EP1244765B1 - Waschmittel - Google Patents

Waschmittel Download PDF

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Publication number
EP1244765B1
EP1244765B1 EP00989891A EP00989891A EP1244765B1 EP 1244765 B1 EP1244765 B1 EP 1244765B1 EP 00989891 A EP00989891 A EP 00989891A EP 00989891 A EP00989891 A EP 00989891A EP 1244765 B1 EP1244765 B1 EP 1244765B1
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Prior art keywords
coox
sequestrant
formula
detergent composition
mole
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EP00989891A
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English (en)
French (fr)
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EP1244765A1 (de
Inventor
Matthew Unilever Research Port Sunlight TYNAN
Jeremy Robert Unilever Res.Port Sunlight WESTWELL
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Unilever PLC
Unilever NV
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Unilever PLC
Unilever NV
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions

Definitions

  • the present invention relates to laundry detergent compositions giving especial benefits in the laundering of white fabrics.
  • the compositions of the invention which contain a combination of two different sequestrants, have been found to give improved maintenance of colour fidelity, especially of white and light-coloured fabrics, during the wash.
  • the water supply contains a relatively high concentration of iron and this can lead to the discolouration (yellowing) of white and light-coloured fabrics on laundering due to the deposition of Fe(III) salts. This changes the appearance and shortens the useful life of the articles.
  • WO 00/34427A discloses and claims non-bleaching laundry detergent compositions containing from 0.05 to 2.5 wt% of the sequestrant, iminodisuccinate (IDS) or hydroxyiminodisuccinate (HIDS).
  • IDS iminodisuccinate
  • HIDS hydroxyiminodisuccinate
  • IDS is known as a detergency builder from US 3 697 453 (Pfizer) and EP 757 094A (Bayer). IDS as a bleach stabiliser is disclosed in EP 509 382A (W R Grace & Co/Hampshire Chemical Corporation) and WO 97 20907A (Procter & Gamble).
  • the second sequestrant may be a water-soluble polymer containing specified aminocarboxylic structural units, or a so-called “surfactant sequestrant", or sodium glucoheptonate.
  • EP 802 177A discloses water-soluble aminocarboxylic monomers which are condensation products of an amino acid with a dicarboxylic acid anhydride, for example aspartic acid/maleic anhydride, and homo- and copolymers thereof. Copolymers of these monomers with acrylic acid and/or maleic acid exhibit excellent chelating and dispersing properties and may be incorporated in detergent compositions.
  • Magnesium glucoheptonate as a laundry detergent ingredient is disclosed in GB 2 016 540A (Rhône-Poulenc).
  • Peroxyacid bleach particles containing glucoheptonate are disclosed in WO 96 11252A (Eka Nobel AB).
  • the use of sodium glucoheptonate in compositions for hard surface cleaning is disclosed in US 3 956 157 (W R Grace), EP 844 301A (Unilever), GB 2 068 405A (Sandoz).
  • EP 757 094A discloses detergent and cleaning compositions containing iminodisuccinates, and also containing polymers containing succinyl units.
  • a specific example contains 23 wt% of tetrasodium iminodisuccinate and 6 wt% of sodium polyaspartate of molecular weight 3000.
  • the present invention provides a laundry detergent composition
  • a laundry detergent composition comprising surfactant, builder, optionally other detergent ingredients, and:
  • a further subject of the invention is a method of protecting new white or light-coloured textile fabrics from colour degradation on laundering, which comprises laundering the fabrics by hand or machine in a wash liquor containing a detergent composition as defined above.
  • a further subject of the invention is the use of a compound of the formula I above in combination with a second sequestrant for di- and polyvalent metal ions in a laundry detergent composition to protect new white or light-coloured textile fabrics from colour degradation on laundering.
  • colour fidelity is used herein to include both the true colour of coloured fabrics and the whiteness of white fabrics.
  • the benefits of the present invention are especially applicable to white or light-coloured fabrics where iron deposition will cause the greatest deterioration in appearance.
  • the detergent compositions of the invention contain, as an essential ingredient, a compound of the formula I: wherein Y is H or OH, preferably H; and X is H or a solubilising cation, preferably a sodium ion.
  • I iminodisuccinic acid or a water-soluble salt thereof.
  • IDS in the following description, the abbreviation "IDS" will be used to denote this material whether in acid or salt form. IDS is commercially available from Bayer AG, Leverkusen, Germany, and from Nippon Shokubai KK, Japan.
  • the formula I represents hydroxyiminodisuccinic acid or a water-soluble salt thereof.
  • HIDS HIDS
  • Nippon Shokubai KK Japan.
  • the IDS or HIDS may be, and preferably is, in the form of a salt, ie X in the formula I is a stable solubilising cation, preferably an alkali metal cation , more preferably sodium.
  • IDS or HIDS is suitably present in an amount of from 0.05 to 2.5 wt%, preferably from 0.2 to 2.5 wt%, more preferably from 0.3 to 1.5 wt%.
  • compositions of the invention also contain a second compound which is a sequestrant of di- and polyvalent metal ions.
  • the optimum amount of the second sequestrant present will depend on the choice of sequestrant, and may range, for example from 0.01 to 2.5 wt%.
  • the second sequestrant is a water-soluble polymer comprising structural units of the formula II wherein R 1 is H or COOX, R 2 is H or CH 2 COOX but R 1 and R 2 cannot both be H, R 3 is COOX, OH or CH 2 COOX, and each X is individually H or a solubilising cation.
  • the aminocarboxylic monomers from which the structural units of the formula II are derived are condensation products of an amino acid, for example, aspartic acid, serine or glutamic acid with the anhydride of an unsaturated dicarboxylic acid, for example, maleic anhydride, itaconic anhydride or aconitic anhydride.
  • An especially preferred monomer is the condensation product of aspartic acid with maleic anhydride, giving in the polymer structural units of the formula II in which R 1 is COOX, R 2 is H and R 3 is COOX.
  • the water-soluble polymers may be homo- or copolymers. Especially preferred are copolymers comprising at least 15 mole%, preferably at least 20 mole%, of structural units of the formula II.
  • the copolymers may further comprise structural units of unsaturated mono- or dicarboxylic acids.
  • Preferred copolymers contain structural units of maleic acid and/or acrylic acid.
  • Preferred copolymers comprise from 15 to 50 mole% of structural units of the formula II, from 50 to 85 mole% of structural units of acrylic acid, and optionally from 0 to 15 mole% of structural units of maleic acid.
  • terpolymers comprising from 20 to 30 mole% of structural units of the formula II, from 60 to 80 mole% of structural units of acrylic acid, and from 1 to 10 mole% of structural units of maleic acid.
  • An especially preferred polymer contains 25 mole% of structural units of a condensation product of aspartic acid and maleic anhydride (MA-Asp), 5 mole% of maleic acid (MA) units, and 70 mole% of acrylic acid (AA) units.
  • MA-Asp aspartic acid and maleic anhydride
  • AA acrylic acid
  • the polymer suitably has a weight average molecular weight of from 800 to 8 million, preferably from 1000 to 100 000. Polymers having a weight average molecular weight of 2000 to 10 000 are preferred.
  • the polymer may suitably be present in the composition in the invention in an amount of from 0.01 to 2 wt%, more preferably from 0.02 to 1 wt% and most preferably from 0.02 to 0.5 wt%.
  • the second sequestrant is "surfactant sequestrant", that is to say, a sequestrant molecule that includes a hydrophobic moiety, for example, a long-chain alkyl group.
  • surfactant sequestrants are aminopolycarboxylates containing at least three carboxyl groups, and a C 8 -C 18 alkyl chain.
  • a preferred surfactant sequestrant is a compound of the formula III wherein R 4 is a C 8 to C 18 alkyl group, preferably a C 12 -C 14 alkyl group, and each X individually is H or a solubilising cation.
  • This compound, alkylglycine diacetic acid, will be referred to hereinafter as AGDA.
  • AGDA is commercially available from BASF AG, Germany.
  • AGDA or other surfactant sequestrant may suitably be present in the compositions of the invention in an amount of from 0.05 to 2.5 wt%, preferably from 0.1 to 2.0 wt%.
  • the second sequestrant is a compound of the formula IV HO - CH 2 - (CH-OH) 5 - COOX wherein X is H or a solubilising cation.
  • This compound is a glucoheptonate.
  • Glucoheptonate preferably sodium glucoheptonate
  • composition of the invention also contains other conventional detergent ingredients.
  • Essential ingredients are surfactants (detergent-active compounds) and detergency builders, and other conventional ingredients may optionally be present.
  • Detergent compositions of the invention may suitably comprise from 5 to 60 wt% of one or more detergent surfactants and from 10 to 80 wt% of one or more detergency builders, as well as the preferred amounts of the first and second sequestrants, and optionally other detergent ingredients to 100 wt%.
  • compositions of the invention may be substantially free of bleaching ingredients.
  • the detergent compositions will contain, as essential ingredients, one or more detergent active compounds (surfactants) which may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
  • surfactants may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
  • surfactants may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
  • surfactants may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
  • suitable detergent active compounds are available and are fully described in the literature, for example, in "Surface-Active Agents and Detergents", Volumes I and II, by Schwartz, Perry and Ber
  • the preferred detergent active compounds that can be used are soaps and synthetic non-soap anionic and nonionic compounds.
  • Anionic surfactants are well-known to those skilled in the art. Examples include alkylbenzene sulphonates, particularly linear alkylbenzene sulphonates having an alkyl chain length of C 8 -C 15 ; primary and secondary alkylsulphates, particularly C 8 -C 15 primary alkyl sulphates; alkyl ether sulphates; olefin sulphonates; alkyl xylene sulphonates; dialkyl sulphosuccinates; and fatty acid ester sulphonates.
  • Sodium salts are generally preferred.
  • Nonionic surfactants that may be used include the primary and secondary alcohol ethoxylates, especially the C 8 -C 20 aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and more especially the C 10 -C 15 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol.
  • Non-ethoxylated nonionic surfactants include alkylpolyglycosides, glycerol monoethers, and polyhydroxyamides (glucamide).
  • Cationic surfactants that may be used include quaternary ammonium salts of the general formula R 1 R 2 R 3 R 4 N + X - wherein the R groups are long or short hydrocarbyl chains, typically alkyl, hydroxyalkyl or ethoxylated alkyl groups, and X is a solubilising cation (for example, compounds in which R 1 is a C 8 -C 22 alkyl group, preferably a C 8 -C 10 or C 12 -C 14 alkyl group, R 2 is a methyl group, and R 3 and R 4 , which may be the same or different, are methyl or hydroxyethyl groups); and cationic esters (for example, choline esters).
  • R 1 is a C 8 -C 22 alkyl group, preferably a C 8 -C 10 or C 12 -C 14 alkyl group
  • R 2 is a methyl group
  • R 3 and R 4 which may be the same or different, are methyl or
  • R 1 represents a C 8 -C 10 or C 12 -C 14 alkyl group
  • R 2 and R 3 represent methyl groups
  • R 4 presents a hydroxyethyl group.
  • Amphoteric surfactants for example, amine oxides, and zwitterionic surfactants, for example, betaines, may also be present.
  • the quantity of anionic surfactant is in the range of from 5 to 50% by weight of the total composition. More preferably, the quantity of anionic surfactant is in the range of from 8 to 35% by weight.
  • Nonionic surfactant if present, is preferably used in an amount within the range of from 1 to 20% by weight.
  • the total amount of surfactant present is preferably within the range of from 5 to 60 wt%.
  • compositions may suitably contain from 10 to 80%, preferably from 15 to 70% by weight, of detergency builder.
  • the quantity of builder is in the range of from 15 to 50% by weight.
  • the detergent compositions may contain as builder a crystalline aluminosilicate, preferably an alkali metal aluminosilicate, more preferably a sodium aluminosilicate (zeolite).
  • a crystalline aluminosilicate preferably an alkali metal aluminosilicate, more preferably a sodium aluminosilicate (zeolite).
  • the zeolite used as a builder may be the commercially available zeolite A (zeolite 4A) now widely used in laundry detergent powders.
  • the zeolite may be maximum aluminium zeolite P (zeolite MAP) as described and claimed in EP 384 070B (Unilever), and commercially available as Doucil (Trade Mark) A24 from Crosfield Chemicals Ltd, UK.
  • Zeolite MAP is defined as an alkali metal aluminosilicate of zeolite P type having a silicon to aluminium ratio not exceeding 1.33, preferably within the range of from 0.90 to 1.33, preferably within the range of from 0.90 to 1.20.
  • zeolite MAP having a silicon to aluminium ratio not exceeding 1.07, more preferably about 1.00.
  • the particle size of the zeolite is not critical. Zeolite A or zeolite MAP of any suitable particle size may be used.
  • phosphate builders especially sodium tripolyphosphate. This may be used in combination with sodium orthophosphate, and/or sodium pyrophosphate.
  • inorganic builders that may be present additionally or alternatively include sodium carbonate, layered silicate, amorphous aluminosilicates.
  • Organic builders that may be present include polycarboxylate polymers such as polyacrylates and acrylic/maleic copolymers; polyaspartates; monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-di- and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates, hydroxyethyliminodiacetates, alkyl- and alkenylmalonates and succinates; and sulphonated fatty acid salts.
  • polycarboxylate polymers such as polyacrylates and acrylic/maleic copolymers
  • polyaspartates monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-di- and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates, hydroxyethyliminodiacetates, alkyl-
  • Organic builders may be used in minor amounts as supplements to inorganic builders such as phosphates and zeolites.
  • Especially preferred supplementary organic builders are citrates, suitably used in amounts of from 5 to 30 wt %, preferably from 10 to 25 wt %; and acrylic polymers, more especially acrylic/maleic copolymers, suitably used in amounts of from 0.5 to 15 wt %, preferably from 1 to 10 wt%.
  • Builders both inorganic and organic, are preferably present in alkali metal salt, especially sodium salt, form.
  • Detergent compositions according to the invention may also suitably contain a bleach system, although, as previously indicated, non-bleaching formulations are also within the scope of the invention.
  • the bleach system is preferably based on peroxy bleach compounds, for example, inorganic persalts or organic peroxyacids, capable of yielding hydrogen peroxide in aqueous solution.
  • Suitable peroxy bleach compounds include organic peroxides such as urea peroxide, and inorganic persalts such as the alkali metal perborates, percarbonates, perphosphates, persilicates and persulphates.
  • Preferred inorganic persalts are sodium perborate monohydrate and tetrahydrate, and sodium percarbonate.
  • sodium percarbonate having a protective coating against destabilisation by moisture Sodium percarbonate having a protective coating comprising sodium metaborate and sodium silicate is disclosed in GB 2 123 044B (Kao).
  • the peroxy bleach compound is suitably present in an amount of from 5 to 35 wt%, preferably from 10 to 25 wt%.
  • the peroxy bleach compound may be used in conjunction with a bleach activator (bleach precursor) to improve bleaching action at low wash temperatures.
  • the bleach precursor is suitably present in an amount of from 1 to 8 wt%, preferably from 2 to 5 wt%.
  • Preferred bleach precursors are peroxycarboxylic acid precursors, more especially peracetic acid precursors and peroxybenzoic acid precursors; and peroxycarbonic acid precursors.
  • An especially preferred bleach precursor suitable for use in the present invention is N,N,N',N'-tetracetyl ethylenediamine (TAED).
  • TAED N,N,N',N'-tetracetyl ethylenediamine
  • the novel quaternary ammonium and phosphonium bleach precursors disclosed in US 4 751 015 and US 4 818 426 (Lever Brothers Company) and EP 402 971A (Unilever) are also of great interest.
  • Especially preferred are peroxycarbonic acid precursors, in particular cholyl-4-sulphophenyl carbonate.
  • peroxybenzoic acid precursors in particular, N,N,N-trimethylammonium toluoyloxy benzene sulphonate; and the cationic bleach precursors disclosed in EP 284 292A and EP 303 520A (Kao).
  • bleach stabiliser may also be present.
  • suitable bleach stabilisers include ethylenediamine tetraacetate (EDTA) and the polyphosphonates such as Dequest (Trade Mark), EDTMP.
  • the detergent compositions may also contain one or more enzymes. Suitable enzymes include the proteases, amylases, cellulases, oxidases, peroxidases and lipases usable for incorporation in detergent compositions.
  • Preferred proteolytic enzymes are catalytically active protein materials which degrade or alter protein types of stains when present as in fabric stains in a hydrolysis reaction. They may be of any suitable origin, such as vegetable, animal, bacterial or yeast origin. Proteolytic enzymes or proteases of various qualities and origins and having activity in various pH ranges of from 4-12 are available. Proteases of both high and low isoelectric point are suitable.
  • enzymes that may suitably be present include lipases, amylases, and cellulases including high-activity cellulases such as "Carezyme”).
  • detergency enzymes are commonly employed in granular form in amounts of from about 0.1 to about 3.0 wt%. However, any suitable physical form of enzyme may be used in any effective amount.
  • Antiredeposition agents for example cellulose esters and ethers, for example sodium carboxymethyl cellulose, may also be present.
  • compositions may also contain soil release polymers, for example sulphonated and unsulphonated PET/POET polymers, both end-capped and non-end-capped, and polyethylene glycol/polyvinyl alcohol graft copolymers such as Sokolan (Trade Mark) HP22.
  • soil release polymers for example sulphonated and unsulphonated PET/POET polymers, both end-capped and non-end-capped, and polyethylene glycol/polyvinyl alcohol graft copolymers such as Sokolan (Trade Mark) HP22.
  • Especially preferred soil release polymers are the sulphonated non-end-capped polyesters described and claimed in WO 95 32997A (Rhodia Chimie).
  • ingredients that may be present include solvents, hydrotropes, fluorescers, photobleaches, foam boosters or foam controllers (antifoams) as appropriate, sodium carbonate, sodium bicarbonate, sodium silicate, sodium sulphate, calcium chloride, other inorganic salts, fabric conditioning compounds, and perfumes.
  • compositions of the invention may be of any suitable physical form, for example, particulates (powders, granules, tablets), liquids, pastes, gels or bars.
  • the detergent composition is in particulate form.
  • the IDS may be incorporated in particulate compositions in the form of granules containing an inert carrier material.
  • Powders of low to moderate bulk density may be prepared by spray-drying a slurry, and optionally postdosing (dry-mixing) further ingredients, in which case the sequestrants may be either incorporated via the slurry or postdosed.
  • "Concentrated” or “compact” powders may be prepared by mixing and granulating processes, for example, using a high-speed mixer/granulator, or other non-tower processes.
  • the detergent composition is in liquid form.
  • Liquid detergent compositions may be prepared by admixing the essential and optional ingredients in any desired order to provide compositions containing the ingredients in the the requisite concentrations.
  • the sequestrants in the concentrations indicated below, were added (IDS first, then the second sequestrant) to 1 litre of demineralised water in a tergotometer pot, then iron(III) chloride was added in an amount sufficient to give a Fe(III) concentration of 10 ppm.
  • the pH of the solution was adjusted to 9.5 ( ⁇ 0.1) by adding sodium hydroxide solution.
  • Three 10x10 cm pieces (approximately 5 grams) of desized non-fluorescent white cotton cloth were added to provide a liquor to cloth ratio of 200:1.
  • a tergotometer wash was then carried out at 30°C and 90 rpm for 30 minutes. The cloths were then rinsed in demineralised water and dried overnight. Reflectance values at 420nm were taken for the cloths before and after washing, and ⁇ R at 420nm calculated to give an indication of the amount of iron deposition onto the cloth.
  • the ideal here is for a result as close as possible to zero, indicating no deposition of iron and no visible deterioration in appearance.
  • the concentrations for the sequestrants were chosen as follows:
  • Example Sequestrant Concentration Equivalent (wt%) ⁇ R 420 nm A IDS 0.20 -26.01 B MA-Asp/MA/AA 0.02 -42.71 C AGDA 0.20 -22.96 D Na glucoheptonate 0.02 -22.59 1 IDS 0.20 -5.31 MA-Asp/MA/AA 0.02 2 IDS 0.20 -4.99 AGDA 0.20 3 IDS 0.20 -4.16 Na glucoheptonate 0.02

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
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Claims (14)

  1. Wäschereinigungszusammensetzung, umfassend ein oberflächenaktives Mittel, einen Aufbaustoff, gegebenenfalls andere Reinigungsmittelinhaltsstoffe und:
    (a) 0,05 bis 2,5 Gew.-% eines ersten Maskierungsmittels aus Fe(III)-Ionen, das eine Verbindung der Formel I ist:
    Figure 00330001
       worin Y H oder OH ist und jedes X jeweils H oder ein löslichmachendes Kation ist; dadurch gekennzeichnet, daß sie weiterhin:
    (b) 0,01 bis 2,5 Gew.-% eines zweiten Maskierungsmittels aus Fe(III)-Ionen, ausgewählt aus
    (b) (i) wasserlöslichen Polymeren, die Struktureinheiten der Formel II umfassen:
    Figure 00330002
    worin
    R1 H oder COOX, vorzugsweise COOX ist;
    R2 H oder CH2COOX ist, aber R1 und R2 nicht beide H sein können und R2 vorzugsweise H ist;
    R3 COOX, OH oder CH2COOX, vorzugsweise COOX ist und
    jedes X jeweils H oder ein löslichmachendes Kation ist;
    (b) (ii) oberflächenaktiven Maskierungsmitteln der Formel III:
    Figure 00340001
       worin
    R4 eine C8-C18-Alkylgruppe ist, vorzugsweise eine C12-C14-Alkylgruppe, und
    jedes X jeweils H oder ein löslichmachendes Kation ist;
    und
    (b) (iii) Verbindungen der Formel IV: HO-CH2-(CH-OH)5-COOX
       worin X H oder ein löslichmachendes Kation ist,
    umfaßt.
  2. Reinigungszusammensetzung nach Anspruch 1, dadurch gekennzeichnet, daß das erste Maskierungsmittel (a) Iminodisuccinat oder Hydroxyiminodisuccinat ist.
  3. Reinigungszusammensetzung nach Anspruch 1 oder Anspruch 2, dadurch gekennzeichnet, daß das erste Maskierungsmittel (a) in einer Menge von 0,1 bis 2,0 Gew.-% der Zusammensetzung vorliegt.
  4. Reinigungszusammensetzung nach einem der vorherigen Ansprüche, dadurch gekennzeichnet, daß das zweite Maskierungsmittel (b) ein wasserlösliches Polymer (b) (i) ist, umfassend zumindest 15 mol-%, vorzugsweise zumindest 20 mol-% an Struktureinheiten der Formel II.
  5. Reinigungszusammensetzung nach einem der vorherigen Ansprüche, dadurch gekennzeichnet, daß das zweite Maskierungsmittel (b) ein wasserlösliches Polymer (b) (i) ist, das ein Copolymer ist, das ferner Struktureinheiten aus einer ungesättigten Monocarbonsäure und/oder einer ungesättigten Dicarbonsäure umfaßt.
  6. Reinigungszusammensetzung nach Anspruch 5, dadurch gekennzeichnet, daß das Polymer (b)(i) ein Copolymer ist, umfassend
    15 bis 50 mol-%, vorzugsweise 20 bis 30 mol-% an Struktureinheiten der Formel II,
    50 bis 85 mol-%, vorzugsweise 60 bis 80 mol-% an Struktureinheiten aus Acrylsäure, und gegebenenfalls 0 bis 15, vorzugsweise 1 bis 10 mol-% an Struktureinheiten aus Maleinsäure.
  7. Reinigungszusammensetzung nach einem der Ansprüche 4 bis 6, dadurch gekennzeichnet, daß das Polymer (b) (i) ein gewichtsmittleres Molekulargewicht im Bereich von 1.000 bis 100.000, vorzugsweise 2.000 bis 10.000 aufweist.
  8. Reinigungszusammensetzung nach einem der Ansprüche 4 bis 7, dadurch gekennzeichnet, daß das Polymer (b) (i) in einer Menge von 0,01 bis 2 Gew.-%, vorzugsweise 0,02 bis 1 Gew.-%, stärker bevorzugt von 0,02 bis 0,5 Gew.-%, basierend auf der Zusammensetzung, vorliegt.
  9. Reinigungszusammensetzung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß das zweite Maskierungsmittel (b) ein oberflächenaktives Maskierungsmittel (b) (ii) ist, das in einer Menge von 0,05 bis 2,5 Gew.-%, vorzugsweise 0,1 bis 2,0 Gew.-% der Zusammensetzung vorliegt.
  10. Reinigungszusammensetzung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß das zweite Maskierungsmittel (b) eine Verbindung der Formel IV (b) (iii) ist, das in einer Menge von 0,01 bis 2 Gew.-%, vorzugsweise 0,02 bis 1 Gew.-%, stärker bevorzugt von 0,02 bis 0,5 Gew.-%, basierend auf der Zusammensetzung, vorliegt.
  11. Reinigungszusammensetzung nach einem der vorherigen Ansprüche, dadurch gekennzeichnet, daß es 5 bis 60 Gew.-% von einem oder mehreren oberflächenaktiven Reinigungsmitteln und 10 bis 80 Gew.-% von einem oder mehreren Aufbaustoffen umfaßt.
  12. Reinigungszusammensetzung nach einem der vorherigen Ansprüche, dadurch gekennzeichnet, daß es im wesentlichen frei von Bleichmittelinhaltsstoffen ist.
  13. Verfahren zum Schutz neuer weißer oder hellfarbiger Textilgewebe vor der Farbverschlechterung beim Waschen, dadurch gekennzeichnet, daß es das Waschen des Gewebes per Hand oder einer Maschine in einer Waschflüssigkeit, die eine Reinigungszusammensetzung wie in einem der Ansprüche 1 bis 12 beansprucht, umfaßt.
  14. Verwendung einer Verbindung der Formel I:
    Figure 00360001
       worin Y H oder OH ist und jedes X jeweils H oder ein löslichmachendes Kation ist; in Kombination mit einem zweiten Maskierungsmittel für Fe(III)-Ionen, ausgewählt aus:
    (i) wasserlöslichen Polymeren, die Struktureinheiten der Formel II umfassen:
    Figure 00360002
    worin
    R1 H oder COOX, vorzugsweise COOX ist;
    R2 H oder CH2COOX ist, aber R1 und R2 nicht beide H sein können und R2 vorzugsweise H ist;
    R3 COOX, OH oder CH2COOX, vorzugsweise COOX ist und jedes X jeweils H oder ein löslichmachendes Kation ist;
    (ii) oberflächenaktiven Maskierungsmitteln der Formel III:
    Figure 00370001
    worin R4 eine C8-C18-Alkylgruppe ist, vorzugsweise eine C12-C14-Alkylgruppe, und jedes X jeweils H oder ein löslichmachendes Kation ist; und
    (iii) Verbindungen der Formel IV: HO-CH2-(CH-OH)5-COOX
    worin X H oder ein löslichmachendes Kation ist;
    in einer Wäschereinigungszusammensetzung zum Schutz neuer weißer oder hellfarbiger Textilgewebe vor Farbverschlechterung bei der Wäsche.
EP00989891A 1999-12-21 2000-11-24 Waschmittel Expired - Lifetime EP1244765B1 (de)

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GB9930240 1999-12-21
GBGB9930240.8A GB9930240D0 (en) 1999-12-21 1999-12-21 Detergent compositions
PCT/EP2000/011793 WO2001046371A1 (en) 1999-12-21 2000-11-24 Detergent compositions

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EP1244765B1 true EP1244765B1 (de) 2004-09-08

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GB0013501D0 (en) 2000-06-02 2000-07-26 Unilever Plc Detergent compositions
GB0121394D0 (en) * 2001-09-04 2001-10-24 Unilever Plc Improvements relating to fabric treatment compositions and process of fabric treatment
ITCR20060016A1 (it) * 2006-06-07 2007-12-08 Silvia Palladini Formulazioni di detersivi a basso impatto ambientale
DE102007047433A1 (de) * 2007-10-04 2009-04-09 Lanxess Deutschland Gmbh Flüssigwasch- und Flüssigreinigungsmittel

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Publication number Priority date Publication date Assignee Title
US3697453A (en) * 1971-03-08 1972-10-10 Pfizer Iminodisuccinic acid salts as detergent builders
FR2419974A1 (fr) * 1978-03-14 1979-10-12 Rhone Poulenc Ind Nouvel agent sequestrant pour compositions lessivielles a base d'un compose gluco-heptonique de magnesium
DE4024552A1 (de) * 1990-08-02 1992-02-06 Henkel Kgaa Derivat der aminobernsteinsaeure als komplexierungsmittel
DE4311440A1 (de) * 1993-04-07 1994-10-13 Henkel Kgaa Gerüststoff für Wasch- oder Reinigungsmittel
DE19528059A1 (de) * 1995-07-31 1997-02-06 Bayer Ag Wasch- und Reinigungsmittel mit Iminodisuccinaten
JPH09279183A (ja) * 1996-04-10 1997-10-28 Kao Corp 高密度粒状洗剤組成物
US5856418A (en) * 1996-04-16 1999-01-05 Nippon Shokubai Co., Ltd. Water-soluble monomer, water-soluble polymer and their production process and use
DE19807104A1 (de) * 1998-02-20 1999-08-26 Basf Ag Feste Textilwaschmittel-Formulierung auf Basis von Glycin-N,N-diessigsäure-Derivaten als Buildern mit stark reduziertem Anteil an Silicat-Buildern
TR200101590T2 (tr) * 1998-12-10 2001-11-21 Unilever N.V. Deterjan bileşimleri
JP2000290698A (ja) * 1999-04-02 2000-10-17 Asahi Denka Kogyo Kk 粉末洗浄剤組成物

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EP1244765A1 (de) 2002-10-02
GB9930240D0 (en) 2000-02-09
WO2001046371A1 (en) 2001-06-28
TR200201626T2 (tr) 2003-02-21
ES2225293T3 (es) 2005-03-16
DE60013646T2 (de) 2005-02-03
DE60013646D1 (de) 2004-10-14

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