EP1341736A2 - Plättchenförmige presskörper - Google Patents
Plättchenförmige presskörperInfo
- Publication number
- EP1341736A2 EP1341736A2 EP01986867A EP01986867A EP1341736A2 EP 1341736 A2 EP1341736 A2 EP 1341736A2 EP 01986867 A EP01986867 A EP 01986867A EP 01986867 A EP01986867 A EP 01986867A EP 1341736 A2 EP1341736 A2 EP 1341736A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- mixture
- body according
- press body
- binder
- water content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 85
- 229910001868 water Inorganic materials 0.000 claims abstract description 73
- 239000000203 mixture Substances 0.000 claims abstract description 55
- 239000002594 sorbent Substances 0.000 claims abstract description 29
- 239000011230 binding agent Substances 0.000 claims abstract description 26
- 238000003825 pressing Methods 0.000 claims abstract description 22
- 235000012431 wafers Nutrition 0.000 claims description 44
- 238000001354 calcination Methods 0.000 claims description 30
- 239000010457 zeolite Substances 0.000 claims description 30
- 229910021536 Zeolite Inorganic materials 0.000 claims description 28
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 28
- 239000000440 bentonite Substances 0.000 claims description 23
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 23
- 229910000278 bentonite Inorganic materials 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 21
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 239000002706 dry binder Substances 0.000 claims description 5
- 238000001694 spray drying Methods 0.000 claims description 5
- 235000017343 Quebracho blanco Nutrition 0.000 claims description 3
- 241000065615 Schinopsis balansae Species 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- -1 fatty acid salts Chemical class 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 235000018553 tannin Nutrition 0.000 claims description 2
- 229920001864 tannin Polymers 0.000 claims description 2
- 239000001648 tannin Substances 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 1
- 229910021647 smectite Inorganic materials 0.000 claims 1
- 239000012798 spherical particle Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 12
- 239000002274 desiccant Substances 0.000 description 11
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 9
- 235000013539 calcium stearate Nutrition 0.000 description 9
- 239000008116 calcium stearate Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 230000007717 exclusion Effects 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 238000001179 sorption measurement Methods 0.000 description 8
- 239000000725 suspension Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000012080 ambient air Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Substances [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 235000019359 magnesium stearate Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229910000882 Ca alloy Inorganic materials 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910000281 calcium bentonite Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000009512 pharmaceutical packaging Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28042—Shaped bodies; Monolithic structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3035—Compressing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3042—Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/14—Colouring matters
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/20—Preparing or treating the raw materials individually or as batches for dry-pressing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/30—Drying methods
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
- C04B35/62655—Drying, e.g. freeze-drying, spray-drying, microwave or supercritical drying
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Definitions
- the invention relates to platelet-shaped pressed bodies (wafers) based on an inorganic sorbent and a binder, with a thickness of less than 700 ⁇ m, which are characterized by high mechanical strength and low brittleness and which are capable of inorganic and organic Effectively sorb gases or vapors.
- zeolite tablets are produced by mixing a zeolite, a binder and a lubricant and extruding the mixture. It is obviously tablets with the same dimensions in all directions.
- zeolite tablets for use as gas adsorbents is known, powdered and dried at 105 to 110 ° C zeolite mixed with 8.1 wt .-% bentonite powder and kneaded with a 4% aqueous urea solution. The mixture is tableted, dried and calcined at 510 ° C. The increase in compressive strength is due to the urea content.
- zeolite is mixed in the Na form with 25% by weight of clay, kneaded with water, extruded, calcined at 650 ° C., immersed in a calcium chloride solution, washed, at 110 ° C. dried and activated at 400 ° C.
- the tablets are used as desiccants.
- zeolite powder is mixed with kaolin and Na (or NH 4 -) hydroxyethyl cellulose, molded, dried and calcined at 650 ° C. in order to increase the strength of the zeolite tablets.
- deodorants are extruded by extruding zeolite powder or grains with calcium chloride or bentonite and water, whereupon the mixture is tabletted and the tablets are calcined.
- drying agents are produced by extruding a mixture of microporous particles (for example gypsum, cement, ceramic 'ulver) and an inorganic or organic filler, such as CaCl, LiCl, bentonite, zeolites, PVA or other water-soluble polymers , The mixture is tabletted and then cured.
- zeolite tablets are produced as drying agents using 20% sepiolite as a binder. The mixture is kneaded with water, tabletted, dried at 150 ° C. and calcined at 550 ° C. The tablets have an improved drying effect compared to bentonite tablets.
- the tablets produced according to the state of the art are unsuitable for use in confined spaces and under mechanical stress, since they are too thick and too heavy and, based on mass and surface area, have too little sorption power for harmful gases and vapors. With the methods and mixtures according to the prior art, brittle compacts are obtained which crumble in particular after firing.
- electroluminescent devices only function properly over a long period of time if a desiccant is present. This is due to the sensitivity of the electrodes, especially the cathodes, e.g. due to moisture (the cathodes are made of Ca or Mg alloys). That is why these devices are sealed as well as possible under protective gas.
- EP 500 382 A2 describes the use of a moisture absorber in an electroluminescent device.
- the drying agent in the form of a powder or small beads is applied to a black silicone resin coating.
- the desiccant is filled in a gas-permeable bag.
- the object of the present invention is to provide plate-shaped pressed bodies (wafers) based on an inorganic sorbent and an inorganic binder with a very small thickness (less than 700 ⁇ m) which, despite their small thickness, have great strength and thus in particular can be installed in electronic components in which only a limited space is available and which can be exposed to vibrations (eg electronic display devices in automobiles and mobile telephones).
- a very small thickness less than 700 ⁇ m
- platelet-shaped pressed bodies based on an inorganic sorbent and a binder with a thickness of less than 700 ⁇ m, which can be obtained by pressing a mixture consisting of or containing at least one inorganic sorbent, at least one binder, and optionally water and pressing aids, at a pressure of at least 70 MPa, the weight ratio of the dry sorbent and the dry binder in the mixture being between about 4 and 0.7 and the water content of the mixture, determined at 160 ° C., is between about 8 and 20%; and calcining the resulting green body at temperatures of at least about 500 ° C to ⁇ to substantially remove the total water content.
- the pressed bodies (wafers) according to the invention have high strength, low brittleness, high sorption speed and high sorption capacities with low mass. They show a low thermal expansion, no abrasion and can easily be colored by adding pigments during manufacture.
- the wafers according to the invention can be produced in automated processes in large numbers per unit of time. They are easy to handle and can be removed from a storage container, for example, using so-called “pick-and-place” machines and inserted into an electronic device.
- the wafers according to the invention are also capable of sorbing other gases (ammonia, amines, oxygen). Since they have a high sorption capacity, the electronic device in which they are used does not need to be completely airtight, i.e. the rate of diffusion for water vapor into the device may be greater than zero.
- a suitable material for sealing the device e.g. an epoxy resin
- the critical time by which this material must have reached its final lowest water vapor permeability can be extended by using the wafer.
- the inorganic sorbent is preferably a natural or artificial zeolite.
- other sorbents such as amorphous silica or aluminum hydroxide, and mixtures of two or more sorbents can also be used.
- any binder which appears suitable to a person skilled in the art in this field can be used as the binder.
- a smectitic clay in particular bentonite, is preferably used as the binder.
- inorganic binders eg aluminum oxide hydroxide (pseudo boehmite).
- organic binders based on carbohydrates or proteins can also be used, for example starch, cellulose derivatives (such as CMC or CEC), casein or synthetic polymers such as PVA, PVP or polyphenols or tannin-containing binders (quebracho). Mixtures of different binders can also be used.
- the thickness of the wafer is preferably not more than about 400 ⁇ m, in particular about 200 to 400 ⁇ m.
- the invention further relates to a method, in particular for the production of the pressed bodies defined above, which is characterized in that a mixture consisting of or comprising at least one inorganic sorbent, at least one binder, and optionally water and pressing aids at a pressure of at least approximately 70 MPa pressed, the weight ratio of the dry sorbent and the dry binder in the mixture being between approximately 4 and 0.7 and the water content of the mixture, determined at 160 ° C., being between approximately 8 and 20%; and calcined the green compact obtained at temperatures of at least about 500 ° C. until the total water content was largely removed.
- the desired water content of the mixture can be determined via the water content of the components (sorbent, binder) and / or additional water can be set.
- Zeolite A which is preferably used as sorbent, is available in powder form and has a water content of about 10 to 22%.
- the bentonite which is preferably used as a binder is available as a powder with a water content of about 10 to 20%.
- the bentonite used has a montmorillonite content of preferably> 80%, based on the dry state.
- the best results can be achieved when the mixture is pressed into the pressed body if the mixture does not contain large proportions, i.e. contains not more than about 15%, preferably not more than about 8%, and particularly preferably 0% of particles> 250 ⁇ m, preferably> 200 ⁇ m and particularly preferably> 150 ⁇ m, and the main proportion of the particles, i.e. at least 50%, preferably at least 60%, is greater than about 45 ⁇ m.
- a preferred process measure is that zeolite and bentonite powder are mixed in the desired ratio with so much water that the mixture can be granulated.
- An intensive mixer is preferably used for this.
- the amount of water that has to be added depends on the mixing ratio of zeolite and bentonite and the colloidal chemical properties of the bentonite used in each case and can easily be determined routinely by a person skilled in the art.
- the mixture is adjusted or dried to a water content of about 8 to 20%, the water content being determined at 160 ° C.
- the mixture is then comminuted to particle sizes ⁇ 250 ⁇ m, preferably ⁇ 200 ⁇ m, particularly preferably ⁇ 150 ⁇ m in accordance with the above information.
- the best results can be achieved when the mixture is pressed into the green compact if the particles of the mixture have at least for the most part a largely spherical character, as obtained, for example, by spray drying.
- a particularly preferred process measure is therefore zeolite. and slurrying bentonite powder in water to a pumpable suspension using a high-shear stirrer, such as an Ultra-Turrax stirrer, and spray-drying this by conventional methods.
- the water content of the mixture can be set to the preferred values between about 8 and 20% (the water content is determined at 160 ° C).
- the setting of the particle size distribution so that the mixture, as defined above, does not contain any larger proportions of particles> 250 ⁇ m, preferably> 200 ⁇ m and particularly preferably> 150 ⁇ m, and the main proportion of the particles is greater than approximately 45 ⁇ m can also be done by Corresponding control of the spray drying process and, if appropriate, subsequent process steps such as deagglomeration, sieving and sifting known as such in the prior art are carried out.
- the compact is formed from the mixture by applying a pressure of at least about 70 MPa.
- the preferred pressing pressure is about 100 to 1300 MPa.
- the mixture can be pressed in commercially available automatic presses, the type of which is known to the person skilled in the art.
- the compacts are calcined at about 500 to 900 ° C, preferably at about 650 ° C, until constant weight is achieved and the water content is largely removed.
- the application of pressure to the pressed bodies during the calcination is brought about by using a specially designed belt calcining device, with the belts being pressurized.
- the pressure can be applied to the compact during the calcination in any way, as long as the curvature of the compact is effectively prevented during the calcination on the one hand and the pressure does not damage the compact on the other.
- a pressure between 10 and 30,000 Pa, in particular between 100 and 5,000 Pa, can be used.
- a certain number of pressed bodies are stacked in tubes which, for example, consist of stainless steel or ceramic. These tubes preferably have bores, which the Allow water to escape during the calcination. This enables quick and even drying.
- the entire stack within the tube is subjected to a pressure sufficient to suppress the curvature of the pressed body during the calcination, but which does not lead to breakage, sticking together or sintering of the pressed body during this process step.
- this pressure is between about 10 and 30,000 Pa, in particular between 100 and 5.00.0 Pa.
- the wafers calcined according to the invention under pressure are flat and show no or only minimal curvature or curvature, which is a prerequisite for use in electroluminescent devices.
- the calcination temperature is approached or increased step by step in order to prevent the formation of cracks and cracks in the pressed bodies due to water escaping too quickly or unevenly.
- the compacts can also be calcined and cooled under vacuum, • which enables them to sorb even permanent gases such as oxygen.
- the compact can also contain coloring pigments, for example Fe 3 O 4 .
- the invention further relates to the use of the pressing bodies defined above as inserts in electronic devices or components, such as display devices, in particular in electroluminescent components, such as organic light-emitting diodes (LEDs). However, they can also be used in moisture sensitive liquid crystal display (LCD) devices.
- LCD moisture sensitive liquid crystal display
- These devices or components can be caused by inorganic or organic gases or vapors during the manufacture or during the Use are damaged in their function and have only a very small space for a sorbent due to their design.
- the electronic component can be significantly reduced in volume and cost.
- the wafers have a higher sorption capacity and speed for water vapor in the required temperature and humidity range within an electronic component.
- the volume of the material increases by 100% during the hydration reaction; Therefore, additional volume must be provided for the expansion of the desiccant within the component and a water vapor permeable film must be applied between BaO and the electroluminescent layer, which prevents contact between the expanding and possibly crumbling desiccant and the layer.
- the wafers show no change in volume when absorbing water vapor and remain mechanically stable, so that the provision of an additional expansion volume within the component and the application of a protective film can be dispensed with.
- BaO also has the disadvantage that it itself and its hydration products react strongly basic; it also heats it up very strongly when it absorbs moisture, and it tends to self-ignite if it comes into direct contact with organic compounds. This limits the choice of polymers for the above-mentioned protective film on very expensive, for example fluoropolymers, and thus increases the cost of the component. In addition, there are disposal problems with the use of BaO, since it is very difficult to disassemble, reuse and dispose of the individual parts of the electronic component as a harmful chemical.
- the compacts according to the invention can also be used for other purposes, e.g. as inserts in pharmaceutical packaging, since there is only a limited volume available to hold a desiccant.
- the compacts can be in any shape, e.g. be round, square, triangular or rectangular or also contain bores and / or recesses.
- the compacts according to the invention are dust-free and wear-resistant. They can be produced in large numbers per time unit in conventional press machines.
- Thickness 300 ⁇ 50 ⁇ m
- drop test serves as a measure of the compressive strength, whereby 100 calcined pressed bodies (round disks with a diameter of 27 mm) are dropped from a height of 1 m with the flat side down. The percentage of broken test specimens is determined.
- Thickness 300 ⁇ 50 ⁇ m
- Example 2 57 kg zeolite 4A (water content 20%), 42 kg bentonite (water content 12%) and 1 kg calcium stearate are mixed in an intensive mixer for 2 minutes. Then water is added until the viscosity rises sharply and mixing is continued for a further 4 minutes. The mixture is dried at 110 ° C. to a water content of 12% and then granulated (Stokes granulator) and sieved on a 250 ⁇ m sieve. 0.22 g of the material with a particle size ⁇ 250 ⁇ m are pressed to a wafer with a pressure of 72 MPa. The green wafers are processed as in Example 2:
- Thickness 300 ⁇ 50 ⁇ m
- Example 4 The procedure of Example 4 was repeated with the difference that the green wafers were calcined in vacuo.
- the calcined wafers had essentially the same product properties as the wafers of Example 4, but additionally showed an oxygen absorption capacity of about 5 ml / g (determined in a dry oxygen atmosphere).
- Thickness 300 ⁇ 50 ⁇ m
- Example 4 The procedure of Example 4 was repeated with the difference that the pressure applied during the pressing was 1200 MPa. The drop test showed 10% break. The reject rate was ⁇ 10%.
- Example 4 The procedure of Example 4 was repeated with the difference that 54 kg of zeolite 4A, 40 kg of bentonite, 5 kg of Fe3Ü4 and 1 kg of calcium stereate were used.
- the wafers obtained were colored dark and could be used as a contrast surface in an LED display.
- 0.17 g of this material is pressed at a pressure of 190 MPa to a wafer with a diameter of 20 mm, the water vapor partial pressure in the ambient air of the pressing tools being about 30 mbar.
- the green wafers are calcined at 650 ° C for three hours using pressure.
- 300 green wafers are stacked in perforated stainless steel tubes (height 120 mm, inner diameter 22 mm), and the stack is subjected to a pressure of 2550 Pa. After the calcination, the product was cooled and packaged with the exclusion of moisture.
- Thickness 300 ⁇ 50 ⁇ m
- 0.17 g of this material are pressed with a pressure of 210 MPa into a wafer from the 'diameter of 20 mm, wherein the water vapor partial pressure is mbar in the ambient air of the pressing tools about 17th
- the green wafers are made using Calcined pressure at 650 ° C for three hours.
- 300 green wafers are stacked in perforated stainless steel tubes (height 120 mm, inner diameter 22 mm) and the stack is subjected to a pressure of 2550 Pa. After the calcination, the product was cooled and packaged with the exclusion of moisture.
- Thickness 300 ⁇ 50 ⁇ m
- 0.17 g of this material is pressed at a pressure of 195 MPa to a wafer with a diameter of 20 mm, the water vapor partial pressure in the ambient air of the pressing tools being approximately 12 mbar and the pressing tools being periodically sprayed with magnesium stearate.
- the green wafers are calcined at 650 ° C for three hours using pressure.
- 300 green wafers are stacked in perforated stainless steel tubes (height 120 mm, inner diameter 22 mm) and the stack is subjected to a pressure of 2550 Pa. After the calci- nation was cooled and packaged with the exclusion of moisture.
- Thickness 300 ⁇ 50 ⁇ m
- Thickness 300 ⁇ 50 ⁇ m
- An organic electroluminescent component 1 (square, area 12.9 cm 2 ), as shown in Figure 1, is produced using a wafer (circular, diameter 27 mm) from Example 4. After the wafer 2 has been attached to the rear wall 3 of the component, this is attached to the glass substrate 5 of the component with the aid of an adhesive 4 and sealed as far as possible with the aid of an adhesive.
- a microscopic photograph (magnification 50 times) of the light-emitting part 6 (consisting of the anode 7, the light-emitting layer 8 and the cathode 9) of the component is then taken. This photograph shows no dark (non-luminous) spots that would indicate an attack on the cathode 9.
- the component is exposed to a temperature of 85 ° C and a relative humidity of 85% for 500 h.
- a microscopic photograph of the light-emitting part 6 of the component 1 is then taken again.
- a comparison of the two photographs shows that there are no dark spots that would indicate an attack on the cathode 9.
- An organic electroluminescent component 1 such as Example 9 is produced using BaO.
- a water-permeable Teflon film is used as a cover for the BaO, which is attached to the rear wall 3 of the component with the aid of a thin double-sided adhesive tape.
- the amount of BaO is adjusted so that the total mass of BaO, the Teflon film and the double-sided adhesive tape corresponds exactly to that of a wafer used in Example 9.
- Example 9 wrote, enlarged photographs of the light-emitting part taken before and after storage for 500 h at 85 ° C and 85% humidity. A comparison of the two photographs shows a clearly recognizable growth of dark spots, which indicate an attack on the cathode 9.
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- Optics & Photonics (AREA)
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Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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DE10065946 | 2000-12-12 | ||
DE10065946A DE10065946A1 (de) | 2000-12-12 | 2000-12-12 | Plättchenförmige Presskörper |
PCT/EP2001/014618 WO2002048025A2 (de) | 2000-12-12 | 2001-12-12 | Plättchenförmige presskörper |
Publications (1)
Publication Number | Publication Date |
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EP1341736A2 true EP1341736A2 (de) | 2003-09-10 |
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ID=7669555
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP01986867A Withdrawn EP1341736A2 (de) | 2000-12-12 | 2001-12-12 | Plättchenförmige presskörper |
Country Status (7)
Country | Link |
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EP (1) | EP1341736A2 (ja) |
JP (1) | JP4142951B2 (ja) |
KR (1) | KR100585542B1 (ja) |
CN (1) | CN1282623C (ja) |
AU (1) | AU2002238423A1 (ja) |
DE (1) | DE10065946A1 (ja) |
WO (1) | WO2002048025A2 (ja) |
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Publication number | Priority date | Publication date | Assignee | Title |
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DE19959957A1 (de) * | 1999-12-13 | 2001-06-21 | Sued Chemie Ag | Plättchenförmige Preßkörper |
US20050238803A1 (en) * | 2003-11-12 | 2005-10-27 | Tremel James D | Method for adhering getter material to a surface for use in electronic devices |
DE102004024676A1 (de) * | 2004-05-18 | 2005-12-15 | Süd-Chemie AG | Filmförmige sorbenshaltige Zusammensetzungen |
US8173995B2 (en) | 2005-12-23 | 2012-05-08 | E. I. Du Pont De Nemours And Company | Electronic device including an organic active layer and process for forming the electronic device |
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JPS60129139A (ja) * | 1983-12-16 | 1985-07-10 | Matsushita Electric Ind Co Ltd | ゼオライトフイルム |
JPH03203193A (ja) * | 1989-12-29 | 1991-09-04 | Sharp Corp | 薄膜elパネル |
JP2000268954A (ja) * | 1999-03-17 | 2000-09-29 | Matsushita Electric Ind Co Ltd | 発光素子 |
DE19959957A1 (de) * | 1999-12-13 | 2001-06-21 | Sued Chemie Ag | Plättchenförmige Preßkörper |
-
2000
- 2000-12-12 DE DE10065946A patent/DE10065946A1/de not_active Ceased
-
2001
- 2001-12-12 CN CNB018216048A patent/CN1282623C/zh not_active Expired - Fee Related
- 2001-12-12 AU AU2002238423A patent/AU2002238423A1/en not_active Abandoned
- 2001-12-12 WO PCT/EP2001/014618 patent/WO2002048025A2/de active IP Right Grant
- 2001-12-12 EP EP01986867A patent/EP1341736A2/de not_active Withdrawn
- 2001-12-12 KR KR1020037007820A patent/KR100585542B1/ko not_active IP Right Cessation
- 2001-12-12 JP JP2002549567A patent/JP4142951B2/ja not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
JP2004515443A (ja) | 2004-05-27 |
WO2002048025A2 (de) | 2002-06-20 |
KR20030067700A (ko) | 2003-08-14 |
WO2002048025A3 (de) | 2003-05-30 |
JP4142951B2 (ja) | 2008-09-03 |
KR100585542B1 (ko) | 2006-06-14 |
WO2002048025A8 (de) | 2003-01-09 |
AU2002238423A1 (en) | 2002-06-24 |
CN1484623A (zh) | 2004-03-24 |
DE10065946A1 (de) | 2002-06-13 |
CN1282623C (zh) | 2006-11-01 |
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