EP1339900A1 - Fibre a plusieurs composants - Google Patents

Fibre a plusieurs composants

Info

Publication number
EP1339900A1
EP1339900A1 EP01994700A EP01994700A EP1339900A1 EP 1339900 A1 EP1339900 A1 EP 1339900A1 EP 01994700 A EP01994700 A EP 01994700A EP 01994700 A EP01994700 A EP 01994700A EP 1339900 A1 EP1339900 A1 EP 1339900A1
Authority
EP
European Patent Office
Prior art keywords
acid
omega
sheath
monomers
polyamide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01994700A
Other languages
German (de)
English (en)
Other versions
EP1339900B1 (fr
Inventor
Paul-Michael Bever
Gerhard Conzelmann
Bernd-Steffen Von Bernstorff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to SI200130431T priority Critical patent/SI1339900T1/sl
Publication of EP1339900A1 publication Critical patent/EP1339900A1/fr
Application granted granted Critical
Publication of EP1339900B1 publication Critical patent/EP1339900B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2973—Particular cross section
    • Y10T428/2976—Longitudinally varying

Definitions

  • the present invention relates to a fiber comprising a core (I) made of a polymer running along the fiber and a sheath (II) surrounding this core (I) and chemically different from core (I), characterized in that sheath (II) on a Polyamide based, which contains a sterically hindered piperidine derivative (III) chemically bound to the polymer chain.
  • the present invention further relates to the use of such a fiber for the production of yarns, fabrics and carpets.
  • the yarn is produced in a manner known per se by melting the polyamide, spinning the polyamide into a fiber, drawing and texturing this fiber and, if appropriate, post-treating the fiber. This is usually followed by cabling and heat fixation of the yarn.
  • a high crimp is desirable in the production of carpets from such yarns, since with higher covering power of the yarn less yarn is required to cover a carpet.
  • the object of the present invention was to provide a fiber from which yarns with improved crimp can be produced.
  • the fiber contains a core (I) made of a polymer and running along the fiber.
  • Suitable polymers are advantageously those which are meltable and spinnable in the molten state, such as polyamides, polyesters, polyolefins, preferably polyamides, polyolefins, in particular polyamides.
  • Polyamides are understood to mean homopolymers, copolymers, mixtures and grafts of synthetic long-chain polyamides which, as an essential component, have recurring amide groups in the main polymer chain.
  • polyamides are nylon 6 (polycaprolactam), nylon 6.6 (polyhexamethylene adipamide), nylon 4.6 (polytetramethylene adipamide), nylon 6.10 (polyhexamethylene sebacamide), nylon 7 (polyenantholactam), nylon 11 (polyundecanolactam) , Nylon 12 (polydodecanolactam). These polyamides are known to have the generic name of nylon.
  • Polyamides also include those known as aramids (aromatic polyamides), such as poly-metaphenyle ⁇ isophthalamide (NOMEX ® fiber, US-A-3, 287, 324) or poly-para-phenyleneterephthalamide (KEVLAR ® fiber, US-A-3 , 671, 542).
  • aramids aromatic polyamides
  • poly-metaphenyle ⁇ isophthalamide NOMEX ® fiber, US-A-3, 287, 324
  • KEVLAR ® fiber US-A-3 , 671, 542
  • polyamides can be produced by two processes.
  • the amino and carboxyl end groups of the starting monomers or starting oligomers react with one another to form an amide group and Water.
  • the water can then be removed from the polymer mass.
  • the amino and amide end groups of the starting monomers or starting oligomers react with one another to form an amide group and ammonia.
  • the ammonia can then be removed from the polymer mass.
  • This polymerization reaction is usually referred to as polycondensation.
  • polyaddition The polymerization from lactams as starting monomers or starting oligomers is usually referred to as polyaddition.
  • Such polyamides can be prepared by methods known per se, as described, for example, in DE-A-14 95 198, DE-A-25 58 480, EP-A-129 196 or in: Polymerization Processes, Interscience, New York, 1977, p. 424-467, in particular pp.
  • monomers selected from the group consisting of lactams, omega-aminocarboxylic acids, omega-aminocarboxylic acid nitriles, omega-aminocarboxylic acid amides, omega-aminocarboxylic acid salts, omega-aminocarboxylic acid esters, equimolar mixtures Diamines and dicarboxylic acids, dicarboxylic acid / diamine salts, di-nitriles and diamines or mixtures of such monomers.
  • Monomers or oligomers of C 2 - to C 2 o ⁇ amino acid amides such as 6-aminocaproic acid amide, 11-aminoundecanoic acid amide and their dimers, trimers, tetramers, pentamers or hexamers,
  • Esters preferably C 1 -C 4 alkyl esters, such as methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, s-butyl ester, from C - to
  • 11-aminoundecanoic acid esters for example methyl 11-aminoundecanoic acid
  • Hexamethylenediamine with a C 2 - to C 2 o ⁇ > preferably C 2 - to -C 4 - aliphatic dicarboxylic acid or its mono- or dinitriles, such as sebacic acid,
  • Monomers or oligomers of a C 6 - to C 2 o ⁇ , preferably Z - to C ⁇ o - aromatic diamine, such as m- or p-phenylenediamine, with a Cg - to C 2 o _ / preferably C 9 - to C ⁇ 8 - arylaliphatic see Dicarboxylic acid or its derivatives, for example chlorides, such as o-, m- or p-phenylenediacetic acid, and also their dimers, trimers, tetramers, pentamers or hexamers,
  • Derivatives for example chlorides, such as 2,6-naphthalenedicarboxylic acid, preferably isophthalic acid or terephthalic acid, as well as their dimers, trimers, tetramers, pentamers or hexamers,
  • the lactam used is caprolactam
  • the diamine is tetramethylene diamine, hexamethylene diamine or mixtures thereof
  • the dicarboxylic acid is adipic acid, sebacic acid, dodecanedioic acid, terephthalic acid, isophthalic acid or mixtures thereof.
  • Caprolactam is particularly preferred as lactam, hexamethylene diamine as diamine and adipic acid or terephthalic acid or mixtures thereof as dicarboxylic acid.
  • starting monomers or starting oligomers which, when polymerized to give the polyamides nylon 6, nylon 6,6, nylon 4,6, nylon 6,10, nylon 6,12, nylon 7, nylon 11, nylon 12 or the aramids Poly-metaphenylene-isophthalamide or poly-paraphenylene-terephthalamide, in particular lead to nylon 6 or nylon 66.
  • one or more chain regulators can be used in the production of the polyamides.
  • Suitable chain regulators are advantageously compounds which have one or more, such as two, amino groups which are reactive in the formation of polyamide or one or more, such as two, carboxyl groups which are reactive in the formation of polyamide.
  • fibers are obtained in which the monomers used to prepare the polyamide of the core (I) have a higher number of amine groups or their equivalents used to form the polymer chain than carboxylic acid groups or their equivalents used to form the polymer chain.
  • fibers are obtained in which the monomers used to produce the polyamide of the core (I) have a higher number of carboxylic acid groups or their equivalents used to form the polymer chain than amine groups or their equivalents used to form the polymer chain.
  • Chain regulators which can advantageously be monocarboxylic acids, such as alkane carboxylic acids, for example acetic acid, propionic acid, such as benzene or naphthalene monocarboxylic acid, for example benzoic acid, dicarboxylic acids, such as C 4 -C 10 -alkanedicarboxylic acid, for example adipic acid, azelaic acid, sebacic acid, dodecanedioic acid, C 5 -C 8 -cycloalkanedicarboxylic acids, for example cyclohexane-1, 4-dicarboxylic acid, benzene or naphthalenedicarboxylic acid, for example terephthalic acid, isophthalic acid, naphthalene-2, 6-dicarboxylic acid, C 2 - to C 20 -, preferably C 2 - to C ⁇ 2 - Alkylamines, such as cyclohexylamine, C 6 - to Co
  • a chain regulator can advantageously be used in amounts of at least 0.01 mol%, preferably at least 0.05 mol%, in particular at least 0.2 mol%, based on 1 mol of acid amide groups of the polyamide.
  • a chain regulator can advantageously be used in amounts of at most 1.0 mol%, preferably at most 0.6 mol%, in particular at most 0.5 mol%, based on 1 mol of acid amide groups of the polyamide.
  • the polymerization or polycondensation is carried out by the process according to the invention in the presence of at least one pigment.
  • Preferred pigments are titanium dioxide, titanium dioxide preferably being in the anatase modification, or coloring compounds of an inorganic or organic nature.
  • the pigments are preferably added in an amount of 0 to 5 parts by weight, in particular 0.02 to 2 parts by weight, based in each case on 100 parts by weight of polyamide.
  • the pigments can be fed to the reactor with the starting materials or separately therefrom.
  • Polyolefins are understood to mean homopolymers, copolymers, mixtures and grafts of synthetic long-chain polyolefins which can be obtained by polymerization from olefinically unsaturated compounds, such as ethylene, propylene, styrene, acrylic acid and their esters, methacrylic acid and their esters, preferably propylene.
  • olefinically unsaturated compounds such as ethylene, propylene, styrene, acrylic acid and their esters, methacrylic acid and their esters, preferably propylene.
  • the fiber contains a sheath (II) surrounding the core (I), which contains a polyamide-based coating which contains a sterically hindered piperidine derivative (III) chemically bound to the polymer chain.
  • Polyamides are understood to mean homopolymers, copolymers, mixtures and grafts of synthetic long-chain polyamides which, as an essential component, have recurring amide groups in the main polymer chain.
  • polyamides are nylon 6 (polycaprolactam), nylon 6.6 (polyhexamethylene adipamide), nylon 4.6 (polytetramethylene adipamide), nylon 6.10 (polyhexamethylene sebacamide), nylon 6.12 (polyhexamethylene dodecanedioic acid amide) nylon 7 ( Polyenantholactam), nylon 11 (polyundecanolactam), nylon 12 (polydodecanolactam). These polyamides are known to have the generic name of nylon.
  • Polyamides also include those known as aramids (aromatic polyamides), such as poly-metaphenylene isophthalamide (NOMEX ® fiber, US-A-3 287.324) or poly-para-phenyleneterephthalamide (KEVLAR ® fiber, US-A-3, 671 , 542).
  • aramids aromatic polyamides
  • poly-metaphenylene isophthalamide NOMEX ® fiber, US-A-3 287.324
  • KEVLAR ® fiber US-A-3, 671 , 542
  • polyamides can be produced by two processes.
  • the amino and carboxyl end groups of the starting monomers or starting oligomers react with one another to form an amide group and Water.
  • the water can then be removed from the polymer mass.
  • the amino and amide end groups of the starting monomers or starting oligomers react with one another to form an amide group and ammonia.
  • the ammonia can then be removed from the polymer mass.
  • This polymerization reaction is commonly referred to as polycondensation.
  • polyaddition The polymerization from lactams as starting monomers or starting oligomers is usually referred to as polyaddition.
  • Such polyamides can be prepared by methods known per se, as described, for example, in DE-A-14 95 198, DE-A-25 58 480, EP-A-129 196 or in: Polymerization Processes, Interscience, New York, 1977, p. 424-467, in particular pp.
  • monomers selected from the group consisting of lactams, omega-aminocarboxylic acids, omega-aminocarboxylic acid nitriles, omega-aminocarboxylic acid amides, omega-aminocarboxylic acid salts, omega-aminocarboxylic acid esters, equimolar mixtures of diamines and dicarboxylic acids, dicarboxylic acid / diamine salts, di-nitriles and diamines or mixtures of such monomers.
  • Monomers or oligomers of C 2 - to C 2 o _ Amino Acid such as 6-aminocaproic, 11-Aminoundecan Textreamid and dimers, trimers, tetramers, pentamers or hexamers,
  • Esters preferably C 1 -C 8 -alkyl esters, such as methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, s-butyl ester, from C 2 - to C 2 o ⁇ , preferably C 3 - to C 3 .8 ⁇ aminocarboxylic acids, such as 6-aminocaproic acid esters, for example methyl 6-aminocaproic acid ester, 11-aminoundecanoic acid ester, for example methyl 11-aminoundecanoate,
  • Hexamethylenediamine with a C 2 - to C 2 o -, preferably C 2 - to C 3.4 - aliphatic
  • Dicarboxylic acid or its mono- or dinitriles, such as sebacic acid Dicarboxylic acid or its mono- or dinitriles, such as sebacic acid,
  • Hexamethylenediamine with a C 8 - to C 2 o -, preferably C 8 - to C 12 - aromatic dicarboxylic acid or its derivatives, for example chlorides, such as
  • 2, 6-naphthalenedicarboxylic acid preferably isophthalic acid or
  • terephthalic acid as well as their dimers, trimers, tetramers, pentamers or hexamers,
  • Monomers or oligomers of a C 6 - to C 2 o ⁇ preferably C 6 - to Cio ⁇ aromatic diamine, such as m- or p-phenylenediamine, with a C 9 - to C 2 o ⁇ ⁇ preferably Cg - to C ⁇ 8 - arylaliphatic see dicarboxylic acid or its derivatives, for example chlorides, such as o-, m- or p-phenylenediacetic acid, and their dimers, trimers, tetramers, pentamers or hexamers,
  • Derivatives for example chlorides, such as 2,6-naphthalenedicarboxylic acid, preferably isophthalic acid or terephthalic acid, as well as their dimers, trimers, tetramers, pentamers or hexamers,
  • the lactam used is caprolactam
  • the diamine is tetramethylene diamine, hexamethylene diamine or mixtures thereof
  • the dicarboxylic acid is adipic acid, sebacic acid, dodecanedioic acid, terephthalic acid, isophthalic acid or mixtures thereof.
  • Caprolactam is particularly preferred as lactam, hexamethylene diamine as diamine and adipic acid or terephthalic acid or mixtures thereof as dicarboxylic acid.
  • starting monomers or starting oligomers which, in the polymerization to give the polyamides nylon 6, nylon 6,6, nylon 4,6, nylon 6,10, nylon 6,12, nylon 7, nylon 11, nylon 12 or the aromatics Poly-metaphenylene-isophthalamide or poly-paraphenylene-terephthalamide, in particular lead to nylon 6 or nylon 66.
  • one or more chain regulators can be used in the production of the polyamides.
  • Compounds which have one or more, such as two, amino groups reactive in the formation of polyamides or one or more, such as two, carboxyl groups which are reactive in the formation of polyamines, are advantageously suitable as chain regulators.
  • fibers are obtained in which the monomers used to produce the polyamide of the core (I) have a higher number of amine groups or their equivalents used to form the polymer chain than carboxylic acid groups or their equivalents used to form the polymer chain.
  • Chain regulators which can advantageously be monocarboxylic acids, such as alkane carboxylic acids, for example acetic acid, propionic acid, such as benzene or naphthalene monocarboxylic acid, for example benzoic acid, dicarboxylic acids, such as C 4 -C 10 -alkanedicarboxylic acid, for example adipic acid, azelaic acid, sebacic acid, dodecanedioic acid,
  • monocarboxylic acids such as alkane carboxylic acids, for example acetic acid, propionic acid, such as benzene or naphthalene monocarboxylic acid, for example benzoic acid
  • dicarboxylic acids such as C 4 -C 10 -alkanedicarboxylic acid, for example adipic acid, azelaic acid, sebacic acid, dodecanedioic acid,
  • C 5 -C 8 cycloalkanedicarboxylic acids for example cyclohexane-1, 4-dicarboxylic acid, benzene or naphthalenedicarboxylic acid, for example terephthalic acid, isophthalic acid, naphthalene-2, 6-dicarboxylic acid, C 2 - to C 2 o - / preferably C 2 - to C ⁇ 2 - alkylamines, such as cyclohexylamine, C $ - to C 2 o -.
  • Cio ⁇ aromatic monoamines such as aniline, or C - to C 2 o -, preferably C 8 - to Cia - arylaliphatic monoamines, such as benzylamine, diamines, such as C 4 -C ⁇ o-alkanediamines, for example hexamethylenediamine.
  • Such chain regulators can carry substituents, such as halogens, for example fluorine, chlorine or bromine, sulfonic acid groups or their salts, such as lithium, sodium, potassium salts, or be unsubstituted.
  • substituents such as halogens, for example fluorine, chlorine or bromine, sulfonic acid groups or their salts, such as lithium, sodium, potassium salts, or be unsubstituted.
  • Sulfonated dicarboxylic acids in particular sulfoisophthalic acid, and one of their salts, such as alkali metal salts, for example lithium, sodium, potassium salts, preferably lithium or sodium salt, in particular lithium salt, are preferred.
  • a chain regulator can advantageously be used in amounts of at least 0.01 mol%, preferably at least 0.05 mol%, in particular at least 0.2 mol%, based on 1 mol of acid amide groups of the polyamide.
  • a chain regulator can advantageously be used in amounts of at most 1.0 mol%, preferably at most 0.6 mol%, in particular at most 0.5 mol%, based on 1 mol of acid amide groups of the polyamide.
  • jacket (II) contains a polyamide which contains a sterically hindered piperidine derivative (III) chemically bound to the polymer chain.
  • Preferred compounds (III) are those of the formula
  • R 1 stands for a functional group which is capable of amide formation with respect to the polymer chain of the polyamide of sheath (II), preferably a group - (NH) R 5 , where R 5 stands for hydrogen or C 1 -C 8 -alkyl, or a carboxyl group or a carboxyl derivative or a group - (CH 2 ) X (NH) R 5 , where X is 1 to 6 and R5 is hydrogen or -CC 8 alkyl, or a group - (CH 2 ) y COOH , where Y is 1 to 6, or a - (CH 2 ) y COOH acid derivative, where Y is 1 to 6, in particular a group -NH 2 ,
  • R 2 represents an alkyl group, preferably a C 1 -C 4 -alkyl group, such as methyl, ethyl, n-propyl, i-propyl, n-butyl, i-
  • R 3 is hydrogen, -CC 4 alkyl or OR 4 , wherein R 4 is
  • R 3 is hydrogen
  • the tertiary, in particular secondary, amino groups of the piperidine ring systems usually do not react because of steric hindrance.
  • Compound (III) can advantageously be used in amounts of at least 0.01 mol%, preferably at least 0.05 mol%, in particular at least 0.1 mol%, based on 1 mol of acid amide groups of the polyamide.
  • Compound (II) can advantageously be used in amounts of at most 0.8 mol%, preferably at most 0.6 mol%, in particular at most 0.4 mol%, based on 1 mol of amide groups of the polyamide.
  • the polymerization or polycondensation is carried out by the process according to the invention in the presence of at least one pigment.
  • Preferred pigments are titanium dioxide, titanium dioxide preferably being in the anatase modification, or coloring compounds of an inorganic or organic nature.
  • the pigments are preferably added in an amount of 0 to 5 parts by weight, in particular 0.02 to 2 parts by weight, based in each case on 100 parts by weight of polyamide.
  • the pigments can be fed to the reactor with the starting materials or separately therefrom.
  • Polyamides which can advantageously be used as sheath (II) and contain a sterically hindered piperidine derivative (III) chemically bound to the polymer chain are described, for example, in WO 95/28443, WO 97/05189, WO 98/50610, WO 99/46323, WO 99/48949, EP-A-822 275, EP-A-843 696 and the two German applications 10030515.6 and 10030512.1.
  • core (I) and jacket (II) are chemically different.
  • Core (I) and jacket (II) advantageously have a different content of sterically hindered piperidine derivative (III) chemically bound to the polymer chain, this content in core (I) preferably being smaller than in jacket (II), in particular this content, calculated in molar terms, in core (I) - is less than 50% of this content in coat (II).
  • core (I) has no sterically hindered piperidine derivative (III) chemically bound to the polymer chain.
  • the fibers can be produced in a manner known per se, for example in US Pat. Nos. 3, 803, 453, 5, 445, 884, 5, 477, 794, 5, 888, 651 , EP-A-410 415, EP-A-056 667.
  • the polymer for core (I) and the polyamide for sheath (II) can be produced separately, by means of a conveying device such as an extruder, in each case feeding a melt of the polymers to a spinning plate pack and spinning the fiber there, in particular by spinning tendons at a take-off speed of at least 4000 m / min.
  • a conveying device such as an extruder
  • sheath (II) to core (I) have a weight ratio in the range from 5:95 to 80:20, preferably 5:95 to 50:50, are advantageous.
  • Yarns, fabrics and carpets can be produced from the fibers according to the invention in a manner known per se, as already described at the beginning.
  • Polyamide 1 Ultramid ® UV 2603 C / BASF Aktiengesellschaft), unpigmented
  • Polyamide 3 Ultramid ® BS 700 (BASF Aktiengesellschaft), unpigmented Made up of the monomers 0.15% by weight propionic acid, the rest being caprolactam
  • Polyamide 4 Ultramid® BS 700 (BASF Aktiengesellschaft), pigmented. Made up of the monomers 0., 15% by weight propionic acid, 0.3% by weight palamide red color pigment, the rest being caprolactam
  • Fibers with a fineness of 2700 dtex and a round cross-section were produced from the polyamides according to Table 1, spun at a weight ratio of core (I) to sheath (II) of 70:30 and stretch-textured to obtain the data shown in the table.
  • the fibers according to the invention have better crimp than fibers according to the prior art which consist only of the material of sheath (II) (comparative example 1) or only of the material of core (I) (Comparative Example 2).

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Polyamides (AREA)
  • Multicomponent Fibers (AREA)
  • Carpets (AREA)
  • Woven Fabrics (AREA)

Abstract

L'invention concerne une fibre qui comporte un noyau (I), s'étendant le long de la fibre et constitué d'un polymère, et une gaine (II), chimiquement différente dudit noyau (I) et entourant ce dernier (I). L'invention est caractérisée en ce que ladite gaine (II) est à base d'un polyamide contenant un dérivé de pipéridine (III) stériquement empêché et chimiquement lié à la chaîne polymère.
EP01994700A 2000-11-23 2001-11-22 Fibre a plusieurs composants Expired - Lifetime EP1339900B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SI200130431T SI1339900T1 (sl) 2000-11-23 2001-11-22 Veckomponentno vlakno

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10058291A DE10058291A1 (de) 2000-11-23 2000-11-23 Mehrkomponenten-Faser
DE10058291 2000-11-23
PCT/EP2001/013576 WO2002042531A1 (fr) 2000-11-23 2001-11-22 Fibre a plusieurs composants

Publications (2)

Publication Number Publication Date
EP1339900A1 true EP1339900A1 (fr) 2003-09-03
EP1339900B1 EP1339900B1 (fr) 2005-08-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP01994700A Expired - Lifetime EP1339900B1 (fr) 2000-11-23 2001-11-22 Fibre a plusieurs composants

Country Status (23)

Country Link
US (1) US6811876B2 (fr)
EP (1) EP1339900B1 (fr)
JP (1) JP2004532357A (fr)
KR (1) KR20030062352A (fr)
CN (1) CN1211511C (fr)
AR (1) AR031476A1 (fr)
AT (1) ATE301736T1 (fr)
AU (1) AU2002224872A1 (fr)
BG (1) BG107776A (fr)
BR (1) BR0115544A (fr)
CA (1) CA2429318A1 (fr)
CZ (1) CZ20031427A3 (fr)
DE (2) DE10058291A1 (fr)
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HU (1) HUP0301533A3 (fr)
IL (1) IL155651A0 (fr)
MX (1) MXPA03004282A (fr)
MY (1) MY134169A (fr)
PL (1) PL362423A1 (fr)
SK (1) SK6122003A3 (fr)
TW (1) TW567201B (fr)
WO (1) WO2002042531A1 (fr)
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Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4596742A (en) * 1985-04-22 1986-06-24 Monsanto Company Partially oriented nylon yarn and process
US5168909A (en) * 1991-04-08 1992-12-08 Joyner Jr George R Combination golf club head cover and hand warmer
ES2118594T5 (es) * 1994-04-15 2007-04-16 Basf Aktiengesellschaft Poliamidas inherentemente estabilizadas frente la luz y frente al calor.
CA2214189C (fr) * 1997-01-10 2001-05-29 Basf Corporation Nouvelles fibres bicomposees a noyau de materiaux polymeres recycles et methodes de fabrication de ces fibres
US6136433A (en) * 1997-05-01 2000-10-24 Basf Corporation Spinning and stability of solution-dyed nylon fibers
DE19812135A1 (de) * 1998-03-20 1999-09-23 Basf Ag Inhärent licht- und hitzestabilisierte Polyamide mit verbesserter Naßechtheit
DE19854421B4 (de) * 1998-11-25 2006-11-02 Ems-Inventa Ag Verfahren zur Herstellung von Polyamid-6 für Spinnzwecke

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0242531A1 *

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TW567201B (en) 2003-12-21
HUP0301533A2 (hu) 2003-09-29
PL362423A1 (en) 2004-11-02
MXPA03004282A (es) 2003-08-19
US6811876B2 (en) 2004-11-02
HUP0301533A3 (en) 2005-11-28
DE50107073D1 (de) 2005-09-15
ES2247195T3 (es) 2006-03-01
AR031476A1 (es) 2003-09-24
CN1476495A (zh) 2004-02-18
CZ20031427A3 (cs) 2003-12-17
EP1339900B1 (fr) 2005-08-10
AU2002224872A1 (en) 2002-06-03
ATE301736T1 (de) 2005-08-15
KR20030062352A (ko) 2003-07-23
MY134169A (en) 2007-11-30
DE10058291A1 (de) 2002-05-29
SK6122003A3 (en) 2003-10-07
US20040028897A1 (en) 2004-02-12
WO2002042531A1 (fr) 2002-05-30
IL155651A0 (en) 2003-11-23
BR0115544A (pt) 2003-09-09
CA2429318A1 (fr) 2002-05-30
JP2004532357A (ja) 2004-10-21
ZA200304802B (en) 2004-09-06
BG107776A (bg) 2004-02-27
CN1211511C (zh) 2005-07-20

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