EP1290121A2 - Compositions de nettoyage pour surfaces dures - Google Patents

Compositions de nettoyage pour surfaces dures

Info

Publication number
EP1290121A2
EP1290121A2 EP00970492A EP00970492A EP1290121A2 EP 1290121 A2 EP1290121 A2 EP 1290121A2 EP 00970492 A EP00970492 A EP 00970492A EP 00970492 A EP00970492 A EP 00970492A EP 1290121 A2 EP1290121 A2 EP 1290121A2
Authority
EP
European Patent Office
Prior art keywords
composition
weight
optionally
cleaning
wipe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00970492A
Other languages
German (de)
English (en)
Other versions
EP1290121B1 (fr
Inventor
Alan Edward Sherry
Nicola John Policicchio
Cynthia Elaine Cella
Jeffrey Lawrence Flora
Toan Trinh
Joseph Paul Morelli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP05028152A priority Critical patent/EP1661503A3/fr
Priority to EP08167764A priority patent/EP2036481A3/fr
Publication of EP1290121A2 publication Critical patent/EP1290121A2/fr
Application granted granted Critical
Publication of EP1290121B1 publication Critical patent/EP1290121B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/049—Cleaning or scouring pads; Wipes
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
    • A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
    • A47L13/16—Cloths; Pads; Sponges
    • A47L13/17—Cloths; Pads; Sponges containing cleaning agents
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet

Definitions

  • compositions including concentrated compositions, premoistened wipes, including optimized substrates, and implements for use in cleaning hard surfaces and/or maintaining their appearance and hygiene, and articles comprising said compositions, concentrates, wipes, and the like, in association with instructions as to how to use them to provide superior performance
  • compositions, wipes, and implement designs along with specific instructions for use are advantageous for use on hard surfaces including bathroom surfaces, glass surfaces, countertops, walls and floors
  • Such compositions typically contain hydrophihc polymer, detergent surfactant, organic cleaning solvent, and optional volatile buffers, perfume, anti-microbials, builders, and the like
  • detergent compositions comprising organic water-soluble synthetic detergent surfactants, polymers, and cleaning solvents for cleaning hard surfaces in, e.g , bathrooms, is well established
  • Known liquid detergent compositions for this purpose comprise organic cleaning solvents, detergent surfactant, and optional detergent builders and/or abrasives
  • the compositions can be acidic for improved removal of hard water deposits
  • Liquid cleaning compositions are usually preferred, since they have the advantage that they can be applied to hard surfaces in neat or concentrated form so that a relatively high level of, e g , surfactant material and/or organic solvent is delivered directly to the soil
  • solid compositions can also be used to form a cleaning solution when diluted with water
  • Concentrated liquid cleaning compositions can also help improve the value equation for consumers by economizing on packaging costs, where the concentrated products are intended to be used in more dilute form
  • a concentrated, e g , 10X refill can also provide additional convenience to the consumer in that it lasts longer, weighs less, and occupies less space than a 1X product
  • Liquid cleaning compositions in the form of a "wipe" also can provide convenience by allowing the consumer to use the wipe once and dispose of it
  • the present invention relates to hard surface cleaning compositions, preferably liquid, suitable for removal of and/or prevention of buildup of soils commonly encountered on floors, walls, counter tops, glass, and/or in the bathroom, said compositions preferably comprising hydrophihc polymers, to render the cleaned surface hydrophihc, and/or specific surfactant, preferably alkylpolyglycoside surfactant, selected to minimize spotting/filming, optionally cleaning solvents, and optionally organic acids
  • the invention also relates to cleaning systems including implements and instructions for how they are used, preferably, with the solutions comprising
  • the invention also relates to compositions and methods of use in which floors, counters, walls, and the like, are cleaned by applying a treatment solution which is then substantially removed by absorption and/or rubbing, while leaving on a low to moderate level of treatment liquid which then dries
  • a treatment solution which is then substantially removed by absorption and/or rubbing
  • Examples of such methods include applications such as the use of pre- moistened wipes (comprising a substrate and aqueous compositions incorporated in the substrate) and/or absorbent articles used in conjunction with cleaning solution
  • pre- moistened wipes comprising a substrate and aqueous compositions incorporated in the substrate
  • the use of these implements facilitates the ease of use and can be advantageous in achieving not only a desired end result but excellent hygiene
  • pre-moistened wipes or absorbent pads are typically disposed of after each use, their use and subsequent disposal reduces the risk of the implement harboring and re-inoculating germs onto the surface being
  • the acidic versions of the present hard surface cleaning compositions can remove soap scum and hard water marks
  • the compositions can have disinfectant properties achieved through the choice of antibacterial actives, including citric acid, and can be used with, or without, additives such as hydrogen peroxide for additional mold/mildew prevention benefits
  • the compositions preferably incorporate one or more hydrophihc polymers which attach to the surface to render it hydrophihc, as measured by, e g , the contact angle, for improved surface wetting and/or filming/streaking properties and, optionally, viscosity control
  • the hard surface cleaning compositions herein which contain the hydrophihc polymers provide superior surface appearance, especially in a no-rinse application
  • the compositions herein are sprayed directly onto tile, more preferably onto wet tile, and then allowed to dry Upon the next exposure to water, e g , during a shower, the d ⁇ ed-on, though not visible, residue allows
  • the cleaning process is preferably a method which comprises using treatment solution (preferably a ready-to-use-solution) comprising a an effective amount to reduce the contact angle and/or increase surface hydrophihcity, up to about 0 5%, preferably from about 0 005% to about 0 4%, more preferably from about 0 01 % to about 0 3%, by weight of the composition, of hydrophihc polymer, preferably substantive, that renders the treated surface hydrophihc, and preferably is a polymer selected from the group consisting of polystyrene sulfonate, polyvinyl pyrrohdone, polyvinyl pyrrohdone acrylic acid copolymer, polyvinyl pyrrohdone acrylic acid copolymer sodium salt, polyvinyl pyrrohdone acrylic acid copolymer potassium salt, polyvinyl pyrrohdone- vinyl imidazolme, polyvinyl py ⁇ dine, polyvinyl py ⁇
  • primary detergent surfactant preferably from about 0.005% to about 0.5%, more preferably from about 0.01 % to about 0.4%, most preferably from about 0.025% to about 0.3%, by weight of the composition
  • said primary detergent surfactant preferably comprising alkyl polysaccharide detergent surfactant having an alkyl group containing from about 8 to about 18 carbon atoms, more preferably from about 8 to about 16 carbon atoms, and from about one to about four, preferably from about one to about 1.5 saccharide moieties per molecule and/or a combination consisting of alkyl polysaccharide detergent surfactant having an alkyl group containing from about 8 to about 18 carbon atoms, more preferably from about 8 to about 16 carbon atoms, and from about one to about four, preferably from about one to about 1.5 saccharide moieties per molecule together with an alkyl ethoxylate comprising from about 8 to about 16 carbon atoms and from about 4 to about 25 oxyethylene units
  • an effective amount to provide increased cleaning of organic cleaning solvent preferably from about 0.25% to about 5%, preferably from about 0.5% to about 4%, more preferably from about 0.5% to about 3%, by weight of the composition, and is preferably selected from the group consisting of: mono-propylene glycol mono-propyl ether; mono-propyiene glycol mono-butyl ether; di-propylene glycol mono-propyl ether; di-propylene glycol mono-butyl ether; di-propylene glycol mono-butyl ether; tri-propylene glycol mono-butyl ether; ethylene glycol mono-butyl ether; diethylene glycol mono-butyl ether, ethylene glycol mono-hexyl ether; diethylene glycol mono-hexyl ether; and mixtures thereof; d. optionally, a minor amount that is less than the amount of primary detergent surfactant b., preferably from about 0.005% to about 0.5%, more preferably from
  • cosurfactant preferably anionic and/or nonionic detergent surfactant, more preferably selected from the group consisting of: C 8 -C 12 linear sulfonates, C 8 -C 18 alkylbenzene sulfonates; C 8 -C ⁇ 8 alkyl sulfates; C 8 -C 18 alkylpolyethoxy sulfates; and mixtures thereof; e. optionally, an effective amount to improve cleaning and/or antimicrobial action, preferably from about 0.01 % to about 1 %, more preferably from about 0.01% to about
  • cyclodextrin preferably alpha, beta, or gamma substituted cyclodextrin, and optionally, with short chain (1-4 carbon atoms) alkyl or hydroxyalkyl groups; the cyclodextrin is preferably beta-cyclodextrin, hydroxypropyl cyclodextrin, or mixtures thereof; g.
  • an effective amount to provide bleaching, cleaning, and/or antibacterial action up to about 5%, preferably from about 0.1 % to about 4%, more preferably from about 1 % to about 3%, by weight of the composition, of hydrogen peroxide; h. optionally, from about 0.005% to about 1%, preferably from about 0.005% to about 0.5%, more preferably from about 0.01 % to about 0.1%, by weight of the composition, of a thickening polymer selected from the group consisting of polyacrylates, gums, and mixtures thereof; i. optionally, an effective amount of perfume to provide odor effects, and/or additional adjuvants; and j.
  • an effective amount preferably from about 0.0001 % to about 0.1%, more preferably from about 0.00025% to about 0.05%, and even more preferably from about 0.001 % to about to about 0.01 %, by weight of the composition, of suds suppressor, preferably silicone suds suppressor, and k.
  • an aqueous solvent system comprising water and optional water soluble solvent
  • said treatment solution has a pH under usage conditions of from about 2 to about 12, preferably from about 3 to about 11.5, with acidic compositions having a pH of from about 2 to about 6, preferably from about 3 to about 5, said method involving applying the treatment solution, optionally rubbing the surface which is wetted by said treatment solution, and then, optionally, removing part of said treatment solution, while leaving a portion of said treatment solution on the surface.
  • the improved surface appearance is the result of the use of the hydrophihc polymer and/or specific surfactant, especially the alkyl polysaccharide, and especially the use of only low levels of all ingredients.
  • the specific alkyl polysaccharide is important for appearance, even without the polymer being present.
  • Concentrates of the above product can be made by reducing the amount of water.
  • Concentrates of the solution of the present invention i.e., products intended to be used diluted
  • concentration factors i.e., products intended to be used diluted
  • concentrates come with a measuring device (usually the cap or a graduated bottle) to help the consumer make accurate dilutions.
  • Examples of concentrates of the present invention include, but are not limited to, 3X, 5X and 10 X products according to the specification levels defined above. Unless otherwise specified, all concentrations are implied to be for "ready-to-use" products hereinafter. It is understood that those skilled in the art would be able to make concentrates, which would then be diluted for use.
  • compositions herein can contain only polymer and perfume since the polymers, especially the preferred amine oxide polymers, are capable of solubilizing/suspending substantial amounts of even water insoluble perfumes Normally, however, the surfactant will also be present Compositions for use with disposable pads are disclosed hereinafter
  • the hard surface cleaning compositions of the present invention are especially useful for maintaining the appearance of hard surfaces and the buildup of hard-to-remove soils that are commonly encountered on floors and/or in the bathroom These include hard water stains, fatty acids, tnglycerides, lipids, insoluble fatty acid soaps, entrenched particulate matter, encrusted food, and the like
  • the detergent compositions can be used on many different surface types, such as ceramic, fiber glass, glass, polyurethane, metallic surfaces, plastic surfaces, and laminates of all the above a Hydrophihc Polymer
  • the polymeric material that improves the hydrophihcity of the surface being treated is essential This increase in hydrophi city provides improved final appearance by providing "sheeting" of the water from the surface and/or spreading of the water on the surface, and this effect is preferably seen when the surface is rewetted and even when subsequently dried after the rewetting
  • Polymer substantivity is beneficial as it prolongs the sheeting and cleaning benefits
  • Another important feature of preferred polymers is lack of residue upon drying Compositions comprising preferred polymers dry more evenly on floors while promoting an end result with little or no haze
  • polymers that contain amine oxide hydrophihc groups Polymers that contain other hydrophihc groups such a sulfonate, pyrrohdone, and/or carboxylate groups can also be used
  • desirable poly-sulfonate polymers include polyvinylsulfonate, and more preferably polystyrene sulfonate, such as those sold by Monomer-Polymer Dajac (1675 Bustleton Pike, Feasterville, Pennsylvania 19053)
  • a typical formula is as follows
  • n is a number to give the appropriate molecular weight as disclosed below
  • Typical molecular weights are from about 10,000 to about 1 ,000,000, preferably from about 200,000 to about 700,000
  • Preferred polymers containing pyrrohdone functionalities include polyvinyl pyrrohdone, quaternized pyrrohdone derivatives (such as Gafquat 755N from International Specialty Products), and co-polymers containing pyrrohdone, such as polyvinylpyrro done /dimethylaminoethylmethacrylate (available from ISP) and polyvinyl pyrrohdone/acrylate (available from BASF)
  • Other materials can also provide substantivity and hydrophihcity including cationic materials that also contain hydrophihc groups and polymers that contain multiple ether linkages
  • Cationic materials include cationic sugar and/or starch derivatives and the typical block copolymer detergent surfactants based on mixtures of polypropylene oxide and ethylene oxide are representative of the polyether materials The polyether materials are less substantive
  • the preferred polymers comprise water-soluble amine oxide moieties It is believed that the partial positive charge of the amine oxide group can act to adhere the polymer to the surface of the surface substrate, thus allowing water to "sheet” more readily
  • the amine oxide moiety can also hydrogen-bond with hard surface substrates, such as ceramic tile, glass, fiberglass, porcelain enamel, linoleum, no-wax tile, and other hard surfaces commonly encountered in consumer homes
  • hard surface substrates such as ceramic tile, glass, fiberglass, porcelain enamel, linoleum, no-wax tile, and other hard surfaces commonly encountered in consumer homes
  • higher molecular weight materials are preferred Increased molecular weight improves efficiency and effectiveness of the amine oxide-based polymer
  • the preferred polymers of this invention have one or more monome ⁇ c units containing at least one N-oxide group At least about 10%, preferably more than about 50%, more preferably greater than about 90% of said monomers forming said polymers contain an amine oxide group
  • the average molecular weight of the polymer is from about 2,000 to about 500,000 preferably from about 5,000 to about 400,000, and more preferably from about 7,500 to about 300,000
  • higher molecular weight polymers are preferred
  • higher molecular weight polymers allow for use of lower levels of the wetting polymer, which can provide benefits in floor cleaner applications
  • the desirable molecular weight range of polymers useful in the present invention stands in contrast to that found in the art relating to polycarboxylate, polystyrene sulfonate, and polyether based additives which prefer molecular weights in the range of 400,000 to 1 ,500,000 Lower molecular weights for the preferred poly-amine oxide polymers of the present invention are due to greater difficulty in manufacturing these polymers in higher molecular weight
  • the level of amine oxide polymer will normally be less than about 0 5%, preferably from about 0 005% to about 0 4%, more preferably from about 0 01% to about 0 3%, by weight of the end use composition/solution
  • adipic acid/ dimethylaminohydroxypropyl diethylenetnamine copolymer adipic acid/epoxypropyl diethylenetnamine copolymer
  • polyvinyl alcohol methacryloyl ethyl betaine/methacrylates copolymer, ethyl acrylate/methyl methacrylate/methacryhc acid/acry c acid copolymer
  • polyamine resins polyquaternary amine resins, poly(ethenylformam ⁇ de), poly(v ⁇ nylam ⁇ ne) hydrochlo ⁇ de, poly(v ⁇ nyl alcohol-co-6% vinylamine), poly(v ⁇ nyl alcohol-co-12% vinylamine), poly(v ⁇ nyl alcohol-co-6% vinylamine hydrochlonde), poly(v ⁇ nyl alcohol-co-12% vinylamine hydrochlo ⁇ de
  • Noniimiting examples of useful hydrophihc monomers are unsaturated organic mono- and polycarboxyhc acids such as acrylic acid, methacryhc acid, crotonic acid, maleic acid and its half esters, and itaconic acid, unsaturated alcohols, such as vinyl alcohol and allyl alcohol, polar vinyl heterocychcs such as vinyl caprolactam, vinyl pyndine, and vinyl imidazole, vinyl amine, vinyl sulfonate, unsaturated amides such as acrylamides, e g , N,N-d ⁇ methylacrylam ⁇ de and N-t-butyl acrylamide, hydroxyethyl methacrylate, dimethylaminoethyl methacrylate, salts of acids and amines listed above, and the like, and mixtures thereof
  • Some preferred hydrophihc monomers are acrylic acid, methacryhc acid, N,N-d ⁇ methyl acrylamide, N,N-d ⁇ methyl methacrylamide,
  • Polycarboxylate polymers are those formed by polymerization of monomers, at least some of which contain carboxy c functionality Common monomers include acrylic acid, maleic acid, ethylene, vinyl pyrrohdone, methacryhc acid, methacryloylethylbetaine, and the like
  • Preferred polymers for substantivity are those having higher molecular weights
  • polyacryhc acid having molecular weights below about 10,000 are not particularly substantive and therefore do not normally provide hydrophihcity for three rewertings with all compositions, although with higher levels and/or certain surfactants like amphote ⁇ c and/or zwittenonic detergent surfactants, molecular weights down to about 1 ,000 can provide some results
  • the polymers should have molecular weights of more than about 10,000, preferably more than about 20,000, more preferably more than about 300,000, and even more preferably more than about 400,000 It has also been found that higher molecular weight polymers, e g , those having mo
  • polycarboxylate polymers An advantage for some polycarboxylate polymers is the detergent builder effectiveness of such polymers Although such polymers do increase filming/streaking, like other detergent builders, they provide increased cleaning effectiveness on typical, common "hard-to-remove" soils that contain particulate matter
  • compositions that are aqueous liquids This can be desirable
  • the viscosity under shear should be less than about 200 cp, preferably less than about 100 cp, more preferably less than about 50 cp
  • suitable materials include sulfonated polystyrene polymers sold under the name Versaflex ® sold by National Starch and Chemical Company, especially Versaflex ® 7000
  • the level of polymeric material will normally be less than about 0 5%, preferably from about 0 01 % to about 0 4%, more preferably from about 0 01 % to about 0 3%
  • lower molecular weight materials such as lower molecular weight poly(acryhc acid), e g , those having molecular weights below about 10,000, and especially about 2,000, do not provide good anti- spotting benefits upon rewetting, especially at the lower levels, e g , about 0 02%
  • substantivity should be increased, e g , by adding groups that provide improved attachment to the surface, such as cationic groups, or the materials should be used at higher levels, e g , more than about 0 05% b Surfactant
  • the compositions will normally have one of the preferred surfactants present, such as alkylpolysaccha ⁇ des or nonionic surfactants, including alkyl ethoxylates
  • the preferred surfactants for use herein are the alkylpolysaccha ⁇ des that are disclosed in U S Patents 5,776,872, Cleansing compositions, issued July 7, 1998, to Giret, Michel Joseph, Langlois, Anne, and Duke, Roland Philip, 5,883,059, Three in one ultra mild lathering antibacterial liquid personal cleansing composition, issued March 16, 1999, to Furman, Christopher Allen, Giret, Michel Joseph, and Dunbar, James Charles, et al , 5,883,062, Manual dishwashing compositions, issued March 16, 1999, to Addison, Michael Crombie, Foley, Peter Robert, and Allsebrook, Andrew Micheal, and 5,906,973, issued May 25, 1999, Process for cleaning vertical or inclined hard surfaces, by Ouzounis, Dimitnos and Nierhaus,
  • Suitable alkylpolysaccha ⁇ des for use herein are disclosed in U S Pat No 4,565,647, Llenado, issued Jan 21 , 1986, which is incorporated herein by reference, having a hydrophobic group containing from about 6 to about 30 carbon atoms, preferably from about 10 to about 16 carbon atoms and a polysaccharide, e g , a polyglycoside, hydrophihc group
  • the preferred alkyl polysaccharide preferably comprises a broad distribution of chain lengths, as these provide the best combination of wetting, cleaning, and low residue upon drying This "broad distribution" is defined by at least about 50% of the chainlength mixture comprising from about 10 carbon atoms to about 16 carbon atoms
  • the alkyl group of the alkyl polysaccharide consists of a mixtures of chainlength, preferably from about 6 to about 18 carbon atoms, more preferably from
  • a polyalkyleneoxide chain joining the hydrophobic moiety and the polysaccharide moiety
  • the preferred alkyleneoxide is ethylene oxide
  • Typical hydrophobic groups include alkyl groups, either saturated or unsaturated, branched or unbranched containing from 8 to 18, preferably from 10 to 16, carbon atoms
  • the alkyl group is a straight-chain saturated alkyl group
  • the alkyl group can contain up to about 3 hydroxyl groups and/or the polyalkyleneoxide chain can contain up to about 10, preferably less than 5, alkyleneoxide moieties
  • Suitable alkyl polysaccha ⁇ des are octyl, nonyldecyl, undecyldodecyl, tndecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, and octadecyl, d ⁇ -, t ⁇
  • the alcohol or alkylpolyethoxy alcohol is formed first and then reacted with glucose, or a source of glucose, to form the glucoside (attachment at the Imposition)
  • the additional glycosyl units can then be attached between their 1 -position and the preceding glycosyl units 2-, 3- 4- and/or 6-pos ⁇ t ⁇ on, preferably predominantly the 2-pos ⁇ t ⁇ on
  • the alkyl moieties can be derived from the usual sources like fats, oils or chemically produced alcohols while their sugar moieties are created from hydrolyzed polysaccha ⁇ des
  • Alkyl polyglycosides are the condensation product of fatty alcohol and sugars like glucose with the number of glucose units defining the relative hydrophihcity
  • the sugar units can additionally be alkoxylated either before or after reaction with the fatty alcohols
  • Such alkyl polyglycosides are described in detail in WO 86/05199 for example
  • Technical alkyl polyglycosides are generally not molecularly uniform products, but represent mixtures of alkyl groups and mixtures of monosaccha ⁇ des and different ohgosaccha ⁇ des
  • Alkyl polyglycosides also sometimes referred to as "APG's" are preferred for the purposes of the invention since they provide additional improvement in surface appearance relative to other surfactants
  • the glycoside moieties are preferably glucose moieties
  • the preferred alkyl polyglucosides are those which have been purified enough for use in personal cleansing. Most preferred are "cosmetic grade" alkyl polyglucosides, particularly C 8 to C 16 alkyl polyglucosides, such as Plantaren 2000®, Plantaren
  • alkyl ethoxylates are either linear or branched, and contain from about 8 carbon atoms to about 14 carbon atoms, and from about 4 ethylene oxide units to about 25 ethylene oxide units. Examples of alkyl ethoxylates include
  • Neodol® 91-6 Neodol 91-8® supplied by the Shell Corporation (P.O. Box 2463, 1 Shell Plaza, Houston, Texas), and Alfonic® 810-60 supplied by Vista corporation, (900 Threadneedle P.O. Box 19029, Houston, TX).
  • More preferred surfactants are the alkyl ethoxylates comprising from about 9 to about 12 carbon atoms, and from about 4 to about 8 ethylene oxide units. These surfactants offer excellent cleaning benefits and work synergistically with the required hydrophihc polymers.
  • a most preferred alkyl ethoxylate is C- 11 EO 5 , available from the Shell Chemical Company under the trademark Neodol® 1-5.
  • This surfactant is found to provide desirable wetting and cleaning properties, and can be advantageously combined with the preferred C 8 . 16 alkyl polyglucoside in a matrix that includes the wetting polymers of the present invention. While not wishing to be limited by theory, it is believed that the C 8 . 16 alkyl polyglucoside can provide a superior end result (i.e., reduce hazing) in compositions that additionally contain the preferred alkyl ethoxylate particularly when the preferred alkyl ethoxylate is required for superior cleaning.
  • the preferred the C 8 -1 6 alkyl polyglucoside is also found to improve perfume solubility of compositions comprising alkyl ethoxylates. Higher levels of perfume can be advantageous for consumer acceptance.
  • compositions are prepared with relatively low levels of active materials.
  • compositions will comprise sufficient surfactant and optional solvent, as discussed hereinafter, to be effective as hard surface cleaners yet remain economical; accordingly they typically contain from about 0.005% to about 0.5% by weight of the composition of surfactant, preferably alkylpolyglycoside and/or C 8 . 14 alkylethoxylate surfactant, more preferably from about 0.01% to about 0.4% surfactant, and even more preferably from about 0.01 % to about 0.3% surfactant. It has been found that use of low, rather than high levels of surfactant are advantageous to overall end result performance.
  • compositions optionally, can also contain one, or more, organic cleaning solvents at effective levels, typically no less than about 0 25%, and, at least about 0 5%, preferably at least about 3 0%, and no more than about 7%, preferably no more than about 5%, by weight of the composition
  • the surfactant provides cleaning and/ or wetting even without an organic cleaning solvent present
  • the cleaning can normally be further improved by the use of the right organic cleaning solvent
  • organic cleaning solvent it is meant an agent which assists the surfactant to remove soils such as those commonly encountered in the bathroom
  • the organic cleaning solvent also can participate in the building of viscosity, if needed, and in increasing the stability of the composition
  • the compositions containing C 8 16 alkyl polyglucosides and/or C 8 14 alkylethoxylates also have lower sudsing when the solvent is present
  • the suds profile can be controlled in large part by simply controlling the level of hydrophobic solvent in the formulation
  • Such solvents typically have a terminal C3-Cg hydrocarbon attached to from one to three ethylene glycol or propylene glycol moieties to provide the appropriate degree of hydrophobicity and, preferably, surface activity
  • Examples of commercially available hydrophobic cleaning solvents based on ethylene glycol chemistry include mono-ethylene glycol n-hexyl ether (Hexyl Cellosolve® available from Union Carbide)
  • Examples of commercially available hydrophobic cleaning solvents based on propylene glycol chemistry include the d ⁇ -, and tn-propylene glycol derivatives of propyl and butyl alcohol, which are available from Arco Chemical (3801 West Chester Pike, Newtown Square, PA 19073) and Dow Chemical (1691 N Swede Road, Midland,
  • preferred solvents are selected from the group consisting of mono-propylene glycol mono-propyl ether, di-propylene glycol mono-propyl ether, mono-propylene glycol mono-butyl ether, di-propylene glycol mono-propyl ether, di-propylene glycol mono-butyl ether, tn-propylene glycol mono-butyl ether, ethylene glycol mono-butyl ether di-ethylene glycol mono-butyl ether, ethylene glycol mono-hexyl ether, di-ethylene glycol mono- hexyl ether, and mixtures thereof "Butyl” includes both normal butyl, isobutyl and tertiary butyl groups Mono-propylene glycol and mono-propylene glycol mono-butyl ether are the most preferred cleaning solvent and are available under the tradenames Dowanol DPnP®
  • compositions of the present invention optionally can include a small amount of additional cosurfactant such as anionic and/or nonionic detergent surfactant
  • anionic surfactants typically comprise a hydrophobic chain containing from about 8 to about 18 carbon atoms, preferably from about 8 to about 16 carbon atoms, and typically include a sulfonate or carboxylate hydrophihc head group
  • nonionic detergent surfactants for use herein are alkoxylated alcohols generally comprising from about 6 to about 16 carbon atoms in the hydrophobic alkyl chain of the alcohol Typical alkoxylation groups are propoxy groups or propoxy groups in combination with ethoxy groups Such compounds are commercially available under the tradename Antarox® available from Rhodia (P O Box 425 Cranberry, New Jersey 08512) with a wide variety of chain length and alkoxylation degrees Block copolymers of ethylene oxide and propylene oxide can also be used and are available from BASF under the tradename Pluronic® Preferred nonionic detergent surfactants for use herein are according to the formula R(X) n H, were R is an alkyl chain having from about 6 to about 16 carbon atoms, preferably from about 8 to about 12 carbon atoms, X is a propoxy, or a mixture of ethoxy and propoxy groups, n is an integer of from about 4 to about 30, preferably from about 5 to about 8.
  • non-ionic surfactants that can be used include those derived from natural sources such as sugars and include C 8 -C 16 N-alkyl glucose amide surfactants. If present, the concentration of alternative nonionic surfactant is from about 0.01 % to about 0.2%, more preferably from about 0.01 % to about 0.1 %, by weight of the composition, e.
  • Mono- or Polycarboxylic Acid For purposes of soap scum and hard water stain removal, the compositions can be made acidic with a pH of from about 2 to about 5, more preferably about 3. Acidity is accomplished, at least in part, through the use of one or more organic acids that have a pKa of less than about 5, preferably less than about 4.
  • suitable mono-carboxylic acids include acetic acid, glycolic acid or ⁇ -hydroxy propionic acid and the like.
  • suitable polycarboxylic acids include citric acid, tartaric acid, succinic acid, glutaric acid, adipic acid, and mixtures thereof. Such acids are readily available in the trade.
  • Examples of more preferred polycarboxylic acids, especially non-polymeric polycarboxylic acids include citric acid (available from Aldrich Corporation, 1001 West Saint Paul Avenue, Milwaukee, Wisconsin), a mixture of succinic, glutaric and adipic acids available from DuPont (Wilmington, Delaware) sold as "refined AGS di-basic acids", maleic acid (also available from Aldrich), and mixtures thereof.
  • Citric acid is most preferred, particularly for applications requiring cleaning of soap scum.
  • Glycolic acid and the mixture of adipic, glutaric and succinic acids provide greater benefits for hard water removal.
  • the amount of organic acid in the compositions herein can be from about 0.01 % to about 1 %, more preferably from about 0.01 % to about 0.5%, most preferably from about 0.025% to about 0.25% by weight of the composition. f. Odor Control Agents
  • cyclodextrin includes any of the known cyclodextrins such as unsubstituted cyclodextrins containing from six to twelve glucose units, especially, alpha- cyclodextrin, beta-cyclodextrin, gamma-cyclodextrin and/or their derivatives and/or mixtures thereof.
  • the alpha-cyclodextrin consists of six glucose units
  • the beta-cyclodextrin consists of seven glucose units
  • the gamma-cyclodextrin consists of eight glucose units arranged in donut-shaped rings.
  • the specific coupling and conformation of the glucose units give the cyclodextrins rigid, conical molecular structures with hollow interiors of specific volumes.
  • the "lining" of each internal cavity is formed by hydrogen atoms and glycosidic bridging oxygen atoms; therefore, this surface is fairly hydrophobic.
  • the unique shape and physical-chemical properties of the cavity enable the cyclodextrin molecules to absorb (form inclusion complexes with) organic molecules or parts of organic molecules which can fit into the cavity Many odorous molecules can fit into the cavity including many malodorous molecules and perfume molecules Therefore, cyclodextrins, and especially mixtures of cyclodextrins with different size cavities, can be used to control odors caused by a broad spectrum of organic odoriferous materials, which may, or may not, contain reactive functional groups
  • the complexation between cyclodextrin and odorous molecules occurs rapidly in the presence of water However, the extent of the complex formation also depends on the polarity of the absorbed molecules In an a
  • the aqueous cleaning solution of the present invention is clear
  • the term “clear” as defined herein means transparent or translucent, preferably transparent, as in “water clear,” when observed through a layer having a thickness of less than about 10 cm
  • the cyclodextrins used in the present invention are highly water-soluble such as, alpha-cyclodext ⁇ n and/or derivatives thereof, gamma-cyclodextrin and/or derivatives thereof, de ⁇ vatised beta-cyclodext ⁇ ns, and/or mixtures thereof
  • the derivatives of cyclodextrin consist mainly of molecules wherein some of the OH groups are converted to OR groups
  • Cyclodextrin derivatives include, e g , those with short chain alkyl groups such as methylated cyclodextrins, and ethylated cyclodextrins, wherein R is a methyl or an ethyl group, those with hydroxyalkyl substituted groups, such as hydroxypropyl cyclodextrins and/or hydroxyethyl cyclodextrins, wherein R is a -CH2-CH(OH)-CH3 or a "CH2CH2-OH group, branche
  • Highly water-soluble cyclodextrins are those having water solubility of at least about 10 g in 100 ml of water at room temperature, preferably at least about 20 g in 100 ml of water, more preferably at least about 25 g in 100 ml of water at room temperature
  • solubihzed, uncomplexed cyclodextrins is essential for effective and efficient odor control performance
  • Solubihzed, water-soluble cyclodextrin can exhibit more efficient odor control performance than non-water-soluble cyclodextrin when deposited onto surfaces
  • Examples of preferred water-soluble cyclodextrin derivatives suitable for use herein are hydroxypropyl alpha-cyclodext ⁇ n, methylated alpha-cyclodext ⁇ n, methylated beta-cyclodextrin, hydroxyethyl beta-cyclodextrin, and hydroxypropyl beta-cyclodextrin Hydroxyalkyl cyclodextrin derivatives preferably have a degree of substitution of from about 1 to about 14, more preferably from about 1 5 to about 7, wherein the total number of OR groups per cyclodextrin is defined as the degree of substitution Methylated cyclodextrin derivatives typically have a degree of substitution of from about 1 to about 18, preferably from about 3 to about 16 A known methylated beta-cyclodextrin is heptak ⁇ s-2,6-d ⁇ -0-methyl- ⁇ -cyclodext ⁇ n, commonly known as DIMEB, in which each glucose unit has about 2 methyl groups with a degree of substitution of about 14.
  • a preferred, more commercially available, methylated beta-cyclodextrin is a randomly methylated beta-cyclodextrin, commonly known as RAMEB, having different degrees of substitution, normally of about 12 6 RAMEB is more preferred than DIMEB, since DIMEB affects the surface activity of the preferred surfactants more than RAMEB
  • the preferred cyclodextrins are available, e g , from Cerestar USA, Inc and Wacker Chemicals (USA), Inc
  • cyclodextrins absorb odors more broadly by complexing with a wider range of odoriferous molecules having a wider range of molecular sizes
  • the cyclodextrin is alpha-cyclodext ⁇ n and/or its derivatives, gamma-cyclodextrin and/or its derivatives, and/or derivatised beta-cyclodextrin, more preferably a mixture of alpha-cyclodextrin, or an alpha-cyclodextrin derivative, and derivatised beta-cyclodextrin, even more preferably a mixture of derivatised alpha-cyclodextrin and derivatised beta-cyclodextrin, most preferably a mixture of hydroxypropyl alpha-cyclodextrin and hydroxypropyl beta-cyclodextrin, and/or a mixture of methylated alpha-cyclodextr
  • the usage compositions of the present invention contain low levels of cyclodextrin so that no visible residue appears at normal usage levels.
  • the solution used to treat the surface under usage conditions is virtually not discernible when dry.
  • Typical levels of cyclodextrin in usage compositions for usage conditions are from about 0.01% to about 1 %, preferably from about 0.05% to about 0.75%, more preferably from about 0.1 % to about 0.5% by weight of the composition.
  • Compositions with higher concentrations can leave unacceptable visible residues, g.
  • Optional Source of Peroxide The compositions of the invention can contain peroxide such as hydrogen peroxide, or a source of hydrogen peroxide, for further disinfectancy, fungistatic and fungicidal benefits.
  • the components of the present composition are substantially compatible with the use of peroxides.
  • Preferred peroxides include benzoyl peroxide and hydrogen peroxide. These can optionally be present in the compositions herein in levels of from about 0.05% to about 5%, more preferably from about 0.1 % to about 3%, most preferably from about 0.2% to about 1.5%.
  • a stabilizing system When peroxide is present, it is desirable to provide a stabilizing system.
  • Suitable stabilizing systems are known.
  • a preferred stabilizing system consists of radical scavengers and/or metal chelants present at levels of from about 0.01 % to about 0.5%, more preferably from about 0.01 % to about 0.25%, most preferably from about 0.01 % to about 0.1 %, by weight of the composition.
  • radical scavengers include anti-oxidants such as propyl gallate, butylated hydroxy toluene (BHT), butylated hydroxy anisole (BHA) and the like.
  • Suitable metal chelants include diethylene triamine penta-acetate, diethylene triamine penta- methylene phosphonate, hydroxyethyl diphosphonate and the like, h.
  • Optional Thickening Polymer Low levels of polymer can also be used to thicken the preferred aqueous compositions of the present invention. To the extent a given polymer can be considered a hydrophihc polymer or a thickening polymer, such polymer shall be considered a hydrophihc polymer for purposes of the present invention. In general, the level of thickening polymer is kept as low as possible so as not to hinder the product's end result properties.
  • Xanthan gum is a particularly preferred thickening agent as it can also enhance end result properties, particularly when used in low concentrations.
  • the thickening polymer agent is present in from about 0.001 % to about 0.1 %, more preferably from about 0.0025% to about 0.05%, most preferably from about 0.005% to about 0.025%, by weight of the composition.
  • compositions which are aqueous comprise at least about 80% aqueous solvent by weight of the composition, more preferably from about 80% to over 99% by weight of the composition.
  • the aqueous compositions are typically in micellar form, and do not incorporate substantial levels of water insoluble components that induce significant micellar swelling.
  • the aqueous solvent system can also comprise, in addition to water, low molecular weight, highly water-soluble solvents typically found in detergent compositions, e.g., ethanol, isopropanol, etc. These solvents can be used to provide disinfectancy properties to compositions that are otherwise low in active. Additionally, they can be particularly useful in compositions wherein the total level of perfume is very low. In effect, highly volatile solvents can provide "lift", and enhance the character of the perfume. Highly volatile solvents, if present are typically present in from about 0.25% to about 5%, more preferably from about 0.5% to about 3%, most preferably from about 0.5% to about 2%, by weight of the composition.
  • solvents examples include methanol, ethanol, isopropanol, n-butanol, / ' so-butanol, 2-butanol, pentanol, 2- methyl-1-butanol, methoxymethanol, methoxyethanol, methoxy propanol, and mixtures thereof.
  • compositions of the present invention can also include other solvents, and in particular paraffins and isoparaffms, which can substantially reduce the suds created by the composition, j.
  • Optional Suds Suppressor Suitable silicone suds suppressors for use herein include any silicone and silica-silicone mixtures. Silicones can be generally represented by alkylated polysiloxane materials while silica is normally used in finely divided forms exemplified by silica aerogels and xerogels and hydrophobic silicas of various types. In industrial practice, the term "silicone” has become a generic term which encompasses a variety of relatively high-molecular-weight polymers containing siloxane units and hydrocarbyl groups of various types.
  • silicone compounds have been extensively described in the art, see for instance United States Patents: US 4,076,648; US 4,021 ,365; US 4,749,740; US 4,983,316 and European Patents: EP 150,872; EP 217,501 ; and EP 499,364, all of said patents being incorporated herein by reference.
  • a preferred type of silicone compounds useful in the compositions herein comprises a mixture of an alkylated siloxane of the type hereinabove disclosed and solid silica.
  • the solid silica can be a fumed silica, a precipitated silica or a silica made by the gel formation technique.
  • the silica particles can be rendered hydrophobic by treating them with diakylsilyl groups and/or trialkylsilane groups either bonded directly onto the silica or by means of silicone resin.
  • a preferred silicone compound comprises a hydrophobic silanated, most preferably trimethylsilanated silica having a particle size in the range from 10 mm to 20 mm and a specific surface area above 50 m 2 /g.
  • Silicone compounds employed in the compositions according to the present invention suitably have an amount of silica in the range of 1 to 30% (more preferably 2.0 to 15%) by weight of the total weight of the silicone compounds resulting in silicone compounds having an average viscosity in the range of from 2 x lO' ⁇ m ⁇ /s to 1m 2 /s.
  • Preferred silicone compounds can have a viscosity in the range of from 5 x lO' ⁇ m- ⁇ /s to O.l m ⁇ /s.
  • silicone compounds with a viscosity of 2 x lO' ⁇ m ⁇ /s or 4.5 x 10" 2 m2/s.
  • Suitable silicone compounds for use herein are commercially available from various companies including Rhone Poulenc, Fueller and Dow Corning. Examples of silicone compounds for use herein are Silicone DB® 100 and Silicone Emulsion 2-3597® both commercially available from Dow Corning. k. Optional Perfume and/or Additional Adjuvants
  • perfumes and/or other conventional adjuvants can also be incorporated in the present compositions.
  • perfumes an optional, but highly preferred ingredient, is a perfume, usually a mixture of perfume ingredients.
  • perfume includes constituents of a perfume which are added primarily for their olfactory contribution, often complimented by use of a volatile organic solvent such as ethanol.
  • Most hard surface cleaner products contain some perfume to provide an olfactory aesthetic benefit and to cover any "chemical" odor that the product may have.
  • the main function of a small fraction of the highly volatile, low boiling (having low boiling points), perfume components in these perfumes is to improve the fragrance odor of the product itself, rather than impacting on the subsequent odor of the surface being cleaned.
  • some of the less volatile, high boiling perfume ingredients can provide a fresh and clean impression to the surfaces, and it is sometimes desirable that these ingredients be deposited and present on the dry surface.
  • the perfumes are preferably those that are more water-soluble and/or volatile to minimize spotting and filming.
  • the perfumes useful herein are described in more detail in U.S. Patent 5,108,660, Michael, issued April 28, 1992, at col. 8 lines 48 to 68, and col. 9 lines 1 to 68, and col. 10 lines 1 to 24, said patent, and especially said specific portion, being incorporated by reference.
  • Perfume components can be natural products such as essential oils, absolutes, resinoids, resins, concretes, etc., and/or synthetic perfume components such as hydrocarbons, alcohols, aldehydes, ketones, ethers, acids, acetals, ketals, nitrites, and the like, including saturated and unsaturated compounds, aliphatic, carbocyclic and heterocyclic compounds.
  • perfume components are: geraniol, geranyl acetate, linalool, linalyl acetate, tetrahydrolinalool, citronellol, citronellyl acetate, dihydromyrcenol, dihydromyrcenyl acetate, terpineol, terpinyl acetate, acetate, 2-phenylethanol, 2-phenylethyl acetate, benzyl alcohol, benzyl acetate, benzyl salicylate, benzyl benzoate, styrallyl acetate, amyl salicylate, dimenthylbenzylcarbinol, t ⁇ chloromethylphenycarbinyl acetate, p-tert butyl-cyclohexyl acetate, isononyl acetate, alpha-n- amylcinammic aldehyde, alpha-hexyl-cinammic alde, al
  • the perfume ingredients are hydrophobic and highly volatile, e g , ingredients having a boiling point of less than about 260°C, preferably less than about 255°C, and more preferably less than about 250°C, and a ClogP of at least about 3, preferably more than about 3 1 , and even more preferably more than about 3 2
  • the logP of many ingredients has been reported, for example, the Pomona92 database, available from Daylight Chemical Information Systems, Inc (Daylight CIS), Irvine, California, contains many, along with citations to the original literature However, the logP values are most conveniently calculated by the "CLOGP” program, also available from Daylight CIS This program also lists experimental logP values when they are available in the Pomona92 database
  • the "calculated logP” (ClogP) is determined by the fragment approach of Hansch and Leo (cf , A Leo, in Comprehensive Medicinal Chemistry, Vol 4, C Hansch, P G Sammens, J B Taylor and C A Ramsden, Eds , p 295, Pergamon Press, 1990, incorporated herein by reference) The fragment approach is based on the chemical structure of each ingredient, and takes into account the numbers and types of atoms, the atom connectivity, and chemical bonding
  • the ClogP values which are the most reliable and widely used estimates for this physicochemical property, are preferably used instead of the experimental log
  • compositions herein can be made suitable for suspending particles in the composition, e g , particles of abrasives Deterqencv Builders
  • Detergent builders that are efficient for hard surface cleaners and have reduced filming/streaking characteristics at the critical levels are another optional ingredient
  • Preferred detergent builders are the carboxyhc acid detergent builders described hereinbefore as part of the polycarboxylic acid disclosure, including citric and tarta ⁇ c acids Tarta ⁇ c acid improves cleaning and can minimize the problem of filming/streaking that usually occurs when detergent builders are added to hard surface cleaners
  • the detergent builder is present at levels that provide detergent building, and, those that are not part of the acid pH adjustment described hereinbefore, are typically present at a level of from about 0 01 % to about 0 3%, more preferably from about 0 005% to about 0.2%, and most preferably from about 0 05% to about 0 1 %, by weight of the composition Buffers
  • compositions herein can also contain other various adjuncts such as buffers, preservatives, and antibacterial agents, which are known to the art for detergent compositions
  • buffers Preferably they are not used at levels that cause unacceptable filming/streaking
  • Buffers are an important class of adjuncts in the present compositions This occurs mainly as a result of the low levels of active employed
  • An ideal buffer system will maintain pH over a desired narrow range, while not leading to streaking/filming issues
  • Preferred buffers in the context of the invention are those which are highly volatile, yet can provide cleaning benefits in use As such, they are advantageous in that they can be used at higher levels than corresponding buffers that are less volatile
  • Such buffers tend to have low molecular weight, i e , less than about 150 g/mole and generally contain no more than one hydroxy group
  • Examples of preferred buffers include ammonia, methanol amine, ethanol amine, 2-am ⁇ no-2-methyl-1-propanol, 2-d ⁇ methylam ⁇ no-2-
  • Non-volatile buffers can also be used in this invention Such buffers are used at generally lower levels than the preferred levels because of increased streaking/filming tendencies
  • buffers include, but are not limited to, sodium carbonate, potassium carbonate and bicarbonate, 1 ,3-b ⁇ s(am ⁇ nomethy!) cyclohexane, sodium citrate, citric acid, maleic acid, tarta ⁇ c acid, and the like
  • Maleic acid is particularly preferred as a buffer because of its tendency not to induce surface damage
  • Citric acid is also desirable since it provides anti-microbial benefits as a registered EPA active
  • acidity has been found to promote better wetting and provide longer lasting "sheeting" effects.
  • non-volatile buffers are present in from about 0.001 % to about 0.05% by weight of the composition.
  • Non-limiting examples of other adjuncts are: enzymes such as proteases; hydrotropes such as sodium toluene sulfonate, sodium cumene sulfonate, and potassium xylene sulfonate; and aesthetic-enhancing ingredients such as colorants, providing they do not have an adverse impact on filming/streaking.
  • enzymes such as proteases
  • hydrotropes such as sodium toluene sulfonate, sodium cumene sulfonate, and potassium xylene sulfonate
  • aesthetic-enhancing ingredients such as colorants
  • Preservatives can also be used, and may be required in many of the compositions of the present invention, since they contain high levels of water.
  • preservatives include bronopol, hexitidine sold by Angus chemical (211 Sanders Road, Northbrook, Illinois, USA).
  • preservatives include Kathon ® , 2-((hydroxymethyl) (amino)ethanol, propylene glycol, sodium hydroxymethyl amino acetate, formaldehyde and glutaraldehyde, dichloro-s-triazinetrione, trichloro-s-triazinetrione, and quaternary ammonium salts including dioctyl dimethyl ammonium chloride, didecyl dimethyl ammonium chloride, C** 2 , C ⁇ 4 and C 16 dimethyl benzyl.
  • Preferred preservatives include 1 ,2-benzisothiazolin-3-one and polyhexamethylene biguanide sold by Avicia Chemicals (Wilmington, Delaware 19897), chlorhexidine diacetate sold by Aldrich-Sigma (1001 West Saint Paul Avenue, Milwaukee, Wl 53233), and sodium pyrithione sold by Arch Chemicals (501 Merritt Seven, P.O. Box 5204, Norwalk CT 06856).
  • preservatives are preferentially present at concentrations of from about 0.0001 % to about 0.01 %. These same preservatives can function to provide antibacterial control on the surfaces, but typically will require use at higher levels from about 0.005 to about 0.1 %.
  • antibacterial agents including quaternary ammonium salts
  • quaternary ammonium salts can be present, but are not preferred in the context of the present invention at high levels, i.e., at levels greater than about 0.05%.
  • Such compounds have been found to often interfere with the benefits of the preferred polymers.
  • quaternary ammonium surfactants tend to hydrophobically modify hard surfaces.
  • the preferred polymers are found to be ineffective in compositions comprising significant concentrations of quaternary ammonium surfactants.
  • amphoteric surfactants including lauryl betaines and coco amido betaines.
  • the level of cationic or amphoteric surfactant should be at levels below about 0.1 %, preferably below about 0.05%.
  • compositions for the cleaning of floors, counters, walls, and other surfaces for which no, or minimal, rinsing is required examples include ready-to-use aqueous cleaners and dilutable aqueous, multipurpose cleaners. These compositions can be used with conventional cleaning processes such as sponge mops, string mops, strip mops, cloth, paper towels, sponges, rags, and the like, as disclosed hereinafter.
  • compositions for use in the bathroom and/or shower on a regular basis provide the benefit of maintaining cleanliness and appearance rather than having to remove large amounts of built-up soil. Such compositions are used after each shower, bath, wash-up, and the like, and left on to protect the surface and make the removal of any subsequent soil easier. Such compositions are essentially dilute "usage" compositions.
  • compositions typically comprise: a. an effective amount to reduce the contact angle and/or increase surface hydrophihcity, up to about 0.5%, preferably from about 0.005% to about 0.4%, more preferably from about 0.01% to about 0.3%, by weight of the composition, of hydrophihc polymer, preferably substantive, that renders the treated surface hydrophihc, and preferably is a polymer selected from the group consisting of: polystyrene sulfonate; polyvinyl pyrrohdone; polyvinyl pyrrohdone acrylic acid copolymer; polyvinyl pyrrohdone acrylic acid copolymer sodium salt; polyvinyl pyrrohdone acrylic acid copolymer potassium salt; polyvinyl pyrrohdone- vinyl imidazoline; polyvinyl pyridine; polyvinyl pyridine n-oxide; and mixtures thereof; and more preferably polyvinyl pyridine n-oxide; b.
  • primary detergent surfactant preferably from about 0.005% to about 0.5%, more preferably from about 0.01% to about 0.4%, most preferably from about 0.025% to about 0.3%, by weight of the composition
  • said primary detergent surfactant preferably comprising alkyl polysaccharide detergent surfactant having an alkyl group containing from about 8 to about 18 carbon atoms, more preferably from about 8 to about 16 carbon atoms, and from about one to about four, preferably from about one to about 1.5 saccharide moieties per molecule and/or a combination consisting of alkyl polysaccharide detergent surfactant having an alkyl group containing from about 8 to about 18 carbon atoms, more preferably from about 8 to about 16 carbon atoms, and from about one to about four, preferably from about one to about 1.5 saccharide moieties per molecule together with an alkyl ethoxylate comprising from about 8 to about 16 carbon atoms and from about 4 to about 25 oxyethylene units;
  • an effective amount to provide increased cleaning of organic cleaning solvent preferably from about 0.25% to about 5%, preferably from about 0.5% to about 4%, more preferably from about 0.5% to about 3%, by weight of the composition, and is preferably selected from the group consisting of: mono-propylene glycol mono-propyl ether; mono-propylene glycol mono-butyl ether; di-propylene glycol mono-propyl ether; di-propylene glycol mono-butyl ether; di-propylene glycol mono-butyl ether; tri-propylene glycol mono-butyl ether; ethylene glycol mono-butyl ether; diethylene glycol mono-butyl ether, ethylene glycol mono-hexyl ether; diethylene glycol mono-hexyl ether; and mixtures thereof; d.
  • a minor amount that is less than the amount of primary detergent surfactant b. preferably from about 0.005% to about 0.5%, more preferably from about 0.01 % to about 0.4%, and even more preferably from about 0.025% to about 0.3%, by weight of the composition, of cosurfactant, preferably anionic and/or nonionic detergent surfactant, more preferably selected from the group consisting of: C 8 -C 12 linear sulfonates, C 8 -C 18 alkylbenzene sulfonates; C 8 -C ⁇ 8 alkyl sulfates; C 8 -C-* 8 alkylpolyethoxy sulfates; and mixtures thereof; e.
  • cosurfactant preferably anionic and/or nonionic detergent surfactant, more preferably selected from the group consisting of: C 8 -C 12 linear sulfonates, C 8 -C 18 alkylbenzene sulfonates; C 8 -C ⁇ 8 alkyl s
  • an effective amount to improve cleaning and/or antimicrobial action preferably from about 0.01% to about 1%, more preferably from about 0.01% to about 0.5%, and even more preferably from about 0.01% to about 0.25%, by weight of the composition, of water-soluble mono- or polycarboxylic acid; f. optionally, an effective amount, up to about 1 %, preferably from about 0.01 % to about
  • cyclodextrin preferably alpha, beta, or gamma substituted cyclodextrin, and optionally, with short chain (1-4 carbon atoms) alkyl or hydroxyalkyl groups
  • the cyclodextrin is preferably beta-cyclodextrin, hydroxypropyl cyclodextrin, or mixtures thereof
  • an effective amount to provide bleaching, cleaning, and/or antibacterial action up to about 5%, preferably from about 0.1 % to about 4%, more preferably from about 1 % to about 3%, by weight of the composition, of hydrogen peroxide; h.
  • composition optionally, from about 0.005% to about 1 %, preferably from about 0.005% to about 0.5%, more preferably from about 0.01 % to about 0.1 %, by weight of the composition, of a thickening polymer selected from the group consisting of polyacrylates, gums, and mixtures thereof; i. optionally, an effective amount of perfume to provide odor effects, and/or additional adjuvants; and j.
  • an effective amount preferably from about 0.0001 % to about 0.1 %, more preferably from about 0.00025% to about 0.05%, and even more preferably from about 0.001 % to about to about 0.01 %, by weight of the composition, of suds suppressor, preferably silicone suds suppressor, and optionally, but preferably, the balance being an aqueous solvent system, comprising water, and optional water soluble solvent, and wherein said composition has a pH under usage conditions of from about 2 to about 12, preferably from about 3 to about 11.5, with acidic compositions having a pH of from about 2 to about 6, preferably from about 3 to about 5.
  • ingredients in these "daily shower" compositions are selected so as to avoid the appearance of spots/films on the treated surface, even when the surface is not rinsed or wiped completely to a dry state.
  • a polyvinylpyridine amine oxide, or polyvinylpyridine polymer, and a preferred primary detergent surfactant, such as an alkyl polysaccharide detergent surfactant are required for optimum appearance.
  • Glass cleaner compositions typically contain less materials than other compositions, since glass composition residues are more easily seen. For these compositions, only the optimal polymers and surfactants, and methods which provide at least some rubbing action, are required.
  • Glass cleaner compositions comprise: a. an effective amount to reduce the contact angle and/or increase surface hydrophihcity, up to about 0.5%, preferably from about 0.005% to about 0.4%, more preferably from about 0.01% to about 0.3%, by weight of the composition, of hydrophihc polymer, preferably substantive, that renders the treated surface hydrophihc, and preferably is a polymer selected from the group consisting of: polystyrene sulfonate; polyvinyl pyrrohdone; polyvinyl pyrrohdone acrylic acid copolymer; polyvinyl pyrrohdone acrylic acid copolymer sodium salt; polyvinyl pyrrohdone acrylic acid copolymer potassium salt; polyvinyl pyrrohdone- vinyl imi
  • primary detergent surfactant preferably from about 0.001 % to about 0.5%, more preferably from about 0.005% to about 0.3%, most preferably from about 0.025% to about 0.3%, by weight of the composition
  • said primary detergent surfactant preferably comprising as the primary surfactant, alkyl polysaccharide detergent surfactant having an alkyl group containing from about 8 to about 18 carbon atoms, more preferably from about 8 to about 16 carbon atoms, the alkyl distribution wherein at least about 50% of the chainlength mixture comprises from about 10 carbon atoms to about 16 carbon atoms, optionally, as the primary surfactant, but preferably as the cosurfactant, a minor amount that is less than the amount of primary surfactant, e.g., from about 0.0001 % to about 0.3%, preferably from about 0.001 % to about 0.2%, more preferably from about 0.05% to about 0.2%, of cosurfactant; c.
  • an effective amount to provide increased cleaning e.g., from about 0.5% to about 7%, preferably from about 0.5% to about 5%, more preferably from about 0.5% to about 3%, of one or more organic cleaning solvents, preferably selected from the group consisting of: mono-propylene glycol mono-propyl ether; mono-propylene glycol mono-butyl ether; di-propylene glycol mono-propyl ether; di-propylene glycol mono-butyl ether; di-propylene glycol mono-butyl ether; tri-propylene glycol mono- butyl ether, ethylene glycol mono-butyl ether, diethylene glycol mono-butyl ether, ethylene glycol mono-hexyl ether, diethylene glycol mono-hexyl ether, and mixtures thereof, d optionally, an effective amount to provide bleaching, cleaning, and/or antibacterial action, up to about 5%, preferably from about 0 1% to about 4%, more
  • Glass cleaning compositions comprising the polymers of the present invention can be used as a spray execution, and with one or more substrates, including rags, cloths, or paper towels
  • some of the preferred polymers such as polyvinyl amine oxides provide anti-fog benefits
  • the hygroscopic properties of the preferred polymers are responsible for the benefits
  • the general purpose and conventional floor cleaning compositions of the present invention can be either liquid or solid and can be used diluted, or, for the liquid, full strength These compositions comprise a an effective amount to reduce the contact angle and/or increase surface hydrophihcity, up to about 0 5%, preferably from about 0 005% to about 0 2%, more preferably from about 0 0125% to about 0 1 %, by weight of the composition, of hydrophihc polymer, preferably substantive, that renders the treated surface hydrophihc, and preferably is a polymer selected from the group consisting of polystyrene sulfonate, polyvinyl pyrrohdone, polyvinyl pyrrohdone acrylic acid copolymer, polyvinyl pyrrohdone acrylic acid copolymer sodium salt, polyvinyl pyrrohdone acrylic acid copolymer potassium salt, polyvinyl pyrrohdone- vinyl imidazo ne, polyvinyl pyridine
  • an effective amount to provide increased cleaning of organic cleaning solvent preferably from about 0.5% to about 10%, preferably from about 0.5% to about 6%, more preferably from about 0.5% to about 5%, by weight of the composition, and is preferably selected from the group consisting of: mono-propylene glycol mono-propyl ether; mono-propylene glycol mono-butyl ether; di-propylene glycol mono-propyl ether; di-propylene glycol mono-butyl ether; di-propylene glycol mono-butyl ether; tri-propylene glycol mono-butyl ether; ethylene glycol mono-butyl ether; diethylene glycol mono-butyl ether, ethylene glycol mono-hexyl ether; diethylene glycol mono-hexyl ether; and mixtures thereof; d.
  • an effective amount to improve cleaning and/or antimicrobial action preferably from about 0.01 % to about 1 %, more preferably from about 0.01 % to about 0.5%, and even more preferably from about 0.01 % to about 0.25%, by weight of the composition, of water-soluble mono- or polycarboxylic acid; e.
  • cyclodextrin preferably alpha, beta, or gamma substituted cyclodextrin, and optionally, with short chain (1-4 carbon atoms) alkyl or hydroxyalkyl groups;
  • the cyclodextrin is preferably beta-cyclodextrin, hydroxypropyl cyclodextrin, or mixtures thereof;
  • an effective amount to provide bleaching, cleaning, and/or antibacterial action up to about 5%, preferably from about 0.1 % to about 4%, more preferably from about 1 % to about 3%, by weight of the composition, of hydrogen peroxide; g. optionally, from about 0.005% to about 1 %, preferably from about 0.005% to about 0.5%, more preferably from about 0.01 % to about 0.1 %, by weight of the composition, of a thickening polymer selected from the group consisting of polyacrylates, gums, and mixtures thereof; h. optionally, an effective amount of perfume to provide odor effects, and/or additional adjuvants; and i.
  • an effective amount preferably from about 0.0001 % to about 0.1 %, more preferably from about 0.00025% to about 0.05%, and even more preferably from about 0.001 % to about to about 0.01 %, by weight of the composition, of suds suppressor, preferably silicone suds suppressor, and the balance being an aqueous solvent system, comprising water and optional water soluble solvent, or, less preferably, the balance comprising water and inorganic salts including detergent builders and/or inert salts and/or abrasives, and wherein said composition has a pH under usage conditions of from about 2 to about 12, preferably from about 3 to about 11 5, with acidic compositions having a pH of from about 2 to about 6, preferably from about 3 to about 5 D Wet Wipes for Glass and Shiny Surfaces, Floors, Counter Walls and Other Surfaces
  • the glass cleaning compositions described in Section B above and General Purpose and Floor compositions described in Section C above can be used in a pre-moistened wipe
  • the wipe substrate can be composed of suitable unmodified and/or modified naturally occurring fibers including cotton, Esparto grass, bagasse, hemp, flax, silk, wool, wood pulp, chemically modified wood pulp, jute, ethyl cellulose, and/or cellulose acetate
  • suitable synthetic fibers can comprise fibers of one, or more, of polyvinyl chloride, polyvinyl fluoride, polytetrafluoroethylene, polyvmyhdene chloride, polyacryhcs such as ORLON®, polyvinyl acetate, Rayon®, polyethylvinyl acetate, non-soluble or soluble polyvinyl alcohol, polyolefms such as polyethylene (e g , PULPEX ® ) and polypropylene, polyamides such as nylon, polyesters such as DACRON ® or
  • the fibers useful herein can be hydrophihc, hydrophobic, or can be a combination of both hydrophihc and hydrophobic fibers As indicated above, the particular selection of hydrophihc or hydrophobic fibers depends upon the other materials included in the absorbent (and to some degree) the scrubbing layer described hereinafter Suitable hydrophihc fibers for use in the present invention include cellulosic fibers, modified cellulosic fibers, rayon, cotton, polyester fibers such as hydrophihc nylon (HYDROFIL®) Suitable hydrophihc fibers can also be obtained by hydrophi zing hydrophobic fibers, such as surfactant-treated or silica-treated thermoplastic fibers derived from, for example, polyolefms such as polyethylene, polypropylene, polyacryhcs, polyamides, polystyrenes, polyurethanes and the like
  • Suitable wood pulp fibers can be obtained from well-known chemical processes such as the Kraft and sulfite processes It is especially preferred to derive these wood pulp fibers from southern soft woods due to their premium absorbency characteristics
  • These wood pulp fibers can also be obtained from mechanical processes, such as ground wood, refiner mechanical, thermomechanical, chemimechanical, and chemi-thermomechanical pulp processes Recycled or secondary wood pulp fibers, as well as bleached and unbleached wood pulp fibers, can be used
  • hydrophihc fibers for use in the present invention are chemically stiffened cellulosic fibers
  • the term "chemically stiffened cellulosic fibers” means cellulosic fibers that have been stiffened by chemical means to increase the stiffness of the fibers under both dry and aqueous conditions
  • Such means can include the addition of a chemical stiffening agent that, for example, coats and/or impregnates the fibers
  • Such means can also include the stiffening of the fibers by altering the chemical structure, e g , by crosshnking polymer chains
  • the fibers can optionally be combined with a thermoplastic material.
  • thermoplastic material Upon melting, at least a portion of this thermoplastic material migrates to the intersections of the fibers, typically due to interfiber capillary gradients. These intersections become bond sites for the thermoplastic material. When cooled, the thermoplastic materials at these intersections solidify to form the bond sites that hold the matrix or substrate of fibers together in each of the respective layers. This can be beneficial in providing additional overall integrity to the cleaning wipe.
  • the melting and migration of the thermoplastic material also has the effect of increasing the average pore size of the resultant substrate, while maintaining the density and basis weight of the substrate as originally formed. This can improve the fluid acquisition properties of the thermally bonded substrate upon initial exposure to fluid, due to improved fluid permeability, and upon subsequent exposure, due to the combined ability of the stiffened fibers to retain their stiffness upon wetting and the ability of the thermoplastic material to remain bonded at the fiber intersections upon wetting and upon wet compression.
  • thermoplastic materials useful in the present invention can be in any of a variety of forms including particulates, fibers, or combinations of particulates and fibers.
  • Thermoplastic fibers are a particularly preferred form because of their ability to form numerous interfiber bond sites.
  • Suitable thermoplastic materials can be made from any thermoplastic polymer that can be melted at temperatures that will not extensively damage the fibers that comprise the primary substrate or matrix of each layer.
  • the melting point of this thermoplastic material will be less than about 190°C, and preferably between about 75°C and about 175°C.
  • thermoplastic material should be no lower than the temperature at which the thermally bonded absorbent structures, when used in the cleaning pads, are likely to be stored.
  • the melting point of the thermoplastic material is typically no lower than about 50°C.
  • the thermoplastic materials, and in particular the thermoplastic fibers can be made from a variety of thermoplastic polymers, including polyolefins such as polyethylene (e.g., PULPEX®) and polypropylene, polyesters, copolyesters, polyvinyl acetate, polyethylvinyl acetate, polyvinyl chloride, polyvinylidene chloride, polyacryhcs, polyamides, copolyamides, polystyrenes, polyurethanes and copolymers of any of the foregoing such as vinyl chloride/vinyl acetate, and the like.
  • polyolefins such as polyethylene (e.g., PULPEX®) and polypropylene
  • polyesters, copolyesters
  • suitable thermoplastic materials include hydrophobic fibers that have been made hydrophihc, such as surfactant-treated or silica-treated thermoplastic fibers derived from, for example, polyolefins such as polyethylene or polypropylene, polyacryhcs, polyamides, polystyrenes, polyurethanes and the like.
  • the surface of the hydrophobic thermoplastic fiber can be rendered hydrophihc by treatment with a surfactant, such as a nonionic or anionic surfactant, e.g., by spraying the fiber with a surfactant, by dipping the fiber into a surfactant or by including the surfactant as part of the polymer melt in producing the thermoplastic fiber.
  • a surfactant such as a nonionic or anionic surfactant
  • spraying the fiber with a surfactant by dipping the fiber into a surfactant or by including the surfactant as part of the polymer melt in producing the thermoplastic fiber.
  • the surfactant will tend to remain at the surfaces of the thermoplastic fiber.
  • Suitable surfactants include nonionic surfactants such as Brij® 76 manufactured by ICI Americas,
  • thermoplastic fibers can be applied to the thermoplastic fibers at levels of, for example, from about 0.2 to about 1 gram per square centimeter of thermoplastic fiber.
  • thermoplastic fibers can be made from a single polymer (monocomponent fibers), or can be made from more than one polymer (e.g., bicomponent fibers).
  • bicomponent fibers refers to thermoplastic fibers that comprise a core fiber made from one polymer that is encased within a thermoplastic sheath made from a different polymer. The polymer comprising the sheath often melts at a different, typically lower, temperature than the polymer comprising the core. As a result, these bicomponent fibers provide thermal bonding due to melting of the sheath polymer, while retaining the desirable strength characteristics of the core polymer.
  • Suitable bicomponent fibers for use in the present invention can include sheath/core fibers having the following polymer combinations: polyethylene/ polypropylene, polyethylvinyl acetate/polypropylene, polyethylene/polyester, polypropylene/polyester, copolyester/polyester, and the like.
  • Particularly suitable bicomponent thermoplastic fibers for use herein are those having a polypropylene or polyester core, and a lower melting copolyester, polyethylvinyl acetate or polyethylene sheath (e.g., those available from Danaklon a/s, Chisso Corp., and CELBOND®, available from Hercules). These bicomponent fibers can be concentric or eccentric.
  • the terms “concentric” and “eccentric” refer to whether the sheath has a thickness that is even, or uneven, through the cross-sectional area of the bicomponent fiber. Eccentric bicomponent fibers can be desirable in providing more compressive strength at lower fiber thicknesses.
  • the absorbent layer can also comprise a HIPE-derived hydrophihc, polymeric foam. Such foams and methods for their preparation are described in U.S. Patent 5,550,167 (DesMarais), issued August 27, 1996; and commonly assigned U.S. patent application Serial No.
  • the wipe can consist of one or more layers including an optional scrub layer for maximum cleaning efficiency.
  • the substrate preferably contains fibers comprising of some combination of hydrophihc and hydrophobic fibers, and more preferably fibers comprising at least about 30% hydrophobic fibers and even more preferably at least about 50% of hydrophobic fibers in a hydroentangled substrate.
  • hydrophobic fibers includes polyester fibers as well as fibers derived from polyolefins such as polyethylene, polypropylene, and the like.
  • the combination of hydrophobic fibers and absorbent hydrophihc fibers represents a particularly preferred embodiment for the single substrate pre-moistened wipe since the absorbent hydrophihc fibers, typically cellulose, aid in the sequestering and removal of dust and other soils present on the surface.
  • the hydrophobic fibers are particularly useful in cleaning greasy soils, in improving the pre-moistened wipe and in lowering the friction between substrate and hard surface (glide).
  • the inventors have found polyester fibers, particularly polyester fibers in combination with polypropylene fibers, to be most effective in providing excellent glide, followed by polyethylene fibers.
  • Fiber blends are more difficult to rank order for providing excellent glide, though it has been found that even low levels of polyester or polypropylene fiber content can significantly improve the glide performance in virtually all cases. Fiber compositions that typically have a coefficient of friction with glass can be improved, as needed, by impregnating or chemically bonding the wipe with low levels of silicone or other chemicals that are known to reduce friction. Silicones are preferred since they also reduce composition sudsing, leading to improved result.
  • the substrate can be made by nonwoven dry forming techniques, such as air-laying, or alternatively by wet laying, such as on a paper-making machine.
  • nonwoven dry forming techniques such as air-laying, or alternatively by wet laying, such as on a paper-making machine.
  • Other non-woven manufacturing techniques including but not limited to techniques such as melt blown, spunbonded, needle punched, and hydroentanglement methods, can also be used.
  • the dry fibrous substrate can be an airlaid nonwoven substrate comprising a combination of natural fibers, staple length synthetic fibers, and a latex binder.
  • the dry fibrous substrate can be from about 20% to about 80%, by weight, of wood pulp fibers, from about 10% to about 60%, by weight, of staple length polyester fibers, and from about 10% to about 25%, by weight, of binder.
  • the dry, fibrous substrate can have a basis weight of between about 30 and about 100 grams per square meter.
  • the density of the dry substrate can be measured after evaporating the liquid from the premoistened wipe, and the density can be less than about 0.15 grams per cubic centimeter.
  • the density is the basis weight of the dry substrate divided by the thickness of the dry substrate, measured in consistent units, and the thickness of the dry substrate is measured using a circular load foot having an area of about 2 square inches and which provides a confining pressure of about 95 grams per square inch
  • the dry substrate can have a basis weight of about 64 grams per square meter, a thickness of about 0 06 cm, and a density of about 0 11 grams per cubic centimeter
  • the dry fibrous substrate can comprise at least about 50 percent, by weight, of wood pulp fibers, and more preferably at least about 70 percent by weight wood pulp fibers
  • the cleaning sheet has at least two regions where the regions are distinguished by basis weight
  • the measure for basis weight is described in US Provisional Applications 60/055,330 and 60/047,619 Briefly, the measurement is achieved photographically, by differentiating dark (low basis weight) and light (high basis) network regions
  • the cleaning sheet comprises one or more low basis weight regions, wherein the low basis reg ⁇ on(s) have a basis weight that is not more than about 80% of the basis weight of the high basis weight regions
  • the first region is relatively high basis weight and comprises an essentially continuous network
  • the second region comprises a plurality of mutually discrete regions of relatively low basis weight and which are circumscribed by the high basis weight first region
  • a preferred cleaning sheet comprises a continuous region having a basis weight of from aoout 30 to about 120 grams per square meter and a plurality of discontinuous regions circumscribed by the high basis weight region, wherein the discontinuous regions are disposed in a random, repeating pattern and have a basis weight of not more than about 80% of
  • the cleaning sheet will have, in addition to regions which differ with regard to basis weight, substantial macroscopic three-dimensionality
  • the term "macroscopic three-dimensionality”, when used to describe three dimensional cleaning sheets means a three dimensional pattern is readily visible to the naked eye when the perpendicular distance between the viewer's eye and the plane of the sheet is about 12 inches
  • the three dimensional structures of the pre-moistened sheets of the present invention are cleaning sheets that are non-planar, in that one or both surfaces of the sheets exist in multiple planes
  • the term “planar” refers to sheets having fine-scale surface aberrations on one or both sides, the surface aberrations not being readily visible to the naked eye when the perpendicular distance between the viewer's eye and the plane of the sheet is about 12 inches
  • the observer will not observe that one or both surfaces of the sheet will exist in multiple planes so as to be three-dimensional
  • the measure for three-dimensionality is described in US Provisional Applications
  • a macroscopically three-dimensional cleaning sheet has a first outward surface and a second outward surface wherein at least one of the outward surfaces has a peak to peak distance of at least about 1 mm and a surface topography index from about 0 01 mm to about 10 mm
  • the macroscopically three-dimensional structures of the pre-moistened wipes of the present invention optionally comprise a scrim, which, when heated and the cooled, contracts so as to provide
  • the pre-moistened wipe is made by wetting the dry substrate with at least about 1.0 gram of liquid composition per gram of dry fibrous substrate.
  • the dry substrate is wetted with at least about 1.5 and more preferably at least about 2.0 grams of liquid composition per gram of the dry fibrous substrate.
  • the exact amount of solution impregnated on the wipe will depend on the product's intended use.
  • optimum wetness is from about 1 to about 5 grams of solution per gram of substrate.
  • the pre-moistened wipe can preferably include an absorbent core reservoir with a large capacity to absorb and retain fluid.
  • the absorbent reservoir has a fluid capacity of from about 5 grams to about 15 grams per gram of absorptive material.
  • Pre-moistened wipes intended to be used for the cleaning of walls, exterior surfaces, etc. will have a capacity of from about 2 grams to about 10 grams of dry fibrous substrate. D1. Glass Wipes:
  • Pre-moistened wipes for use on glass can comprise either mono-layer or multi-laminate substrates.
  • mono-layer substrates since the surface is not wiped to dryness in the context of a pre-moistened wipe, it is essential that the content of non-volatile materials in the aqueous composition be kept to a minimum.
  • the actives described above are preferably used at even lower levels for best end result. Also, it has been found that compositions consisting solely of organic hydrophobic cleaning solvents can deliver an excellent end result along with good cleaning in a pre-moistened wipe.
  • the cleaning solvents are employed in a level of from about 0.5% to about 10%, more preferably from about 1% to about 5%.
  • Preferred hydrophobic organic cleaning solvents include mono-propylene glycol propyl ether, mono-propylene glycol butyl ether, mono- ethylene glycol butyl ether, and mixtures thereof.
  • Other aqueous hydrophihc solvents such as ethanol, isopropanol, isobutanol, 2-butanol, methoxypropanol, and the like, can be used to provide perfume lift.
  • Buffers with molecular weights of less than about 150 g/mole as described above can be used advantageously to improve cleaning without harming end result performance
  • preferred buffers include ammonia, methanol amine, ethanol amine, 2-am ⁇ no-2- methyl-1-propanoi, 2-d ⁇ methylam ⁇ no-2-methyl-1-propanol, acetic acid, glycolic acid, and the like Most preferred among these are ammonia, 2-d ⁇ methylam ⁇ no-2-methyl-1-propanol and acetic acid When used, these buffers are present from about 0 005% to about 0 5%, by weight of the composition, with the higher levels being more preferred for the more volatile chemicals
  • simple compositions using low levels of non-volatile surfactant with preferably high levels of the preferred organic cleaning solvent are sufficient to provide excellent cleaning and wetting performance even in the absence of the hydrophihc polymer
  • the addition of polymer can advantageously be used to provide other benefits such as anti-spotting, antif
  • US Patent 4,276,338 discloses a multi-laminate absorbent article comprising adjacent first and second layers maintained together to improve wickmg
  • US Patent 4,178,407 discloses a single towel having absorbent surface on both sides that additionally comprises an inner layer impermeable to liquid The towel is designed to have little wet strength and the layer of absorbent material consists of loose fibers
  • US Patent 4,448,704 discloses an article suitable for cleaning hard surfaces such as glass The article may be wet or comprise compositions contained within rupturable pouches
  • the article of U S Patent 4,448,704 is pre-washed with deminerahzed water or the solution used to impregnate said article, the liquid composition has a surface tension of less than 35 dynes/cm, and preferably includes a surface-active agent and a partially este ⁇ fied resin such as a partially este ⁇ fied styren
  • the pre-moistened wipes of the present invention advantageously are not pre-washed, yet the inventors have found that they deliver excellent end result even as single layered sheets
  • An additional benefit of the premoistened glass wipes is to keep hnting at a minimum Steps such as pre-washing typically loosens up fibers, making the substrate more prone to hnting
  • the tightness of the fiber integration is optimally achieved in processing of the fibrous materials, not during the making or preparation of the pre- moistened wipe
  • preferred compositions of the present invention display improved hnting
  • the liquid composition used on the pre-moistened wipes for glass is preferably substantially free of surface active agents As such, the surface tension of the liquid does not need to reduce surface tension below 35 dynes/cm
  • the wipe can have two sides that differ in function One side is pre-moistened and acts to
  • a preferred embodiment includes a dry fibrous substrate substrate where at least about 65% of the dry fibrous substrate is composed of hydrophobic fibers such as polyester, polypropylene, polyethylene fibers, and the like, and lower levels of hydrophihc fibers such as wood pulp, cotton fibers, and the like, are at levels of less than about 35%
  • hydrophobic fibers such as polyester, polypropylene, polyethylene fibers, and the like
  • hydrophihc fibers such as wood pulp, cotton fibers, and the like
  • Hydrophobic fibers in the substrate of the premoistened wipe provide glide benefits whether the wipe is completely pre-moistened and when the wipe is completely dry This is significant since wipes become increasingly dry as they are used
  • the level of C 14 or higher chainlength surfactants which are known to provide lubricity benefits, can be substantially reduced or preferably altogether eliminated from the liquid composition used in the pre-moistened wipe herein while still preserving excellent glide (low friction) characteristics
  • wipes comprising some level of hydrophobic fibers, particularly polyester, also provides increased flexibility in developing pre-moistened wipes for glass at acidic pH It has been found that acidic cleaning compositions significantly hinder the glide of cellulosic substrates such as common paper towels or cellulosic pre-moistened wipes
  • the wipe dimensions can also be used to control dosing as well as provide ergonomic appeal
  • Preferred wipe dimensions are from about 5 1/2 inches to about 9 inches in length, and from about 5 1/2 inches to about 9 inches in width to comfortably fit in a hand
  • the wipe preferably has dimensions such that the length and width differ by no more than about 2 inches
  • wipes are preferably bigger so that they can used and then folded, either once or twice, so as to contain dirt within the inside of the fold and then the wipe can be re-used
  • the wipe has a length from about 5 V- inches to about 13 inches and a width from about 10 inches to about 13 inches As such, the wipe can be folded once or twice and still fit comfortably in the hand
  • the wipe consists of a multi-laminate substrate comprising a premoistened outer layer, an impermeable film or membrane inner layer and second outer-layer which is substantially dry
  • an optional absorbent reservoir layer can be placed between the pre-moistened first outer-layer and the impermeable film or membrane inner layer
  • the dimensions of the reservoir layer are smaller than the dimensions of the two outer layers to prevent liquid wickmg from the front layer onto the back layer
  • a multi-laminate substrate as herein described can be highly desirable in that it allows for a dry buffing step, aimed at substantially removing most of the liquid remaining on the glass following application of the wet side of the pre-moistened wipe on the glass.
  • the inventors have found that even with a buffing step, hydrophihc polymer in the pre-moistened wipe, if present, remains on the glass providing anti-fog properties to the glass
  • the buffing step also provides improved overall flexibility in the level of solids used in the liquid composition because most of the solids are wiped up together with the remainder of the aqueous composition during the buffing step
  • very low levels preferably less than about 0 02%, water-soluble, though crystalline, surfactants because of improved propensity for dry the substrate to remove such crystalline solids from the glass surface
  • the multi-laminate substrate is further advantageously used in the context of heavier soiled situations, such as those encountered on outside windows or car glass
  • the multi-laminate substrate reduces the amount of dirty liquid pushed around by the pre-moistened wipe
  • the outer pre-moistened layer contain at least about 30% hydrophobic fibers for oil removal and glide
  • the impermeable inner layer is most preferably polyethylene, polypropylene, or mixtures thereof
  • the composition mixture and thickness of the impermeable layer is chosen so as to minimize, or more preferably eliminate any seepage of liquid from the pre-moistened first outer-layer to the dry second outer- layer
  • Use of a reservoir core layer or of a high fluid capacity pre-moistened outer-layer will test the impermeable layer, such that more than one impermeable layer can be required to ensure sufficient dryness for the second outer-layer of the wipe
  • the reservoir layer if present, will preferably consist of treated or untreated cellulose, either as a stand-alone material or as a hybrid with hydrophobic fibers
  • the hydrophobic content of the reservoir layer is preferably less than about 30%, more preferably less than about 20% by weight of the total fiber content of the layer
  • the reservoir consists of
  • a starter kit comprises a sturdy box or other receptacle capable of holding from about eight to about twenty-four wipes which have been folded at least once, and lower cost packages capable of holding from about five to about twelve wipes are used as refill packages
  • the pre-moistened wipe can be used as a stand-alone or in conjunction with an implement comprising a handle and attachment device for the wipe
  • implement signifies any physical means for attachment of substrate, such as pad, dry wipe premoistened wipe, and the like
  • the pre-moistened wipe includes one or more preservatives so as to ensure fungistatic benefits
  • preservatives to be used in association with the pre-moistened wipes of the invention include methyl paraben, bronopol, hexetidine, dichloro-s-t ⁇ azinet ⁇ one, trichloro-s-triazinet ⁇ one, and quaternary ammonium salts including dioctyl dimethyl ammonium chloride, didecyl dimethyl ammonium chloride, C* ⁇ 2 , C 14 and C- I6 dimethyl benzyl (Bardac® 2280 and Barquat® MB-80 sold by Lonza), and the
  • aqueous cleaning compositions described in Sections B and C above can be used in a pre-moistened wipe for general purpose, counter, wall and floor cleaning
  • the material descriptions and processes described above in Sections D and D1 are also applicable to floor, counter and wall cleaning methods It is particularly advantageous in the context of floor wipes to have structures with three-dimensionality
  • the three-dimensional structure of the substrates described above have been found to provide improved hair pick-up relative to planar sheets, which in a wet surface environment is surprising
  • the user advantageously uses slight weaving motions in an up-and-down wiping pattern to maximize hair pick-up
  • the substrate can optionally include an absorbent core reservoir layer with a large capacity to absorb and retain fluid
  • the absorbent reservoir layer has a fluid capacity of from about 5 to about 15 grams per gram of absorptive material
  • Pre-moistened wipes intended to be used for the cleaning of walls, exterior surfaces, etc will have an absorbent capacity of from about 2 to about 10 grams of liquid per gram of dry fibrous substrate Since there is no rinsing step in the context of a general purpose pre-moistened wipe, it is essential that the non-volatile content be kept to a minimum to avoid film/streak residue from product
  • the active materials described in Section C "General purpose and Conventional Floor Cleaners" above are preferably used at even lower levels for best end result Also, it has been found that compositions consisting of primarily organic hydrophobic cleaning solvents can deliver an excellent
  • the premoistened wipe has the added convenience of delivering the cleaning and disinfectancy benefits in one package.
  • the residual properties result from a combination of low vapor pressure and high cidal efficacy of the antimicrobial actives associated with the compositions of the present invention.
  • residual disinfectancy benefits if present in the context of compositions comprising a very low level of surfactant, are even more easily achieved in compositions wherein the level of surfactants is raised.
  • Residual disinfectancy in addition to excellent end result, can provide consumers with reassurance as to the effectiveness of the wet wipe. Such reassurance is most important for tasks such as cleaning of surfaces that are particularly susceptible to harboring germs, most particularly counter tops, stove tops, appliances, sinks, furniture, showers, glass and other fixtures that are near or inside the kitchen or bathroom(s).
  • Preferred antimicrobial actives for residual benefits as delivered from a wet wipe or a dry wipe that becomes wet as a result of contact with a wet composition during the cleaning process include Kathon®, 2-((hydroxymethyl) (amino)ethanol, propylene glycol, sodium hydroxymethyl amino acetate, formaldehyde, and glutaraldehyde, quaternary ammonium salts such as dioctyl dimethyl ammonium chloride, octyl decyl dimethyl ammonium chloride, didecyl dimethyl ammonium chloride, C 12 ,C 14 and C 6 dimethyl benzyl (Bardac® 2280 and Barquat® MB-80 sold by Lonza), dichloro-s-triazinetrione, trichloro-s-triazinetrione, and more preferably tetrakis(hydroxymethyl) phosphonium sulphate (THPS), 1 ,2-benzisothiazolin-3-one sold
  • the specific antimirobial actives and combinations thereof are chosen so as to be effective against specific bacteria, as desired by the formulator.
  • the antimicrobial actives are chosen to be effective against gram-positive and gram-negative bacteria, enveloped and non-enveloped viruses, and molds that are commonly present in consumer homes, hotels, restaurants, commercial establishments and hospitals.
  • the antimicrobials provide residual disinfectancy against Salmonella choleraesuis, Pseudomonas aeruginosa, Staphylococcus aureus and Escherichia coli, and combinations thereof.
  • the antimicrobial actives are chosen to have residual disinfectancy benefits against more than one bacterial organism, and more preferably against at least one gram-negative organism and at least one gram-positive organism.
  • compositions at a pH 10.5 or greater or a pH of 3 or lower are found to deliver the desired residual efficacy.
  • the preferred hydrophihc, substantive polymer can be used to improve residuality, particularly for voltaile actives such as acetic acid.
  • the use of pH can also help lower the level of the above actives needed to achieve residual.
  • Preferred actives that are effective as a result of pH include lactic acid, glycolic acid, C 8 ,C 9 ,C 10 fatty acids, sodium hydroxide, potassium hydroxide.
  • This approach i.e., using a combination of hydrophobic organic solvent plus volatile buffer plus optionally low levels of non-volatile raw materials to deliver a superior end result, in combination with effective and low streaking antimicrobials, can be used in a variety of practical applications herein disclosed, including general purpose cleaners, glass cleaners, glass cleaner wipes, solutions used with disposable pads (either with or without mop implements).
  • perfume incorporation can be achieved by directly applying concentrated perfume to either the wipe (or pad). In this manner, virtually any perfume can be used. In order to minimize any residue negatives that can be caused by the concentrated perfume, the perfume is preferentially applied to the perimeter of the wipe or pad, or to areas that do not directly contact the surface to be treated. In another embodiment, perfume can also be added into the package containing the wipes.
  • Preferred suds suppressors are those that are effective at levels of no more than about 0.1 grams of suds suppressor per gram of substrate, more preferably at levels less than about 0.01 grams suds suppressor per gram of substrate, most preferably, less than about 0.005 grams suds suppressor per gram of substrate.
  • the most preferred suds suppressor in this context is DC AF, manufactured by the Dow Corning company.
  • the use of suds suppressors to improve surface appearance is particularly significant since these materials are effective at very low levels.
  • compositions for Use with Disposable Cleaning Pads The compositions described in the previous sections on glass wipes and floor wipes also pertain to a cleaning system where solution is applied to the surface and then cleaned with a disposable cleaning pad particularly since it again involves a no-rinse cleaning application. The proper selection of ingredients and levels used can have a significant impact on performance.
  • Compositions for use with a disposable cleaning pad where no rinsing is involved comprise: a.
  • an effective amount to reduce the contact angle and/or increase surface hydrophihcity up to about 0.5%, preferably from about 0.001% to about 0.4%, more preferably from about 0.005% to about 0.3%, of preferably relatively substantive hydrophihc polymer that renders the treated surface hydrophihc, e.g., polymer selected from the group consisting of: polystyrene sulfonate; polyvinyl pyrrohdone; polyvinyl pyrrohdone acrylic acid copolymer; polyvinyl pyrrohdone acrylic acid copolymer sodium salt; polyvinyl pyrrohdone acrylic acid copolymer potassium salt; polyvinyl pyrrohdone- vinyl imidazoline; polyvinyl pyridine; polyvinyl pyridine n- oxide; and mixtures thereof, preferably polyvinyl pyridine n-oxide; b.
  • polystyrene sulfonate polyvinyl pyrrohdon
  • detergent surfactant optionally, but preferably, an effective amount of detergent surfactant, preferably from about 0.001 % to about 0.5%, more preferably from about 0.005% to about 0.3%, most preferably from about 0.02% to about 0.3%, by weight of the composition, said detergent surfactant preferably comprising alkyl polysaccharide detergent surfactant having an alkyl group containing from about 8 to about 18 carbon atoms, more preferably from about 8 to about 16 carbon atoms, and from about one to about four, preferably from about one to about 1.5 saccharide moieties per molecule and/or a combination consisting of alkyl polysaccharide detergent surfactant having an alkyl group containing from about 8 to about 18 carbon atoms, more preferably from about
  • alkyl polysaccharide detergent surfactant being present when said hydrophihc polymer is not present, and, optionally, as a cosurfactant, from about 0.01 % to about 0.5%, preferably from about 0.01 % to about
  • anionic and/or nonionic detergent surfactant e.g., preferably selected from the group consisting of: C 8 -C 12 linear sulfonates, C 8 -C-
  • an effective amount to provide increased cleaning e.g., from about 0.5% to about 7%, preferably from about 0.5% to about 5%, more preferably from about 0.5% to about 4%, of one, or more, organic cleaning solvents, preferably selected from the group consisting of: mono-propylene glycol mono-propyl ether, mono- propylene glycol mono-butyl ether, di-propylene glycol mono-propyl ether di- propylene glycol mono-butyl ether, di-propylene glycol mono-butyl ether; tri-propylene glycol mono-butyl ether; ethylene glycol mono-butyl ether; diethylene glycol mono- butyl ether, ethylene glycol mono-hexyl ether and diethylene glycol mono-hexyl ether, and mixtures thereof, most preferably propoxypropanol; d.
  • organic cleaning solvents preferably selected from the group consisting of: mono-propylene glycol mono-propyl ether,
  • an effective amount to improve cleaning and/or antimicrobial action e.g., from about 0.01 % to about 1 %, preferably from about 0.01 % to about 0.5%, more preferably from about 0.01 % to about 0.25%, of water soluble mono- or polycarboxylic acid; e.
  • an effective amount up to 1%, preferably from about 0.01 % to about 0.5%, more preferably from about 0.025% to about 0.25%, of either an unsubstituted or substituted cyclodextrin, either alpha, beta, or gamma cyclodextrin substituted, optionally, with short chain (1-4 carbon atoms) alkyl or hydroxyalkyl groups, preferably beta-cyclodextrin, hydroxypropyl cyclodextrin or mixtures thereof; f.
  • an effective amount to provide bleaching, cleaning, and/or antibacterial action up to about 5%, preferably from about 0.1% to about 4%, more preferably from about 1 % to about 3%, of hydrogen peroxide; g. optionally, from about 0.005% to about 1 o, preferably from about 0.005% to about 0.5%, more preferably from about 0.01 % to about 0.1 %, of a thickening polymer selected from the group consisting of polyacrylates, gums and mixtures thereof; h. optionally, an effective amount of perfume to provide odor effects and/or additional adjuvants; i.
  • an effective amount from about 0.0001 % to about 0.1%, more preferably from about 0.00025 to about 0.05%, most preferably from about 0.001% to about to about 0.01% of suds suppressor, preferably silicone suds suppressor; j. optionally, detergent builder; and optionally, but preferably, the balance being an aqueous solvent system, comprising water, and optional water soluble solvent, and wherein said composition has a pH under usage conditions of from about 2 to about 12, preferably from about 3 to about 11.5, the level of hydrophobic materials, including hydrophobic cleaning solvents being limited.
  • These detergent compositions are used in combination with a disposable, preferably superabsorbent, cleaning pad, preferably attached to an implement which facilitates its use.
  • Preferred detergent compositions which can be used with the preferred pads containing superabsorbent material and optional implement, described hereinafter, require sufficient detergent to enable the solution to provide cleaning without overloading the superabsorbent material with solution, but, typically, if there is more than about 0.5% detergent surfactant the performance suffers. Therefore, the level of detergent surfactant is preferably from about 0.001 %to about 0.5%, more preferably from about 0.005% to about 0.4%, and even more preferably from about 0.02% to about 0.3%, by weight of the composition.
  • the level of hydrophobic materials, including cleaning solvent, is preferably less than about 7%, more preferably less than about 6%, and even more preferably less than about 5% and the pH is typically provided, at least in part, by volatile materials, to minimize streaking/filming problems.
  • an alkaline pH is preferred where soils are higher in grease composition while in other cases a lower pH is preferred where soils could have calcium or calcium soap deposits
  • Preferred buffers include ammonia, methanol amine, ethanol amine, 2-am ⁇ no-2-methyl-1- propanol, 2-d ⁇ methylam ⁇ no-2-methyl-1-propanol, acetic acid, glycolic acid and the like Most preferred among these are ammonia, 2-d ⁇ methylam ⁇ no-2-methyl-1-propanol and acetic acid
  • Suitable hydrophobic cleaning solvents include short chain (e g , C- j -C ⁇ ) derivatives of oxyethylene glycol and oxypropylene glycol, such as mono- and di-ethylene glycol n-hexyl ether, mono-, di- and tn-propylene glycol n-butyl ether, and the like, most preferably propoxypropanol
  • the level of hydrophobic cleaning solvent, e g , solvent having a solubility in water of less than about 10%, is in the cleaning composition at less than about 6%, more preferably less than about 5% by weight of the composition
  • Suitable detergent builders include those derived from phosphorous sources, such as orthophosphates, pyrophosphates, t ⁇ polyphosphates, etc , and those derived from non- phosphorous sources, such as nit ⁇ lot ⁇ acetates, S,S-ethylene diamine disuccinates, and the like
  • Suitable chelants include ethylenediaminetetraacetates, citrates, and the like
  • Suitable suds suppressors include silicone polymers and linear or branched C-io-C-j ⁇ fatty acids or alcohols
  • Suitable detergent enzymes include hpases, proteases, amylases and other enzymes known to be useful for catalysis of soil degradation
  • the total level of such ingredients is low, preferably less than about 0 1 %, more preferably less than about 0 05%, to avoid causing filming/streaking problems
  • the compositions should be essentially free of materials that cause filming/streaking problems Accordingly, it is desirable to use al
  • each R is selected from the group consisting of hydrogen and alkyl groups containing from one to four carbon atoms and the total of carbon atoms in the compound is from three to six, preferably, 2-d ⁇ methylam ⁇ no-2-methyl-1-propanol
  • Soil suspending agents preferably water soluble polymers, for use in the detergent composition and/or cleaning solution of this invention in addition to the said hydrophihc polymers, can optionally be selected from a group consisting of, ethoxylated and/or propoxylated polyalkylamines, carboxylate polymers, nitrogen-based zwirte ⁇ onic polymers, polyethyleneoxides, polyphosphates, and cellulosic polymers
  • Preferred soil suspending agents are ethoxylated polyalkylamines Such agents are disclosed in U S Pat Patent Number 4,891 ,160, issued January 2, 1990, entitled Detergent compositions containing ethoxylated amines having, clay soil removal/anti-redeposition properties, by Vander Meer, James M Specific methods for preparing ethoxylated amines are disclosed in U S Pat No 2,182,306 to Ul ⁇ ch et al , issued Dec 5, 1939, U S Pat No 3,033,746 to Mayle et al , issued May 8, 1962
  • An improvement in soil suspension can be achieved at all mixing ratios of the vinyl pyrrohdone polymer and the nonionic cellulose ether.
  • the ratio of the vinyl pyrrohdone polymer to the nonionic cellulose ether in the detergent composition is within the range from about 8:2 to about 2:8, most preferably from about 6:4 to about 4:6, by weight.
  • Mixtures of this type are disclosed in U. S. Pat. Patent Number: 4,999,129, entitled Process and composition for washing soiled polyester fabrics, by Michael Hull.
  • compositions contain primarily the organic cleaning solvents from about 0.5% to about 10%, more preferably 1 % to about 5% to provide cleaning and wetting, in combination with non-volatile buffers described above.
  • Low levels of non-volatiles including hydrophihc polymer can advantageously be incorporated such that the total level of non-volatiles excluding perfume and antimicrobials, is from about 0% to about 0.2%, more preferably from 0% to about 0.1 %, more preferably from about 0% to about 0.055% and most preferably from about 0% to about 0.025%. Also as in the case of glass wipes and floor, counter and wall wipes, the inventors have found that simple compositions using low levels of non-volatile surfactant with preferably high levels of the preferred organic cleaning solvent are sufficient to provide excellent cleaning and wetting performance even in the absence of the hydrophihc polymer.
  • the addition of polymer can advantageously be used to provide other benefits such as anti-spotting, antifogging and easier next-time-cleaning.
  • the combination of surfactants, wetting polymers, buffers and hydrophobic organic cleaning solvents are chosen so as a provide a surface tension reduction from water (72 dynes/cm) of more than about 25 dynes/cm, more preferably more than 30 dynes/cm, most preferably more than 35 dynes/cm.
  • low levels anti-microbial ingredients such as bronopol, hexitidine sold by Angus chemical (211 Sanders Road, Northbrook, Illinois, USA), dichloro-s-triazinetrione, trichloro- s-triazinetrione, quaternary ammonium salts including dioctyl dimethyl ammonium chloride, octyl decyl ammmonium chloride, didecyl dimethyl ammonium chloride, C12,C14 and C16 dimethyl benzyl (Bardac® 2280 and Barquat® MB-80 sold by Lonza), Kathon®, 2-((hydroxymethyl) (amino)ethanol, propylene glycol, sodium hydroxymethyl amino acetate, formaldehyde, and glutaraldehyde, and more preferably tetrakis (hydroxymethyl phosphonium sulfate (THPS), 1 ,2- benzisothiazolin-3-one, chlorhexidine dia
  • the cleaning pads will preferably have an absorbent capacity, when measured under a confining pressure of 0 09 psi after 20 minutes (1200 seconds) (hereafter referred to as "t-
  • the absorbent capacity of the pad is measured at 20 minutes (1200 seconds) after exposure to deionized water, as this represents a typical time for the consumer to clean a hard surface such as a floor
  • the confining pressure represents typical pressures exerted on the pad during the cleaning process As such, the cleaning pad should be capable of absorbing significant amounts of the cleaning solution within this 1200 second period under 0 09 psi
  • the cleaning pad will preferably have a t-
  • the cleaning pad will preferably have a tggo
  • the cleaning pads will also preferably, but not necessarily, have a total fluid capacity (of deionized water) of at least about 100 g, more preferably at least about 200 g, still more preferably at least about 300 g and most preferably at least about 400 g While pads having a total fluid capacity less than 100 g are within the scope of the invention, they are not as well suited for cleaning large areas, such as seen in a typical household, as are higher capacity pads
  • Pads that absorb less than about 100 g or less can be advantageous, particularly when used with in conjunction preferred liquid compositions described above for cleaning and disinfecting smaller areas like bathroom floors or for consumers who typically have smaller areas of washable floors in their home of about 100 square feet or less Under these situations consumers will be less forced to keep partially used pads which still have absorptive capacity available These pads can also be advantageous in that maybe better suited for spill pick-up where again keeping partially used pads is not desired.
  • This pad can be composed of an absorbent structure with or without superabsorbent polymer.
  • the pads there is preferably an absorbent layer which serves to retain any fluid and soil absorbed by the cleaning pad during use and a scrubbing layer. While the preferred scrubbing layer, described hereinafter, has some effect on the pad's ability to absorb fluid, the preferred absorbent layer plays a major role in achieving the desired overall absorbency. Furthermore, the absorbent layer preferably comprises multiple layers which are designed to provide the cleaning pad with multiple planar surfaces.
  • the absorbent layer is preferably capable of removing fluid and soil from any "scrubbing layer” so that the scrubbing layer will have capacity to continually remove soil from the surface.
  • the absorbent layer also is preferably capable of retaining absorbed material under typical in-use pressures to avoid "squeeze-out" of absorbed soil, cleaning solution, etc.
  • the absorbent layer can comprise any material that is capable of absorbing and retaining fluid during use. To achieve desired total fluid capacities, it will be preferred to include in the absorbent layer a material having a relatively high fluid capacity (in terms of grams of fluid per gram of absorbent material).
  • a material having a relatively high fluid capacity in terms of grams of fluid per gram of absorbent material.
  • the term "superabsorbent material” means any absorbent material having a g/g capacity for water of at least about 15 g/g, when measured under a confining pressure of 0.3 psi. Because a majority of the cleaning fluids useful with the present invention are aqueous based, it is preferred that the superabsorbent materials have a relatively high g/g capacity for water or water-based fluids.
  • Representative superabsorbent materials include water insoluble, water-swellable superabsorbent gelling polymers (referred to herein as "superabsorbent gelling polymers") which are well known in the literature. These materials demonstrate very high absorbent capacities for water.
  • the superabsorbent gelling polymers useful in the present invention can have a size, shape and/or morphology varying over a wide range. These polymers can be in the form of particles that do not have a large ratio of greatest dimension to smallest dimension (e.g., granules, flakes, pulverulents, interparticle aggregates, interparticle crosslinked aggregates, and the like) or they can be in the form of fibers, sheets, films, foams, laminates, and the like.
  • Superabsorbent gelling polymers useful in the present invention include a variety of water- insoluble, but water-swellable polymers capable of absorbing large quantities of fluids.
  • Such polymeric materials are also commonly referred to as "hydrocolloids", and can include polysaccharides such as carboxymethyl starch, carboxymethyl cellulose, and hydroxypropyl cellulose; nonionic types such as polyvinyl alcohol, and polyvinyl ethers; cationic types such as polyvinyl pyridine, polyvinyl morphoiine, and N,N-dimethylaminoethyl or N,N-diethylaminopropyl acrylates and methacrylates, and the respective quaternary salts thereof.
  • Preferred superabsorbent gelling polymers contain carboxy groups. These polymers include hydrolyzed starch-acrylonitrile graft copolymers, partially neutralized hydrolyzed starch- acryionitrile graft copolymers, starch-acrylic acid graft copolymers, partially neutralized starch- acrylic acid graft copolymers, saponified vinyl acetate-acrylic ester copolymers, hydrolyzed acrylonitrile or acrylamide copolymers, slightly network crosslinked polymers of any of the foregoing copolymers, partially neutralized polyacryhc acid, and slightly network crosslinked polymers of partially neutralized polyacryhc acid.
  • Most preferred polymer materials for use in making the superabsorbent gelling polymers are slightly network crosslinked polymers of partially neutralized polyacryhc acids and starch derivatives thereof.
  • the hydrogel-forming absorbent polymers comprise from about 50 to about 95%, preferably about 75%, neutralized, slightly network crosslinked, polyacryhc acid (i.e. poly (sodium acrylate/acrylic acid)).
  • Network crosshnking renders the polymer substantially water-insoluble and, in part, determines the absorptive capacity and extractable polymer content characteristics of the superabsorbent gelling polymers. Processes for network crosshnking these polymers and typical network crosshnking agents are described in greater detail in U.S. Patent 4,076,663.
  • superabsorbent gelling polymers is preferably of one type (i.e., homogeneous), mixtures of polymers can also be used in the implements of the present invention.
  • mixtures of starch-acrylic acid graft copolymers and slightly network crosslinked polymers of partially neutralized polyacryhc acid can be used in the present invention.
  • Patent 5,149,335 (Kellenberger et al.), issued September 22, 1992, describe superabsorbent gelling polymers in terms of their Absorbency Under Load (AUL), where gelling polymers absorb fluid (0.9% saline) under a confining pressure of 0.3 psi.
  • AUL Absorbency Under Load
  • Polymers described therein can be particularly useful in embodiments of the present invention that contain regions of relatively high levels of superabsorbent gelling polymers.
  • those polymers will preferably have an AUL, measured according to the methods described in U.S.
  • Patent 5,147,343 of at least about 24 ml/g, more preferably at least about 27 ml/g after 1 hour; or an AUL, measured according to the methods described in U.S. Patent 5,149,335, of at least about 15 ml/g, more preferably at least about 18 ml/g after 15 minutes.
  • hydrophihc polymeric foams such as those described in commonly assigned U.S. patent application Serial No. 08/563,866 (DesMarais et al.), filed November 29, 1995 and U.S. Patent No. 5,387,207 (Dyer et al.), issued February 7, 1995.
  • HIPEs high internal phase water-in-oil emulsion
  • these foams are readily tailored to provide varying physical properties (pore size, capillary suction, density, etc.) that affect fluid handling ability.
  • these materials are particularly useful, either alone or in combination with other such foams or with fibrous structures, in providing the overall capacity required by the present invention.
  • the absorbent layer will preferably comprise at least about 15%, by weight of the absorbent layer, more preferably at least about 20%, still more preferably at least about 25%, of the superabsorbent material.
  • the absorbent layer can also consist of or comprise fibrous material.
  • Fibers useful in the present invention include those that are naturally occurring (modified or unmodified), as well as synthetically made fibers. Examples of suitable unmodified/modified naturally occurring fibers include cotton, Esparto grass, bagasse, hemp, flax, silk, wool, wood pulp, chemically modified wood pulp, jute, ethyl cellulose, and cellulose acetate.
  • Suitable synthetic fibers can be made from polyvinyl chloride, polyvinyl fluoride, polytetrafluoroethylene, polyvinylidene chloride, polyacryhcs such as ORLON ® , polyvinyl acetate, Rayon®, polyethylvinyl acetate, non-soluble or soluble polyvinyl alcohol, polyolefins such as polyethylene (e.g., PULPEX ® ) and polypropylene, polyamides such as nylon, polyesters such as DACRON ® or KODEL ® , polyurethanes, polystyrenes, and the like.
  • the absorbent layer can comprise solely naturally occurring fibers, solely synthetic fibers, or any compatible combination of naturally occurring and synthetic fibers.
  • the fibers useful herein can be hydrophihc, hydrophobic or can be a combination of both hydrophihc and hydrophobic fibers.
  • the particular selection of hydrophihc or hydrophobic fibers depends upon the other materials included in the absorbent (and to some degree the scrubbing) layer. That is, the nature of the fibers will be such that the cleaning pad exhibits the necessary fluid delay and overall fluid absorbency.
  • Suitable hydrophihc fibers for use in the present invention include cellulosic fibers, modified cellulosic fibers, rayon, polyester fibers such as hydrophihc nylon (HYDROFIL®).
  • Suitable hydrophihc fibers can also be obtained by hydrophilizing hydrophobic fibers, such as surfactant-treated or silica-treated thermoplastic fibers derived from, for example, polyolefms such as polyethylene or polypropylene, polyacryhcs, polyamides, polystyrenes, polyurethanes and the like.
  • hydrophilizing hydrophobic fibers such as surfactant-treated or silica-treated thermoplastic fibers derived from, for example, polyolefms such as polyethylene or polypropylene, polyacryhcs, polyamides, polystyrenes, polyurethanes and the like.
  • Suitable wood pulp fibers can be obtained from well-known chemical processes such as the Kraft and sulfite processes. It is especially preferred to derive these wood pulp fibers from southern soft woods due to their premium absorbency characteristics. These wood pulp fibers can also be obtained from mechanical processes, such as ground wood, refiner mechanical, thermomechanical, chemimechanical, and chemi-thermomechanical pulp processes. Recycled or secondary wood pulp fibers, as well as bleached and unbleached wood pulp fibers, can be used. Another type of hydrophihc fiber for use in the present invention is chemically stiffened cellulosic fibers.
  • the term "chemically stiffened cellulosic fibers” means cellulosic fibers that have been stiffened by chemical means to increase the stiffness of the fibers under both dry and aqueous conditions. Such means can include the addition of a chemical stiffening agent that, for example, coats and/or impregnates the fibers. Such means can also include the stiffening of the fibers by altering the chemical structure, e.g., by crosshnking polymer chains.
  • the fibers can optionally be combined with a thermoplastic material. Upon melting, at least a portion of this thermoplastic material migrates to the intersections of the fibers, typically due to interfiber capillary gradients. These intersections become bond sites for the thermoplastic material. When cooled, the thermoplastic materials at these intersections solidify to form the bond sites that hold the matrix or substrate of fibers together in each of the respective layers. This can be beneficial in providing additional overall integrity to the cleaning pad. Amongst its various effects, bonding at the fiber intersections increases the overall compressive modulus and strength of the resulting thermally bonded member.
  • the melting and migration of the thermoplastic material also has the effect of increasing the average pore size of the resultant substrate, while maintaining the density and basis weight of the substrate as originally formed.
  • This can improve the fluid acquisition properties of the thermally bonded substrate upon initial exposure to fluid, due to improved fluid permeability, and upon subsequent exposure, due to the combined ability of the stiffened fibers to retain their stiffness upon wetting and the ability of the thermoplastic material to remain bonded at the fiber intersections upon wetting and upon wet compression.
  • thermally bonded substrates of stiffened fibers retain their original overall volume, but with the volumetric regions previously occupied by the thermoplastic material becoming open to thus increase the average interfiber capillary pore size.
  • Thermoplastic materials useful in the present invention can be in any of a variety of forms including particulates, fibers, or combinations of particulates and fibers.
  • Thermoplastic fibers are a particularly preferred form because of their ability to form numerous interfiber bond sites.
  • Suitable thermoplastic materials can be made from any thermoplastic polymer that can be melted at temperatures that will not extensively damage the fibers that comprise the primary substrate or matrix of each layer.
  • the melting point of this thermoplastic material will be less than about 190°C, and preferably between about 75°C and about 175°C. In any event, the melting point of this thermoplastic material should be no lower than the temperature at which the thermally bonded absorbent structures, when used in the cleaning pads, are likely to be stored.
  • the melting point of the thermoplastic material is typically no lower than about 50°C.
  • thermoplastic materials can be made from a variety of thermoplastic polymers, including polyolefins such as polyethylene (e.g., PULPEX®) and polypropylene, polyesters, copolyesters, polyvinyl acetate, polyethylvinyl acetate, polyvinyl chloride, polyvinylidene chloride, polyacryhcs, polyamides, copolyamides, polystyrenes, polyurethanes and copolymers of any of the foregoing such as vinyl chloride/vinyl acetate, and the like.
  • polyolefins such as polyethylene (e.g., PULPEX®) and polypropylene
  • polyesters copolyesters
  • polyvinyl acetate polyethylvinyl acetate
  • polyvinyl chloride polyvinylidene chloride
  • polyacryhcs polyamides, copolyamides, polystyrenes, polyurethanes
  • suitable thermoplastic materials include hydrophobic fibers that have been made hydrophihc, such as surfactant-treated or silica-treated thermoplastic fibers derived from, for example, polyolefins such as polyethylene or polypropylene, polyacryhcs, polyamides, polystyrenes, polyurethanes and the like.
  • the surface of the hydrophobic thermoplastic fiber can be rendered hydrophihc by treatment with a surfactant, such as a nonionic or anionic surfactant, e.g., by spraying the fiber with a surfactant, by dipping the fiber into a surfactant or by including the surfactant as part of the polymer melt in producing the thermoplastic fiber.
  • a surfactant such as a nonionic or anionic surfactant
  • spraying the fiber with a surfactant by dipping the fiber into a surfactant or by including the surfactant as part of the polymer melt in producing the thermoplastic fiber.
  • the surfactant will tend to remain at the surfaces of the thermoplastic fiber.
  • Suitable surfactants include nonionic surfactants such as Brij® 76 manufactured by ICI Americas,
  • thermoplastic fibers can be applied to the thermoplastic fibers at levels of, for example, from about 0 2 to about 1 g per sq of centimeter of thermoplastic fiber
  • thermoplastic fibers can be made from a single polymer (monocomponent fibers), or can be made from more than one polymer (e g , bicomponent fibers)
  • bicomponent fibers refers to thermoplastic fibers that comprise a core fiber made from one polymer that is encased within a thermoplastic sheath made from a different polymer The polymer comprising the sheath often melts at a different, typically lower, temperature than the polymer comprising the core As a result, these bicomponent fibers provide thermal bonding due to melting of the sheath polymer, while retaining the desirable strength characteristics of the core polymer
  • Suitable bicomponent fibers for use in the present invention can include sheath/core fibers having the following polymer combinations polyethylene/ polypropylene, polyethylvinyl acetate/polypropylene, polyethylene/polyester, polypropylene/polyester, copolyester/polyester, and the like
  • Particularly suitable bicomponent thermoplastic fibers for use herein are those having a polypropylene or polyester core, and a lower melting copolyester, polyethylvinyl acetate or polyethylene sheath (e g , those available from Danaklon a/s, Chisso Corp , and CELBOND®, available from Hercules)
  • These bicomponent fibers can be concentric or eccentric
  • the terms “concentric” and “eccentric” refer to whether the sheath has a thickness that is even, or uneven, through the cross-sectional area of the bicomponent fiber Eccentric bicomponent fibers can be desirable in providing more compressive strength at
  • the absorbent layer can also comprise a HIPE-de ⁇ ved hydrophihc, polymeric foam that does not have the high absorbency of those described above as "superabsorbent materials"
  • HIPE-de ⁇ ved hydrophihc, polymeric foam that does not have the high absorbency of those described above as "superabsorbent materials”
  • the absorbent layer of the cleaning pad can be comprised of a homogeneous material, such as a blend of cellulosic fibers (optionally thermally bonded) and swellable superabsorbent gelling polymer
  • the absorbent layer can be comprised of discrete layers of material, such as a layer of thermally bonded airlaid material and a discrete layer of a superabsorbent material
  • a thermally bonded layer of cellulosic fibers can be located lower than (i e , beneath) the superabsorbent material (i e , between the superabsorbent material and the scrubbing layer).
  • the superabsorbent material can be located remote from the scrubbing layer by including a less absorbent layer as the lower-most aspect of the absorbent layer.
  • a layer of cellulosic fibers can be located lower (i.e., beneath) than the superabsorbent material (i.e., between the superabsorbent material and the scrubbing layer).
  • the absorbent layer comprises a thermally bonded airlaid substrate of cellulose fibers (Flint River, available from Weyerhaeuser, Wa) and AL Thermal C (thermoplastic available from Danaklon a/s, Varde, Denmark), and a swellable hydrogel-forming superabsorbent polymer.
  • the superabsorbent polymer is preferably incorporated such that a discrete layer is located near the surface of the absorbent layer which is remote from the scrubbing layer.
  • a thin layer of, e.g., cellulose fibers (optionally thermally bonded) are positioned above the superabsorbent gelling polymer to enhance containment.
  • the scrubbing layer is the portion of the cleaning pad that contacts the soiled surface during cleaning.
  • materials useful as the scrubbing layer must be sufficiently durable that the layer will retain its integrity during the cleaning process.
  • the scrubbing layer when the cleaning pad is used in combination with a solution, the scrubbing layer must be capable of absorbing liquids and soils, and relinquishing those liquids and soils to the absorbent layer. This will ensure that the scrubbing layer will continually be able to remove additional material from the surface being cleaned.
  • the scrubbing layer will, in addition to removing particulate matter, facilitate other functions, such as polishing, dusting, and buffing the surface being cleaned.
  • the scrubbing layer can be a mono-layer, or a multi-layer structure one or more of whose layers can be slitted to facilitate the scrubbing of the soiled surface and the uptake of particulate matter. This scrubbing layer, as it passes over the soiled surface, interacts with the soil (and cleaning solution when used), loosening and emulsifying tough soils and permitting them to pass freely into the absorbent layer of the pad.
  • the scrubbing layer preferably contains openings (e.g., slits) that provide an easy avenue for larger particulate soil to move freely in and become entrapped within the absorbent layer of the pad.
  • Openings e.g., slits
  • Low density structures are preferred for use as the scrubbing layer, to facilitate transport of particulate matter to the pad's absorbent layer.
  • materials particularly suitable for the scrubbing layer include synthetics such as polyolefins (e.g., polyethylene and polypropylene), polyesters, polyamides, synthetic cellulosics (e.g., Rayon ® ), and blends thereof.
  • synthetics such as polyolefins (e.g., polyethylene and polypropylene), polyesters, polyamides, synthetic cellulosics (e.g., Rayon ® ), and blends thereof.
  • Such synthetic materials can be manufactured using known process such as carded, spunbond, meltblown, airlaid, needle punched and the like.
  • Cleaning pads of the present invention optionally have an attachment layer that allows the pad to be connected to an implement's handle or the support head in preferred implements
  • the attachment layer will be necessary in those embodiments where the absorbent layer is not suitable for attaching the pad to the support head of the handle
  • the attachment layer can also function as a means to prevent fluid flow through the top surface (i.e , the handle-contacting surface) of the cleaning pad, and can further provide enhanced integrity of the pad
  • the attachment layer can consist of a mono-layer or a multi-layer structure, so long as it meets the above requirements
  • the attachment layer can comprise a surface which is capable of being mechanically attached to the handle's support head by use of known hook and loop technology
  • the attachment layer will comprise at least one surface which is mechanically attachable to hooks that are permanently affixed to the bottom surface of the handle's support head
  • the attachment layer is a t ⁇ -layered material having a layer of meltblown polypropylene film located between two layers of spun-bonded polypropylene Making processes
  • compositions herein can be made by mixing together all ingredients. It has been found that for maximum perfume solubihzation in compositions where the actives are present at low levels, a preferred order of addition is necessary This involves the making of a premix like the perfume compositions disclosed hereinbefore, that is then added to the "base" product
  • the premix comprises raw materials added in the following order surfactant(s), if any, at about 25% activity or higher, then perfume, then polymer, then the optional suds suppressor
  • solvent(s) and/or the optional buffer, to the premix after the optional suds suppressor Thorough mixing of the premix provides the best results
  • the premix is then added to the base, which contains water and the other components
  • the combined mixture i e , premix in the base
  • Another preferred method to incorporate maximum perfume into compositions with limited surfactant is to create a premix in which perfume is added to a cyclodextrin mixture in aqueous media
  • the perfume-cyclodext ⁇ n mixture can be pre-formed prior to the premix This approach ensures maximum perfume incorporation into the composition, and can provide perfume to compositions with little or no surfactant
  • perfume solubihzation can not be achieved, even with the preferred processing methods
  • the entire heterogeneous composition can be added directly to the article of use
  • this method of use is desirable include pre-moistened wipes, dry absorbent substrates used in conjunction with solution
  • a single step making process can be followed. For example, an acceptable order of addition is to first incorporate water, any detergent surfactant and/or organic acid, followed by any hydrophobic cleaning solvent. Once the solvent is added, pH is adjusted to optimum as desired by the formulator. The polymer can then be added followed by any optional peroxide, perfume and/or dye.
  • compositions described in A., B., C, D., and E. above can advantageously be used in concentrated form because their ability to solubilize significant levels of perfume via hydrophihc polymer.
  • perfumes not completely soluble in water at 100 parts per million can be dissolved using about 0.05% or more hydrophihc polymer.
  • the preferred alkyl polyglucoside at low levels can be used to improve perfume solubility.
  • concentrations of less than about 0.05% polyglucoside it is meant concentrations of less than about 0.05% polyglucoside. It is found that the preferred polyglucoside can dissolve three to ten times of perfume on a weight basis in water, and the ability of the polymer to dissolve/disperse perfume is improved even more. This is beneficial since it keeps the amount of non-volatile materials low to minimize residue.
  • 0.5% of the preferred alkyl polyglucoside with 0.5% PVNO can be used to dissolve up to about 0.5% perfume.
  • a larger ratio of perfume to actives can be dissolved.
  • the combination of 0.03% alkyl polyglucoside and 0.015% can dissolve up to about 0.1 % perfume, where other nonionics can only dissolve about half the level of perfume.
  • the compositions herein are distributed over substantially all of the shower, bath tub, floor, counter, walls, glass, and the like, using either a spray container or distributing device like a sponge, cloth, mop, wipe, roller, absorbent pad, pre-moistened wipe, and the like.
  • a spray container or distributing device like a sponge, cloth, mop, wipe, roller, absorbent pad, pre-moistened wipe, and the like.
  • the distribution is substantially uniform. It is an advantage of the type of product herein that no rinsing is needed and, in fact, can be counterproductive since the efficiency of the method is improved by not rinsing.
  • the polymer is primarily effective as a result of staying on the surface to render it hydrophihc.
  • the method can comprise applying only an aqueous solution of the polymer, or the polymer plus perfume, to the surface.
  • Instructions for use are rendered in consumer-friendly language on the packaging and/or advertising (e.g., leaflets, coupons, displays, etc.).
  • consumer-friendly language it is meant that consumers would be instructed how to preferably use the product, e.g., "apply five sprays of product over a two square foot area”, “use electrical sprayer device to cover your entire shower walls”, or “use one cap-full of concentrated floor cleaner product diluted into half a bucket of water”, to achieve best results.
  • the units of measurement provided to consumers will reflect consumer understanding, e.g., English dosing units will be preferred in the United States, and metric units will be used in most European countries. Pictures can be used, either with, or without, words in helping make the instructions consumer-friendly.
  • Special packaging design can also be advantageously used to convey instructions in a consumer-friendly fashion. Ergonomic appeal can also make product use more intuitive, either with or without words and pictures.
  • the packaging can be designed to facilitate proper dispensing. Although all of the following methods described herein (below) are written in metric units; it is understood that these units will be converted into consumer-friendly language instructions in the actual product packaging, advertising etc., as illustrated above.
  • compositions herein as opposed to the types of compositions sold heretofore for treating hard surfaces, provides improved performance.
  • a method in which a detergent composition comprising the preferred C 8 . 16 alkylpolyglycoside, especially alkylpolyglucoside surfactant with broad alkyl distribution, to bathroom surfaces as part of a treatment after each shower or bath to maintain the surfaces in clean condition and, similarly, a method for cleaning floors using an absorbent pad are also desirable, since the surface appearance is improved, even without the presence of the polymer.
  • the best appearance is provided by the combination.
  • compositions sold heretofore cause the surface to be unsightly due to the failure of the surface to dry evenly, thus exhibiting spots and/or streaks.
  • compositions/solutions herein can reverse this and immediately improve appearance. Similar benefits are observed in the context of floor cleaners etc.
  • the polymers inhibit soil, hardness, etc. from adhering to the surface and especially inhibit the formation of unsightly spots upon drying, thus avoiding the appearance concerns that might cause the consumer to rinse, or otherwise remove the polymer for appearance reasons. G1. "Daily shower" Method
  • an effective amount of the composition containing the hydrophihc polymer is used to cover the surface to be treated. Distribution can be achieved by using a spray device, a roller, one or more pads etc., although sprayer devices are preferred.
  • a spray device a roller, one or more pads etc., although sprayer devices are preferred.
  • One of the more important benefits of the compositions and mode of use thereof, is soil prevention and prevention of soil build-up, and general cleanliness of the shower and related areas.
  • the product is applied using from about 5 milliliters per square meter to about 50 milliliters per square meter, more preferably from about 10 milliliters to about 30 milliliters per square meter.
  • the dosing amount will depend on the cleanliness of the shower to begin.
  • the method will begin with a clean shower. This reduces the amount of product needed, provides longer lasting, sustainable benefits and leads to better initial and ongoing results. When low levels of soil are present, it requires longer periods of use, usually from two to four weeks, to achieve the same desired end result.
  • the daily shower maintenance product can advantageously include cyclodextrin Care should be taken in the selection of level and type of perfume and cyclodextrin so as to minimize filming and/or streaking This is particularly true on shiny surfaces such as chrome and glass, where residual solids are highly visible
  • the perfume is preferably selected to be highly water soluble Even when little or no cyclodextrin is used, deodorization and malodor control can still be achieved if the product is used as directed, i.e., on a daily basis For surfaces where lighting is poor or the surfaces are not as shiny, such as fiberglass and mat ceramic, higher levels of surfactant, polymer, perfume and cyclodextrin can be used
  • the amount of solution is sufficient to completely cover the surface to be treated so as to evenly distribute the polymer and achieve maximum sheeting/spotting benefits In any event, daily application of the compositions of the invention will result in eventual full coverage of the surface
  • the packaging and delivery mechanism is preferably designed to be kept in close proximity to areas of use As such, the packaging should be light, easy to handle and easy to apply
  • the packaging can preferably encompass aesthetically pleasing features that blend in well in a bathroom setting and optionally includes devices that allow easy storage and retrieval of product Devices separate from the package include but are not limited to, hanging baskets or shelving directly on the shower head, walls, doors sides of tubs, and the like Devices that can be part of the package include hooks, fasteners, suction cups, adhesives, screws, and the like to attach and/or store product to walls, doors, showers, etc
  • the refill should also be designed for easy access and storage as above This can be important in that daily use of the product is easily maintainable when the refill package is proximate
  • larger system units comprising a hose or related delivery mechanism
  • delivery systems include hand-actuated pressure pumps and boxes with built in mechanical, battery operated or electrical pumps These devices can be directly attached as part of the shower and tub unit, or can be separate external units Electrical pumps should be attached to the source of electricity through a device that limits the voltage for safety reasons.
  • all of the fastening mechanisms described above can be used, or the device can be completely non-attached.
  • all of the above system units can be equipped with devices for proper dosage quantity, pressure, steam, temperature control and coverage pattern control. In one such execution, a concentrate can be blended with water so as to provide optimum and long lasting delivery of actives.
  • the compositions can be distributed using a spray device combined with a buffing implement, or dosed more conveniently using a roller, such as manual or powered paint rollers.
  • a roller such as manual or powered paint rollers.
  • the wringing device can be used separately or housed together with the roller.
  • Hand implements for wall cleaning can also be used.
  • the implement is attached to a handle for harder to reach areas, coverage and ease of use.
  • the compositions can be delivered in the form of a premoistened wipe.
  • the pre-moistened wipe can provides cleaning liquid and scrubbing surface all in one execution.
  • dosing should be preferably from about 1 milliliter to about 20 milliliters per square meter, more preferably from about 2 milliliters to about 10 milliliters per square meter.
  • the product is applied at the above-recommended doses, covering surfaces to be treated completely, and allowed to air- dry.
  • Instructions for use include pictures and/or words detailing preferred application pattern and dosing.
  • the compositions of this invention are mild and minimize harm to most painted surfaces. Preferably solvent use is limited or not present for this application.
  • Preferred compositions for wall cleaning include the preferred C 8 .
  • compositions are ideally suited for light duty jobs, i.e., general maintenance of painted and/ or wall-papered surfaces, because of product mildness and generally low levels of actives. Additional benefits for painted walls, provided by the hydrophihc polymer, include shine, luster restoration, and soil prevention.
  • the compositions can be distributed using a spray device combined with a buffing implement, or dosed more conveniently using a hand- implement or an implement attached to a handle for harder to reach areas, coverage, and ease of use.
  • the compositions can be delivered in the form of a pre-moistened wipe.
  • the pre-moistened wipe provides liquid and scrubbing all in one execution.
  • the wipe can also incorporate soft and abrasive materials as needed for spot cleaning.
  • compositions of this invention are mild and minimize harm to most painted surfaces and woods or worn Formica ®
  • Preferred compositions for wall cleaning include the preferred C 8 16 alkylpolyglycoside either with or without hydrophihc polymers
  • the compositions are ideally suited for light duty jobs, i.e , daily or weekly maintenance, because of product mildness and generally low levels of actives
  • residual levels of the hydrophihc polymers provide shine and soil prevention Solvents, particularly volatile solvents, are preferably incorporated in these compositions, as they can provide additional cleaning, if needed, without streaking in a no- ⁇ nse application
  • the compositions also deliver next-time easier cleaning advantages of grease, encrusted foods and
  • compositions can be distributed using a spray device combined with a buffing implement, or dosed more conveniently using or hand-implement or an implement attached to a handle for harder to reach areas, coverage, and ease of use
  • product can be wiped with absorbent paper towels, cloths, etc
  • a preferred wiping pattern consists of a side-to-side- overlappmg motion starting in the upper left hand (or right hand) corner of the glass, progressing the wipe pattern down the glass continuing in side-by side patterns, and ending in the bottom left or right corner
  • the towel or cloth is then flipped to provide clean dry area, and the glass is buffed in an up-and-down pattern starting from the left (or right) end of the glass and progressing to the right (or left) such that the wiping motion covers the entire piece of glass
  • An alternative wiping pattern begins with up-and-down wiping motions, flipping the towel or cloth and finishing with side-to-side wiping motions
  • the alternative wiping pattern begins with up-and-down wiping motions, flipping the
  • the compositions can be distributed using a sponge, string or strip mop
  • floor cleaners we mean compositions intended to clean and preserve common flooring inside or outside of the home or office
  • Floors that can be cleaned with compositions of the present invention include living room, dining room, kitchen, bathroom, cellar, attic, patio etc
  • These floors can consist of ceramic, porcelain, marble, Formica®, no-wax vinyl, linoleum, wood, quarry tile, brick or cement, and the like
  • the compositions can be ready to use, i e , used as is, or diluted in a bucket or other suitable receptacle at dilution factors specified in the instructions
  • thorough sweeping and/or vacuuming is recommended before wet mopping It is recommended that the lowest soiled floors be cleaned first, with progression toward more heavily surfaces This maximizes the mileage of the solution and limits room to room contamination
  • the implement head is dunked or immersed into the solution (either dilute or ready to use) and wrung out
  • the implement should not be completely dry nor should it be dripping wet prior to mopping
  • a preferred mopping pattern with a sponge mop or floor cloth used with a brush with a handle is performed in an up-and-down overlapping motion from left to right (or right to left) and then repeated using an up-and-down overlapping pattern from right to left (or left to right)
  • the up-and-down motion preferentially covers about 0 5 meters to about 1 meter
  • the left to right distance preferentially is about 1 to about 2 meters
  • the sponge mop or floor cloth should be re-immersed in solution and wrung again
  • the volume of solution left on solution left on the floor is from about 20 milliliters to about 50 milliliters per square meter, preferably from about 30 milliliters to about 40 milliliters per square meter
  • a preferred mopping pattern consists of an up-and-down overlapping motion from left to right (or right to left) which is then repeated using a side to side overlapping motion from right to left (or left to right)
  • the up-and-down motion preferentially covers about 0 5 meters to about 1 meter
  • the side-to-side pattern right to left (or left to right) is preferably covers from about 0 5 meters to about 1 meter
  • the mopping pattern preferably outlines a square shape, i e , from about 0 5 square meters to about 1 square meter
  • the strip or string mop should be re-immersed in solution and wrung again
  • the volume of solution left on solution left on the floor is from about 20 milliliters to about 50 milliliters per square meter, preferably from about 30 milliliters to about 40 milliliters per square meter
  • the composition (either diluted or ready to use) is stored in one receptacle, and the mop-rinsing water is stored in another receptacle
  • This dual-receptacle approach can consist of two separate units or can be combined as one Examples of this mode of use include squirt bottles, trigger sprays, mechanical sprays, garden misters, and electrical or battery-operated dosing devices
  • the advantages of this mode of use include always providing fresh solution to the floor, and keeping soiled water (from the cleaning of the floors) from re-contaminating the floor Additionally, this approach effectively controls micro-organisms through less re-inoculation, thereby providing a more germ-free end result
  • This mode of use is also advantageous for spot cleaning, i e , tough- to-clean areas can be pre-treated with product before the mopping begins, this mode of use also allows flexibility with respect to dosage control in that more solution can be administered to dirty areas, and less to cleaner areas, thereby improving value
  • the composition can be applied directly to the floor as a ready to use solution in either liquid or spray form
  • this mode of use include squirt bottles, trigger sprays, mechanical sprays, garden misters, and electrical or battery-operated dosing devices
  • Advantages of this mode of use include always providing fresh solution to the floor, and better mop maintenance, particularly if the mop is not re- exposed to dirty solution (i e , the mop can be preserved longer by wringing out old solution and only applying fresh solution to the floor ) Additionally, this approach more effectively removes microorganisms from the cleaning mechanism, thereby providing a more germ-free end result (i e , less re-inoculation of the microorganisms)
  • This mode of use is also advantageous for spot cleaning, i e , tough-to-clean areas can be pre-treated with product before the mopping begins, this mode of use also allows flexibility with respect to dosage control in that more solution can be administered to dirty areas, and less to cleaner areas,
  • the fresh solution dispensing approach can be delivered using a motorized system
  • a motorized system for floor cleaning is the Dirt Devil® Wet Vac
  • the motorized system would comprise a chamber containing fresh solution and a second chamber to suck up and hold the dirty solution removed from the floor
  • the motorized unit also preferably comprises squeegee and/or scrubbing devices
  • the scrubbing device can be made of cotton, cellulose sponge etc
  • the dispensing unit can consist of a simple unit containing a lever (which can be calibrated for one or more dosing levels) to meter liquid onto the floor Thorough sweeping and/or vacuuming is recommended prior to using the motorized cleaning system
  • a preferred wiping pattern consists of an up-and-down overlapping motion from left to right (or right to left) and then repeated using an up-and-down overlapping pattern from right to left (or left to right)
  • the up-and-down motion preferentially covers about 0 5 meters to about 1 meter
  • the left to right distance
  • the compositions can be delivered in the form of a pre-moistened wipe
  • the pre-moistened wipe is optionally but preferably attached to a mop head and handle
  • the handle can consist of one or more small extendible attachment or a telescopic pole
  • the mop head unit includes a squeegee for optional buffing
  • the pre-moistened wipe provides liquid and scrubbing all in one execution
  • i e soil removal with delivery of high gloss and no streaks to treated areas such that no rinsing is required
  • dosing should be preferably from about 1 milliliter to about 10 milliliters per square meter, more preferably from about 3 milliliters to about 5 milliliters per square meter
  • a preferred wiping pattern consists of a side-to-side- overlapping motion starting in the upper left hand
  • compositions also deliver next-time easier cleaning advantages of grease, encrusted foods and stains via the residual polymer left on surface. Additionally, the compositions can be used with articles to improve cleaning, such as abrasive pads, heat and steam and combinations thereof. For particularly tough soil removal or highly soiled surfaces, use of a multi-laminate wipe is even more advantageous.
  • the same level of liquid and wiping pattern(s) is used as described above, but instructions would include an additional buffing or polishing step in order to remove potentially dirty liquid and prevent soil redeposition on glass.
  • the compositions can be delivered in the form of a pre-moistened wipe as described hereinbefore, preferably attached to a mop head and/or handle.
  • the pre-moistened wipe can provide liquid and scrubbing all in one execution.
  • Mopping pattern with a pre-moistened mop used with a handle is preferably performed in an up- and-down overlapping motion from left to right (or right to left) and then repeated using an up-and- down overlapping pattern from left to right (or right to left).
  • the up-and-down motion preferentially covers about 0.5 meters to about 1 meter.
  • Pre-moistened wipes can be advantageous particularly for cleaning small areas, such as encountered in typical bathrooms. They are also readily available and versatile in that they can be used to clean surfaces other than floors, such as counter tops, walls, etc., without having to use a variety of other liquids and/or implements. This approach also effectively removes and controls microorganisms by minimizing implement inoculation, which is often seen with conventional re-usable systems such as sponge, string and strip mops. Lack of implement inoculation leads to a cleaner and more germ-free end result. G8. Floor Cleaning Using a Disposable Pad
  • a system composed of a disposable cleaning pad and a mode for applying fresh solution onto the floor.
  • the pad is composed of a laminate of non-wovens, cellulose and super-absorbent polymer.
  • This pad is attached to a device comprising a mop head and handle.
  • solution application can be achieved via a separate squirt bottle or spray trigger system, or can be directly attached or built-in to the device (i.e., on the mop head or the handle).
  • the delivery mechanism can be actuated by the operator, or can be battery-induced or electrical.
  • This system provides multiple benefits versus conventional cleaning modes. It reduces time to clean the floor, because the pad sucks up dirty solution. It eliminates the need to carry heavy, messy buckets. Due to the absorbent pad which absorbs and locks away dirty solution, a single pad can clean large surface areas.
  • the cleaning process involves use of low levels of solution in contact with the floor for much shorter periods of time relative to conventional cleaning systems, (less solution is applied on the floor and the super- absorbent polymer absorbs most of it such that volume left behind with the disposable pad and mop is only from about 1 to about 5 milliliters of solution per square meter), the system provides improved surface safety on delicate surfaces. This is particularly important for the cleaning of wood, which tends to expand and then contract when excess treated with excess water.
  • this system is well suited for pre-treating tough soil spots prior to full floor cleaning because of the controlled dosing of solution. Unlike conventional mops, this system is more effective and more convenient for removal of spills. For example, conventional mops actually wet the floor in attempting to control spills, while absorbent paper towels or cloths require the user to bend down to achieve spill removal.
  • the implement plus pad can be designed to allow easy access to tough to clean and hard to reach areas, e.g., under appliances, tables, counters, and the like.
  • super-absorbent polymer allows a reduction in volume of the pad, i.e., the pad is thin though highly absorbent due to the super-absorbent structure being able to absorb 100 times its weight; this is achievable with conventional mops, which require greater bulk for absorption purposes (cellulose or a synthetic structures absorb only up to about from 5 to about 10 times their weight).
  • a priming set can optionally be to spray solution directly onto the pad, with even coverage using from about 10 to about 20 milliliters. Apply solution at rate of from about 5 to about 40 milliliters, more preferably from about 10 to about 30 milliliters per square meter, spreading the liquid out as much as possible over the area section to be cleaned. This is followed by wiping using the disposable pad.
  • a preferred wiping pattern consists of an up-and-down overlapping motion starting in the bottom left hand (or right hand) side of the section to be cleaned, and progressing the wiping pattern across the floor continuing to use up-and-down wiping motions. Wiping is then continued beginning at the top right (or left) side of the section to be cleaned and reversing the direction of the wipe pattern using a side-to-side motion.
  • Another preferred wipe pattern consists of an up- and-down wiping motion, followed by an up-and-down wiping motion in the reverse direction.
  • the pads are versatile in that they can be used for multiple cleanings and multiple surfaces Each pad is designed to clean one average size floor (i e , from about 10 to about 20 square meters) with an average soil load Pads can need to be changed sooner if floors are larger than average, or especially dirty To determine if the pad needs changing, look at the back of the pad and ascertain if the back absorbent layer is saturated with liquid and/or dirt
  • the use of the compositions herein, where no rinsing is desirable, as opposed to the types of compositions sold heretofore for treating non-bathtub/shower area surfaces including floor surfaces, walls and counter tops, provides improved performance H Article of Manufacture
  • compositions of the present invention are used in the context of a cleaning implement that comprises a removable cleaning pad which alleviates the need to rinse the pad during use
  • a cleaning implement that comprises a removable cleaning pad with sufficient absorbent capacity, on a gram of absorbed fluid per gram of cleaning pad basis, that allows the cleaning of a large area, such as that of the typical hard surface floor or wall (e g , 80-100 ft 2 ), without the need to change the pad
  • a superabsorbent material preferably of the type disclosed hereinbefore and in S N 08/756,507, incorporated by reference hereinbefore
  • liquid compositions described above can be desirably used with an implement for cleaning a surface, the implement comprising a cleaning pad, preferably removable, containing an effective amount of a superabsorbent material, and having a plurality of substantially planar surfaces, wherein each of the substantially planar surfaces contacts the surface being cleaned, more preferably said pad is a removable cleaning pad having a length and a width, the pad comprising i scrubbing layer, and ii. optionally an absorbent layer comprising a first layer and a second layer, where the first layer is located between the scrubbing layer and the second layer (i.e., the first layer is below the second layer) and has a smaller width than the second layer; and b. optionally, a handle.
  • a cleaning pad preferably removable, containing an effective amount of a superabsorbent material, and having a plurality of substantially planar surfaces, wherein each of the substantially planar surfaces contacts the surface being cleaned, more preferably said pad is a removable cleaning pad having a length and
  • a preferred aspect of the cleaning pad is the use of multiple planar surfaces that contact the soiled surface during the cleaning operation.
  • these planar surfaces are provided such that during the typical cleaning operation (i.e., where the implement is moved back and forth in a direction substantially perpendicular to the pad's width), each of the planar surfaces contact the surface being cleaned as a result of "rocking" of the cleaning pad.
  • the preferred cleaning implements have a pad which offers beneficial soil removal properties due to continuously providing a fresh surface, and/or edge to contact the soiled surface, e.g., by providing a plurality of surfaces that contact the soiled surface during the cleaning operation.
  • the detergent surfactant is preferably linear, e.g., branching and aromatic groups should not be present, and the detergent surfactant is preferably relatively water soluble, e.g., having a hydrophobic chain containing preferably from about 8 to about 16, , carbon atoms, and, for nonionic detergent surfactants, having an HLB of from about 9 to about 15, more preferably from about 10 to about 13.5.
  • the most preferred surfactants are the alkylpolyglucosides described hereinbefore.
  • alkyl ethoxylates comprising from about 9 to about 12 carbon atoms, and from about 4 to about 8 ethylene oxide units. These surfactants offer excellent cleaning benefits and work synergistically with the required hydrophihc polymers.
  • a most preferred alkyl ethoxylate is C- ⁇ E0 5 , available from the Shell Chemical Company under the trademark Neodol® 1-5. The CnE0 5 is particularly preferred when used in combination with the preferred cosurfactants, C 8 sulfonate and/or Poly-Tergent CS-1.
  • the preferred alkyl ethoxylate surfactant is found to provide excellent cleaning properties, and can be advantageously combined with the preferred C 8 _ ⁇ 6 alkyl polyglucoside in a matrix that includes the wetting polymers of the present invention. While not wishing to be limited by theory, it is believed that the C 8 . 16 alkyl polyglucoside can provide a superior end result (i.e., reduce hazing) in compositions that additionally contain the preferred alkyl ethoxylate particularly when the preferred alkyl ethoxylate is required for superior cleaning.
  • the preferred the C 8 _- ⁇ 6 alkyl polyglucoside is also found to improve perfume solubility of compositions comprising alkyl ethoxylates. Higher levels of perfume can be advantageous for consumer acceptance.
  • the invention also comprises a detergent composition as disclosed herein in a container in association with instructions to use it.
  • This container can have an assembly of one or more units, either packaged together or separately.
  • the container can include a pad or a dry wipe with cleaning solution.
  • a second example is a container with pad or dry wipe, implement and solution.
  • a third example is a container with concentrated refill, ready to use solution and pads with or without superabsorbent gelling.
  • Yet another example is a container with a premoistened wipe, either with or without an implement, with or without a handle.
  • the detergent composition (cleaning solution) is an aqueous-based solution comprising the hydrophihc polymer, optionally, but preferably, and optionally one or more detergent surfactants, the preferred alkylpolyglycosides being present if the hydrophihc polymer isn't present, optional solvents, builders, chelants, suds suppressors, enzymes, etc.
  • Suitable polymers are those previously described herein.
  • Suitable surfactants are commercially and are described in McCutcheon's Vol. 1 : Emulsifiers and Detergents, North American edition, McCutcheon's Division, MC Publishing Company, 1999. Again, the most preferred polymers are polymers containing amine oxide moieties.
  • the most preferred surfactants are the C 8 -C 16 polyalkylglucosides, and C 9 . ⁇ 2 ethoxylates with from about 4 to about 8 oxyethylene units, and mixtures thereof.
  • a suitable preferred cleaning solution for use in the context of floors, counters, walls, either as a stand-alone or in conjunction with conventional sponges, mops, rags, or with disposable pre-moistened wipes, pads, mops etc. comprises: from about 0.001 % to about 0.25%, preferably from about 0.005% to about 0.15%, more preferably from about 0.01 % to about 0.07% of the hydrophihc polymer.
  • the level of polymer chosen will depend on the application. For example, it is found that higher levels of hydrophihc polymer can leave a sticky feel on floors. Such a tack is more easily tolerated in applications such counters, stove tops and walls.
  • the composition can contain only the polymer, but preferably also contains from about 0.001% to about 0.5%, preferably from about 0.005% to about 0.25%, more preferably from about 0.005% to about 0.1 %, of detergent surfactant, preferably comprising said alkylpolyglucoside, more preferably the preferred alkyl polyglycoside containing a C 8 - 16 alkyl group and from about 1 to about 1.5, preferably from about 1.1 to about 1.4 glycosyl groups, and/or linear alkyl ethoxylate detergent surfactant (e.g., Neodol 1-5TM, available from Shell Chemical Co.) and/or an alkyl sulfonate (e.g., Bioterge PAS-8sTM, a linear Cg sulfonate available from Stepan Co.); optionally, from about 0.001 % to about 0.5%, preferably from about 0.01 % to about 0.3 volatile buffer material, e.g., ammonia, 2-dimethylamino-2
  • One embodiment of the invention also preferably comprises a detergent composition as disclosed herein in a container in association with instructions to use it with an absorbent structure comprising an effective amount of a superabsorbent material, and, optionally, in a container comprising the implement, or, at least, a disposable cleaning pad comprising a superabsorbent material.
  • This invention also relates to the use of a composition with hydrophihc polymer and a cleaning pad comprising a superabsorbent material to effect cleaning of soiled surfaces, i.e., the process of cleaning a surface comprising applying an effective amount of a detergent composition, typically containing no more than about 1 % detergent surfactant; a level of hydrophobic materials, including solvent, that is less than about 5%; and having a pH of more than about 9 and absorbing the composition in an absorbent structure comprising superabsorbent material.
  • the present invention relates to the use of the described detergent composition optionally containing a disappearing dye, with an implement for cleaning a surface of the type disclosed hereinbefore, the implement comprising: a. removable cleaning pad comprising a superabsorbent material and having a plurality of substantially planar surfaces, wherein each of the substantially planar surfaces contacts the surface being cleaned, and preferably a pad structure which has both a first layer and a second layer, wherein the first layer is located between the scrubbing layer and the second layer and has a smaller width than the second layer; and b. optionally, a handle
  • the pad preferably contains a superabsorbent material and preferably also provides significant cleaning benefits.
  • the preferred cleaning performance benefits are related to the preferred structural characteristics described below, combined with the ability of the pad to remove solubihzed soils.
  • the preferred cleaning pad, as described herein, when used with the preferred detergent composition, as described hereinbefore, provides optimum performance.
  • the preferred pads provide multiple planar surfaces as discussed hereinbefore. As used herein, all numerical values are approximations based upon normal variations; all parts, percentages, and ratios are by weight and by weight of the composition unless otherwise specified; and all patents and other publications referred to herein are incorporated herein by reference.
  • compositions are made by mixing the listed ingredients in the listed proportions in the listed order of addition.
  • Comparison products include those marketed under the following names with the indicated nominal compositions.
  • LAS Sodium Linear Alkylbenzene Sulfonate. The MW used for the calculation is 344 g/mol.
  • NaXS Sodium Xylene sulfonate.
  • BKC Benzalkonium Chloride.
  • the MW used for the calculation is 351 g ⁇ mol.
  • Alkylpolyglucoside Primary Detergent Surfactant 2
  • PVNO polyvinyl pyridine n-oxide
  • Gloss measurements Five gloss readings are made (60° angle measurements using a micro-TRI-gloss glossmeter manufactured by BYK Gardner, Germany) for each tile and the average of the readings recorded. Measurements are conducted near each of the corners and at the center of the tile.
  • Tile treatment with product Each tile is positioned vertically against a wall (or a sink). It is then sprayed with 5 ml of test product (note: this corresponds to 5 sprays), applied from a distance of about 2 feet (60 centimeters) using T8500 sprayers manufactured by Continental Sprayers Inc., St. Peters, MO, USA. Tile spraying (misting) is performed so as to maximize the product coverage on the tile. Following product treatment, tiles are allowed to air dry. Once dry, tile gloss is measured. The tiles are then visually inspected graded for spots, streaks and film left by the test product. On average, the difference between the gloss on the clean tile, and the gloss following product treatment corresponds to gloss loss due to product.
  • Simulated showers Water of known hardness is used to simulate shower events.
  • the tiles are positioned to stand vertically on a sink wall and are then sprayed with city warm city water (T ⁇ 100°F or 37°C) at a distance of about 2 feet (60 centimeters) using T8500 sprayers.
  • Each tile is sprayed at a constant dosage rate of 80 sprays per minute for three minutes (240 ml) and then allowed to dry under ambient conditions.
  • Tile spraying is performed so as to maximize the product coverage on the tile. Once dry, tiles are visually inspected and graded for spots and streaks (all product film is rinsed away over the three minute simulated shower event).
  • Cycles The above procedure can be repeated a number of times in an effort to simulate the effects of continuous use of the product following each shower event. It is observed that some products perform better with additional uses, though performance does not tend to improve any more after the third cycle use.
  • compositions All raw materials are purchased from commercial sources.
  • the PVNO used in the tests below is made by Reilly industries, and has a molecular weight of -20,000 g/mole.
  • the APG used in all tests is Plantaren 2000 from Henkel, a commercially available cosmetic grade C 8 _ ⁇ 6 polyalkylglucoside.
  • the Tivoli-cyclodextrin complex described in example 2 is made by mixing perfume and ⁇ -cyclodextrin so as to saturate the cavity of the ⁇ eta- cyclodextrin. Excess perfume is then removed and the complex is dried to a solid.
  • compositions comprising PVNO can be used to deliver excellent end result. All of these PVNO-compositions also provided unsurpassed sheeting benefits versus the competitive set.
  • the invention provides benefits of in a floor cleaning process which involves the use of a disposable pad that absorbs most, but not all, of the cleaning solution and in which there is no rinse step.
  • a floor cleaning process which involves the use of a disposable pad that absorbs most, but not all, of the cleaning solution and in which there is no rinse step.
  • Examples 1-14 each contain Dow Corning AF suds suppressor at 0.015%, Perfume at 0.04%. and deionized water balance to 100%.
  • compositions All raw materials are purchased from commercial sources.
  • the PVNO used in the tests below is made by Reilly industries, and has a molecular weight of -20,000 g/mole.
  • the surfactants used are Plantaren 2000 from Henkel a commercially available, cosmetic grade, C 8 . ⁇ 6 alkylpolyglucoside, Plantaren 1200 from Henkel is a commercially available cosmetic grade C 10-16 alkylpolyglucoside. AG-6210 from Akzo, a commercially available C 8 .
  • Neodol C11 E05 is a commercially available non-ionic alkylethoxylate containing an alkyl group with an average chain length of about 11 carbon atoms and about five ethoxy groups per molecule on the average.
  • the solvent used is Propylene Glycol Propyl Ether from Sigma Aldrich.
  • Soil Preparation The soil used in the test is prepared by mixing 820 g of isopropyl alcohol with 320 g de-ionized water. To this add 28.1 g of sifted Vacuum cleaner soil (provided by Empirical), 0.78 g of Crisco oil. 0.09 g of polymerized Crisco oil (viscosity 1800 cps) and 1.25 g of
  • Soiling Procedure Apply 3 mis. of soil solution to the center of each tile. Using a 3 inch nap paint roller, spread the soil out evenly across the tile until uniform coverage is achieved. Allow to dry.
  • the cleaning Pad Cut an absorbent mopping pad to 100 x 130mm.
  • This pad is composed of a 3 layer density gradient core made by Buckeye Chemicals.
  • the first layer (floor layer) has a density of 0.06 g/cc and a thickness of 4.5 mm and width of 63 mm.
  • the middle layer has a density of 0.1 g/cc and a thickness of 3mm and width of 89 mm.
  • the third layer (storage layer) has a density of 0.15 g/cc and a thickness of 1 mm and width of 120 mm.
  • Over the core on the floor side is an apertured formed film provided by Tredegar.
  • a Swiffer ® dry dusting mop head is cut down to 100 x 130 mm dimension (includes swivel head to create mopping action). To this mop head, a male Velcro strip is glued to provide means for attaching the pad. Cleaning Procedure:
  • Pad priming On a separate clean 332mmX332mm tile apply 3 mis. of a cleaning solution. Starting from the left and moving to the right, wipe up and down the tile for 6 cycles then back 6 cycles from right to left. Repeat wiping again such that 24 cycles of wiping are used.
  • the alkylpolyglucoside (APG) surfactants provide better performance than a standard ethoxylated nonionic, which is screened as being one of the better versions of this surfactant type.
  • the version with the broadest chain length range (C 8 . 16 ) provides the best performance (better than either C 10 . 16 or C 8 - ⁇ 2 ).
  • an additionally improvement is seen when surfactant, PVNO and a specific solvent is added (propylene glycol propyl ether, e.g., "PGPE").
  • Material can be tested wet or dry.
  • Glide test can be performed on other surfaces. Surfaces need to be cut to 7"x18". Use C- clamps to attach to INSTRON slope board.
  • Metric measurement kilograms of force - maximum force level calculated Slope Board: angle 12.4° Cross Head Travel: 350 mm
  • premoistened wipes comprising the specified substrates are tested for glide performance on glass with the INSTROM apparatus described above.
  • the specific substrates are: #1. Bounty paper towel (-100% cellulose); #2. 70% Cellulose 13% Polyester, 17% binder; #3. 75% cellulose, 25% polypropylene; #4. 70% polyester, 30% cellulose; #5. 100% polypropylene.
  • Premoistened wipes are tested wet using a 1.7 loading factor, i.e., 1.7 grams of liquid (Cinch® cleaning spray, available from The Procter & Gamble Company, is used as the liquid in all of this testing) per gram of dry substrate.
  • the substrates are also tested dry, i.e., with no liquid on the dry wipe. Lower friction numbers are indicative of preferred glide performance. T groupings are used to establish significance between the friction readings.
  • the cellulosic substrate has the largest degree of friction on glass, and the high polyester and high polypropylene-content substrates display significantly better glide, i.e., lower friction on glass.
  • Combinations of cellulosic or superabsorbent polymers and polyester, nylon, or polyakylene are desirable, especially so long as the hydrophobic fibers, spots, etc., are on the surface to provide glide.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Detergent Compositions (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Nonwoven Fabrics (AREA)
  • Cleaning In General (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des compositions préférées de nettoyage pour surfaces dures, de préférence liquides, des compositions avec une composition liquide de nettoyage sur un substrat, des compositions utilisées avec des tampons absorbants, des équipements et appareils servant à effectuer le nettoyage de surfaces dures et/ou à entretenir leur aspect et leur hygiène plus facilement et plus efficacement. Ces compositions, ainsi que des instructions spécifiques quant à leur emploi, sont très utiles pour enlever et/ou empêcher l'accumulation de salissures fréquemment trouvées sur les sols, surfaces en verre, comptoirs, murs, douches et/ou baignoires. Lesdites compositions comportent des polymères hydrophiles, permettant de rendre la surface nettoyée hydrophile et d'améliorer son aspect, lorsque la surface n'est pas rincée, ou lorsque la composition n'est pas complètement enlevée, un surfactant spécifique, choisi de préférence, en vue de limiter au maximum les tâches/couches, éventuellement des solvants de nettoyage organiques spécifiques, afin de nettoyer et d'humidifier, en particulier dans les applications, où les niveaux de produits non volatiles doivent être réduits au minimum et éventuellement, des agents anti-bactériens servant à préserver l'activité de la surface et éventuellement des parfums par souci de goût.
EP00970492A 1999-09-27 2000-09-26 Compositions de nettoyage pour surfaces dures Expired - Lifetime EP1290121B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP05028152A EP1661503A3 (fr) 1999-09-27 2000-09-26 Compositions de nettoyage pour surfaces dures, chiffons prehumidifiés, méthodes de utilisation et produits contenant ses compositions
EP08167764A EP2036481A3 (fr) 1999-09-27 2000-09-26 Lingettes pré-humidifiées et procédés d'utilisation

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US15628699P 1999-09-27 1999-09-27
US156286P 1999-09-27
PCT/US2000/026401 WO2001023510A2 (fr) 1999-09-27 2000-09-26 Compositions de nettoyage pour surfaces dures, tampons prehumidifies, procedes d'utilisation et articles comportant lesdites compositions, ou tampons et instructions d'emploi permettant un nettoyage et un entretien facilites, un aspect de la surface et/ou de l'hygiene ameliores dans des conditions d'urgence telles que le no

Related Child Applications (2)

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EP08167764A Division EP2036481A3 (fr) 1999-09-27 2000-09-26 Lingettes pré-humidifiées et procédés d'utilisation
EP05028152A Division EP1661503A3 (fr) 1999-09-27 2000-09-26 Compositions de nettoyage pour surfaces dures, chiffons prehumidifiés, méthodes de utilisation et produits contenant ses compositions

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EP1290121A2 true EP1290121A2 (fr) 2003-03-12
EP1290121B1 EP1290121B1 (fr) 2008-10-29

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EP05028152A Withdrawn EP1661503A3 (fr) 1999-09-27 2000-09-26 Compositions de nettoyage pour surfaces dures, chiffons prehumidifiés, méthodes de utilisation et produits contenant ses compositions
EP08167764A Withdrawn EP2036481A3 (fr) 1999-09-27 2000-09-26 Lingettes pré-humidifiées et procédés d'utilisation

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EP08167764A Withdrawn EP2036481A3 (fr) 1999-09-27 2000-09-26 Lingettes pré-humidifiées et procédés d'utilisation

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EP (3) EP1290121B1 (fr)
JP (1) JP3908535B2 (fr)
AR (1) AR022660A1 (fr)
AT (1) ATE412726T1 (fr)
AU (1) AU7986400A (fr)
CA (2) CA2524671C (fr)
DE (1) DE60040691D1 (fr)
EG (1) EG22597A (fr)
ES (1) ES2316391T3 (fr)
MX (1) MXPA02003223A (fr)
WO (1) WO2001023510A2 (fr)
ZA (2) ZA200202004B (fr)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11097030B2 (en) 2014-12-08 2021-08-24 Kinnos, Inc. Additive compositions for pigmented disinfection and methods thereof
US11583603B2 (en) 2014-12-08 2023-02-21 Kinnos Inc. Additive compositions for pigmented disinfection and methods thereof
US11992574B2 (en) 2014-12-08 2024-05-28 Kinnos Inc. Additive compositions for pigmented disinfection and methods thereof
US11555167B2 (en) 2016-02-12 2023-01-17 Kinnos Inc. Compositions and methods for use in surface decontamination
US11555166B2 (en) 2016-02-12 2023-01-17 Kinnos Inc. Compositions and methods for use in surface decontamination
US11555168B2 (en) 2016-02-12 2023-01-17 Kinnos Inc. Compositions and methods for use in surface decontamination
US11802260B2 (en) 2016-02-12 2023-10-31 Kinnos Inc. Compositions and methods for use in surface decontamination
US11185605B2 (en) 2016-07-25 2021-11-30 Kinnos Inc. Device and related compositions and methods for use in surface decontamination
US11464371B2 (en) 2018-07-12 2022-10-11 Kinnos Inc. Devices, compositions, and methods for use in surface decontamination
US11969123B2 (en) 2018-07-12 2024-04-30 Kinnos Inc. Devices, compositions, and methods for use in surface decontamination

Also Published As

Publication number Publication date
CA2384307A1 (fr) 2001-04-05
ZA200202004B (en) 2003-06-11
WO2001023510A8 (fr) 2001-10-25
AU7986400A (en) 2001-04-30
JP3908535B2 (ja) 2007-04-25
EG22597A (en) 2003-04-30
DE60040691D1 (de) 2008-12-11
ES2316391T3 (es) 2009-04-16
CA2384307C (fr) 2009-06-02
EP1661503A2 (fr) 2006-05-31
AR022660A1 (es) 2002-09-04
EP1290121B1 (fr) 2008-10-29
EP2036481A2 (fr) 2009-03-18
ZA200202001B (en) 2003-08-27
WO2001023510A2 (fr) 2001-04-05
EP1661503A3 (fr) 2008-01-02
ATE412726T1 (de) 2008-11-15
CA2524671A1 (fr) 2001-04-05
CA2524671C (fr) 2012-01-10
JP2003528164A (ja) 2003-09-24
EP2036481A3 (fr) 2010-09-22
MXPA02003223A (es) 2002-09-30

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