EP1457732A2 - Druckbehälter und Methode zu dessen Herstellung - Google Patents

Druckbehälter und Methode zu dessen Herstellung Download PDF

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Publication number
EP1457732A2
EP1457732A2 EP04251063A EP04251063A EP1457732A2 EP 1457732 A2 EP1457732 A2 EP 1457732A2 EP 04251063 A EP04251063 A EP 04251063A EP 04251063 A EP04251063 A EP 04251063A EP 1457732 A2 EP1457732 A2 EP 1457732A2
Authority
EP
European Patent Office
Prior art keywords
pressurized container
reinforced
polyesters
container
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04251063A
Other languages
English (en)
French (fr)
Other versions
EP1457732A3 (de
Inventor
Gerrit De Wit
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SABIC Global Technologies BV
Original Assignee
SABIC Innovative Plastics IP BV
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SABIC Innovative Plastics IP BV, General Electric Co filed Critical SABIC Innovative Plastics IP BV
Publication of EP1457732A2 publication Critical patent/EP1457732A2/de
Publication of EP1457732A3 publication Critical patent/EP1457732A3/de
Withdrawn legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C1/00Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
    • F17C1/02Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge involving reinforcing arrangements
    • F17C1/04Protecting sheathings
    • F17C1/06Protecting sheathings built-up from wound-on bands or filamentary material, e.g. wires
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01Shape
    • F17C2201/0104Shape cylindrical
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05Size
    • F17C2201/056Small (<1 m3)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05Size
    • F17C2201/058Size portable (<30 l)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/01Reinforcing or suspension means
    • F17C2203/011Reinforcing means
    • F17C2203/012Reinforcing means on or in the wall, e.g. ribs
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0602Wall structures; Special features thereof
    • F17C2203/0612Wall structures
    • F17C2203/0614Single wall
    • F17C2203/0617Single wall with one layer
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0639Steels
    • F17C2203/0643Stainless steels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0646Aluminium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0658Synthetics
    • F17C2203/0663Synthetics in form of fibers or filaments
    • F17C2203/0665Synthetics in form of fibers or filaments radially wound
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0658Synthetics
    • F17C2203/0663Synthetics in form of fibers or filaments
    • F17C2203/0668Synthetics in form of fibers or filaments axially wound
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0658Synthetics
    • F17C2203/0663Synthetics in form of fibers or filaments
    • F17C2203/0673Polymers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/068Special properties of materials for vessel walls
    • F17C2203/0697Special properties of materials for vessel walls comprising nanoparticles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00Vessel construction, in particular methods of manufacturing
    • F17C2209/21Shaping processes
    • F17C2209/2109Moulding
    • F17C2209/2118Moulding by injection
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00Vessel construction, in particular methods of manufacturing
    • F17C2209/21Shaping processes
    • F17C2209/2109Moulding
    • F17C2209/2127Moulding by blowing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00Vessel construction, in particular methods of manufacturing
    • F17C2209/22Assembling processes
    • F17C2209/221Welding
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00Vessel construction, in particular methods of manufacturing
    • F17C2209/23Manufacturing of particular parts or at special locations
    • F17C2209/232Manufacturing of particular parts or at special locations of walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/01Pure fluids
    • F17C2221/011Oxygen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/01Pure fluids
    • F17C2221/013Carbone dioxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0107Single phase
    • F17C2223/0123Single phase gaseous, e.g. CNG, GNC
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0146Two-phase
    • F17C2223/0153Liquefied gas, e.g. LPG, GPL
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/03Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
    • F17C2223/033Small pressure, e.g. for liquefied gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/03Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
    • F17C2223/035High pressure (>10 bar)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/03Dealing with losses
    • F17C2260/035Dealing with losses of fluid
    • F17C2260/036Avoiding leaks
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/02Applications for medical applications
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/05Applications for industrial use
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/05Applications for industrial use
    • F17C2270/0545Tools
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/05Applications for industrial use
    • F17C2270/0563Pneumatic applications
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/07Applications for household use
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/07Applications for household use
    • F17C2270/0754Fire extinguishers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]

Definitions

  • the present invention relates to pressurized containers or vessels made from reinforced thermoplastics and methods for making pressurized containers or vessels from reinforced thermoplastics.
  • plastics for pressurized containers primarily for containing beverages, but increasingly for other utilities such as containers to dispense either gaseous or liquid carbon dioxide for use in pneumatic power devices such as garden pressure sprayers, power tools, etc. wherein the high pressure carbon dioxide provides mechanical power.
  • plastic containers in applications such as fire extinguishers, cylinders containing medical gases for distribution in laboratories and larger (e.g. 5 to 50 liters capacity), and cylinders such as those used in the distribution of oxygen, nitrogen, carbon dioxide and the like to industrial users.
  • U.S. Patent No. 3,712,497 discloses bottles formed of thin walled, flexible synthetic plastics, in separate parts which are later friction welded together forming the bottles, capable of withstanding internal pressures of up to 75 psi.
  • U.S. Patent No. 4,591,066 discloses a unitary molded plastic body for containing pressurized liquid beverage made out of polystyrene, PET, or polypropylene.
  • these containers are quite permeable to carbon dioxide.
  • beer stored in the plastic containers of the prior art will have lost so much of its carbon dioxide content after a few days that the remaining beer will no longer be palatable and flat-tasting.
  • EP 0 578 711B1 discloses an improved container for beer and other beverages in the form of a layered construction of at least two plastic materials, with the plastic materials being arranged in adjacent layers fastened together, or being laminated together.
  • the improved container herein can withstand pressure of up to approximately 420kPA or about 65 psi.
  • the first plastic material is a polyethylene terepthalate
  • the second plastic material is nylon.
  • the invention relates a pressurized container made of reinforced polyesters having sufficient creep resistance, impact strength, CO 2 and O 2 barrier resistance, wherein upon being filled with a liquid having a dissolved carbon dioxide content of in the range of 0.4 - 0.6 wt % at an internal pressure of at least 1 bar, said pressurized container maintains a dissolved carbon dioxide content of at least about 0.25 wt % after 6 months at a storage temperature of about 30 to 35 °C, and an O 2 -permeation of less than 1.0 ppm.
  • the invention also relates to the use of long-glass fiber reinforced polyesters in pressurized containers for excellent creep resistance, impact strength, water and CO 2 /O 2 barrier properties.
  • reinforced plastic materials i.e., polyesters reinforced with various materials, e.g., long-glass fibers, provide a combination of excellent barrier and physical properties such as low permeability to gases, high strength, and low creep at elevated temperatures, thus excellent for packaging applications such as pressurized containers for beverages and foodstuff.
  • polyester resins utilized in this invention include, in general, linear saturated condensation products of diols and dicarboxylic acids, or reactive derivatives thereof. Polyesters are well known as film and fiber formers, and they are manufactured by methods known in the art including those disclosed in U.S. Pat. Nos. 2,465,319 and 3,047,539.
  • the polyesters comprise condensation products of aromatic dicarboxylic acids and aliphatic diols.
  • the polyesters are poly(1,4-dimethylol cyclohexane dicarboxylates, e.g., terephthalates).
  • terephthalates small amounts of other aromatic dicarboxylic acids, such as isophthalic dicarboxylic acid, naphthalene dicarboxylic acid, or aliphatic dicarboxylic acids, such as adipic acid, can also be present in the resins.
  • the diol constituent can likewise be varied, in some embodiments, by adding small amounts of cycloaliphatic diols.
  • the polyesters comprise a poly(alkylene terephthalate, isophthalate or mixed isophthalate-terephthalate, e.g., up to 30 mole percent isophthalate), with the alkylene groups containing from 2 to 10 carbon atoms, e.g., poly(ethylene terephthalate) (“PET”) or poly(1,4-butylene terephthalate) (“PBT”).
  • PET poly(ethylene terephthalate)
  • PBT poly(1,4-butylene terephthalate)
  • the polyester resins may comprise entirely of PET, PBT, or a combination thereof.
  • the polyesters comprise a mixture of PBT to PET at a weight ratio of about 1:1 to about 20:1.
  • the poly(1,4-butylene terephthalate) resin used is one obtained by polymerizing a glycol component at least 70 mol %, preferably at least 80 mol %, of which consists of tetramethylene glycol and an acid or ester component at least 70 mol %, preferably at least 80 mol %, of which consists of terephthalic acid, and polyester-forming derivatives therefore.
  • the polyester is a poly(1,4-butylene terephthalate) homopolyester.
  • copolyesters are used. These comprise at least about 70 mole percent, based on total monomer content, of butylene and terephthalate units.
  • the comonomer may be either a dicarboxylic acid or diol or a combination of the two. Suitable dicarboxylic acid comonomers include the C 8 to C 16 aromatic dicarboxylic acids, including the benzene dicarboxylic acids, i.e. phthalic and isophthalic acids and their alkyl, e.g.
  • Suitable diol comonomers include but are not limited to C 2 to C 8 aliphatic and cycloaliphatic diols, e.g. ethylene glycol, hexanediol, butanediol and 1,2-, 1,3- and 1,4-cyclohexanedimethanol.
  • the polyester resin having a coefficient of thermal expansion (CTE) higher than that of the intended reinforcing material used, so that the polyester material shrinks around the reinforcing material causing compressive stresses which grip the reinforcing material in place.
  • CTE coefficient of thermal expansion
  • the polyesters may be blended with a polycarbonate resin.
  • Polycarbonate resins useful in preparing the blends of the present invention are generally aromatic polycarbonate resins.
  • the polyesters may be modified with additives such as a high molecular weight polyetherimide base material (e.g. an polyetherimide ester elastomer) as a warpage control additive.
  • a high molecular weight polyetherimide base material e.g. an polyetherimide ester elastomer
  • additives such as (co-)polyolefins or polyethylenes are added for improved impact strength.
  • the impact strength additive is selected from ethylene-vinyl acetate (EVA), linear low-density polyethylene (LLDPE), and alpha-olefin-glycidyl methacrylate copolymers and terpolymers.
  • a copolymer or interpolymer comprising glycidyl 2-alkenoates and alpha-olefins is added to the polyester for improved impact strength and improved melt viscosity to facilitate the construction of the finished pressurized containers.
  • the polyesters may further contain one or more conventional additives such as, for example, antioxidants, carbon black, reinforcing agents, plasticizers, lubricity promoters, color stabilizers, ultraviolet absorbers, X-ray opacifiers, dyes, pigments, fillers including mineral fillers, mold release agents such as polyethylene, and the like.
  • additives such as, for example, antioxidants, carbon black, reinforcing agents, plasticizers, lubricity promoters, color stabilizers, ultraviolet absorbers, X-ray opacifiers, dyes, pigments, fillers including mineral fillers, mold release agents such as polyethylene, and the like.
  • mineral fillers include alumina, amorphous silica, anhydrous aluminum silicates, feldspar, talc, milled glass, phenolic resins, glass microspheres, metal oxides such as titanium dioxide, zinc sulfide, ground quartz, clays such as hydrated aluminum silicate, and the like are used in the polyester matrix.
  • thermal, oxidative and/or ultraviolet stabilizers comprise phenols and their derivatives, amines and their derivatives, compounds containing both hydroxyl and amine groups, hydroxyazines, oximes, polymeric phenolic esters and salts of multivalent metals may be optionally added to the polyester resins.
  • the reinforcing agents are fibers in the form of fiberglass, carbon or aramid fibers in roving, woven fabric form, or in combination of fiberglass and carbon or aramid fibers.
  • the reinforcing agents are metals drawn into wire or filaments, or polyamide polymers characterized by the presence of the amide group - CONH.
  • the reinforcing agents are solely glass fibers available in roving, continuous strand mat, and stitched rovings (0°, 90°, and ⁇ 45° orientations).
  • the fibers are precoated with a binder to enhance compatibility with the polyester resin matrix.
  • the coating can comprise normal fiberglass coating materials: polyurethane resin, polyacrylate resin, polyester resin, polyepoxide resin, and functional silanes, especially epoxy or amine functional alkoxy silanes.
  • the amount of the coating agent employed is generally that amount which is sufficient to bind the filaments into a continuous strand. Generally, this may be about 1.0 weight percent based on the weight of the glass filament.
  • the fiber diameters typically range from about 3 to 50 microns.
  • the filaments in the form of glass fibers have a diameter of about 5 to 30 microns.
  • the fiber has a diameter of about 10 to 20 microns.
  • the fibers in the form of chopped fiberglass strands have a length of about 1/8" to about 1".
  • long-fibers with lengths of more than 1" are used, for increased strength and moldability of the containers.
  • the fiberglass fibers are comprised of lime-aluminum borosilicate glass that is relatively soda free. This is known as "E" glass.
  • other glasses are used as well e.g., the low soda glass known as "C.”
  • glass filaments known as G-filaments are used.
  • the glass filaments are made by standard processes, e.g., by steam or air blowing, flame blowing and mechanical pulling. In one embodiment, the filaments are made by mechanical pulling. In one embodiment, the filaments are in the form of being bundled into fibers and the fibers bundled in turn to yams, ropes or rovings, for final use in reinforcing the polyesters for use in the pressurized containers of the invention.
  • the reinforcing agents comprise a range of materials other than glass fibers and in the form other than filaments, e.g., microspheres. These include but are not limited to glass, ceramic materials such as graphite, wollastonite, carbons, metals, e.g., aluminum, iron, nickel, stainless steel and the like, titanates, e.g., titanate whiskers, quartz, clay, mica, talc, mixtures of the foregoing and the like.
  • the metal and metal glass fiber materials that can be used include those disclosed in the U.S. Pat. No. 4,525,314, the entire disclosure of which is incorporated herein by reference.
  • the ceramic materials from which the reinforcing fibers can be made include silicon carbide, silicon nitride, carbon, graphite and aluminum oxide.
  • the metal, ceramic, and glass microspheres than can be used as reinforcing agents include those disclosed in U.S. Pat. No. 4671994, the entire disclosure of which is incorporated herein by reference.
  • reinforcing agents are used in an amount ranging from about 5 to about 60 weight percent based on the total weight of the thermoplastic blend composition.
  • the concentration of the reinforcing agents is expressed as volume %, and ranging from about 1 to about 50 volume % (vol. %).
  • the volume percent can be calculated by comparing the total area of the cross section of a finished part with the cross sectional area of the fibers. In another embodiment, this amount is less than about 40 vol. %. In a third embodiment, it is less than 30 vol. %. In a fourth embodiment, it is about 5 to 20 vol. %.
  • the reinforcing agents used are long fibers
  • a pultrusion process known in the art is used to form the components into shape.
  • the long glass fiber material is drawn through a bath containing the polyester resins plus any additives.
  • the long glass fiber material is first impregnated with the polyester resin of the invention (plus any optional additives).
  • Laminate formed is pulled through a heated die controlled to precise tolerances depending on the final container application specifications.
  • the finished product is cut and tooled into various parts of the container, e.g., sidewall, top or bottom part and the like. The parts are subsequently welded forming the finished containers.
  • a process as generally described in EP 0 820848B1 is used for a lineal structure particularly useful for a tall pressurized container, which reference is expressedly incorporated herein.
  • This process comprises feeding the melted polyester materials of the invention into a die having an inlet for receiving the melted material, and an outlet having a geometry corresponding to the desired part of the container of the invention.
  • the outlet is positioned downstream from the inlet wherein the melted polyester resin flows from the inlet to the outlet.
  • a plurality of fiber bundles are introduced to the stream at predetermined spaced apart radial positions for providing the fiber reinforcement to the lineal profile.
  • the fiber bundles extend in the longitudinal direction at predetermined locations in the profile.
  • the finished product is cut and tooled into various parts of the container, e.g., sidewall, top or bottom part and the like.
  • the containers can be further reinforced with additional bands of materials as generally taught in EP0852695B1 for "Blast Resistant And Blast Directing Containers.”
  • the pressurized container further comprises a plurality of spaced, substantially parallel composite strips attached to and reinforcing the container with each strip being a tape of unidirectional high strength fibers or oriented film encircling the container in a hoop direction at least once.
  • chopped glass strands are used as reinforcing agents.
  • the chopped glass strands may be first blended with the polyester resin and then fed to an extruder and the extrudate cut into pellets.
  • they may be separately fed to the feed hopper of an extruder to preparing reinforced polyester pellets.
  • the pellets so prepared when cutting the extrudate may be one-fourth inch long or less.
  • the dispersed glass fibers are reduced in length as a result of the shearing action on the chopped glass strands in the extruder barrel.
  • the reinforced polyester resins are subsequently shaped into pressurized containers or parts thereof, via common processes known in the art, such as extrusion blow molding, injection blow molding, profile extrusion, pipe extrusion, co-extrusion, extrusion coating, foam molding, foam extrusion, thermoforming, and the like.
  • the parts can be subsequently welded to form the finished pressurized containers.
  • the reinforced polyester pressurized containers of 2-4 mm thickness are used as beer containers, i.e., beer kegs
  • the reinforced polyester pressurized containers of the invention have inherently low CO 2 and oxygen permeation properties, wherein upon being filled with a liquid having a dissolved carbon dioxide content of 0.4 - 0.6 wt % at an internal pressure of at least 1 bar, said pressurized container maintains a dissolved carbon dioxide content of at least 0.25 wt % after 0.5 year at a storage temperature of about 30 to 35 °C and an O 2 -permeation of less than 1.0 ppm.
  • the pressurized containers made out of reinforced polyesters, used at an initial internal pressure of 1-5 bar have a creep ⁇ 3 % after 0.5 year at room temperature.
  • the reinforced polyesters containers of the present invention do not import unacceptable levels flavoring changes to the products.
  • reinforced polyester compositions comprising PBT (poly(butyleneterephthalate) with molecular weight of approximately 80,000 (as expressed as PS molecular weight), 0.15 % Irganox 1010 as a stabilizer, approximately 1 % of a polyethylene as release agent., and from 30 to 50 wt. % of glass fiber.
  • compositions are referred to as 30% SGF, 50% LGF, 30% LGF, and 50% LGF, depending on whether short glass or long glass fiber is used.
  • the short glass fiber is in the form of E-glass chopped strands commercially available from NEG as T-120.
  • the long glass fiber e.g. E-glass based
  • a finishing agent such as a silane-based coupling agent, greige goods such as urethane-based resins or epoxy-based resins, a thermal stabilizer such as typically phosphite-based resins, or any other adequate surface-treating agents depending upon aimed uses, if required.
  • the LGF compositions are made according to the pultrusion process as generally disclosed in U.S. Patent No. 4,559,262, the entire disclosure of which is incorporated herein by reference.
  • PBT polymer melts are prepared in a bath of about 260°C.
  • Fiber glass filaments in the form of a glass roving
  • the impregnated roving is pulled through a 3 mm diameter die in the wall of the bath and then cooled, for a completely wetted material.
  • the amount of PBT in the finished product (for 30 or 50 wt. % concentration of fiber) is controlled by the length of the path over which the fiber band contacts the heated spreader surface.
  • the products obtained by the continuous pultrusion are subsequently chopped to form pellets having a length in the range of at least 5 - 10 mm.
  • the used LGF products are supplied by LNP under the name of Verton AF 7006 (30 % LGF) and WF 700 10 (50 % LGF).
  • the SGF blends are made by dry blending of ingredients with exception of the glass fiber.
  • the blends are subsequently compounded on a WP25 mm co-rotating extruder, where the glass is separately fed down-stream the extruder.
  • the melt temperature was approx. 250-260°C and at RPM of 300.
  • the products obtained are extrudated to form pellets.
  • the SGF and LGF products are molded into samples using an Engel 75 tons machine with a temperature setting of 240-260°C (from throat to nozzle) and a mold temperature of 60°C. Prior to molding the pellets were predried at 120°C for 2 hours.
  • SGF short-glass fiber
  • LGF long-glass fiber
  • Example 2 the 50% LGF composition in Example 2 is used in a fiber-reinforced polyester pressurized vessel, i.e., beer kegs, with a pultrusion process is used to form the components of the beer kegs.
  • a fiber-reinforced polyester pressurized vessel i.e., beer kegs
  • the beer kegs are filled from beer tanks at suitable internal pressure of about 2 bars and at temperature of about 20 to 35 °C, and with the beer having a dissolved carbon dioxide content of about 0.5 wt %.
  • the beer in the fiber-reinforced polyester beer kegs of the present invention has a dissolved carbon dioxide content of at least 0.25 wt. %. It is also found that the beer is not flat when dispensed and consumed. It is also found that after the beer is partially consumed and in storage in the keg at about 20 to 35°C for two to three days, the remaining beer still contains a dissolved carbon dioxide volume of about 0.25 wt %. Additionally, the beer also retains a palatable taste and is not flat, all without the need for any external pressure source.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
EP04251063A 2003-02-26 2004-02-26 Druckbehälter und Methode zu dessen Herstellung Withdrawn EP1457732A3 (de)

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US45045403P 2003-02-26 2003-02-26
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US10/661,444 US20040166266A1 (en) 2003-02-26 2003-09-12 Pressurized containers and method for making thereof
US661444 2003-09-12

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