EP1478234A1 - Synergistische insektizide mischungen - Google Patents

Synergistische insektizide mischungen

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Publication number
EP1478234A1
EP1478234A1 EP03704580A EP03704580A EP1478234A1 EP 1478234 A1 EP1478234 A1 EP 1478234A1 EP 03704580 A EP03704580 A EP 03704580A EP 03704580 A EP03704580 A EP 03704580A EP 1478234 A1 EP1478234 A1 EP 1478234A1
Authority
EP
European Patent Office
Prior art keywords
spp
active
active ingredients
methyl
emamectin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03704580A
Other languages
German (de)
English (en)
French (fr)
Inventor
Wolfram Andersch
Christoph Erdelen
Peter Jeschke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience AG
Original Assignee
Bayer CropScience AG
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Filing date
Publication date
Application filed by Bayer CropScience AG filed Critical Bayer CropScience AG
Publication of EP1478234A1 publication Critical patent/EP1478234A1/de
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings

Definitions

  • the present invention relates to new active ingredient combinations which contain the known active ingredient thiacloprid on the one hand and at least one other known insecticidal active ingredient on the other hand and have very good insecticidal and acaricidal properties.
  • insects cf. EP-A-0 235 725.
  • the effectiveness of this compound is good, but leaves at low application rates or against individual pests in some
  • abamectin (II) (DE 2 717 040) and emamectin (III) or emamectin-benzoate (purple) (EP 089 202) can be used to control insects and / or acarines.
  • the compounds (II), (III) and (lilac) are synergistically active and are suitable for controlling animal pests. Because of this synergism, significantly smaller amounts of active ingredient can be used, ie the effect of the mixture is greater than the effect of the individual components.
  • the ratio of the compound of formula (I) used to the compounds of formula (II), (III) or (purple) and the total amount of the mixture to be used depends on the type and the occurrence of the insects or acarines. The optimal ratios and total amounts used can be determined for each application using test series.
  • a preferred mixture according to the invention contains the active ingredient thiacloprid of the formula (I) and abamectin (II).
  • Abamectin is also known from "The Pesticide Manual, 11 * Edition, British Crop Protection Council, 1997, page 3. The terms abamectin and avermectin are used synonymously in the present patent application.
  • the ratio of the active ingredients to one another can be varied within a substantial range.
  • the weight ratio of thiacloprid to abamectin is preferably between 1: 1 and 500: 1, in particular between 5: 1 and 25: 1.
  • Another preferred mixture according to the invention contains the active ingredient thiacloprid of the formula (I) and emamectin (III) or emamectin benzoate (purple).
  • Emamectin or salts of emamectin are also known as MK-244 from Journal of Organic Chemistry, Vol. 59 (1994), 7704-7708, US-P-4,4874,794, US-P-5,5,288,710 and EP- 00 089 202.
  • the ratio of the active ingredients to one another can be varied within a substantial range.
  • the weight ratio of thiacloprid to emamectin or emamectin benzoate is preferably between 1: 1 and 500: 1, in particular between 100: 1 and 500: 1.
  • the active substance combinations are suitable for good plant tolerance and favorable warm-blood toxicity for combating animal pests, in particular insects, arachnids and nematodes, which occur in agriculture, in forests, in the protection of stocks and materials and in the hygiene sector. They can preferably be used as pesticides. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the pests mentioned above include:
  • Thysanura e.g. Lepisma saccharina.
  • Orthoptera e.g. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
  • Thysanoptera e.g. Hercinothrips femoralis, Thrips tabaci
  • Anthrenus spp. Attagenus spp., Lyctus spp., Meligethes aeneus, " Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolonthica, Amphimallelystit , Lissorhoptrus oryzophilus.
  • Hymenoptera e.g. Diprion spp., Hoplocampa spp., Lasius spp.
  • Plant-parasitic nematodes include, for example, Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.
  • plants and parts of plants can be treated.
  • Plants are understood here to mean all plants and plant populations, such as desired and unwanted wild plants or crop plants (including naturally occurring crop plants).
  • Cultivated plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by plant breeders' rights.
  • Plant parts are to be understood to mean all above-ground and underground parts and organs of plants, such as shoots, leaves, flowers and roots, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds as well as roots, tubers and rhizomes.
  • Plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.
  • Habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, vaporizing, atomizing, scattering, spreading and, in the case of propagation material, in particular seeds, furthermore by single- or multi-layer coating.
  • the active substance combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension emulsion concentrates, active substance-impregnated natural and synthetic substances and very fine encapsulations in polymeric substances.
  • These formulations are prepared in a known manner, for example by mixing the active ingredients with extenders, that is to say liquid solvents and / or solids
  • Carriers if appropriate using surface-active agents, ie emulsifiers and / or dispersants and or foam-generating agents.
  • organic solvents can also be used as auxiliary solvents.
  • auxiliary solvents e.g. organic solvents.
  • aromatics such as xylene, toluene, or alkylnaphthalenes
  • chlorinated aromatics and chlorinated ahphatic hydrocarbons such as
  • Chlorobenzenes chlorethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • aliphatic hydrocarbons such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • Possible solid carriers are: e.g. Ammonium salts and natural rock flours, such as kaolins, clays,
  • Talc chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic stone powder, such as highly disperse silica, aluminum oxide and
  • Silicates as solid carriers for granules are possible: e.g. broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite as well as synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stems ;
  • suitable emulsifiers and / or foam-generating agents are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates;
  • Possible dispersing agents are, for example, lignin sulfite waste liquor and methyl cellulose.
  • Adhesives such as carboxymethyl cellulose, natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids, such as cephalins and lecithins and synthetic phospholipids, can be used in the formulations.
  • Other additives can be mineral and vegetable oils.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
  • the formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.
  • the active ingredient combinations according to the invention can be obtained in commercially available
  • Formulations and in the use forms prepared from these formulations are present in a mixture with other active compounds, such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides.
  • active compounds such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides.
  • Insecticides include, for example, phosphoric acid esters, carbamates, carboxylic acid esters, chlorinated hydrocarbons, phenylureas, substances produced by microorganisms, etc.
  • Aldirnorph ampropylfos, ampropylfos potassium, andoprim, anilazine, azaconazole, azoxystrobin,
  • Debacarb dichlorophene, diclobutrazole, diclofluanide, diclomezin, dicloran, diethofencarb, difenoconazole, dimethirimol, dimethomorph, diniconazole, diniconazol-M, dinocap, diphenylamine, dipyrithione, ditalimfos, dithorphoxinodonine, dithorphononine
  • Imazalil Imibenconazol, Iminoctadin, Iminoctadinealbesilat, Iminoctadinetriacetat, Iodocarb, Ipconazol, Iprobefos (IBP), Iprodione, Irumamycin, Isoprothiolan,
  • Kasugamycin, Kresoxim-methyl, copper preparations such as: copper hydroxide, copper phthalate, copper oxychloride, copper sulfate, copper oxide, oxy-copper and Bordeaux mixture, Mancopper, Mancozeb, Maneb, Meferimzone, Mepanipyrim, Mepronil, Metalaxyl, Metconazol, Methasulfocarb, Methfuroxam, Metiram, Metomeclam, Metsulfovax, Mildiomycin, Myclobutanil, Myclozolin,
  • Oxadixyl Oxamocarb, Oxolinicacid, Oxycarboxim, Oxyfenthiin,
  • Paclobutrazole pefurazoate, penconazole, pencycuron, phosdiphen, pimaricin, piperahn, polyoxin, polyoxorim, probenazole, prochloraz, procymidon, propamocarb,
  • Tebuconazole Tebuconazole, tecloftalam, tecnazen, tetcyclacis, tetraconazole, thiabendazole, thicyofen, thifluzamide, thiophanate-methyl, thiram, dioxymid, tolclofos-methyl, tolylfluanid, triadimefon, triadimenol, triazbutichl, triazoxid, triazoxid, triazoxide, triazoxide
  • Tridemorph triflumizole, triforin, triticonazole
  • Methantetrathiol sodium salt Methyl 1 - (2,3-dihydro-2,2-dimethyl-1 H-inden-1-yl) - 1 H-imidazole-5-carboxylate,
  • Cadusafos Carbaryl, Carbofuran, Carbophenothion, Carbosulfan, Cartap, Chloethocarb, Chlorethoxyfos, Chlorfenapyr, Chlorfenvinphos, Chlorfluazuron, Chlorrnephos, Chlorpyrifos, Chlorpyrifos M, Chlovaporthrin, Cis-Resmethrin, Clocethyrythrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cispermethrin, Cisper
  • Disulfoton Disulfoton, Docusat-sodium, Dofenapyn, Efiusilanate, Emamectin, Empenthrin, Endosulfan, Entomophthora spp., Esfenvalerate, Ethiofencarb, Ethion, Ethiprole, Ethoprophos, Etofenprox, Etoxazole, Etrimfos,
  • Fenamiphos Fenazaquin, Fenbutatin oxide, Fenitrothion, Fenothiocarb, Fenoxacrim, Fenoxycarb, Fenpropathrin, Fenpyrad, Fenpyrithrin, Fenpyroximate, Fenvalerate, Fipronil, Fluazinam, Fluazuron, Flubrocythrinate, Flucycloxoxinon, Fluutinoxuron, Fluutinoxuron, Fluutinoxuron, Fluutinoxinone, , Furathiocarb,
  • Halofenozide HCH, Heptenophos, Hexaflumuron, Hexythiazox, Hydroprene,
  • Paecilomyces flimosoroseus Parathion A, Parathion M, Permethrin, Phenthoat,
  • Triazamate Triazophos, triazuron, trichlophenidines, trichlorfon, triflumuron, trimethacarb,
  • the active compound combinations according to the invention can furthermore be present in their commercially available formulations and in the use forms prepared from these formulations in a mixture with synergists.
  • Synergists are compounds that increase the effectiveness of the active ingredients without the added synergist itself having to be active.
  • the active substance content of the use forms prepared from the commercially available formulations can vary within wide ranges.
  • Application forms can be from 0.0000001 to 95% by weight of active compound, preferably between 0.0001 and 1% by weight.
  • the application takes place in a customary manner adapted to the application forms.
  • the active substance combinations are notable for an excellent residual action on wood and clay and for good stability to alkali on limed substrates. '
  • the active compound combinations according to the invention act not only against plant, hygiene and stored product pests, but also in the veterinary sector against animal parasites (ectoparasites) such as tick ticks, leather ticks, mites, running mites, flies (stinging and licking), parasitic fly larvae, lice, hair lice, Featherlings and fleas.
  • animal parasites ectoparasites
  • tick ticks leather ticks
  • mites running mites
  • flies stinging and licking
  • parasitic fly larvae lice, hair lice, Featherlings and fleas.
  • Anoplurida e.g. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.
  • Nematocerina and Brachycerina e.g. Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp.,
  • Hybomitra spp. Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp.,.
  • Hydrotaea spp. Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.
  • Siphonaptrida e.g. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
  • Panstrongylus spp From the order of the Blattarida, for example Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.
  • Actinedida Prostigmata
  • Acaridida e.g. Acarapis spp., Cheyletiella spp., Ornitrocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypppectoles spp ., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.
  • the active substance combinations according to the invention are also suitable for combating arthropods which are used in agricultural animals, e.g. Cattle, sheep, goats, horses, pigs, donkeys, camels, buffalo, rabbits, chickens, turkeys, ducks, geese,
  • the active compound combinations according to the invention are used in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, capsules, drinkers, drenches, granules, pastes, boluses, etc. Feed-through procedure, from suppositories, by parenteral administration of ner, such as by injections (intramuscular, subcutaneous, intravenous, intraperitonel, etc.), implants, by nasal application, by dermal application in the form of, for example, diving or bathing (dipping), spraying (Spray), pouring on (pour-on and spot-on), washing, powdering and with the help of shaped articles containing active ingredients, such as necklaces, ear tags, tail tags, limb straps, holsters, marking devices, etc.
  • enteral administration in the form of, for example, tablets, capsules, drinkers, drenches, granules, pastes, boluses, etc.
  • Feed-through procedure from suppositories
  • the active ingredients can be used as formulations (for example powders, emulsions, flowable agents) which
  • Contain active ingredients in an amount of 1 to 80% by weight apply directly or after 100 to 10,000-fold dilution or use them as a chemical bath.
  • Dermatologists such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur. Termites like
  • Kalotermes flavicollis Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.
  • Bristle tails such as Lepisma saccharina.
  • non-living materials such as preferably plastics, adhesives, glues, papers and cartons, leather, wood, wood processing products and paints.
  • the material to be protected against insect infestation is very particularly preferably wood and wood processing products.
  • Wood and wood processing products which can be protected by the agent according to the invention or mixtures containing it are to be understood as examples:
  • the active ingredient combinations can be used as such, in the form of concentrates or generally customary formulations such as powders, granules, solutions, suspensions, emulsions or pastes.
  • the formulations mentioned can be prepared in a manner known per se, for example by mixing the active ingredients with at least one solvent or diluent, emulsifier, dispersant and / or binder or fixative, water repellants, optionally siccatives and UV stabilizers and, if appropriate Dyes and pigments as well as other processing aids.
  • the msecticidal agents or concentrates used to protect wood and wood-based materials contain the active ingredient according to the invention in a concentration of 0.0001 to 95% by weight, in particular 0.001 to 60% by weight.
  • the amount of the agents or concentrates used depends on the type and occurrence of the insects and on the medium. The optimal amount can be determined in each case by test series. In general, however, it is sufficient to use 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active compound, based on the material to be protected.
  • Water and optionally an emulsifier and / or wetting agent optionally an emulsifier and / or wetting agent.
  • the organic chemical solvents used are preferably oily or oily solvents with an evaporation number above 35 and a flash point above 30 ° C., preferably above 45 ° C.
  • Corresponding mineral oils or their aromatic fractions or mineral oil-containing solvent mixtures, preferably white spirit, petroleum and / or alkylbenzene, are used as such low-volatility, water-insoluble, oily and oily solvents.
  • Mineral oils with a boiling range of 170 to 220 ° C, white spirit with a boiling range of 170 to 220 ° C, spindle oil with a boiling range of 250 to 350 ° C, petroleum or aromatics with a boiling range of 160 to 280 ° C, Te ⁇ entinöl and Like. Used.
  • organic low-volatility oily or oily solvents with an evaporation number above 35 and a flash point above 30 ° C, preferably above 45 ° C can be partially replaced by slightly or medium-volatile organic chemical solvents, with the proviso that the solvent mixture also has an evaporation number 35 and a flash point above 30 ° C, preferably above 45 ° C, and that the insecticide-fungicide mixture is soluble or emulsifiable in this solvent mixture.
  • part of the organic chemical solvent or solvent mixture is replaced by an aliphatic polar organic chemical solvent or solvent mixture.
  • Ahphatic organic chemical solvents containing hydroxyl and / or ester and / or ether groups, such as, for example, glycol ethers, esters or the like, are preferably used.
  • the organic-chemical binders which are known are water-dilutable and / or synthetic resins which are soluble or dispersible or emulsifiable in the organic-chemical solvents used and / or binding drying oils, in particular binders consisting of or containing an acrylate resin, a vinyl resin, for example polyvinyl acetate ⁇ polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin such as indene-coumarone resin, silicone resin, drying vegetable and / or drying oils and or physically drying binders based on a natural and / or synthetic resin used.
  • binders consisting of or containing an acrylate resin, a vinyl resin, for example polyvinyl acetate ⁇ polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin such as indene-coumarone
  • the synthetic resin used as a binder can be used in the form of an emulsion, dispersion or solution. Bitumen or bituminous substances up to 10% by weight can also be used as binders. In addition, known dyes, pigments, water-repellants, odor correctors and inhibitors or anticorrosive agents and the like can be used.
  • At least one alkyd resin or modified alkyd resin and / or a drying vegetable oil is preferably contained in the agent or in the concentrate as the organic chemical binder.
  • Alkyd resins having an oil content of more than 45% by weight, preferably 50 to, are preferred according to the invention
  • binder mentioned can be replaced by a fixative (mixture) or a plasticizer (mixture). These additives are said to cause volatilization of the active ingredients and crystallization or precipitation! prevent. They preferably replace 0.01 to 30% of the binder (based on 100% of the binder used).
  • the plasticizers come from the chemical classes of phthalic acid esters such as dibutyl, dioctyl or. Benzyl butyl phthalate, phosphoric acid esters such as tributyl phosphate, adipic acid esters such as di- (2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, oleates such as butyl oleate, glycerol ether or higher molecular weight glycol ether, glycerol ester and p-toluenesulphonic acid ester.
  • phthalic acid esters such as dibutyl, dioctyl or.
  • Benzyl butyl phthalate phosphoric acid esters such as tributyl phosphate
  • adipic acid esters such as di- (2-ethylhexyl) adipate
  • stearates such as buty
  • Fixing agents are chemically based on polyvinyl alkyl ethers such as e.g. Polyvinyl methyl ether or ketones such as benzophenone, ethyl dibenzophenone.
  • Water is also particularly suitable as a solvent or diluent, if appropriate in a mixture with one or more of the above-mentioned organic chemical solvents or diluents, emulsifiers and dispersants.
  • a particularly effective wood protection is achieved by industrial impregnation processes, e.g. vacuum, double vacuum or pressure processes.
  • the ready-to-use compositions can optionally contain further insecticides and, if appropriate, one or more fungicides.
  • the active compound combinations according to the invention can be used to protect objects, in particular ship hulls, sieves, nets, structures, quay systems and signaling systems which come into contact with sea or brackish water.
  • barnacles such as various Lepas and Scalpellum species
  • Balanomo ⁇ ha (barnacles) such as Baianus or Pollicipes species
  • heavy metals such as in bis (trialkyltin) sulfides, tri-72-butyltin laurate, tri-n-butyltin chloride, copper (I) oxide, triethyltin chloride, tri-7?
  • the ready-to-use antifouling paints may also contain other active ingredients, preferably algicides, fungicides, herbicides, molluscicides or other antifouling active ingredients.
  • Suitable combination partners for the antifouling agents according to the invention are preferably:
  • Molluscicides such as Fe complexing agents
  • Fentin acetate, metaldehyde, methiocarb, niclosamide, thiodicarb and trimethacarb; or conventional antifouling agents such as
  • the antifouling agents used contain the active ingredient in a concentration of 0.001 to 50% by weight, in particular 0.01 to 20% by weight.
  • the antifouling agents further contain the usual ingredients such as e.g. in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.
  • antifouling paints contain binders in particular.
  • Examples of recognized binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in one
  • Solvent system especially in an aqueous system, vinyl chloride / vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of organic solvent systems, butadiene / styrene / acrylonitrile rubbers, drying 'oils such as linseed oil, Harzester or modified hardened resins in combination with tar or bitumens , Asphalt and epoxy compounds, small amounts of chlorine, rubber, chlorinated polypropylene and vinyl resins.
  • Paints may also contain inorganic pigments, organic pigments or dyes, which are preferably insoluble in sea water. Furthermore, paints can contain materials such as rosin in order to be controlled
  • the paints may also contain plasticizers, modifiers that affect the rheological properties, and other conventional ingredients.
  • the active ingredient combinations according to the invention can also be incorporated into self-polishing antifouling systems.
  • the active compound combinations according to the invention are also suitable for combating animal pests, in particular insects, arachnids and mites, which occur in closed rooms, such as, for example, apartments, factory halls, offices, vehicle cabins and others. To control these pests, they can be used alone or in combination with other active ingredients and auxiliaries in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include:
  • Sco ⁇ ionidea e.g. Buthus occitanus.
  • Acarina e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornifhodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophosphides pteronissimus for Dermatophagoides.
  • Opiliones e.g. Pseudosco ⁇ iones chelifer, Pseudosco ⁇ iones cheiridium, Opiliones phalangium.
  • Diplopoda e.g. Blaniulus guttulatus, Polydesmus spp.
  • Ctenocephalides canis Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
  • Hymenoptera for example Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
  • anoplura for example Pediculus humanus capitis, Pediculus humanus co ⁇ oris, Phthirus pubis.
  • the application rates can be varied within a substantial range, depending on the type of application.
  • the application rates of active compound combination are generally between 0.1 and 10,000 g / ha, preferably between 10 and 1000 g / ha.
  • the good insecticidal and acaricidal activity of the active compound combinations according to the invention can be seen from the examples below. While the individual active ingredients have weaknesses in their effects, the combinations show an effect that goes beyond a simple summation of effects. Insecticides and acaricides always have a synergistic effect if the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
  • Pa expresses the proportion of the mixture of active ingredient A
  • Pb expresses the proportion of the mixture of active ingredient B
  • LC 50 (or 95) a indicates the concentration at which 50% (or 95%) of the animals treated with active ingredient A die
  • LC 50 (b ⁇ , 95) b indicates the concentration at which 50% ' (or 95%) of the animals treated with active ingredient B die
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier, and the concentrate is diluted to the desired concentration with water containing emulsifier.
  • Soybean shoots (Glycine max) are treated by dipping into the active ingredient preparation of the desired concentration and are populated with Heliothis armigera caterpillars while the leaves are still moist.
  • the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
  • the determined killing values are calculated using the Ca ⁇ enter formula (see previous page).
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and populated with larvae of the horseradish beetle (Phaedon cochleariae) while the leaves are still moist.
  • the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed.
  • the determined killing values are calculated using the Ca ⁇ enter formula.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and populated with caterpillars of the cabbage cockroach (Plutella xylostella, sensitive strain) while the leaves are still moist.
  • the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
  • the determined killing values are calculated using the Ca ⁇ enter formula.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and populated with caterpillars of the cabbage cockroach (Plutella xylostella, resistant stem) while the leaves are still moist.
  • the failure is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
  • the determined killing values are calculated using the Ca ⁇ enter formula.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and populated with caterpillars of the army worm (Spodoptera frugiperda) while the leaves are still moist.
  • the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
  • the determined killing values are calculated using the Ca ⁇ enter formula.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and populated with larvae of the horseradish beetle (Phaedon cochleariae) while the leaves are still moist.
  • the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed.
  • the determined killing values are calculated using the Ca ⁇ enter formula.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • Cabbage leaves (Brassica oleracea) are treated by being dipped into the preparation of active compound of the desired concentration and populated with caterpillars of the army worm (Spodoptera frugiperda) while the leaves are still moist.
  • the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
  • the determined killing values are calculated using the Ca ⁇ enter formula.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
EP03704580A 2002-02-21 2003-02-10 Synergistische insektizide mischungen Withdrawn EP1478234A1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10207242A DE10207242A1 (de) 2002-02-21 2002-02-21 Synergistische insektizide Mischungen
DE10207242 2002-02-21
PCT/EP2003/001283 WO2003070000A1 (de) 2002-02-21 2003-02-10 Synergistische insektizide mischungen

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EP1478234A1 true EP1478234A1 (de) 2004-11-24

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JP (1) JP2005517713A (pl)
KR (1) KR20040088075A (pl)
CN (1) CN100508753C (pl)
AP (1) AP2004003106A0 (pl)
AU (1) AU2003206870B2 (pl)
BR (1) BR0307834A (pl)
CA (1) CA2476818A1 (pl)
DE (1) DE10207242A1 (pl)
HR (1) HRP20040866A2 (pl)
MX (1) MXPA04008065A (pl)
OA (1) OA12773A (pl)
PL (1) PL370385A1 (pl)
RU (1) RU2004128087A (pl)
WO (1) WO2003070000A1 (pl)
ZA (1) ZA200406488B (pl)

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DE10347440A1 (de) * 2003-10-13 2005-05-04 Bayer Cropscience Ag Synergistische insektizide Mischungen
DE10360836A1 (de) * 2003-12-23 2005-07-21 Bayer Chemicals Ag Mittel zum Schutz von technischen Materialien
DE102004006324A1 (de) * 2004-02-10 2005-08-25 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
MX2007009958A (es) * 2005-02-24 2007-09-26 Syngenta Participations Ag Metodo para mejorar el desarrollo de plantas tolerantes o resistentes a los nematodos.
US20070099963A1 (en) * 2005-11-01 2007-05-03 Bayer Cropscience Lp Nematicidal compositions and methods
EP1849363A1 (en) * 2006-03-09 2007-10-31 Cheminova A/S Synergistic combination of glutamate- and GABA-gated chloride agonist pesticide and at least one of Vitamin E or Niacin
BRPI0716712B1 (pt) * 2006-09-12 2016-06-28 Nippon Soda Co agente para o controle de infestações na forma de suspensão estável
WO2012045680A2 (de) * 2010-10-04 2012-04-12 Bayer Cropscience Ag Insektizide und fungizide wirkstoffkombinationen
CN102057937A (zh) * 2011-01-21 2011-05-18 赤峰市帅旗农药有限责任公司 噻虫啉与甲氨基阿维菌素苯甲酸盐的杀虫组合物
AU2014280848C1 (en) * 2013-06-12 2020-11-05 Elanco Australasia Pty Limited Ectoparasitic treatment method and composition
CN103975915B (zh) * 2014-05-23 2016-04-13 青岛金正农药有限公司 一种用于甲维盐微乳剂的助剂组合物及其应用方法
WO2016182491A1 (en) * 2015-05-08 2016-11-17 Sp Sveriges Tekniska Forskningsinstitut Ab Antifouling film
WO2020002189A1 (de) * 2018-06-27 2020-01-02 Bayer Aktiengesellschaft Wirkstoffkombinationen
CN111568886B (zh) * 2020-06-16 2022-09-13 福建师范大学福清分校 一种用于治疗牛螨病的中西药复方涂膜剂及其制备方法

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JPH0717621B2 (ja) * 1986-03-07 1995-03-01 日本バイエルアグロケム株式会社 新規ヘテロ環式化合物
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ZA200406488B (en) 2005-08-16
CN100508753C (zh) 2009-07-08
PL370385A1 (pl) 2005-05-30
RU2004128087A (ru) 2005-05-27
HRP20040866A2 (en) 2005-04-30
CA2476818A1 (en) 2003-08-28
AP2004003106A0 (en) 2004-09-30
AU2003206870B2 (en) 2008-01-31
WO2003070000A1 (de) 2003-08-28
BR0307834A (pt) 2004-12-07
OA12773A (en) 2006-07-04
JP2005517713A (ja) 2005-06-16
KR20040088075A (ko) 2004-10-15
DE10207242A1 (de) 2003-09-04
CN1646016A (zh) 2005-07-27
MXPA04008065A (es) 2004-11-26
AU2003206870A1 (en) 2003-09-09
US20050130913A1 (en) 2005-06-16

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