EP1291463A1 - Procédé de préparation d'un feuille métallisée sélectivement, et le produit correspondant - Google Patents

Procédé de préparation d'un feuille métallisée sélectivement, et le produit correspondant Download PDF

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Publication number
EP1291463A1
EP1291463A1 EP02019580A EP02019580A EP1291463A1 EP 1291463 A1 EP1291463 A1 EP 1291463A1 EP 02019580 A EP02019580 A EP 02019580A EP 02019580 A EP02019580 A EP 02019580A EP 1291463 A1 EP1291463 A1 EP 1291463A1
Authority
EP
European Patent Office
Prior art keywords
layer
carrier substrate
paint
film
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP02019580A
Other languages
German (de)
English (en)
Other versions
EP1291463B1 (fr
Inventor
Friedrich Dr. Kastner
Martin Dr. Bergsmann
Roland Einsiedler
Johann Hillburger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hueck Folien GmbH
Original Assignee
Hueck Folien GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hueck Folien GmbH filed Critical Hueck Folien GmbH
Publication of EP1291463A1 publication Critical patent/EP1291463A1/fr
Application granted granted Critical
Publication of EP1291463B1 publication Critical patent/EP1291463B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0027After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30Identification or security features, e.g. for preventing forgery
    • B42D25/355Security threads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40Manufacture
    • B42D25/405Marking
    • B42D25/43Marking by removal of material
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06QDECORATING TEXTILES
    • D06Q1/00Decorating textiles
    • D06Q1/04Decorating textiles by metallising
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/40Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
    • D21H21/42Ribbons or strips
    • B42D2033/10

Definitions

  • the invention relates to a selectively metallized film, in particular for Use as a security element, especially in value documents, as well a method for producing the selectively metallized film.
  • EP-A 0 330 733 are security elements, in particular Security threads consisting of a translucent plastic film, a extending over the entire security element extending opaque Coating, the recesses in the form of the coding to be introduced, especially in the form of characters and patterns known. At least in the areas defined by the recesses can be congruent coloring and / or luminescent substances may be present, through which the coding of the opaque coating under appropriate The influence of light differs in a contrasting color.
  • security elements for use as security elements for value documents, in particular banknotes, identity documents and the like, it is necessary that these security elements, for example in thread or tape form as inconspicuous as possible in the carrier, in particular paper or the like, can be integrated. Therefore, it is necessary to strive for the smallest possible thickness of the security elements. Furthermore, however, at the same time a great precision in the dimensions of the recesses to be produced is necessary to ensure sufficient security against counterfeiting, since irregularities in the dimensions of the recesses forming a coding make it difficult to clearly establish the authenticity or any imitation. Furthermore, it is sometimes also desirable to register corresponding coatings and codings on both sides of the carrier substrate of the security element in order to ensure a mutual identification of the authenticity.
  • the object of the invention is therefore to metallized films and a method to To provide their preparation, the disadvantages described above avoids and in particular due to the small thickness and at the same time high precision are particularly suitable as security elements in Value documents to be integrated.
  • the task of Invention a metallized film and a method for their preparation to provide, the film is almost independent of the substrate structured layers of different metals, metal compounds, Alloys or insulators on one or both sides of the carrier substrate optionally, wherein the structured layers accurate registration should be produced.
  • the invention therefore provides a selectively metallized film by providing a carrier substrate, applying one in one Solvent-soluble partial paint application with recesses in the form of a (negative) coding, treating the printed carrier film by means of a Inline plasma, corona or flame process, applying a thin Covering layer of metals, metal compounds, alloys and / or Insulators and detachment of the paint by the action of a Solvent optionally combined with a mechanical action.
  • Another object is a method for producing a selectively metallized film, characterized in that on a carrier substrate in a first step, a paint application which is soluble in a solvent is applied to one or both sides of the carrier substrate in a second step, this layer is treated by means of an in-line plasma, corona or flame process, and in a third step, a layer of a material to be structured is applied, which layer may consist of metals, metal compounds, alloys or insulators, whereupon, in a fourth step, the paint application is removed by means of a solvent, optionally combined with a mechanical action.
  • carrier foils are preferably flexible plastic foils, for example, from Pl, PP, MOPP, PE, PPS, PEEK, PEK, PEI, PSU, PAEK, LCP, PEN, PBT, PET, PA, PC, COC, POM, ABS, PVC in question.
  • the carrier films preferably have a thickness of 5 to 700 .mu.m, preferably 8 to 200 .mu.m, more preferably 12 to 50 .mu.m.
  • metal foils for example Al, Cu, Sn, Ni, Fe or stainless steel foils having a thickness of 5-200 ⁇ m, preferably 10 to 80 ⁇ m, particularly preferably 20-50 ⁇ m, may also serve as the carrier substrate.
  • the films can also be surface-treated, coated or laminated, for example, with plastics or painted.
  • carrier substrates also paper or composites with paper, for example, composites with plastics with a grammage 20-500 g / m 2, preferably 40-200 g / m 2. be used.
  • nonwovens such as continuous fiber webs, staple fiber webs and the like, which may optionally be needled or calendered, can be used as carrier substrates.
  • nonwovens consist of plastics, such as PP, PET, PA, PPS and the like, but it is also possible to use nonwovens of natural, optionally treated fibers, such as viscose fiber webs.
  • the nonwovens used have a basis weight of about 20 g / m 2 to 500 g / m 2 .
  • the carrier substrates may additionally comprise a lacquer layer which unstructured or structured, for example can be embossed Die Paint layer, for example, an adhesive paint layer or a be releasable transfer lacquer layer, it can by radiation, For example, UV radiation, thermally or reactively crosslinked or crosslinkable and additional properties such as e.g. Scratch-resistant and / or antistatic Have equipment or chemical resistance.
  • Suitable are both aqueous and solvent-containing coating systems, in particular also Lacquer systems based on PE - acrylate, PET acrylate, urethane acrylate, PVC, PMMA or epoxy acrylate.
  • the carrier substrate can on one or both sides with a hot or Be provided cold seal adhesive or a self-adhesive coating.
  • the surface of the carrier substrate may be structured or unstructured, or for example, be embossed with micro or macrolines, that is on the Surface may optionally have two- or three-dimensional structures to be available.
  • the application of the paint can be done by any method, for example by gravure printing, flexographic printing, screen printing, digital printing and the like.
  • the color or lacquer used is soluble in a solvent, preferably water, but it is also possible to use a dye soluble in any solvent, for example in alcohol, esters and the like.
  • the color or the colored lacquer can be customary compositions based on natural or artificial macromolecules.
  • the soluble color may be pigmented or unpigmented.
  • pigments all known pigments can be used. Particularly suitable are TiO 2 , ZnS, kaolin and the like.
  • the printed carrier substrate is treated by means of an in-line plasma (low pressure or atmospheric plasma), corona or flame process.
  • High-energy plasma for example Ar or Ar / O 2 plasma, cleans the surface of toning residues of the printing inks. The necessary sharp delimitation of the contours of the recesses, which is necessary for the necessary precision of the coding is achieved.
  • the surface is activated. In this case, terminal polar groups are generated on the surface. This improves the adhesion of metals and the like to the surface.
  • a thin metal or metal oxide layer can be applied as adhesion promoter, for example by sputtering or vapor deposition.
  • adhesion promoter particularly suitable are Cr, Al, Ag, Ti, Cu, TiO 2 , Si oxides or chromium oxides.
  • This adhesion promoter layer generally has a thickness of 0.1 nm to 5 nm, preferably 0.2 nm to 2 nm, particularly preferably 0.2 to 1 nm.
  • This layer consists of a metal, a metal compound, an alloy or an insulator.
  • the metal layer layers of Al, Cu, Fe, Ag, Au, Cr, Ni, Zn and the like are suitable.
  • suitable metal compounds are oxides or sulfides of metals, in particular TiO 2 , Cr oxides, ZnS, ITO, ATO, FTO, ZnO, Al 2 O 3 or silicon oxides.
  • Suitable alloys are, for example, Cu-Al alloys, Cu-Zn alloys and the like.
  • the radiation-curing can be, for example, by heat or UV radiation, suitable.
  • This functional layer can be prepared by known methods, for example by sputtering, sputtering, printing (gravure, flexo, screen, digital printing and the like), spraying, electroplating and the like.
  • the Thickness of the functional layer is 0.001 to 50 ⁇ m, preferably 0.1 to 20 ⁇ m.
  • the ink layer by a suitable solvent, the on the composition of the color layer is matched, removed.
  • the paint is water-soluble.
  • the replacement by mechanical action are supported.
  • the thickness of this layer is about 0.01 - 5 microns.
  • the desired end product is obtained.
  • the carrier film can be applied.
  • the layers applied one on top of the other can be used have different properties. It is possible by Combination of different properties of the individual layers, For example, layers with different conductivity, magnetizability, optical properties, absorption behavior and the like structures for Example of security features with several precise authentication features manufacture.
  • adhesion promoter can be advantageous.
  • the thus produced coated film also by a protective lacquer layer are protected or, for example, by laminating or the like further refined.
  • the metallized films according to the invention are in particular as Security elements, in particular in value documents and data carriers, For example, banknotes, securities, identity documents, cards and used or as security elements or security labels in packaging, textiles, seals and the like.
  • the films according to the invention are also suitable for producing Embedding in banknotes and the like suitable.
  • the product can be applied with a sealable adhesive, such as a hot or cold seal adhesive to the appropriate substrate, or embedded in paper for security papers by conventional methods, for example.
  • sealants can be equipped with visible or visible in the UV light, fluorescent, phosphorescent or laser and IR radiation absorbing features to increase the security against counterfeiting.
  • These features may also be present in the form of patterns or characters or show color effects, in principle any number of colors, preferably 1 to 10 colors or color mixtures, are possible.
  • the carrier substrate may be used after one-sided coating after application be removed or left on the product.
  • the carrier film optionally specially equipped on the uncoated side be scratch resistant, antistatic and the like. The same applies to a possible lacquer layer on the carrier substrate.
  • a water-soluble ink layer based on a thickness of 3 microns is applied by gravure, with recesses are provided in the form of letters.
  • the printed film is subjected to a low-pressure plasma process with Ar plasma and simultaneously applied a layer of Cr as a primer with a thickness of 0.3 nm. Then it is steamed with Al.
  • the layer thickness of the vapor-deposited layer is 0.2 ⁇ m.
  • the film is washed with water and thus the paint application is removed with the adhesion promoter on the paint application and the metal layer located in this area.
  • the finished product has a selective Al coating with a coding in the form of letters.
  • a water-soluble ink based on 9 wt% TiO 2 pigments with recesses in the form of defined lines is applied.
  • the printed film is subjected to a corona process and at the same time a layer of silicon dioxide is applied as a primer with a thickness of 0.3 nm.
  • the thus treated film is vapor-deposited with Cu, wherein the thickness of the layer is 0.5 microns.
  • the film is washed with water and thus the paint application is removed with the adhesion promoter on the paint application and the metal layer located in this area.
  • the film now has a selective metallic coating in the form of defined lines.
  • a film prepared according to Example 1 is subjected to a plasma treatment with Ar / O 2 plasma and then printed over the entire surface of a functional layer of a urethane coating system by gravure printing. Subsequently, the thus treated film is provided with a paint with an alcohol-soluble ink with 10% ZnS as a pigment, wherein partially with the recesses of the first inking overlapping recesses are provided in the form of a pattern. Subsequently, the film is again subjected to a plasma treatment with Ar / O 2 plasma and simultaneously applied a 0.2 nm thick layer of chromium (III) oxide as a primer. Subsequently, a layer of Al is sprayed with a layer thickness of 0.2 microns. Subsequently, a washing process is carried out with alcohol, which in turn the paint application is replaced with the layers thereon.
  • Example 2 It is produced a film analogous to Example 1, although all there described process steps on both sides of the carrier film passer- and be carried out in register.
  • the film thus produced is subsequently with a protective lacquer layer with a fluorescent color in UV light Mistake.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Laminated Bodies (AREA)
  • Printing Methods (AREA)
EP02019580.6A 2001-09-05 2002-09-02 Procédé de préparation d'un feuille métallisée sélectivement, et le produit correspondant Expired - Lifetime EP1291463B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10143523A DE10143523B4 (de) 2001-09-05 2001-09-05 Verfahren zur Herstellung einer selektiv metallisierten Folie
DE10143523 2001-09-05

Publications (2)

Publication Number Publication Date
EP1291463A1 true EP1291463A1 (fr) 2003-03-12
EP1291463B1 EP1291463B1 (fr) 2014-12-10

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EP (1) EP1291463B1 (fr)
DE (1) DE10143523B4 (fr)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1516957A1 (fr) * 2003-09-17 2005-03-23 Hueck Folien Ges.m.b.H Element de securité avec indications colorées
EP1516956A1 (fr) * 2003-09-17 2005-03-23 Hueck Folien Ges.m.b.H Element de securité avec indications colorées négatives
WO2005043965A2 (fr) * 2003-10-29 2005-05-12 Steiner Gmbh & Co. Kg Transpondeur
WO2005082201A1 (fr) * 2004-03-01 2005-09-09 Schreiner Group Gmbh & Co. Kg Porte-echantillons, de preference pour un produit cosmetique
EP1746208A1 (fr) 2005-07-19 2007-01-24 Hueck Folien GmbH & Co. KG Procédé pour la fabrication d'un substrat partiellement metallisé
EP2135987A1 (fr) * 2008-06-20 2009-12-23 Commissariat à l'Energie Atomique (Etablissement Public) Procédé de dépôt de capteurs sur un support poreux
EP2154084A1 (fr) 2008-08-14 2010-02-17 Hueck Folien Ges.m.b.H. Feuille adaptée à la fabrication d'un sac tubulaire, sac tubulaire et procédé de fabrication de la feuille
WO2010041226A1 (fr) * 2008-10-10 2010-04-15 Arjowiggins Security Procédé de fabrication d'un document de sécurité
EP2177645A1 (fr) 2008-09-29 2010-04-21 Hueck Folien Ges.m.b.H. Procédé de structuration de couches anorganiques ou organiques
US7767591B2 (en) * 2005-04-22 2010-08-03 Steiner Gmbh & Co. Kg Method and device for producing electronic components
CN101581061B (zh) * 2008-05-13 2010-11-03 上海纳尔实业有限公司 一种导气槽车身贴的制作方法
EP2251207A1 (fr) * 2009-05-11 2010-11-17 HUECK Folien Ges.m.b.H. Caractéristique de sécurité et procédé destiné à sa fabrication
EP2420391A2 (fr) 2010-07-19 2012-02-22 Hueck Folien Ges.m.b.H. Elément de sécurité doté d'une couche optiquement variable
WO2012153114A1 (fr) * 2011-05-06 2012-11-15 D W Spinks (Embossing) Limited Dispositif de sécurité fenêtré
WO2014013410A1 (fr) 2012-07-16 2014-01-23 Arjowiggins Security Structure de securite
EP2851194A1 (fr) 2013-09-20 2015-03-25 Hueck Folien Ges.m.b.H Elément de sécurité, notamment étiquette de sécurité
GB2527763A (en) * 2014-06-30 2016-01-06 Innovia Films Ltd Process
GB2527764A (en) * 2014-06-30 2016-01-06 Innovia Films Ltd Process
EP1972462B2 (fr) 2007-01-05 2019-09-18 Giesecke+Devrient Currency Technology GmbH Procédé de fabrication de feuilles de sécurité, et feuilles de sécurité
DE102020207090A1 (de) 2020-06-05 2021-12-09 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein Verfahren zum Herstellen eines strukturierten Objekts auf einem flexiblen Substrat durch elektrohydrodynamisches Drucken

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT412273B (de) 2001-12-07 2004-12-27 Hueck Folien Gmbh Verfahren zur herstellung von registergenau gedruckten multilayer-aufbauten, nach diesem verfahren hergestellte produkte und deren verwendung
AT412267B (de) 2002-03-27 2004-12-27 Hueck Folien Gmbh Uv-kaschierter sicherheitsfaden
DE102008030409A1 (de) 2008-06-27 2009-12-31 Giesecke & Devrient Gmbh Sicherheitselement mit Aussparung und Verfahren zur Herstellung desselben
DE102011002077B4 (de) * 2011-04-15 2020-12-10 Kunststoff-Institut Für Die Mittelständische Wirtschaft Nrw Gmbh (Kimw Nrw Gmbh) Verfahren zum Herstellen eines mit wenigstens einem elektrischen Funktionsteil versehenen Kunststoffwerkstückes
DE102013108666A1 (de) 2013-08-09 2015-03-05 Leonhard Kurz Stiftung & Co. Kg Verfahren zur Herstellung eines Mehrschichtkörpers sowie Mehrschichtkörper
DE102015010744A1 (de) 2015-08-17 2017-02-23 Giesecke & Devrient Gmbh Sicherheitselement, Verfahren zum Herstellen desselben und mit dem Sicherheitselement ausgestatteter Datenträger
DE102021109967A1 (de) * 2021-04-20 2022-10-20 Leonhard Kurz Stiftung & Co. Kg Verfahren zum Herstellen eines Mehrschichtkörpers, Mehrschichtkörper, Verwendung eines Mehrschichtkörpers, Verwendung einer ersten Schicht aus einem ersten Metall und einer zweiten Schicht aus einem zweiten Metall in einem Mehrschichtkörper sowie Verwendung einer Wärmebeaufschlagungsvorrichtung

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4242378A (en) * 1979-03-29 1980-12-30 Reiko Co., Ltd. Method of making a decorated film with a metal layer in the form of a given pattern
US4354911A (en) * 1981-08-07 1982-10-19 Western Electric Company Inc. Method of selectively depositing a metal on a surface by means of sputtering
US4643912A (en) * 1982-10-29 1987-02-17 Marui Industry Co., Ltd. Method for forming a metal layer with pattern on a substrate
US5697649A (en) * 1995-05-11 1997-12-16 Crane & Co., Inc. Articles employing a magnetic security feature
DE19739193A1 (de) * 1997-09-08 1999-03-11 Giesecke & Devrient Gmbh Sicherheitsfolien für Wertpapiere und Verfahren zu ihrer Herstellung
FR2801910A1 (fr) * 1999-12-07 2001-06-08 Banque De France Document de securite fabrique avec papier dont la trame fibreuse est enrobee par une substance protectrice
WO2002031214A1 (fr) * 2000-10-09 2002-04-18 Hueck Folien Film metallise, procede permettant de le produire et utilisation

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2748031A (en) * 1952-12-31 1956-05-29 Kafig Emanuel Reproduction of printed patterns by vacuum evaporation
ES2048186T3 (es) * 1988-03-04 1994-03-16 Gao Ges Automation Org Elemento de seguridad en forma de un hilo o de una banda para su incorporacion en documentos de seguridad y procedimiento para su fabricacion.
US5059454A (en) * 1989-04-26 1991-10-22 Flex Products, Inc. Method for making patterned thin film

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4242378A (en) * 1979-03-29 1980-12-30 Reiko Co., Ltd. Method of making a decorated film with a metal layer in the form of a given pattern
US4354911A (en) * 1981-08-07 1982-10-19 Western Electric Company Inc. Method of selectively depositing a metal on a surface by means of sputtering
US4643912A (en) * 1982-10-29 1987-02-17 Marui Industry Co., Ltd. Method for forming a metal layer with pattern on a substrate
US5697649A (en) * 1995-05-11 1997-12-16 Crane & Co., Inc. Articles employing a magnetic security feature
DE19739193A1 (de) * 1997-09-08 1999-03-11 Giesecke & Devrient Gmbh Sicherheitsfolien für Wertpapiere und Verfahren zu ihrer Herstellung
FR2801910A1 (fr) * 1999-12-07 2001-06-08 Banque De France Document de securite fabrique avec papier dont la trame fibreuse est enrobee par une substance protectrice
WO2002031214A1 (fr) * 2000-10-09 2002-04-18 Hueck Folien Film metallise, procede permettant de le produire et utilisation

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1516956A1 (fr) * 2003-09-17 2005-03-23 Hueck Folien Ges.m.b.H Element de securité avec indications colorées négatives
EP1516957A1 (fr) * 2003-09-17 2005-03-23 Hueck Folien Ges.m.b.H Element de securité avec indications colorées
WO2005043965A2 (fr) * 2003-10-29 2005-05-12 Steiner Gmbh & Co. Kg Transpondeur
DE10350648A1 (de) * 2003-10-29 2005-06-16 Steiner Gmbh & Co. Kg Transponder
WO2005043965A3 (fr) * 2003-10-29 2005-06-30 Steiner Gmbh & Co Kg Transpondeur
WO2005082201A1 (fr) * 2004-03-01 2005-09-09 Schreiner Group Gmbh & Co. Kg Porte-echantillons, de preference pour un produit cosmetique
US7767591B2 (en) * 2005-04-22 2010-08-03 Steiner Gmbh & Co. Kg Method and device for producing electronic components
EP1746208A1 (fr) 2005-07-19 2007-01-24 Hueck Folien GmbH & Co. KG Procédé pour la fabrication d'un substrat partiellement metallisé
EP1972462B2 (fr) 2007-01-05 2019-09-18 Giesecke+Devrient Currency Technology GmbH Procédé de fabrication de feuilles de sécurité, et feuilles de sécurité
CN101581061B (zh) * 2008-05-13 2010-11-03 上海纳尔实业有限公司 一种导气槽车身贴的制作方法
EP2135987A1 (fr) * 2008-06-20 2009-12-23 Commissariat à l'Energie Atomique (Etablissement Public) Procédé de dépôt de capteurs sur un support poreux
FR2932823A1 (fr) * 2008-06-20 2009-12-25 Commissariat Energie Atomique Procede de depot de capteurs sur un support poreux
US8257792B2 (en) 2008-06-20 2012-09-04 Commissariat A L'energie Atomique Process for depositing sensors on a porous support
EP2154084A1 (fr) 2008-08-14 2010-02-17 Hueck Folien Ges.m.b.H. Feuille adaptée à la fabrication d'un sac tubulaire, sac tubulaire et procédé de fabrication de la feuille
EP2177645A1 (fr) 2008-09-29 2010-04-21 Hueck Folien Ges.m.b.H. Procédé de structuration de couches anorganiques ou organiques
WO2010041226A1 (fr) * 2008-10-10 2010-04-15 Arjowiggins Security Procédé de fabrication d'un document de sécurité
FR2937058A1 (fr) * 2008-10-10 2010-04-16 Arjowiggins Procede de fabrication d'un document de securite.
EP2251207A1 (fr) * 2009-05-11 2010-11-17 HUECK Folien Ges.m.b.H. Caractéristique de sécurité et procédé destiné à sa fabrication
WO2010130301A1 (fr) * 2009-05-11 2010-11-18 Hueck Folien Ges.M.B.H. Caractéristique de sécurité et son procédé de production
EP2420391A2 (fr) 2010-07-19 2012-02-22 Hueck Folien Ges.m.b.H. Elément de sécurité doté d'une couche optiquement variable
WO2012153114A1 (fr) * 2011-05-06 2012-11-15 D W Spinks (Embossing) Limited Dispositif de sécurité fenêtré
WO2014013410A1 (fr) 2012-07-16 2014-01-23 Arjowiggins Security Structure de securite
US10583682B2 (en) 2012-07-16 2020-03-10 Oberthur Fiduciaire Sas Security structure
EP2851194A1 (fr) 2013-09-20 2015-03-25 Hueck Folien Ges.m.b.H Elément de sécurité, notamment étiquette de sécurité
WO2015039711A1 (fr) 2013-09-20 2015-03-26 Hueck Folien Ges.M.B.H. Élément de sécurité, notmament étiquette de sécurité
GB2527763A (en) * 2014-06-30 2016-01-06 Innovia Films Ltd Process
GB2527764A (en) * 2014-06-30 2016-01-06 Innovia Films Ltd Process
GB2527764B (en) * 2014-06-30 2017-02-22 Innovia Films Ltd Process for producing a security film
GB2527763B (en) * 2014-06-30 2017-10-04 Innovia Films Ltd A process for producing a security film
DE102020207090A1 (de) 2020-06-05 2021-12-09 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein Verfahren zum Herstellen eines strukturierten Objekts auf einem flexiblen Substrat durch elektrohydrodynamisches Drucken

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DE10143523A1 (de) 2003-03-27
EP1291463B1 (fr) 2014-12-10
DE10143523B4 (de) 2008-08-21

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