EP1416038B1 - Verdickte flüssige Bleichmittelzusammensetzungen - Google Patents
Verdickte flüssige Bleichmittelzusammensetzungen Download PDFInfo
- Publication number
- EP1416038B1 EP1416038B1 EP02257478A EP02257478A EP1416038B1 EP 1416038 B1 EP1416038 B1 EP 1416038B1 EP 02257478 A EP02257478 A EP 02257478A EP 02257478 A EP02257478 A EP 02257478A EP 1416038 B1 EP1416038 B1 EP 1416038B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- amine oxide
- toilet
- hypochlorite
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 66
- 239000007788 liquid Substances 0.000 title claims abstract description 22
- 238000004061 bleaching Methods 0.000 title claims abstract description 8
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims abstract description 53
- 238000004140 cleaning Methods 0.000 claims abstract description 17
- 239000006260 foam Substances 0.000 claims abstract description 11
- 238000000518 rheometry Methods 0.000 claims abstract description 7
- 150000001412 amines Chemical class 0.000 claims description 22
- 239000004094 surface-active agent Substances 0.000 claims description 21
- -1 alkali metal cation Chemical class 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 229940071089 sarcosinate Drugs 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- 238000009826 distribution Methods 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-M sarcosinate Chemical compound CNCC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-M 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000007844 bleaching agent Substances 0.000 description 6
- 239000005708 Sodium hypochlorite Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 108700004121 sarkosyl Proteins 0.000 description 5
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 5
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 5
- 239000004115 Sodium Silicate Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 229910052911 sodium silicate Inorganic materials 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 125000002252 acyl group Chemical group 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 235000013799 ultramarine blue Nutrition 0.000 description 2
- FRYOUKNFWFXASU-UHFFFAOYSA-N 2-(methylamino)acetic acid Chemical compound CNCC(O)=O.CNCC(O)=O FRYOUKNFWFXASU-UHFFFAOYSA-N 0.000 description 1
- XQMVBICWFFHDNN-UHFFFAOYSA-N 5-amino-4-chloro-2-phenylpyridazin-3-one;(2-ethoxy-3,3-dimethyl-2h-1-benzofuran-5-yl) methanesulfonate Chemical compound O=C1C(Cl)=C(N)C=NN1C1=CC=CC=C1.C1=C(OS(C)(=O)=O)C=C2C(C)(C)C(OCC)OC2=C1 XQMVBICWFFHDNN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical class ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229940060304 sodium myristoyl sarcosinate Drugs 0.000 description 1
- URBCOZYCCAFMJK-UHFFFAOYSA-M sodium;2-[methyl(octadecanoyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)N(C)CC([O-])=O URBCOZYCCAFMJK-UHFFFAOYSA-M 0.000 description 1
- KHCOJQDJOCNUGV-UHFFFAOYSA-M sodium;2-[methyl(tetradecanoyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCCC(=O)N(C)CC([O-])=O KHCOJQDJOCNUGV-UHFFFAOYSA-M 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Claims (4)
- Flüssige Hypochloritbleichzusammensetzung, die zur Verwendung in einer am Toilettenrand angebrachten Toilettenbeckenreinigungsvorrichtung geeignet ist, wobei die Zusammensetzung eine strukturviskose Rheologie aufweist und unmittelbar nach dem Spülen eine Schaumhöhe von mindestens 3 cm erzeugen kann, wenn sie in einer am Toilettenrand angebrachten Reinigungsvorrichtung verwendet wird; wobei die Zusammensetzung- oberflächenaktives Sarkosinat;- oberflächenaktives Aminoxid mit der Formel R2R'NO umfaßt, worin jeder R eine Niederalkylgruppe ist, und R' eine langkettige Alkylgruppe mit 12 bis 18 Kohlenstoffatomen ist, und worin die Verteilung der Kettenlängen der langkettigen Alkylgruppe (R'), jeweils basierend auf dem Gesamtgewicht des Aminoxids, wie folgt ist:- von 25 bis 30 Gew.-%: ist R' C12;- von 40 bis 60 Gew.-%: ist R' C14;- von 10 bis 35 Gew.-%: ist R' C16 und/oder C18.
- Zusammensetzung nach Anspruch 1, worin das oberflächenaktive Sarkosinat die Formel RCON(CH3)CH2COOM hat, worin M ein Alkalimetallkation ist, insbesondere Natrium oder Kalium, und R eine verzweigte oder geradkettige C8-C18-Alkylgruppe ist.
- Zusammensetzung nach einem der Ansprüche 1 oder 2, worin die Menge des oberflächenaktiven Aminoxids im Bereich von 6 bis 15 Gew.-%, bezogen auf das Gesamtgewicht des oberflächenaktiven Aminoxids, basierend auf dem Gesamtgewicht der Zusammensetzung, liegt.
- Verwendung der Zusammensetzung nach einem der Ansprüche 1 bis 3 in einer am Toilettenrand angebrachten Toilettenbeckenreinigungsvorrichtung.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE60217358T DE60217358T2 (de) | 2002-10-29 | 2002-10-29 | Verdickte flüssige Bleichmittelzusammensetzungen |
| EP02257478A EP1416038B1 (de) | 2002-10-29 | 2002-10-29 | Verdickte flüssige Bleichmittelzusammensetzungen |
| AT02257478T ATE350452T1 (de) | 2002-10-29 | 2002-10-29 | Verdickte flüssige bleichmittelzusammensetzungen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02257478A EP1416038B1 (de) | 2002-10-29 | 2002-10-29 | Verdickte flüssige Bleichmittelzusammensetzungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1416038A1 EP1416038A1 (de) | 2004-05-06 |
| EP1416038B1 true EP1416038B1 (de) | 2007-01-03 |
Family
ID=32088055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02257478A Expired - Lifetime EP1416038B1 (de) | 2002-10-29 | 2002-10-29 | Verdickte flüssige Bleichmittelzusammensetzungen |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP1416038B1 (de) |
| AT (1) | ATE350452T1 (de) |
| DE (1) | DE60217358T2 (de) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9487742B2 (en) | 2012-09-10 | 2016-11-08 | The Clorox Company | Drain formulation for enhanced hair dissolution |
| US10208273B2 (en) | 2012-09-10 | 2019-02-19 | The Clorox Company | Drain formulation for enhanced hair dissolution |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1988985B1 (de) * | 2005-06-24 | 2013-08-07 | Rhodia, Inc. | Strukturierte tensidzusammensetzungen |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8325541D0 (en) * | 1983-09-23 | 1983-10-26 | Unilever Plc | Liquid thickened bleaching composition |
| FR2570713B1 (fr) * | 1984-09-21 | 1987-08-21 | Lesieur Cotelle | Compositions de nettoyage aqueuses epaissies |
| US5693601A (en) * | 1993-07-23 | 1997-12-02 | The Procter & Gamble Company | Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants |
| CA2191343C (en) * | 1994-06-07 | 2007-07-31 | Dennis Thomas Smialowicz | Cleaning compositions thickened with n-alkyl-n-acyl amino acids and myristyl/cetyl dimethyl amine oxides |
| MX9801081A (es) * | 1995-08-10 | 1998-04-30 | Reckitt & Colman Inc | Composiciones de limpieza reopecticas pigmentadas con propiedades tixotropicas. |
-
2002
- 2002-10-29 DE DE60217358T patent/DE60217358T2/de not_active Expired - Lifetime
- 2002-10-29 AT AT02257478T patent/ATE350452T1/de not_active IP Right Cessation
- 2002-10-29 EP EP02257478A patent/EP1416038B1/de not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9487742B2 (en) | 2012-09-10 | 2016-11-08 | The Clorox Company | Drain formulation for enhanced hair dissolution |
| US10208273B2 (en) | 2012-09-10 | 2019-02-19 | The Clorox Company | Drain formulation for enhanced hair dissolution |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE350452T1 (de) | 2007-01-15 |
| EP1416038A1 (de) | 2004-05-06 |
| DE60217358D1 (de) | 2007-02-15 |
| DE60217358T2 (de) | 2007-05-16 |
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