EP1280735A2 - Aragonite precipitee et procede de production associe - Google Patents

Aragonite precipitee et procede de production associe

Info

Publication number
EP1280735A2
EP1280735A2 EP01908077A EP01908077A EP1280735A2 EP 1280735 A2 EP1280735 A2 EP 1280735A2 EP 01908077 A EP01908077 A EP 01908077A EP 01908077 A EP01908077 A EP 01908077A EP 1280735 A2 EP1280735 A2 EP 1280735A2
Authority
EP
European Patent Office
Prior art keywords
aragonite
particulate precipitated
acid
precipitated aragonite
active agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01908077A
Other languages
German (de)
English (en)
Other versions
EP1280735A4 (fr
Inventor
Isaac Yaniv
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3P Technologies Ltd
Original Assignee
3P Technologies Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/519,749 external-priority patent/US6685908B1/en
Application filed by 3P Technologies Ltd filed Critical 3P Technologies Ltd
Publication of EP1280735A2 publication Critical patent/EP1280735A2/fr
Publication of EP1280735A4 publication Critical patent/EP1280735A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/043Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/20Inorganic substances, e.g. oligoelements
    • A23K20/24Compounds of alkaline earth metals, e.g. magnesium
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/70Fixation, conservation, or encapsulation of flavouring agents
    • A23L27/77Use of inorganic solid carriers, e.g. silica
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/294Inorganic additives, e.g. silica
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P10/00Shaping or working of foodstuffs characterised by the products
    • A23P10/40Shaping or working of foodstuffs characterised by the products free-flowing powder or instant powder, i.e. powder which is reconstituted rapidly when liquid is added
    • A23P10/43Shaping or working of foodstuffs characterised by the products free-flowing powder or instant powder, i.e. powder which is reconstituted rapidly when liquid is added using anti-caking agents or agents improving flowability, added during or after formation of the powder
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K33/00Medicinal preparations containing inorganic active ingredients
    • A61K33/06Aluminium, calcium or magnesium; Compounds thereof, e.g. clay
    • A61K33/10Carbonates; Bicarbonates
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00Formulations or additives for perfume preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011Other properties, e.g. density, crush strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/60Preparation of carbonates or bicarbonates in general
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00Compounds of calcium, strontium, or barium
    • C01F11/18Carbonates
    • C01F11/182Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00Compounds of calcium, strontium, or barium
    • C01F11/18Carbonates
    • C01F11/182Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds
    • C01F11/183Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds the additive being an organic compound
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers
    • C05D3/02Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/1233Carbonates, e.g. calcite or dolomite
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/08Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances oxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/10Particle morphology extending in one dimension, e.g. needle-like
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/10Solid density
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675Oxides, hydroxides or carbonates

Definitions

  • a process for producing a particulate precipitated aragonite calcium carbonate, and the particulate precipitated aragonite calcium carbonate thus produced comprises reacting an aqueous calcium hydroxide slurry with a gas selected from the group consisting of carbon dioxide and a gas containing it, wherein the parameters of said process, including at least one preselected active agent, mode of operation, operating concentrations of raw materials, operating temperature, operating mixer speed and operating pH, wherein said at least one active agent is selected from nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tetradecanoic acid, octadecanoicacid, and undecylenic acid, their carboxylate salts, their acid anhydrides, their esters, their acyl halides and their ketenes.
  • this threshold concentration discussed above, for catalyzing the production of particulate precipitated aragonite, of the present invention ( ⁇ 0.2% wt.%, based on CaCOs) is substantially above the threshold concentration that is required to cause the flotation of this product in aqueous solutions ( ⁇ 0.02% wt.%, based on CaCOs) and that by operating in the concentration range merely for a "proper" flotation process, nothing that is disclosed in the present invention really happens.
  • the optimal physical and chemical properties of the particulate precipitated aragonite calcium carbonate, of the present invention are attained at above 100 fold of this concentration ( ⁇ 2-3 wt.%, based on CaCOs).
  • the first 10 I. of resulting slurry were discarded.
  • the residual slurry was collected and it was filtered through a filter-cloth on the Buchner using a vacuum pump to dewater the product.
  • the filter cake was dried for 12 hours at 120°C and the crystallographic morphologies and the shapes of the crystals of the precipitated calcite and/or aragonite calcium carbonate particles were determined using XRD and SEM analyses, respectively. The results are shown in the Table 1 , below.
  • the active agents were investigated by producing precipitated calcium carbonate particles according to the following procedure:
  • the resulting slurry was filtered through a filter cloth on the Buchner using a vacuum pump to dewater the product.
  • the filter cake was dried for 12 hours at 120°C and the crystallographic morphologies and the shapes of the crystals of the precipitated calcite particles were determined using XRD and SEM analyses, respectively. As mentioned above, no precipitated aragonite particles were obtained.
  • Rotor Speed 4800 rpm (Tip Speed ⁇ 12 m/sec).
  • pH variable.
  • Temperature 87°C.
  • Carbon dioxide flow rate 180 L.P.H. (liters/hour)
  • Aqueous calcium hydroxide slurry (of Shfeya) -10 wt.% ⁇ 6 L.P.H. (to maintain the preset pH value).
  • Active agent concentration decanoic acid; 0.5 wt.% based on CaCO 3 .
  • Active agent concentration decanoic acid; 1 wt.% based on CaCO 3 .
  • Active agent concentration decanoic acid 1 wt.% based on CaCO 3 .
  • Aqueous calcium hydroxide slurry (of Shfeya) -10 wt.% - 6 L.P.H. (to maintain the preset pH value).
  • Cellosize QP 15000 thickener (hydroxy ethyl cellulose).
  • Copolymer vinyl acetate acrylate (55% N.V.) (emulsion).
  • particulate precipitated aragonite calcium carbonate of the present invention (PCC-Aragonite) is not yet optimized for its use in the production of paints and though the formulations used are by no means optimized, still this product is able to substitute over 50% of the expensive titanium oxide pigment without any deterioration of the resulting paint, as it manifested by the hiding power measured.
  • Aqueous calcium hydroxide slurry (of Shfeya) -10 wt.% ⁇ 6 L.P.H. (to maintain the preset pH value).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • Analytical Chemistry (AREA)
  • Nutrition Science (AREA)
  • Epidemiology (AREA)
  • Medicinal Chemistry (AREA)
  • Geology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Dispersion Chemistry (AREA)
  • Animal Husbandry (AREA)
  • Zoology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Paper (AREA)

Abstract

L'invention concerne une nouvelle forme d'aragonite précipitée particulaire, ainsi qu'un nouveau procédé de production associé.
EP01908077A 2000-03-06 2001-02-22 Aragonite precipitee et procede de production associe Withdrawn EP1280735A4 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US09/519,749 US6685908B1 (en) 2000-03-06 2000-03-06 Precipitated aragonite and a process for producing it
US519749 2000-03-06
US778920 2001-02-08
US09/778,920 US20010033820A1 (en) 2000-03-06 2001-02-08 Precipitated aragonite and a process for producing it
PCT/IL2001/000166 WO2001066467A1 (fr) 2000-03-06 2001-02-22 Aragonite precipitee et procede de production associe

Publications (2)

Publication Number Publication Date
EP1280735A2 true EP1280735A2 (fr) 2003-02-05
EP1280735A4 EP1280735A4 (fr) 2003-07-09

Family

ID=27059948

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01908077A Withdrawn EP1280735A4 (fr) 2000-03-06 2001-02-22 Aragonite precipitee et procede de production associe

Country Status (6)

Country Link
EP (1) EP1280735A4 (fr)
CN (1) CN1443136A (fr)
AU (1) AU2001235934A1 (fr)
CA (1) CA2401899A1 (fr)
IL (1) IL151510A0 (fr)
WO (1) WO2001066467A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10120635A1 (de) * 2001-04-27 2002-10-31 Voith Paper Patent Gmbh Verfahren und Vorrichtung zum Beladen von Fasern mit Calciumcarbonat
CN1328327C (zh) * 2002-10-03 2007-07-25 丸尾钙株式会社 经表面处理的碳酸钙和含有该碳酸钙的树脂组合物
US20040108081A1 (en) * 2002-12-09 2004-06-10 Specialty Minerals (Michigan) Inc. Filler-fiber composite
RU2436734C2 (ru) 2007-04-20 2011-12-20 Омйа Девелопмент Аг Способ получения осажденного карбоната кальция, способ для повышения содержания сухого вещества продукта осажденного карбоната кальция и реакторная система для производства осажденного карбоната кальция
FR3025792B1 (fr) * 2014-09-17 2016-11-25 Veolia Water Solutions & Tech Dispositif de traitement d'effluents salins sursatures en presence d'inhibiteurs de precipitation
EP2997833B1 (fr) * 2014-09-22 2018-01-31 Omya International AG Carbonate de calcium traité par réaction en surface pour une utilisation en tant qu'agent anti-agglomérant

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5164172A (en) * 1989-06-29 1992-11-17 Maruo Calcium Company Limited Process for producing aragonite crystal form calcium carbonate with acicular shape
US5376343A (en) * 1992-02-26 1994-12-27 Pretoria Portland Cement Company Limited Production of purified calcium carbonate
WO2000003949A1 (fr) * 1998-07-14 2000-01-27 Unilever N.V. Composition administree par voie orale
US6022517A (en) * 1996-09-05 2000-02-08 Minerals Technologies Inc. Acicular calcite and aragonite calcium carbonate

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Publication number Priority date Publication date Assignee Title
US3669620A (en) * 1969-09-08 1972-06-13 Tate & Lyle Ltd Manufacture of aragonite
JPS54111000A (en) * 1978-02-21 1979-08-30 Ito Masaaki Porous calcium carbonate and its manufacture
JPS5964527A (ja) * 1982-09-29 1984-04-12 Shiraishi Chuo Kenkyusho:Kk アモルファス炭酸カルシウムの製造方法
JPS59232916A (ja) * 1983-06-16 1984-12-27 Shiraishi Chuo Kenkyusho:Kk 針柱状炭酸カルシウム結束体、その製造法及び該結束体を含有する感熱紙用塗被組成物
JPH075302B2 (ja) * 1988-07-21 1995-01-25 奥多摩工業株式会社 繊維状炭酸カルシウムの製造方法
RU2156737C1 (ru) * 2000-03-07 2000-09-27 Кузнецов Игорь Олегович Способ получения химически осажденного мела

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5164172A (en) * 1989-06-29 1992-11-17 Maruo Calcium Company Limited Process for producing aragonite crystal form calcium carbonate with acicular shape
US5376343A (en) * 1992-02-26 1994-12-27 Pretoria Portland Cement Company Limited Production of purified calcium carbonate
US6022517A (en) * 1996-09-05 2000-02-08 Minerals Technologies Inc. Acicular calcite and aragonite calcium carbonate
WO2000003949A1 (fr) * 1998-07-14 2000-01-27 Unilever N.V. Composition administree par voie orale

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
DATABASE CA [Online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; TANAKA, KOICHI ET AL: "Manufacture of fibrous calcium carbonate" retrieved from STN Database accession no. 113:135182 CA XP002236058 & JP 02 034514 A (OKUTAMA KOGYO CO., LTD., JAPAN) 5 February 1990 (1990-02-05) *
DATABASE WPI Section Ch, Week 197941 Derwent Publications Ltd., London, GB; Class C01,Page e33, AN 1979-742328 XP002236061 & JP 54 111000 A (ITO), 30 August 1979 (1979-08-30) *
DATABASE WPI Section Ch, Week 199011 Derwent Publications Ltd., London, GB; Class E33, AN 1990-080250 XP002236059 & JP 02 034514 A (OKUTAMA KOGYO KK), 5 February 1990 (1990-02-05) *
DATABASE WPI Section Ch, Week 200110 Derwent Publications Ltd., London, GB; Class E33, AN 2001-089330 XP002236060 & RU 2 156 737 C (KUZNETSOV I O), 27 September 2000 (2000-09-27) *
PATENT ABSTRACTS OF JAPAN vol. 008, no. 162 (C-235), 26 July 1984 (1984-07-26) & JP 59 064527 A (SHIRAISHI CHUO KENKYUSHO:KK), 12 April 1984 (1984-04-12) *
See also references of WO0166467A1 *

Also Published As

Publication number Publication date
CA2401899A1 (fr) 2001-09-13
IL151510A0 (en) 2003-04-10
CN1443136A (zh) 2003-09-17
EP1280735A4 (fr) 2003-07-09
AU2001235934A1 (en) 2001-09-17
WO2001066467A8 (fr) 2002-02-21
WO2001066467A1 (fr) 2001-09-13

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