EP1280735A2 - Aragonite precipitee et procede de production associe - Google Patents
Aragonite precipitee et procede de production associeInfo
- Publication number
- EP1280735A2 EP1280735A2 EP01908077A EP01908077A EP1280735A2 EP 1280735 A2 EP1280735 A2 EP 1280735A2 EP 01908077 A EP01908077 A EP 01908077A EP 01908077 A EP01908077 A EP 01908077A EP 1280735 A2 EP1280735 A2 EP 1280735A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- aragonite
- particulate precipitated
- acid
- precipitated aragonite
- active agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K20/00—Accessory food factors for animal feeding-stuffs
- A23K20/20—Inorganic substances, e.g. oligoelements
- A23K20/24—Compounds of alkaline earth metals, e.g. magnesium
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/70—Fixation, conservation, or encapsulation of flavouring agents
- A23L27/77—Use of inorganic solid carriers, e.g. silica
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/294—Inorganic additives, e.g. silica
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P10/00—Shaping or working of foodstuffs characterised by the products
- A23P10/40—Shaping or working of foodstuffs characterised by the products free-flowing powder or instant powder, i.e. powder which is reconstituted rapidly when liquid is added
- A23P10/43—Shaping or working of foodstuffs characterised by the products free-flowing powder or instant powder, i.e. powder which is reconstituted rapidly when liquid is added using anti-caking agents or agents improving flowability, added during or after formation of the powder
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
- A61K33/06—Aluminium, calcium or magnesium; Compounds thereof, e.g. clay
- A61K33/10—Carbonates; Bicarbonates
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28011—Other properties, e.g. density, crush strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/60—Preparation of carbonates or bicarbonates in general
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
- C01F11/182—Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
- C01F11/182—Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds
- C01F11/183—Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds the additive being an organic compound
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1233—Carbonates, e.g. calcite or dolomite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/08—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
Definitions
- a process for producing a particulate precipitated aragonite calcium carbonate, and the particulate precipitated aragonite calcium carbonate thus produced comprises reacting an aqueous calcium hydroxide slurry with a gas selected from the group consisting of carbon dioxide and a gas containing it, wherein the parameters of said process, including at least one preselected active agent, mode of operation, operating concentrations of raw materials, operating temperature, operating mixer speed and operating pH, wherein said at least one active agent is selected from nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tetradecanoic acid, octadecanoicacid, and undecylenic acid, their carboxylate salts, their acid anhydrides, their esters, their acyl halides and their ketenes.
- this threshold concentration discussed above, for catalyzing the production of particulate precipitated aragonite, of the present invention ( ⁇ 0.2% wt.%, based on CaCOs) is substantially above the threshold concentration that is required to cause the flotation of this product in aqueous solutions ( ⁇ 0.02% wt.%, based on CaCOs) and that by operating in the concentration range merely for a "proper" flotation process, nothing that is disclosed in the present invention really happens.
- the optimal physical and chemical properties of the particulate precipitated aragonite calcium carbonate, of the present invention are attained at above 100 fold of this concentration ( ⁇ 2-3 wt.%, based on CaCOs).
- the first 10 I. of resulting slurry were discarded.
- the residual slurry was collected and it was filtered through a filter-cloth on the Buchner using a vacuum pump to dewater the product.
- the filter cake was dried for 12 hours at 120°C and the crystallographic morphologies and the shapes of the crystals of the precipitated calcite and/or aragonite calcium carbonate particles were determined using XRD and SEM analyses, respectively. The results are shown in the Table 1 , below.
- the active agents were investigated by producing precipitated calcium carbonate particles according to the following procedure:
- the resulting slurry was filtered through a filter cloth on the Buchner using a vacuum pump to dewater the product.
- the filter cake was dried for 12 hours at 120°C and the crystallographic morphologies and the shapes of the crystals of the precipitated calcite particles were determined using XRD and SEM analyses, respectively. As mentioned above, no precipitated aragonite particles were obtained.
- Rotor Speed 4800 rpm (Tip Speed ⁇ 12 m/sec).
- pH variable.
- Temperature 87°C.
- Carbon dioxide flow rate 180 L.P.H. (liters/hour)
- Aqueous calcium hydroxide slurry (of Shfeya) -10 wt.% ⁇ 6 L.P.H. (to maintain the preset pH value).
- Active agent concentration decanoic acid; 0.5 wt.% based on CaCO 3 .
- Active agent concentration decanoic acid; 1 wt.% based on CaCO 3 .
- Active agent concentration decanoic acid 1 wt.% based on CaCO 3 .
- Aqueous calcium hydroxide slurry (of Shfeya) -10 wt.% - 6 L.P.H. (to maintain the preset pH value).
- Cellosize QP 15000 thickener (hydroxy ethyl cellulose).
- Copolymer vinyl acetate acrylate (55% N.V.) (emulsion).
- particulate precipitated aragonite calcium carbonate of the present invention (PCC-Aragonite) is not yet optimized for its use in the production of paints and though the formulations used are by no means optimized, still this product is able to substitute over 50% of the expensive titanium oxide pigment without any deterioration of the resulting paint, as it manifested by the hiding power measured.
- Aqueous calcium hydroxide slurry (of Shfeya) -10 wt.% ⁇ 6 L.P.H. (to maintain the preset pH value).
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Analytical Chemistry (AREA)
- Nutrition Science (AREA)
- Epidemiology (AREA)
- Medicinal Chemistry (AREA)
- Geology (AREA)
- Pharmacology & Pharmacy (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Animal Husbandry (AREA)
- Zoology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Paper (AREA)
Abstract
L'invention concerne une nouvelle forme d'aragonite précipitée particulaire, ainsi qu'un nouveau procédé de production associé.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/519,749 US6685908B1 (en) | 2000-03-06 | 2000-03-06 | Precipitated aragonite and a process for producing it |
US519749 | 2000-03-06 | ||
US778920 | 2001-02-08 | ||
US09/778,920 US20010033820A1 (en) | 2000-03-06 | 2001-02-08 | Precipitated aragonite and a process for producing it |
PCT/IL2001/000166 WO2001066467A1 (fr) | 2000-03-06 | 2001-02-22 | Aragonite precipitee et procede de production associe |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1280735A2 true EP1280735A2 (fr) | 2003-02-05 |
EP1280735A4 EP1280735A4 (fr) | 2003-07-09 |
Family
ID=27059948
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01908077A Withdrawn EP1280735A4 (fr) | 2000-03-06 | 2001-02-22 | Aragonite precipitee et procede de production associe |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1280735A4 (fr) |
CN (1) | CN1443136A (fr) |
AU (1) | AU2001235934A1 (fr) |
CA (1) | CA2401899A1 (fr) |
IL (1) | IL151510A0 (fr) |
WO (1) | WO2001066467A1 (fr) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10120635A1 (de) * | 2001-04-27 | 2002-10-31 | Voith Paper Patent Gmbh | Verfahren und Vorrichtung zum Beladen von Fasern mit Calciumcarbonat |
CN1328327C (zh) * | 2002-10-03 | 2007-07-25 | 丸尾钙株式会社 | 经表面处理的碳酸钙和含有该碳酸钙的树脂组合物 |
US20040108081A1 (en) * | 2002-12-09 | 2004-06-10 | Specialty Minerals (Michigan) Inc. | Filler-fiber composite |
RU2436734C2 (ru) | 2007-04-20 | 2011-12-20 | Омйа Девелопмент Аг | Способ получения осажденного карбоната кальция, способ для повышения содержания сухого вещества продукта осажденного карбоната кальция и реакторная система для производства осажденного карбоната кальция |
FR3025792B1 (fr) * | 2014-09-17 | 2016-11-25 | Veolia Water Solutions & Tech | Dispositif de traitement d'effluents salins sursatures en presence d'inhibiteurs de precipitation |
EP2997833B1 (fr) * | 2014-09-22 | 2018-01-31 | Omya International AG | Carbonate de calcium traité par réaction en surface pour une utilisation en tant qu'agent anti-agglomérant |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5164172A (en) * | 1989-06-29 | 1992-11-17 | Maruo Calcium Company Limited | Process for producing aragonite crystal form calcium carbonate with acicular shape |
US5376343A (en) * | 1992-02-26 | 1994-12-27 | Pretoria Portland Cement Company Limited | Production of purified calcium carbonate |
WO2000003949A1 (fr) * | 1998-07-14 | 2000-01-27 | Unilever N.V. | Composition administree par voie orale |
US6022517A (en) * | 1996-09-05 | 2000-02-08 | Minerals Technologies Inc. | Acicular calcite and aragonite calcium carbonate |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3669620A (en) * | 1969-09-08 | 1972-06-13 | Tate & Lyle Ltd | Manufacture of aragonite |
JPS54111000A (en) * | 1978-02-21 | 1979-08-30 | Ito Masaaki | Porous calcium carbonate and its manufacture |
JPS5964527A (ja) * | 1982-09-29 | 1984-04-12 | Shiraishi Chuo Kenkyusho:Kk | アモルファス炭酸カルシウムの製造方法 |
JPS59232916A (ja) * | 1983-06-16 | 1984-12-27 | Shiraishi Chuo Kenkyusho:Kk | 針柱状炭酸カルシウム結束体、その製造法及び該結束体を含有する感熱紙用塗被組成物 |
JPH075302B2 (ja) * | 1988-07-21 | 1995-01-25 | 奥多摩工業株式会社 | 繊維状炭酸カルシウムの製造方法 |
RU2156737C1 (ru) * | 2000-03-07 | 2000-09-27 | Кузнецов Игорь Олегович | Способ получения химически осажденного мела |
-
2001
- 2001-02-22 WO PCT/IL2001/000166 patent/WO2001066467A1/fr not_active Application Discontinuation
- 2001-02-22 EP EP01908077A patent/EP1280735A4/fr not_active Withdrawn
- 2001-02-22 CN CN01808836A patent/CN1443136A/zh active Pending
- 2001-02-22 IL IL15151001A patent/IL151510A0/xx unknown
- 2001-02-22 CA CA002401899A patent/CA2401899A1/fr not_active Abandoned
- 2001-02-22 AU AU2001235934A patent/AU2001235934A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5164172A (en) * | 1989-06-29 | 1992-11-17 | Maruo Calcium Company Limited | Process for producing aragonite crystal form calcium carbonate with acicular shape |
US5376343A (en) * | 1992-02-26 | 1994-12-27 | Pretoria Portland Cement Company Limited | Production of purified calcium carbonate |
US6022517A (en) * | 1996-09-05 | 2000-02-08 | Minerals Technologies Inc. | Acicular calcite and aragonite calcium carbonate |
WO2000003949A1 (fr) * | 1998-07-14 | 2000-01-27 | Unilever N.V. | Composition administree par voie orale |
Non-Patent Citations (6)
Title |
---|
DATABASE CA [Online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; TANAKA, KOICHI ET AL: "Manufacture of fibrous calcium carbonate" retrieved from STN Database accession no. 113:135182 CA XP002236058 & JP 02 034514 A (OKUTAMA KOGYO CO., LTD., JAPAN) 5 February 1990 (1990-02-05) * |
DATABASE WPI Section Ch, Week 197941 Derwent Publications Ltd., London, GB; Class C01,Page e33, AN 1979-742328 XP002236061 & JP 54 111000 A (ITO), 30 August 1979 (1979-08-30) * |
DATABASE WPI Section Ch, Week 199011 Derwent Publications Ltd., London, GB; Class E33, AN 1990-080250 XP002236059 & JP 02 034514 A (OKUTAMA KOGYO KK), 5 February 1990 (1990-02-05) * |
DATABASE WPI Section Ch, Week 200110 Derwent Publications Ltd., London, GB; Class E33, AN 2001-089330 XP002236060 & RU 2 156 737 C (KUZNETSOV I O), 27 September 2000 (2000-09-27) * |
PATENT ABSTRACTS OF JAPAN vol. 008, no. 162 (C-235), 26 July 1984 (1984-07-26) & JP 59 064527 A (SHIRAISHI CHUO KENKYUSHO:KK), 12 April 1984 (1984-04-12) * |
See also references of WO0166467A1 * |
Also Published As
Publication number | Publication date |
---|---|
CA2401899A1 (fr) | 2001-09-13 |
IL151510A0 (en) | 2003-04-10 |
CN1443136A (zh) | 2003-09-17 |
EP1280735A4 (fr) | 2003-07-09 |
AU2001235934A1 (en) | 2001-09-17 |
WO2001066467A8 (fr) | 2002-02-21 |
WO2001066467A1 (fr) | 2001-09-13 |
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