EP1436774A1 - Document de valeur et marquage de securite au moyen d'une substance de marquage - Google Patents

Document de valeur et marquage de securite au moyen d'une substance de marquage

Info

Publication number
EP1436774A1
EP1436774A1 EP02781215A EP02781215A EP1436774A1 EP 1436774 A1 EP1436774 A1 EP 1436774A1 EP 02781215 A EP02781215 A EP 02781215A EP 02781215 A EP02781215 A EP 02781215A EP 1436774 A1 EP1436774 A1 EP 1436774A1
Authority
EP
European Patent Office
Prior art keywords
marking
security
imprint
value
document
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP02781215A
Other languages
German (de)
English (en)
Inventor
Karlheinz Mayer
Dirk Uwe SÄNGER
Jürgen ZERBES
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Giesecke and Devrient GmbH
Original Assignee
Giesecke and Devrient GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Giesecke and Devrient GmbH filed Critical Giesecke and Devrient GmbH
Publication of EP1436774A1 publication Critical patent/EP1436774A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/14Security printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/20Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
    • B42D25/29Securities; Bank notes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/40Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
    • D21H21/44Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
    • D21H21/48Elements suited for physical verification, e.g. by irradiation
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06KGRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
    • G06K19/00Record carriers for use with machines and with at least a part designed to carry digital markings
    • G06K19/06Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
    • G06K19/06009Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking
    • G06K19/06018Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking one-dimensional coding
    • G06K19/06028Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking one-dimensional coding using bar codes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06KGRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
    • G06K19/00Record carriers for use with machines and with at least a part designed to carry digital markings
    • G06K19/06Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
    • G06K2019/06215Aspects not covered by other subgroups
    • G06K2019/06225Aspects not covered by other subgroups using wavelength selection, e.g. colour code

Definitions

  • the invention relates to a document of value, a security element and a security marking which have a marking substance which absorbs in the infrared spectral range, which shows no significant absorption in the visible range and is preferably largely transparent, as well as an examination method and a device for carrying out the examination.
  • marking materials for example introduced in printing ink, markings can be produced on any objects or their packaging, which are preferably used for authenticity checking or in the field of logistics, for example for recording and tracking the flow of goods.
  • a security code is known from EP 0340 898 B1, which has two identification marks.
  • An identification mark is essentially colorless and absorbs in the near infrared part of the electromagnetic spectrum from 700 to 1500 ran. This first marking is overprinted with a second color marking, which is opaque in the visible range and does not absorb in the infrared spectral range mentioned. The marking absorbing in infrared is detected with a reader that works at 780 to 800 nm. Such readers, which work with commercially available and inexpensive silicon detectors, are now widespread and accessible to everyone.
  • the object of the present invention is therefore a possibility for marking and a method for testing objects and in particular to propose documents of value that meet further security requirements without having the disadvantages of the prior art.
  • the documents of value, security elements and security markings according to the invention are distinguished by a marking substance which has a significant absorption in the infrared spectral range from 1000 to 2500 nm.
  • the marking substance In the visible spectral range, on the other hand, the marking substance has no or only a weak intrinsic color and therefore shows no significant absorption in this part of the spectrum.
  • the marking substance also shows no significant absorption at a wavelength of or around 800 nm.
  • the marking substance has the advantage that it cannot be detected with the widespread and inexpensive silicon detectors, which operate in the range from approx. 780 to 800 nm.
  • IR absorbers In addition to organic compounds, inorganic materials are used as IR absorbers according to the present invention, which have a better stability against environmental influences. Those absorbers based on doped semiconductor materials are preferred. Metal oxides which are also distinguished by their aging resistance are particularly preferred.
  • the marking substance is preferably present in an average particle size which is less than 50 nm. As a result, visible light is hardly scattered by the particles. The marking substance is colorless or has only a very weak intrinsic color.
  • the marking substance is preferably applied to the value document in the form of an imprint.
  • the marking substance is added to a binder or a printing ink mixed with color pigments.
  • the printing ink or the binder must not have any significant absorption in the infrared range from 1000 to 2500 nm, in particular 1500 to 2000 nm.
  • the print image to be displayed with the marking substance is arbitrary and can be, for example, a logo, alphanumeric characters, a bar code or the like.
  • the process of coextrusion is particularly suitable for this in film production. It can also be used to produce foils that only contain the marking substance in certain sections or strips.
  • the marking substance is preferably not applied or applied over the entire area, but only at selected locations or along predetermined tracks. Coding can be generated through targeted recesses or interruptions in the application or application of the marking substance. Such codes can be used, for example, to reproduce batch numbers, lot sizes or product or manufacturer names.
  • Value documents in the sense of the invention are understood to mean in particular bank notes, but also other monetary documents, such as checks, shares and vouchers. Identity cards and identification documents are also counted. Such documents of value are often provided with an individual serial number.
  • the serial number is preferably displayed in addition to a visually visible representation or exclusively by means of the marking substance absorbing in the infrared.
  • the so-called non-impact printing processes are particularly suitable for this.
  • other printing methods such as offset printing, are also suitable.
  • the area of a document of value provided with the marking substance can remain free or can be combined with a visually visible marking to be explained in more detail below.
  • the area provided with the infrared absorbing marking substance remains free and this has a slight intrinsic color in the visible, it can be advantageous to color the value document in the color or the color tone of the marking substance.
  • a further advantageous possibility for camouflaging and disguising the marking can consist in that the area provided with the marking substance is additionally coated with a layer of paint or to provide a thin cover film. Such an additional covering layer must then be sufficiently transparent both at 800 nm and in the selected measuring range, which can be between 1000 and 2500 nm.
  • the document of value can have a security marking which consists of at least a first imprint, which absorbs significantly in the visible and at 800 nm and has no significant absorption peaks between 1000 and 2500 nm, and a second imprint, which is visible and at 800 nm has no significant absorption, but is significantly absorbed in the spectral range from 1000 to 2500 nm.
  • the first and the second imprint are arranged to overlap at least in regions.
  • the security marking according to the invention has the advantage that it is not accessible with the widespread and inexpensive silicon detectors operating at approx. 780 to 800 nm, since only the imprint is recognized in this spectral range, which due to its absorption in the visible can be recognized even without technical information Aid and is recognizable with the normal human eye.
  • the marking formed by the second imprint remains hidden in such a measurement since it has no significant absorption at 800 nm.
  • the second marking is only accessible in the spectral range of> 1000 nm, since only in this range is there any appreciable absorption.
  • the infrared range from 1000 to 2500 nm is of particular interest for the purposes mentioned, since it has advantages in terms of measurement technology. The range from 1500 to 2000 nm is particularly preferred.
  • the imprint absorbs in the entire spectral range.
  • Sufficient and effective absorption is also present if absorption is only carried out in a subinterval of the visible spectral range.
  • the corresponding imprint is then easily visible and recognizable to the normal human eye under normal lighting conditions and normal viewing distance.
  • the visually visible marking can also be checked mechanically using appropriate optical devices, such as scanners or photodiodes, which operate at a suitable wavelength.
  • the absorption of which is not significant if it is less than 40%, in particular less than 30% of the value which it has at the wavelength between 1000 and 2500 nm at which the infrared test is carried out.
  • Binder and colorant are the essential components of a printing ink with which the prints forming the security marking can be produced.
  • Both the first and the second imprint can form a closed surface or can be interrupted. Designs are preferred in which additional information is reproduced by the respective imprint. This can consist, for example, of a logo, a national emblem, a lettering or other alphanumeric characters or display an image.
  • the execution as a barcode, with which information can be represented in encrypted form, is particularly preferred. Execution as a two-dimensional barcode is also possible.
  • the camouflage and concealment of the second print by the first is particularly efficient when the first and the second print are printed on essentially the same area, i.e. are congruent. However, only partially overlapping arrangements are also suitable. Regardless of the order in which they are arranged and positioned relative to one another, the two imprints can have any shape. They can be symmetrical and / or asymmetrical. The contour of the two prints can be the same as well as different.
  • the ink jet method is particularly preferred since it is a contactless printing method with which, for example, non-flat and curved surfaces can also be printed without particular difficulties. It is also particularly suitable Way to create individual, changing prints, such as a serial number.
  • the security marking according to the invention can also be applied to packaging and wrappings, such as cardboard boxes and foils, or can be printed on a tag or label, a seal or a banderole and then subsequently connected to the object which is actually to be protected.
  • An embodiment is also preferred in which the security marking is generated as an intermediate carrier on a transfer belt and from there onto a belt to be protected or identified
  • the attachment of the security marking on deposit containers, such as bottles or cans, is particularly preferred, the security marking according to the invention also having the function of a token.
  • the security marking according to the invention is advantageously used wherever the authenticity of an object or document is to be checked. Their use is also advantageous in the field of logistics, since information contained in the marking can be queried when the marking is checked at different “security levels”. For example, first information may be visually visible, but coded as a barcode, while second information , which can be identical or different to the first, is only accessible when measuring in the infrared range of> 1000 nm. The second information can also be additionally coded, for example as a bar code.
  • Preferred applications of security marking for documents concern documents of value, such as checks and vouchers, admission tickets, Lottery tickets, ID documents, such as passports, company or ID cards, accompanying documents, such as delivery notes, certificates of authenticity and customs papers.
  • Printing inks that appear visually black are preferably used, which are produced by subtractive color mixing using red and yellow base colors and one or both of the aforementioned colorants.
  • 2,5-cyclohexadiene-l, 4-diylidene-bis N, N- bis (4-dibutylan ⁇ ophenyl) amm.omun ⁇ ] comes as the infrared absorber, which has no effective absorption either in the visible spectral range or at approx.
  • the security marking is preferably checked automatically, ie by machine.
  • Commercially available scanners can be used for this, laser beams of suitable wavelength being preferably used as test beams.
  • Laser diodes are particularly suitable for irradiating the measuring range.
  • the marking substance absorbing in the infrared can be checked, for example, at approximately 1070 or 1550 nm. If the absorption is measured in several different spectral ranges or wavelengths, the tests can be carried out both in succession and at the same time, since they contradict each other. do not influence each other.
  • the absorption of the visually visible portion can be determined, for example, at 630 or 650 nm.
  • the visually visible, i.e. imprint absorbing in this spectral range according to the present invention is of particular importance that it also absorbs at or around 800 nm.
  • both colored, colored and black printing inks can be used. Black prints are preferred because on the one hand they are particularly widespread for marking objects and also form a particularly strong contrast on light and transparent objects. Black markings are therefore particularly noticeable.
  • a black print is also particularly suitable to hide or hide the print absorbing in the infrared.
  • the second print which absorbs essentially between 1000 and 2500 nm, to remain inconspicuous and hidden, it is necessary that it has no significant absorption in the visible spectral range.
  • Substances that are transparent and colorless are preferably used for this.
  • their concentration in the second print should be adjusted so that it has only a weak color in the visible spectral range and still leads to sufficient absorption in the infrared between 1000 and 2500 nm.
  • the marking substance or the safety marking is usually checked in reflection. If the object to which the marking is applied is sufficiently transparent in the relevant spectral range, can also be checked in transmitted light, ie in transmission.
  • the marking substance is preferably checked at approximately 1070 nm and / or at 1550 nm.
  • the appearance in the visible spectral range or perceived by measurement or measurement technology is determined almost entirely by the first imprint, while the second portion of the security marking is not perceived here.
  • the security marking according to the invention could not be realized if normal black standard printing ink was used for the visually visible print, since this usually contains carbon black, which also absorbs above 1000 nm.
  • the printing inks or dyes mentioned in EP 0340898 B1 which absorb in the visible but are not effective above 700 nm, do not lead to this either
  • the effect of the present invention that the visually visible print can also be used as camouflage or to conceal the second print even in the near infrared at approximately 800 nm.
  • a document of value or security element according to the invention is checked, in which the area provided with the marking substance does not necessarily have to be combined with an additional, visually visible marking, a single measurement of the absorption at at least one wavelength that was between 1000 and 2500 nm can in principle be carried out - may be sufficient. It is checked whether the visually essentially invisible marking is present at the checked point. However, a further measurement is preferably carried out at a different wavelength. This is preferably around 800 nm or in the visible spectral range. In this way, imitations can be identified that use, for example, the IR absorbers known from the above-mentioned prior art or very broadband absorbing compounds, for example containing carbon black. The latter would be recognizable both in the measurement of the absorption between 1000 and 2500 nm and in the visible spectral range, while the real marking substance according to the invention can only be recognized in the measurement carried out between 1000 and 2500 nm.
  • security elements can be manufactured separately and connected to a value document or any other object to be secured at any time, for example via an adhesive layer.
  • the security element is preferred designed as a label, seal, banderole or transfer ribbon or integrated into one.
  • Such prefabricated security elements can be arranged on, for example, a band-shaped carrier and, if necessary, can be transferred from this to an object to be protected.
  • the value documents and security elements according to the invention can have other elements that are difficult to imitate, such as watermarks, security threads, diffraction structures or other so-called feature substances, in order to increase their security against forgery.
  • These feature substances are preferably substances which have luminescence or are magnetic or are electrically conductive.
  • a further print or the first print absorbing in the visible additionally contains these feature substances. Due to their special physical properties, the feature substances make it possible to check the print, in particular for further mechanical testing, using appropriately designed sensors.
  • 3 shows a detail from the cross section of a value document
  • 4 shows a detail from the cross section of a document of value with a coating
  • Fig. 7 is a label in cross section.
  • FIG. 1 shows a simple embodiment of a value document 1 according to the invention.
  • This can be a bank note, for example.
  • the document contains a marking substance which is absorbing in the infrared but is essentially invisible visually.
  • the marking substance can, for example, be contained in a printing ink and printed on the value document 1.
  • Other coating or transfer processes are also possible.
  • the area 2 in which the marking substance is present is formed in FIG. 1 as a simple, unstructured surface.
  • the marking substance can preferably also be applied in a structured form, for example as a pattern, symbol or barcode.
  • the areas 2 provided with the marking substance can also represent alphanumeric characters which represent, for example, the serial number of the document.
  • the areas 2 containing the marking substance are arranged along a predetermined track 3.
  • the trace with the marking substances is not continuous and continuous, but is interrupted by areas in which no marking substance is present. Due to the location, length and spacing of the areas 2, for example encoded information can be reproduced. This information can, for example, reflect a batch number, the name of the manufacturer or the value of the document, in particular the value of a banknote.
  • the areas 2 can contain the marking substance only on the surface of the value document 1 or also in its volume.
  • FIG. 3 It schematically shows a section of the cross section of a value document 1. It is predominantly formed from fibers 4, which can be paper and / or plastic fibers. Individual particles 5 of the marking substance are embedded in an irregular distribution in the fleece-like fiber matrix. In particular, the representation of the size of the particles 5 is not to scale.
  • the particles can be added to the paper or fiber mass before the sheet is formed or, for example, can be introduced into the fiber matrix after the layer formation using the methods described in EP-A-0659 935 and DE 101 20 818.
  • the concentration of the particles can vary in the value document 1 and, as shown for example in FIG. 2, can be specifically changed along one direction.
  • the document of value 1 consists of a core layer 7, which is formed, for example, by a paper or plastic substrate, the upper and lower surfaces of which have been provided with a coating 6.
  • This coating can be, for example, a coating slip, surface sizing, a top coat, a lacquer layer or a cover film.
  • an object 8 is shown in cross-section in sub-figures a) and b), which has a security marking 9.
  • the first imprint 10 which absorbs in the visible spectral range, is on the outside and above the second imprint 11, which is non-absorbing in the visible, but absorbs in the infrared at> 1000 nm.
  • the imprints 10, 11 are arranged in reverse order.
  • the first and the second overlap only partially overlap, while in Fig. 5a) they are congruent, ie they have been printed on the same surface. 5a) and 5b), the imprints 10, 11 are shown as continuous layers.
  • the second imprint 11 still has a weak intrinsic color in the visible, it is advantageous to choose an embodiment according to FIG hides or camouflages.
  • 6 shows a document 1 in supervision, which bears a security marking 9.
  • the visually visible imprint 10 was imprinted using an inkjet process and is designed as a barcode. It overlaps to a large extent with the surface on which the second IT imprint, which is not visible in the visual, was applied. Since the second imprint 11 only absorbs in the infrared above 1000 nm, but has no intrinsic color in the visual spectral range and is therefore not visible to the naked eye, only the outline of the imprint 11 is indicated by a dashed line in FIG. 6.
  • the visually invisible imprint 11 can also be produced using the ink jet method, but also using another suitable printing method. Imprint 11 can also be designed as a barcode, but can also reproduce other symbols or characters, for example a national emblem or a company logo.
  • additional coloring or lacquer layers which can lie above, below or between the two described.
  • additional layers must be essentially transparent in the measuring range between 1000 and 2500 nm. With a suitable color or gloss, these layers can serve as additional camouflage for the marking absorbing in the infrared.
  • the additional layers can have the function of a protective layer or a so-called design layer, through which the markings are graphically integrated into their environment.
  • an additional layer or an imprint can be provided, by means of which a marking or a code is represented, which in the range between 760 and 1000 nm represents a significant edge absorption.
  • a marking or a code is represented, which in the range between 760 and 1000 nm represents a significant edge absorption.
  • FIG. 7 shows a cross-section of a label 12 which has the security marking 9 on one surface and is provided with an adhesive layer 13 on the other surface.
  • the label 12 can be attached to any objects.
  • the label 12 consists of a carrier layer that is transparent both in the visible and in the infrared spectral range, the adhesive layer can also be arranged on the same side as the security marking 9.
  • Both the print 10 and the print 11 are composed of non-contiguous sub-segments, as is the case, for example, with a bar code. The one in this case is outside
  • Imprint 10 takes up a larger area than imprint 11. Even if ink has not been transferred at every point of the imprint 10, the imprints 10 and 11 overlap, i.e. their printing areas completely. Although not all segments of the inside print 11 are covered by printing ink of the outside print 10, this is not disturbing, since the print 11 has at best a weak intrinsic color in the visually visible spectral range.

Landscapes

  • Business, Economics & Management (AREA)
  • Accounting & Taxation (AREA)
  • Finance (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Credit Cards Or The Like (AREA)
  • Printing Methods (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

L'invention concerne un document de valeur, un élément de sécurité et un marquage de sécurité, lesquels comportent une substance de marquage absorbant dans le domaine spectral infrarouge entre 1000 et 2500 nm, cette substance n'absorbant de manière significative ni dans le domaine spectral visible ni à 800 nm. C'est pourquoi cette substance de marquage n'est pas lisible pour les appareils de lecture infrarouges simples et largement répandus, lesquels fonctionnent à environ 800 nm. Une impression en surcharge est de préférence ajoutée, laquelle absorbe dans le domaine spectral visible ainsi qu'à environ 800 nm, mais pas dans la zone de 1000 à 2500 nm. Selon la présente invention, la vérification est réalisée par irradiation de l'emplacement marqué avec de la lumière infrarouge dans la zone de 1000 à 2500 nm et par détermination de l'absorption.
EP02781215A 2001-10-05 2002-10-04 Document de valeur et marquage de securite au moyen d'une substance de marquage Withdrawn EP1436774A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10149265A DE10149265A1 (de) 2001-10-05 2001-10-05 Gegenstand mit Sicherheitsmarkierung
DE10149265 2001-10-05
PCT/EP2002/011142 WO2003032243A1 (fr) 2001-10-05 2002-10-04 Document de valeur et marquage de securite au moyen d'une substance de marquage

Publications (1)

Publication Number Publication Date
EP1436774A1 true EP1436774A1 (fr) 2004-07-14

Family

ID=7701574

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02781215A Withdrawn EP1436774A1 (fr) 2001-10-05 2002-10-04 Document de valeur et marquage de securite au moyen d'une substance de marquage

Country Status (12)

Country Link
US (1) US20050052519A1 (fr)
EP (1) EP1436774A1 (fr)
JP (2) JP2005505444A (fr)
CN (1) CN100476870C (fr)
BR (1) BR0213133A (fr)
CA (1) CA2462803A1 (fr)
DE (1) DE10149265A1 (fr)
MX (1) MXPA04002958A (fr)
PL (1) PL368057A1 (fr)
RU (1) RU2305866C2 (fr)
WO (1) WO2003032243A1 (fr)
ZA (1) ZA200402086B (fr)

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DE102007058888A1 (de) 2007-12-05 2009-06-10 Informium Ag Fälschungsschutz für Einweggebinde

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BR0213133A (pt) 2004-10-19
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US20050052519A1 (en) 2005-03-10
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MXPA04002958A (es) 2004-07-15
CA2462803A1 (fr) 2003-04-17

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