EP1315688A2 - Method of improving the crushing strength and the impact resistance of urea, and urea composition - Google Patents

Method of improving the crushing strength and the impact resistance of urea, and urea composition

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Publication number
EP1315688A2
EP1315688A2 EP01975023A EP01975023A EP1315688A2 EP 1315688 A2 EP1315688 A2 EP 1315688A2 EP 01975023 A EP01975023 A EP 01975023A EP 01975023 A EP01975023 A EP 01975023A EP 1315688 A2 EP1315688 A2 EP 1315688A2
Authority
EP
European Patent Office
Prior art keywords
urea
additive
group
amount
salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01975023A
Other languages
German (de)
French (fr)
Inventor
John Van Der Hoeven
Johannes Joseph Noordover
Erik Alexander Bijpost
Arjen Wim Velzel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Holland Novochem BV
Original Assignee
Holland Novochem BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Holland Novochem BV filed Critical Holland Novochem BV
Publication of EP1315688A2 publication Critical patent/EP1315688A2/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/02—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
    • C07C273/14—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C9/00—Fertilisers containing urea or urea compounds
    • C05C9/005—Post-treatment

Definitions

  • the invention relates to a method of improving the crushing strength and impact resistance of urea granules by the addition of an additive to the urea, comprising a polyvinyl compound.
  • an additive to the urea comprising a polyvinyl compound.
  • urea present in the form of prills and granulate urea is subject to crushing during production, storage and transport. Up to 25 wt% of the urea granules may be crushed if the urea granules are moved into a storage tank or storage ship at a relatively high temperature of e.g. more than 40°C.
  • Formaldehyde, hexamethylenetetramine and formaldehyde/ urea condensate products are known as crushing strength improvers, while poly (vinylacetate) /surfactant is used as a moisture resistance improver. All these additives must either be added in relatively large quantities, or the toxic characteristics make them difficult to handle. Moreover, the use of a surface-active component as in poly (vinylacetate) /surface- active agent, results in increased foaming when the urea is used for industrial applications, such as glue, whilst formaldehyde derivatives are unsuitable in the case of melamine production.
  • Formol compounds and the compositions according to the invention are admixed to a urea melt.
  • the polyvinyl/surface-active agent is nevertheless atomized onto a preformed granule.
  • GB-A-1217106 describes a method of reducing the caking of urea by making use of a poly(vinyl alcohol) having a high molecular weight as an anticaking additive. More in particular, according to this method, an aqueous solution of the additive is admixed to an aqueous solution of urea. Preferentially, an amount of additive of from 0.005 to 5 wt%, based on the weight of the urea, is admixed.
  • the concentration of the aqueous urea solution is initially 80%, according to the example given; after admixture of the solution of the additive, concentration up to 95% takes place at elevated temperature, after which the urea is allowed to crystallize by cooling.
  • PVA as an anticaking additive makes little sense, however, since unstructured urea granules exhibit no caking tendency. Moreover, the large amount of water present and the admixed amount of aqueous PVA cause serious problems in the production process of urea, since all the water has to be evaporated from the urea prior to storage and transport of the granules .
  • biuret An undesirable by-product of urea is biuret which is toxic to plants and animals .
  • the maximum permitted concentration of biuret is 0.75%. Nevertheless, as the residence time of the urea in the production process increases (mainly due to the evaporation of water) , the biuret content will be higher.
  • the invention therefore relates to a method of the type mentioned in the preamble which is characterized in that a urea melt is admixed with an aqueous solution of a urea additive, comprising a polyvinyl compound of the general formula
  • n is a number from 4-10 000
  • X and Y independently pf one another are selected from the group consisting of a hydrogen atom or a polar, organic group, in such a way that the admixed amount of water is at most 5 wt%, based on the amount of urea, after which the mixture obtained is concentrated to dryness .
  • the additive is admixed in an amount of at most 10 000 ppm, based on the rate of urea, to a melt of urea, with the option of adjusting the melting temperature by the admixture of a small amount of water, after which the melt obtained is concentrated, usually at 100-140°C. This afforded considerable improvements in the crushing strength and impact resistance, in conjunction with the use of relatively small amounts of the additive, said additive as such not being toxic and therefore being readily handled.
  • the starting point according to the process described in GB-A-1217106 is a solution of urea in water, with a urea concentration of at most 95 wt%; according to the invention, in contrast, the starting point is a urea melt, to which at most 5 wt% of water is admixed.
  • a polyvinyl compound having an ester group is a poly (vinyl ester) which can be an acetate ester of an unhydrolysed poly (vinyl alcohol) .
  • a polyvinyl compound having a hydroxyl group is a poly (vinyl alcohol) .
  • An example of a polyvinyl compound having an amide group, i.e. a poly (vinylamide) is a polyacrylamide; and an example of a polyvinyl compound having a carboxylic acid group, i.e. a poly (vinylcarboxylic acid), is a poly(maleic acid) .
  • the additive chosen is such that the viscosity of a 4% strength solution of the additive in water is between 2 and
  • centipoise 100 centipoise, more preferably between 4 and 70 centipoise, at 20°C.
  • the additive is employed with the aid of an aqueous solution having a concentration of between 0.5 and 25 wt%, more preferably between 1 and 20 wt%.
  • an aqueous solution of the urea additive having a concentration of from 100 to 10 000 ppm, preferably from 500 to 3 000 ppm, is used.
  • the invention also relates to a composition
  • a composition comprising a mixture of urea and poly (vinyl alcohol) whose solidification point is from 5 to 15°C, in particular from 10 to 15°C, below the solidification point of urea.
  • Applicant found, according to a second aspect of the present invention, that the addition of salt (s) to the urea melt, besides the polyvinyl compound, has a favourable effect to the compressibility of the urea granules to be formed, which means that the compressibility of the granules is lowered.
  • This salt (or these salts) can be added separately to the molten urea as an aqueous solution, or together with the aqueous solution of the polyvinyl compound.
  • the amount of water to be added in total may nevertheless not be more than 5 % b.w., based on the amount of urea.
  • the compressibility of granules is a quantity which indicates whether the form of the granules is contained after a certain (storage) period or that there is talk of flattening or other deformation.
  • Urea granules which have a small compressibility are highly desirable for the use of urea, in an industrial scale, in other processes.
  • the hardness is nevertheless a quantity, which is measured by applying a large force to the material until fracture takes place .
  • clays and powders are used. Clays and powders are nevertheless difficult to be handled during the production of urea. Besides, it is due to the bad solubility in the urea melt often impossible to obtain a good dispersion of the additive in the urea.
  • a salt is used according to the invention, whereof the cation is chosen from among the group, consisting of ammonium and the elements from the groups I, II and III of the Periodical System.
  • the elements sodium, calcium, magnesium and aluminium are used.
  • Other elements, such as for example potassium or strontium, from these groups can nevertheless also be used.
  • the anion of the salt is selected from the group, consisting of oxide, hydroxide, phosphate, sulphate, nitrate and acetate, preferably sulphate.
  • the total added amount of salt(s) is at most 10 % b.w., based on the total amount of urea.
  • the present application relates to a intimate mixture of urea, a polyvinyl compound and a salt of an inorganic or organic acid, whereby the compressibility of the composition is lower than that of the urea being free of additive.
  • the polyvinyl compound is a polyvinylalcohol.
  • EXAMPLES To demonstrate the effect of the invention, a number of experiments were carried out, employing a method which is representative for production and for testing the quality of the urea granules produced. PREPARATION METHOD
  • a urea melt was admixed with an aqueous solution of the additive (of the concentrations specified in the experiments) .
  • the urea prills were then formed by allowing molten urea droplets to descend in aliphatic oil having a viscosity of from 10 to 50 centipoise at 80°C. After crystallization the prills were taken from the oil and washed with chloroform to remove the oil. The prills can then be screened in order to obtain a particular size.
  • the prills were then dried in a fluidized bed for 1 hour at about 40°C. They were then collected and kept in an airtight flask until the crushing strength and the impact resistance were measured.
  • the crushing strength was measured via the IFDC.S-115 method.
  • the impact resistance was measured via the IFDC.S-118 method.
  • the solidification temperature of the urea samples was measured by the urea melt in question being cooled slowly, but in a controlled manner, in a calorimeter. This was done at a rate of 1°C per minute within the range from 140 to 60°C.
  • Polyvinyl compounds were found to result in an improvement in both the crushing strength and the impact resistance, compared with blank material. Among all the compounds tested, the polyvinyl compounds were found to result in a considerable improvement compared with customary additives such as urea/formaldehyde condensate, HMT and lignosulphonates . EXPERIMENT 2;
  • the viscosity was determined of a 4% (w/w) strength solution of the poly (vinyl alcohol) in water at 20 °C.
  • the effect of the dose of the additive in urea was tested.
  • the tested solution of the additive consisted of an 8% (w/w) strength solution of the poly (vinyl alcohol) from test No . 3 in Experiment 2.
  • a transparent round tube having an inner diameter of 3 cm was filled with 40 g urea pellets. Onto this a plunger was brought, through which a pressure of about 600 kPa was exerted onto the sample. Directly after the application of the overpressure and again after 24 hours the height of the urea column was measured. The relative difference in height, which is a measure for the compressibility, was calculated from these two values ( ⁇ height (%) ) .

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Fertilizers (AREA)
  • Disintegrating Or Milling (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention relates to a method of improving the crushing strength and impact resistance of urea granules by the addition of an additive comprising a polyvinyl compound of the general formula (CHX-CHY)n, where n = 4-10 000, and X and Y independently of one another are selected from the group consisting of a hydrogen atom, a hydroxyl radical, carboxylic acid radical, amine radical or amide radical. This method is characterized in that it starts with a urea melt.

Description

Short title: Method of improving the crushing strength and the impact resistance of urea, and urea composition
The invention relates to a method of improving the crushing strength and impact resistance of urea granules by the addition of an additive to the urea, comprising a polyvinyl compound. It is generally known that urea present in the form of prills and granulate urea is subject to crushing during production, storage and transport. Up to 25 wt% of the urea granules may be crushed if the urea granules are moved into a storage tank or storage ship at a relatively high temperature of e.g. more than 40°C.
Even though the urea granules as such do not absorb any moisture and are virtually nonsusceptible to caking, high percentages of crushed granules do lead to dust problems with a strong caking tendency. It is also known that a number of chemical compositions can be used as an additive to improve the crushing strength, the caking tendency and the resistance to moisture.
Formaldehyde, hexamethylenetetramine and formaldehyde/ urea condensate products are known as crushing strength improvers, while poly (vinylacetate) /surfactant is used as a moisture resistance improver. All these additives must either be added in relatively large quantities, or the toxic characteristics make them difficult to handle. Moreover, the use of a surface-active component as in poly (vinylacetate) /surface- active agent, results in increased foaming when the urea is used for industrial applications, such as glue, whilst formaldehyde derivatives are unsuitable in the case of melamine production.
There is also a major difference with respect to the use of additives . Formol compounds and the compositions according to the invention are admixed to a urea melt. The polyvinyl/surface-active agent is nevertheless atomized onto a preformed granule.
GB-A-1217106 describes a method of reducing the caking of urea by making use of a poly(vinyl alcohol) having a high molecular weight as an anticaking additive. More in particular, according to this method, an aqueous solution of the additive is admixed to an aqueous solution of urea. Preferentially, an amount of additive of from 0.005 to 5 wt%, based on the weight of the urea, is admixed.
The concentration of the aqueous urea solution is initially 80%, according to the example given; after admixture of the solution of the additive, concentration up to 95% takes place at elevated temperature, after which the urea is allowed to crystallize by cooling.
The use of PVA as an anticaking additive makes little sense, however, since unstructured urea granules exhibit no caking tendency. Moreover, the large amount of water present and the admixed amount of aqueous PVA cause serious problems in the production process of urea, since all the water has to be evaporated from the urea prior to storage and transport of the granules .
The large amount of water that has to be evaporated again will therefore slow down the production process, i.e. a lesser production results.
An undesirable by-product of urea is biuret which is toxic to plants and animals . The maximum permitted concentration of biuret is 0.75%. Nevertheless, as the residence time of the urea in the production process increases (mainly due to the evaporation of water) , the biuret content will be higher.
It is therefore an object of the invention to provide a method by means of which urea having improved crushing strength and impact resistance is obtained and by means of which the abovementioned drawbacks are overcome. The invention therefore relates to a method of the type mentioned in the preamble which is characterized in that a urea melt is admixed with an aqueous solution of a urea additive, comprising a polyvinyl compound of the general formula
(CHX-CHY)n,
where n is a number from 4-10 000, and X and Y independently pf one another are selected from the group consisting of a hydrogen atom or a polar, organic group, in such a way that the admixed amount of water is at most 5 wt%, based on the amount of urea, after which the mixture obtained is concentrated to dryness .
The additive is admixed in an amount of at most 10 000 ppm, based on the rate of urea, to a melt of urea, with the option of adjusting the melting temperature by the admixture of a small amount of water, after which the melt obtained is concentrated, usually at 100-140°C. This afforded considerable improvements in the crushing strength and impact resistance, in conjunction with the use of relatively small amounts of the additive, said additive as such not being toxic and therefore being readily handled.
As explained hereinabove, the starting point according to the process described in GB-A-1217106 is a solution of urea in water, with a urea concentration of at most 95 wt%; according to the invention, in contrast, the starting point is a urea melt, to which at most 5 wt% of water is admixed.
Preferably, the additive used according to the invention is a polyvinyl compound of the general formula (CHX-CHY)n, where n is a number from 4 to 10 000, and X and Y independently of one another represent a hydrogen atom or a polar organic group, such as a carboxylic acid radical, ester radical, hydroxyl radical, amine radical, amide radical, more preferably the formula (CH2-CHY)n/ where n = 4-10 000, and Y = a hydrogen atom or a polar organic group, such as a carboxylic acid radical, ester radical, hydroxyl radical, amine radical, amide radical, more preferably the formula (CH2-CHY)n, where n = 4-10 000, and Y = a mixture of an acetate ester radical and hydroxyl group, preferably 70% or more hydroxyl group, more preferably the formula
(CH2-CHY)n, where n = 4-10 000, and Y = a mixture of an acetate ester radical and hydroxyl group, preferably more than 95% hydroxyl group .
An example to be mentioned of a polyvinyl compound having an ester group is a poly (vinyl ester) which can be an acetate ester of an unhydrolysed poly (vinyl alcohol) . One example of a polyvinyl compound having a hydroxyl group is a poly (vinyl alcohol) . An example of a polyvinyl compound having an amide group, i.e. a poly (vinylamide) , is a polyacrylamide; and an example of a polyvinyl compound having a carboxylic acid group, i.e. a poly (vinylcarboxylic acid), is a poly(maleic acid) .
In a preferred embodiment of the invention, the additive chosen is such that the viscosity of a 4% strength solution of the additive in water is between 2 and
100 centipoise, more preferably between 4 and 70 centipoise, at 20°C.
Preferably, the additive is employed with the aid of an aqueous solution having a concentration of between 0.5 and 25 wt%, more preferably between 1 and 20 wt%.
Preferably, an aqueous solution of the urea additive having a concentration of from 100 to 10 000 ppm, preferably from 500 to 3 000 ppm, is used.
The invention also relates to a composition comprising a mixture of urea and poly (vinyl alcohol) whose solidification point is from 5 to 15°C, in particular from 10 to 15°C, below the solidification point of urea.
The fact is that applicant has found, surprisingly, that the use of poly (vinyl alcohol) as a urea additive is able to effect a lowering of the solidification temperature of urea.
It is precisely this lowering which is very important and as such has never been observed with other additives for urea.
Applicant found, according to a second aspect of the present invention, that the addition of salt (s) to the urea melt, besides the polyvinyl compound, has a favourable effect to the compressibility of the urea granules to be formed, which means that the compressibility of the granules is lowered. This salt (or these salts) can be added separately to the molten urea as an aqueous solution, or together with the aqueous solution of the polyvinyl compound. The amount of water to be added in total may nevertheless not be more than 5 % b.w., based on the amount of urea.
It is observed that the compressibility of granules is a quantity which indicates whether the form of the granules is contained after a certain (storage) period or that there is talk of flattening or other deformation. Urea granules which have a small compressibility are highly desirable for the use of urea, in an industrial scale, in other processes.
Besides, it is observed that it is known as such from for example US-A-5 , 676, 729 and US-A-5 , 782 , 951 to add inorganic material to molten urea to improve the hardness of the urea particles to be formed.
The hardness is nevertheless a quantity, which is measured by applying a large force to the material until fracture takes place . Moreover, according to both abovementioned publications, clays and powders are used. Clays and powders are nevertheless difficult to be handled during the production of urea. Besides, it is due to the bad solubility in the urea melt often impossible to obtain a good dispersion of the additive in the urea.
Preferably, a salt is used according to the invention, whereof the cation is chosen from among the group, consisting of ammonium and the elements from the groups I, II and III of the Periodical System. Preferably, from this group the elements sodium, calcium, magnesium and aluminium are used. Other elements, such as for example potassium or strontium, from these groups can nevertheless also be used.
Expediently, the anion of the salt is selected from the group, consisting of oxide, hydroxide, phosphate, sulphate, nitrate and acetate, preferably sulphate.
According to a preferred embodiment, the total added amount of salt(s) is at most 10 % b.w., based on the total amount of urea.
Further the present application relates to a intimate mixture of urea, a polyvinyl compound and a salt of an inorganic or organic acid, whereby the compressibility of the composition is lower than that of the urea being free of additive.
Preferably the polyvinyl compound is a polyvinylalcohol. EXAMPLES To demonstrate the effect of the invention, a number of experiments were carried out, employing a method which is representative for production and for testing the quality of the urea granules produced. PREPARATION METHOD
A urea melt was admixed with an aqueous solution of the additive (of the concentrations specified in the experiments) . The urea prills were then formed by allowing molten urea droplets to descend in aliphatic oil having a viscosity of from 10 to 50 centipoise at 80°C. After crystallization the prills were taken from the oil and washed with chloroform to remove the oil. The prills can then be screened in order to obtain a particular size. The prills were then dried in a fluidized bed for 1 hour at about 40°C. They were then collected and kept in an airtight flask until the crushing strength and the impact resistance were measured. MEASURING METHOD
The crushing strength was measured via the IFDC.S-115 method.
The impact resistance was measured via the IFDC.S-118 method.
The solidification temperature of the urea samples was measured by the urea melt in question being cooled slowly, but in a controlled manner, in a calorimeter. This was done at a rate of 1°C per minute within the range from 140 to 60°C. EXPERIMENT 1;
The following additives were tested after the admixture of doses of 3 000 ppm to the urea.
Table 1
Polyvinyl compounds were found to result in an improvement in both the crushing strength and the impact resistance, compared with blank material. Among all the compounds tested, the polyvinyl compounds were found to result in a considerable improvement compared with customary additives such as urea/formaldehyde condensate, HMT and lignosulphonates . EXPERIMENT 2;
The effect of the degree of hydrolysis and the range of the value of n of the polyvinylalcohols were tested in this experiment .
3 000 ppm of a 2% (w/w) strength solution of a poly (vinyl alcohol) were admixed to the molten urea prior to prilling.
The viscosity was determined of a 4% (w/w) strength solution of the poly (vinyl alcohol) in water at 20 °C.
This experiment makes it clear that within a range of n = 4-10 000 a high degree of hydrolysis affords a considerable improvement both in crushing strength and impact resistance. EXPERIMENT 3:
The effect of the concentration of the ' active components in the additive.
This experiment made use of the poly (vinyl alcohol) of test No. 3 from Experiment 2. The dose of the additive was 3 000 ppm, based on the weight of the urea.
Table 3
Employing a dose of 3 000 ppm of an 8 to 12% (w/w) strength solution of poly (vinyl alcohol) therefore produces the optimal results in terms of crushing strength and impact resistance. EXPERIMENT 4:
The effect of the dose of the additive in urea was tested. The tested solution of the additive consisted of an 8% (w/w) strength solution of the poly (vinyl alcohol) from test No . 3 in Experiment 2.
Table 4
The optimum dose in urea was therefore found to be between 1 000 and 3 000 ppm, based on the weight of the urea. EXPERIMENT 5 Method of making pellets
An aqueous solution of the additive (having the concentrations indicated in the experiments) was added to an urea melt consisting of 99.7 w/w % urea and 0.3 w/w % water. Thereafter the urea pellets were formed by allowing the molten urea droplets to fall separately from a height of 1 cm onto a glass plate. After solidification the pellets were scraped from the glass plate and the fines where removed by means of a sieve. Then the pellets were collected and kept in an airtight bottle until the compressibility was measured. Method for the determination of the compressibility:
A transparent round tube having an inner diameter of 3 cm was filled with 40 g urea pellets. Onto this a plunger was brought, through which a pressure of about 600 kPa was exerted onto the sample. Directly after the application of the overpressure and again after 24 hours the height of the urea column was measured. The relative difference in height, which is a measure for the compressibility, was calculated from these two values (Δheight (%) ) .
Table 5
From the results mentioned in table 5 the favourable effect of the addition of a salt to the compressibility of the urea granulate appears clearly.

Claims

1. A method of improving the crushing strength and impact resistance of urea granules by the addition of an additive to the urea, consisting of a polyvinyl compound, characterized in that to a urea melt, an aqueous solution of a urea additive, consisting of a polyvinyl compound of the general formula (CHX-CHY)n, where n = 4-10 000, and X and Y independently of one another are selected from the group consisting of a hydrogen atom or a polar, organic group, is added in such a way that the added amount of water is at most 5 wt%, based on the amount of urea, after which the mixture obtained is concentrated to dryness .
2. A method according to claim 1, characterized in that an additive is used of the formula specified in claim 1, wherein the said polar organic group is selected from a carboxylic acid group, an ester group, a hydroxyl group, an amine group and an amide group .
3. A method according to claim 1 or 2, characterized in that a urea additive is added as described in claim 1 or 2, wherein X is a hydrogen atom and Y substantially consists of a hydroxyl group .
4. A method according to one or more of claims 1 to 3 , characterized in that at least 70%, preferably at least 95%, of
Y consists of a hydroxyl group.
5. A method according to one or more of claims 1 to 4 , characterized in that an additive is used, whereof the viscosity of a 4% strength solution of the additive in water is between 2 and 100 centipoise at 20°C.
6. A method according to claim 5, characterized in that an additive is used whereof the viscosity of a 4% strength solution of the additive in water is between 4 and 70 centipoise at 20°C.
7. A method according to one or more of claims 1 to 6, characterized in that an aqueous solution of the urea additive having a concentration of from 0.5 to 25 wt% is used.
8. A method according to one or more of claims 1 to 7, .characterized in that an aqueous solution of the urea additive having a concentration of from 1 to 20 wt% is used.
9. A method according to one or more of claims 1 to 8, characterized in that an aqueous solution of the urea additive having a concentration of from 100 to 10 000 ppm, preferably from 500 to 3 000 ppm, is used.
10. A composition consisting of an intimate mixture of urea and poly (vinyl alcohol) whose solidification point is from 5 to 15°C, in particular from 10 to 15°C, below the solidification point of the urea.
11. A composition according to claim 10, the composition containing at most 3 000 ppm of poly (vinyl alcohol) , based on the weight of the urea.
12. A method according to one or more of the claims 1 to 9 , characterized in that further a salt of an inorganic or organic acid is added to the urea melt, such that the total added amount' of water is at most 5 wt%, based on the amount of urea.
13. A method according to claim 12, characterized in that a salt is used whereof the cation is selected from the group, consisting of ammonium, and the elements from the groups I, II and III of the Periodical System, preferably the elements sodium, calcium, magnesium and aluminium from these groups.
14. A method according to claim 12 or 13, characterized in that a salt is' used, whereof the anion is selected from the group, consisting of oxide, hydroxide, phosphate, sulphate, nitrate and acetate, preferably sulphate.
15. A method according to one or more of the claims 12 to 14, characterized in that the amount of salt(s) to be added in total is at most 10 wt%, based on the amount of urea.
16. A composition consisting of an intimate mixture of urea, a polyvinyl compound and a salt of an inorganic of organic acid, the compressibility of the composition being lower than that of the urea being free of additive.
17. A composition according to claim 16, characterized in that the polyvinyl compound is polyvinylalcohol .
EP01975023A 2000-09-07 2001-09-07 Method of improving the crushing strength and the impact resistance of urea, and urea composition Withdrawn EP1315688A2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL1016123 2000-09-07
NL1016123 2000-09-07
PCT/NL2001/000663 WO2002020471A2 (en) 2000-09-07 2001-09-07 Method of improving the crushing strength and the impact resistance of urea, and urea composition

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Publication number Priority date Publication date Assignee Title
ES2391089T3 (en) 2003-10-06 2012-11-21 Yara International Asa Procedure to improve crush resistance, impact resistance and urea compressibility
NO321761B1 (en) * 2004-06-30 2006-07-03 Yara Int Asa Process for improving crushing strength and reducing dust formation and tendency to cook urea, particles, and use of carbohydrates and optionally polyvinyl compounds as additive to molten urea
RU2007130919A (en) * 2005-01-14 2009-02-20 Холланд Новохем Б.В. (Nl) METHOD FOR PRODUCING FREE FLUID GRANULATED PARTICLES FOR PLANT AUXILIARY

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Publication number Priority date Publication date Assignee Title
DE1916089A1 (en) * 1968-04-01 1969-12-18 Kurashiki Rayon Company Ltd Non-aggregating urea composition
DD131062A3 (en) * 1973-09-06 1978-05-31 Friedrich Wolf METHOD FOR PRODUCING STORAGE-RICH DYES
SU698967A1 (en) * 1978-01-06 1979-11-25 Предприятие П/Я А-1676 Method of producing non-caking urea
US4587358A (en) * 1985-08-26 1986-05-06 Tennessee Valley Authority Production of high-strength, storage-stable particulate urea

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Title
See references of WO0220471A3 *

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