EP1250204B1 - Method for making light alloy components - Google Patents

Method for making light alloy components Download PDF

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Publication number
EP1250204B1
EP1250204B1 EP00993697A EP00993697A EP1250204B1 EP 1250204 B1 EP1250204 B1 EP 1250204B1 EP 00993697 A EP00993697 A EP 00993697A EP 00993697 A EP00993697 A EP 00993697A EP 1250204 B1 EP1250204 B1 EP 1250204B1
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Prior art keywords
preform
graphite
forging
casting
container
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German (de)
French (fr)
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EP1250204A1 (en
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Emile Di Serio
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Saint Jean Industries SAS
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Saint Jean Industries SAS
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21JFORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J5/00Methods for forging, hammering, or pressing; Special equipment or accessories therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D31/00Cutting-off surplus material, e.g. gates; Cleaning and working on castings
    • B22D31/002Cleaning, working on castings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21JFORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J1/00Preparing metal stock or similar ancillary operations prior, during or post forging, e.g. heating or cooling
    • B21J1/06Heating or cooling methods or arrangements specially adapted for performing forging or pressing operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21JFORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J5/00Methods for forging, hammering, or pressing; Special equipment or accessories therefor
    • B21J5/002Hybrid process, e.g. forging following casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21JFORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J5/00Methods for forging, hammering, or pressing; Special equipment or accessories therefor
    • B21J5/02Die forging; Trimming by making use of special dies ; Punching during forging
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon

Definitions

  • the invention relates to the technical sector of the manufacture of light alloy parts, in particular aluminum, obtained in foundry, forging and similar processes.
  • EP 119.365 discloses a specific process called COBAPRESS which combines the techniques of foundry and forging of aluminum or aluminum alloy parts.
  • this process consists of casting aluminum or aluminum alloy in a mold and after casting, to release the part still hot called preform at a temperature of the order of 400 ° C at 500 ° C, we place it between two matrices or parts of a matrix defining a footprint of dimensions slightly smaller than those of the mold, which correspond to those of the final piece, the two shells or parts being strongly pressed against each other to exert on the casting preform put between the parts of the dies a combined effect of core pressing and surface dressing.
  • COBAPRESS 2 therefore makes it possible to reduce production time and manufacturing cost so significant parts, while obtaining the same characteristics of the parts compared to the teaching of the COBAPRESS process described in the EP patent 119,365.
  • the aim sought after according to the invention was therefore to ensure optimization of the initial COBAPRESS process of cast-forged light alloy.
  • the applicant has attempted to optimize the COBAPRESS process as defined by the aforementioned prior patents.
  • a first step was to focus on improving the conditions for depositing graphite in the forging matrix by spraying the graphite solution on the forging matrix, with better control of the distribution using robots. In practice, this solution is not very satisfactory, because it still requires human intervention, and the costs and environmental problems are still there.
  • the process for manufacturing the light alloy parts according to the invention requires installation with five successive specific zones covering the different stages of the process.
  • the first zone (Z1) corresponds to the casting of the light alloy in a mold (1) enabling a preform (2) to be obtained under the conditions previously recalled.
  • the second zone (Z2) corresponds to the transfer of the preform (2) heated in a tank (3) for immersion and graphitation by coating the preform (2).
  • the bath is a solution of graphite and water.
  • a phase (Z3) of drying the preformed part is provided out of the bath.
  • the following zone (Z4) corresponds to the transfer of the preform dried graphite in the tunnel oven (4) for homogenization in temperature.
  • the following zone (Z5) corresponds to the exit of the tunnel oven from the preform to be then forged in a matrix (5) which is the object less and faster lubrication limited to the burr bead depending on the conditions mentioned above, then cooled to temperature ambient or accelerated or drenched.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Forging (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Mold Materials And Core Materials (AREA)

Abstract

The invention concerns a method for making alloy components characterised in that after casting the preform (2) and before transferring it into a forging matrix (5), said preform, still hot at the end of casting, is transferred and completely immersed in a vessel (3) for graphitization coating, then, on coming out of the vessel, the preform temperature enabling the water to be evaporated so that the preform is homogeneously coated with graphite.

Description

L'invention se rattache au secteur technique de la fabrication de pièces en alliage léger, notamment en aluminium, obtenues en fonderie, forgeage et procédés similaires.The invention relates to the technical sector of the manufacture of light alloy parts, in particular aluminum, obtained in foundry, forging and similar processes.

On connaít, par le brevet EP 119.365, un procédé spécifique dénommé COBAPRESS qui combine les techniques de fonderie et de forgeage de pièces en aluminium ou alliages d'aluminium.EP 119.365 discloses a specific process called COBAPRESS which combines the techniques of foundry and forging of aluminum or aluminum alloy parts.

On rappelle que ce procédé consiste à couler de l'aluminium ou alliage d'aluminium dans un moule et après la coulée, à démouler la pièce encore chaude dénommée préforme à une température de l'ordre de 400°C à 500°C, on la place entre deux matrices ou parties d'une matrice définissant une empreinte de dimensions légèrement inférieures à celles du moule, qui correspondent à celles de la pièce finale, les deux coquilles ou parties étant fortement pressées l'une contre l'autre pour exercer sur la préforme coulée mise entre les parties de matrices un effet combiné de pressage à coeur et de corroyage superficiel.Remember that this process consists of casting aluminum or aluminum alloy in a mold and after casting, to release the part still hot called preform at a temperature of the order of 400 ° C at 500 ° C, we place it between two matrices or parts of a matrix defining a footprint of dimensions slightly smaller than those of the mold, which correspond to those of the final piece, the two shells or parts being strongly pressed against each other to exert on the casting preform put between the parts of the dies a combined effect of core pressing and surface dressing.

On connaít par ailleurs, par le brevet FR 2.778.125, un procédé du type précité amélioré qui vise à profiter de l'opération de préchauffe pour réaliser en même temps l'opération de traitement thermique économisant ainsi sur l'opération de traitement thermique classique postérieure à l'opération de frappe. Entre la coulée de la préforme et le forgeage, on transfère ladite préforme coulée dans un four assurant la mise en solution de ladite préforme coulée à la température de mise en solution du matériau constitutif et placée ensuite entre les deux parties de la matrice de frappe pour l'opération de forgeage avec refroidissement ambiant, en accéléré ou trempé.We also know, from patent FR 2,778,125, a method of aforementioned improved type which aims to take advantage of the preheating operation for simultaneously perform the heat treatment operation saving thus on the conventional heat treatment operation after the typing operation. Between the casting of the preform and the forging, we transfers said preform poured into an oven ensuring the dissolution of said preform poured at the dissolution temperature of the material component and then placed between the two parts of the striking matrix for the forging operation with ambient, accelerated or tempered.

Ce procédé amélioré dénommé COBAPRESS 2 permet donc de réduire le temps de production et le coût de fabrication de manière significative des pièces, tout en obtenant les mêmes caractéristiques des pièces par rapport à l'enseignement du procédé COBAPRESS décrit dans le brevet EP 119.365.This improved process called COBAPRESS 2 therefore makes it possible to reduce production time and manufacturing cost so significant parts, while obtaining the same characteristics of the parts compared to the teaching of the COBAPRESS process described in the EP patent 119,365.

La mise en oeuvre du procédé précité dans les deux versions requiert de manière courante dans l'activité de forgeage de pulvériser sur la matrice de forge une solution eau plus graphite à l'état liquide, qui a pour but de faciliter le fluage de la matière ainsi forgée et le démoulage de la pièce finale.The implementation of the above method in both versions requires commonly in forging activity to spray on the die forging a water solution plus graphite in the liquid state, which aims to facilitate the flow of the material thus forged and the release of the part final.

En pratique, la pulvérisation de la solution graphite sur la matrice de forge est une opération qui, en fonction de la complexité des formes de la pièce finale brute, est relativement longue et coûteuse, qui ne permet pas systématiquement d'avoir une homogénéité de pulvérisation dans les parties d'accès difficile de la pièce, et enfin qui est très salissante pour le poste de travail.
   On connaít par ailleurs le brevet US 4683742 qui prévoit le préchauffage des billettes avant de leur appliquer un revêtement de type graphite puis les billettes étant forgées ensuite après passage dans une installation de séchage.
In practice, the spraying of the graphite solution on the forging die is an operation which, depending on the complexity of the shapes of the raw final part, is relatively long and costly, which does not systematically allow uniformity of spraying. in the parts of difficult access of the part, and finally which is very messy for the work station.
We also know US Patent 4683742 which provides preheating of the billets before applying a coating of graphite type and then the billets being forged after passing through a drying installation.

Le but recherché selon l'invention était donc d'assurer une optimisation du procédé COBAPRESS initial de coulé-forgé en alliage léger.
   On connaít aussi par le brevet JP 6005433 le forgeage de billettes avec utilisation d'un revêtement graphite.
   Face à l'ensemble de l'art antérieur précité, le demandeur a tenté d'optimiser le procédé du COBAPRESS tel que défini par les brevets antérieurs précités.
   Une première démarche a été de s'orienter sur une amélioration des conditions de dépose du graphite dans la matrice de forgeage par pulvérisation de la solution de graphite sur la matrice de forge, avec un meilleur contrôle de la distribution à l'aide de robots. En pratique, cette solution est peu satisfaisante, car elle nécessite tout de même l'intervention de l'homme, et les coûts et problèmes environnementaux sont toujours là.
The aim sought after according to the invention was therefore to ensure optimization of the initial COBAPRESS process of cast-forged light alloy.
We also know from JP 6005433 the forging of billets with the use of a graphite coating.
Faced with all of the aforementioned prior art, the applicant has attempted to optimize the COBAPRESS process as defined by the aforementioned prior patents.
A first step was to focus on improving the conditions for depositing graphite in the forging matrix by spraying the graphite solution on the forging matrix, with better control of the distribution using robots. In practice, this solution is not very satisfactory, because it still requires human intervention, and the costs and environmental problems are still there.

La démarche du demandeur s'est donc orientée de manière inattendue sur une autre possibilité qui s'intercale entre les deux phases principales de coulée et de forgeage, possibilité qui offre toutes les garanties dans une répartition homogène de la solution graphite sur la préforme, et qui au surplus apporte des caractéristiques particulières intéressantes, en améliorant la productivité du procédé.The applicant's approach was therefore unexpectedly oriented on another possibility which is inserted between the two main phases of casting and forging, possibility which offers all the guarantees in a homogeneous distribution of the graphite solution on the preform, and which at surplus brings interesting particular characteristics, in improving the productivity of the process.

Selon une première caractéristique, le procédé de fabrication des pièces en alliage léger est du type mettant en oeuvre les phases suivantes :

  • coulage de la préforme à une température de l'ordre de 250° à 500°C,
  • transfert de la préforme chauffée dans une matrice définissant une empreinte de dimensions légèrement inférieures à celle du moule, les deux parties de la matrice étant pressées l'une contre l'autre pour exercer l'effort de forgeage, de matriçage de la pièce brute finale,
  • refroidissement de la pièce brute à la température ambiante, le procédé étant caractérisé en ce que après coulage de la préforme chauffée et avant le transfert de la préforme dans une matrice de forge, ladite préforme, à température de fin de coulée est transférée et immergée totalement dans un bac pour graphitage par enduction, pour autoriser le dépôt de la solution graphite sur la préforme, puis en sortie de bac, la température de la préforme permettant l'évaporation naturelle de l'eau de sorte que la préforme est recouverte d'une manière homogène de graphite.
According to a first characteristic, the process for manufacturing the light alloy parts is of the type implementing the following phases:
  • pouring the preform at a temperature of the order of 250 ° to 500 ° C,
  • transfer of the heated preform into a matrix defining an imprint of dimensions slightly smaller than that of the mold, the two parts of the matrix being pressed one against the other to exert the forging effort, forging the final blank ,
  • cooling of the blank to ambient temperature, the process being characterized in that after casting the heated preform and before transferring the preform into a forging die, said preform, at end of casting temperature, is transferred and completely immersed in a graphitation tank by coating, to allow the graphite solution to be deposited on the preform, then at the tank outlet, the temperature of the preform allowing the natural evaporation of water so that the preform is covered with a homogeneous graphite.

Ainsi on a plus besoin de remettre la pièce en chauffe pour la tenue du produit de revêtement ni d'avoir un système pour faire évaporer l'eau, celle-ci étant naturelle.
   Selon une autre caractéristique, le procédé perfectionné de fabrication des pièces en alliage léger est du type mettant en oeuvre les phases suivantes :

  • coulage de préforme à une température de l'ordre de 250° à 500°C ;
  • transfert de la préforme coulée obtenue dans un four assurant la mise en solution de ladite préforme coulée à la température de mise en solution du matériau constitutif ;
  • transfert de la préforme mise en solution en sortie du four dans une matrice définissant une empreinte de dimensions légèrement inférieures à celles du moule, les parties de la matrice étant pressées l'une contre l'autre pour exercer l'effort de forgeage, de matriçage de la pièce brute finale ;
  • refroidissement de la pièce brute obtenue à la température ambiante, en accéléré ou trempé, le procédé étant caractérisé en ce que, après coulage de la préforme chauffée et avant le transfert dans le four tunnel, ladite préforme, à température de fin de coulée, est transférée et immergée totalement dans un bac pour graphitage par enduction, pour autoriser le dépôt de la solution graphite sur la préforme, puis en sortie de bac, à ce stade, la température de la préforme et celle du procédé en amont permettant l'évaporation naturelle de l'eau, de sorte que la préforme est recouverte d'une manière homogène de graphite, ladite préforme étant ensuite remise en température dans le four tunnel assurant l'homogénéisation en température de la préforme graphitée.
Thus, there is no longer any need to reheat the part to hold the coating product or to have a system for evaporating the water, the latter being natural.
According to another characteristic, the improved process for manufacturing light alloy parts is of the type implementing the following phases:
  • casting of preform at a temperature of the order of 250 ° to 500 ° C;
  • transfer of the casting preform obtained in an oven ensuring the dissolution of said casting preform at the dissolution temperature of the constituent material;
  • transfer of the preform dissolved in the outlet of the furnace in a matrix defining an imprint of dimensions slightly smaller than those of the mold, the parts of the matrix being pressed one against the other to exert the effort of forging, forging of the final blank;
  • cooling of the blank obtained at room temperature, accelerated or quenched, the process being characterized in that, after pouring the heated preform and before transferring it to the tunnel oven, said preform, at the end of casting temperature, is transferred and completely immersed in a tray for graphitation by coating, to authorize the deposition of the graphite solution on the preform, then at the exit of the tray, at this stage, the temperature of the preform and that of the upstream process allowing natural evaporation water, so that the preform is homogeneously covered with graphite, said preform then being brought back to temperature in the tunnel oven ensuring the temperature homogenization of the graphite preform.

Ces caractéristiques et d'autres encore ressortiront bien de la suite de la description.These and other characteristics will become apparent from the following the description.

Pour fixer l'objet de l'invention illustré d'une manière non limitative aux figures du dessin où la figure 1 représente le schéma de mise en oeuvre du procédé selon l'invention.To fix the object of the invention illustrated in a nonlimiting manner to the drawing figures where Figure 1 shows the implementation diagram of the process according to the invention.

Le procédé de fabrication des pièces en alliage léger selon l'invention requiert une installation avec cinq zones spécifiques successives couvrant les différentes étapes du procédé.The process for manufacturing the light alloy parts according to the invention requires installation with five successive specific zones covering the different stages of the process.

La première zone (Z1) correspond à la coulée de l'alliage léger dans un moule (1) permettant l'obtention d'une préforme (2) dans les conditions de température rappelées précédemment. The first zone (Z1) corresponds to the casting of the light alloy in a mold (1) enabling a preform (2) to be obtained under the conditions previously recalled.

La seconde zone (Z2) correspond au transfert de la préforme (2) chauffée dans un bac (3) pour immersion et graphitage par enduction de la préforme (2). Le bain est une solution de graphite et eau.The second zone (Z2) corresponds to the transfer of the preform (2) heated in a tank (3) for immersion and graphitation by coating the preform (2). The bath is a solution of graphite and water.

Adjacent au bac permettant le graphitage par enduction, ou dans son plan supérieur, est prévue une phase (Z3) de séchage de la pièce préformée hors du bain.Adjacent to the tray for graphitation by coating, or in its upper plane, a phase (Z3) of drying the preformed part is provided out of the bath.

La zone (Z4) suivante correspond au transfert de la préforme graphitée séchée dans le four tunnel (4) pour homogénéisation en température. La zone (Z5) suivante correspond à la sortie du four tunnel de la préforme pour être ensuite forgée dans une matrice (5) qui fait l'objet d'une lubrification moindre et plus rapide limitée au cordon de bavure selon les conditions évoquées précédemment, puis refroidie à température ambiante ou accélérée ou trempée.The following zone (Z4) corresponds to the transfer of the preform dried graphite in the tunnel oven (4) for homogenization in temperature. The following zone (Z5) corresponds to the exit of the tunnel oven from the preform to be then forged in a matrix (5) which is the object less and faster lubrication limited to the burr bead depending on the conditions mentioned above, then cooled to temperature ambient or accelerated or drenched.

Le procédé optimisé selon l'invention apparaít donner aux pièces ainsi traitées des avantages spécifiques.The optimized process according to the invention appears to give the parts thus treated specific benefits.

Les avantages du procédé optimisé de l'invention sont nombreux .
   On profite de la température de la préforme pour permettre au graphite d'accrocher sur la préforme puis à l'eau de s'évaporer avant les opérations suivantes

  • une qualité d'état de surface plus affiné de la pièce grâce à une homogénisation du dépôt de solution graphite qui a une influence sur les conditions d'essai de rupture ;
  • une meilleure tenue en essai de fatigue ;
  • une longévité accrue de l'outillage de frappe
  • une amélioration de l'environnement ;
  • un gain de productivité ;
  • une formation humaine moindre et moins complexe, ce qui est important en regard du recrutement de main d'oeuvre qualifié, ce qui est toujours difficile ou une automatisation plus simple ;
  • au moment de l'homogénisation en température dans le four tunnel pour homogénéisation en température, la couleur noire issue du bain graphité permet de mieux emmagasiner les calories et donc d'améliorer les caractéristiques de structure et mécaniques de la pièce ;
  • De plus, une nuance de couleur pourrait répondre à un besoin d'esthétique et de coloris. Une plus grande discrétion pour des éléments de sécurité et plus particulièrement de suspension - châssis pour éviter l'effet de brillance sous carrosserie visible par les conducteurs voisins au véhicule concerné.
The advantages of the optimized method of the invention are numerous.
We take advantage of the temperature of the preform to allow the graphite to hang on the preform and then the water to evaporate before the following operations
  • a more refined surface finish quality of the part thanks to a homogenization of the graphite solution deposit which has an influence on the failure test conditions;
  • better resistance in fatigue test;
  • increased longevity of impact tools
  • improvement of the environment;
  • increased productivity;
  • less and less complex human training, which is important with regard to the recruitment of qualified labor, which is always difficult or simpler automation;
  • at the time of temperature homogenization in the tunnel oven for temperature homogenization, the black color resulting from the graphite bath makes it possible to better store calories and therefore to improve the structural and mechanical characteristics of the part;
  • In addition, a shade of color could meet a need for aesthetics and colors. Greater discretion for safety elements and more particularly suspension - chassis to avoid the shine effect under the body visible by drivers next to the vehicle concerned.

Les avantages sont donc nombreux. Le procédé est optimisé selon l'invention et apporte des améliorations inattendues et récentes qui justifient son développement.The advantages are therefore numerous. The process is optimized according to the invention and makes unexpected and recent improvements that justify His development.

Claims (4)

  1. Process for manufacturing light alloys parts involves the following operations :
    Having a casting preform at about 250°C to 500°C
    transferring the cast preform in a furnace to solution heat treat the preform material.
    transferring the cast preform thus obtained from the preheat furnace directly to the forging press between two halves of a die that defines a cavity having dimensions that are slightly less than those of the mould, the two halves being forced together in order to exert an impact forging force
    cooling the rough forging thus obtained at room temperature or accelerated cooling or cooling by quench
    What makes the invention specific is that after the casting of the as said preform and before the forging operation, the as said hot preform is transferred and dipped in a graphite solution container for lubrication.. Outside of the container, the preform temperature allows the water to evaporate and the graphite to stick to the preform creating an homogeneous graphite skin all around it.
  2. Process for manufacturing light alloys parts involves the following operations :
    Having a casting preform at about 250°C to 500°C
    transferring the cast preform in a furnace to solution heat treat the preform material.
    transferring the cast preform thus obtained from the preheat furnace directly to the forging press between two halves of a die that defines a cavity having dimensions that are slightly less than those of the mould, the two halves being forced together in order to exert an impact forging force
    cooling the rough forging thus obtained at room temperature or accelerated cooling or cooling by quench
    What makes the invention specific is that after the casting of the as said preform and before the forging operation, the as said hot preform is transferred and dipped in a graphite solution container for lubrication.. Outside of the container, the preform temperature allows the water to evaporate and the graphite to stick to the preform creating an homogeneous graphite skin all around it.
    The as said preform is after transferred in a tunnel furnace for temperature homogenization.
  3. Process as claimed in claim 1 and 2, characterized in that we can introduce color in the lubrication container.
  4. The process of this invention needs an installation of five successive specific areas .
    The first zone (Z1) corresponds to the casting of the alloy in a mold in order to obtain a preform in hot temperature conditions.
    The second zone (Z2) corresponds to the transfer of the hot preform (2) in a container (3) for a graphite solution dipping for lubrication. The bath is a graphite and water solution.
    On the side of the lubrication container, or above it, is the drying sequence (Z3) of the preform out of the bath.lubrication,
    The next (Z4) area corresponds to the transfer of the graphite lubricated preform in the tunnel furnace (4) for temperature homogenization. The (Z5) area is the exit of the preform from the tunnel furnace then brought to the forging die which is only slightly and therefore quicker lubricated and this only inside the cavity limited to the rib around it according to the above conditions. The part is then cooled naturally, or in an accelerated process or quenched.
EP00993697A 1999-12-29 2000-12-27 Method for making light alloy components Expired - Lifetime EP1250204B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9916831A FR2803232B1 (en) 1999-12-29 1999-12-29 IMPROVED PROCESS FOR MANUFACTURING LIGHT ALLOY PARTS
FR9916831 1999-12-29
PCT/FR2000/003703 WO2001049435A1 (en) 1999-12-29 2000-12-27 Improved method for making light alloy components

Publications (2)

Publication Number Publication Date
EP1250204A1 EP1250204A1 (en) 2002-10-23
EP1250204B1 true EP1250204B1 (en) 2003-07-30

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EP00993697A Expired - Lifetime EP1250204B1 (en) 1999-12-29 2000-12-27 Method for making light alloy components

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US (1) US20020166357A1 (en)
EP (1) EP1250204B1 (en)
JP (1) JP5025870B2 (en)
KR (1) KR100730711B1 (en)
CN (1) CN1221348C (en)
AT (1) ATE246063T1 (en)
AU (1) AU771366B2 (en)
CA (1) CA2396043C (en)
DE (1) DE60004271T2 (en)
ES (1) ES2204753T3 (en)
FR (1) FR2803232B1 (en)
WO (1) WO2001049435A1 (en)

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KR20020086877A (en) 2002-11-20
EP1250204A1 (en) 2002-10-23
FR2803232A1 (en) 2001-07-06
CN1414890A (en) 2003-04-30
DE60004271D1 (en) 2003-09-04
JP5025870B2 (en) 2012-09-12
KR100730711B1 (en) 2007-06-21
FR2803232B1 (en) 2002-04-26
CA2396043A1 (en) 2001-07-12
JP2003527966A (en) 2003-09-24
CA2396043C (en) 2009-04-21
ATE246063T1 (en) 2003-08-15
ES2204753T3 (en) 2004-05-01
WO2001049435A1 (en) 2001-07-12
DE60004271T2 (en) 2004-04-22
AU2860501A (en) 2001-07-16
US20020166357A1 (en) 2002-11-14
AU771366B2 (en) 2004-03-18
CN1221348C (en) 2005-10-05

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