EP1491818B1 - Brûleur à combustion catalytique en matière poreuse et flacon équipé d'un tel brûleur - Google Patents
Brûleur à combustion catalytique en matière poreuse et flacon équipé d'un tel brûleur Download PDFInfo
- Publication number
- EP1491818B1 EP1491818B1 EP04291475A EP04291475A EP1491818B1 EP 1491818 B1 EP1491818 B1 EP 1491818B1 EP 04291475 A EP04291475 A EP 04291475A EP 04291475 A EP04291475 A EP 04291475A EP 1491818 B1 EP1491818 B1 EP 1491818B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- burner
- zone
- catalyst
- catalytic combustion
- peripheral surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007084 catalytic combustion reaction Methods 0.000 title claims abstract description 24
- 239000011148 porous material Substances 0.000 title claims description 14
- 230000002093 peripheral effect Effects 0.000 claims abstract description 47
- 239000003054 catalyst Substances 0.000 claims abstract description 22
- 230000008016 vaporization Effects 0.000 claims abstract description 6
- 238000009834 vaporization Methods 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 4
- 238000007598 dipping method Methods 0.000 claims description 3
- 239000003570 air Substances 0.000 description 9
- 239000000446 fuel Substances 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 229910052878 cordierite Inorganic materials 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000506680 Haemulon melanurum Species 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D3/00—Burners using capillary action
- F23D3/02—Wick burners
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2900/00—Special features of, or arrangements for burners using fluid fuels or solid fuels suspended in a carrier gas
- F23D2900/03081—Catalytic wick burners
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2900/00—Special features of, or arrangements for burners using fluid fuels or solid fuels suspended in a carrier gas
- F23D2900/31002—Wick burners with flame spreaders or burner hood
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2900/00—Special features of, or arrangements for burners using fluid fuels or solid fuels suspended in a carrier gas
- F23D2900/31004—Wick burners using alcohol as a fuel
Definitions
- the present invention relates to a catalytic combustion burner made of porous material adapted to cooperate with a wick intended to supply the burner with a combustible composition which penetrates into the pores of said porous material, said burner comprising a peripheral zone which supports a catalyst and which surrounds a central zone without catalyst forming vaporization zone, the peripheral zone and the central zone being located in the upper part of the burner.
- Such catalytic combustion burners in particular described in application WO 99/63267, conventionally have a substantially cylindrical peripheral surface.
- the object of the present invention is therefore to overcome the aforementioned drawback of known burners and to provide a burner of the aforementioned type whose demolding is facilitated and which also has improved functional characteristics.
- this catalytic combustion burner has a frustoconical peripheral surface which flares upwards.
- the frustoconical structure allows easier removal of the burner without damaging the peripheral surface of the burner.
- the frustoconical burner of the invention has a peripheral surface exchange greater dimension than that of a burner of the prior art having a peripheral surface of substantially cylindrical shape.
- the heat exchange is greater during the implementation of a burner according to the invention, the air located near the burner, more heated, rises faster and consequently generates convection currents. more dynamic.
- the half-angle at the top of the frustoconical peripheral surface of the burner is between 10 ° and 40 °, advantageously between 15 ° and 25 °, and preferably between 18 ° and 23 °.
- the frustoconical peripheral surface of the burner has at least a first substantially peripheral shoulder and directed inwards and downwards to increase the diameter between a lower portion and an upper portion of the burner.
- Such a structure makes it possible to further increase the exchange surface between the hot air and the burner and reinforces the contact between the rising hot air and at least a part of the peripheral surface of the burner, and therefore the thermal and chemical exchanges. .
- a second aspect of the invention also relates to a catalytic combustion flask adapted to contain a liquid fuel composition and to receive, at its neck, a catalytic combustion burner adapted to cooperate with a wick dipping in said composition.
- this bottle is equipped with a burner according to the first aspect of the invention.
- FIGS. 1 to 5 are identified by identical reference numerals.
- FIG. 1 shows a catalytic combustion flask 1 adapted to contain a liquid fuel composition 2 and to receive, at its upper part, a catalytic combustion burner 3 according to the invention.
- This bottle 1 can be of any shape and has a neck 4 adapted to receive the catalytic burner 3.
- the catalytic combustion burner 3 is made of a suitable porous material and adapted to withstand the temperatures of at least 400 ° C reached in the zone carrying the catalyst during the operation of the burner 3.
- This material may in particular be a ceramic material, and for example prepared from kaolin or cordierite.
- the catalytic combustion burner 3 is adapted to cooperate with a wick 5 dipping in said composition 2. This wick 5 is intended to bring to the burner 3 the fuel composition 2 which penetrates into the pores of the porous material.
- the fuel composition 2 is a suitable fuel liquid, in accordance with the regulations in force and adapted to catalytic combustion and vaporization.
- This combustible composition 2 may in particular be an alcohol, in particular isopropyl alcohol, and may further comprise a scented material and / or an active material.
- the wick 5 is any known wick, for example a cotton wick.
- the wick 5 may also be a wick of mineral material, for example a wick of mineral fibers, or a wick of porous material.
- the catalytic combustion burner 3 may be provided at its lower part with a support (not shown) for its introduction, either directly into the neck 4 of the bottle 1, or into the central hole of a base (not shown). , the latter being adapted to be fixed at the neck 4 of the bottle 1.
- the catalytic burner 3 has a solid structure and a frustoconical peripheral surface 3a which flares upwards.
- This burner 3 comprises, at its upper part 3b, a peripheral zone 6, for example of annular shape, which supports a catalyst 7 and which surrounds a central zone 8 without catalyst forming vaporization zone.
- the catalyst 7 is for example a metal belonging to group VIII of the periodic table of the elements.
- the half-angle A at the top of the frustoconical peripheral surface 3a of the burner 3 is between 10 ° and 40 °, advantageously between 15 ° and 25 °, and preferably between 18 ° and 23 °.
- the catalytic combustion burner 3 of FIG. 2 may be combined with a sleeve 9 so as to form a catalytic combustion system, such as the catalytic combustion system 10 shown in FIG.
- This sleeve 9 is disposed in the extension of the lower part 3c of the burner 3.
- This sleeve 9 is also made of a porous material, which may in particular be a ceramic material, for example prepared from kaolin or cordierite.
- This sleeve 9 comprises a substantially axial cavity 11 adapted to grip the wick 5 in such a way that the fuel composition 2 can migrate from the pores of the upper part 9a of the sleeve 9 to the pores of the lower part 3c of the burner 3.
- the junction between the lower parts 3c of the burner 3 and upper 9a of the sleeve 9 must be such that the migration of the fuel composition 2 of the sleeve 9 to the burner 3 is ensured. It is thus possible to provide mechanical interlocking and / or assembly by means of a porous seal.
- FIG. 4 shows two half-views of a catalytic combustion burner 13 according to a second embodiment of the invention.
- This burner 13 has a peripheral surface 13a of frustoconical shape which flares upwards.
- This peripheral surface 13a has at least a first shoulder 14a, 14b substantially peripheral and directed inwardly and downwardly of said burner 13.
- This first shoulder 14a, 14b has the effect of increasing the diameter between a lower portion 13c and an upper portion 13b of the burner 13.
- the first shoulder 14a is formed in the substantially middle portion of the burner 13.
- the first shoulder 14b is formed in the lower part 13c of the burner 13.
- the first shoulder can obviously be located at a height different from those shown on the two half-views of Figure 4.
- the deposition of the catalyst was made up to the first shoulder 14a, which thus separates the peripheral zone 16 supporting the catalyst 7 from the lower part 13c the catalyst-free burner 13 at the peripheral surface 13a of the burner 13.
- the first shoulder 14b does not correspond to a demarcation zone for the location of the catalyst 7 at the peripheral surface 13a of the burner 13.
- This first shoulder 14b is located in a part of the burner 13 which has no catalyst.
- the burner 13 comprises, at least at its lower part 13c, a cavity 15 substantially axial, open downwards, adapted to receive, over all or part of its height, the upper end 5a of the wick 5 intended to bring at the burner 13 the combustible composition 2.
- the end 5a of the wick 5 only partially fills the volume of the cavity 15 of the burner 13. However, it is quite possible to provide that this end 5a substantially completely fills said cavity 15, as in the case of the burner 23 shown in FIG.
- the cavity 15, which opens at the lower end 3d of the burner 13, extends axially over a large part of the axial dimension of the burner 13.
- This cavity 15 is closed, at the top 13b of the burner 13, by a wall 17.
- the burner 13 has a substantially axial annular groove 19 extending from the upper surface 13e of the burner 13 downwards and separating the substantially annular peripheral zone 16 which supports the catalyst 7, of the central zone 18 of the upper part 13b of the burner 13.
- this catalytic combustion burner 23 has a frustoconical peripheral surface 23a which flares upwards.
- the upper part 23b of the burner 23 comprises an annular peripheral zone 26 supporting the catalyst 7 and surrounding a central zone 28 without catalyst, as well as a cavity 25.
- the upper part 25a of the cavity 25 communicates with the atmosphere by the presence of at least one open channel 29 formed, for example, in the upper part 23b of the burner 23.
- the channel 29 is located in the center of the central zone 28 and formed substantially axially.
- This channel 29 has a cross section narrower than the cross section of the cavity 25 of the burner 23, so that the cavity 25 is closed at least partially, at the top 23b of the burner 23, by a wall 27 located in the central area 28.
- the peripheral surface 23a has a first substantially peripheral shoulder 24 and a second substantially peripheral shoulder 30.
- Each shoulder 24, 30 separates a portion of the burner 23, which is immediately larger and has a larger diameter, of another part of the burner 23, which is immediately below it and which is smaller in diameter.
- this first shoulder 24 separates, at the level of the peripheral surface 23a of the burner 23, the annular peripheral zone 26 supporting the catalyst 7 of the lower part 23c of the burner 23 without catalyst 7.
- Such a structural arrangement makes it possible to precisely determine the area of the burner 23 on which the catalyst 7 must be deposited.
- the burners 13 and 23 shown in FIGS. 4 and 5 may be provided with a sleeve such as the sleeve 9 shown in FIG.
- annular groove such as the annular groove 19 of FIG. 2, to separate the annular peripheral zones 6 and 26 from the central zones 8 and 28 of the burners 3 and 23, represented respectively in FIGS. part, and 5 on the other hand.
- the upper part of the cavity 15 of the burner 13 of FIG. 4 is connected to the atmosphere by a channel, such as that represented in FIG. 5 and having the reference 29.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wick-Type Burners And Burners With Porous Materials (AREA)
- Spray-Type Burners (AREA)
- Catalysts (AREA)
- Gas Burners (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0307765 | 2003-06-27 | ||
FR0307765A FR2856775B1 (fr) | 2003-06-27 | 2003-06-27 | Bruleur a combustion catalytique en matiere poreuse et flacon equipe d'un tel bruleur |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1491818A1 EP1491818A1 (fr) | 2004-12-29 |
EP1491818B1 true EP1491818B1 (fr) | 2006-08-23 |
Family
ID=31985454
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04291475A Expired - Lifetime EP1491818B1 (fr) | 2003-06-27 | 2004-06-11 | Brûleur à combustion catalytique en matière poreuse et flacon équipé d'un tel brûleur |
Country Status (15)
Country | Link |
---|---|
US (1) | US7241136B2 (es) |
EP (1) | EP1491818B1 (es) |
JP (1) | JP3814601B2 (es) |
KR (1) | KR100717614B1 (es) |
CN (1) | CN1271368C (es) |
AT (1) | ATE337522T1 (es) |
CA (1) | CA2470072C (es) |
DE (2) | DE602004002037T2 (es) |
ES (1) | ES2238209T3 (es) |
FR (1) | FR2856775B1 (es) |
HK (2) | HK1056485A2 (es) |
MY (1) | MY136766A (es) |
PT (1) | PT1491818E (es) |
SG (1) | SG126733A1 (es) |
TW (1) | TWI232918B (es) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2856775B1 (fr) | 2003-06-27 | 2005-08-19 | Prod Berger | Bruleur a combustion catalytique en matiere poreuse et flacon equipe d'un tel bruleur |
KR100727624B1 (ko) * | 2005-06-14 | 2007-06-13 | 주식회사 아이파워 | 비연소 및 무소음 방식의 촉매히터 |
US20070202450A1 (en) * | 2006-02-08 | 2007-08-30 | The Board Of Regents, The University Of Texas System | Catalytic burner for combustion of liquid fuels |
FR2905164B1 (fr) * | 2006-08-23 | 2012-12-21 | Prod Berger | Composition a base de carbure de silicium pour bruleur a combustion catalytique en matiere poreuse. |
FR2905163B1 (fr) * | 2006-08-23 | 2008-10-17 | Prod Berger Soc Par Actions Si | Bruleur a combustion catalytique, dispositif de support pour bruleur, et ensemble bruleur-dispositif de bruleur avec events. |
FR2905165B1 (fr) * | 2006-08-23 | 2008-10-10 | Prod Berger Soc Par Actions Si | Bruleur a combustion catalytique presentant un embout particulier et flacon equipe d'un tel bruleur. |
US10041669B2 (en) * | 2006-10-12 | 2018-08-07 | Stonewick, Llc | Catalytic burner |
CA2702099A1 (en) * | 2006-10-12 | 2008-04-17 | Stonewick, Inc. | Catalytic burner |
FR2950257B1 (fr) | 2009-09-22 | 2012-01-20 | Prod Berger | Ensemble pour la diffusion d'une composition dans l'air |
GB201321309D0 (en) * | 2013-12-03 | 2014-01-15 | Ashleigh & Burwood | A Catalytic fragrance burner assembly and a method of manufacture thereof |
PL2896407T3 (pl) * | 2014-01-15 | 2019-04-30 | Dc & Bv France Holding Sas | Urządzenie do rozpraszania substancji chemicznej |
US11877687B2 (en) | 2015-07-27 | 2024-01-23 | The United States Of America As Represented By The Secretary Of The Army | Heater and cookware for flameless catalytic combustion |
US10584869B2 (en) | 2015-07-27 | 2020-03-10 | The United States Of America As Represented By The Secretary Of The Army | Heater |
KR101953846B1 (ko) | 2016-09-30 | 2019-03-06 | 대한민국 | 농축액 플라스크 |
FR3061543B1 (fr) * | 2016-12-30 | 2019-08-23 | Produits Berger | Bruleur a combustion catalytique en materiau poreux a performances de fonctionnement optimisees et flacon equipe d'un tel bruleur |
JP1614249S (es) * | 2017-02-13 | 2018-09-25 | ||
FR3090420B1 (fr) * | 2018-12-21 | 2020-12-11 | Berger Produits | Procede de depot d’un catalyseur a la surface d’un bruleur a combustion catalytique |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1956749A (en) * | 1931-01-09 | 1934-05-01 | Terret Henri Georges | Catalytic heating device |
US2938343A (en) * | 1944-12-16 | 1960-05-31 | Robert H Canfield | Combustion flask for liquid oxidants and fuels |
US3240256A (en) * | 1963-11-19 | 1966-03-15 | Canadian Patents Dev | Catalytic heater |
JPS5784907A (en) | 1980-11-18 | 1982-05-27 | Matsushita Electric Ind Co Ltd | Combustor |
DE3436310A1 (de) * | 1984-10-03 | 1986-04-10 | Globol-Werk Gmbh, 8858 Neuburg | Verdampfervorrichtung fuer in feste traegermaterialien eingelagerte wirkstoffe, wie pyrethrum |
FR2579465B1 (fr) * | 1985-03-27 | 1987-09-11 | Berger Sa Produits | Dispositif pour la diffusion atmospherique de produits actifs en phase gazeuse |
FR2610390B1 (fr) * | 1987-01-29 | 1990-09-07 | Berger Sa Produits | Bruleur a combustion catalytique |
JPH03241212A (ja) * | 1990-02-19 | 1991-10-28 | Toshiba Corp | 触媒燃焼装置 |
FR2680118B1 (fr) * | 1991-08-09 | 1995-02-10 | Senteurs Parfums Cie | Procede pour diffuser par catalyse un liquide combustible melange a un produit parfume, assainissant, deodorant, insecticide, expectoriant ou autre et diffuseur catalytique mettant en óoeuvre ce procede. |
US6162046A (en) * | 1995-05-10 | 2000-12-19 | Allports Llc International | Liquid vaporization and pressurization apparatus and methods |
FR2779509B1 (fr) | 1998-06-04 | 2000-07-07 | Prod Berger | Bruleur a combustion catalytique en matiere poreuse et flacon equipe d'un tel bruleur |
FR2821749B1 (fr) * | 2001-03-08 | 2003-05-30 | 3E Degre Sa | Bruleur-diffuseur catalytique pour diffuseur de parfum |
TW513531B (en) | 2001-07-23 | 2002-12-11 | Yi-Cheng Liou | Method for producing burning head of aroma essential oil and product thereof |
FR2856775B1 (fr) | 2003-06-27 | 2005-08-19 | Prod Berger | Bruleur a combustion catalytique en matiere poreuse et flacon equipe d'un tel bruleur |
-
2003
- 2003-06-27 FR FR0307765A patent/FR2856775B1/fr not_active Expired - Fee Related
- 2003-09-24 MY MYPI20033649A patent/MY136766A/en unknown
- 2003-09-26 TW TW092126703A patent/TWI232918B/zh not_active IP Right Cessation
- 2003-10-02 HK HK03107109A patent/HK1056485A2/xx not_active IP Right Cessation
- 2003-10-09 KR KR1020030070295A patent/KR100717614B1/ko not_active IP Right Cessation
- 2003-10-10 JP JP2003351985A patent/JP3814601B2/ja not_active Expired - Fee Related
- 2003-10-10 SG SG200305934A patent/SG126733A1/en unknown
- 2003-10-10 CN CNB2003101006558A patent/CN1271368C/zh not_active Expired - Fee Related
-
2004
- 2004-06-11 DE DE602004002037T patent/DE602004002037T2/de not_active Expired - Lifetime
- 2004-06-11 PT PT04291475T patent/PT1491818E/pt unknown
- 2004-06-11 ES ES04291475T patent/ES2238209T3/es not_active Expired - Lifetime
- 2004-06-11 EP EP04291475A patent/EP1491818B1/fr not_active Expired - Lifetime
- 2004-06-11 DE DE04291475T patent/DE04291475T1/de active Pending
- 2004-06-11 AT AT04291475T patent/ATE337522T1/de active
- 2004-06-15 CA CA002470072A patent/CA2470072C/fr not_active Expired - Fee Related
- 2004-06-24 US US10/876,203 patent/US7241136B2/en not_active Expired - Lifetime
-
2005
- 2005-06-08 HK HK05104810A patent/HK1072098A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1271368C (zh) | 2006-08-23 |
CN1576693A (zh) | 2005-02-09 |
HK1072098A1 (en) | 2005-08-12 |
ATE337522T1 (de) | 2006-09-15 |
DE04291475T1 (de) | 2005-06-23 |
FR2856775B1 (fr) | 2005-08-19 |
US7241136B2 (en) | 2007-07-10 |
ES2238209T1 (es) | 2005-09-01 |
EP1491818A1 (fr) | 2004-12-29 |
KR100717614B1 (ko) | 2007-05-15 |
JP2005016925A (ja) | 2005-01-20 |
FR2856775A1 (fr) | 2004-12-31 |
DE602004002037D1 (de) | 2006-10-05 |
HK1056485A2 (en) | 2004-01-30 |
DE602004002037T2 (de) | 2007-02-15 |
JP3814601B2 (ja) | 2006-08-30 |
US20050037309A1 (en) | 2005-02-17 |
PT1491818E (pt) | 2006-12-29 |
CA2470072C (fr) | 2008-08-19 |
KR20050005706A (ko) | 2005-01-14 |
CA2470072A1 (fr) | 2004-12-27 |
TW200500572A (en) | 2005-01-01 |
MY136766A (en) | 2008-11-28 |
ES2238209T3 (es) | 2007-04-16 |
TWI232918B (en) | 2005-05-21 |
SG126733A1 (en) | 2006-11-29 |
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