EP1327850A1 - Initiateur électropyrotechnique - Google Patents
Initiateur électropyrotechnique Download PDFInfo
- Publication number
- EP1327850A1 EP1327850A1 EP02290061A EP02290061A EP1327850A1 EP 1327850 A1 EP1327850 A1 EP 1327850A1 EP 02290061 A EP02290061 A EP 02290061A EP 02290061 A EP02290061 A EP 02290061A EP 1327850 A1 EP1327850 A1 EP 1327850A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- initiator according
- plastic
- subassembly
- height
- initiator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003999 initiator Substances 0.000 title claims abstract description 41
- 239000002360 explosive Substances 0.000 title description 2
- 239000004033 plastic Substances 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 238000003466 welding Methods 0.000 claims abstract description 11
- 239000004952 Polyamide Substances 0.000 claims description 11
- 229920002647 polyamide Polymers 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 4
- -1 polybutylene Polymers 0.000 claims description 4
- 229920001470 polyketone Polymers 0.000 claims description 4
- 229920001748 polybutylene Polymers 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B3/00—Blasting cartridges, i.e. case and explosive
- F42B3/10—Initiators therefor
- F42B3/195—Manufacture
Definitions
- the present invention relates to an initiator An electro.
- the initiator There are two main categories of initiator.
- the first uses "glass-to-metal crossing" type bases and the second to initiators with base or crossing type "plastic".
- the initiators belonging to the first category are often seen as synonymous with insurance hermeticity and infallible protection of the compositions pyrotechnics and / or explosives against the effects of extreme environments (humidity among others).
- glass-to-metal crossings are sensitive to mechanical and thermal stresses that can be applied during the different stages of their process assembly or during the assembly stages (crimping, welding, ...) said initiators to an application device civil pyrotechnics (for example, pretensioners, cushions inflatable for automotive safety), military or space.
- the initiators on plastic traverse suffer for their of a hermeticity problem related to the plastic material (for example, moisture-sensitive polyamide) selected for their realization or at their internal joints (by clipping, gluing ..) not waterproof.
- plastic material for example, moisture-sensitive polyamide
- the current initiators that they belong to one any of the above categories include usually several subassemblies to assemble making the total cost of such an expensive device.
- the initiators of the first category are significantly more expensive because the necessary preparation (surfacing, %) of said crossings "Glass-metal”.
- the objective of the present invention is to propose a electropyrotechnic initiator of plastic type, simple in its design and in its operating mode, compact and economic having excellent hermetic qualities.
- the electropyrotechnic initiator comprises a housing 1.
- This housing 1 comprises a first 2 and second 3 subsets.
- the first subset 2 comprises a wall 4 made of plastic integral with a bottom 5 also made of plastic, the first subassembly 2 being made in one piece.
- This first subassembly 2 is called a container.
- Said container 2 receives a pyrotechnic charge 6 by a dry loading process.
- the load 6 comprises at less a composition.
- the containing 2 receives a first composition 7 called secondary composition and a second composition 8 called primary composition.
- Each of the compositions of the load pyrotechnic 6 is mass loaded and is precompressed.
- the precompression is carried out with a pressure below 120 bar for the primary composition 8 and with a pressure greater than 150 bar for the composition 7.
- the final compression effort is ensured when the hermetic assembly of the first subassembly 2 with a second subassembly 3 comprising the electrical part of the initiator, said subset 3 being also called base.
- the assembly is performed by ultrasonic welding ensuring a extreme hermeticity.
- the first 7 and second 8 compositions are free of heavy metals in an effort to respect the environment. said compositions are also resistant to warming up caused by ultrasonic welding which is of the order of 260 ° C.
- the inner diameter D 1 of the first subassembly 2 is less than 5.6 mm.
- the adaptation of the interior volume of the container 2 to allow the loading of pyrotechnic compositions of different types and particle size is therefore ensured by the variation of the height of said container 2.
- the small inner diameter of the first subassembly 2 advantageously allows not to having to use an intermediate pyrotechnic container such as, for example, a ring attached to the base 3 to limit the pyrotechnic charge 6. This limitation of the pyrotechnic charge 6 also offers increased safety without risk to the reliability of pyrotechnic operation insofar as the thickness of the charged composition is sufficient.
- the second subassembly 3, the plastic base has a main axis 10 and is traversed by at least two pins 11, 12 in the direction of said axis 10.
- the pins 11, 12 are interconnected by an electrical bridge 13 on one face 14 of said subassembly 3.
- the electrical bridge 13 is of the resistive type.
- it is either a filament or a metal layer.
- the electrical bridge 13 is of the semiconductor type.
- Said face 14 is recessed symmetrically over a height H and a depth L so that the outer diameter of the portion of the second subassembly 3 having been recessed is D 2 .
- the height H is between 2 and 3 mm.
- the inside diameter D 1 of the first subset 2 is smaller than the outside diameter D 2 .
- these parts of the first 2 and second 3 subassemblies facing each other during ultrasonic welding, this difference in diameter between D 1 and D 2 ensures a maximum hermeticity and a sufficient dielectric strength for the insulation of the internal parts. conductors 11, 12 of the initiator.
- the weld joint 16 is a shear joint.
- the recessed face 14 of the second subassembly 3 also has a symmetrical recess 17 of height h and width 1 to form an elevation island of the electrical bridge, this ensuring a good intimacy between the electric bridge 13 and the primary composition 8.
- h is between 0.5 and 1.0 mm and the width l is between 0.2 and 0.8 mm.
- the second subset 3 is overmolded on pins 11, 12.
- - pin - feed means current for the initiator.
- the pins 11, 12 comprise electrodes.
- the electrodes are striated. These streaks 18 ensure not only a hermetic barrier of the initiator along the pins 11, 12 but they also facilitate the fixation of the plastic material during overmolding.
- the pins 11, 12 are son.
- the first 2 and second 3 subassemblies are made of the same plastic material to allow their assembly by ultrasonic welding.
- the plastic used to make the first 2 and second 3 subassemblies is a material with low moisture absorption.
- the plastic is a polyketone.
- the plastic is a polybutylene teraphthalate (PBT).
- the plastic material is a polyamide.
- polyamides that may be used according to the invention mention may be made of polyamides with low moisture uptake, and in particular the polyamide of formula: designated in this application by PA 6.12.
- FIG. 1 shows a 16 ultrasound solder joint that does not include a seal in shear but a semi-shear joint.
- the present pyrotechnic initiator can advantageously be used for the realization of application device civil, military and space pyrotechnics.
- the initiator in polyketone, it can advantageously be put in contact with or placed near vapors or liquids chemical products.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- General Engineering & Computer Science (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Air Bags (AREA)
- Conductive Materials (AREA)
- Push-Button Switches (AREA)
- Lighters Containing Fuel (AREA)
- Connections Effected By Soldering, Adhesion, Or Permanent Deformation (AREA)
Abstract
Description
- un premier sous-ensemble comprenant une paroi en plastique solidaire d'un fond également en plastique et formant un contenant,
- un deuxième sous-ensemble en plastique ayant un axe principal, traversé par au moins deux broches selon la direction dudit axe, lesdites broches étant reliées entre elles par un pont électrique sur une face dudit sous-ensemble, ladite face étant évidée symétriquement sur une hauteur H et une largeur L, ledit sous-ensemble formant une embase,
- l'assemblage hermétique des premier et deuxième sous-ensembles est réalisé par soudage ultrasons.
- le diamètre intérieur D1 du premier sous-ensemble est inférieur au diamètre externe D2 de la partie évidée du deuxième sous-ensemble,
- le joint de soudure ultrason est un joint en cisaillement,
- le joint de soudure ultrason est un joint en semi-cisaillement,
- la face évidée du deuxième sous-ensemble présente un évidement symétrique de hauteur h et de largeur l pour former un ílot de surélévation du pont électrique.
- le plastique utilisé pour réaliser le premier et deuxième sous-ensembles est un matériau à faible reprise d'humidité,
- le plastique est un polycétone,
- le plastique est un polybutylène teraphtalate (PBT),
- le plastique est un polyamide,
- le plastique est le polyamide PA 6.12,
- la charge pyrotechnique est déposée dans le premier sous-ensemble par un procédé de chargement à sec,
- chacune des compositions de la charge pyrotechnique est précompressée,
- la composition primaire est précompressée avec une pression inférieure à 120 bars et la composition secondaire avec une pression supérieure à 150 bars,
- la hauteur de vide h' est inférieure à la hauteur h+H, H étant la hauteur du talon de soudure et h la hauteur de l'ílot,
- le deuxième sous-ensemble est surmoulé sur les broches,
- les broches sont des électrodes,
- les électrodes sont striées.
- la figure 1 est une représentation schématique d'un initiateur de type plastique, selon l'invention;
- la figure 2 représente un contenant, premier sous-ensemble de l'initiateur électropyrotechnique, selon l'invention;
- la figure 3 représente une embase, deuxième sous-ensemble de l'initiateur électropyrotechnique, selon l'invention;
- la figure 4 est une représentation schématique d'un autre mode de réalisation du joint de soudure ultrason, selon l'invention;
Claims (17)
- Initiateur électropyrotechnique comportant un boítier (1) en matière plastique et une charge pyrotechnique (6), ladite charge (6) comprenant au moins une composition, caractérisé en ce que le boítier (1) comporte deux sous-ensembles :un premier sous-ensemble (2) comprenant une paroi (4) en plastique solidaire d'un fond (5) également en plastique et formant un contenant,un deuxième sous-ensemble (3) en plastique ayant un axe principal (10), traversé par au moins deux broches (11, 12) selon la direction dudit axe (10), lesdites broches (11, 12) étant reliées entre elles par un pont électrique (13) sur une face (14) dudit sous-ensemble (3), ladite face (14) étant évidée symétriquement sur une hauteur H et une largeur L, ledit sous-ensemble (3) formant une embase,et en ce que l'assemblage hermétique des premier (2) et deuxième (3) sous-ensembles est réalisé par soudage ultrasons.
- Initiateur selon la revendication 1, caractérisé en ce que le diamètre intérieur D1 du premier sous-ensemble (2) est inférieur au diamètre externe D2 de la partie évidée du deuxième sous-ensemble (3).
- Initiateur selon l'une des revendications 1 et 2, caractérisé en ce que le joint de soudure (16) ultrason est un joint en cisaillement.
- Initiateur selon l'une des revendications 1 et 2, caractérisé en ce que le joint de soudure (16) ultrason est un joint en semi-cisaillement.
- Initiateur selon l'une des revendications 1 à 4, caractérisé en ce que la face évidée (14) du deuxième sous-ensemble (3) présente un évidement (17) symétrique de hauteur h et de largeur 1 pour former un ílot de surélévation du pont électrique (13).
- Initiateur selon l'une des revendications 1 à 5, caractérisé en ce que le plastique utilisé pour réaliser le premier et deuxième sous-ensembles est un matériau à faible reprise d'humidité.
- Initiateur selon la revendication 6, caractérisé en ce que le plastique est un polycétone.
- Initiateur selon la revendication 6, caractérisé en ce que le plastique est un polybutylène teraphtalate (PBT).
- Initiateur selon la revendication 6, caractérisé en ce que le plastique est un polyamide.
- Initiateur selon la revendication 9, caractérisé en ce que le plastique est le polyamide PA 6.12.
- Initiateur selon l'une des revendications 1 à 10, caractérisé en ce que la charge pyrotechnique (6) est déposée dans le premier sous-ensemble (2) par un procédé de chargement à sec.
- Initiateur selon la revendication 11, caractérisé en ce que chacune des compositions (7, 8) de la charge pyrotechnique (6) est précompressée.
- Initiateur selon la revendication 12, caractérisé en ce que la composition primaire (8) est précompressée avec une pression inférieure à 120 bars et la composition secondaire (7) avec une pression supérieure à 150 bars.
- Initiateur selon l'une des revendications 1 à 13, caractérisé en ce que la hauteur de vide h' est inférieure à la hauteur h+H, H étant la hauteur du talon de soudure, et h la hauteur de l'ílot.
- Initiateur selon l'une des revendications 1 à 14, caractérisé en ce que le deuxième sous-ensemble (3) est surmoulé sur les broches (11, 12).
- Initiateur selon la revendication 15, caractérisé en ce que les broches (11, 12) comprennent des électrodes.
- Initiateur selon la revendication 16, caractérisé en ce que les électrodes sont striées.
Priority Applications (17)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02290061A EP1327850B1 (fr) | 2002-01-10 | 2002-01-10 | Initiateur électropyrotechnique et procédé d'assemblage |
| AT02290061T ATE326679T1 (de) | 2002-01-10 | 2002-01-10 | Pyrotechnischer elektrischer anzünder und montageverfahren |
| ES02290061T ES2261605T3 (es) | 2002-01-10 | 2002-01-10 | Iniciador electropirotecnico. |
| DE60211462T DE60211462T2 (de) | 2002-01-10 | 2002-01-10 | Pyrotechnischer elektrischer Anzünder und Montageverfahren |
| CZ2004-794A CZ304930B6 (cs) | 2002-01-10 | 2003-01-10 | Elektrický pyrotechnický iniciátor |
| PL371132A PL203293B1 (pl) | 2002-01-10 | 2003-01-10 | Zapalnik elektro-pirotechniczny i sposób montażu zapalnika elektro-pirotechnicznego |
| US10/501,237 US7293504B2 (en) | 2002-01-10 | 2003-01-10 | Electro-pyrotechnic initiator |
| TW092100506A TWI282403B (en) | 2002-01-10 | 2003-01-10 | Electropyrotechnic initiator |
| HU0500019A HUP0500019A2 (hu) | 2002-01-10 | 2003-01-10 | Villamos pirotechnikai iniciáló gyutacs, valamint eljárás annak összeszerelésére |
| KR1020047010757A KR100916824B1 (ko) | 2002-01-10 | 2003-01-10 | 전자불꽃 기폭제 |
| AU2003214308A AU2003214308A1 (en) | 2002-01-10 | 2003-01-10 | Electro-pyrotechnic initiator |
| CA002472652A CA2472652A1 (fr) | 2002-01-10 | 2003-01-10 | Initiateur electropyrotechnique |
| PCT/FR2003/000080 WO2003058154A1 (fr) | 2002-01-10 | 2003-01-10 | Initiateur electropyrotechnique. |
| JP2003558418A JP4295115B2 (ja) | 2002-01-10 | 2003-01-10 | 電気式ロケット点火装置 |
| MXPA04006624A MXPA04006624A (es) | 2002-01-10 | 2003-01-10 | Iniciador electropirotecnico. |
| CNB038021331A CN100365374C (zh) | 2002-01-10 | 2003-01-10 | 电烟火起爆器 |
| ZA200405412A ZA200405412B (en) | 2002-01-10 | 2004-07-07 | Electro-pyrotechnic initiator. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02290061A EP1327850B1 (fr) | 2002-01-10 | 2002-01-10 | Initiateur électropyrotechnique et procédé d'assemblage |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1327850A1 true EP1327850A1 (fr) | 2003-07-16 |
| EP1327850B1 EP1327850B1 (fr) | 2006-05-17 |
Family
ID=8185696
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02290061A Expired - Lifetime EP1327850B1 (fr) | 2002-01-10 | 2002-01-10 | Initiateur électropyrotechnique et procédé d'assemblage |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US7293504B2 (fr) |
| EP (1) | EP1327850B1 (fr) |
| JP (1) | JP4295115B2 (fr) |
| KR (1) | KR100916824B1 (fr) |
| CN (1) | CN100365374C (fr) |
| AT (1) | ATE326679T1 (fr) |
| AU (1) | AU2003214308A1 (fr) |
| CA (1) | CA2472652A1 (fr) |
| CZ (1) | CZ304930B6 (fr) |
| DE (1) | DE60211462T2 (fr) |
| ES (1) | ES2261605T3 (fr) |
| HU (1) | HUP0500019A2 (fr) |
| MX (1) | MXPA04006624A (fr) |
| PL (1) | PL203293B1 (fr) |
| TW (1) | TWI282403B (fr) |
| WO (1) | WO2003058154A1 (fr) |
| ZA (1) | ZA200405412B (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006106257A1 (fr) * | 2005-04-04 | 2006-10-12 | Davey Bickford | Initiateur electropyrotechnique de technologie plastique modulable |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1504047B1 (fr) * | 2002-05-03 | 2007-12-12 | Janssen Pharmaceutica N.V. | Microemulsions polymeres |
| FR2861389B1 (fr) * | 2003-10-22 | 2006-03-10 | Davey Bickford | Composition pyrotechnique faiblement sensible a l'electricite statique et aux ultrasons. |
| FR2885684B1 (fr) * | 2005-05-10 | 2012-04-27 | Davey Bickford | Initiateur electrique a structure plastique et fonctionnement rapide et generateur de gaz comportant un tel initiateur |
| DE102005058721A1 (de) * | 2005-12-08 | 2007-06-14 | Trw Airbag Systems Gmbh | Pyrotechnische Aktuatoreinheit sowie Gassackmodul mit einer solchen Akruatoreinheit |
| AU2009308168B2 (en) * | 2008-10-24 | 2014-10-30 | Battelle Memorial Institute | Electronic detonator system |
| DE102012010608B4 (de) * | 2012-05-16 | 2025-02-13 | Zf Airbag Germany Gmbh | Anzünder und Verfahren zur Herstellung eines Anzünders für einen Gasgenerator |
| DE102018218001B4 (de) * | 2018-10-22 | 2021-09-30 | Schott Ag | Verfahren zur Herstellung eines Anschlussstiftes für Durchführungen, sowie Anschlussstift |
| RU2723364C1 (ru) * | 2019-10-31 | 2020-06-10 | Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" (Госкорпорация "Росатом) | Способ изготовления электродетонатора |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5423261A (en) * | 1992-12-01 | 1995-06-13 | Giat Industries | Pyrotechnic trigger |
| US5648634A (en) * | 1993-10-20 | 1997-07-15 | Quantic Industries, Inc. | Electrical initiator |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5235915A (en) * | 1992-05-26 | 1993-08-17 | Stevens Robert D | Shotgun slug tracer round and improved shotgun slug |
| US5728964A (en) * | 1993-10-20 | 1998-03-17 | Quantic Industries, Inc. | Electrical initiator |
| US5479861A (en) * | 1994-01-03 | 1996-01-02 | Kinchin; Anthony E. | Projectile with sabot |
| US5932832A (en) * | 1996-04-15 | 1999-08-03 | Autoliv Asp, Inc. | High pressure resistant initiator with integral metal oxide varistor for electro-static discharge protection |
-
2002
- 2002-01-10 ES ES02290061T patent/ES2261605T3/es not_active Expired - Lifetime
- 2002-01-10 AT AT02290061T patent/ATE326679T1/de active
- 2002-01-10 EP EP02290061A patent/EP1327850B1/fr not_active Expired - Lifetime
- 2002-01-10 DE DE60211462T patent/DE60211462T2/de not_active Expired - Lifetime
-
2003
- 2003-01-10 HU HU0500019A patent/HUP0500019A2/hu unknown
- 2003-01-10 JP JP2003558418A patent/JP4295115B2/ja not_active Expired - Lifetime
- 2003-01-10 CA CA002472652A patent/CA2472652A1/fr not_active Abandoned
- 2003-01-10 WO PCT/FR2003/000080 patent/WO2003058154A1/fr not_active Ceased
- 2003-01-10 CZ CZ2004-794A patent/CZ304930B6/cs not_active IP Right Cessation
- 2003-01-10 AU AU2003214308A patent/AU2003214308A1/en not_active Abandoned
- 2003-01-10 US US10/501,237 patent/US7293504B2/en not_active Expired - Lifetime
- 2003-01-10 TW TW092100506A patent/TWI282403B/zh not_active IP Right Cessation
- 2003-01-10 MX MXPA04006624A patent/MXPA04006624A/es active IP Right Grant
- 2003-01-10 PL PL371132A patent/PL203293B1/pl not_active IP Right Cessation
- 2003-01-10 CN CNB038021331A patent/CN100365374C/zh not_active Expired - Lifetime
- 2003-01-10 KR KR1020047010757A patent/KR100916824B1/ko not_active Expired - Lifetime
-
2004
- 2004-07-07 ZA ZA200405412A patent/ZA200405412B/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5423261A (en) * | 1992-12-01 | 1995-06-13 | Giat Industries | Pyrotechnic trigger |
| US5648634A (en) * | 1993-10-20 | 1997-07-15 | Quantic Industries, Inc. | Electrical initiator |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006106257A1 (fr) * | 2005-04-04 | 2006-10-12 | Davey Bickford | Initiateur electropyrotechnique de technologie plastique modulable |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1327850B1 (fr) | 2006-05-17 |
| ZA200405412B (en) | 2005-10-11 |
| US7293504B2 (en) | 2007-11-13 |
| HUP0500019A2 (hu) | 2005-06-28 |
| CN100365374C (zh) | 2008-01-30 |
| PL203293B1 (pl) | 2009-09-30 |
| JP4295115B2 (ja) | 2009-07-15 |
| US20050081731A1 (en) | 2005-04-21 |
| CZ2004794A3 (cs) | 2005-03-16 |
| CN1615425A (zh) | 2005-05-11 |
| DE60211462T2 (de) | 2007-04-26 |
| MXPA04006624A (es) | 2005-03-31 |
| DE60211462D1 (de) | 2006-06-22 |
| PL371132A1 (en) | 2005-06-13 |
| ATE326679T1 (de) | 2006-06-15 |
| ES2261605T3 (es) | 2006-11-16 |
| CZ304930B6 (cs) | 2015-01-28 |
| CA2472652A1 (fr) | 2003-07-17 |
| JP2005514578A (ja) | 2005-05-19 |
| WO2003058154A1 (fr) | 2003-07-17 |
| KR20040101203A (ko) | 2004-12-02 |
| AU2003214308A1 (en) | 2003-07-24 |
| TW200305708A (en) | 2003-11-01 |
| TWI282403B (en) | 2007-06-11 |
| KR100916824B1 (ko) | 2009-09-14 |
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