009-05-20 欧瑞康莱宝真空公司 制备涡轮分子泵转子或定子的方法
RU2461643C1 (ru) * 2011-06-20 2012-09-20 Открытое акционерное общество "Раменское приборостроительное конструкторское бюро" (ОАО "РПКБ") Способ термической стабилизации размеров деталей прецизионных приборов из закаленного алюминиевого сплава д20
US20150284826A1 (en) * 2011-09-12 2015-10-08 Alex Cho High strength al-cu-mg-ag-si alloy for structural applications
DE102013219043A1 (de) 2013-09-23 2015-03-26 Oerlikon Leybold Vacuum Gmbh Legierungen von Rotoren einer Turbomolekularpumpe
DE102013219050B3 (de) * 2013-09-23 2015-01-22 Oerlikon Leybold Vacuum Gmbh Hochleistungsrotoren einer Turbomolekularpumpe
ES2596512T3 (es) 2014-04-03 2017-01-10 Otto Fuchs Kg Aleación de bronce de aluminio, procedimiento de producción y producto de bronce de aluminio
US20150322556A1 (en) 2014-05-06 2015-11-12 Goodrich Corporation Lithium free elevated temperature aluminum copper magnesium silver alloy for forged aerospace products
DE102014106933A1 (de) 2014-05-16 2015-11-19 Otto Fuchs Kg Sondermessinglegierung und Legierungsprodukt
CN103981410B (zh) * 2014-05-27 2016-07-27 中南大学 一种高耐损伤铝合金及其制备方法
US9786440B2 (en) 2014-12-17 2017-10-10 Avx Corporation Anode for use in a high voltage electrolytic capacitor
DE202016102696U1 (de) 2016-05-20 2017-08-29 Otto Fuchs - Kommanditgesellschaft - Sondermessinglegierung sowie Sondermessinglegierungsprodukt
DE202016102693U1 (de) 2016-05-20 2017-08-29 Otto Fuchs - Kommanditgesellschaft - Sondermessinglegierung sowie Sondermessinglegierungsprodukt
CN108103373B (zh) * 2017-12-28 2019-11-19 中南大学 一种含银Al-Cu-Mg合金及获得高强度P织构的热处理方法
CN109898000B (zh) * 2019-03-29 2020-12-15 郑州轻研合金科技有限公司 一种超高强耐热铝合金及其制备方法
US11009074B1 (en) * 2019-11-11 2021-05-18 Aktiebolaget Skf Lightweight bearing cage for turbine engines and method of forming a lightweight bearing cage
JP7469072B2 (ja) * 2020-02-28 2024-04-16 株式会社神戸製鋼所 アルミニウム合金鍛造材及びその製造方法
CN114855039B (zh) * 2021-02-03 2023-06-23 中国石油化工股份有限公司 一种Al-Cu-Mg-Ag合金及其制备方法和应用

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3475166A (en) * 1969-01-15 1969-10-28 Electronic Specialty Co Aluminum base alloy
GB1320271A (en) 1971-01-29 1973-06-13 Atomic Energy Authority Uk Aluminium alloys
JPH03107440A (ja) 1989-09-20 1991-05-07 Showa Alum Corp ロードセル用アルミニウム合金

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
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See references of WO2004003244A1 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2559779A1 (fr) * 2011-08-17 2013-02-20 Otto Fuchs KG Alliage d'Al-Cu-Mg-Ag résistant à la chaleur et procédé de fabrication d'un demi-produit ou d'un produit à partir d'un tel alliage d'aluminium
US10240228B2 (en) 2011-08-17 2019-03-26 Otto Fuchs Kg Heat-resistant Al—Cu—Mg—Ag alloy and process for producing a semifinished part or product composed of such an aluminum alloy

Also Published As

Publication number Publication date
US20050115645A1 (en) 2005-06-02
DE50204136D1 (de) 2005-10-06
US7214279B2 (en) 2007-05-08
WO2004003244A1 (fr) 2004-01-08
EP1518000B1 (fr) 2005-08-31
ATE303457T1 (de) 2005-09-15
AU2002368060A1 (en) 2004-01-19

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